Advanced cleaning product formulations

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Author: Ernest W. Flick

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ADVANCED CLEANING RODUCT FORMULATIONS

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ADVANCED CLEANING PRODUCT FOR MULATlONS Volume 5

Ernest W. Flick

NOYES PUBLICATIONS WILLIAM ANDREW PUBLISHING, LLC Nomich, New York, U.S.A.

Copyright 0 1999 by Ernest W. Flick No part of this book may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying, recording or by any information storage and retrieval system, without permission in writing from the Publisher. Library of Congress Catalog Card Number: 89-30274 ISBN: 0-8155-1431-X Printed in the United States Published in the United States of America by Noyes Publications/William Andrew Publishing, LLC 13 Faton Avenue, Norwich, New York 13815

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Library of Congress Cataloging-in-Publication Data (Revised for vol. 5) Flick, Ernest W. Advanced cleaning product formulations Includes bibliographical references and index. 1. Cleaning compounds. I. Title TP990.F56 1989 668'1 89-30274 ISBN 0-8155-1186-8 (v. 1) ISBN 0-8155-1346-1 (v. 2) ISBN 0-8155-1382-1 (v. 3) ISBN 0-8155-1396-8 (v. 4) ISBN 0-8155-1431-X (v. 5)

To the late Ernie and Jeanne and Allyn and Barbara and Chris and Rachel

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reface ohme 5) presents more than 423 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volumes 1, 2, 3 and 4 published earlier. ~ ~ in the cleaning ~ ~ industry ~ has gradually a product been~undergoing~ significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost/performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presents manufacturers' suggested formulations which might meet new performance criteria.

The formulations in this book are divided into the following sections and chapters, with the number of formulations indicated in ( ):

H.

Household and Industrial Cleaners and Polishes 1. Bathroom Cleaners (9) 2. Dairy, Food and General Industrial Cleaners (27) 3. Degreasers (9) 4. Dishwashing Detergents (34) 5. General Purpose Cleaners (31) 6. Glass CleanersPoiishes (12) ard Surface Cleaners (21) 8. Laundry Products (55) 9. Metal Cleaners and Polishes (72) 10. Oven, Grill and Hot Plate Cleaners (9) 11. Polishes, Coatings and Finishes (6) 12. Rinse Aids (2) 13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (33) 14. Miscellaneous (33)

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Preface Transportation Cleaners and Polishes 15. Auto Cleaners and Polishes (6) 16. Car and Truck Wash Compounds (49) 17. Whitewall Tire Cleaners (3) 18. Miscellaneous (12)

Each formula is located in the chapter which is most applicable. The reader, seeking a formula for a specific end use, should check each chapter which could possibly apply. In addition to the above, there are two other sections which will be helpful to the reader.

111. A chemical trademark section where each tradenamed raw material included in the book is listed with a chemical description rand the supplier's name. The specifications which each raw material meets are included, if applicable.

IV. Main office addresses of the suppliers of trademarked raw materials. Each formulation in the book lists the following information, as available, in the manufacturer's own words: Description of end use and most outstanding properties. The percent by weight or volume of each raw material included in the formula, rounded to a decimal figure. Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type. The formula source, which is the company or organization that supplied the formula. The secondary source may be the originating company andlor the primary source's publication title, or both. A formula number is included, if applicable. The table of contents is organized in such a way as to serve as a subject index. My fullest appreciation is expressed to the companies and organizations who supplied the original starting formulations included in this book. I also thank the suppliers of the raw materials included in these formulations, who furnished information describing their trademarked raw materials. Newburyport, Massachusetts July 1999

Ernest W. Flick

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NOTICE To the best of our knowledge the information in this publication is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequences arising from, such information. This book is intended for informational purposes only. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Publisher. Final determination of the suitability of any information or product for use contemplated by any user. We recommend that anyone intending to rely on any recommendation of materials QB procedures mentioned in this publication should satisfy himself as to such suitability, and that he can meet all applicable safety and health standards. X

ntents and Subject Index SECTION I OUSEHOLD AND INDUSTRIAL CLEANERS AND POLISHES

B

OM CLEANERS:

...............................

Toilet Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . athroom Cleaner with Disinfectant . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Acid Bathroom Cleaner . . . . . . . . . . . . . . . . . . . . . . . Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ o w ~ ~ ~ Cleaner l d e w ................................. Tile Porcelain and Bathroom Cleaner. Acid . . . . . . . . . . . . . . . . . . Tub and Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hypochlorite Tub and Tile Cleaner and Mildew Stain Remover . . . Toilet Bowl Cleaner with Bleach .........................

2.

.

2 3 4

4 5 5 6 6 6 7

FOOD AND GENERAL INDUSTRIAL CLEANERS . . . . . 8 Acid Industrial and Household Cleaners Oxalic Acid Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 ust Removal Jelly . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 Cleaners for Industrial Application 10 Desinfecting Cleaner. Acid . . . . . . . . . . . . . . . . . . . . . . . . . . Dipping Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Destainer sphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 uced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . 11 Zero phosphate. powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . Baking Pan Cleaner phosphate. powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Cleaners BBll Purpose-Food Process Plant . . . . . . . . . . . . . . . . . . . . . . Hard Surface Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . .

xi

12 12

13 13

xii

Contents and Subject Index High Foaming Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . 14 Heavy Duty Alkaline Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . 44 Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 Industrial and High Pressure Cleaners Cleaner, Strongly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . 15 Cleaner. Weakly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 Cleaner. Strongly Alkaline (Phosphate-Free) . . . . . . . . . . . . . 15 Cleaner. Weakly Alkaline (Phosphate-Free) . . . . . . . . . . . . . . 45 Metal Cleaner (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 Food Industry Cleaner (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 Milk Can Cleaner (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 Powdered Enzyme Presoaks Economy Presoak . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 Premium Presoak . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 Enzyme Prespotter for Oily/Smutty Soils . . . . . . . . . . . . . . . . IS Sanitizing Cleaner (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 Sanitizing Agent (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

.

3 DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 Aqueous Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 Aqueous Degreaser d-Limonene Microemulsion . . . . . . . . . . . . . . . . . . . . . . . . . 21 Water Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 Degreaser Concentrate (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . 22 Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . . . . . 22 Solvent Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 Solvent Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 Engine Cleaner and Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . 24

4. DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . . .

25

Automatic Dishwash Detergent-Consumer (Zero Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . 26 Automatic Dishwash Detergent-Consumer (Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . . . . . 26 Automatic Dishwash Detergent-Industrial & Institutional (Phosphate. Solid Block . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27 Automatic Dishwashing Detergent-Industrial & Institutional (Liquid~7

Contents and Subject Index

xiii

Automatic Dishwash Detergent-Industrial & Institutional (Zero.Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . 28 Automatic Dishwash Detergent-Industrial & Institutional (Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . . . . . 28 Automatic Dishwashing Gel with Chlorine Bleach . . . . . . . . . . . . 29 Clear. Colorless Manual Dish Wash . . . . . . . . . . . . . . . . . . . . . . 30 Powder Stainless Silverware Pre-Soak . . . . . . . . . . . . . . . . . . . . 30 Low Alkaline Warewashing Block . . . . . . . . . . . . . . . . . . . . . . . 30 Dish Washing Agents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 sh w/Amine Oxide/LABS/SLES . . . . . . . . . . . . . . . . . . . 33 Dish Wash w l h i n e Oxide/LABS/ALES . . . . . . . . . . . . . . . . . . 33 Hand Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 Foam Booster: E-14-5 in Hand Dishwashing Liquids 34 Economy Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Standard Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 90% Premium Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 34 Rernium Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 Hand Dish Detergent Formulations Clear Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 Pearlescent Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 Hand Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 Rand Dishwashing Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 Light Duty Liquid. Premium Hand Dishwash . . . . . . . . . . . . . . . 38 Light Duty Liquid Low Cost Hand Dishwash . . . . . . . . . . . . . . . 38 Liquid Automatic Dishwasher Detergent . . . . . . . . . . . . . . . . . . . 39 Manual Dishwashing Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40 Manual Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 Now-Chlorinated Machine Dishwashing Compound. Liquid . . . . . 42 Chlorinated Machine Dishwashing Compound. Powder . . . . . . . . 42 Non-Chlorinated Machine Dishwashing Compound. Powder . . . . 42 Premium Hand Dishwashing Detergent . . . . . . . . . . . . . . . . . . . . 43 Dish Washing Agents for Manual Use . . . . . . . . . . . . . . . . . . . . 43

.

5 GEN LEANERS . . . . . . . . . . . . . . . . . . . . . . . Abrasive Cleaner with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . . rasive Cleaner Without Bleach . . . . . . . . . . . . . . . . . . . . . . . . Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . All Purpose Cleaner - No Rinse . . . . . . . . . . . . . . . . . . . . . . . . . AB1-Purpose Disinfectant Cleaner . . . . . . . . . . . . . . . . . . . . . . . . All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . &alp Purpose Cleaner w/Amide/€’hosphate Ester . . . . . . . . . . . . . . A1 Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

44 45 46 47 48 49 49 50 50

xiv

Contents and Subject Index All Purpose Cleaner Concentrate

(Phosphate. Liquid. Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . 51 All Purpose Concentrate (Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5% Calcium Carbonate Abrasive Cleaner Without Bleach . . . . . . . . . 52 Citric Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 General Purpose Cleaner (Consumer Low Alkaline. Non-Phosphate Powder) . . . . . . . . 54 General Purpose Cleaner (Consumer High Alkaline. Non-Phosphated Powder) . . . . . . . 54 General Purpose Spray & Wipe Cleaner . . . . . . . . . . . . . . . . . . . 55 General Purpose Spray & Wipe . . . . . . . . . . . . . . . . . . . . . . . . . 56 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 Hypochlorite Vertical Surface Cleaner . . . . . . . . . . . . . . . . . . . . 57 Pump Spray All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 57 Liquid Cleanser with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 Pine Oil Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Disinfecting Cleaner. Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Sodium Bicarbonate Abrasive Cleaner Without Bleach . . . . . . . . 60

.

6 GLASS CLEANERS/POLISHES . . . . . . . . . . . . . . . . . . . . . . . . . . 61 Anti.Fogging. Anti-Static Glass Cleaner . . . . . . . . . . . . . . . . . . 62 Glass Cleaner. Ready to Use . . . . . . . . . . . . . . . . . . . . . . . . . . . 62 Glass Cleaner Concentrate (Non-Ammoniated) . . . . . . . . . . . . . . 63 Glass Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 Ammoniated Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 Glass and Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 Premium Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . 65 Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 Windows/Glass Glass Cleaner (Concentrate) . . . . . . . . . . . . . . . . . . . . . . . . . 66 Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . 66 Windshield Washer Concentrate (Low VOC) . . . . . . . . . . . . . . . . 66

.

7 HARD SURFACE CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . Alkaline Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . Hard Surface Cleaner Concentrate (All Purpose Type) . . . . . . . . . Concentrated Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . Hard Surface Cleaner-Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . Pine Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

67 58 68

69 69 69 70

Contents and Subject Index Bard Surface Cleaner w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . Hard Surface Cleaner Concentrate w/d’Limonene . . . . . . . . . . . . . Bard Surface Cleaner Concentrate (Phosphate. Liquid) . . . . . . . . . Hard Surface Spray Cleaner (Phosphate. Liquid) . . . . . . . . . . . . . Hard Surface Cleaner Concentrate wmipentene . . . . . . . . . . . . . . Alkaline Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Abrasive Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Tile and Sanitary Cleaners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . Hard Surface Cleaner-All Purpose . . . . . . . . . . . . . . . . . . . . . . . old and Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . .

PRODUCTS

................................

gent for Fine Fabrics-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . Detergent for Fine Fabrics-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Laundry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 h 1 Liquid Laundry Detergent with Enzyme & Optical . . . . . . . Surfactant Rich Detergent for Nursing Homes . . . . . . . . . . . . . . . Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . . dustrial Heavy Duty Laundry Liquid . . . . . . . . . . . . . . . . . . . . Industrial Laundry Detergents High Caustic Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . Mixed Builder Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . Washing Paste with Bleaching Agent . . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Consumer (Liquid) . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Consumer (Zeolite Built. Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . Laundry Detergent-Consumer (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Consumer phosphate. Powder) ............................... bundry Break-Industrial & Institutional (Liquid. Phosphate) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Break-Industrial & Institutional (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Industrial & Institutional (NTAJZeolite. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Break-Industrial & Institutional (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Industrial & Institutional (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Industrial & Institutional (Sodium Carbonate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . .

xv

71 71 72 72 73 73 74 74 74 75 76 77 78 78 79 80 80 80 81 82 82 82 83 83 84

84 85

85 86 86 87

87

mi

Contents and Subject Index Laundry Break-Industrial & Institutional phosphate. Powder. High Alkalinity) . . . . . . . . . . . . . . . . . . 88 Laundry Break-Industrial & Institutional (Zero Phosphate Powder. High Alkalinity . . . . . . . . . . . . . . . . 88 Laundry Detergent-Industrial & Institutional (Reduced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . 89 Laundry Detergent-Industrial & Institutional (NTA, Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 Laundry Detergent-Industrial & Institutional (Sodium Carbonate with Flow Aid. Powder) . . . . . . . . . . . . . . 90 Laundry Detergant-Industrial & Institutional (Phosphate. Solid Block) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 964 Laundry Detergent-Industrial and Institutional (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 91 Laundry Detergent-Industrial and Institutional (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 911 Laundry Detergent-Industrial & Institutional (Phosphate Built. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . 92 Laundry Detergent-Industrial & Institutional (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92 Laundry Builder-Industrial & Institutional 93 (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Laundry Detergent-Industrial & Institutional (Zeolite Built. Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . 93 Laundry Prespotter Sprayable Gel . . . . . . . . . . . . . . . . . . . . . . . . 94 Laundry Prespotter Sprayable Liquid . . . . . . . . . . . . . . . . . . . . . 95 Light Duty Liquid Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 Calsoft LAS-99 Based . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98 Dry Cleaner: Pre Spot-Water Soluble . . . . . . . . . . . . . . . . . . . . . 99 99 Wool Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Two Part Industrial Laundry Detergents Break Formulations Highly Alkaline Break . . . . . . . . . . . . . 5100 Mixed Builder Break . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 Detergent Additive . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 Ultra Liquid Laundry Detergent . . . . . . . . . . . . . . . . . . . . . . . . 101 Fine Fabric Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1641

.

9 METAL CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . Acid Metal Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dipping Cleaner for Silver . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aluminum CleanerBrightener . . . . . . . . . . . . . . . . . . . . . . . . . Powdered Metal Cleaning Concentrate . . . . . . . . . . . . . . . . . . . Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

802 p03

103 104 104 1104

Contents and Subject Index Aluminum Cleaner Concentrate F-498 . . . . . . . . . . . . . . . . . . . Aluminum Wash F-499 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ffing Compound Remover . . . . . . . . . . . . . . . . . . . . . . . . . . t Alkaline Paint Stripper Concentrate . . . . . . . . . . . . . . . . . . Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . . . . Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Semi-synthetic Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . Cutting Oil Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . General Purpose Machine Cleaner . . . . . . . . . . . . . . . . . . . . . . Aircraft Cleaner Type IV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . General Purpose Synthetic Fluid (A) . . . . . . . . . . . . . . . . . . . . . General Purpose Synthetic Fluid (€3) . . . . . . . . . . . . . . . . . . . . . Copper Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . General Purpose Synthetic Fluid (C) . . . . . . . . . . . . . . . . . . . . . General Purpose Synthetic Fluid @) . . . . . . . . . . . . . . . . . . . . . Metal Cleaner (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aluminum Cleaner phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . eta1 Cleaner phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . Non-Phosphorous Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . Alkaline Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . Semi Synthetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Silver and Metal Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Soluble Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Soluble Oil Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . Synthetic Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . Synthetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Synthetic DrawindStamping Fluid . . . . . . . . . . . . . . . . . . . . . . Oil Based DrawindStamping Fluid . . . . . . . . . . . . . . . . . . . . . . Spray Metal Cleaning Concentrate . . . . . . . . . . . . . . . . . . . . . . Synthetic Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Synthetic Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Universal Scouring Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Water Soluble Stamping Fluid . . . . . . . . . . . . . . . . . . . . . . . . . -40 Type Lubricant Concentrate . . . . . . . . . . . . . . . . . . . . Penetrating Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Burnishing Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

xvii 105 105 106 106 106 107 109 109 110 110 111 111 111 112 112 113 113 114 115 116 116 117 119 120 122 122 123 124 124 124 125 130 133 133 134 134 134 134

xviii

.

Contents and Subject Index

OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Non-Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . High Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aerosol Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . Oven Cleaner w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . . . . . Oven Cleaner wphosphate . . . . . . . . . . . . . . . . . . . . . . . . . . . .

135 136 B36 137 138

11 POLISHES. COATINGS AND FINISHES . . . . . . . . . . . . . . . . Furniture Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . LeatherPlastic Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Marble Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Rust Removing Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Scratched Wood Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . High Gloss. Detergent Resistant Polish . . . . . . . . . . . . . . . . . . .

141

10

.

.

12

.

13

RINSE AIDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

138

139 139

140 140

142 143 144 144

145 145

1.46

Rinse Aid. Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Rinse Aid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

147 147

RUG. FLOOR, CARPET. UPHOLSTERY SHAMPOOS AND CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

n48

Carpet Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Low Foam Carpet Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . Steam Rug Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Steam Rug Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Carpet Cleaners for the Spray-Extraction Process . . . . . . . . . . . Carpet Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Rug Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Carpet Shampoo. High Foam . . . . . . . . . . . . . . . . . . . . . . . . . . Carpet Spot Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Carpet & Upholstery Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . Vinyl Dressing (B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Carpet & Upholstery Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Steam Carpet Cleaner For Hard Water Systems . . . . . . . Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy-Duty Floor Scrubber . . . . . . . . . . . . . . . . . . . . . . . . . . . Household Carpet Freshenedhtistat . . . . . . . . . . . . . . . . . . . .

149 149 149 149 150 150 1151

151 152 1152 153 153 154 154

155 155 155 156

Contents and Subject Index Pump Spray Carpet Antistat . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Leather. Vinyl. and Plastic Cleaner and Restorer . . . . . . . Liquid Leather. Vinyl. and Plastic Cleaner . . . . . . . . . . . . . . . . Low Cost Extraction Carpet Cleaner . . . . . . . . . . . . . . . . . . . . . Premium. Medium Duty Steam Extraction Carpet Cleaner . . . . . uty Steam Extraction Carpet Cleaner . . . . . . . . . . . . . . aming Carpet Extractor Detergent . . . . . . . . . . . . . . . . . m Cleaner (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . No Rinse Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . No-Rinse Floor Cleaner Degreaser ...................... Wax Stripper (A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ax Stripper (B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concentrated Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . .

CEELANEQUS

.................................

acteriostatic Concentrate w/Pine Oil . . . . . . . . . . . . . . . . . . . . General Disinfectant Solution . . . . . . . . . . . . . . . . . . . . . . . . . . Hospital Disinfectant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cutting Oil Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concrete Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . White Wall Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . d ' l h o n e n e Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . Paste Nand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dipentene Microemulsion Formulations -alkaline Formulations . . . . . . . . . . . . . . . . . . . . . . . . . line Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . Hydrocarbon Solvent Microemulsions Emsol D-110 Formulations . . . . . . . . . . . . . . . . . . . . . . . . Isopar M Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . h w Viscosity Silicone Emulsion Using Pemulen Resins . . . . . . Luminizing Pet conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . Pea Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iao-Emulsions with d-Limonene ..................... Micro-Emulsions with Pine Oil . . . . . . . . . . . . . . . . . . . . . . . . Plastic Bottle Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Bottle Wash Formulations w Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . oderate Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Terpene Microemulsions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concentrated Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . Wax Emulsion Using Pemulen Resins . . . . . . . . . . . . . . . . . . . .

xix

156 157 157 158 158 158 159 159 160 160 160 161 161 161 162 163 163 163 164 164 164 164 165 165 166 167 168 169 170 171 171 172 173 174 174 174 175 175 176

xx

Contents and Subject Index SECTION 11 TRANSPORATION CLEANERSl AND POLISHES

.

15 AUTO CLEANERS AND POLISHES

.

16

....................

Chrome Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Car Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Spray Cleaner for Aluminum Trucks . . . . . . . . . . . . . . . Aluminum Cleanermrightener . . . . . . . . . . . . . . . . . . . . . . . . . Non-Phosphorous Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . Mild Abrasive Automobile Polish . . . . . . . . . . . . . . . . . . . . . . .

CAR AND TRUCK WASH COMPOUN S . . . . . . . . . . . . . . . . Car Shampoo Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . Automobile Car Wash Concentrate . . . . . . . . . . . . . . . . . . . . . . Car Wash (Calsoft LAS-99-Based) . . . . . . . . . . . . . . . . . . . . . Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . Car Wash (Calsoft T-60-Based) . . . . . . . . . . . . . . . . . . . . . . . CarWash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Paste Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Car Wash w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . Windshield Washer Formulation . . . . . . . . . . . . . . . . . . . . . . . . Car Wash Concentrate w/Alcohol Ethoxylate . . . . . . . . . . . . . . Car and Truck Wash Formula . . . . . . . . . . . . . . . . . . . . . . . . . Car Wash powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . Car Wash and Care Car Shampoo with Water-Repellent Effect . . . . . . . . . . . . . Rinse-off Agent (Water Repellent) . . . . . . . . . . . . . . . . . . . Rinse-off Agent (Water-Repellent) Without Hydrocarbons . Windshield-Cleaner (Summer) . . . . . . . . . . . . . . . . . . . . . . Windshield-Cleaner (Winter) . . . . . . . . . . . . . . . . . . . . . . . Insect Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Wheel Cleaner, Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . Tar Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Car Wax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Auto Wipe & Shine Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concentrated Traffic Film Removers . . . . . . . . . . . . . . . . . . . . Foamy Brush Car Wash, Liquid . . . . . . . . . . . . . . . . . . . . . . . . Low Cost Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . General Purpose Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~

11’9’8 179 180 181

181 1181 182 %83 184

184 185

185 185 186 186 187 187

187 133

189 189

189 190

190 190 190 19B

191 191 191

192 192 193 194 194 195 195

Contents and Subject Index

n

xxi

Boat Wash & Car Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Truck Wash. Liquid . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Truck Wash. Powder . . . . . . . . . . . . . . . . . . . . . . . Premium Car Wash Concentrate . . . . . . . . . . . . . . . . . . . . . . . . Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Auto Shampoo Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . Touchless Vehicle Wash Detergent (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . Vehicle Wash Detergent (Low pH) (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . Tmck/Bus Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Economy Tnuck/Bus Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . Car Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Car Wash and Wax Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . Vehicle Wash Detergent (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (Liquid. low foam) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Vehicle Wash Detergent (Low pH) (Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . Touchless Vehicle Wash Booster/Additive (Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . .

195 196 196 197 197 197

ITEWALL TIRE CLEANERS . . . . . . . . . . . . . . . . . . . . . . Mitewall Tire Cleaner (Zero Phosphate Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . phosphate Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

202

SCEEUNEOUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Aircraft Cleaner (Reduced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Auto Care: Hnterior/Exterior Rubber & Vinyl Protectant . . . . . . . Boat Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Concrete CIeanerDegreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . Garage Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Acid Rust Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ConcreteDriveway Cleaners For Other Stains . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Heavy Duty Concrete Cleaner (Phosphate Free) Formula 1C . . . Vinyl Dressing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ressing (A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

204

198 198 199 199 199 199 200 200 201 201

203 203 203

205 205 206 207 208 208 208 209 209 210 210

xxii

Contents and Subject Index

SECTION III: TRADEMARKED RAW MATE SECTION IV: SUPPLIERS' ADDRESSES

s . . . . . . . . . . 2nn .

. ... . . . . . . . . . . . . . a

~

~

229

ection I

Household and Industrial Cleaners and Polishes

1

1. Bathroom Cleaner

a

Bathroom Cleaners

3

A c i d i c Toilet Bowl C l e a n e r Carbopol r e s i n s a r e used t o t h i c k e n t h i s a c i d i c t o i l e t bowl c l e a n e r f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p r o v i d e s v e r t i c a l c l i n g t o increase t h e contact time o f t h e detergent on t h e s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e .

5

I n s r e d ie n t :

DI Water Carbopol 6 7 4 ( 1 ) C i t r i c A c i d (50%) A l k y l benzene s u l f o n i c a c i d 97%) ( 2 ) Sodi um d o d e c y l d i p h e n y l o x i de d i s u l f o n a t e (45%) ( 3 ) B r o o k f ie l d v i s c o s i t y ( R V T 20 rpm): 4,000 P r o d u c t pH: 1 .O-2.0 Product C l a r i t y : C l e a r (1)

43.00 2.00

50.00 2.00 3.00

cps

BFGoodrich

i2j Stepan Co.: B i o s o f t 5-100 ( 3 ) Dow Chemical Co.:

Dowfax 2A1

Procedure: 1 . M i x t h e D I w a t e r and c i t r i c a c i d s o l u t i o n t o g e t h e r . 2 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e w a t e r / c i t r i c a c i d solu t i o n . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 30 m i n u t e s . The p r o d u c t w i l l become i n c r e a s i n g l y t h i c k e r w i t h t i m e - h e a t i n g t o 40-50C w i l l h a s t e n t h e p r o c e s s . 3 . Add t h e s u l f o n i c a c i d and t h e d i p h e n y l o x i d e d i s u l f o n a t e surfactant. 4 . Add c o l o r and f r a g r a n c e , as d e s i r e d . Cool t h e p r o d u c t t o room t e m p e r a t u r e .

Total Actives: C i t r i c a c i d : 25.00 A l k y l benzene s u l f o n i c a c i d : 1.94 Dodecyl d i p h e n y l o x i d e d i s u l f o n a t e :

SOURCE:

1.35

BFGoodrich S p e c i a l t y Chemicals:

DET-351

4

Advanced Cleaning Product Formulatioris

Bathroom Cleaner with Disinfectant Inqredi ents: A: Veegum T, Magnesium Aluminum Silicate Rhodopol 23, Xanthan Gum Deionized Water B: Diatomaceous Earth (Super Floss) Tetrasodium EDTA (Hampene 100) Sodium o-Phenylphenate (Dowicide A) Sodi um A1 kyl benzene Sul fonate (Cal soft L - 4 0 ) Butyl Cellosolve

Wt .%* 1

.oo

0.35 86.65

5.00 2.75 0.25 3.00 1

.oo

Procedure: 1 . Dry blend the Veegum T and Rhodopol 23 and add them to the water while stirring with an homogenizer at 5000 rpm. Continue mixing for 30 minutes. 2. Slowly add the Part 8 ingredients in the order shown, mixing each for 5 minutes. * A s received basis SOURCE: R.T. Vanderbilt Co., Inc.: Formulation No. 363 Heavy Duty Acid Bathroom Cleaner Inqredi ents: Hydroxyacetic acid Sulfamic acid Ammonyx LO Water, D.I.

Wt% 5.0 5.0 10.0 80.0

Mixing Procedure: Add ingredients to water in the order given and mix until homogeneous. Properties: Appearance: Clear liquid pH, as is: 1.0 Solids, %: 1 4 . 0 Density, lbs/gal: 8.7 Use Instructions: Use as is o r dilute as needed. Do not use on natural marble or polished aluminum. Use gloves. Do not mix with bleach. Storage Stability: Formulation is freeze/thaw stable through 3 cycles. Formulation is stable for 3 weeks @ 50C. SOURCE: Stepan Co.: Formulation No. 200

Bathroom Cleaners

M i 1dew Remover Ingredients: Van Gel 0 D e i o n i z e d Water Sodium H y d r o x i d e , 50% S o l u t i o n Sodium H y p o c h l o r i t e , 10% S o l u t i o n ( H y p u r e N ) Vanseal NALS-30

Wt%* 3.00 85.55 0.45 10.00 1.oo

Procedure: 4 . S l o w l y s p r i n k l e t h e Van Gel 0 i n t o w a t e r a t room t e m p e r a t u r e w h i l e m i x i n g w i t h a homogenizer o r d i s p e n s e r o p e r a t i n g a t 5000 rpm. C o n t i n u e m i x i n g f o r 40 m i n u t e s . 2 . Add sodium h y d r o x i d e and m i x u n t i l u n i f o r m l y d i s s o l v e d . Slow t h e m i x e r t o 1 0 0 0 rpm o r l e s s . 3 . Add t h e Vanseal NALS-30. A v o i d a i r e n t r a p m e n t . M i x u n t i l uniform. F o r m u l a t i o n No. 458 Bowl /Mi 1dew C 1 e a n e r Ingredients: Veegum T , Magnesium Aluminum S i l i c a t e T e t r a s o d i u m P y r o p h o s p h a t e (TSPP) Water

0.25 50.75

8 : Sodium H y p o c h l o r i t e , 5 . 2 5 % Sodium M e t a s i l i c a t e , Anhydrous

34.00 10.00

A:

5.00

Procedure: 1 . D r y b l e n d t h e Veegum T and TSPP. S l o w l y add t h e w a t e r w h i l e a g i t a t i n g a t maximum a v a i l a b l e s h e a r . C o n t i n u e u n t i l smooth. 2 . Add P a r t B i n g r e d i e n t s s l o w l y i n t h e o r d e r shown, m i x i n g a f t e r each a d d i t i o n u n t i l smooth and u n i f o r m . F o r m u l a t i o n No. 424 *As r e c e i v e d b a s i s SOURCE: R.T.

V a n d e r b i l t Co.,

I n c . : Suggested F o r m u l a t i o n s

5

6

Advanced Cleaning Product Formulations

Tile,

P o r c e l a i n a n d Bathroom C l e a n e r , A c i d

Ingredients: 75.5 Water, D . I . Xanthan Gum 0.5 P e t r o BAF Powder 2.0 P h o s p h o r i c A c i d , 75% 12.0 10.0 H y d r o x y a c e t i c A c i d , 70% q.s. Perfume, Dye B l e n d i n g Procedure: Add Xanthan Gum s l o w l y t o w a t e r w i t h h i g h speed m i x i n g . A l l o w t o m i x u n t i l m a t e r i a l t h i c k e n s . Add r e m a i n i n g i n g r e d i e n t s i n o r d e r l i s t e d . I f p r o b l e m s d e v e l o p a d d i n g Xanthan Gum t o w a t e r , p r e m i x t h e Xanthan Gum i n some i s o p r o p a n o l b e f o r e a d d i n g t o water. F o r m u l a 529 Tub and T i l e C l e a n e r Ingredient: Water, D . I . P h o s p h o r i c A c i d , 86% H y d r o c h l o r i c A c i d , 37% R e w o t e r i c AM TEG V a r o n i c T202 SR Blending Procedure: Add in g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y each a d d i t i o n . T y p i c a l P r o p e r t ie s : V i s c o s i t y , c p s : 293 S o l i d s : 16.3% pH: 1 . 7 F o r m u l a 530 H y p o c h l o r i t e Tub and T i l e C l e a n e r a n d M i l * S t a i n

67.4

17.6 13.5 0.5 1.o between

Remoz

Ingredients: Water, D . I . 44.9 Sodium H y d r o x i d e (30%) 1.o Varox 365 1.5 Sodi urn H y p o c h l o r i t e ( 5 . 7 % ) 52.6 Blending Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t io n . Typical Properties: V i s c o s i t y , cps: 4 S o l i d s : 3.8% pH: 13.5 F o r m u l a 531

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s

Bathroom Cleaners

7

T o i l e t Bowl C l e a n e r w i t h B l e a c h Carbopol r e s i n s a r e used t o t h i c k e n t h i s t o i l e t bowl w i t h c h l o r i n e b l e a c h f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n provides v e r t i c a l c l i n g t o increase the contact time of the d e t e r g e n t on t h e s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e .

i-w

I n qr e d D I Water Carbopol 676 ( 1 ) P o t a s s i um h y d r o x i d e ( 4 5 % ) 2 . l r P o t a s s i u m s i l i c a t e (39%) ( 2 ) Potassium carbonate Sodium h y p o c h l o r i t e ( 1 2 . 5 0 % ) Amine O x i d e (30%) ( 3 )

Wt% 60.75 1.25 5.00 5.00 5.00 8.00 10.00

B r o o k f i e l d v i s c o s i t y (RVT-20rpm) : 2 , 5 0 0 c p s P r o d u c t pH: 12-13 P r o d u c t c l a r i t y : Opaque ( 1 ) BFGoodri c h ( 2 ) PQ C o r p . ( 3 ) Lonza, I n c . : B a r l o x 12 Procedure: 1 . U s i n g m o d e r a t e a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . W i t h c o n s t a n t a g i t a t i o n , add t h e p o t a s s i u m h y d r o x i d e and t h e p o t a s s i u m s i l i c a t e . M i x u n t i l homogeneous. 3 . C o n t i n u e a g i t a t i o n and add t h e p o t a s s i u m c a r b o n a t e f o l l o w e d by t h e b l e a c h . 4 . Add t h e amine o x i d e s u r f a c t a n t and m i x u n t i l homogeneous. 5 . Add c o l o r a n d f r a g r a n c e , a s d e s i r e d .

Total Actives: S i l i c a t e (as Si02): 1.32 C a r b o n a t e ( a s Na2C03): 3 . 8 4 Available Chlorine: 1.OO Amine O x i d e : 3 . 0 0

SOURCE:

BFGoodrich S p e c i a l t y Chemicals:

DET-350

2. Dairy, Food and

General Industrial Cleaner

8

D a i q , Food and General Industrial Cleaners

A c i d I n d u s t r i a l and Household C l e a n e r s O x a l i c A c i d Gel

Inqredients: Water Van Gel B Rhodopol 2 3 O x a l i c A c i d D i h y d r a t e , 12.59n Aqueous S o l u t i o n P o l y s o r b a t e 40 (Tween 4 0 )

W t .%*

53.70 2.50 0.80 40.00 3.00

Procedure: 1 . Dry b l e n d t h e Van Gel €3 and Rhodopol 2 3 and add them t o t h e w a t e r w h i l e m i x i n g w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm. C o n t i n u e m i x i n g f o r 60 m i n u t e s . 2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t v o r t e x and s l o w l y add t h e o x a l i c a c i d s o l u t i o n . 3 . When a l l t h e a c i d has been added, add t h e P o l y s o r b a t e 40 and mix u n t i l u n i f o r m . F o r m u l a t i o n N o . 466 Rust Removal J e l IY Insredi ents: Water Van Gel B Rhodopol 2 3 P h o s p h o r i c A c i d, Octoxynol-9

WtD/ou

50% Aqueous Sol u t ion

53.20 3.00 0.80 40 0 0 3 00

Procedure: 1 . D r y b l e n d t h e Van Gel 0 and Rhodopol 2 3 and add them t o he w a t e r w h i l e m i x i n g w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm. C o n t i n u e m i x i n g f o r 60 m i n u t e s . 2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t v o r t e x and s l o w l y add t h e P h o s p h o r i c A c i d s o l u t i o n . 3 . A f t e r a l l t h e a c i d has been added, add t h e O c t o x y n o l - 9 and mix u n t i l u n i f o r m . F o r m u l a t i o n No. 467 *As r e c e i v e d b a s i s

SOURCE: R . T .

V a n d e r b i l t Co.,

I n c . : Suggested F o r m u l a t i o n s

9

10

Advanced Cleaning Product Formulations

Cleaners f o r I n d u s t r i a l A p p l i c a t i o n D e s i n f e c t i n q Cleaner, A c i d

I n s ed ien t s : water P h o s p h o r i c a c i d (85Oh) S u l p h u r i c a c i d (98%) P r o p e t a l 241 Dodigen 226 F o r m u l a CT 06-06-01

wts/, 48.0 24.0 5.0 3.0 20.0

D i ppi n q C1 e a n e r In r e d ie-n-t-sL itatger Tetrapotassium pyrophosphate C a u s t i c soda D i p r o p y l e n e g l y c o l monomethyl S u l f e t a l 4069 Zusol a t 1008/85 F o r m u l a CT 07-03-01

Wt%

ether

75.5 10.0 1.5 5.0 5.0 3.0

Spray C 1 e a n e r Insredients: Water Cublen D50 T r i e t h a n o l ami ne S u l f e t a l 4105 P r o p e t a l 241 Z u s o l a t l005/85 P h o s f e t a l 201 Butyl glycol C i t r u s terpene I n h i b i t o r 4000 F o r m u l a CT 07-06-01 Ingredients water Sul f e t a l 4105 P r o p e t a l 99 Zusolat 1005/85 Butyl glycol Orange t e r p e n e Formula CT 07-06-03

SOURCE:

Zschimmer & Schwarz GmbH 8, C o . :

Q 58.0 3.0 3.0 4.0 2.0 0.5 2.0 5.0 0.5 22.0

86.0

6.0 3.0 0.5 4.0 0.5 General Formulations

Dairy, Food and General Industrial Cleaners

D e s t a in e r (Phosphate, Powder) S o i l - O r g a n i c s t a i n s : f o o d , mold and g r a s s Surface-Cement, wood, p a i n t , p o l y m e r i c A p p l i c a t i o n Method-Brush Manufacture-Dry blend/Agglomeration Compos i t to^ *STPP M e t s o Beads 2048 Sodium S u l f a t e PQ Epsom S a l t **Octylphenoxy Polyethoxyethanol, Sodium P e r b o r a t e , Monohydrate

Wt%

9-

38.0

Use D i l u t i o n : 2 . 3 - 4 . 5 % bw ( 3 - 6 oz/ga

*

**

0 M o l e s EO

25.0 25.0 8.0 2.0 2.0

ion)

FMC Rhone P o u l e n c I g e p a l C A - 6 3 0 Destai ner (Reduced Phosphate,

Powder)

S o i l - O r g a n i c s t a i n s : f o o d , mold and g r a s s Surface-Cement, wood, p a i n t , p o l y m e r i c A p p l i c a t i o n Methods-Brush Manufacture-Dry blend/Agglomeration Composi t i on: *STPP M e t s o Beads 2048 Sodi um S u l f a t e PQ Epsom S a l t **Octylphenoxy Polyethoxyethanol, V a l f o r 100 Z e o l i t e A Sodium P e r b o r a t e , Monohydrate Use L e v e l : 3-6

* **

oz/gallon

FMC Rhone-Poulenc

SOURCE:

9 - 1 0 Moles EO

PQ C o r p . :

I g e p a l CA-630 D e t e r g e n t F o r m u l a t i o n Guide

% & 10.0 25.0 8.0 2.0 2.0 15.0 38.0

I1

12

Advanced Cleaning Product Formulations

Eaa C l e a n e r

L x o phosphatS?,.powder) S o i 1- P r o t e i n S u r f a c e - E g g and egg h a n d l i n g e q u i p m e n t A p p l i c a t i o n M e t h o d - H i g h p r e s s u r e s p r a y (700-1400 Manufacture-Dry blend Composi t i o n : Sodium C a r b o n a t e M e t s o Beads 2048 Sodium S u l f a t e V a l f o r 100 Z e o l i t e A * S o d i urn D i c h l o r o i s o c y a n u r a t e 2H20 * * S o d i um A1 k y l a r y l S u l f o n a t e Powder ( 9 0 % ) Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2

*

**

psi)

Wt%

30.0 20.0 12.0 30.0 3.0 5.0

oz/gallon)

O l i n Chemical Witco

B g k i - n g Pan C l e a n e r (Phosphate,- Powder) S o i l - A n i m a l f a t and g r e a s e , v e g e t a b l e o i l S u r f a c e - A 1 umi num and s t e e l A p p l i c a t i o n Method-Irnmersion/brush Manufacture-Dry blend/Agglomeration O ~ ~t 1 So n l : *Sodium C a r b o n a t e *STPP **Nonylphenoxy P o l y e t h o x y e t h a n o l , Metso Pentabead 2 0 C

Use D i l u t i o n .

* **

1 . 5 % bw ( 2 o z / g a l l o n )

FMC Rhone-Poulenc

SOURCE:

9-10 M o l e s € 0

PQ C o r p . .

I g e p a l CO-630 Detergent F o r m u l a t i o n Guide

Wt% 35.0 12.0 3.0 50.0

Dairy, Food and General Industrial Cleaners

Heavv D u t v C l e a n e r s A l l Purpose-Food P r o c e s s P l a n t Ingredients: Water EDTA ( E t h y l e n e d i a m i n e t e t r a c e t i c A c i d ) TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) P i l o t SXS-40 KOH, 45% Calamide C

Weight% 74.00 2.00 4.00 5.00 10.00 5.00

Comments a b o u t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s i n o r d e r l i s t e d . 2 . Water and EDTA g i v e a m i l k y w h i t e s o l u t i o n . 3 . Upon a d d i n g t h e o t h e r i n g r e d i e n t s t h e s o l u t i o n i s c l e a r . 4. EDTA can b e s u b s t i t u t e d w i t h Na4EDTA t o make a c l e a r f i n a l solution. 5 . T h i s i s a heavy d u t y c l e a n e r f o r f o o d p r o c e s s i n g p l a n t s . 6 . Use l e v e l . 2-4 o z p e r g a l l o n . F o r m u l a t i o n HDC-004-01 Hard S u r f a c e Spray Cleaner Inqredients:

Water TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) E t h y l e n e G l y c o l Monobutyl E t h e r C a l s u d s 81 NH40H, 28%

Weight% 89.00 1.oo 3.00 4.00 3.00

Comments a b o u t t h i s f o r m u l a : 1 . I n g r e d i e n t Water and TKPP when m i x e d a r e c l e a r . 2 . Hazy s o l u t i o n when E t h y l e n e G l y c o l M o n o b u t y l E t h e r i s added. 3 . W i t h t h e a d d i t i o n o f C a l s u d s 81 t h e s o l u t i o n t u r n s c l e a r and has a pH o f 9. 4 . When iUH40H i s added, t h e pH i n c r e a s e s t o 1 2 . F o r m u l a t i o n HDC-002-01 SOURCE: P i 1o t Chemical

Co. : Suggested Formul a t i ons

13

14

Advanced Cleaning Product Formulations

H i qh Foaming A1 k a l ine C l e a n e r M o n a t e r i c EH c o n t r i b u t e s t o d e t e r g e n c y and e f f e c t i v e l y cont r o l s b o t h t h e k r a f f t and c l o u d p o i n t i n t h i s h i g h foaming formulation. I n n r e d ie n t s : Wt9/o Water 76.0 Sodium H y d r o x i d e (50%) 10.0 Sodium M e t a s i l i c a t e ( P e n t a h y d r a t e ) 2.0 Dodecyl benzenesul f o n i c a c i d 2.0 M o n a t e r i c EH 8.0 Nonoxynol -1 0 2.0 Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package. Recommened Use D i l u t i o n : 1 : 2 0 w i t h w a t e r F o r m u l a t i o n F-768 Heavy D u t y A l k a l i n e Degreaser M o n a t e r i c EH a i d s i n t h e removal o f o i l y s o i l s w i t h o u t emuls i f i c a t i o n . I t e a s i l y displaces o i l y s o i l s from hard surfaces and keeps them f r o m r e d e p o s i t i n g . Ingredients: Wt% Water 65.0 20.0 Sodi u m H y d r o x i de ( 5 0 % ) Sodium M e t a s i l i c a t e ( P e n t a h y d r a t e ) 3.0 M o n a t e r i c EH 10.0 Nonoxynol -1 0 2.0 Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package. Recommended Use D i l u t i o n : 1 : 2 0 w i t h w a t e r . F o r m u l a t i o n F-769 Steam C1eaner Mona NF-20 c o n t r i b u t e s t h e non-foaming and d e t e r g e n c y t i e s i n t h i s formulation. I n a r e d ients: Water P o t a s s i um H y d r o x i d e Sodium M e t a s i l i c a t e (Anhydrous) T e t r a p o t a s s i um Pyrophosphate Mona NF-20 Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Typical Properties: Cloud P o i n t : 75C K r a f f t Point: tOC Recommended Use D i l u t i o n : 4-6 o z . / g a l . F o r m u l a t i o n F-762

SOURCE: Mona I n d u s t r i e s ,

I n c . : Suggested F o r m u l a t i o n s

proper-

WtO/o 65.00 3.00 10.00 10.00 12.00

Dairy, Food and General Industrial Cleaners

I n d u s t r i a l and Hiqh Pressure Cleaners C1 eaner. Strong1 y A1 Kal ine

yw%

Inqredients: Water Cublen D 50 Tetrapotassi um pyrophosphate C a u s t i c soda Sodi u m m e t a s i 1 i c a t e S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 Butyl glycol F o r m u l a CT 06-13-01

76.5 1.o 4.0 0.6 4.9 4.0 2.0 2.0 5.0

C1 e a n e r , Weakly A1 k a l ine Ingredients: Water Cublen D 50 Tetrapotassium pyrophosphate T r i e t h a n o l ami ne S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 Butyl glycol F o r m u l a CT 0 6 - 1 3 - 0 2

80.4 1.o 2.0 3.6 4.0 2.0 2.0 5.0

Cleaner, S t r o n q l y A1 k a l i n e (Phosphate-Free) I n g r e d i e c Water Cublen D50 Sodi um m e t a s i 1 i c a t e C a u s t i c soda S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 Butyl glycol F o r m u l a CT 06-13-03 @1eaner, Weak1 y A1 k a l ine ( Phosphate-Free1 Ingredients: Water C u b l e n D 50 T r i s o d i um c i t r a t e S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 Butyl glycol T r i e t h a n o l ami n e F o r m u l a CT 06-13-04

SOURCE:

Zschimmer & Schwarz GmbH & C o . :

15

Wt%

Wt% 80.5 1. o 4.9 0.6 4.0 2.0 2.0 5.0

Wt% 80.4

1. o

2.0 4.0 2.0 2.0 5.0 3.6

General Formulations

16

Advanced Cleaning Product Formulations

Metal Cleaner

(m

S o i l - P e t r o l e u m and a n i m a l o i l and g r e a s e Surface-Metal: Steel A p p l ic a t i on Method-Immersi on Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i on : Water S t a r Sodi um S i 1 ic a t e Sodium H y d r o x i d e (50%) *Phosphate E s t e r * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11;

w.t%

6 Moles EO)

65.6 15.6 6.3 5.0 7.5

Use D i l u t i o n : 2%-5% b v

*

**

Rhone-Poulenc Rhodafac RE-610 Rhone-Poulenc R h o d a s u r f 91-6 Food I n d u s t r y C l e a n e r

(W

S o i l - H e a v y f o o d g r e a s e , o i l and p r o t e i n Surface-Metal, ceramic, polymeric, glass A p p l i c a t i o n Method-Wipe, mop o r b r u s h Manufacture-Mix t a n k w i t h p r o o e l l e r s t i r r e r Composition: Water TKPP (60%) N C l e a r Sodium S i l i c a t e Sodi um H y d r o x i d e (50%) *Phosphate E s t e r **Ethylene Glycol n-Butyl Ether * * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3;

Wt%

6 . 5 Moles € 0 )

Use D i l u t i o n : 6-12% bw ( 8 - 1 6 o z / g a l l o n )

*

**

***

Rhone-Poulenc Rhodafac RE-600 Dow C h e m i c a l , U n i o n C a r b i d e Rhone-Poulenc R h o d a s u r f LA-7

SOURCE: PQ C o r p . :

Detergent F o r m u l a t i o n Guide

74.0 3.0 7.0 3.5 2.5 5.0 5.0

Dairy, Food and General Industrial Cleaners

M i l k Can C l e a n e r (Phosphat_e, Powder) Sol 1 - F a t

and p r o t e i n Surface-Metal A p p l i c a t i o n Method-Wipe o r b r u s h Manufacture-Dry blend/Agglomeration

Compo_sition’ *STPP M e t s o Beads 2048 *Sod1 u m C a r b o n a t e +*Sod1 um D i c h l o r o i s o c y a n u r a t e , 2H20 * * * S o d i u m A1 k y l a r y l S u l f o n a t e Powder, Use D i l u t i o n

* ** ***

0.75-1

WX/, 30.0 30.0

(90%)

35.0 3.0 2.0

5% bw (1-2 o z / g a l l o n )

FMC O l i n Chemical w1 t c o M i l k Can CLea-ner (Zeco Phosphate, Powder) S o l 1 - F a t and p r o t e i n S u r f ace-Metal A p p l i c a t i o n Method-Wipe o r b r u s h Manufacture-Dry blend

Composi t i on : Val f o r 100 Z e o l i t e A Metso Pentabead 20 Sodium C a r b o n a t e *Sodium D i c h l o r o i s o c y a n u r a t e , 2H20 **Sod1 um A 1 k y l a r y l S u l f o n a t e Powder,

Wt%

20.0 40.0 35.0

3.0 (90%)

Use L e v e l : 1 - 2 o z / g a l l o n

* **

O l i n Chemical Stepan, W i t c o

SOURCE:

PQ C o r p . :

D e t e r g e n t F o r m u l a t i o n Guide

2.0

17

18

Advanced Cleaning Product Formulations

Powdered Enzyme Presoaks Economy Presoak Component: Soda Ash Sodium Metasilicate Pentahydrate Sodium Dodecylbenzenesulfonate Powder Burcosperse AP Powder Burcotase EP-60

Wt% 80.0 10.0 5.0 3.0 2.0

Premi um Presoak Component: Soda Ash STPP Neodol 25.7 Sodium Metasi 1 icate Pentahydrate Sodium Dodecylbenzenesulfonate Powder Burcosperse AP Powder Burcotase EP-60 The recommended use concentration o f these products i s g/1 in the presoak bath. F o r optimum results, the presoak temperature should be 130-15OF.

5 40.0 35. n 5.0 10.0 5.0 3.0 2.0 1-4

Enzyme Prespotter f o r Oilv/Smuttv Soils Component: Water Propyl ene G1 ycol Dodecyl benzenesul foni c Acid TEA-85 Burco TME Nonionic Surfactant* Burcotase LL-100 *An HLB of 9 . 5 - 1 0 . 0 preferred.

wtD/, 49.0 10.0 10.0 20.0 5.0 5.0 1.o

i s preferred. Alcohol ethoxylates are

Add components in the order listed. Blend until uniform between each addition. Cool before adding the enzyme. SOURCE: Burlington Chemical G o . , Inc. : Suggested Formulations

Dairy,Food and General Industrial Cleaners

S a n i t i z i n s Cleaner (Phosphate, Powder) S o i l - H o s p i t a l s o i l : sebum, b l o o d , u r i n e , e t c . Surface-Metal, ceramic, polymeric A p p l i c a t i o n Method-Wipe o r b r u s h Manufacture-Dry Blend

Wt%

Composi t 1 1 0 ~ Metso Beads 2048 *Sodium C a r b o n a t e *STPP **Sodi urn D i c h l o r o i s o c y a n u r a t e , 2H20 ***Sod; um A1 k y l a r y l S u l f o n a t e Powder (99%) Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2

* ** ***

20.0 35.0 30.0 10.0 5.0

oz/gallon)

FMC 01 i n Chemical witco Sani t i z i na A a e n t (Phosphate, Powder)_

S o i l - H o s p i t a l s o i l : sebum, b l o o d , u r i n e , Surface-Metal, ceramic, polymeric A p p l i c a t i o n Method-Wipe, b r u s h Manufacture-Dry blend/Agglomeration Composi t i on : *STPP *Sodi um C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl6; M e t s o Pentabead 20 Quaternary Germicide Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2

*

**

Wt% 12 M o l e s EO)

oz/gallon)

FMC Rhone-Poulenc R h o d a s u r f LA-12

SOURCE: PQ C o r p . :

etc.

Detergent F o r m u l a r y Guide

30.0 25.0 10.0 30.0 5.0

19

3. Degreaser

20

Degreasers

Aqueous D e s r e a s e r Ingredients: Water NaOH, 50% Cal s o f t LAS-99 P i l o t SXS-40 C a l o x y l a t e N-9 TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) Sodium M e t a s i 1 i c a t e E t h y l e n e G l y c o l Monobutyl Ether

Wei q h t % 60.80 2.00 9.40 8.70 4.60 4.70 6.60 3.20

Comments a b o u t t h i s f o r m u l a : D i s s o l v e t h e s a l t s i n t h e water f i r s t . F o r m u l a t i o n DEG-001-01 Aqueous D e q r e a s e r d - L i monene M i c r o e m u l s i o n Ingredients: d - L i monene C a l s u d s CD-6 C a l imu1 se PRS Diethylene Glycol n-Butyl Water

Ether

Weight% 9.90 9.80 2.44 4.93 73.00

Comments a b o u t t h i s f o r m u l a : 1 . A d d i t i o n a l C a l s u d s CD-6 may b e needed t o c l a r i f y t h e sample. 2 . Add t h e w a t e r s l o w l y . F o r m u l a t i o n DEG-002-01 Water Based D e a r e a s e r Ingredients: Water NaOH, 50% Cal s o f t LAS-99 P i lot SXS-40 Na4EDTA C a l o x y l a t e N-9 E t h y l e n e G l y c o l Monobutyl Ether Sodi urn M e t a s i 1 ic a t e

Weight% 68.50 2.00 7.00 7.50 2.00 5.00 3.00 5.00

Comments a b o u t t h i s f o r m u l a : 1 . T h e r e i s a p h o s p h a t e v e r s i o n where 3 . 5 % sodium t r i p h o s p h a t e i s s u b s t i t u t e d f o r t h e sodium m e t a s i l i c a t e and Na4EDTA. 2 . Use w a t e r t o b a l a n c e i n g r e d i e n t s . F o r m u l a t i o n DEG-006-01

SOURCE:

P i l o t Chemical C o . :

Suggested F o r m u l a t i o n s

21

22

Advanced Cleaning Product Formulatiorrs

m r e a s e r Concentrate ( L i q u i d)

Soil-Grease, o i l Surface-Pai n t , polymeric, metal A p p l i c a t i o n Method-Spray o r w i p e Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i on : Water M e t s o Beads 2048 *Sodi urn P o l y a c r y l a t e (40%) **Phosphate E s t e r * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 6 M o l e s EO) * * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles EO)

wt"/o

67.0 8.0 5.0 10.0 5.0

5.0

Use D i l u t i o n : Normal Duty-1.5% bw ( 2 o z / g a l l o n ) Heavy D u t y - 3 . 0 % bw ( 4 o z / g a l l o n )

* ** ***

****

Rhone-Poulenc Rhone-Poulenc Rhone-Poulenc Rhone-Poulenc

C o l l o i d 226/35 P o l y a c r y l a t e (40%) Rhodafac R E - 6 1 0 R h o d a s u r f 91-6 R h o d a s u r f A-24

Metal De-Oiling L i q u i d Concentrate ( L i quid ) Soi 1 - P e t r o l e u m - b a s e d o i 1 S u r f a c e - M e t a l : S t e e l , c o p p e r , aluminum, e t c . Appl i c a t i o n Method-Spray a n d / o r immersi on Manufacture: Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i on : Water S t a r s o Sodi urn S i 1 i c a t e EDTA, T e t r a s o d i u m (37%) Sodium X y l e n e S u l f o n a t e (40%) * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11

W

6 M o l e s EO) 2 . 5 M o l e s EO)

Use D i l u t i o n : 2%-4% b v

*

**

Rhone-Poulenc R h o d a s u r f 91-6 Rhone-Poulenc R h o d a s u r f A-24

SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t on G u i d e

B

42.0 12.0 16.0 20.0 3.0 7.0

aegreasers

23

S o l v e n t Denreaser Carbopol r e s i n s a r e used t o e m u l s i f y and s t a b i l i z e t h i s d-limonene o i l based e m u l s i o n . I n a d d i t i o n , t h e use o f t h e r e s i n provides v e r t i c a l c l i n g t o increase the contact time o f t h e d e t e r g e n t on t h e s o i l e d s u r f a c e and enhance consumer convenience.

9

I n q r e d ient : D I Water Carbopol ETD 2623 ( 1 ) d-Limonene ( 2 ) Propylene g l y c o l methyl e t h e r ( 3 ) Alkylbenzene s u l f o n i c a c i d ( 4 ) C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO ( 5 ) Isopropanol Sodium h y d r o x i d e (50%) B r o o k f ie l d v i s c o s i t y (RVT-20 P r o d u c t pH: 9 . 5 - 1 0 P r o d u c t C1 a r i t y : Opaque (1)

(2) (3) (4) (5)

81.18 0.32 10.00 2.00 2.00 1.50 2.50 0.50

rpm) : 750 cps

BFGoodrich A r y l e s s e n c e , I n c . : H-7892 d-limonene Dow Chemical : Dowanol PM Stepan C o . : B i o s o f t S-100 S h e l l Chemical: Neodol 23-6.5

Procedure: 1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . Add t h e d-limonene w i t h good a g i t a t i o n and mix u n t i l homogeneous. 3 . Reduce a g i t a t i o n and add t h e g l y c o l e t h e r , s u l f o n i c a c i d , and alcohol ethoxyl ate. 4 . Add t h e i s o p r o p a n o l 5 . Add t h e sodium h y d r o x i d e u n t i l t h e t a r g e t pH r a n g e i s reached. 6 . Add c o l o r , as d e s i r e d .

.

T o t a l Actives: d-limonene: Propylene g l y c o l methyl e t h e r : Sodium a1 k y l b e n z e n e s u l f o n a t e : Psopropanol : C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO: SOURCE: BFGoodrich S p e c i a l t y Chemicals:

10.0 2.0 2.2 1.5 2.5

DET-330

24

Advanced Cleaning Product Formulations

S o l v e n t Based Deqreaser Insredients: Kerosene Aristonate M Pine O i l T a l l O i l F a t t y Acid C a l o x y l a t e N-9 Hexyl ene G1 y c o l

Wei ghP% 72.85 3.00 10.00 10.06 3.02 1.06

Comments a b o u t t h i s f o r m u l a : 1 . Use a l o w o d o r g r a d e o f t a l l o i l f a t t y a c i d . 2 . Add i n g r e d i e n t s i n t h e o r d e r i n d i c a t e d . 3. A r i s t o n a t e L can be s u b s t i t u t e d f o r A r i s t o n a t e M~ F o r m u l a t i o n DEG-004-01 S o l v e n t Based Degreaser We ig h t % 5.10 5.00 2.99 86.93

Ingredients: Aristonate M T r i t o n X-45 T r i t o n N-101 Kerosene Comments a b o u t t h i s f o r m u l a : 1 . Kerosene can be s u b s t i t u t e d w i t h A r o m a t i c Naphtha. 2 . A r i s t o n a t e M can be s u b s t i t u t e d w i t h A r i s t o n a t e L . F o r m u l a t i o n DEG-003-01 E n q i n e C l e a n e r and Deqreaser Ingredients: Water M I PA C a l imu1s e PRS Dowanol DPM Na4EDTA Comments a b o u t t h i s f o r m u l a : Clear, p a l e y e l l o w product F o r m u l a t i o n DEG-005-01 SOURCE: P i 1o t Chemi c a l Co. : Suggested Formul a t ions

Weight% 58.94 20.33 5.08 45.24 0.41

lshwashing Detergents

25

26

Advanced Cleaning Product Formulations

A u t o m a t i c Dishwash Deteraent-Consumer ( Z e r o Phosohate. C h l o r i n e F r e e . Powder1 S o i l - F o o d g r e a s e , o i l and p r o t e i n S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manufacture-Dry Blend/Agglomeration Composi t i on : Sodi urn C i t r a t e D i h y d r a t e * B r i t e s i l H20 Hydrous P o l y s i l i c a t e Sodi urn C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) * * * A c u s o l 445ND S o d i um P o l y a c r y l a t e ( 9 2 % sol id s ) ****Sodium P e r b o r a t e Monohydrate V a l f o r 100 Z e o l i t e A Sodium S u l f a t e

* **

*** ****

10.0 20.0 23.0 3.0 4.0 10.0 15.0 15.0

2 . 0 w e i g h t r a t i o powder w i t h 1 7 . 5 % w a t e r Rhone-Poulenc A n t a r o x BL-330 Rohm & Haas; o r use a c o m b i n a t i o n o f A c u s o l 445ND and A c u s o l 479ND ( 2 w t . % each) O r use Sodium D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r i n e ) a t 2 w t % . Balance w i t h s u l f a t e . A u t o m a t i c Dishwash Detersent-Consumer (Phosphate, C h l o r i n e F r e e , Powder)

S o i 1-Food g r e a s e , o i 1 and p r o t e i n S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manufacture-Dry blend/Agglomeration Composi t i on : RU L i q u i d Sodium S i l i c a t e *Sodium C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) * * * A c u s o l 445ND Sodi um P o l y a c r y l a t e (92% s o l id s ) ****Sodium P e r b o r a t e M o n o h y d r a t e *STPP Sodi um S u l f a t e

* ** *** ****

15.0 23.0 3.0 4.0 10.0 30.0 15.0

FMC Rhone-Poulenc A n t a r o x BL-330 Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and A c u s o l 479ND ( 2 w t . % each) O r u s e Sodi u m D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r i n e ) a t 2 w t %. B a l a n c e w i t h s u l f a t e .

SOURCE: PO C o r p . :

Detergent F o r m u l a t i o n Guide

Dishwashing Detergents

27

A u t o m a t i c Dishwash D e t e r c i e n t - I n d u s t r i a l & I n s t i t u t i o n a l (Phosphate, S o l i d B l o c k ) S o i l - F o o d g r e a s e , o i l and p r o t e i n S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manufacture-Solid block Composi t i on : M e t s o Beads 2048 NaOH (50% S o l u t i o n ) *STPP *Sodi um C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9

* **

Wt% 25.0 25.0 35.0 12.0 M o l e s EO;

C12-15)

3.0

FMC Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7 A u t o m a t i c D i shwashi n g D e t e r g e n t - I n d u s t r i a1 & I n s t i t u t i o n a l (L iquid) S o i l - F o o d g r e a s e , o i l and p r o t e i n S u r f a c e - M e t a l , c e r a m i c and g l a s s A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Wt%

Composition : Water * A c r y s o l ASE 108 ( A c r y l i c P o l y m e r ) * * T r i t o n DF-16 ( N o n i o n i c S u r f a c t a n t ) P o t a s s i um H y d r o x i d e (45%) TKPP (60%) N C l e a r Sodium S i l i c a t e

Use D i l u t i o n : 0 . 1 5 - 0 . 3 0 % bw ( 0 . 2 - 0 . 4

* **

Rohm & Haas; Rohm & Haas;

50.9 6.9 3.0 1.2 25.0 13.0 oz/gallon)

o r Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e ( 4 0 % ) o r Rhone-Poulenc A n t a r o x EL-330

SOURCE: PQ C o r p . :

Detergent F o r m u l a t i o n Guide

28

Advarrced Clearring Product Formulatiorls

A u t o m a t i c D i s h w a s h D e t e r g e n t T I n d u s t r i a l - &- I n s t i ~ ! . ! t i g n ~ j (Zero-Phosphate, C h l o r i n e F r e e , Powde_rj S o i l - F o o d g r e a s e , oil and p r o t e i n S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manuf a c t u r e - D r y B1 e n d / A g g l o m e r a t i on Composi t io n : M e t s o P e n t a b e a d 20 Sod1 um C a r b o n a t e * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 M o l e s € 0 ; C12-15) * * A c u s o l 445ND Sodium P o l y a c r y l a t e ( 9 2 % s o l i d s ) ***Sodium P e r b o r a t e M o n o h y d r a t e B l e a c h Val f o r 100 Z e o l i t e A Sodium S u l f a t e

* ** ***

Wt%

30.0 26.0

3.0 4.0 10.0 15.0

12.0

Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l C h e m i c a l Neodol 25-7 Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and A c u s o l 479ND ( 2 w t % e a c h ) . O r use sodium d i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r i n e ) a t 2 w t % . Balance w i t h s u l f a t e .

Autom.aticP~hwa~h_Dete~e_n~ Stri-a . ~ I ~1.d_&-Ins -u t_ii-tluti_ o?e_a_8 LP h o s p h a t e _ , C h l _ o r i n e _Free- Pow_s1ec) S o i l - F o o d g r e a s e , o i l and p r o t e i n S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manufacture-Dry Blend/Agglomeration Composition: G t s o P e n t a b e a d 20 *STPP * S o d i um C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 M o l e s EO; C12-15) * * * A c u s o l 445ND S o d i um P o l y a c r y l a t e ( 9 2 % sol i d s ) ****Sodium P e r b o r a t e Monohydrate B l e a c h

* **

*** ****

FMC Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l C h e m i c a l Neodol 2 5 - 7 Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and A c u s o l 479ND ( 2 w t % e a c h ) O r use sodium d i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r i n e ) a t 2 w t % . Balance w i t h s u l f a t e .

SOURCE: PP C o r p . :

Detergent F o r m u l a t i o n Guide

Wt% 30.0 25.0 28.0 3.0 4.0 10.0

Dishwashing Detergents

29

A u t o m a t i c D i s h w a s h i ng Gel w i tJ1_..Chlori n e B1 e a c h Carbopol r e s i n s a r e used t o t h i c k e n t h e p r o d u c t t o reduce s p l a s h i n g , p r o v i d e c u p r e t e n t i o n i n t h e d i s h w a s h e r , and c r e a t e a s t a b l e suspension o f i n s o l u b l e s ( i . e . phosphate b u i l d e r s ) i n t h i s AOL f o r m u l a t i o n c o n t a i n i n g c h l o r i n e b l e a c h . Inqredient: 01 w a t e r C a r b o p o l 672 ( 1 ) P o t a s s i um h y d r o x i d e ( 4 5 % ) 2 . l r p o t a s s i u m s i l i c a t e (39%) ( 2 ) P o t a s s i urn c a r b o n a t e ( 3 ) Sodium t r i p o l y p h o s p h a t e ( 4 ) S o d i um h y p o c h l o r i t e ( 1 2 . 5 C 0 h ) Sodium n - d e c y l d i p h e n y l o x i d e d i s u l f o n a t e ( 4 5 % ) ( 5 ) B r o o k f i e l d v i s c o s i t y (RVT-20 P r o d u c t p H : 12-13 P r o d u c t c l a r i t y : Opaque

rpm):

Wt% 44.75 1.25 5.00 15.00 5.00 20.00 8.00 1.oo

15,000 cps

(1 BFGoodri c h ( 2 The PO C o r p . ( 3 Armand (4 FMC C o r p . ( 5 ) O o w C h e m i c a l : Dowfax 382 Procedure: 1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l 1e r s u i t a b 1 e f o r g e n e r a l m i x i ng and b l e n d i n g o p e r a t i o n s . Screen t h e Carbopol r e s i n i n t . 0 t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r ( 8 0 0 r p m ) . A l l o w t o m i x u n t i l homogeneous and f r e e o f p o l y m e r l u m p s . 2 . Add i n t h e p o t a s s i u m h y d r o x i d e a n d p o t a s s i u m s i l i c a t e . M i x u n t i l homogeneous. The p r o d u c t w i l l become v e r y t h i c k a t t h i s poi n-t. 3 . Add t h e p o t a s s i u m c a r b o n a t e and p h o s p h a t e . M i x u n t i l t h e r e a r e no more p h o s p h a t e p a r t i c l e s . H e a t i n g t o 50-60C w i l l speed t h i s p r o c e s s . 4 . Add t h e b l e a c h and t h e n t h e s u r f a c t a n t . M i x u n t i l homogeneous. A d j u s t t h e pH t o 12-13 u s i n g KOH. 00 n o t u s e a c i d t o r e d u c e t h e pH, e s p e c i a l l y a f t e r t h e a d d i t i o n o f t h e b l e a c h . 5 . Add c o l o r and f r a g r a n c e , a s d e s i r e d . Cool t h e p r o d u c t t o b e l o w 30C t o a v o i d e x c e s s i v e b l e a c h d e c o m p o s i t i o n .

Total Actives: Phosphorous c o n t e n t : S i l i c a t e (as Si02): C a r b o n a t e ( a s Na2CO3): Ava i 1a b 1e c ti 1o r ine : SOURCE:

5.0 3.9 3.8 1.o

BFGoodrich S p e c i a l t y C h e m i c a l s : DET-100

30

Advanced Cleaning Product Formulations

Clear,

C o l o r l e s s Manual - D i s h Wash

Wt%

Insredients: Water, D . I. W i t c o l a t e ES-3 R e w o t e r i c AM 8-14 Ethanol Sodium C h l o r i d e

57.5 34.2

5.0 3.0 3.3

B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . D i s s o l v e c o m p l e t e l y between each a d d i t i o n . Comment: R e w o t e r i c AM 8-14: Formula 1 3 2

Grease c u t t e r and foam b o o s t e r .

Powder S t a i n l e s s S i l v e r w a r e Pre-Soak I n q r e d ie n t s : Sodium Carbonate (Soda Ash) P e t r o BAF Powder DeSonic 1 1 N T r i s o d i um Phosphate, Anhydrous C a u s t i c Soda Beads

Wt% 67.0 5.0 11 . o 2.0 25.0

61 e n d i ng P r o c e d u r e : Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d Use D i 1u t u i on : 1 o z / g a l Formula 1 2 7 Low A1 k a l ine Warewashi nq Block I n q r e d ie n t s : Water, D . I . R.U. S i l i c a t e DeSoni c LFD-97 Sodium Carbonate (Soda Ash) Sodium T r i p o l y p h o s p h a t e Code 185 B l e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . When s l u r r y i s produced, p o u r i n t o molds and a l l o w t o harden. Formula 1 2 9

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s

W B 16.0 29.0 2.0 23.0 30.0

Dishwashing Detergents

Dish Washi nq Agents clear, liquid, 25% W A S alkanesulphonate:ethersulphate=4:l Ingredi e m A : H o s t a p u r SAS 6 0 Genapol Z R O l i q u i d

33.30 17.90

B: Water Preservative DY e Perfume

48.50 0.10 q.s. 0.20

Tests: v i s c o s i t y (rnPas) : 75 C l o u d p o i n t : <-5C Wto/,

Inqredients: A : H o s t a p u r SAS 60 Genapol ZRO l i q u i d

33.30 17.90

B: Water P r e s e r v a t iv e DYe Perfume Genagen LAB

47.50 0.10 q.s. 0.20 1 .oo

Tests: V i s c o s i t y (mPas): Cloud p o i n t : <-5C

100

Inqredients: A : H o s t a p u r SAS 60 Genapol ZRO l i q u i d

33.30 17.90 44.50

B: Water Preservative DY e Perfume Genagen LAB

0.10 9,s. 0.20 4.00

Tests: V i s c o s i t y (mPas): 2 3 0 C l o u d p o i n t : <-5c Manufacturing: One a f t e r a n o t h e r , SOURCE:

t h e components o f B a r e added t o A

Hoechst A k t i e n g e s e l l s c h a f t :

Suggested F o r m u l a t i o n s

31

32

Advanced Cleaning Product Formulations

D i s h Washi nq A g e n t s

C l e a r , liquid, 30% WAS a1 k a n e s u l p h o n a t e : e t h e r s u l p h a t e = 4 : 1 W

Insredients: A : H o s t a p u r SAS 60 Genapol Z R O l i q u i d €3:

B

40.00 21 . 4 0 37.30 0.10 q.s. 0.20

Water Preservative DY e Perfume Genagen LAB

1.oo

Tests: V i s c o s i t y (mPas) : 380 C l o u d p o i n t : <-5C

wtsl,

Inqredients: A : H o s t a p u r SAS 60 Genapol Z R O l i q u i d

40.00 21.40

37.30 0.10

0 : Water Preservative DY e Perfume Hoe S 3924

q.s.

0.20 1 .oo

Tests: V i s c o s i t y (mPas) : 420 C l o u d p o i n t : <-5C

wt./, 40.00 21.40

Ingredients: A : H o s t a p u r SAS 60 Genapol Z R O l i q u i d El:

34.30 0.10 q.s. 0.20 4.00

Water P r e s e r v a t iv e DY e Perfume Hoe S 3924

Tests: V i s c o s i t y (mPas) : 61 0 C l o u d p o i n t : <-5C Manufacturing: One a f t e r a n o t h e r ,

SOURCE:

t h e components o f 8 a r e added t o A .

Hoechst A k t i e n g e s e l l s c h a f t :

Suggested F o r m u l a t i o n s

Dishwashing Detergents

D i s h Wash w/Am&e

33

Oxide/LABS/SLES

Wtl

lngredients: Water, D . I . W i t c o n a t e 1240 Varox 1770 W i t c o l a t e SE-5

66.3 10.3 5.3 18.1

81 e n d i ng P r o c e d u r e : Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . Add e t h a n o l as needed t o l o w e r v i s c o s i t y . Typical Properties: V i s c o s i t y , c p s : 620 S o l i d s : 16.8% pH: 9 . 1 2 F o r m u l a 117

D i s h Wash w / A m i n e Oxi de/LABS/ALES I n g r e d i e n t s1 Water, D . I . W i t c o n a t e 1240 Varox 1770 W i t c o l a t e LES-6OA Ethanol

70.0 13.8 3.1 8.2 5.0

B1 end? ng P r o c e d u r e : Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . A c i d i f y w i t h C i t r i c A c i d t o pH=6.5. Typical Properties: V i s c o s i t y , cps: 4 S o l i d s : 10.1% pH: 6 . 6 8 F o r m u l a 118

__ Hand Di shwashi ng L i sui d

K%

Ingredients: Water W i t c o n a t e AOS W i t c a m i de 128T W i t c o l a t e LES-6OC

60.0 26.0

4.0 10.0

Blendjng Instructions: Add a l l i n g r e d i e n t s i n t h e o r d e r l i s t e d , a d d i t i ons . F o r m u l a 106

SOURCE:

Witco Corp.:

Suggested F o r m u l a t i o n s

m i x i n g w e l l between

34

Advanced Cleaning Product Formulations

Foam B o o s t e r :

Ez-4-5

in Hand D i shwashi na L i q u i d s

L i q u i d d i s h f o r m u l a t o r s a r e challenged t o produce low c o s t q u a l i t y p r o d u c t s . Hand d i s h d e t e r g e n t s a r e e x p e c t e d t o foam i n t h e p r e s e n c e o f f o o d s o i l s , c u t g r e a s e and c l e a n . I n a d d i t i o n , a e s t h e t i c s , s k i n m i l d n e s s , and e n v i r o n m e n t a l i m p a c t a r e a l s o m a j o r p r o d u c t c o n s i d e r a t i o n s . The f o l l o w i n g d a t a i l l u s t r a t e d how E-14-5 can b e used t o f o r m u l a t e c o s t e f f e c t i v e p r o d u c t s s u i t a b l e f o r t h e v a r i o u s l i q u i d d i s h soap m a r k e t segments. O p t i m i z e d l i q u i d d i s h d e t e r g e n t s c o n t a i n i n g E-14-5 p r o v i d e t h e optimum i n c o s t p e r f o r m a n c e when compared t o a l l o t h e r t y p e s o f foam b o o s t e r s . A l t h o u g h i t p e r f o r m s w e l l a l o n e , E-14-5 s y n e r g i s t i c a l l y enhances t h e p e r f o r m a n c e o f most t r a d i t i o n a l foam b o o s t e r s a s i l l u s t r a t e d b e l o w w i t h Coco d i e t h a n o l a m i d e . Economy Eormul a t i on In g r e d i e n t s : Deionized water Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s ) L a u r y l a l c o h o l e t h e r s u l f a t e - 4 EO, (60% s o l i d s ) Ethyl alcohol Tomah E-14-5 Coco d i e t h a n o l ami de

Wt.% 59.7 2 5 . 9 ( 15) 8.4(5) 0

3 3

Standard Formulation

In g r e d i e m Deionized water Dodecylbenzene s u l f o n a t e , sodium s a l t , ( 6 0 % s o l i d s ) L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (60% s o l i d s ) Ethyl alcohol Tomah E-14-5 Coco d i e t h a n o l ami de

wt> 52.9 31 . 0 ( 1 8 ) 10. l ( 6 ) 1.5 3 3

90% Premi u m Formul a t ion Inqredi ents: Deionized water Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s ) L a u r y i a l c o h o e t h e r s u l f a t e - 4 EO, (60% s o l i d s ) Ethyl alcohol Tomah E-14-5 Coco d i e t h a n o ami de

_ Premi _ urn _F o r _ m u l a~t i o n-

Wt.% 38.6 38.8(22.5) 12.6(7.5) 4

3

~

I n q r e d i en& Deionized water Dodecyl benzene s u l f o n a t e , s o d i um s a l t , (60% s o l i d s ) L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (6O0h s o l i d s ) Ethyl alcohol Tomah E-14-5 Coco d i e t h a n o l ami de SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s

Wt.% 28.3 46.6( 27) 15.1 (9) 4 3 3

Dishwashing Detergents

Hand D i s h D e t e r a e n t F o r m u l a t i o n s C l e a r D i shwash

\N t %

IngredienPs 1

12.30 8.00 52.50 18.20 6.00

Water SXS (4O%j C12 A i f a O i e f in s u i f o n a t e ( 2 8 . 7 5 % s o i i d s j Lauryl e t h e r s u l f a t e - 3E0 (27.5% s o l i d s ) Tomah AO-728 S p e c i a l NaCl*

3.00

M i x i ng I n s t r u c t i o n s : Add t h e i n g r e d i e n t s i n t h i s o r d e r . M i x u n t i l homogeneous a f t e r each a d d i t i o n SpG 2 0 / 2 0 C : 1 . 0 5 pH: 6 V i s c o s i t y : 505 c p s ( B r o o k f i e i d LVT 3 0 rpm s p i n d l e number 2) NOTES:

*Add more N a c l t o i n c r e a s e v i s c o s i t y .

__ P e a r i e s c e n t U i shwash ingredients: Water Dodecyibenzene s u i f o n a t e ( 6 0 % s o l i d s ) C a u r y i e t h e r s u l f a t e - 4 E 0 (60% s o i i d s j O p a c i f i e r L a t e x (4OWja P e a r l i z i n g Agent ( 4 7 % j * * Tomah A0-728 S p e c i a i Tomah A m p h o t e r i c L

WLL7O

54.40 25.00 8 . 30 0.04 2.30 4.00 6.00

Mixing Instructions: Add t h e i n g r e d i e n t s i n t h i s o r d e r . M i x u n t i i homogeneous a f t e r each a d d i t i o n . SpG 2 0 / 2 0 C : 1 . 0 3 6.5 V i s c o s i t y : 1363 c p s ( B r o o k f i e l d LVT, PH:

NOTES:

* **

12 rpm,

s p i n d l e number

L y t r o n 295 Mortor! i n t e r n a t i o n a l E u p e r i a n PK-771, Henkei

SOURCE: Tomah P r o d u c t s , f n c . :

Suggested F o r m u l a t i o n s

35

36

Advanced Cleaning Product Formulations

Hand D i s h w a s h i n g L i q u i d C a r b o p o l r e s i n s c a n be used t o b u i l d r h e o l o g y i n p l a c e o f u s i n g h i g h e r s u r f a c t a n t l e v e l s . T h i s w i l l improve t h e s k i n f e e l and m i l d n e s s . A d d i t i o n a l l y , because o f t h e i r h i g h y i e l d v a l u e , t h e use o f Carbopol r e s i n s w i l l i n c r e a s e foam s t a b i l i t y . Q 38.11 0.70 4.00 27.03 5.50 17.86 2.00

Inqredient: D I Water Carbopol ETD 2623 ( 1 ) 5 8 0 0 MW p o l y a c r y l i c a c i d ( 2 ) A l p h a s u l f o m e t h y l e s t e r (37%) ( 3 ) TEA (99%) Sodium l a u r y l e t h e r s u l f a t e (28%) ( 4 ) Coconut d i e t h a n o l ami de ( 5 ) B r o o k f i e l d v i s c o s i t y (RVT-20 P r o d u c t pH: 6 . 0 - 7 . 0 Product c l a r i t y : Clear

rpm):

400-600

cps

( 1 ) BFGoodrich ( 2 ) BFGoodrich: Good-Rite K-7058 ( 3 ) Stepan Co.: A l p h a s t e p ML-40 ( 4 ) Henkel C o r p . : S t a n d a p o l ES-3 ( 5 ) Stepan C o . : N i n o l 11-CM Procedure: 1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s P r e h e a t t h e w a t e r t o 40-5OC. Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 r p m ) . A l l o w t o m i x f o r a t l e a s t 15 m i n u t e s o r u n t i l homogeneous and f r e e o f p o l y m e r lumps. 2 . Add i n t h e l o w m o l e c u l a r w e i g h t p o l y a c r y l a t e w i t h c o n s t a n t mixing. 3 . Add i n t h e ASME s u r f a c t a n t w i t h a l o w l e v e l o f a g i t a t i o n t o a v o i d e x c e s s i v e foam g e n e r a t i o n . 4 . Add i n t h e TEA, l a u r y l e t h e r s u l f a t e , and c o c o n u t DEA. 5 . A d j u s t t h e pH u s i n g TEA t o r e a c h t h e t a r g e t r a n g e . Add c o l o r and p e r f u m e , a s d e s i r e d . Cool b a t c h t o room t e m p e r a t u r e . Total Actives: Alpha s u l f o methyl e s t e r : Sodium l a u r y l e t h e r s u l f a t e : Coconut d i e t h a n o l a m i d e : 5 8 0 0 MW p o l y a c r y l i c a c i d :

SOURCE:

10.00 5.00 2.00 2.00

BFGoodrich S p e c i a l t y C h e m i c a l s :

DET-I10

Dishwashing Detergents

37

Hand Dishwashina P a s t e Carbopol r e s i n s a r e used t o t h i c k e n and suspend i n s o l u b l e s i n t h i s hand d i s h w a s h i n g p a s t e . A d d i t i o n a l l y , because o f t h e i r h i g h y i e l d v a l u e , t h e use o f Carbopol r e s i n s w i l l i n c r e a s e t h e foam s t a b i 1it y .

Wt%

I n a r e d ient : D I water

41.50 1 .oo 17.00 5.00 7.50 15.00 5.00 8.00

Carbopol 672 ( 1 ) A l k y l b e n z e n e s u l f o n i c a c i d (9796) ( 2 ) Sodi um h y d r o x i d e (50%) 2 . 4 r sodium s i l i c a t e (52%) ( 3 ) Sodium t r i p o l y p h o s p h a t e ( 4 ) Sodium c a r b o n a t e Sodium o l e f i n s u l f o n a t e (40%) (5) B r o o k f i e l d v i s c o s i t y (RVT-20 rpm) : 75,000 cps P r o d u c t pH: 10-11 P r o d u c t c l a r i t y : Opaque BFGoodri ch Stepan Co.: B i o s o f t S-100 The PO Corp. FMC Corp. ( 5 ) Stepan Go.: E i o t e r g e AS-40

( 1) (2) (3) (4)

Procedure: 1 . Use a L i g h t n i n ’ M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t o n s . Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 r p m ) . A l l o w t o m i x u n t i l homogeneou and f r e e o f polymer lumps. 2 . Add t h e s u l f o n i c a c i d w i t h c o n t i n u o u s a a i t a t i o n . 3 . Add t h e sodium h y d r o x i d e and sodium s i l i c a t e w i t h c o n t i n u o u s a g i t a t i on. M i x u n t i1 homogeneous. 4 . S l o w l y , add t h e phosphate. M i x u n t i l homogeneous and f r e e o f phosphate p a r t i c l e s . H e a t i n g t h e p r o d u c t t o 50-60C w i l l speed up t h i s p r o c e s s . 5 . Add t h e sodium c a r b o n a t e and o l e f i n s u l f o n a t e . M i x u n t i l homogeneous. 6 . A d d c o l o r and f r a g r a n c e , as d e s i r e d .

T o t a l A c t ives : Phosphorous c o n t e n t : S i l i c a t e (as Si02): Carbonate ( a s Na2C03): Sodium o l e f i n s u l f o n a t e : Sodium a l k y l b e n z e n e s u l f o n a t e : SOURCE:

3.7 2.7 5.0 3.2 17.6

BFGoodrich S p e c i a l t y Chemicals:

1

DET-111

38

Advanced Cleaning Product Formulations

L i g h t Duty Liquid,

Premium Hand D i s h w a s h

Wt%

Ingredients: Water, D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y W i t c a m i de 128T P e t r o LBA L i q u i d Sodium S u l f a t e Ethanol Formal i n P e r f u m e , Dye

30.2 21.7 36.7 5.0 1.9 2.6 1.8 0.1 9,s.

81 e n d i n g P r o c e d u r e : B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . A d j u s t pH t o 6 . 5 - 7 . 0 using C i t r i c Acid. Typical Properties: V i s c o s i t y , c p s : 230 A p p e a r a n c e : C1 e a r L i q u i d F o r m u l a 113

L i g h t D u t y L i q u i d Low C o s t Hand D i s h w a s h Ingredients:. W a t e r , D . I. W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y W i t c a m i d e 128T P e t r o LBA L i q u i d Sodium C h l o r i d e Formal i n Perfume, Dye

81 . 5

5.5 9.2 1.2 0.5 2.0 0.1 q.s.

Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . A d j u s t pH=6.5-7.0 using C i t r i c Acid. Typical Properties: V i s c o s i t y , c p s : 170 Appearance: C l e a r L i q u i d Formula 116

SOURCE:

Witco Corp.:

Suggested F o r m u l a t i o n s

Dishwashing Detergents

Liquid Automatic Dishwasher Deterqent T h i s f o r m u l a t i o n f e a t u r e s Van Gel ES, magnesium aluminum s i l i c a t e , as a s u s p e n d i n g a g e n t and r h e o l o g y m o d i f i e r . The sodium h y p o c h l o r i t e f u n c t i o n s as a d i s i n f e c t a n t , c l e a n i n g a g e n t and b l e a c h . Sodium m e t a s i l i c a t e a d j u s t s t h e f o r m u l a p H . The p h o s p h a t e b l e n d p r o v i d e s d e t e r g e n c y and t h e s u r f a c t a n t s contribute excellent r i n s a b i l i t y .

Wt%

Inqredi ents: A : Van Gel ES D e i o n i z e d Water

4.00 53.00

B : T e t r a p o t a s s i u m P y r o p h o s p h a t e , t e c h n i c a l powder Sodi um T r i p o l y p h o s p h a t e , t e c h n i c a l powder

10.00 20.00

C:

Sodium M e t a a s i l i c a t e . Anhydrous Sodium H y p o c h l o r i t e , 1 2 . 5 % s o l n .

2.00 8.00

D:

Sodium X y l e n e s u l f o n a t e Deceth-4-Phosphate

2.25 0.75

Procedure: P r e h e a t t h e w a t e r t o 5 5 t o 60C. H y d r a t e t h e Van Gel ES s l o w l y b y a d d i n g i t t o t h e a v a i l a b l e w a t e r u s i n g a h i g h speed d i s p e r s e r . Preblend B i n g r e d i e n t s , Add B t o A s l o w l y w i t h m i x i n g . M i x u n t i l u n i f o r m . Add C i n g r e d i e n t s i n t h e o r d e r l i s t e d , mixing u n t i l dissolved. Continue mixing w h i l e c o o l i n g r a p i d l y t o 25C. F i n a l l y , combine D i n g r e d i e n t s and add w h i l e m i x i n g s l o w l y u n t i l smooth and u n i f o r m ( a v o i d i n c o r p o r a t i o n of air). C o n s i s t e n c y and pH: Pumpable l i q u i d , V i s c o s i t y 1300-1800 c p s , B r o o k f i e l d Model LVT, S p i n d l e 4 a t 60 rpm measured a t room t e m p e r a t u r e a f t e r 3 0 days a g i n g ; pH a p p r o x i m a t e l y 1 2 . 5 . Suggested P a c k a g i n g : Squeeze b o t t l e o r pump.

SOURCE:

R.T.

V a n d e r b i l t Co.,

Inc.:

F o r m u l a t i o n No. 438

39

40

Advanced Cleaning Product Formulations

Manual D i shwashi n q G e l F u n c t i o n s & B e n e f i t s : C a r b o p o l EX-473: * v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, independent o f surfactant type *provides high c l a r i t y across s u r f a c t a n t l e v e l * i m p a r t s y i e l d v a l u e f o r s u s p e n s i o n o f , f o r i n s t a n c e , encapsulated actives * a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems *easy-to-use, odorless, l i q u i d form i n i r e d l ent :

Wt%

DI w a t e r

37.50

C a r b o p o l EX-473 ( 3 0 % ) * Sodium c i t r a t e Sodium h y d r o x i d e ( 1 8 % ) Ammonium l a u r y l s u l f a t e (30%)** Sodium l a u r y l e t h e r s u l f a t e (30%)***

10.00 0.50 2.00 25.00 25.00

* V i s c o s i t y modi f i e r : B F G o o d r i c h * * A n i o n i c s u r f a c t a n t : Standapol A : Stepan Chemical * * * A n i o n i c s u r f a c t a n t : S t a n d a p o l ES-3: S t e p a n C h e m i c a l P h y s i c a l P r o p e r t i es : B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 8 , 0 0 0 C P P r o d u c t pH: 6 . 5 - 7 . 0 Product c l a r i t y : c l e a r Procedure: 1 . U s i n g s l o w a g i t a t i o n ( 2 0 0 rpm) p r o v i d e d b y a L i g h - t n i n ' m i x e r o r s i m i l a r v a r i a b l e speed u n - i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i ng o p e r a t i o n s , add t h e C a r b o p o l EX-473 r e s i n i n t o t h e D I w a t e r . M i x u n t i l u n i f o r m a n d homogeneous. 2 . Add t h e sodium c i t r a t e . M i x u n t i l t h e sodium c i t r a t e i s completely dissolved. 3 . A d j u s t t h e pH w i t h sodium h y d r o x i d e t o d e s i r e d pH. 4. Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n . 5 . Check pH, r e a d j u s t w i t h a d d i t i o n a l s o d i u m h y d r o x i d e i f necessary. 6 . Add f r a g r a n c e and c o l o r , a s d e s i r e d .

SOURCE:

BFGoodrich S p e c i a l t y Chemicals:

DET-130

Dishwashing Detergents

_ Manual _ D i shwashi nq L i q u i d F u n c t i o n s B B e n e f i t s : Carbopol EX-473: * v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, i n d e p e n d e n t o f surfactant type *provides h i g h c l a r i t y across s u r f a c t a n t l e v e l * i m p a r t s y i e l d v a l u e f o r s u s p e n s i o n o f , f o r i n s t a n c e , encapsulated actives * a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems *easy-to-use, odorless, l i q u i d form

yt%

I n g r e d i en t . DI w a t e r

43.00 5.50 25.00 25.00 0.50 I .oo

Carbopol EX-473 ( 3 0 % ) Ammonium l a u r y l s u l f a t e (30%)* Sodium l a u r y l e t h e r s u l f a t e ( 3 0 % ) * + Sodium c i t r a t e Sodium h y d r o x i d e (18%) * A n i o n i c s u r f a c t a n t : S t a r i d a p o l A : Stepari Chemical * * A n i o n i c s u r f a c t a n t : S t a n d a p o l ES-3: Stepan Chemical Physical Properties: B r o o k f i e l d R V T v i s c o s i t y - 2 0 rpm: 5 0 0 CP Product pH: 6.5-7.0 Product c l a r i t y : Clear

Procedure: 1 . Using slow a g i t a t i o n (200 r p m ) provided by a L i g h t n i n ' Mixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , add t h e C a r b o p o l E X - 4 7 3 r e s i n i n t o t h e D I w a t e r . M i x u n t i l u n i f o r m and homogeneous. 2 . Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n . 3 . Add t h e sodium c i t r a t e , M i x u n t i l t h e sodium c i t i - a t e i s completely dissolved. 4 . A d j u s t t h e p H w i t h sodium h y d r o x i d e . 5 . Add f r a g r a n c e and c o l o r , a s d e s i r e d .

SOURCE:

BFGoodrich S p e c i a l t y C h e m i c a l s :

DET-120

41

42

Advanced Cleaning Product Formulations

N o n - C h l o r i n a t e d M a c h i n e D i s h w a s h i n q Compound,

Liquid

\Mt%

I n Q r e d ie n t s : Water, D . I . Sodi um T r i p o l y p h o s p h a t e Versene 2 2 0 , Powder Sodi um G1 u c o n a t e Sodium M e t a s i l i c a t e , P e n t a h y d r a t e C a u s t i c Soda 50% P e t r o ULF L i q u i d 81 e n d i ng P r o c e d u r e : Add a l l components i n t h e o r d e r shown, a d d i t i ons F o r m u l a 109

.

79.5 2.0

1

.o

1.o 7.0

8.5 1 .o

m i x i n g w e l l between

C h l o r i n a t e d M a c h i n e D i shwashi n q Compound,

Powder

Ingredients: Sodi um C a r b o n a t e (Soda A s h ) , L i g h t D e n s i t y Sodi um T r i p o l y p h o s p h a t e (STPP) , L i g h t D e n s i t y DeSoni c LFD-97 Sodium M e t a s i l i c a t e , Anhydrous C a u s t i c Soda Beads CDB C l e a r o n

30.0 25.0 1. o

30.0 10.0 4.0

Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d , mixing thoroughly w i t h each a d d i t i o n . F o r m u l a 111 N o n - C h l o r i n a t e d M a c h i n e D i shwashi n g Compound. Inqredi ents: Sodi um C a r b o n a t e (Soda A s h ) , L i g h t D e n s i t y Sodium T r i p o l y p h o s p h a t e (STPP), L i g h t D e n s i t y DeSoni c LFD-97 Sodium M e t a s i l i c a t e , Anhydrous C a u s t i c Soda Beads Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d , w i t h each a d d i t i o n . F o r m u l a 112

Powder

Wt% 33.0 25.0 2.0 30.0 10.0

mixing thoroughly

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s

Dishwashing Detergents

43

P r e m i um Hand D i shwashi ng D e t e r q e n t

Wt%

Inqredients: Water, D . I . A1 p h a - S t e p MC-48 S t e o l CS-330 N i n o l 30-LL o r N i n o l 40-CO Sodium C h l o r i d e P r o p e r t i es : Appearance: C l e a r y e l l o w l i q u i d pH, as i s : 6 . 5 - 7 . 5 V i s c o s i t y @ 25 deg. C , c p s : 220 S o l i d s , % : 39-40 Density, l b s / g a l : 8 . 8 Freeze/thaw, 3 c y c l e s : Pass C o l d s t o r a g e @ 4 deg. C . , 2 weeks: F l a s h p o i n t , deg. F: >200

6.9 56.0 30.0 5.6 1.5

Pass

M i x i n g Procedure: CHarge w a t e r . Add MC-48 and CS-330 and m i x . Add 30-LL o r 40-CO and m i x u n t i l homogeneous. S l o w l y add sodium c h l o r i d e t o t h i c k e n . M i x u n t i l c l e a r . A d j u s t p H w i t h s u l f u r i c a c i d o r sodium h y d r o x i d e as n e c e s s a r y .

Comment : The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e .

SOURCE:

Stepan C o . :

F o r m u l a t i o n No. 173

D i s h Washina A q e n t s f o r Manual Use

Inqredi ents: Water Lumorol 4154 Z e t e s o l NL Z u s o l a t 1008/85 Sodium c h l o r i d e F o r m u l a t i o n CT 02-01-04

79.0 12.0 6.0 1.o approx. 2 . 0

m e d ien t s : Water Z e t e s o l 2056 Amphotensid B 4 Z u s o l a t 1008/85 P u r t o n CFD F o r m u l a t i o n CT-02-01-05

76.5 20.0 2.0 1.o 0.5

SOURCE:

Zschimmer & Schwarz GmbH & C o . :

Wt%

Suggested F o r m u l a t i o n s

5. General Purpose

44

General Purpose Cleaners

45

Abrasive Cleaner w i t h Bleach Carbopol r e s i n s a r e used t o a c h i e v e a s t a b l e s u s p e n s i o n o f t h e c a l c i u m carbonate a b r a s i v e o a r t i c l e s i n t h e presence o f c h l o r i n e bleach lnqredient : DI[ Water Carbopol 674 o r 691* Good-Rite K-7058 (50%)** Sodi um h y d r o x i d e (50%) 2 . 4 ~sodium s i l i c a t e (52%) Sodium h y p o c h l o r i t e (14%) C a l c i urn c a r b o n a t e * * * Sodium n - d e c y l d i p h e n y l o x i d e d i s u l f o n a t e (45%

Wt% 53.76 0.80 2.00 2.80 2.50 7.14 30.00

****

1 .oo

*Suspension a i d : BFGoodrich * * A n t i - r e d e p o s i t i o n : BFGoodrich + * + A b r a s i v e : W h i t e #8 ( G e o r g i a M a r b l e ) * * * * A n i o n i c s u r f a c t a n t : Dowfax 382 (Dow Chemi

Physi ea9 P r o p e r t i e s : B r o o k f i e l d RVT v i s c o s i t y Product pH: 12-13 P r o d u c t c l a r i t y : Opaque ~

~

~

~

-

20 rpm: 3,960 c p

~

d

~

r

1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n '

2.

3. 4.

5.

M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous Add t h e low m o l e c u l a r w e i g h t p o l y a c r y l a t e p o l y m e r f o l l o w e d by t h e sodium h y d r o x i d e and sodium s i l i c a t e . M i x u n t i l homogeneous. Reduce a g i t a t i o n speed and add t h e sodium h y p o c h l o r i t e b l e a c h . (The p r o d u c t w i l l d r o p i n v i s c o s i t y a t t h i s p o i n t . ) Add t h e c a l c i u m c a r b o n a t e and f i n a l l y t h e s u r f a c t a n t w i t h c o n s t a n t a g i t a t i o n . M i x u n t i l homogeneous. Add f r a g r a n c e , as d e s i r e d . FGoedrich S p e c i a l t y Chemicals:

DET-343

~

46

Advanced Cleaning Product Formulations

A b r a s i v e Cleaner W i t h o u t

B1 each

Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a s t a b l e suspension o f t h e h i g h l o a d i n g o f c a l c i u m carbonate abrasives

.

Wt%

Insredient: D I Water Ethanol Carbopol 674 ( 1 ) Sodium h y d r o x i d e (50%) Sodium b i c a r b o n a t e Calcium carbonate ( 2 ) C12-15 1in e a r a1 coho1 , 3 moles EO ( 3 ) Coconut d i e t h a n o l ami de ( 4 ) B r o o k f ie l d v i s c o s i t y (RVT-20 P r o d u c t pH: 8-10 P r o d u c t c l a r i t y : Opaque

62.10 2.00 0.60 1 .00 1.20 30.00 2.50 0.60

rpm) : 4,500

cps

( 1 ) BFGoodr ich

( 2 ) G e o r g i a M a r b l e Co.: G e o r g i a M a r b l e W h i t e # 8 ( 3 ) S h e l l Chemical: Neodol 25-3 ( 4 ) Stepan Co.: N i n o l 11-CM

Procedure: 1 . Add t h e e t h a n o l t o t h e w a t e r - h o l d i n g back 10 p a r t s o f w a t e r f o r s t e p #3. 2 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n ’ M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r / e t h a n o l m i x t u r e . M i x t h e s l u r r y for a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 3 . P r e p a r e a n e u t r a l i z i n g s o l u t i o n o f t h e 10 p a r t s o f w a t e r w i t h t h e sodium h y d r o x i d e and sodium b i c a r b o n a t e . Add t h i s t o t h e m i x t u r e formed above and m i x u n t i l homogeneous. 4 . Add t h e c a l c i u m c a r b o n a t e , a l c o h o l e t h o x y l a t e and coconut QEA. M i x u n t i l homogeneous. 5 . Add f r a g r a n c e , as d e s i r e d . Total Actives: C a l c i um c a r b o n a t e : C12-15 l i n e a r a l c o h o l , Coconut DEA:

SOURCE:

3 moles EO:

30.0 2.5 0.6

BFGoodrich S p e c i a l t y Chemicals:

DET-340

General Purpose Cleaners

A l l Purpose C l e a n e r

Wei q h t % 2.00 2.00 88.00 1 .oo 5.00 2.00

Ingredients: Urea Na4EOTA Water 2990 Ammonia C a l s o f t L-40 C a l o x y l a t e N-9 Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n APC-001-01 A l l Purpose C l e a n e r

Wei q h t % 4.00 84.00 4.00 8.00

Ingredients: Na4EDTA Water, Perfume Dowanol DPnB C a l s o f t L-40

Comments a b o u t t h i s f o r m u l a : Compare t o M r . C l e a n , a t r a d e m a r k o f P r o c t o r & Gamble. F o r m u l a t i o n APC-002-01 A l l Purpose C l e a n e r Wei q h t % 40.00 4.00 4.00 10.00 42.00

Inqredi ent s : d - L i monene Calamide C C a l a m i d e CWT Cal imu1 se PRS Water Comments a b o u t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s f i r s t and m i x . 2 . Add w a t e r s l o w l y . 3 . M i x u n t i l homogeneous. F o r m u l a t i o n APC-005-01 A l l Purpose C l e a n e r

Weight% 85.00 15.00

Inqredi ents: Water Calamide CWT Comments a b o u t t h i s f o r m u l a : Formula t h i c k e n s e f f e c t i v e l y . F o r m u l a t i on APC-003-01 SOURCE: P i l o t Chemical C o . :

Suggested F o r m u l a t i o n s

47

48

Advanced Cleaning Product Formulations

A l l Purpose C l e a n e r Inqredients: Na4EDTA Water Calamide C Calamide CWT P i l o t SXS-40 Laurami ne O x i d e

Wei q h t % 5.00 77.50 2.50 2.50 2.50 10.00

Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n APC-006-01

A l l Purpose C l e a n e r Inqredients: Na4EDTA Water 50% NaOH Cal s o f t LAS-99 P i l o t SXS-40 Calamide C Calamide CWT

Wei q h t % 5.00 76.10 0.80 2.80 5.30 5.00 5.00

Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n APC-007-01

A l l Purpose C l e a n e r - No R i n s e Inqredients: Water C a l f a x 1OL-45 Na4 EDTA E t h y l e n e G l y c o l Monobutyl E t h e r Calamide CWT Comments a b o u t t h i s f o r m u l a : Spray a s i s , t h e n w i p e w i t h a p a p e r t o w e l . F o r m u l a t i o n APC-008-01 SOURCE: P i l o t Chemical Co.:

Suggested F o r m u l a t i o n s

Weight% 89.00 3.00 3.00 3.00 2.00

General Purpose Cleaners

49

A 1 1- P u r p o s e C 1 e a n e r Composi t ion : K e l z a n x a n t h a n gum A1 ip a l CD-128 G a f a m i d e CDD 518 B u t y l C e l l o s o l ve S o d i urn M e t a s i 1 ic a t e T r i s o d i urn P h o s p h a t e Water, Perfume

0.3 1.7 0.5 3.5 1.7 1.o 91.3

Procedure: P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum b y a d d i n g t h e powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n . Add o t h e r i n g r e d i e n t s as i n d i c a t e d . F o r a e r o s o l u s e , c h a r g e w i t h a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n a n d 15 p e r c e n t G e n e t r o n 12.

All-Purpose

D i s i n f e c t a n t Cleaner

Q 0.5 10.0 3.0 3.0 1.o 82.5

Composi ti= K e l z a n x a n t h a n gum Makon 1 0 Sodium T r i p o l y p h o s p h a t e V e r s e n e 100 Hyarnine 1 O X Water

Procedure: P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum b y a d d i n g t h e powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n . Add o t h e r i n g r e d i e n t s a s i n d i c a t e d . F o r a e r o s o l u s e , c h a r g e w i t h a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n and 15 p e r c e n t G e n e t r o n 12.

SOURCE: M o n s a n t o P e r f o r m a n c e M a t e r i a l s : K e l z a n S u g g e s t e d Formulations A l l Purpose C l e a n e r

Wt%

l n q r e d i en& R h o d a t e r g e SMC STPP Water

SOURCE:

Rhone-Poulenc Formulations

10 2 88 Surfactants & Specialties:

Suggested

50

Advanced Cleaning Product Formulations

A l l Purpose C l e a n e r w/Amide/Phosphate Innredi ents: W a t e r , D.I. Tetrapotassium Pyrophosphate Varami de A-1 0 Emphos 5AP

Ester

Wt% 83.0 5.0 10.0 2.0

81 e n d i ng P r o c e d u r e : Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . Typical Properties: V i s c o s i t y , c p s : 145 S o l i d s : 17.0% pH: 8 . 8 Formula 514 A l l Purpose C l e a n e r

wto/,

Ingredients: Water W i t c o n a t e 1 2 6 0 S1 u r r y Witcamide 6445

56.0

38.5 5.5

Blending Procedure: B1 end i n g r e d i e n t s i n t h e o r d e r 1 is t e d . Typical Properties: V i s c o s i t y , c p s : 670 Sol i d s : 33.0% pH, as i s : 9 . 2 Formula 520 A1 1 Purpose C l e a n e r Ingredients: Water Sodi um T r i p o l y p h o s p h a t e C a u s t i c Soda, 50% W i t c o 12988 W i t c a m i de 6 4 4 5 Perfume, Dye Blending Procedure: Blend i n g r e d i e n t s i n order l i s t e d . T y p i c a l P r o p e r t ie s : Speci f ic G r a v i t y : 1 . 0 2 0 6 Wt./Gal. l b s . : 8 . 5 pH, as i s : 9 . 1 2 V i s c o s i t y , c p s : 107 Color: Beige Use D i l u t i o n : 1 - 2 o z . / G a l . Formula 535 SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s

W S 90.0 2.0 0.5 2.0 5.0 q.s.

General Purpose Cleaners

A l l Purpose C l e a n e r C o n c e n t r e (Phosphate, - L i q u i d ,

Foam)

S o i 1 - G r e a s e and o i 1 Surface-Paint, polymeric, metal A p p l i c a t i o n Method-Spray Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t ion: Water M e t s o Beads 2048 TKPP ( 6 0 % ) *Phosphate E s t e r * * D i p r o p y l e n e G l y c o l Monomethyl E t h e r * * * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 9-10 M o l e s E O ****Octylphenoxy P o l y e t h o x y e t h a n o l , 5 M o l e s EO

Wt% 78.1 2.4 3.0

3.0 6.0 5.0 2.5

Use D i l u t i o n : Normal D u t y - 1 . 5 % bw ( 2 o z / g a l l o n ) Heavy D u t y - 2 . 5 % b w ( 3 . 3 o z / g a l 1on) Tough D u t y - a s s u p p l i e d

* **( *** ****

Rhone-Poulenc R h o d a f a c RE-610 Dow, A r c 0 C h e m i c a l Rhone-Poulenc I g e p a l CA-630 Rhone-Poulenc I g e p a l CA-520

A l l Purpose C o n c e n t r a t e (Phosphate,

Liquid1

S o i 1 - G r e a s e and o i 1 Surface-Paint, polymeric, metal A p p l i c a t i o n Method-Wipe o r b r u s h Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i on : Water M e t s o Beads 2048 TKPP Sodium X y l e n e S u l f o n a t e , 40% *Ethylene Glycol n-Butyl Ether Pine O i l * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3, 6 . 5 M o l e s EO) * * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5, 3 M o l e s EO) Use D i 1u t i o n :

* *l *S*

1 . 5 - 3 . 0 % bw ( 2 - 4 o z / g a l l o n )

Dow C h e m i c a l , U n i o n C a r b i d e Rhone-Poul enc R h o d a s u r f LA-7 Rhone-Poulenc R h o d a s u r f A-24

SOURCE:

PQ C o r p . :

D e t e r g e n t F o r m u l a t i o n Guide

wto/, 78.75 1 .oo 3.00 3.50 6.00

0.25 5.00 2.50

51

52

Advanced Cleaning Product Formulations

Calcium Carbonate A b r a s i v e Cleaner W i t h o u t Bleach Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a s t a b l e suspension o f t h e h i g h l o a d i n g o f c a l c i u m c a r b o n a t e abrasives

.

I n q r e d ie n t : D I Water Carbopol ETD 2623 ( 1 ) Sodium h y d r o x i d e (50%) C12-I5 l i n e a r a l c o h o l , 3 moles EO ( 2 ) Sodium a l k y l benzene s u l f o n a t e ( 3 ) Calcium carbonate ( 4 ) P h y s i c a l P r o p e r t ies : B r o o k f i e l d V i s c o s i t y (RVT-20 P r o d u c t pH: 8-10 P r o d u c t C l a r i t y : Opaque

rpm):

62.10 0.25 0.20 1.50 0.50 30.00

7,500 c p

Raw M a t e r i a l S u p p l i e r s : ( 1 ) BFGoodrich ( 2 ) S h e l l Chemical Co.: Neodol 25-3 ( 3 ) Stepan Co. : Nacconol SQG ( 4 ) Georgia Marble C o . : Georgia Marble White #8 Procedure: 1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i ng and b l endi ng o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s or u n t i l t h e s l u r r y i s homogeneous. 2. Add t h e sodium h y d r o x i d e t o r e a c h t a r g e t pli. The p r o d u c t w i l l become v e r y t h i c k a t t h i s p o i n t . 3 . Add t h e a l c o h o l e t h o x y l a t e and a l k y l b e n z e n e s u l f o n a t e s u r f a c t a n t s . M i x u n t i l homogeneous. 4 . Add t h e c a l c i u m c a r b o n a t e . M i x u n t i l homogeneous. 5. Add f r a g r a n c e , as d e s i r e d . Total Actives: Calcium carbonate: 30.00 C12-15 l i n e a r a l c o h o l , 3 moles EO: 1.50 Sodium a1 k y l b e n z e n e s u l f o n a t e : 0.50

SOURCE:

BFGoodrich S p e c i a l t y Chemicals:

BET-341

General Purpose Cleaners

53

C i t r i c A c i d Cleaner

F u n c t i a n e 8 B e n e f i t s : Carbopol ETD 2623: * P r o v i d e s l o w p H t h i c k e n i n g v i a hydrogen b o n d i n g w i t h s u r f actant * I m p a r t s y i e l d v a l u e f o r suspension o f a b r a s i v e p a r t i c l e s *Provides v e r t i c a l c l i n g f o r increased s u r f a c e c o n t a c t t i m e *Shear t h i n n i n g r h e o l o g y f o r easy d i s p e n s i n g t h r o u g h t r i g g e r sprayer o r nozzle * E a s y - t o - d i s p e r s e r e s i n f o r improved and e a s i e r f u l l - s c a l e processing

Wt%

Inqiredi e n t :

DI Water

78.40 0.10 5.00 2.50 2.00 12.00

Carbopo? ETD 2623 R e s i n * C12-15 l i n e a r a l c o h o l , 3 moles EO** C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO*** Alkylbenzene s u l f o n i c acid**** C i t r i c A c i d (50%) *V iscos ity modi f ie r : BFGoodr ic h s W o n i o n i c s u r f a c t a n t : Neodol 25-3: She1 1 Chemical S h e l l Chemical >N**Nonionic s u r f a c t a n t : Neodol 23-6.5: * * r * A n i o n i c s u r f a c t a n t : B i o s o f t 5-100: Stepan

P h y s i c a l P r o p e r t iee: B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: Initial: Age-Up V i s c o s i t y : Week 2 : Week 4 : Week 6: P r o d u c t pH: 1 . 4 Product c l a r i t y : T r a n s l u c e n t

S t o r a g e Temperature -25C .

5oc

50cP 170cP 250cP 350cP

50cP 400cP 600cP 400cP

Procedurw: 4.

2.

3. 4.

5.

U s i n g J m a r i n e b l a d e p r o p e l l e r and r a p i d a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t , s p r i n k l e t h e Carbopol ETD 2623 r e s i n i n t o t h e v o r t e x . A l l o w t o h y d r a t e f o r 15-20 m i n u t e s o r u n t i l no lumps a r e p r e s e n t . Warming t h e d e i o n i z e d w a t e r t o 30C w i l l decrease t h e h y d r a t i o n t i m e and i m p r o v e t h e d i s p e r s i b i l i t y o f t h e Carbopol powder. M i x t h e Neodol 25-3 and Neodol 2 3 - 6 . 5 ( o r warm s l i g h t l y i f needed) t o e n s u r e homogeneity. A d d w i t h moderate m i x i n g (300 r p m ) . A l l o w t o mix u n t i l u n i f o r m and smooth. Add t h e B i o s o f t S-100 w i t h moderate (300 rpm) m i x i n g and a l l o w t o m i x u n t i l u n i f o r m and smooth. S ~ O W add ~ Y t h e C i t r i c A c i d w i t h s l o w m i x i n g (200 r p m ) . M i x u n t i l smooth and u n i f o r m . Add f r a g r a n c e and c o l o r , a s d e s i r e d .

S O U R C E : B F G o o d r i c k S p e c i a l t y ChemicaJs:

DET-352

54

Advanced Cleaning Product Formulations

G e n e r a l P u r p o s e C1 e a n e r (Consumer Low Alkaline, Non-Phasphate Powder) S o i l - F o o d ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , c l a y and p a r t i c u l a t e s o i l Surface-Hard surface, i . e . , metal, p l a s t i c , ceramic, concrete, and a s p h a l t A p p l i c a t i on Method-Wi p e o r B r u s h Manufacture-Dry blend/Agglomeration Composi t i o n : Sodi um C a r b o n a t e ( 1 i g h t d e n s i t y ) * B r i t e s i 1 C20 Hydrous P o l y s i 1 i c a t e * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5; 9 M o l e s EO) V a l f o r 100 Z e o l i t e A * * * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) Sodi um S u l f a t e Use L e v e l :

* ***

**

Wt% 30.0 10.0 15.0 30.0 0.5 14.5

1-4 o z / g a l l o n

2 . 0 w e i g h t r a t i o s i l i c a t e powder, Rhone-Poulenc R h o d a s u r f LA-9 Rohm & Haas

82.5% s o l i d s

G e n e r a l Purpose C l e a n e r (Consumer H i g h A 1 k a l ine, Non-Phosphated Powder1 S o i -Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , c l a y and p a r t i c u l a t e s o i l Sur ace-Hard s u r f a c e , i . e . , m e t a l , p l a s t i c , c e r a m i c , c o n c r e t e , and a s p h a l t App i c a t i o n Method-Wipe o r b r u s h Manufacture-Dry blend/Agglomeration Composi t i o n 1 Sodium S u l f a t e Sodi um C a r b o n a t e ( 1 ig h t d e n s i t y ) * L i q u i d N o n i o n i c S u r f a c t a n t ( C 1 2 - C l 5 ; 9 M o l e s EO) V a l f o r 100 Z e o l i t e A M e t s o Beads 2048 * * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) Use L e v e l :

*

**

1-4 o z / g a l l o n

Rhone-Poulenc Rohm & Haas

R h o d a s u r f LA-9

SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t i o n Guide

Wt%

14.5 30.0 15.0 30.0 10.0 0.5

General Purpose Cleaners

55

G e n e r a l P u r p o s e S p r a y & Wipe C l e a n e r Carbopol r e s i n s a r e used t o i n c r e a s e t h e y i e l d v a l u e r e s u l t i n g i n v e r t i c a l c l i n g when s p r a y e d on a v e r t i c a l s u r f a c e . T h i s "no-drip" action w i l l increase the contact time o f t h e detergent on t h e s o i l e d s u r f a c e a s w e l l a s enhance consumer c o n v e n i e n c e .

wto/, 90.70 0.20 2.00 2.30 3.00 1.50

Ingredient: D I Water C a r b o p o l ETD 2 6 9 1 ( 1 ) EDTA ( t e t r a s o d i u m s a l t ) Sodium m e t a s i l i c a t e , a n h y d r o u s P r o p y l ene g l y c o l m e t h y l e t h e r ( 2 ) C12-15 l i n e a r a l c o h o l , 7 m o l e s EO ( 3 ) B r o o k f i e l d v i s c o s i t y (RVT-20 rpm) : 120 c p s P r o d u c t p H : 12-13 P r o d u c t C l a r i t y : C l e a r t o hazy ( 1 ) BFGoodri c h ( 2 ) Dow C h e m i c a l : Dowanol DPM ( 3 ) S h e l l C h e m i c a l : Neodol 25-7

Procedure: 1 . U s i n g m o d e r a t e a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s or u n t i l t h e s l u r r y i s homogeneous. 2 . Under s l i g h t a g i t a t i o n , add t h e EDTA and M e t a s i l i c a t e . 3 . C o n t i n u e a g i t a t i o n and add t h e g l y c o l e t h e r and a l c o h o l e t h o x y 1a t e . 4 . Add c o l o r and f r a g r a n c e , a s d e s i r e d . T o t a l Actives: Propylene g l y c o l methyl e t h e r : C 1 2 - I 5 l i n e a r a l c o h o l , 7 m o l e s EO:

SOURCE:

3.0 1.5

BFGoodrich S p e c i a l t y Chemicals:

DET-310

56

Advanced Cleaning Product Formulations

G e n e r a l P u r p o s e Spray & Wipe

Wt%

Ingredients: Water, D.I. Sodi um C i t r a t e A1 p h a - S t e p MC-48 S t e p a n o l WA-Extra N i n o l 11-CM

79.0 2.0 10.0 7.0 2.0

M i x i n g Procedure: Charge w a t e r and s u r f a c t a n t s and m i x . Add sodium c i t r a t e and m i x u n t i 1 homogeneous. T y p i c a l P r o p e r t i es : Appearance: C l e a r c o l o r l e s s l i q u i d pH, as i s : 9 . 4 Viscosity I 3 2 5 deg. C : V e r y t h i n S o l i d s , %: 1 0 . 0 Density, l b s / g a l : 8.54 C o l d s t o r a g e @ 4 d e g . C, 1 d a y : p a s s F r e e z e / t h a w , 3 c y c l e s : pass Performance: Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t : Commercial P r o d u c t - 66% s o i l removed f r o m t i l e s Above f o r m u l a t i o n - 82%' s o i l removed f r o m t i l e s Above f o r m u l a t i o n p e r f o r m s b e t t e r t h a n c o m m e r c i a l product. Use I n s t r u c t i o n s :

Use as i s

Comment : The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e .

SOURCE:

Stepan Co.:

Suggested F o r m u l a t i o n

No. 575

A1 1 -Purpose C1 e a n e r Ingredients: Water Z e t e s o l 2056 Z u s o l a t 1008/85

SOURCE:

Zschimmer & Schwarz GmbH & C o . :

82.0 14.0 4.0 F o r m u l a t i o n CT 02-04-02

General Purpose Cleaners

H y p o c h l o r it e V e r t i c a l S u r f a c e C l e a n e r M o n a t r o p e 1250 i s a h y p o c h l o r i t e s t a b l e s u r f a c t a n t t h a t c o n t r i b u t e s t o w e t t i n g and f o a m i n g c h a r a c t e r i s t i c s .

Wt%

In q r e d ie n t s : M o n a t r o p e 1250 Sodium C14-17 A l k y l Sec S u l f o n a t e (60%) Laurami ne O x i d e (30%) P o t a s s i u m H y d r o x i d e (45%) Sodi um T r i p o l y p h o s p h t e Sodium H y p o c h l o r i t e 5 . 2 5 % )

2.0 2.0 10.0 15.0 5.0 66.0

Procedure: Add i n g r e d i e n t s w t h a g i t a t i o n .

Typical Properties: Appearance: C l e a r y e l l o w l i q u i d p H : 13 Recommended Use D i l u t i o n : Formul a t i on F-783

1:lO w i t h w a t e r

Pump S p r a v A l l

Purpose C l e a n e r

A f a s t a c t i o n s p r a y and w i p e f o r m u l a t i o n . streak-f ree.

Surfaces w i l l

Inqredients: Water M o n a t e r g e 779 (DEA-Laureth S u l f a t e ) Propylene Glycol B u t y l Ether Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r l i q u i d Recommended Use D i 1 u t i o n : As i s SOURCE: Mona I n d u s t r i e s ,

I n c . : Suggested F o r m u l a t i o n s

dry

Wt% 94.0 3.0 3.0 Package.

57

58

Advanced Cleaning Product Formulations

L i q u i d C 1 eanser w i t R B1 each I n t h i s f o r m u l a Van Gel B i s used t o suspend t h e a b r a s i v e and t o a d j u s t t h e v i s c o s i t y . The sodium c a r b o n a t e b u f f e r h e l p s m a i n t a i n a pH o f a b o u t 1 1 , n e c e s s a r y f o r t h e s t a b i l i t y o f t h e h y p o c h l o r i t e . T h i s l i q u i d c l e a n s e r o f f e r s t h e advantage o f m i l d ness i n u s e and g r e a t e r ease and e f f e c t i v e n e s s on v e r t i c a l s u r f a c e s a s compared t o powders. Ingredients: A : Van Gel B Water

2.25 62.25 '10.00 4.50 20.00 1 .oo

6 : Diatomaceous E a r t h Sodium c a r b o n a t e Sodium h y p o c h l o r i t e , 5 . 2 5 % s o l n . Sodium L a u r y l S u l f a t e , 29% s o l n .

Procedure: S l o w l y add Van Gel B t o t h e w a t e r w h i l e a g i t a t i n g a t maximum a v a i l a b l e s h e a r . C o n t i n u e m i x i n g u n t i l smooth. Add r e m a i n i n g i n g r e d i e n t s i n o r d e r , m i x i n g w e l l a f t e r each a d d i t i o n . Consistency:

Medium v i s c o s i t y

Suggested Packaging:

liquid.

P l a s t i c squeeze b o t t l e .

SOURCE: R . T . V a n d e r b i l t

Co.,

Inc.:

F o r m u l a t i o n N o . 391

A l l Purpose C l e a n e r Clear,

liquid

Ingredients: A : H o s t a p u r SAS 6 0 Genapol ZRO 1 iq u i d Genapol UD-080 B : Water

Perfume Preservative Dye

Wt% 10.0-15.0 0.0- 4.0 1.0- 3 . 0

ad 1 0 0 . 0 0.2 0.1 q.s.

Manufacturing: Add one a f t e r a n o t h e r , t h e components o f B t o A . Modern s t a n d a r d f o r m u l a t i o n s a r e based on a l k a n s u l p h o n a t e s and noni oni c s E t h e r s u l p h a t e s a r e used i n r a r e cases. Phosphates, sodium c a r b o n a t e and ammonia a r e n o t common any 1onger The above g u i d e f o r m u l a t i o n c o v e r s t h e common european p r o d u c t s .

.

.

SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n

General Purpose Cleaners

59

Pine O i l Cleaner Concentrate

g

Ingredients: Pine o i l N i n o l 11-CM Makon 12 Ammonyx LO B i o - S o f t S-1 0 0 Isopropanol Water, D . I .

20.0 9.0 5.0 0.5 2.0 10.0 53.5

M i x i ng Procedure: Combine p i n e o i l , s u r f a c t a n t s and I P A . M i x u n t i l c l e a r . Add water s l o w l y w h i l e under a g i t a t i o n . Mix u n t i l c l e a r . Properties: Appearance: C l e a r y e l l o w l i q u i d Odor: P i n e V i s c o s i t y @ 25C, c p s : 50 pH ( a s i s ) : 8 . 1 D e n s i t y 1b s / g a l : 8 . 0 6 Freeze/Thaw ( 3 c y c l e s ) : Pass 50 C oven ( 1 week): Pass Use I n s t r u c t i o n s : D i l u t e 1-2 o z s i n t o one g a l l o n Performance: Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t : Above f o r m u l a t i o n : 73.0% s o i l removed f r o m t i l e s Commercial f o r m u l a t i o n : 5 5 . 5 % s o i l removed f r o m t i l e s SOURCE: S t e p a n Co.: F o r m u l a t i o n No. 208 D i s i n f e c t i n g Cleaner, Ingredients: Water C i t r i c acid Z u s o l a t 1008/85 Lumorol 4192 Trilon A liquid Lonzabac-1230 Ingredients: Water Disodium t e t r a b o r a t e decahydrate Sodi um b i c a r b o n a t e Burdac-114 Z u s o l a t '1008/85 Ingredients: Water Trilon A liquid Citric acid S u l f e t a l 4069 Z u s o l a t 1008/85 Lonrabac-1230

SOURCE:

Zschimmer & Schwarz GmbH & Co.: CT 06-09-02, CT 06-09-03

Alkaline

Wt% 57.5 2.0 3.5 5.0 7.0 25.0

Wt% 69.0 0.5 1.0 20.0 9.5

g 57.5 7.0 2.0 5.0 3.5 25.0 F o r m u l a t i o n s CT 06-09-01,

60

Advanced Cleaning Product Formulatiorrs

Sodi urn B i c a r b o n a t e A b r a s i v e C l e a n e r W i t h o u t B l e a c h Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a s t a b l e s u s p e n s i o n o f t h e h i g h l o a d i n g o r sodium b i c a r b o n a t e abrasives.

wtsl, 44.25

Ingredient:

D I Water C a r b o p o l ETD 2691 ( 1 ) A l k y l benzene s u l f o n i c a c i d ( 2 ) C12-13 l i n e a r a l c o h o l , 6 . 5 m o l e s € 0 ( 3 ) Sodium h y d r o x i d e ( 5 0 % ) Sodium b i c a r b o n a t e ( 4 ) : Grade 1 : Grade 5 :

Physical Properties: B r o o k f i e l d V i s c o s i t y (RVT-20 rprn): Product pH: 8.50 P r o d u c t C l a r i t y : Opaque

0.50 0.75 2.50 2.00 20.00 30.00

6,000 c p

Raw M a t e r i a l S u p p l i e r s : ( 1 ) BFGoodrich ( 2 ) Stepan Co.: B i o s o f t 5-100 ( 3 ) S h e l l C h e m i c a l C o . : Neodol 2 3 - 6 . 5 ( 4 ) Church & Dwight Procedure: 1 . U s i n g moderate a g i t a t i o n ( 8 0 0 r p m ) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 1 5 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . Add t h e a l k y l b e n z e n e s u l f o n i c a c i d f o l l o w e d b y t h e a l c o h o l e t h o x y l a t e . M i x u n t i l homogeneous. 3 . Add t h e s o d i u m h y d r o x i d e . M i x u n t i l homogeneous. A d j u s t pH t o 8.50 p r i o r t o t h e next step. 4 . W i t h m i n i m a l a g i t a t i o n , s l o w l y add t h e s o d i u m b i c a r b o n a t e . M i x u n t i l smooth, homogeneous, and f r e e o f b i c a r b o n a t e l u m p s . Re-check p H and a d j u s t , i f n e c e s s a r y . 5 . Add c o l o r a n d f r a g r a n c e , a s d e s i r e d . T o t a l A c t iv e s : S o d i um b i c a r b o n a t e : C12-13 l i n e a r a l c o h o l , 6 . 5 m o l e s EO: Sodium a1 k y l benzene s u l f o n a t e : SOURCE: B F G o o d r i c h S p e c i a l t y C h e m i c a l s :

50.00

2.50 0.90

DET-342

leaners/Polishes

61

62

Advanced Cleaning Product Formulations

A n t i -Foggi ng , A n t i -Stat ic G l a s s C l eaner

MIBo/o

In g r e d i e n t s : Water Isopropyl Alcohol Adogen 66 Varox 365 Emcol 4500

90.0 9.0 0.I 0.5 0.4

Blending Instructions: Combine i n g r e d i e n t s i n t h e o r d e r shown and m i x t h o r o u g h l y . I f p r o d u c t i s hazy, a d d i t i o n a l I s o p r o p y l Alcohol can be used t o c l a r i f y t h e s o l u t i o n . G e n t l y h e a t i n g can b e used t o f a c i l i t a t e m i x i n g o f t h e Emcol 4500. Use I n s t r u c t i o n s : A p p l y f i n i s h e d p r o d u c t t o a t o w e l l e t e (Kimwipe, wipe onto t h e glass. A l l o w t o d r y .

e t c . ) and

Product I n f o r m a t i o n : Product: Benefit : Varox 365 W e t t i n g a g e n t , d e g r e a s e r and d e t e r g e n t Adogen 66 A n t i - s t a t i c agent Emcol 4500 W e t t i n g a g e n t , c o u p l e r and d e t e r g e n t T h i s f o r m u l a t i o n p r e s e n t s a t h i n b a r r i e r between t h e w a t e r v a p o r ( f o g , steam, e t c . ) and t h e g l a s s w h i c h w i l l p r e v e n t f o g g i n g . The a b i l i t y t o l o w e r t h e s u r f a c e t e n s i o n o f t h e w a t e r prevents t h e c l i n g i n g o f i n d i v i d u a l water d r o p l e t s t o the glass; t h e r e f o r e l i g h t i s n o t s c a t t e r e d as much a s i t i s when p a s s i n g through i n d i v i d u a l d r o p l e t s . F o r m u l a 708

Glass Cleaner,

Ready t o Use

Ingredients: Water, D . I . P e t r o BAF L i q u i d Isopropanol E t h y l e n e G l y c o l Monobutyl E t h e r Dye B l e n d i ng P r o c e d u r e : B l e n d i n g r e d i e n t s i n t h e o r d e r 1is t e d . F o r m u l a 705 SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s

84.9 0.1 10.0 5.0 q.s.

Glass CleanerslPolishes

63

G l a s s C l e a n e r C o n c e n t r a t e (Non-Ammoniated)

K %

Ingredients: W a t e r , D . I. I s o p r o p a n o l , 99% P e t r o LBA Powder Monoethanol ami ne Perfume, Dye

7.5

82.0 1.o 0.5 q.

B l e n d i n g Procedure:

s

Blend i n g r e d i e n t s i n t h e order l i s t e d .

T h i s c o n c e n t r a t e s h o u l d be m i x e d w i t h n i n e p a r t s o f w a t e r t o one p a r t c l e a n e r t o b e r e a d y t o u s e . T h i s p r o d u c t r e q u i r e s a red label. F o r m u l a 702 Glass Cleaner Concentrate

Wt%

Inqredi ents: Water, D . I . P e t r o BAF L i q u i d DeSonic 5 N Ammonia, 29% Dye

77.0 20.0 1.o 2.0 q.s.

B l e n d i n g Procedure: Use D i l u t i o n : F o r m u l a 703

Blend i n g r e d i e n t s i n t h e order l i s t e d .

1 p a r t c o n c e n t r a t e t o 50 p a r t s w a t e r .

Amrnoniated G l a s s C l e a n e r

Wt%

m r e d ients: Water W i t c o l a t e 231 0 B u t y l C e l l o s o l ve Aqua Ammonia, 26 B e ' B l e n d i n g Procedure: F o r m u l a 704

94.0 3.0 2.0 2.0

Blend i n g r e d i e n t s i n t h e order l i s t e d .

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s

64

Advanced Cleaning Product Formulations

G l a s s and Window C l e a n e r Carbopol r e s i n s a r e used t o i n c r e a s e t h e y i e l d v a l u e r e s u l t i n g i n v e r t i c a l c l i n g when s p r a y e d on a v e r t i c a l s u r f a c e . T h j s "no-drip" a c t i o n w i l l increase the contact time o f t h e detergent on t h e s o i l e d s u r f a c e as w e l l as enhance consumer c o n v e n i e n c e .

wel

Inaredient: D I Water Carbopol ETD 2623 Isopropanol Ammonium h y d r o x i d e A l k y l b e n z e n e s u l f o n i c a c i d (97%) ( 2 ) Propylene g l y c o l methyl e t h e r (3)

92 * 45 (4.10 5.00 0.20 0.25 2.00

Physical Properties: B r o o k f ie l d V i s c o s i t y (RVT-20 rpm) : 200 c p P r o d u c t pH: 9 . 5 - 1 0 . 0 Product C l a r i t y : Clear Raw M a t e r i a1 Suppl ie r s : ( 1 ) BFGoodrich ( 2 ) Stepan Chemical: B i o s o f t 5-100 ( 3 ) Dow Chemical: Dowanol PM Procedure: 1 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . Add t h e i s o p r o p a n o l . 3 . Add t h e ammonium h y d r o x i d e . M i x u n t i l homogeneous. 4 . Add t h e s u l f o n i c a c i d and g l y c o l e t h e r w i t h m i n i m a l a g i t a t i o n t o a v o i d e x c e s s i v e foaming. 5 . Add a d d i t i o n a l ammonium h y d r o x i d e , i f necessary, t o r e a c h the t a r g e t pH r a n g e . 6 . Add c o l o r and f r a g r a n c e , as d e s i r e d . Total Actives: Ammonium a l k y l b e n z e n e s u l f o n a t e : 0 . 3 0 Propylene g l y c o l methyl e t h e r : 2.00 Isopropanol: 5.00 SOURCE: BFGoodrich S p e c i a l t y Chemicals:

DET-300

Glass CleanerslPolishes

65

H o u s e h o l d Window C l e a n e r

Wt%

Inqredients: Water. D . I . Isopropanol Varox 365 Methylene Blue

89.3 10.0 0.7 q.s.

Blending Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . T y p i c a l P r o p e r t ies: V i s c o s i t y , cps: 4 S o l i d s : 0.2% pH: 7 . 4 F o r m u l a 706 Bremi u m Household W i ndow C1 e a n e r Q 89.4 10.0 0.6 q. s

Ingredi ents: Water, D . I . Isopropanol Varox 1770 Methylene Blue

81 e n d i ng P r o c e d u r e : Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . Typical Properties : V i s c o s i t y , cps: 4 S o l i d s : 0.23% pH: 6 . 2 F o r m u l a 707

GI ass @1e a n e r Wt%

Ingredients: Water. D . I . Isopropanol Dowanol EB R e w o t e r i c AM V

q.s. 6.0 4.0 0.85

81 endi ng P r o c e d u r e : B l e n d i n g r e d i e n t s i n t h e o r d e r shown, ween each a d d i t i o n . F o r m u l a 709 SQURCE: W i t c o G o r p . :

mixing thoroughly bet-

Suggested F o r m u l a t i o n s

66

Advanced Cleaning Product Formulations

W i n d o w s / G l ass

Gl-ass Cl g a n g r C C o n c e n t r a t e ) Ingredients: Water Ethylene G l y c o l Monobutyl Ether Isopropyl Alcohol Ammonia, 2 9 . 4 % C a l foam SLS-30

We i s h t YO 10.04 21.34 53.30 2.35 5.00

Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d F o r m u l a t i o n WIN-001-01

W i n-dzhield Washer C c n c e n t r a t e

Ingredients: Water Isopropyl Alcohol C a l s u d s 81

Weigh_% 47.66 47.30 5.10

Comments a b o u t t h i s f o r m u l a : Use 4 0 2 . o f t h e c o n c e n t r a t e p e r g a l l o n . F o r m u l a t i o n WIN-002-01

W i ndshjeld-pWashec C o n c e n t y a t e (Low VOC)

Ing r e d i-en t s : Water P r o p y l ene G1 y c o l Calsuds 81

We i gh ts/, 62.20 33.80 4.02

Comments a b o u t t h i s f o r m u l a Use l e v e l : 2-4 o z p e r g a l l o n . F o r m u l a t i o n WIN-003-01 SOURCE: P i l o t C h e m i c a l C o . :

Suggested F o r m u l a t i o n s

ard Surface Cleaners

67

68

Advanced Cleaning Product Formulations

A l k a l i n e Hard Surface Cleaner In g r e d i e n t s : Water, D . I . Sodi um M e t a s i 1 ic a t e Varami de A-83 W i t c o n a t e 30DS W i t c o n a t e SXS L i q u i d

34.0 8.0 12.0 40.0 8.0

81 e n d i n g P r o c e d u r e : Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t io n . Typical Properties: V i s c o s i t y , c p s : 205 S o l ids : 3 4 . 4 % pH: 1 2 . 5 F o r m u l a 516 Hard Surface CleaEer Concentrate ( A l l Ingredients: Water, D . I . T e t r a s p o t a s s i u m P y r o p h o s p h a t e , Anhydrous W i t c a m i de 1 PET Emphos 5AP W i t c o 1298S A Blending Procedure: Blend i n g r e d i e n t s i n order l i s t e d , addition.

\Ne% 82.0 10.0 1.o 4.0 3.0

m i x i n g w e l l a f t e r each

Typical Properties: S p e c i f i c G r a v i t y : 1.085 Wt./Gal. l b s : 9.04 pH, a s i s : 7 . 5 7 V i s c o s i t y , c p s : 94 3 Freeze/Thaw c y c l e s : Passed 1 Week @ 52C: Passed 4 Weeks Room Temp: Passed S o l i d s : 17.8% Appearance: C 1 e a r L i q u i d Use D i l u t i o n : 1-3 o z . / g a l . F o r m u l a 540

SOURCE: W i t c o C o r p . :

P u r p o s e Type)

Suggested F o r m u l a t i o n s

Hand Surface Cleaners

Concentrated Hard Surface Cleaner Ingredients: D e o d o r i z e d Kerosene Calamide CWT C a l o x y l a t e N-9 E t h y l e n e G l y c o l Monobutyl E t h e r Water N a4 E DTA Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . Use 1-2 o z p e r g a l l o n . F o r m u l a t i o n HSC-009-01

Wei q h t % 25.00 16.30 9.00 9.00 41 .30 0.40

Hard Surface Cleaner-Spray Inqredi ents: Wei q h t % Water 86.50 Ammonia, 29% 3.00 0.50 Na4EDTA Ethylene G l y c o l Monobutyl E t h e r 5.00 C a l s u d s 81 5.00 Comments a b o u t t h i s f o r m u l a : 1 . A f t e r a d d i t i o n o f E t h y l e n e G l y c o l Monobutyl E t h e r , t h e mixture i s cloudy. 2 . It becomes c l e a r w i t h t h e a d d i t i o n o f C a l s u d s 8 1 . F o r m u l a t i o n HSC-008-01

P i n e Cleaner Inqredi ents : Pine O i l IPA Calamide CWT Cal o x y l a t e N-9 C a l s o f t LAS-99 Water Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . Use a t 1-2 o z p e r g a l l o n . F o r m u l a t i o n HSC-004-01 Pine

Cleaner

Ingredients: Pine O i l C a l s u d s CD-6 C a l o x y l a t e N-9 IPA Water Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HSC-007-01 ~~~~~~~

Weight% 20.00 10.00 9.00 5.00 2.00 54.00

P i l o t Chemical Co. : Suggested F o r m u l a t i o n s

Weight% 15.00 10.00 8.00 10.00 57.00

69

70

Advanced Cleatiing Product Formulations

H a r d S u r f a c e Cleanerc Ingredients: Water Sodi um M e t a s i 1 i c a t e Na4EDTA Dowanol PnB P i l o t SXS-40 C a l o x y l a t e N-9 P i n e 01 1 Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d F o r m u l a t i o n HSC-001-01 Hard-Surface-C1

weight% 75.25 2.00 2.00 6.00 9.00 5.50 0.25

@anex

Ingredi ents : Water Sodi um M e t a s i 1 i c a t e Na4EDTA P i l o t SXS-40 Cal imu1 se PRS Dowanol PnB Cal o x y l a t e N-9 Comments s b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HSC-002-01

Wi q h t 9 6 74.50 2.00 2.00 7.00 3.00 5.00 6.50

H a r d S u r f a c e Cle&ne_r

Ingredisnts : Water Sodi um M e t a s i 1 i c a t e Na4EDTA P i l o t SXS-40 Calamide CWT Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . Use 1 - 4 o z p e r g a l l o n . F o r m u l a t i o n HSC-005-01

Weisht_"L. 79.30

5.20 2.50 5.00 8.00

Hardsu.!-33Cs~_ec1eaner Irns r e d i en t-s 1 Water Sodi um C i t r a t e Soda Ash Ammonia, 29% P i l o t SXS-40 Calamide CWT Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . Use 2-4 o z p e r g a l l o n . F o r m u l a t i o n HSC-006-01 SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s

We i_pht % 58.50 15.00 5.00 3.50 8.00 1O.DO

Hand Sqface Cleaners

71

Hard Surface Cleaner w/Amphoteric

Wt%

Inqredi ents: Water, D . I . Sodi um C a r b o n a t e R e w o t e r i c AM KSF-40 Dowanol DPM Versene 100 W i t c o n a t e SXS (40%)

75.0 4.0 10.0 5.0 2.0 4.0

Blending Procedure: Add i n g r e d i e n t s in o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . T y p i c a l P r o p e r t i es : V i s c o s i t y , cps: 4 S o l i d s : 10.2% pH: 10.8 F o r m u l a 507 H a r d S u r f a c e C l e a n e r C o n c e n t r a t e w/d'Limonene Ingredients: Phase I: Isopropanol Oleic A c i d .Varoni c K205 d ' L i monene

10.0 8.8 5.0 12.0

Phase 11: Water, D . I . P o t a s s i u m H y d r o x i d e (87%)

62.2 2.0

B1 e n d i ng P r o c e d u r e : Combine Phase

I

i n g r e d i e n t s and m i x t h o r o u g h l y .

Combine Phase

I 1 i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o Phase 11. T y p i c a l P r o p e r t i es : V i s c o s i t y , cps: 75 S o l i d s : 13.8% pH: 1 0 . 2 F o r m u l a 508

SOURCE: W i t c o C o r p . :

Suggested F o r m u l a t i o n s

72

Advanced Cleaning Product Formulations

Hard Surface Cleaner Concentrate IPhosphate. L i q u i d ) S o i l - F o o d g r e a s e , o i l and p r o t e i n , p e t r o l e u m g r e a s e and o i l Surface-Metal, ceramic, polymeric, g l a s s A p p l i c a t i o n Method-Wipe, mop o r s p r a y ( d i l u t e d ) M a n u f a c t u r e - M i x t a n k w i t h p r o p e l 1e r s t i r r e r ComDosition A: Water TSP S t a r s o Sodium S i l i c a t e Sodium H y d r o x i d e (50%) *Phosphate E s t e r * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 6 Moles EO) * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 2 . 5 Moles EO)

71.4 1.6 14.0 4.0 5.0 2.8 1 .2

Composition B: Water TSP S t a r s o Sodi um S i 1 ic a t e Sodium H y d r o x i d e (50%) *Phosphate E s t e r * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cl1; 6 M o l e s EO) * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles EO)

65.4 1.6 18.0 5.0 6.0 2.8 1.2

Use D i l u t i o n : 3-6% bw ( 4 - 8

* ** ***

Wt%

oz/gallon)

Rhone-Poulenc Rhodafac RE-600 Rhone-Poulenc R h o d a s u r f 91-6 Rhone-Poulenc R h o d a s u r f A-24 Hard S u r f a c e Spray Cleaner LPhosphate, L i q u i d ) S o i l - F o o d g r e a s e , o i l and p r o t e i n , p e t r o l e u m g r e a s e and o i l Surface-Metal, ceramic, polymeric, g l a s s A p p l i c a t i o n Method-Spray and w i p e Manufacture-Mix tank w i t h p r o p e l l e r s t i r r e r

Composi t i on : Water TKPP N C l e a r Sodium S i l i c a t e Sodium H y d r o x i d e (50%) * D i p r o p y l ene G1 y c o l Monomethyl E t h e r * * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 12-13 M o l e s Use: As i s ,

*

**

spray

Dow Chemical Rhone-Poulenc

SOURCE: PQ C o r p . :

I g e p a l CA-720 Detergent F o r m u l a t i o n Guide

Wt% ~-

EO

90.00 2.00 1.88 0.12 5.00 1 .00

Hand Surface Cleaners

73

Hard S u r f a c e C l e a n e r C o n c e n t r a t e w/Dipentene

Wt%

I nnredi e n t s : Phase I : Isopropanol Oleic Acid V a r o n i c K205 D i pentene

10.0 8.8 5.0 12.0

Phase 11: Water, D . I . Potassium H y d r o x i d e (87%)

62.2 2.0

B l e n d i n g Procedure: Combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . Combine Phase I 1 i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o Phase XI ~

Typical Properties: V i s c o s i t y , cps: 50 Solids: 13.8% pH: 10.1 Formula 509 A 1 k a l ine Hard S u r f a c e C l e a n e r I n q r e d ients: Water, D . I . Sodi um M e t a s i 1i c a t e Varami de A-83 \Mi t c o n a t e 3 0 D S W i t c o n a t e SXS L i q u i d

Wt% 62.7 3.0 5.0 6.8 2.5

B l e n d i n g Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . Typical Properties: V i s c o s i t y , c p s : 32 S o l i d s : 1 1 .O% pH: 12.0 Formula 515

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s

74

Advanced Cleaning Product Formulations

L i q u i d A b r a s i v e C 1e a n s e r

Wt%

Inqredients: Water, t a p C a l c i u m c a r b o n a t e , 100 mesh Sodium t a l l o w soap, f l a k e s A l p h a - S t e p MC-48 N i n o l 11-CM Sodi um C h l o r i d e

48.5 42.5 2.0 2.5 2.0 2.5

M i x i ng P r o c e d u r e : Charge warm w a t e r and add c a l c i u m c a r b o n a t e w h i l e m i x i n g . Add soap and m i x u n t i l d i s p e r s e d . Add MC-48 and 11-CM and m i x u n t i l homogeneous. Add sodium c h l o r i d e t o t h i c k e n . P r o p e r t i es : Appearance: Opaque, o f f - w h i t e creamy l i q u i d pH, a s i s : 9 . 3 V i s c o s i t y @ 25 deg C . : t h i x o t r o p i c s p i n d l e #3, 6 rpm, B r o o k f i e l d : 4520 c p s s p i n d l e #3, 12 rpm, B r o o k f i e l d : 3840 c p s s p i n d l e # 3 , 30 rpm, B r o o k f i e l d : 3060 c p s S o l i d s , % : 50 D e n s i t y , l b s / g a l : 11.69 S t o r a g e a t a m b i e n t temp, 1 week: N o s e p a r a t i o n Use I n s t r u c t i o n s :

Use as i s

Performance: C l e a n s g r e a s e p e n c i l , s c u f f marks and l i p s t i c k f r o m v i n y l t i l e s s i m i 1 a r t o commerci a1 p r o d u c t s .

SOURCE: S t e p a n C o . :

F o r m u l a t i o n No. 3 1 4 T i l e and Sani t a r v C l e a n e r s

Inqredi ents: Z u s o l a t 1008/85 Water Xanthan Gum C i t r i c acid Inqredients: Amphotensid B 4 Water Citric acid

SOURCE: Zschimmer & Schwarz GmbH & Co.: CT 02-10-03 and CT 02-10-04

Wt% 5.0 79.6 0.4 15.0

Wt% 30.0 60.0 10.0 Suggested F o r m u l a t i o n s

Hand Sutface Cleaners

75

L i q u i d Hard Surface Cleaner

Wt%*

Ingredients: A : Van Gel ES, Magnesium Aluminum S i l i c a t e Rhodopol 23, Xanthan Gum D e i o n i z e d Water

4.00 0.50 68.50

0 : Cocamide DEA (Monamid 150-ADD) A1 k o x y l a t e d F a t t y A l c o h o l (P1 u r a f a c C-17) T e t r a p o t a s s i um P y r o p h o s p h a t e P o t a s s i u m Phosphate T r i b a s i c D e i o n i z e d Water

0.50 2.50 1.25 0.75 21 .oo

1 .oo

C: Ammonium H y d r o x i d e , 28%

Procedure: 1 . D r y b l e n d t h e Van Gel ES and Rhodopol 23 and s l o w l y add them t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 r p m . C o n t i n u e m i x i n g f o r 40 m i n u t e s . 2. Combine t h e P a r t B i n g r e d i e n t s w i t h s l o w s t i r r i n g . 3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o produce a s l i g h t v o r t e x . 4 . Add P a r t I3 t o P a r t A, m i x f o r 5 m i n u t e s and t h e n add P a r t C and m i x f o r 5 m i n u t e s . F o r m u l a t i o n No. 303 Hard Surface C l e a n e r - A l l

Purpose

Ingredients: A : Veegum, Magnesi um A1 umi num S i 1 i c a t e Rhodopol 23, Xanthan Gum D e i o n i z e d Water

W t .%* 1.20 0.40 48.40

B : Calcium Carbonate

40.00

C:

C12-CI3 L i n e a r P r i m a r y A l c o h o l E t h o x y l a t e (Neodol 23-6.5) Cocamide DEA ( N i n o l 40-CO) P r e s e r v a t i v e , Dye, F r a g r a n c e

9.00 1 .oo q.s.

Procedure: 1 . D r y b l e n d t h e Veegum and Rhodopol 23 and s l o w l y add t h e b l e n d t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 rpm. C o n t i n u e m i x i n g f o r 20 m i n u t e s . 2 . Add P a r t B and m i x f o r 10 m i n u t e s . 3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o produce a s l i g h t v o r t e x . 4 . Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g f o r 5 m i n u t e s a f t e r each a d d i t i o n . F o r m u l a t i o n f r o m S h e l l Chemical Co. AS r e c e i v e d b a s i s

SOURCE:

R . T . V a n d e r b i l t Co., I n c . : Van Gel and Veegum i n H a r d S u r f a c e C l e a n e r s and P o l i s h e s : Suggested F o r m u l a t i o n s

76

Advanced Cleaning Product Formulations

M o l d and M i l d e w Remover Carbopol r e s i n s a r e used t o v e r t i c a l c l i n g when s p r a y e d on "no-drip" a c t i o n w i l l increase g e n t on t h e s o i l e d s u r f a c e and

reduce s p l a s h i n g and t o p r o v i d e a v e r t i c a l surface. This the contact time o f the deterenhance consumer c o n v e n i e n c e .

\Rlt%

I n p r e d ie n t : D I water Carbopol 672 ( 1 ) Sodium h y d r o x i d e (50%) Sodium m e t a s i l i c a t e , p e n t a h y d r a t e P r i m a r y a l k a n e s u l f o n a t e (40%) ( 2 ) Sodium h y p o c h l o r i t e (15.00%) B r o o k f ie l d v i s c o s i t y (RVT-PO P r o d u c t p H : 12-13 P r o d u c t c l a r i t y : Opaque

( 1 ) BFGoodrich ( 2 ) Stepan C o . :

84.50 1 .00 2.00 0.50 5.00

7.00

rpm) : 120 cps

B i o - T e r g e PAS-8S

Procedure : 1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i ng and b l e n d i ng o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . Under moderate a g i t a t i o n , add t h e sodium h y d r o x i d e and t h e metasilicate. 3. Add t h e a l k a n e s u l f o n a t e . 4 . Under l o w a g i t a t i o n , add t h e sodium h y p o c h l o r i t e b l e a c h . 5 . Add c o l o r and f r a g r a n c e , as d e s i r e d . Total Actives: Primary alkane sulfonate: Available chlorine:

SOURCE:

2.0 1.0

BFGoodrich S p e c i a l t y Chemicals:

DET-320

Laundry Products

77

78

Advanced Cleaning Product Formulations

Detergent f o r Fine Fabrics-1 Powder Inpredi ents: Genapol OA-080 DDBS-Na* Thermphos NW T a l l o w soap, Powder Sodi um d i s i 1 i c a t e S o k a l a n CP 5 S o k a l a n HP 22 A q u a m o l l i n BC Powder Perfume Sodi um s u l p h a t e

Q

3.0 15.0 25.0 1 .O-3.0 3.0

1 .o 1 .o 0.5 q.s.

ad 1 0 0 . 0

Manufacturing: To b e p r e p a r e d by s p r a y m i x p r o c e s s . T h e r e f o r e DDBS-Na must b e employed i n f o r m o f a s p r a y d r i e d powder. DDBS-Na p a s t e i s not suitable. *DDBS=Dodecyl Benzene S u l p h o n a t e Detergent f o r Fine Fabrics-2 Powder Inqredients: Genapol OA-080 DDBS-Na* Z e o l i t h A (Wessalith T a l l o w soap, Powder Sodi um d i s i 1 ic a t e S o k a l a n CP 5 S o k a l a n HP 22 Aquamoll i n BC Powder Perfume Sodium s u l p h a t e

Wt% 3.0 15.0 20.0-25.0 1.0- 3.0 3.0 2.0- 3.0 1 .o 0.5 q.s. ad 100.0

Manufacturing: To b e p r e p a r e d b y s p r a y m i x p r o c e s s . T h e r e f o r e DDBS-Na must b e employed i n f o r m o f a s p r a y d r i e d powder. DDBS-Na p a s t e i s not suitable. *DDBS=Dodecyl Benzene S u l f o n a t e

SOURCE: H o e c h s t A k t i e n g e s e l l s c h a f t :

Suggested F o r m u l a t i o n s

Laundry Products

Heavy D u t y L a u n d r y Ingredients: Wei q h t % Water 28.90 Sodi um H y d r o x i d e , 50% 6.60 Calamide C 7.00 P i l o t SXS-40 12.50 40.00 Cal s o f t LAS-99 Cal o x y l a t e N - 9 5.00 Comments a b o u t t h i s f o r m u l a : Add C a l o x y l a t e N - 9 a f t e r 50% o f LAS-99 has been n e u t r a l i z e d . F o r m u l a t i o n HDL-001-01 Heavy D u t y L a u n d r y Inqredients: Water P i l o t SXS-40 Calamide CWT Sodium S i l i c a t e ( S o l i d ) C a l s o f t L-60 EDTA (Ethylenediaminetetraacetic A c i d ) Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HDL-006-01

Wei o h t % 42.50 22.50 4.00 3.01 18.00 2.50

Heavv D u t y L a u n d r y

I n q r e d ie n t s : Water C a l f a x DB-45 C a l o x y l a t e N-9 P r o p y l ene G1 y c o l TKPP ( T e t r a P o t a s s i um Pyrophosphate) Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HDL-007-01

Weight% 78.50 7.00 7.00 2.50 5.00

Heavv D u t y L a u n d r y Inqredients: Water TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) Sodium S i l i c a t e ( S o l i d ) C a l s o f t L-60 P i l o t SXS-40 Calamide CWT Comments a b o u t t h i s f o r m u l a : May need t o be h e a t e d t o s o l u b i l i z e t h e s u r f a c t a n t . F o r m u l a t i o n HDL-008-01

SOURCE:

P i 1o t Chemical

Co. : Suggested Formul a t i ons

Wei q h t % 42.00 15.00 10.00 18.00 10.00 5.00

79

80

Advanced Cleaning Product Formulations

I

& I L i q u i d Laundrv Detergent w i t h Enzyme & O p t i c a l

Components: Water T r i e t h a n o l ami ne 85% D i e t h y l ene G1 y c o l B u r c o l 117 B u r c o l LAF-6 Burcowi t e BBH-PO B u r c o t a s e SL-160

% by Weisht

50.00 3.25 20.00 10.00 10.00 1.25 0.50

B u r c o LAF-6 i s used t o c o n t r o l foam as w e l l a s t o p r o v i d e w e t t i n g and d e t e r g e n c y . Procedure: Charge 1 / 2 o f w a t e r I3 120F. Add 1 , 2 , 3 , & 4 and b l e n d . Add r e m a i n i n g w a t e r . Cool t o 1OOF. Add 5 and 6 . B l e n d u n t i l u n i f o r m . 1% pH: 9 . 5 % s o l i d s : 26 Lbs/gal : 8.66 S u r f a c t a n t R i c h D e t e r g e n t f o r N u r s i n o Homes Ingredients: Water TKPP Sodium M e t a s i l i c a t e P e n t a h y d r a t e B u r c o t e r g e DG-40 B u r c o NPS-876 SXS-40%

% bv W e i q h t 30 5 5

40 10 10

6-8 ounces p e r 100 pounds o f l a u n d r y . Heavy s o i l s may r e q u i r e s l i g h t l y higher levels. SOURCE: B u r l i n g t o n Chemical Co.:

Suggested F o r m u l a t i o n s

Powder f o r A u t o m a t i c D i s h w a s h i n n M a c h i n e s Ingredients: A Genapol 2908 B Sodium m e t a s i 1 i c a t e x 5H20 C Sodium c a r b o n a t e Sodi um d i c h l o r o i s o c y a n u r a t e Thermphos NW

YO

by W e i q h t

1 .oo

52.00 10.00 2.00 35.00

Manufacturing: I Spray A on B . I 1 One a f t e r a n o t h e r , t h e components o f C a r e added t o 1 A p p l i c a t i o n : 1-29 d e t e r g e n t / L d i s h w a s h i n g l i q u o r SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n

Laundry Products

81

IndustriaT Heavy Duty Laundry L i q u i d Carbopol ETD 2691 is t o p r o v i d e p r o d u c t phase s t a b i l i z a t i o n i n t h i s high a l k a l i n i t y i n d u s t r i a l strength cleaner.

Wt%

I nsredient : D I water

49.00 0.50 18.00 5.50 2.00 5.00 20.00

Carbopol ETD 2691 ( 1 ) 612-15 l i n e a r a l c o h o l , 7 moles EO ( 2 ) Sodium a l k y l b e n z e n e s u l f o n a t e (60%) ( 3 ) Potassium h y d r o x i d e (45%) Sodium m e t a s i l i c a t e , anhydrous T e t r a p o t a s s i u m pyrophosphate P h y s i c a l Pi-opert ie s : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 900 P r o d u c t pH: 14 P r o d u c t C l a r i t y : Opaque

Raw M a t e r i a l S u p p l i e r s : ( 1 ) BFGoodrich ( 2 ) S h e l l Chemical C o . : Neodol 25-7 ( 3 ) Stepan Co.: B i o s o f t D-62

PP.0cedure: I . Use a b i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an

2. 3. 4.

5.

i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s . Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 rpm). A l l o w t o mix u n t i l homogeneous and f r e e o f polymer lumps. W i t h s l o w m i x i n g , add i n t h e a l c o h o l e t h o x y l a t e and a l k y l benzene s u l f o n a t e s u r f a c t a n t s . C o n t i n u e a g i t a t i n g and add t h e p o t a s s i u m h y d r o x i d e and metas i li c a t e . Add i n t h e pyrophosphate w i t h minimal a g i t a t i o n t o a v o i d a i r entrapment. Add dyes and f r a g r a n c e , as d e s i r e d .

Total Wcti ves : Sodi um a1 k y l benzene sul f o n a t e : C12-15 l i n e a r a l c o h o l , 7 moles EO: T e t r a p o t a s s i u m pyrophosphate:

SOURCE:

3.30 18.00 20.00

BFGoodrich S p e c i a l t y Chemicals:

DET-201

82

Advanced Cleaning Product Formulatioris

I n d u s t r i a l Laundry D e t e r a e n t s H i g h C a u s t i c Formula% bv Weiaht 15.0 10.0 5.0 5.0 65.0

Components: Burco NPS-816 Burcosperse LP B u r c o l i t e BSGH-255 Dequest 2000 50% NaOH

Procedure: B l e n d a l l components e x c e p t 50% NaOH. S l o w l y add NaOH w i t h a g i t a t i o n . Keep t e m p e r a t u r e below 1 6 0 F d u r i n g t h e e n t i r e agitation. Mixed B u i l d e r F o r m u l a t i o n % by Weight

Components: Water 45% KOH B u r c o s p e r s e LP TKPP Burco NPS-816 S t a r Grade Sodium S i l i c a t e

31.5 23.5 10.0 10.0 15.0 10.0

Procedure: D i s s o l v e KOH i n w a t e r . S l o w l y add Burcosperse LP w h i l e a g i t a t i n g . Keep t e m p e r a t u r e below 160F. Add TKPP and s t i r u n t i l d i s s o l v e d . Add Burco NPS-816, t h e n S t a r Grade Sodium S i l i c a t e and b l e n d u n t i l u n i f o r m . Use l e v e l s a r e 6-12 ounces p e r 100 pounds, l o a d i n g , temperature, e t c .

SOURCE: B u r l i n g t o n Chemical Co.,

depending on s o i l

I n c . : Suggested F o r m u l a t i o n s

Washi np P a s t e w i t h 81 e a c h i n g A g e n t Ingredients: Water Sodium t r i p o l y p h o s p h a t e Sodium d i t h i o n i t Xanthan Gum Whi t e - s p i r i t Lumorol 4154 Zusol a t 1005/85

SOURCE:

Zschimmer & Schwarz GmbH & Co.:

% b y Weiaht 39.0 3.0 12.0 2.0 10.0 30.0 5.0 F o r m u l a t i o n CT 07-06-01

Laundry Products

83

L a u n d r y Deteraent-Consumer (Liquid) S o i l - B o d y o i l and p e r s p i r a t i o n , body w a s t e . make-up, S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n Method-Household w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

food s o i l

Composition: Water Fluorescent Brightener C a r b o x y m e t h y l c e l l u l o s e (CMC) * A c r y s o l A S E - I 08 **Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 M o l e s €0 Potassium H y d r o x i d e (45%) ***Sodium C i t r a t e ( a n d / o r C i t r i c A c i d ) K a s i l #6 Potassium S i l i c a t e EDTA

Enzymes ( P r o t e a s e )

x(

** ***

Wt% 37.6 0.2 0.5 6.0 10.0 2.2 25.0 12.5 5.0 1.o

Rohm & Haas; o r Rhone-Poulenc C o l l o i d 225/35 P o l y a c r y l a t e (40%) Rhone-Poul enc I g e p a l CO-630 A d j u s t p H w i t h c i t r i c a c i d t o m a i n t a i n pH f o r e f f e c t i v e enzyme p e r f o r m a n c e ( i . e . 8 . 5 - 9 . 5 p H ) . L a u n d r y Detergent-Consumer I Z e o l i t e B u i l t , Z e r o Phosphate, L i q u i d ) S o i l - B o d y o i l and p e r s p i r a t i o n , body w a s t e , f o o d s o i l , S u r f a c e - C o t t o n and c o t t o n - p o l y e s t e r A p p l i c a t i o n Method-Household w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Composition : Water C a r b o p o l 674 D L i q u i d Sodium S i l i c a t e * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) Sodium C a r b o n a t e V a l f o r 100 Z e o l i t e A * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-.13, EO 6 . 5 M o l e s ) t:

**

Rohm & Haas S h e l l Chemical Neodol 23-6.5

SOURCE:

PQ C o r p . :

Detergent Formulary Guide

make-up

Wt% 52.6 0.5 8.1 0.9 9.1 24.5 4.3

84

Advanced Cleaning Product Formulations

Laundry Detergent-Consumer ( Z e r o Phosphate, Powder) S o i l - A c i d i c f o o d f a t , o i l grease, b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n - p o l y e s t e r A p p l i c a t i o n Method-Household Washing Machine Manufacture-Dry Blend/Agglomeration

Wt9/o

Composition: Sodi um Carbonate B r i t e s i l H20 Hydrous P o l y s i l i c a t e *Acusol 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) * * L i n e a r A 1 k y l benzene S u l f o n a t e (LAS) * * * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) V a l f o r 100 Z e o l i t e A Sodi um S u l f a t e O p t i c a l B r i g h t e n e r , Perfume Use L e v e l :

* **

***

30.0 10.0 2.0 10.0 5.0 30.0 12.5 0.5

1000 ppm d e t e r g e n t d e l i v e r e d t o wash ( 1 gram d e t e r g e n t / l i t e r o f water)

Rohm & Haas Stepan Nacconol 9OG (90% a c t i v e ; powder) Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7

Laundry Detergent-Consumer (Phosphate, Powder) S o i l - A c i d i c f o o d f a t and p r o t e i n , body p e r s p i r a t i o n , dirt Surface-Polyester, cotton/polyester, cotton A p p l i c a t i o n Method-Household washing machine Manufacture-Dry blend/agglomeration Composi t i on : B r i t e s i l H20 Hydrous P o l y s i l i c a t e *STPP *Sodium Carbonate Sodi um S u l f a t e * * L i n e a r A1 k y l benzene Sul f o n a t e (LAS) * * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 Moles EO; O p t i c a l B r i g h t e n e r , Perfume Use L e v e l :

* ** ***

C12-15)

g r a s s and

Q 10.0 30.0 30.0 14.5 10.0 5.0 0.5

1000 ppm d e t e r g e n t d e l i v e r e d t o wash ( 1 g r a m / l i t e r water)

FMC Stepan Nacconol 90G (90% a c t i v e ; powder) Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Co. Neodol 25-7

SOURCE: PQ C o r p . :

D e t e r g e n t F o r m u l a t i o n Guide

of

Laundry Products

85

Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l ( L i q u i d , Phosphate1 S o i l - A c i d i c f o o d f a t , o i l a n d g r e a s e ; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composition A : Water TKPP P o t a s s i urn H y d r o x i d e (45%) S t a r Sodium S i l i c a t e Sodium H y d r o x i d e (50%)

34.1 10.0 30.4 18.0 7.5

C o m p o s i t i o n B: Water TKPP P o t a s s i u m H y d r o x i d e (45%) S t a r Sodi um S i 1 i c a t e Sodium H y d r o x i d e (50%)

wts/, 25.6 10.0 30.4 24.0 10.0

0.25% by w e i g h t o r 1 l b p e r 100 l b s 1a u n d r y Medium t o Heavy S o i l : 0.25%-0.50% b y w e i g h t o r 1-2 l b s p e r 100 l b s l a u n d r y N o t e : Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s o f b u i l d e r t o 1 p a r t d e t e r g e n t .

Use D i l u t i o n :

Light Soil:

Laundry B r e a k - I n d u s t r i a l (Liquid)

& Institutional

S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composition: Water N C l e a r Sodium S i l i c a t e Sodium H y d r o x i d e (50%) Use D i l u t i o n :

Light Soil:

% 0-20 70-90 10-20

0.25% b y w e i g h t o r 1 l b p e r 100 l b s 1a u n d r y Medium/Heavy S o i l : 0.25%-0.50% b y w e i g h t o r 1-2 l b s p e r 100 l b s l a u n d r y Notes: Blend t h i s b u i l d e r s o l u t i o n t o 1.7-2.0 r a t i o Si02/Na20 b w f o r b e s t s t a b i l i t y and i n d u s t r i a l d e t e r g e n c y . D o r BJ-120 sodium s i l i c a t e s c a n a l s o b e used as b u i l d e r solutions without blending. Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r t o 1 p a r t d e t e r g e n t . SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n G u i d e

86

Advanced Cleaning Product Formulatiom

Laundry D e t e r s e n t - I n d u s t r i a l & I n s t i t u t i o n a l (NTA/Zeol it e , P o w d e d S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Dry blend/Agglomeration Composi t i on : M e t s o Beads 2048 Sodi um C a r b o n a t e NTA * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles V a l f o r 100 Z e o l i t e A

EO; C 1 2 - 1 5 )

25.0 38.0 15.0 12.0 10.0

Use L e v e l : L i g h t S o i l - O . 2 5 % b y w e i g h t o r 1 l b p e r 1 0 0 l b s 1a u n d r y Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s 1a u n d r y Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s 1a u n d r y N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y or f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .

*

Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7 L a u n d r y B r e a k - I n d u s t r i a1 & I n s t i t u t i o n a l ( Z e r o Phosphate, Powder) S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine M a n u f a c t u r e - U s e as r e c e i v e d

Wt46

Composi t i on : M e t s o Beads 2048 Use D i l u t i o n :

100.0

L i g h t S o i l - O . 2 5 % by w e i g h t o r 1 l b p e r 1 0 0 l b s 1a u n d r y Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s 1a u n d r y Heavy S o i l - O . 7 5 % by w e i g h t o r 3 l b s p e r 100 I b s 1a u n d r y

N o t e : Use i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) 2-4 p a r t s b w o f b u i l d e r w i t h 1 p a r t d e t e r g e n t .

SOURCE: PQ C o r p . :

D e t e r g e n t F o r m u l a t i o n Guide

at

Laundqi Products

87

Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l (Phosphate, Powder) S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry blend/Agglomeration WtO/o Composition: Metso Beads 2048 25.0 35.0 *Sodium C a r b o n a t e *STPP 30.0 10.0 * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 m o l e s EO; C12-15) Use L e v e l : L i g h t Soi 1-0.25% b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y Medium S o i l - O . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s 1a u n d r y Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s 1a u n d r y N o t e : Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspendi n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n c r e a s e t h e s u r f a c t a n t adosrbency o f d e t e r g e n t b l e n d . x< FMC Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7

**

Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l (Sodium Carbonate, Powder) S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry blend/Agglomeration Q Composi t i on : Metso Beads 2048 25.0 55.0 Sodium C a r b o n a t e Sodi um S u l f a t e 10.0 * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) 10.0 Use L e v e l : L i g h t Soi 1-0.25% b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s 1a u n d r y Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s 1a u n d r y N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d . 'k Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7 SQURCE:

PQ G o r p . : D e t e r g e n t F o r m u l a t i o n G u i d e

88

Advanced Cleaning Product Formulations

Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l (Phosphate. Powder, H i g h A l k a l i n i t y ) S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry b l end/Agglomeration Wt% Composition A : 60.0 Metso Beads 2048 Sodium H y d r o x i d e Beads 40.0 Composition 8: Wt% Metso Beads 2048 30.0 *STPP 20.0 *Sodium Carbonate 28.0 Carboxymethylcellulose 2.0 20.0 Sodium H y d r o x i d e Beads Use D i l u t i o n : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s 1aundry Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 1 0 0 I b s 1aundry Heavy S o i l - 0 . 7 5 % by w e i g h t o r 3 l b s p e r 1 0 0 lbs 1aundry Note: Use t h e s e a l k a l i b u i l d e r s i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r w i t h 1 p a r t detergent FMC

*

Laundrv B r e a k - I n d u s t r i a1 8, I n s t i t u t i o n a l ( Z e r o Phosphate Powder, H i ah A1 k a l in i t v ) S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry blend/Agglomeration Wt% Composi t i on A : Metso Beads 2048 60.0 Sodium H y d r o x i d e Beads 40.0 Composition 8: W S Metso Beads 2048 30.0 Sodi um Carbonate 28.0 Carboxymethylcel l u l o s e 2.0 20.0 Sodium H y d r o x i d e Beads V a l f o r 100 Z e o l i t e A 20.0 Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s l a u n d r y Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 I b s 1aundry Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 0 0 l b s 1aundry N o t e : Use t h e s e a l k a l i b u i l d e r s i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2 - 4 p a r t s bw o f b u i l d e r w t h 1 p a r t detergent SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide

Laundry Products

89

Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l (Reduced Phosphate, Powder) S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Dry blend/Agglomeration Composition: Wt% 25.0 M e t s o Beads 2048 35.0 *Sodium C a r b o n a t e 20.0 *STPP 10.0 % * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 m o l e s EO; C12-15) 10.0 V a l f o r 100 Z e o l i t e A Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 1 0 0 l b s l a u n d r y Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s 1a u n d r y Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s 1a u n d r y N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspendi n g / e m u l s i f y i ng power i s needed. B r i t e s i 1 H20 w i 11 a1 so i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d . 96 FMC dc* Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7 Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l (NTA, Powder) S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a1 washi ng machine Manufacture-Dry blend/Agglomeration Composi t i on : Wt% M e t s o Beads 2048 25.0 Sodium C a r b o n a t e 40.0 NTA 25.0 10.0 * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) Use L e v e l : L i g h t S o i l - 0 . 2 5 % b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s 1a u n d r y Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s 1a u n d r y N o t e : U s e B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l also i n crease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d . *Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7

SOURCE:

PQ C s r p . : D e t e r g e n t F o r m u l a t i o n G u i d e

90

Advanced Cleaning Product Formulations

Laundry D e t e r q e n t - I n d u s t r i a l B I n s t i t u t i o n a l (Sodium Carbonate w i t h F l o w A i d . Powder) S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r Appl ic a t ion Method-I n d u s t r ia1 wash ing mach i ne Manufacture-Dry blend/agglomeration Composi t ion : Metso Beads 2048 Sodium Carbonate Sodi um S u l f a t e * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C 1 2 - 1 5 ) V a l f o r 100 Z e o l i t e A Use L e v e l :

Wt%

20.0 55.0 10.0 10.0 5.0

L i g h t S o i l : 0.25% by w e i g h t o r 1 l b p e r 1 0 0 l b s 1aundry Medium S o i l : 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s 1 aundry Heavy S o i l : 0.75% b y w e i g h t o r 3 l b s p e r 100 l b s 1 aundry

Note: Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more susp e n d i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .

*

Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7 Laundry D e t e r g a n t - I n d u s t r i a l & I n s t i t u t i o n a l IPhosphate, S o l i d Block) S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a1 washing machine Manufacture-Sol i d b l o c k

Composi t i on : Metso Beads 2048 NaOH ( 5 0 % S o l u t i o n )

*STPP *Sodium Carbonate * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 Moles EO; C12-15)

* **

FMC Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7

SOURCE:

PQ C o r p . :

D e t e r g e n t F o r m u l a t i o n Guide

Wt% 25.0 25.0 35.0 12.0

3.0

Laundry Products

91

Laundry D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l (Zero Phosphate, Powder) S o i l - A c i d i c f o o d f a t , o i l g r e a s e , b l o o d , sebum and body w a s t e S u r f a c e - C o t t o n and c o t t o n p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Dry Blend/Agglomeration

Wt% Composition : Sodi um C a r b o n a t e 35.0 15.0 * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles € 0 ; C12-15) V a l f o r 100 Z e o l i t e A 25.0 M e t s o Beads 2048 25.0 Use L e v e l : L i g h t S o i l - 0 . 2 5 % b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y Medium S o i l - O . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s 1a u n d r y Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s 1a u n d r y N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a1 k a l in i t y is d e s i r e d and more s u s p e n d i n g / e m u l s i f y i n g powder i s needed. B r i t e s i l H20 w i l l a l s o i n crease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t blend. *Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7 L a u n d r y D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l ( Z e r o Phosphate, Powder) S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine M a n u f a c t u r e - D r y B1 end/Aggl o m e r a t i on Composi t ion : Wt% Sodium C a r b o n a t e 44.5 * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) 18.0 30.0 V a l f o r 100 Z e o l i t e A * * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) 2.5 5.0 M e t s o Beads 2048 Use L e v e l : L i g h t S o i 1-0.25% b y w e i g h t o r 1 l b p e r 1 0 0 l b s l a u n d r y Medium S o i l - O . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s 1a u n d r y Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s 1a u n d r y N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n crease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d . Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7 Rohm & Haas

**

SOURCE:

PQ Corp. : D e t e r g e n t F o r m u l a t i o n G u i d e

92

Advanced Cleaning Product Formulations

Laundry D e t e r q e n t - I n d u s t r i a l & I n s t i t u t i o n a l [ P h o s p h a t e B u i 1t , L i q u i d ) S o i l - B o d y o i l and p e r s p i r a t i o n , body waste, make-up, S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composition A: Water TKPP P o t a s s i u m H y d r o x i d e (45%) S t a r s o Sodium S i l i c a t e Sodi um H v d r o x i d e (,5 0 %.) *PhosphaGe E s t e r **Liquid Nonionic Surfactant

food s o i l

Wt%

(C12-C15,

7-9 M o l e s € 0 )

54.5 4.6 13.7 15.0 4.2 5.0 3.0

C o m p o s i t i o n B: Wt% Water 59.1 P o t a s s i u m H y d r o x i d e (45%) 13.7 S t a r s o Sodi um S i 1 i c a t e 15.0 Sodium H y d r o x i d e ( 5 0 % ) 4.2 *Phosphate E s t e r 5.0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-C15, 9 Moles EO) 3.0 Use D i l u t i o n : 0 . 2 5 % - 0 . 5 0 % b y w e i g h t or 1-2 l b s p e r 1 0 0 l b s 1a u n d r y Rhone-Poulenc Rhodafac RE-610 Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9

* **

Laundry D e t e r g e n t - I n d u s t r i a l ( L i quid)

& Institutional

Soi 1-Body o i 1 and p e r s p i r a t i o n , body w a s t e , make-up, S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

food soi 1

wts/, Composition: 28.7 Water 0.1 F1 u o r e s c e n t B r i g h t e n e r C a r b o x y m e t h y l c e l l u l o s e (CMC) 0.5 * A c r y s o l ASE-108 ( A c r y l i c P o l y m e r ) 6.0 **Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-1 0 M o l e s EO 10.0 2.2 P o t a s s i um H y d r o x i d e (45%) TKPP (60%) 40.0 K a s i 1 #6 P o t a s s i um S i 1 i c a t e 12.5 Use D i l u t i i o n : 0.25%-0.50% by w e i g h t or 1-2 l b s p e r 1 0 0 I b s 1a u n d r y Rohm & Haas; or Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e (40%) **Rhone-Poulenc I g e p a l CO-630

*

SOURCE: PQ C o r p . :

Detergent Formulary Guide

Laundry Products

Laundry B u i l d e r - I n d u s t r i a l (L iquid)

93

& Institutional

S o i l - A c i d i c f o o d , f a t , o i l and grease; b l o o d , sebum and body waste S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r

Wt%

Composition A : P o t a s s i u m H y d r o x i d e (45%) iU C l e a r o r E Sodium S i l i c a t e

35-45 55-65

C o m p o s i t i o n B: Water Potassium Hydroxide ( S o l i d ) N C l e a r or E Sodium S i l i c a t e

11.0 37.0 52.0

Composition C: Water Potassium Hydroxide ( S o l i d ) N C l e a r o r E Sodium S i l i c a t e Sodium H y d r o x i d e ( S o l i d ) Use D i l u t i o n :

Wt%

Wt% 6.0 28.0 52.0 14.0

0.25% by w e i g h t o r 1 l b p e r 100 l b s 1a u n d r y Medium t o Heavy S o i l : 0.25%-0.50% b y w e i g h t o r 1-2 l b s p e r 100 l b s l a u n d r y Light Soil:

N o t e : Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r t o 1 p a r t d e t e r g e n t Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l ( Z e o l i t e B u i l t , Z e r o Phosphate, L i q u i d ) S o i l - B o d y o i l and p e r s p i r a t i o n , body waste, f o o d s o i l , S u r f a c e - C o t t o n and. c o t t o n - p o l y e s t e r a c h i ne A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing Manufacture-Mix t a n k w i t h p r o p e l l e r s t r r e r Composition: Water C a r b o p o l 674 Metso Beads 2048 *Acusol 445N Sodi um P o l y a c r y a t e (45% s o l d s ) Sodium C a r b o n a t e V a l f o r 100 Z e o l i t e A * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-13; EO 6 . 5 M o l e s ) 8

**

Rohm 8: Haas S h e l l Chemical Neodol 2 3 - 6 . 5

SOURCE:

PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide

make-up

WtO/o 57.06 0.5 2.7 1.04 9.1 24.5 4.3

94

Advanced Cleaning Product Formulations

Laundry P r e s o o t t e r S p r a y a b l e Gel Carbopol ETD 2623 i s used i n t h i s f o r m u l a t i o n t o c o s t e f f e c t i v e l y t h i c k e n t h e s u r f a c t a n t system i n t o a g e l f o r m - which can be a p p l i e d t o t h e f a b r i c by b r u s h o r sprayed on due to C a r b o p a l ' s shear t h i n n i n g n a t u r e . Inaredi ent: D I water Carbopol ETD 2623 ( 1 ) C12-15 l i n e a r a l c o h o l , 3 moles €0 ( 2 ) C12-13 l i n e a r a l c o h o l , 6 . 5 males €0 ( 3 ) EDTA ( t e t r a sodium s a l t ) Sodium h y d r o x i d e (18%)

83.75 0.20 10.00 5.00 0.50 0.55

B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 8,300 cps P r o d u c t pH: 7.0-8.0 P r o d u c t c l a r i t y : Opaque ( 1 ) BFGoodrich ( 2 ) S h e l l Chemical Co.: ( 3 ) S h e l l Chemical C o . :

Neodol 25-3 Neodol 23-6.5

Procedure: 1 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i ng and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . Add i n b o t h o f t h e a l c o h o l e t h o x y l a t e s u r f a c t a n t s . M i x u n t i l homogeneous. 3. Add i n t h e EDTA. 4 . Add i n t h e sodium h y d r o x i d e u n t i l t h e pH i s a t t a i n e d . 5 . Add c o l o r and f r a g r a n c e , as d e s i r e d . Total Actives: C12-15 l i n e a r a l c o h o l , 3 moles EO ( 2 ) : C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO ( 3 ) :

SOURCE:

10.0 5.0

BFGoodrich S p e c i a l t y Chemicals: DET-224

Laundry Products

95

Laundry Presootter Sorayable L i q u i d

Carbopol ETD 2 6 2 3 i s used i n t h i s f o r m u l a t i o n t o s l i g h t l y t h i c k e n t h e s u r f a c t a n t system and e n a b l e t h e p r o d u c t t o s t a y i n c o n t a c t w i t h t h e s o i l l o n g e r b y r e d u c i n g seepage t h r o u g h t h e fabric.

Wt%

I n s r e d ie n t :

84.30 0.05 10.00 5.00 0.50 0.15

D I water

Carbopol ETO 2623 ( 1 ) C12-15 l i n e a r a l c o h o l , 3 moles €0 ( 2 ) C12-13 l i n e a r a l c o h o l , 6 . 5 moles €0 ( 3 ) EOTA ( t e t r a sodium s a l t ) Sodi um h y d r o x i d e (18%) B r o o k f i e l d v i s c o s i t y (RVT-20 P r o d u c t pH: 7 . 0 - 8 . 0 P r o d u c t c l a r i t y : Opaque

rpm) : 2 5 0 cps

( 1 ) BFGoodri ch ( 2 ) S h e l l Chemical Co.: Neodol 2 5 - 3 ( 3 ) S h e l l Chemical Co.: Neodol 2 3 - 6 . 5

Procedure: I . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 1 5 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-

eous. Add i n b o t h o f t h e a l c o h o l e t h o x y l a t e s u r f a c t a n t s . Mix u n t i l homogeneous. 3 . Add i n t h e EDTA. 4 . Add i n t h e sodium h y d r o x i d e u n t i l t h e pH i s a t t a i n e d . 5 . Add c o l o r s o l u t i o n and f r a g r a n c e , as d e s i r e d . 2.

Total Actives: C12-15 l i n e a r a l c o h o l , C12-13 l i n e a r a l c o h o l ,

SOURCE:

3 moles EO: 6 . 5 moles EO:

BFGoodrich S p e c i a l t y Chemicals:

10.0 5.0

DET-220

96

Advanced Cleaning Product Formulations

L i g h t Duty L i q u i d Detergent wej-ghs Ingredients: 48.45 Water 7.50 P i l o t SXS-40 30.00 C a l s o f t L-60 5.00 Calamide C 8.30 C a l foam EA-603 0.60 C a l s o f t LAS-99 0.10 C i t r i c Acid 0.05 Sodium C i t r a t e Comments a b o u t t h i s f o r m u l a : 1 . pH=7.1 2 . Add C i t r i c A c i d i f pH i s h i g h o r Sodium C i t r a t e i f pH i s l o w . 3 . V i s c o s i t y s h o u l d b e 300 c P s . F o r m u l a t i o n LDL-001-01

L i s h t Duty Liquid Detergent Ingredients: Water C a l s o f t L-60 P1 l o t s x s - 4 0 Calamide C C a l f o a m EA-603 C a l s o f t LAS-99 Opaci f i e r Sod1 um C i t r a t e Comments a b o u t t h i s f o r m u l a : 1 . Add e i t h e r C i t r i c A c i d o r C a l s o f t LAS-99

Weight% 22.31 39.70 22.10 7.06 7.35 0.56 0.88 0.04 t o a d j u s t pH t o

7.0-7.2. 2 . S o l i d s 45%. 3 . S u b s t i t u t i n g C a l s o f t L-40 p r o d u c t s o l i d s t o 42%. F o r m u l a t i o n LDL-002-01

for

C a l s o f t L-60 w i l l

lower

L i g h t Duty L i q u i d Detergent Weight% Ingredients: 18.80 Water 70.00 Calsuds A 10.00 C a l foam ES-303 0.10 Perfume 0.10 K a t h o n CG 1.oo Opaci f ie r Comments a b o u t t h i s f o r m u l a : 1 . I f o p a c i f i e r i s t o be added, w i t h h o l d 5% o f t h e w a t e r 2 . Add t h e o p a c i f i e r t o t h e w a t e r p r i o r t o a d d i n g t o t h e detergent. F o r m u l a t i o n LDL-004-01

SOURCE:

P i l o t Chemical C o . : Suggested F o r m u l a t i o n s

Laundry Products

L i g h t -Duty L i q u i d Detergent Weight% 50.20 25.00 6.80 10.00

Ingredi ents : Water C a l s u d s CD-6 P i l o t SXS-40 C a l foam EA-603 Cal s o f t LAS-99

6.00

Comments a b o u t t h i s f o r m u l a : 1 . I n g r e d i e n t s s h o u l d be added i n t h e o r d e r l i s t e d t o a i d i n blending. 2. Sodium C i t r a t e / C i t r i c A c i d s h o u l d be added f o r pH a d j u s t m e n t t o 7+. 3 . S a l t ( S o d i u m o r Ammonium C h l o r i d e ) w i l l r a i s e t h e v i s c o s i t y . F o r m u l a t i o n LDL-006-01

L i g h t Duty L i q u i d Detergent Weight% 36.90 5.00 40.00 15.00 2.00 0.10 1 .00

In g r e d i e n t s : Water P i l o t SXS-40 C a l s o f t T-60 C a l foam ES-303 Calamide C P r e s e r v a t iv e S o d i um C h l o r i d e Comments a b o u t t h i s f o r m u l a : V i s c o s i t y 275 cPs. Sol i d ~ = 3 2 - 3 3 % pH=6.2 F o r m u l a t i o n LOI-007-01 L i g h t Duty L i q u i d Detergent Ingredients: Water P i l o t sxs-40 L i n e a r A1 coho1 E t h o x y l a t e NaOH, 5 0 % D i e t h a n o l am1 ne C a l s o f t LAS-99 Comments a b o u t t h i s f o r m u l a : S o l 1 ds=30% Good f o r g r e a s y a p p l i c a t i o n s . F o r m u l a t i o n IDL-006-01

SOURCE:

P i l o t C h e m i c a l Co : S u g g e s t e d F o r m u l a t i o n s

Weight% 65.16 6.29

2.52 2.81 0.43 19.77

97

98

Advanced Cleaning Product Formulations

L i g h t Duty L i q u i d Detergent Weight% 13.90 2.40 19.60 44.10 15.80 4.00 0.10 0.10

I n g r e d i ent-sl Water Ammonium C h l o r i d e P i l o t sxs-40 C a l s o f t L-60 Cal foam ES-303 Calamide C C i t r i c Acid P r e s e r v a t iv e

Comments a b o u t t h i s f o r m u l a : 1 . “ A s i s ” pH=8.0. 2 . Add C i t r i c A c i d i n p l a c e o f Sodium C i t r a t e t o l o w e r pH. F o r m u l a t i o n LDL-009-01 Ligh-t- D u t y L i q u i d D e t e r q e n t C a l s o f t LAS-99 Based Weight% 43.60 5.80 21.70 16.70 3.00 8.00 0.10 1 .oo 0.10

Ingredients: Water NaOH, 50% C a l s o f t LAS-99 P i l o t SXS-40 Cal foam ES-303 C a l o x y l a t e N-9 C i t r i c Acid Opaci f ie r Preservative Comments a b o u t t h i s f o r m u l a : A d d in g r e d i e n t s i n o r d e r 1 is t e d . F o r m u l a t i o n LDL-011-01 L i g h t D u t y L i q u i d Detergent C a l s o f t LAS-99 Based Ingredients: Water NaOH, 50% Cal s o f t LAS-99 Calamide C P i l o t SXS-40 Cal foam ES-303 C a l o x y l a t e N-9 C i t r i c Acid Opaci f ie r Comments a b o u t t h i s f o r m u l a : Add ingredients i n order l i s t e d . F o r m u l a t i o n LDL-012-01 SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s

Weight% 52.40 4.40 16.30 5.00 12.50 2.20 6.00 0.10 1.oo

Laundry Products

a h t Duty L i q u i d Detergent __ C a l s o f t LAS-99 Based Inaredients; Water C a l s o f t LAS-99 NaOH, 50% Alcohol Ethoxyl a t e Calamide C P i l o t SXS-40 Perfume P r e s e r v a t iv e Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . Formul a t i on LDL-014-01

Weight% 54.60 16.30 4.35 10.00 2.05 12.50 0.10 0.10

Light DutLLCquid D e t e r E n t Pre-Spot-Water S o l u b l e

Dry Cleaner:

Ingredients: Weight% Water 75.70 2.00 Calamide C C a l o x y l a t e N-9 11.00 C a l i mu1 s e PRS 11 .oo C i t r i c Acid 0.20 Perfume & C o l o r 0.10 Comments a b o u t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s i n o r d e r 1 i s t e d . V i s c o s i t y i n c r e a s e s as C a l o x y l a t e N-9 i s added. 2 . A c l e a r p r o d u c t i s o b t a i n e d when a l l i n g r e d i e n t s a r e m i x e d together. 3 . D e t e r g e n t f r a g r a n c e R-1264 can be used i n t h i s f o r m u l a . 4 . Use l e v e l : d i l u t e 8 : l w i t h w a t e r . F o r m u l a t i o n LDY-001-01 Li-ght D u t y Li.qu2d D e t e r g e n t Wool _Wash I c g r e d i ents-: C a l s o f t T-60 C a l ami d e CW-100 C a l f o a m ES-303 C i t r i c Acid Comments a b o u t t h i s f o r m u l a : The room t e m p e r a t u r e v i s c o s i t y i s a b o u t 520 c P s . F o r m u l a t i o n LDY-002-01

Wei g h t % 14.15 5.48 39.64 0.13

L i g h t D u t E L i q u j d Detergent Wool Wash

--

Ing r e d i g n t s : Calsuds A Water Comments a b o u t t h i s f o r m u l a : The room t e m p e r a t u r e v i s c o s i t y i s a b o u t 25 c P s . F o r m u l a t i o n LDY-004-01

SOURCE:

P i l o t Chemical Co. : Stiggested F o r m u l a t i o n s

We1 g h t % 50.06 49.93

99

100

Advanced Cleaning Product Formulations

Two Part Industria1 Laundry Deteraents

Break Formulations Hi q h l v A 1 kal ine Break Components: Water Burcosperse LP Burcolite BSGH-255 Dequest 2000 50% NaOH

% by

Weight 5 10 5 5

75 Mixed Builder Break

Components: Water 45% KOH Burcosperse LP TKPP Sodi um Si 1 i cate (Star Grade)

%

by Weight 40.0

27.5 10.0

10.0 12.5

Procedure: Add components in the order listed. Blend until homogeneous between each addition. Keep temperature below 160F during bl endi ng. Detergent Additive Components: Water Burco NPS-816 Neodol 25-7 Dodecylbenzenesulfonic Acid TEA-85

% by

Weight 60.00 10.00 12.50 11.65 5.85

Procedure: Add components in the order listed. Blend until homogeneous between each addition. Use Level: Break: 4-12 ounces/100 pounds Detergent: 2-4 ounces/100 pounds SOURCE: Burlington Chemical Co., Inc.: Suggested Formulations

Laundry Products

101

U l t r a L i q u i d Laundrv Deterqent Ingredients: Wt% A l p h a - S t e p MC-48 29.0 5.0 Sodi urn 01e a t e Alcohol, Ethoxylate, 7 19.0 Borax 1.3 0.5 3A A l c o h o l P r o p y l ene G1 y c o l 5.0 PVP K-15 0.8 Q . S . t o 100.0 W a t e r , f r a g r a n c e & dye M i x i n g Procedure: Combine A l p h a - S t e p MC-48, p r o p y l e n e g l y c o l , a l c o h o l e t h o x y l a t e and w a t e r w h i l e m i x i n g u n t i l s o l u t i o n i s homogeneous. H e a t t o a p p r o x i m a t e l y 50 deg. C, add sodium o l e a t e and m i x u n t i l s o l u t i o n and i s a g a i n homogeneous. A l l o w m i x t u r e t o c o o l t o room t e m p e r a t u r e and add t h e r e m a i n i n g i n g r e d i e n t s w i t h m i x i n g . A d j u s t p H w i t h c a u s t i c soda o r c i t r i c a c i d i f n e c e s s a r y . Typical Formulation Properties: F o r m u l a t i o n D e s c r i p t i o n : SME/Soap Based HDL pfl: 8-10 V i s c o s i t y : 200-350 c p s Density: 8.6 Appearance: C l e a r , l i g h t y e l l o w 1 q u i d Use I n s t r u c t i o n s : Use 1 / 3 c u p p e r n o r m a l s i z e w a s h l o a d Comment: A l p h a - S t e p MC-48 i s an e x c e l l e n t oap s o l u b i l i z e r t h a t c a n make h i g h soap l e v e l s p o s s i b l e i n f i n i s h e d p r o d u c t s . F o r m u l a t i o n N o . 658 F i n e F a b r i c Wash Ingredients: Wt% Water, D . I . 43.4 A l p h a - S t e p MC-48 46.0 N i n o l 30-LL 4.6 Sodi um c h l o r i d e 6.0 M i x i n g Procedure: Charge w a t e r and MC-48 and m i x . Add 30-LL and m i x u n t i l homogeneous. Add sodium c h l o r i d e t o t h i c k e n . A d j u s t pH w i t h s u l f u r i c a c i d o r sodium h y d r o x i d e as n e c e s s a r y . Properties: Appearance: C l e a r y e l l o w l i q u i d pH, as i s : 7 . 5 V i s c o s i t y @ 25 deg. C, c p s : 220 S o l i d s , %: 2 9 . 0 F r e e z e / t h a w , 3 c y c l e s : pass C o l d s t o r a g e @ 4 deg. C, 1 week: p a s s H i g h temp. s t o r a g e @ 50 deg. C, 1 week: p a s s Density, l b s / g a l : 0.6 Use I n s t r u c t i o n s : Use s m a l l amount f o r hand w a s h i n g o r 1 / 4 cup f o r machine washing. Comment : The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e . F o r m u l a t i o n No. 358 SOURCE: Stepan C o . : Suggested F o r m u l a t i o n s

9. Metal Cleaners and Polish

Metal Cleaners and Polishes

103

Acid Metal Cleaner* The c o m b i n a t i o n o f Veegum and Rhodopol 2 3 suspends t h a a b r a s i v e and p r o v i d e s a s t a b l e , f r e e f l o w i n g c l e a n e r w i t h good v e r t i c a l s u r f a c e c l i n g . Veegum i s p r o t e c t e d a g a i n s t f l o c c u l a t i o n i n t h i s pH 1 c o m p o s i t i o n t h r o u g h base exchange w i t h t h e i m i d a z o l i n e . T e t r a s o d i u m EDTA f a c i l i t a t e s t h i s exchange. Veegum and Rhodopol p r o v i d e s y n e r g i s t i c t h i c k e n i ng w i t h b e t t e r v i s c o s i t y s t a b i l i t y and i n h i b i t i o n o f s y n e r e s i s t h a n i s p o s s i b l e w i t h e i t h e r t h i c k e n e r a l o n e . Diatomaceous E a r t h p r o v i d e s good c l e a n s i n g and p o l i s h i n g .

y &

A:

Inqredients: Veegum Rhodopol 23 Water

0.8 0.4 72.1

6: T e t r a s o d i u m EDTA 1 - H y d r o x y e t h y l - 2 - c a p r y l i m i d a z o l i ine Phosphoric a c i d Diatomaceous E a r t h

0.9 0.8 15.0 10.0

Procedure: S l o w l y add them t o t h e w a t e r w h i l e B l e n d Veegum and Rhodopol a g i t a t i ng a t maximum a v a i 1ab e s h e a r . C o n t i n u e m i x i n g u n t i l smooth. Add B i n g r e d i e n t s i n o r d e r , m i x i n g w e l l a f t e r each a d d i t i o n u n t i l smooth and un f o r m ( a v o i d i n c o r p o r a t i o n o f a i r )

.

Consistency:

White,

pourable l i q u i d .

Suggested P a c k a g i n g : P l a s t i c squeeze b o t t l e w i t h p r e c a u t i o n a r y labeling f o r acid. *U.S. P a t e n t No. 4,302,253

SOURCE:

R.T.

V a n d e r b i l t Co.,

I n c . : F o r m u l a t i o n No. 392

D i ppi ns C1 e a n e r f o r S i 1v e r

Ingredients: Z u s o l a t 1008/85 Thiourea Hydrochloric acid Water

SOURCE: Zschimmer & Schwarz GmbH & C o . :

2.5 8.0 3.0 86.5 F o r m u l a t i o n CT 0 2 - 1 5 - 0 2

104

Advanced Cleaning Product Formulations

A1 umi num C1 e a n e r / B r i g h t e n e r T r a d i t i o n a l l y , a n i o n i c s u r f a c t a n t s have o f f e r e d b e t t e r d e t ergency t h e n n o n i o n i c s , b u t were n o t c o m p a t i b l e i n a c i d systems. T h i s f o r m u l a t i o n uses Avanel S - 7 0 , an a n i o n i c m o l e c u l e w h i c h p e r f o r m s even a t v e r y low p H ' s and a i d s i n t h e removal o f s u r f a c e o i l s and d e p o s i t s . U n l i k e n o n i o n i c s , Avanel 5-70 w i l l d i s s o l v e r e a d i l y i n t o the formulation without forming gel p a r t i c l e s thus e l i m i n a t i n g t h e need f o r e x c e s s i v e a g i t a t i o n . T h i s f o r m u l a t i o n can be used f o r o v e r - t h e - r o a d aluminum t r a i l e r s , w i r e wheels on a u t o m o b i l e s o r i n t h e p r e p a r a t i o n o f aluminum f o r a n o d i z i n g and c l eani ng.

Wt%

Inqredients: Dei o n i zed Water Phosphoric A c i d ( 8 5 % ) C i t r i c Acid (50%) N i t r i c Acid (70%) Avanel S-70

83.0 6.0

8.0

1.o

2.0

Procedure: Charge t h e w a t e r t o a m i x i n g v e s s e l . Under slow a g i t a t i o n and w i t h due c a r e , add t h e a c i d s t o t h e w a t e r . Add t h e Avanel S - 7 0 and m i x 10 m i n u t e s . NOTE: I f a d d i t i o n a l b r i g h t e n i n g i s r e q u i r e d , t h e n i t r i c a c i d c o n c e n t r a t i o n may be i n c r e a s e d t o 1 . 5 % . F o r m u l a t i o n CM-101 Powdered M e t a l C l e a n i n g C o n c e n t r a t e

Wt%

I n a r e d ients: Sodi um H y d r o x i d e Sodium Carbonate STPP Avanel 5-70

58.5

13.5 20.0 8.0

Procedure: Add i n g r e d i e n t s as l i s t e d . A1 u m i num C1 eaner Ingredients: D e i o n i z e d Water Avanel S - 7 0 T e t r a p o t a s s i u m Pyrophosphate Sodium M e t a s i l i c a t e P e n t a h y d r a t e C a r b i t o l Solvent

85.0 6.0

5.0 1.o

3.0

Procedure: Charge v e s s e l w i t h i n g r e d i e n t s i n t h e o r d e r l i s t e d u s i n g mode r a t e a g i t a t i o n . NOTE: Other Avanel p r o d u c t s c o u l d be used i n t h i s f o r m u l a t i o n t o achieve d i f f e r e n t s u r f a c t a n t c h a r a c t e r i s t i c s .

SOURCE:

PPG I n d u s t r i e s ,

I n c . : Suggested F o r m u l a t i o n s

105

Metal Cleaners and Polishes

A1 umi num C l e a n e r C o n c e n t r a t e F-498

UhWeight 75 10 5 10

Water Sodium M e t a s i l i c a t e (Anhydrous) T e t r a Potassium Pyrophosphate (Powder) Mona NF-10

Procedure: D i s s o l v e sodium m e t a s i l i c a t e and t e t r a p o t a s s i u m p y r o p h o s p h a t e i n w a t e r w i t h m i x i n g , t h e n add Mona N F - 1 0 . Typical Properties: Appearance : C l e a r 1 iq u i d Cloud P o i n t : 8 8 C Recommended Use D i l u t i o n : 1 t o 4 o z / g a l Aluminum Wash F-499 % By Weiaht

Water Sodium M e t a s i l i c a t e (Anhydrous) T e t r a Sodium Pyrophosphate (Powder) B u t y l Carbi t o 1 Mona N F - I 0

88 2

3 2 5

Procedure: D i s s o l v e sodium m e t a s i l i c a t e and t e t r a sodium p y r o p h o s p h a t e i n w a t e r , t h e n add B u t y l C a r b i t o l and Mona NF-10. Typical Properties: Appearance: C l e a r 1 iq u i d pH: 1 2 . 8 Recommended Use D i l u t i o n : 1 : l O w i t h water

SOURCE: Mona I n d u s t r i e s , I n c . :

Suggested F o r m u l a t i o n s

106

Advanced Cleaning Product Formulations

B u f f i nq Compound Remover

%

Component: Water TEA B u r c o t r o p e 1250 B u r c o s p e r s e LP Borax B u r c o TME B u r c o LAF-6

42.5 20.0 12.5 12.5 5.0 5.0 5.0

Add components i n o r d e r l i s t e d . each a d d i t i o n .

B l e n d u n t i l homogeneous between

H o t A1 k a l in e P a i n t S t r i p p e r C o n c e n t r a t e

a

Compo n e n t s : 45% KOH K a s i l #1 B u r c o HCS-50 NF

67 32 1

Add components i n t h e o r d e r l i s t e d . between each a d d i t i o n . SOURCE: B u r l i n g t o n Chemical

Co.,

B l e n d u n t i l homogeneous

I n c . : Suggested F o r m u l a t i o n s

M e t a l De-Oi 1 in g L i q u i d C o n c e n t r a t e (Liquid) S o i l - Petroleum-based o i l S u r f a c e - M e t a l : S t e e l , c o p p e r , aluminum, e t c . A p p l i c a t i o n Method - Spray a n d / o r i m m e r s i o n Manufacture - Mix tank w i t h p r o p e l l e r s t i r r e r Composi t i on : Water Starso EDTA, T e t r a s o d i u m ( 3 7 % ) Sodi um X y l ene S u l f o n a t e ( 4 0 % ) C9-C11 L i n e a r A l c o h o l , 6 Moles EO C9-C11 L i n e a r A l c o h o l , 2.5 M o l e s EO Use D i l u t i o n : 2%-4% b v SOURCE: The

PQ C o r p . : Suggested F o r m u l a t i o n

wtu/, 42.0 12.0 16.0 20.0 3.0

7.0

Metal Cleaners and Polishes

107

Cutting O i l

Monalube 215 p r o v i d e s e x c e l l e n t l u b r i c i t y , and e x t r e m e p r e s s u r e p r o p e r t i e s . T h i s f o r m u l a t i o n i s used i n machining, stamping and d r a w i n g f e r r o u s and n o n f e r r o u s m e t a l s . Wt% Innredients: 100 P a l e O i l 95.0 Monalube 215 5.0 Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. Typical Properties: Appearance: C1 e a r Amber L i q u i d V i s c o s i ty/4OC: 24 CS Performance Data: Fa1 ex ( D i r e c t S c a l e ) : 2000 Lbs. /56 I n . -Lbs Draw Bead E f f i c i e n c y : 95 Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115 Formul a t ion F-791

.

Cutting O i 1

Inqredients: 100 P a l e O i l 90.0 Monalube 205 5.0 Monalube 215 5.0 Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. Typical Properties: Appearance: C l e a r Amber L i q u i d V i s c o s i t y ( 4 0 C ) : 25 CS Fa1 e x : 2250 Lbs / 6 0 I n . -Lbs Appl i c a t i ons: F o r machi n i ng s t a m p i n g and d r a w i n g . F o r m u l a t i o n F-792

.

.

Cutting O i l

Wt% Inqredients: 85.0 100 P a l e O i l Monalube 205 5.0 Monalube 215 5.0 5.0 Monalube 225 Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. Typical Properties: Appearance: C1 e a r Amber L i q u i d V i s c o s i t y / 4 0 C : 30 CS Performance Data: F a l e x ( D i r e c t S c a l e ) : 2750 L b s . / 7 0 I n . . - L b s . Draw Bead E f f i c i e n c y : 90 Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115 Appl i c a t i ons: Heavy d r a w i n g and s t a m p i n g F o r m u l a t i o n F-793 SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s

108

Advanced Cleaning Product Formulations

Cutting O i l Ingredients: 100 P a l e O i l Monalube 215 Monalube 225

% &

90.0 5.0 5.0

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. T y p i c a l P r o p e r t ie s : Appearance: C l e a r Amber L i q u i d V i s c o s i t y 40C: 27 CS Performance D a t a : F a l e x ( D i r e c t S c a l e ) : 2500 Lbs./6O I n . - L b s . Draw Bead E f f i c i e n c y : 90 Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115 Formul a t ion F-794 Cuttina O i l

WtO/o

Insredients: 100 Pale O i l Monalube 225

95.0 5.0

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. Typical Properties: Appearance: C1 e a r Amber L i q u i d V i s c o s i t y 40C: 24 C S Performance D a t a : F a l e x ( D i r e c t S c a l e ) : 2750 Lbs./6O I n . - L b s . Draw Bead E f f i c i e n c y : 90 Draw Bead E f f i c i e n c y R e f e r e n c e O i l : 115 Formul a t ion F-795 Cutting Oi1

Wt%

Inqredients: 100 P a l e O i l Monalube 215 Monalube 325

90.0 5.0 5.0

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. Typical Properties: Appearance: C l e a r Dark Brown L i q u i d V i s c o s i t y 40C: 22 CS P e r f o r m a n c e Data: F a l e x ( D i r e c t S c a l e ) : 2250 L b s . / 5 5 I n . - L b s . F o r m u l a t i o n F-796 SOURCE: Mona I n d u s t r i e s ,

Inc.:

Suggested F o r m u l a t i o n s

Metal Cleaners and Polishes

109

Cutting O i l s Semi-Synthetic-Cutting

Oi1 Wei q h t % 17.77 2.98 2.75 15.04 61.48

Ingredients: A r i s t o n a t e M-LF Oleic Acid TEA P r o p y l ene G l y c o l Water

Comments a b o u t t h i s f o r m u l a : 1 . M i x a l l of t h e i n g r e d i e n t s , e x c e p t t h e P r o p y l e n e G l y c o l . 2 . Add t h e w a t e r SLOWLY. 3 . Add t h e P r o p y l e n e G l y c o l l a s t . F o r m u l a t i o n SOF-001-01 C u t t i n g O i 1 Concentrate Ingredi ents: Aristonate M D r e s i n a t e 91 I g e p a l CO-430 KOH, 45% O l e i c A c i d , Emersol 2 1 3 O l e i c A c i d Diethylene Glycol Water

Wei g h t % 60.60 20.20 0.10 1.25 8.25 7.10 2.50

Comments a b o u t t h i s f o r m u l a : 1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l . 2 . E m u l s i o n - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r . F o r m u l a t i o n SOL-001-01 Cutting O i 1 C o n c e n t m e

I ny,,edie n t s : Aristonate M Neodol 2 5 - 3 TEA, 85% Oleic Acid D i e t h y l ene G1 y c o l Water

Weight% 51.80 21.60 4.50 8.50 8.60 5.00

Comments a b o u t t h i s f o r m u l a : 1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 1 0 0 SUS n a p h t h e n i c o i l . 2 . E m u l s i o n - D i l u t e 4 : 7 6 w i t h 1 6 0 ppm h a r d w a t e r . F o r m u l a t i o n SOL-002-01

SOURCE:

P i l o t Chemical Co. : Suggested F o r m u l a t i o n s

I 10

Advanced Cleaning Product Formulations

G e n e r a l Purpose Machine C l e a n e r T h i s i s an e x c e l l e n t a l l - p u r p o s e c l e a n e r f o r c l e a n i n g a l l t y p e s o f f e r r o u s p a r t s and machine s u r f a c e s . Monacor 4000 i s i n c o r p o r a t e d f o r added c o r r o s i o n p r o t e c t i o n .

In g r e d i e n t s : Water T r i e t h a n o l a m i ne Monacor 4000 Monami ne CF-1 OOM M o n a t e r i c CyNa-50 T e t r a s o d i u m EDTA (40%) T r i a d i n e 10 ( P r e s e r v a t i v e ) Procedure: Mix t h e i n g r e d i e n t s i n o r d e r a t ambient temperature. between each a d d i t i o n a t moderate speed. Typical Properties: Appearance: C l e a r amber l i q u i d S p e c i f i c G r a v i t y : 1 .06 pH C o n c e n t r a t e : 1 0 . 2 p H o f a 1:10 s o l u t i o n : 9 . 8 Recommended Use D i l u t i o n : 1 : 1 0 w i t h w a t e r Cast I r o n B l o c k : Pass Corrosion Test: 1:10 D i l u t i o n F o r m u l a t i o n F-770

69.00 4.00 3.50 6.00 6.00 10.00 I .50 M i x we1 1

A i r c r a f t C l e a n e r Type I V The f o l l o w i n g f o r m u l a t i o n uses Monamulse 653-838 as an emuls i f i e r i n a m i l i t a r y s p e c i f i c a t i o n (MIL-C-855706) f o r m u l a t i o n . Inaredient: P a r t A: Monamulse 653-0313 Monami ne 1-76 A r o m a t i c 150 Isopar M (Odorless Mineral S p i r i t s ) Diethylene Glycol Butyl Ether Decanol

vvts/, 7.0 2.7 7.5 7.5 3.5 1.6

P a r t B: T r i s o d i u m Phosphate (Dodecahydrate) 2.7 Water 55.1 P l u r o n i c F98 1.8 Hycar 1422 10.6 Procedure: Add i n g r e d i e n t s o f P a r t A & P a r t 8 s e p a r a t e l y w i t h a g i t a t i o n . Add P a r t B t o P a r t A . A g i t a t e u n t i l u n i f o r m . Typical Properties: Appearance: C1 e a r L i q u i d F o r m u l a t i o n F-784

SOURCE: Mona I n d u s t r i e s ,

Inc.:

Suggested F o r m u l a t i o n s

Metal Cleaners and Polishes

General Purpose S y n t h e t i c F l u i d ( A )

Wt96

Ingredients: M a s l i p 501 Bas= Maphos 8135 Mazon R I 4 A T r i e t h a n o l a m i n e , 85% B i o c i de Water

5.0 8.0 8.0

12.0 0.5 Balance

Procedure: 4 . Add i n g r e d i e n t s as l i s t e d . 2. T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d be f u r t h e r d i l u t e d f r o m 1:lO (heavy d u t y ) t o 1:40 ( l i g h t d u t y ) w i t h water t o form a ready-to-use f l u i d . For increased and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 4 A . For i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f l u b r i c a n t o r extreme p r e s s u r e a d d i t i v e . General Purpose S y n t h e t i c F l u i d (BZ

Wt%

Ingredients: M a s l i p 500 Mazon R I 8 B P r o p y l ene G1 y c o l T o l y t r i a z o l e (Climax) T r i e t h a n o l a m i ne, 85% 8 i o c i de Water

38.0

12.0 2.5 2.5 10.0 0.5 Balance

Procedure: 1 . Add i n g r e d i e n t s as l i s t e d . 2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d be f u r t h e r d i l u t e d f r o m 1:lO (heavy d u t y ) t o 1:40 ( l i g h t d u t y ) w i t h water t o form a ready-to-use f l u i d . For increased r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 8 B . For i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f l u b r i c a n t o r extreme p r e s s u r e a d d i t i v e . Copper M a c h i n i n a F l u i d Ingredients: Macol 5100 Mazon R I 6 Maphos 8135 P o t a s s i um H y d r o x i d e B i o c i de Water

8.0

7.0 6.0 0.5 Balance

Procedure: Add i n g r e d i e n t s as l i s t e d .

SOURCE:

PPG I n d u s t r i e s ,

Wt% 15.0

I n c . : Suggested F o r m u l a t i o n s

111

112

Advanced Cleaning Product Formulations

G e n e r a l Purpose S y n t h e t i c F l u i d ( C ) Ingredients: M a s l i p 501 A Mazon R I 8 B Maphos 58 T r i e t h a n o l ami ne, B i o c i de Water

Mle9/0 30.0 12.0 6.0

85%

7.0 0.5

5al ance

Procedure: 1. Add i n g r e d i e n t s as l i s t e d . 2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d b e f u r t h e r d i l u t e d f r o m 1:lO ( h e a v y d u t y ) t o 1 : 4 0 ( l i g h t d u t y ) w i t h water t o form a ready-to-use f l u i d . For increased r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 8 8. F o r i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount of l u b r i c a n t o r extreme pressure a d d i t i v e . G e n e r a l Purpose S y n t h e t i c F l u i d ( D ) I n s r e d ients: M a s l i p 501 Base Mazon R I 8 A Maphos 8135 T r i e t h a n o l ami n e , B i o c i de Water

Wt% 12.0 25.0 5.0 12.0 0.5 5 a l ance

85%

Procedure: 1 . Add i n g r e d i e n t s as l i s t e d . 2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d b e f u r t h e r d i l u t e d f r o m 1 : l O (heavy d u t y ) t o 1 : 4 0 ( l i g h t d u t y ) w i t h water t o form a ready-to-use f l u i d . For increased r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 8 A . F o r i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f l u b r i c a n t o r extreme pressure a d d i t i v e .

SOURCE:

PPG I n d u s t r i e s ,

Inc.:

Suggested F o r m u l a t i o n s

Metal Cleaners and Polishes

Metal Cleaner (Phosphate, Powder) Soi 1 -Drawing l u b r i c a n t , a n i m a l f a t and g r e a s e Surface-Steel A p p l i c a t i o n Method-Spray M a n u f a c t u r e - D r y b l e n d / A g g l o m e r a t on Composi t i on :

*STPP *Sodi um C a r b o n a t e **Alkoxylated l i n e a r alcohol nonion c s u r f a c t a n t ( 1ow foam) Metso Beads 2048 Sodi um H y d r o x i d e Beads

10.0 25.0 5.0 30.0 30.0

Use: Heavy d u t y l o w - f o a m i n g m e t a l c l e a n e r w h i c h i s good f o r a spray c l e a n i n g process. Use D i l u t i o n : 0.8-1.5% bw ( 1 - 2 o z / g a l l o n )

**

FMC O l i n P o l y t e r g e n t S-305LF o r Rhone-Poulenc I g e p a l CO-530 A1 umi num C1 e a n e r (Phosphate, Powder)

Soi 1- L i g h t d r a w i n g o i 1 Surface-Aluminum A p p l i c a t i o n Method-Spray washer M a n u f a c t u r e - D r y b l end/Aggl o m e r a t i on Composi t i on : Metso Beads 2048 *STPP *Sodi um B i c a r b o n a t e **Sodium P o l y a c r y l a t e * * * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 9-10 Moles EO Use D i l u t i o n : 1.5-3.036 bw ( 2 - 4 o z / g a l )

* ** ***

FMC Rohm 8, Haas A c u s o l 445ND (92% s o l i d s ) Rhone-Poul enc I g e p a l CA-630

SOURCE:

PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide

Wt% 45.0 30.0 20.0 3.0 2.0

113

114

Advanced Cleaning Product Formulations

M e t a l C1 e a n e r (Phosphate. Powder2 S o i l - O i l , d r a w i n g l u b r i c a n t , a n i m a l f a t and g r e a s e Surface-Steel A p p l i c a t i o n Method-Immersion ManufacturekDry blend/Agglomeration Composi t i o m *Sodium C a r b o n a t e *STPP **Octylphenoxy Polyethoxyethanol ( 6 Moles € 0 ) Metso Beads 2048 Sodi um H y d r o x i d e Beads

20.0 8.0 2.0 30.0 40.0

Use D i l u t i o n : 2 . 3 - 4 . 5 % bw ( 3 - 6 o z / g a l l o n )

* **

FMC Rhone-Poulenc I g e p a l CA-630 M e t a l C1 eaner (Phosphate, Powder) S o i l - O i l , d r a w i n g l u b r i c a n t , animal f a t and g r e a s e Surface-Steel A p p l i c a t i o n Method-Immersion/electrolytic c l e a n i n g Manufacture-Dry blend/Agglorneration

Com o s i t i o n : TSPF TSP Metso Beads 2048 Sodium C a r b o n a t e * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l (12-13 Moles EO) Sodium H y d r o x i d e Beads Use D i l u t i o n : 2 . 3 - 4 . 5 % bw ( 3 - 6 o z / g a l )

*

Rhone-Poulenc I g e p a l CA-720

SOURCE: PO C o r p . : D e t e r g e n t F o r m u l a t i o n Guide

Wt% 15.0 5.0 35.0 28.0 2.0 15.0

Metal Cleaners and Polishes

Metal Cleaner Powder 1

I Phosphate,

S o i 1 - 0 i 1, f a t , p r o t e i n Surface-Stai nless s t e e l A p p l i c a t i o n Method-Cleaning i n p l a c e Manufacture-Dry blend/Agglomeration Composi t i o n A : *STPP *Sodium C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; M e t s o Beads 2048 Sodi um H y d r o x i d e Beads

3 M o l e s EO)

WtO/o

Composition

0: *STPP *Sodium C a r b o n a t e * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; Metso Pentabead 20 Use D i l u t i o n :

*

**

40.0 12.0 3.0 25.0 20.0

3 Moles EO)

40.0 12.0 3.0 45.0

1 . 5 - 3 . 0 % bw ( 2 - 4 o z / g a l l o n )

FMC Rhone-Poluenc R h o d a s u r f A-24 M e t a l C1 e a n e r ( Z e r o Phosphate, Powder) S o i 1-Oi 1 , d r a w i n g l u b r i c a n t , animal f a t and g r e a s e Surface-Steel A p p l i c a t i o n Method-Immersion M a n u f a c t u r e - D r y b l e n d / A g g l o r n e r a t i on

n : Composi t i o V a l f o r 100 Z e o l i t e A Sodium C a r b o n a t e * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l (9-10 Moles E O ) Metso Pentabead 20 A c u s o l 445ND Sodi um P o l y a c r y l a t e Use L e v e l : 3-6 o z / g a l l o n g

Rhone-Poulenc

SOURCE:

I g e p a l CA-630

PB C o r p . :

Detergent F o r m u l a t i o n Guide

WtO/o 15.0 38.0 2.0 43.0 2.0

115

116

Advanced Cleaning Product Formulations

Non-Phosphorous Aluminum C l e a n e r T h i s i s a t o t a l l y o r g a n i c , p h o s p h a t e - f r e e aluminum c l e a n e r t h a t p r o v i d e s e x c e l 1e n t c l e a n i ng and b r i g h t e n i ng o f a1 umi num. The Avanel S - 7 0 p r o v i d e s f o r removal o f o r g a n i c s u r f a c e d e p o s i t s and, by s u r f a c e t e n s i o n r e d u c t i o n , b e t t e r c o n t a c t between t h e aluminum s u r f a c e and t h e o r g a n i c a c i d s . I n a d d i t i o n t o i n d u s t r i a l a p p l i c a t i o n s l i k e c l e a n i n g o v e r - t h e - r o a d aluminum t r a i l e r s and aluminum p r i o r t o a n o d i z i n g , t h i s c l e a n e r may also be used i n household a p p l i c a t i o n s such as c l e a n i n g aluminum f l a s h i n g , windows and door f i x t u r e s . Depending on t h e a p p l i c a t i o n , t h i s p r o d u c t may be used i n a D r e s s u r e wash, pump s p r a y o r d i p tank.

w.e-l

Inqredients: C i t r i c A c i d , 50% G l u c o n i c A c i d , 50% Avanel S-70 D e i o n i z e d Water, Dye

12.0 8.0 3.0 Balance

Procedure: Charge t h e w a t e r , c i t r i c a c i d , g l u c o n c a c i d and Avanel S - 7 0 M i x w e l l . Ifdye i s t o be added, p a r t o f t h e w a t e r s h o u l d be he d good a g i t a t i o n . The o u t ; and t h e dye added t o t h i s w a t e r w i t d i s s o l v e d dye can t h e n be added t o t h e b a t c h . NOTE: C e r t a i n dyes may n o t be s t a b l e under t h e s e c o n d i t i o n s . Consequently, s h e l f s t a b i l i t y t e s t s s h o u l d be p e r f o r m e d . F o r m u l a t i o n CM-102

A 1 k a l ine A1 u m i num C1 eaner I n a r e d ie n t s : Dei o n i zed Water Avanel S - 7 0 T e t r a p o t a s s i u m Pyrophosphate Sodium M e t a s i l i c a t e P e n t a h y d r a t e Macol 48

87.0 4.0 5.0

1.o

3.0

pH ( a s i s ) : 1 1 . 5 - 1 2 . 5 Appearance: C l e a r , w a t e r - w h i t e l i q u i d S p e c i f i c G r a v i t y : 1.05 Procedure: Charge t h e w a t e r and d i s s o l v e t h e b u i l d e r s a l t s under a g i t a t i o n . When d i s s o l v e d , c h a r g e t h e r e m a i n i n g i n g r e d i e n t s . C o n t i n u e m i x i n g f o r a t l e a s t 15 m i n u t e s . NOTE: T h i s a l k a l i n e aluminum c l e a n e r has shown e x c e l l e n t c l eani ng p r o p e r t i e s w i t h o u t c h e m i c a l a t t a c k o f t h e m e t a l . T h i s f o r m u l a t i o n may b e c u t -!:I w i t h water t o prepare a m i l d hard-surface c l e a n e r . F o r m u l a t i o n CM-1034

SOURCE:

PPG I n d u s t r i e s ,

I n c . : Suggested F o r m u l a t i o n s

Metal Cleaners and Polishes

117

Semi S y n t h e t i c T h i s f o r m u l a t i o n i s p a r t i c u l a r l y u s e f u l f o r heavy m a c h i n i n g and l i g h t d r a w i n g f o r f e r r o u s and s t a i n l e s s s t e e l . Ingredients: 100 P a l e O i l Monalube 320 Monalube 610 Monalube 205 Monalube 215 T r i e t h a n o l ami ne (99%) Monacor BE Water

wt9j0 9.0

9.0

13.6 0.8 0.8 3.2 5.0 58.6

Procedure: Combi ne i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Fa1 ex ( D i r e c t S c a l e ) : 2500 L b s . /50 I n . - L b s . Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Appearance: C l e a r pH: 9 . 6 F o r m u l a t i o n F-797 Semi S y n t h e t i c wt9j0 9.0

InQredients: 100 P a l e O i 1 Monalube 320 Monalube 610 Monalube 220 T r i e t h a n o l a m i n e (99%) Monacor BE Water

9.0

13.6 1.6 3.2 5.0 58.6

Procedure: M i x i t e m s 1,2, and 3 u n t i l c l e a r . Add i t e m s 4,5, and 6 . 5% o f c o n c e n t r a t e t o 95% w a t e r f o r m s m i c r o e m u l s i o n . F o r m u l a t i o n c a n be u s e d f o r g r i n d i n g and l i g h t m a c h i n i n g . T y p i ca9 P r o p e r t i es : Appearance : C1 e a r Amber L i q u i d Performance Data ( 5 % i n Water): Appearance: C l e a r L i q u i d pH:

9.5

S u r f a c e T e n s i o n (dynes/cm): 32 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs./45 I n . - L b s . Formul a t ion F-800

SOURCE: Mona I n d u s t r i e s ,

Inc.:

Suggested F o r m u l a t i o n s

I18

Advanced Cleaning Product Forniulations

Semi S y n t h e t i c

y&

Inaredients: 100 P a l e O i l Monalube 225 TEA Monalube 610 Water

10.0 5.5 7.5 25.0 47.5

Typical Properties: Appearance: C 1 e a r Amber L i q u i d Performance Data ( 5 % i n w a t e r ) : Appearance: C1 e a r L i q u i d pH: 9 . 0 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t S c a l e ) : 2750 Lbs. / 5 5 I n . -Lbs F o r m a c h i n i n g l i g h t s t a m p i n g and d r a w i n g . F o r m u l a t i o n F-799

.

Semi S y n t h e t i c

Wt%

Inqredients: 100 P a l e O i l Monalube 320 Monalube 610 Monalube 205 T r i e t h a n o l a m i n e (99%) Monacor BE Water

9.0 9.0 13.6 1.6 3.2 5.0 58.6

Procedure: M i x i t e m s 1 , 2, and 3 u n t i l c l e a r . Add i t e m s 4 and 5 t h e n 6 . 5% o f c o n c e n t r a t e added t o w a t e r f o r m s m i c r o e m u l s i o n . S u g g e s t e d f o r g r i n d i n g and m a c h i n i n g f o r b o t h f e r r o u s and n o n f e r r o u s metals. Typical Properties: Appearance: C l e a r Amber L i q u i d Performance Data ( 5 % i n Water): Appearance: C l e a r L i q u i d pH: 9.5 Surface Tension: 27.0 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 e x ( D i r e c t S c a l e ) : 2500 L b s . /57 I n . -Lbs F o r m u l a t i o n F-801

SOURCE: Mona I n d u s t r i e s ,

Inc.:

.

Suggested F o r m u l a t i o n s

Metal Cleaners and Polishes

119

Silver and M e t a l Polish I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become permanently suspended The r e s i n a1 so p r e v e n t s "creami ng" o r phase separa t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s . ~

Insredient: SF96 S i l i c o n e F l u i d (350) ( 1 ) Dow C o r n i n p 20 Release C o a t i n g ( 2 ) S t o d d a r d S o l v e n t (3) P r i f a c 2922 L a u r i c A c i d D I Water Morphol ine Carbopol EZ-2 ( 4 ) Ammoni um h y d r o x i d e b g o p g l i e K a o l i C l a y (5) ysp c a f Proper€+es. B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): P r o d u c t pH: 8.50 Product C l a r i t y : P a s t e

Wt%

1 .oo 2.00 20.00 2.00

43.48 0.86

0.35 0.31 14.00 1 0 , 0 0 0 cps

Raw M a t e r i a l S u p p l i e r s : ( 1 ) General E l e c t r i c ( 2 ) Dow C o r n i n g Corp. ( 3 ) Exxon Corp. ( 4 ) BFGoodrich (5) Kaopolite, Inc. Procedure: 4 . Add t h e s i l i c o n e f l u i d , r e l e a s e c o a t i n g , s o l v e n t , and l a u r i c a c i d P o a v e s s e l . Mix u s i n g a h i g h shear m i x e r . 2 . C o n t i n u e t o m i x , and add t h e water (43.48 p a r t s ) and t h e morphol ine. 3 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r (16.00 p a r t s ) by s i m p l y "dumping" i t i n . The polymer w i l l wet o u t i n a few m i n u t e s . Add t h e d i s p e r s i o n t o t h e above m i x t u r e w i t h good a g i t a t i o n . 4 . Add t h e ammonium h y d r o x i d e t o r e a c h t h e t a r g e t pH. 5 . Add t h e c l a y and mix u n t i l u n i f o r m .

T o t a l A c t ives : Silicone f l u i d : Stoddard s o l v e n t : Re1ease c o a t i ng : Abras i vet

1 .oo 20.00 2.00

14.00

FGoodrich S p e c i a l t y Chemicals: DET-563

120

Advanced Cleaning Product Formulations

Soluble O i 1

WtO/o

Ingredients: 100 P a l e O i l Monalube 605 P a r o i l 160

80.0 20.0 20.0

Procedure: Combine a l l i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. Typi c a l P r o p e r t i es : Appearance: C l e a r Dark Brown Performance Data (5% i n w a t e r ) : Appearance: M i 1 ky L i q u i d pH: 8 . 5 F a l e x ( D i r e c t S c a l e ) : 2750 L b s . / 6 0

In.-Lbs.

Above f o r m u l a t i o n f o r heavy d u t y m a c h i n i n g and d r a w i n g f o r use on s t a i n l e s s s t e e l and f e r r o u s m e t a l s . F o r m u l a t i o n F-803

Soluble O i 1 Ingredients: 100 P a l e O i l Monalube 605

Wt% 85.0 15.0

Procedure: Combine above i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 5 0 C . Typical Properties: Appearance: C l e a r L i g h t Brown L i q u i d Performance Data (5% i n w a t e r ) : Appearance: M i 1 ky Emulsion pH: 8 . 8 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 1750 L b s . / 4 7 I n . - L b s . Appl i c a t i o n : For g r i n d i n g and v e r y l i g h t m a c h i n i n g . Formul a t ion F-804

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s

Metal Cleaners and Polishes

S o l u b l e Qi 1

Wt%

Inaredients: 100 P a l e O i l Monalube 6 0 5 Wonalube 2 1 5 T EA

78.0 15.0 5.0 2.0

Procedure: M i x above i n g r e d i e n t s w i t h a g i t a t i o n . Warm t o 12OF. I f s o l u t i o n i s s l i g h t l y hazy, a d j u s t w i t h t a l l o i l f a t t y a c i d . Typical Properties: Appearance: M i l k y E m u l s i o n P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: M i 1 ky Emu1 s i o n pH: 8 . 0 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t S c a l e ) : 2500 L b s . / 5 5 I n . - L b s . The above f o r m u l a t i o n i s s u g g e s t e d f o r g r i n d i n g and l i g h t machining. F o r m u l a t i o n F-805 Soluble O i 1

Wt%

Ingredients: 100 P a l e O i l Monalube 6 0 5 Monalube 215

85.0 10.0 5.0

Procedure: Combine i n g r e d i e n t s w i t h a g i a t i o n w h i l e warming t o 50C. Typical Properties: Appearance: C l e a r Amber L i q u d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Aooearance: M i 1 k v E m u l s i o n pH: 8 . 0 Falex ( D i r e c t S c a l e ) : 1250 Lbs./45

..

In.-Lbs.

The above f o r m u l a t i o n i s s u g g e s t e d f o r g r i n d i n g and l i g h t machining. F o r m u l a t i o n F-806

SOURCE:

Mona I n d u s t r i e s ,

I n c . : Suggested F o r m u l a t i o n s

121

122

Advanced Cleaning Product Formulations

Soluble O i l Machining F l u i d Monalube 225 p r o v i d e s l u b r i c i t y , and EP p r o p e r t i e s i n t h i s m a c h i n i n g f l u i d . T h i s f o r m u l a t i o n was d e s i g n e d f o r m a c h i n i n g c a r b o n s t e e l , b r a s s , b r o n z e c o p p e r and s t a i n l e s s s t e e l . Ingredients: N a p h t h e n i c O i l (lOOSUS/lOO) Monalube 225 Monalube 605 T r i e t h a n o l a r n i n e (99%)

Wt% 72.0 5.0 20.0 3.0

Procedure: Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . F a l e x EP T e s t : D i r e c t Load S c a l e : 2 7 5 0 l b s Torque: 47 i n c h pounds Use D i l u t i o n s : G r i n d i n g : I-2% i n water L i g h t M a c h i n i n g : 3-5% i n w a t e r M o d e r a t e M a c h i n i n g : 5-7% i n w a t e r Heavy M a c h i n i n g : 8-10% i n w a t e r F o r m u l a F-764 S y n t h e t i c Machininq F l u i d T h i s f o r m u l a t i o n i s i d e a l f o r machining carbon s t e e l , b r o n z e , c o p p e r , aluminum and s t a i n l e s s s t e e l .

wto/, 15.0 30.0 55.0

Ingredients: Monalube 225 T r i e t h a n o l a m i n e (99%) Water Procedure: Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . F a l e x EP T e s t P r o c e d u r e : C o n c e n t r a t i o n : 20% Aqueous s o l u t i o n D i r e c t Load S c a l e 3000 l b s . T o r q u e 60 i n c h pounds Formul a t i on F-766 SOURCE: Mona I n d u s t r i e s ,

brass,

I n c . : Suggested F o r m u l a t i o n s

Metal Cleaners and Polishes

123

Svnthetic

Wt%

Ingredients: Monalube 210 T r i e t h a n o l a m i n e (99%) Water A n t i foam

16.6 33.3 50.0 0.1

Procedure: Combine in g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d Performance Data (5% i n Water): Appearance: C l e a r L i q u i d pH: 8 . 5 S u r f a c e T e n s i o n : 42 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 5 6 I n . - L b s . The f o r m u l a t i o n i s d e s i g n e d f o r f e r r o u s and n o n f e r r o u s m e t a l s primarily f o r grinding. Formul a t i on F-819 Synthetic

K%

Inqredi ents: Monalube 210 Monalube 315 T r i e t h a n o l a m i n e (99%) Water

12.5 12.5 25.0 50.0

Procedure.: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 0 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 5 6 I n . - L b s . F o r m u l a t i o n i s d e s i g n e d f o r b o t h f e r r o u s and n o n f e r r o u s systems p r i m a r i l y f o r g r i n d i n g . F o r m u l a t i o n F-820

SOURCE: Mona I n d u s t r i e s ,

I n c . : Suggested F o r m u l a t i o n s

124

Advanced Cleaning Product Formulations

S y n t h e t i c Drawing/Stampinp F l u i d T h i s f o r m u l a t i o n i s i d e a l f o r stamping hot o r c o l d r o l l e d s t e e l . Ingredients: Monalube 225 T r i e t h a n o l a m i n e (99%) Monalube 315 Water

15.0 30.0 20.0 35.0

Procedure: Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . F a l e x EP T e s t P r o c e d u r e : C o n c e n t r a t i o n : 20% Aqueous s o l u t i o n D i r e c t Load S c a l e 3 0 0 0 l b s . T o r q u e 55 i n c h pounds F o r m u l a t i o n F-765 O i 1 Based Drawi ng/Stampi ng F1ui d

Monalube 225 p r o v i d e s l u b r i c i t y , EP and c o n t r i b u t e s t o t h e c o r r o s i o n p r o t e c t i o n p r o p e r t i e s i n t h i s heavy-duty stamping/ d r a w i n g f 1u i d . Ingredients: Paraffinic O i l Monalube 225

Wt% 90.0 10.0

(300SUS/lOO)

Procedure: B l e n d Monalube 225 i n t o t h e o i l F a l e x EP T e s t : D i r e c t Load S c a l e : 3000 l b s T o r q u e 57 i n c h pounds F o r m u l a t i o n F-763 S p r a y M e t a l C1 e a n i n g C o n c e n t r a t e Ingredients: Water Sodi um M e t a s i 1 i c a t e Sodium C a r b o n a t e Sodi um H y d r o x i d e M o n a t r o p e 1250 Alkyl Polyal kylene Ether

75.00 3.00 4.00 5.00 11.00 2.00

Procedure: Add i n o r d e r l i s t e d w i t h a g i t a t i o n , making s u r e each ingredient i s dissolved before next addition. F o r m u l a t i o n F-751

SOURCE:

Mona I n d u s t r i e s ,

Inc.:

Suggested F o r m u l a t i o n s

Metal Cleaners and Polishes

125

S y n t h e t i c Formula

Wyt

Inqredients: Monalube 205 Monalube 210 T r i e t h a n o l a m i n e (99%) Water

5.0 10.0 30.0 55.0

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C1 e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH:

8.7

S u r f a c e T e n s i o n : 27 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 4 7 I n . - L b s . T h i s f o r m u l a t i o n i s d e s i g n e d f o r b o t h f e r r o u s and n o n f e r r o u s systems f o r a r e a s o f m a c h i n i n g and g r i n d i n g a t 10% f o r m i l d s t a m p i ng. F o r m u l a t i o n F-813 S y n t h e t i c Formula

wt%

Inqredients: Monalube 205 Monalube 210 Monalube 315 T r i e t h a n o l ami ne (99%) Water

5.0 10.0 10.0 30.0 45.0

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C1 e a r Amber L i q u i d Performance Data ( 5 % i n Water): Appearance: C1 e a r L i q u i d pH: 8 . 0 S u r f a c e T e n s i o n : 32 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2750 L b s . / 5 7 I n . - L b s . T h i s f o r m u l a t i o n i s d e s i g n e d f o r b o t h f e r r o u s and n o n f e r r o u s systems f o r a r e a s o f m a c h i n i n g and g r i n d i n g a t 10% f o r m i l d s t a m p i ng. F o r m u l a t i o n F-814

SOURCE: Mona I n d u s t r i e s ,

Inc,:

Suggested F o r m u l a t i o n s

126

Advanced Cleaning Product Formulations

S y n t h e t i c Formula

w%%

Inqredients: Monalube 2 0 5 Monalube 2 2 0 T r i e t h a n o l a m i n e (99%) Monalube 315 Water Procedure: M i x i t e m s 1, 2 , 3,

4.5 9.0 27.0 20.0 39.5

and 4 . Add w a t e r and mix u n t i l homogeneous.

Typical Properties: Appearance: C l e a r Amber L i q u i d Performance Data (5% i n W a t e r ) : Appearance: T r a n s l u c e n t S o l u t i o n pH: 9 . 0 Surface Tension: 32 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Falex ( D i r e c t S c a l e ) : 2500 Lbs./47 I n . - L b s . F o r m u l a t i o n F-815 S y n t h e t i c Formula C l e a r product designed f o r f e r r o u s g r i n d i n g . Ingredients: Monalube 210 Mona1ube 1 1 0 Water

15.0

40.0 45.0

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C1 e a r Sol u t i on Performance Data (5% i n W a t e r ) : Appearance: C1 e a r L i q u i d pH: 7 . 5 F a l e x ( D i r e c t S c a l e ) : 2 5 0 0 Lbs./45 N o t e : No TEA needed. F o r m u l a t i o n F-816

In.-Lbs.

Excess DEA i n Monalube 110 n e u t r a l i z e s PE.

SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s

Metal Cleaners and Polishes

127

S y n t h e t i c Formula P r o d u c t d e s i gned f o r g r i n d i ng and 1 ig h t m a c h i n i n g

Wt%

Ingredients: Monalube 2 1 0 T r i e t h a n o l a m i n e (99%) Monalube 315 Water

15.0 30.0 10.0 45.0

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties : Appearance: C l e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C1 e a r L i q u i d pH: 8 . 0 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 4 5 I n . - L b s . F o r m u l a t i o n F-817 S y n t h e t i c Formula

Wt%

Inaredients: Monalube 215 T r i e t h a n o l ami ne (99%) A n t i foam Water

16.6

33.3 0.1

50.0

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 5 S u r f a c e T e n s i o n : 42 bs./44 F a l e x ( D i r e c t S c a l e ) : 2500

In.-Lbs.

P r o d u c t d e s i g n e d f o r machi n ng f e r r o u s and n o n f e r r o u s m e t a l . A l s o some v e r y l i g h t s t a m p i n g . F o r m u l a t i o n F-818

SOURCE: Mona I n d u s t r i e s ,

Inc.:

Suggested F o r m u l a t i o n s

128

Advanced Cleaning Product Formulations

S y n t h e t i c Formula Q 16.6

Ingredients: Monalube 210 Monoethanol ami ne Water

33.3 50.4

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d Performance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 1 1 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1ex ( D i r e c t Scal e ) : 2250 Lbs. /58 I n . - L b s . Formulated f o r g r i n d i n g a p p l i c a t i o n s . F o r m u l a t i o n F-821

Ferrous metals o n l y .

S y n t h e t i c Formula Ingredients: Monalube 205 T r i e t h a n o l a m i n e (99%) A n t i foam Water

16.6

33.3 0.1 50.0

Procedure: Combi ne in g r e d i e n t s w i t h a g i t a t i o n . T y p i c a l P r o p e r t i es : Appearance: C l e a r Amber L i q u i d Performance Data (5% i n W a t e r ) : Appearance: C1 e a r L i q u i d pH: 8 . 3 S u r f a c e T e n s i o n (dynes/cm): 24 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1ex ( D i r e c t S c a l e ) : 2500 Lbs / 5 5 In. -Lbs

.

.

T h i s i s t h e most u n i v e r s a l f o r m u l a s i n c e i t can be used on all m e t a l l u r g y a t 1% t o 2%. I t a l s o can be used f o r g r i n d i n g a t 5% t o 8% f o r m a c h i n i n g and a t 8% t o 15% f o r r e a l heavy m a c h i n i n g . F o r m u l a t i o n F-822

SOURCE:

Mona I n d u s t r i e s ,

Inc.:

Suggested F o r m u l a t i o n s

Metal Cleaners and Polishes

S v n t h e t i c Formul a

Wt%

Inaredi ents: Monalube 205 Monalube 1 1 0 Water

10.0

30.0 60.0

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r S o l u t i o n P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C1 e a r L i q u i d ptl: 8 . 0 S u r f a c e T e n s i o n : 28 C a s t I r o n B l o c k C o r r o s i o n e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2250 Lbs./5O I n . - L b s . F o r use i n m a c h i n i n g and 1 g h t s t a m p i n g f o r f e r r o u s and nonferrous metals. 10 i s enough t o n e u t r a l i z e t h e NOTE: Excess DEA i n Monalube phosphate e s t e r . F o r m u l a t i o n F-823 *thetic

Formula

Ingredients: Monalube 2 0 5 Monoethanol ami ne Water

25.0 25.0 50.0

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH:

10

C a s t I r o n B l o c k : Pass Fa1 ex ( D i r e c t S c a l e ) : 2000 Lbs. /50

I n . -Lbs.

F o r f e r r o u s systems f o r m a c h i n i n g and g r i n d i n g . Formul a t ion F-824

SOURCE: Mona I n d u s t r i e s ,

Inc.:

Suggested F o r m u l a t i o n s

129

130

Advanced Cleaning Product Formulations

Synthetic Formulation Inqredients: Monalube 210 Monalube 225 TEA Water

10.0 10.0 40 0 ~

40.0

Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n . T y p i c a l P r o p e r t i es : Appearance: C l e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C1 e a r L i q u i d pH: 8 . 5 S u r f a c e T e n s i o n ( d y n e s / c m ) : 42 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 4 6 I n - L b s . For machining,

forming, Forrnul a t i on F-807

and s t a m p i n g a l l m e t a l s

S y n t h e t i c Formulat Inqredients: Monalube 225 Monalube 3 1 0 T r i e t h a n o l ami ne (99%) Water

15.0 25.0

30.0 30.0

Procedure: M i x Monalube 225 w i t h t r i e t h a n o l a m i n e and add Monalube 315. M i x u n t i l c l e a r , t h e n add w a t e r . T y p i c a l P r o p e r t i es : Appearance: C l e a r C o n c e n t r a t e P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 6 S u r f a c e T e n s i o n : 41 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2750 Lbs./55 I n . -Lbs F o r heavy d u t y s t a m p i n g o f f e r r o u s m e t a l s a t 1 0 t o 20% i n w a t e r . F o r m u l a t i o n F-808

SOURCE: Mona I n d u s t r i e s ,

I n c . : Suggested F o r m u l a t i o n s

Metal Cleaners and Polishes

Svnthetic Formulation

I n g r e d i en t s : Monalube 2 0 5 Monalube 210 Monalube 220 T r i e t h a n o l a m i n e (99%) Water Procedure: M i x i t e m s 1,

2,

5.0 10.0 10.0 50.0 25.0

3 , and 4 . Then add w a t e r .

Typical Properties: Appearance: C l e a r L i q u i d Performance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 9 . 0 S u r f a c e T e n s i o n : 32 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2750 L b s . / 5 7 I n . - L b s F o r s t a m p i n g , d r a w i n g and b r o a c i n g 10 t o 20% i n w a t e r . Formul a t ion F-809 Synthetic Formulation

wtsl,

Inqredients: Monalube 205 Monalube 225 T r i e t h a n o l a m i n e (99%) Water Procedure: Mix items 1,

2,

3,

5.0 10.0 30.0 55.0

and 4 ,

t h e n add w a t e r and m i x .

Typical Properties: Appearance: C1 e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 7 Surface Tension: 35 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2250 L b s . / 5 1 I n . - L b s . Application: F o r f e r r o u s and n o n f e r r o u s systems f o r and s t a m p i n g . F o r m u l a t i o n F-810

SOURCE: Mona I n d u s t r i e s ,

Inc.:

mach n i ng,

Suggested Formu a t i ons

forming,

131

132

Advanced Cleaning Product Formulations

Synthetic Formulation

Wt%

Inqredients: Monalube 215 Monalube 220 T r i e t h a n o l a m i n e (99%) Water

9.0 9.0 36.0 46.0

Procedure: Combine in g r e d i e n t s w i t h a g i t a t i o n . Typical Properties: Appearance: C l e a r Amber L i q u i d Performance Data (5% i n Water): Appearance: C l e a r L i q u i d pH: 9 . 0 S u r f a c e T e n s i o n : 42 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t S c a l e ) : 2500 Lbs. / 4 7 I n . -Lbs Use i n m a c h i n i n g and s t a m p i n g f o r b o t h f e r r o u s and n o n f e r r o u s metallurgy. F o r m u l a t i o n F-811 Synthetic Formulation Inqredients: Monalube 205 Monalube 220 T r i e t h a n o l a m i n e (99%) Water

5.0 10.0 30.0 55.0

Procedure: Combine in g r e d i e n t s w i t h a g i t a t i o n . T y p i c a l P r o p e r t i es : Appearance: C1 e a r Amber L i q u i d P e r f o r m a n c e D a t a (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 0.7 S u r f a c e T e n s i o n : 35 C a s t I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 L b s . / 3 5 I n . - L b s . For machining, forming, F o r m u l a t i o n F-812

SOURCE: Mona I n d u s t r i e s ,

and s t a m p i n g f o r a1 1 m e t a l 1u r g y Inc.:

Suggested F o r m u l a t i o n s

Metal Cleaners and Polishes

133

U n i v e r s a 1 S c o u r i na P a s t e

WtO/o

Inqredients: A : T y l o s e CBR 10000

5.00 51 . 8 0

5: Water (50C) C:

H o s t a p u r SAS 60 Genapol ZRO 1 iq u i d Genapol U D - 0 3 0 K o m p e r l a n KD NaCl

0:

Preservative,

21.80 10.70 2.00 0.70 0.00

q.s.

Perfume

M a n u f a c k u r i ng: I. A, w h i c h i s added b y c o n t i n u i n g s t i r r i n g , s h o u l d s w e l l , u n t i l a homogeneous g e l f r e e o f lumps h a s been o b t a i n e d I I . Add one a f t e r a n o t h e r , t h e components o f C t o I . 1 1 1 . F i n a l l y D i s added.

Tests : V i s c o s i t y ( B r o o k i e l d RVT,

SOURCE:

sp.

6,

Hoeckst A k t e n g e s e l l s c h a f t :

1 0 m i n -1,

25C):

49b00 mPas

Suggested F o r m u l a t i o n

A1 u m i n u m C 1 e a n e r

Wt%

Comoosi t i o n : K e l z a n x a n t h a n gum Butyl Cellosolve T e r g i t o l NP Phosphoric A c i d (85%) Citric Acid S o d i um D i c h r o m a t e Water

1 .o 4.0 3.0

3.0 4.0 trace 85.0

Procedure: D i s s o l v e K e l z a n x a n t h a n gum i n w a t e r . Add t h e c i t r i c and p h o s p h o r i c a c i d s f o l l o w e d b y 5 u t y l C e l l o s o l v e a n d T e r g i t o l NP. To u s e , s p r e a d e v e n l y on t h e s u r f a c e t o b e c l e a n e d and a l l o w s u f f i c i e n t t i m e f o r t h e c l e a n i n g a c t i o n t o be accomplished.

SOURCE:

Monsanto P e r f o r m a n c e M a t e r i a l s : Formulation

K e l z a n Suggested

134

Advanced Cleaning Product Formulations

Water Sol u b l e Stampi ng F1u i d Ingredients: \nit% M a s l i p 501 Base 30.0 Mazon R I 8 B 12.0 D i e t h a n o l ami ne 8.8 1.2 P r o p y l ene G1 y c o l T r i e t h a n o l a m i n e , 85% 10.0 Water Balance Procedure: Add i n g r e d i e n t s as l i s t e d . I f more l u b r i c i t y i s r e q u i r e d , add Macol 5 1 0 0 . I f more c o r r o s i o n i n h i b i t o r i s r e q u i r e d , add more Mazon R I 8 8. Use 1O:l d i l u t i o n r a t e f o r heavy d u t y a p p l i c a t i o n . WD-40 Type L u b r i c a n t C o n c e n t r a t e I nq r e d ien t s : S-Maz 8 0 Mazawet 7 7 H i t e c E-515 ( E t h y l ) Palmetic Acid S h e l l f l e x 213 S h e l l Sol 135 Procedure: Add i n g r e d i e n t s as l i s t e d .

W 3.7 1.Q 5.2 0.7 10.5 70.9

Penetrating O i l I n a r e d ie n t s : Wt% S-Maz 80 2- 6 Mazon R I 6 7-1 2 M a s i l SF-10 0- 1 0- 1 Nekal WT-27 Gafac RE-40 0- 1 0- 6 I n d o p o l H-100 Odor1 ess M i n e r a S p i r i t s 11ance Procedure: Add i n g r e d i e n t s as l i s t e d . NOTE: A p o r t i o n o f t h e m i n e r a l s p i r i t s may be d e l e t e d and s u b s t i t u t e d w i t h a n a p h t h e n i c o i l ( 5 - 1 5%). B u r n i s h i n s Compound Ingredients: Mazamide 65 Mafo 1 3 MOD 1 Mazon R I 4 A T r i s o d i um Phosphate EDTA Water Procedure: Add i n g r e d i e n t s as l i s t e d .

SOURCE:

PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s

Wt% 10.0 7.0 5.0 7.0 1 .o 70.0

10. Oven, Grill and Hot Plate Cleaners

136

Advanced Cleaning Product Formulations

C a u s t i c Oven C l e a n e r Inaredients: A : Van Gel C, 4 . 8 % Aqueous D i s p e r s i o n Dei o n i zed Water B: Sodium H y d r o x i d e ,

C:

50% S o l u t i o n

Butyl Carbitol Aminomethyl P r o p a n o l (AMP-95) Sodium Cocoamphoacetate ( M o n a t e r i c CM-36s)

D . Sodium H y d r o x i d e ,

50% S o l u t i o n

Wt%* 62.50 45.75 5.00

'10.00 1.50 0.25 5.00

Procedure: 1 . Make t h e 4.8% Van Gel C d i s p e r s i o n b y s l o w l y a d d i n g 4 . 8 p a r t s b y w e i g h t o f Van Gel C i n t o 9 5 . 2 p a r t s b y w e i g h t o f w a t e r o f a t room t e m p e r a t u r e , w h i l e m i x i n g w i t h a homogenizer a t 5000 rpm. C o n t i n u e m i x i n g f o r 60 m i n u t e s . Add t h e r e m a i n i n g P a r t A w a t e r t o t h e i n d i c a t e d amount o f d i s p e r s i o n and m i x u n t i l uniform. 2 . S l o w l y add P a r t B and a d j u s t homogenizer speed as r e q u i r e d t o a c h i e v e good m i x i n g o f e n t i r e b a t c h . 3 . Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g each u n t i l u n i f o r m . A v o i d e n t r a p m e n t o f a i r and g e n e r a t i o n o f foam. 4. S l o w l y add P a r t D and m i x u n t i l u n i f o r m . F o r m u l a t i o n N o . 461 N o n - C a u s t i c Oven C l e a n e r

Wt%*

Inqredi ents: A : Water Van Gel C, Magnesium Aluminum S i l i c a t e Rhodopol 50MD, Xanthan Gum

55.00 0.75 0.25

6 : D i e t h a n o l ami n e Triethanolamine T r i p r o p y l e n e g l y c o l M e t h y l E t h e r (Dowanol TPM) P o t a s s i u m C a r b o n a t e , 25% Aqueous S o l u t i o n Vanseal NACS-30, Sodium L a u r o y l S a r c o s i n a t e

5.00 5.00 5.00 28.00 1.oo

Procedure: 1 . D r y b l e n d t h e Van Gel C and Rhodopol 50MD and add t h e m i x t u r e t o t h e w a t e r w h i l e s t i r r i n g w i t h a homogenizer o p e r a t i n g a t 5000 r p m . C o n t i n u e m i x i n g f o r 30 m i n u t e s . 2 . S l o w l y add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r shown. M i x each f o r 5 m i n u t e s . Package. F o r m u l a t i o n No. 468 *As r e c e i v e d b a s i s SOURCE: R.T.

V a n d e r b i l t Co.,

I n c . : Suggested F o r m u l a t i o n s

Oven, Grill and Hot Plate Cleaners

137

H i g h C a u s t i c Oven C l e a n e r

Carbopol r e s i n s a r e used t o t h i c k e n t h i s h i g h c a u s t i c f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p r o v i d e s v e r t i c a l c l i n g t o i n c r e a s e t h e c o n t a c t t i m e o f t h e d e t e r g e n t on t h e s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e . Inaredient: D I Water Carbopol 674 ( 1 ) Potassium h y d r o x i d e (45%) Propylene g l y c o l methyl e t h e r ( 2 ) C8-16 a l k y l p o l y g l y c o s i d e (50%) ( 3 ) B r o o k f i e l d v i s c o s i t y (RVT-20

Wei Qht P e r c e n t 71.03 69.78 2.00 0.75 22.22 22.22 3.00 3.00 3.00 3.00

rpm) :

250 CPS 13-14 Clear

Product pH: Product c l a r i t y :

5,000 CPS 13-14 Clear

8FGoodrich ( 2 ) Dow Chemical : Dowanol PM ( 3 ) Henkel C o r p . : Glucopon 425CS (1)

Procedure: 1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e DI w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2 . Add t h e p o t a s s i u m h y d r o x i d e w i t h c o n t i n u o u s m i x i n g . 3 . Add t h e g l y c o l e t h e r . 4 . Add t h e APG s u r f a c t a n t . M i x u n t i l homogeneous. 5. Add f r a g r a n c e , as d e s i r e d . Total Actives: Potassium h y d r o x i d e : 10.00 P r o p y l e n e g l y c o l m e t h y l e t h e r : 3.00 C8-16 a l k y l p o l y g l y c o s i d e : 1.50 FGoodrich S p e c i a l t y Chemicals:

OET-360

138

Advanced Cleaning Product Formulations

Oven C l e a n e r Ingredients: A : Veegum T, Magnesium Aluminum S i l i c a t e Rhodopol 23, Xanthan Gum D e i o n i z e d Water B:

Sodium H y d r o x i d e , 50% Deceth-4 Phosphate (Rhodafac RA-600)

VVt%* 0.40 1.20 80.40

8.00 10.00

Procedure: 1 . Weigh t h e w a t e r , h e a t i t t o 85-9OC and m i x w i t h an homogenizer a t 5000 rpm. 2 . D r y b l e n d t h e Veegum T and Rhodopol 23 and s l o w l y add them t o t h e w a t e r . C o n t i n u e m i x i n g f o r 20 m i n u t e s . 3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o p r o d u c e a s m a l l v o r t e x . Cool t o 55C. 4 . Add t h e P a r t B i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g f o r 5 m i n u t e s a f t e r each a d d i t i o n . NOTE: I t i s p a r t i c u l a r l y i m p o r t a n t t h a t t h e Sodium H y d r o x i d e s o l u t i o n be added v e r y s l o w l y w i t h good m i x i n g o f t h e e n t i r e batch. F o r m u l a t i o n f r o m Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s A e r o s o l Oven C1 e a n e r Ingredients: A : Veegum T, Magnesium Aluminum S i l i c a t e Dei o n i zed Water

.

W t %* 1 .50 74.25

8 : n-Methyl

P y r r o l i d o n e (M-Pyrol) 20.00 D i s o d i u m C o c o a m p h o d i p r o p i o n a t e ( M i r a n o l C2M-SF C o n c . ) 3.25 Nonoxynol ( I g e p a l CO-630) 1 .oo

Procedure: 1 . Weigh w a t e r and p l a c e on h o m o g e n i z e r . 2 . D i s p e r s e t h e Veegum T i n t h e w a t e r u s i n g a homogenizer a t 5000 r p m . C o n t i n u e m i x i n g for 20 m i n u t e s , w h i l e h e a t i n g t o 70C. 3 . Combine t h e i n g r e d i e n t s o f P a r t 8 , h e a t t o 70C. 4 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o provide a s l i g h t vortex. 5 . Add P a r t B t o P a r t A and c o o l w h i l e m i x i n g t o 30C. 6 . Package i n a e r o s o l can u s i n g Propane/Butane p r o p e l l a n t . Formulation from I n t e r n a t i o n a l S p e c i a l t y Products. *As r e c e i v e d b a s i s

SOURCE:

R.T. V a n d e r b i l t Co.,

Inc.:

Suggested F o r m u l a t i o n s

Oven, Grill and Hot Plate Cleaners

139

Oven C l e a n e r Composition: K e l z a n x a n t h a n gum T r i s o d i um Phosphate Sodi urn m e t a s i 1 ic a t e S u l f o n a t e OA5 B r i j 96 S i 1 icone 2 0 0 F l u i d 3 5 0 c s Hexane Water

0.1 3.2 1.l 2.1 3.2 4.0 4.2 82.1

Procedure: P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum as b e f o r e and add n e x t t h r e e i n g r e d i e n t s . M i x t h e B r i j 96, S i l i c o n e and hexane s e p a r a t e l y . Then add w a t e r s o l u t i o n t o t h e s i l i c o n e / h e x a n e m i x w i t h c o n s t a n t a g i t a t i o n . F o r a e r o s o l u s e c h a r g e w i t h 90% conce n t r a t e and 10% G e n e t r o n 1 2 . Heavy D u t y Oven C l e a n e r Compos i t i on : Kelzan xanthan gum A n t a r o n FC-34 Sodi um h y d r o x i d e Water

Wt% 0.3 2.0

10.0 87.0

Procedure: P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum t h e n add A n t a r o n . S e p a r a t e l y , p r e p a r e t h e 40% sodium h y d o x i d e s o l u t i o n and s l o w l y add t o m i x . F o r a e r o s o l use c h a r g e w i t h 80% m i x t u r e and 20% o f 1 : l m i x o f G e n e t r o n 1 2 and 1 1 4 .

SOURCE:

Monsanto P e r f o r m a n c e M a t e r i a l s : T e c h n i c a l B u l l e t i n 1 - 2 0 : K e l zan Formul a t i ons

140

Advanced Cleaning Product Formulatioris

Oven C 1 e a n e r w / A m p h o t e r i c

\Mt96

Ingredients: Water, D . I . Sodi urn C i t r a t e Sodi um M e t a s i 1 ic a t e Sodium H y d r o x i d e , 40% Monoethanol ami ne Dowanol PM R e w o t e r i c AM HC W i t c o 1298SA DeSonic 9 N

71 . 6 2.1 4.2 6.5 4.2 3.1 3.1

3.1 2.1

Blending Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i on. Typical Properties: V i s c o s i t y , c p s : 96 pH: 1 3 . 9 F o r m u l a 1114 Oven

C l e a n e r w/Phosphate

Ingredient s : Phase I : Water, D . I . C a r b o p o l 940 Phase 11: Water, D . I . P o t a s s i u m H y d r o x i d e , 87% Tetrapotassium Pyrophosphate Phase 111: R e w o t e r i c AM HC

71 . 4 1.3 15.4 2.4 3.6

5.9

Blending Procedure: Combine Phase I i n g r e d i e n t s and m i x u n t i l homogeneous. Combine Phase I1 i n g r e d i e n t s i n s e p a r a t e v e s s e l and m i x t h o r o u g h l y . W h i l e m i x i n g , p o u r Phase I1 i n t o Phase I . M i x t h o r o u g h l y t h e n add Phase 1 1 . Formula 1115

SOURCE: W i t c o C o r p . :

Suggested F o r m u l a t i o n s

dishes, Coatings and Finishes

141

142

Advanced Cleaning Product Formulations

F u r n i t u r e P o l i sh I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y suspended. The r e s i n a1 so p r e v e n t s "creaming" o r phase separa t i o n b y suspending and s e p a r a t i n g t h e o i l d r o p l e t s . Inqredient: P a r t A: D I Water Carbopol EZ-2 TEA

wp9b

91.10 0.20 0.20

(1)

P a r t B: C a r d i s 36 Wax ( 2 ) Hoechst Wax S ( 3 ) Oleic Acid Morphol i ne D I Water

0.25 0.25 0.08 0.10 1.82

Part C: SM2133 S i l i c o n e Emulsion ( 4 ) SM2135 S i l i c o n e Emulsion ( 4 ) Physical Properties: B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): Product pH: 7.00 Product C l a r i t y : P o l i s h

4.00

2.00

9,500 cps

Raw M a t e r i a l S u p p l i e r s : ( 1 ) BF G o o d r i c h ( 2 ) P e t r o l i t e S p e c i a l t y Polymers ( 3 ) Hoechst Celanese ( 4 ) General E l e c t r i c Procedure: 1 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r b y s i m p l y "dumping" i t i n . The p o l y m e r w i l l wet o u t i n a few m i n u t e s . 2. Add t h e TEA. M i x u n t i l homogeneous. 3. P r e p a r e P a r t B. Add t h e C a r d i s Wax, Hoechst Wax S, and o l e i c a c i d t o a vessel. With m i l d s t i r r i n g , b r i n g t h e temperature up t o 96-IOOC. When m e l t e d , add t h e m o r p h o l i n e u n t i l t h e m i x t u r e i s homogeneous. Add t h e w a t e r a t 95C. C o n t i n u e s t i r r i n g u n t i l t h e t e m p e r a t u r e reaches 45C. Cool t o room temperature. 4. Add P a r t B. 5. Add i n t h e s i l i c o n e e m u l s i o n s w i t h m i l d m i x i n g . Total Actives: 0.50 T o t a l Wax : T o t a l S i l i c o n e : 6.00

SOURCE:

BFGoodrich S p e c i a l t y Chemicals:

DET-530

Polishes, Coatings and Finishes

Leather/Plastic

143

Polish

I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y suspended. The r e s i n a1 so p r e v e n t s "creami ng" o r phase s e p a r a t i o n b y suspending and s e p a r a t i n g t h e o i l d r o p l e t s .

Wt%

I n q r e d ie n t :

50.00 2.00

DI Water Renex 20 ( 1 ) Morphol ine SF96 S i l i c o n e F l u i d ( 3 5 0 ) Oleic Acid Mineral S p i r i t s 01 Water Carbopol EZ-2 ( 3 )

1.oo

5.00 2.00 20.00 19.60

(2)

Physical Properties: B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): P r o d u c t pH: 8 . 5 P r o d u c t C l a r i t y : Opaque

0.40

3,200 c p s

Raw M a t e r i a l S u p p l i e r s : (1) I C I Surfactants ( 2 ) General E l e c t r i c ( 3 ) BFGoodrich Procedure: 1 . D i s s o l v e t h e Renex 2 0 and m o r p h o l i n e i n t h e w a t e r w i t h m i l d agitation. 2 . D i s s o l v e t h e s i l i c o n e f l u i d and t h e o l e i c a c i d i n t h e m i n e r a l s p i r i t s . Add t o t h e above m i x t u r e w i t h good a g i t a t i o n . 3 . I n a s e p a r a t e v e s s e l , d i s p e r s e 0 . 4 0 p a r t s o f Carbopol i n t o 49.60 p a r t s o f w a t e r b y s i m p l y "dumping" t h e p o l y m e r i n t o t h e w a t e r . I n j u s t a few m i n u t e s , t h e polymer w i l l c o m p l e t e l y wet o u t . Add t h i s d i s p e r s i o n t o t h e above m i x t u r e . 4 . M i x u n t i l homogeneous.

Total A c t i wes: Silicone Fluid: Mineral S p i r i t s :

5.00 20.00

SOURCE: BFGoodrich S p e c i a l t y Chemicals:

DET-540

144

Advanced Cleaning Product Formulations

M a r b l e P o l ish I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y suspended. The r e s i n a1 so p r e v e n t s "creami ng" o r phase s e p a r a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s . Ingredient: we% D I Water 74.80 0.20 Carbopol EZ-2 ( 1 ) Mineral S p i r i t s 15.00 I g e p a l 630 ( 2 ) 3.70 Diatomaceous e a r t h ( 3 ) 8.00 T r i e t h a n o l ami ne 0.30 Physical Properties: B r o o k f ie l d V i s c o s i t y (RVT-20 rpm) : 1 I , 700 cp P r o d u c t pH: 7 . 5 0 P r o d u c t C l a r i t y : Opaque Raw M a t e r i a l S u p p l i e r s : ( 1 ) BFGoodrich ( 2 ) Rhone-Poul enc (3) Kaopolite Procedure: 1 . D i s p e r s e t h e Carbopol i n t h e w a t e r b y s i m p l y "dumping" i t i n . The polymer w i l l wet o u t i n a few m i n u t e s . Add t h e s u r f a c t a n t w h i l e m i x i n g under moderate a g i t a t i o n . 2 . Add t h e m i n e r a l s p i r i t s . M i x u n t i l t h e e m u l s i o n becomes homogeneous. 3 . Add t h e TEA. M i x u n t i l smooth. 4 . Add t h e diatomaceous e a r t h . Mix u n t i l homogeneous. DET-552 Rust Removing P o l i s h Carbopol r e s i n s a r e used i n t h i s f o r m u l a t o t h i c k e n t h e g l u c o n i c a c i d t o e n a b l e improved a p p l i c a t i o n e f f i c a c y . The p o l y m e r w i l l a l s o i m p a r t v e r t i c a l c l i n g t o e n a b l e a p p l i c a t i o n s on v e r t i c a l o r angled surfaces. I n q r e d ie n t : Wt% D I Water 44.64 1-79 Carbopol €2-2 ( 1 ) Sodium h y d r o x i d e (50%) 35.71 G l u c o n i c a c i d s o l u t i o n (50%) ( 2 ) 17.86 Physical Properties: B r o o k f i e l d V i s c o s i t y (RVT-20 r p m ) : 3,000 c p P r o d u c t p H : 13.90 Product C l a r i t y : T r a n s l u c e n t Procedure: 1 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r . 2. A d d t h e sodium h y d r o x i d e w i t h a g i t a t i o n . T h i c k e n i n g will o c c u r immedi a t e l y 3 . Add t h e g l u c o n i c a c i d s o l u t i o n . M i x u n t i l homogeneous. DET-560

.

SOURCE: BFGoodrich S p e c i a l t y Chemicals:

Suggested Formulations

Polishes, Coatings and Finishes

145

S c r a t c h e d Wood P o l i s h

Wt%

A:

Ingredients: Veegum T, Magnesium Aluminum S i l i c a t e Dei o n i zed Water

1.50 31.25

B: S t e a r i c A c i d Carnauba Wax Beeswax, Ye1 1ow

4.50 16.50 16.50

C:

T r i e t h a n o l ami ne, M i n e r a l Spi r it s

D:

P r e s e r v a t i v e , Dye,

2.75 27.00

99%

Fragrance

q.s

Procedure: 1 . Weigh t h e w a t e r and m i x w i t h a p r o p e l l e r m i x e r a t 1800 rpm. 2 . S l o w l y add t h e Veegum T and m i x f o r 20 m i n u t e s w h i l e h e a t i n g t o 9OC. 3 . Combine t h e P a r t B i n g r e d i e n t s and h e a t t o 9OC. 4 . Add t h e P a r t C i n g r e d i e n t s t o t h e P a r t B m i x t u r e i n t h e o r d e r shown, m i x i n g each f o r 10 m i n u t e s . 5 . Add P a r t B+C t o P a r t A and m i x f o r 10 m i n u t e s . 6 . Cool t h e b a t c h t o 35C, add P a r t D, and m i x u n t i l u n i f o r m . *As r e c e i v e d b a s i s

SOURCE:

R.T.

V a n d e r b i l t Co., H i qh

Inc.:

F o r m u l a t i o n No. 2 1 0

Gloss, D e t e r q e n t R e s i s t a n t P o l ish

A wax-free p o l i s h , which provides a high-gloss, detergent r e s i s t a n t f i n i s h on non-porous s u b s t r a t e s . S i m p l e a p p l i c a t i o n , w i t h o u t hard r u b b i n g o r b u f f i n g , r e s u l t s i n b o t h d e p t h o f g l o s s and d e t e r g e n t r e s i s t a n c e f o r e x t e n d e d p r o t e c t i o n .

Ingredients: ( 1 ) GP-121 S i l i c o n e P o l i s h A d d i t i v e ( 2 ) GP-RA-159 S i l i c o n e P o l i s h A d d i t i v e ( 3 ) Stoddard Solvent ( 4 ) Mineral S p i r i t s (Odorless) ( 5 ) GP-227 S i l i c o n e S u r f a c t a n t S o l u t i o n ( 6 ) K a o p o l i t e SF ( 7 ) S o f t Water ( 8 ) Bactericide

Wt% 9.0 1.5 3.5 3.5 9.0 3.4 70.0 0.1

Combine i n o r d e r shown w i t h h i g h s h e a r m i x i n g u n t i l t h i c k e n i n g o c c u r s . M i x u n t i l homogeneous and package. Formulation Properties: C o n t a i n s no wax High g l o s s Detergent r e s i s t a n t E a s i 1 y a p p l ied SQURCE: Genesee P o l y m e r s C o r p . :

Non-smeari ng Cost e f f i c i e n t Cold b l e n d (Only m i x i n g r e q u i r e d ) Resistant t o wash-off Formula 20-12

12. Rinse Aids

146

Rinse Aids

R i nse A i d ,

Inqredients: Water, D . I . P e t r o 22 Powder DeSoni c LFD-97 Hydroxyacetic Acid,

Acid

Wt9/o 50.0

5.0 35.0 10.0

70%

Blending Procedure: 51 end i n g r e d i e n t s in t h e o r d e r 1 is t e d . Typical Properties: S p e c i f i c G r a v i t y : 1.105 Wt/Gal, l b s : 9 . 2 1 V i s c o s i t y , c p s : 85 C l o u d P o i n t , C : 59 S o l i d s , %: 4 0 Formula 131

R i nse A i d

Ingredients: Water, D . I . P e t r o 22 Powder DeSoni c LFD-97 Typical Properties: S p e c i f i c G r a v i t y : 1.029 Wt/Gal. l b s : 8 . 5 8 pH, as i s : 6 . 4 V i s c o s i t y , c p s : 80 C l o u d P o i n t , C : 68 S o l i d s : 40% Formula 130 SOURCE; W i t c o C o r p . : Suggested Formul a t ions

Wt% 60.0 5.0 35.0

147

13. Rug, Floor, Carpet,

Upholstery Shampoos an

148

Rug, Floor, Carpet, Upholstery Shampoos and Cleaners

149

C a r p e t C1 e a n e r

I n qr e d i e n t s : Water T r i s o d i urn Phosphate Tetrapotassium Pyrophosphate P l u r a f a c D-25 A1 ip a l CO-436 Mazawet 7 7 EDTA ( T e t r a s o d i u m S a l t ) T i n o p a l 5 BM

wt%

56.0 15.0 10.0 7.0 10.0 1.25 0.5 0.25

Procedure: Add i n g r e d i e n t s as l i s t e d .

Low Foam C a r p e t Shampoo Ingredients: Macol 2LF Ethylene Glycol Methyl Ether Sodi urn T r i p o l y p h o s p h a t e Sodi urn X y l ene S u l f o n a t e Mazu DF 210 SX Water ( s o f t )

Wt% 6.0 10.0 1. o 1 .o 0.5 81 . 5

Procedure: Add i n g r e d i e n t s as l i s t e d . Steam Rua C l e a n e r - A

w a

Ingredients: Macol OP 1 0 SP Sodium S i l i c a t e Sodi urn X y l ene S u l f o n a t e Water

5.0 10.0 5.0 80.0

Procedure: Add i n g r e d i e n t s as l i s t e d . S t e a m Rug C l e a n e r - 8

Wt%

Inqredients: Macol OP 1 0 SP Sodi um S i 1 ic a t e Sodium X y l e n e S u l f o n a t e Water

3.0 10.0 3.0 84.0

Procedure: Add i n g r e d i e n t s as l i s t e d SOURCE: PPG I n d u s t r i e s ,

I n c . : Suggested F o r m u l a t i o n s

150

Advanced Cleaning Product Formulations

Carpet Cleaners f o r t h e Spray-Extraction Process W S 1.o

Inqredients: C u b l e n 0 50 Tetrapotassium pyrophosphate P r o p e t a l 241 P r o p e t a l 281 S u l f e t a l 4105 Isopropanol Water F o r m u l a CT 02-08-01

5.0 2.0 3.0 4.0 4.0 81 . o

Wt%

Ingredients: Water Soap S u l f e t a l 4105 P r o p e t a l 99 Cont raspum 3 0 0 U b a t o l TR 1138 Isopropanol F o r m u l a C T 02-08-02

75.0

1 .o

5.0 5.0 1. o 3.0 10.0

SOURCE: Zschimmer & Schwarz GmbH & C o . : G e n e r a l F o r m u l a t i o n s C a r p e t Shampoo Liquid, transparent Ingredients: A : Hostapur 0s l i q u i d M e d i a l a n KA c o n c .

wtu/, 25.00 3.00

B: W a t e r ,

72.00

Preservative

Manu f a c t u r i ng : One a f t e r a n o t h e r ,

t h e components o f A a r e added t o 8 .

SOURCE: Hoechst A k t i e n g e s e l l s c h a f t :

Suggested F o r m u l a t i o n

Rug, Floor, Carpet, Upholstery Shampoos and Cleaners

C a r p e t Shampoo L i quid)

I Phosphate,

S o i l - F o o d ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , and p a r t i c u l a t e S u r f a c e - P o l y e s t e r and n y l o n A p p l i c a t i o n Method-Rug s c r u b b e r Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i on : Water *TSP *STPP K a s i 1 # 6 P o t a s s i um S i 1 ic a t e **Phosphate E s t e r ***Sodi um A1 k y l naphtha1 ene S u l f o n a t e ****Octylphenoxy P o l y e t h o x y e t h a n o l , 7 - 8 M o l e s EO

clay

Wt% 62.5 2.0 5.0 20.0 3.0 3.5 4.0

Use D i l u t i o n : 0 . 8 - 1 . 5 % bw ( 1 - 2 o z / g a l l o n )

*

** *** ****

FMC Rhone-Poulenc Rhodafac RE-610 DeSoto Rhone-Poulenc I g e p a l CA-620 RUQ Steam C l e a n e r

S o i 1 -Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , and p a r t i c u l a t e S u r f a c e - P o l y e s t e r and n y l o n A p p l i c a t i o n Method-Rug s c r u b b e r Manufacture-Mix t a n k w i t h p r o p e l l e r s t r r e r Composi t i on : Water Wetso Beads 2048 Sodi um X y l ene S u l f o n a t e , 40% * M i r a n o l JEM C o n c e n t r a t e (34%) Use D i l u t i o n : 4 . 7 - 9 . 4 % b w ( 6 - 1 2 o z / g a l l o n ) *Rhone-Poul enc;

o r She1 1 Chemical Neodol 25-1 2

SOURCE: PQ C o r p . :

Detergent F o r m u l a t i o n Guide

clay

84.0 5.0 6.0 5.0

151

152

Advanced Cleaning Product Formulations

C a r p e t Shampoo,

H i s h Foam

WtS/o

I n Q r e d ie n t s : Water P e t r o BAF L i q u i d W i t c o l a t e WAC-LA

78.3 5.0 16.7

B1 e n d i n g P r o c e d u r e : B1 end in g r e d i e n t s i n t h e o r d e r 1 is t e d . P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , r e d u c e s t h e low temperature cloud p o i n t , g i v i n g e x c e l l e n t freeze/thaw p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n sodium l a u r y l s u l f a t e a l o n e . F o r m u l a 908 C a r p e t Shampoo, H i g h Foam

Wt%

Inqredients: Water P e t r o BAF L i q u i d W i t c o l a t e WAC-LA

71.1 6.7 22.2

B l e n d i n g P r o c e d u r e : B 2nd i n g r e d i e n t s i n t h e o r d e r Use L e v e l :

is

I

1 t o 2 ounces p e r g a l l o n .

Comments : P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , r e d u c e s t h e low t e m p e r a t u r e c l o u d p o i n t , g i v i n g e x c e l l e n t f r e e z e / t h a w p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n sodium l a u r y l s u l f a t e a l o n e . F o r m u l a 910 C a r p e t S p o t Remover

Wt%

Inqredients: Water, 13.1. W i t c o l a t e WAC-LA P e t r o BA L i q u i d G l y c o l E t h e r DPM G l y c o l E t h e r PM FC-129 ( 1 % S o l i d s ) Blending Procedure:

90.3 3.3 0.5 3.5 2.3 0.1 Blend ingredients i n t h e order l i s t e d .

Typical Properties: S p e c i f i c G r a v i t y : 0.999 Wt./Gal. l b s . : 8.33 pH: 1 0 . 3 5 Use D i l u t i o n : Use as i s F o r m u l a 945 SOURCE: W i t c o C o r p . : S u g g e s t e d F o r m u l a t i o n s

Rug, Floor, Carpet, Upholstery Shampoos and Cleaners

153

Carpet 8 U p h o l s t e r y Cleaner T h i s o e n e r a l Duroose s t a i n remover f o r m u l a t i o n is o a r t i c u l a r l v e f f e c t i v e i n removing o i l s t a i n s . Ingredient : Wt% D e i o n i z e d Water ( h o t ) 37.0 SMA-2625 R e s i n 2.4 Aqua Ammonia 0.7 W i t c o l a t e WACLA 18.0 W i t c o n a t e 60T L i q u i d 4.0 Avanel 5-70 4.0 Dei o n i zed Water 34.0 Dye, Fragrance, e t c . (2.5. pH ( a s i s ) : 8.0-9.0 Appearance: C l e a r l i q u i d S p e c i f i c G r a v i t y : 1.016 Procedure: 1 . Charge t h e h o t w a t e r t o a m i x i n g v e s s e l and s t a r t a g i t a t i o n . S l o w l y s i f t i n t h e SMA-2625 R e s i n t o a v o i d c l u m p i n g . Add t h e Aqua Ammonia, a p p l y c o o l i n g , and mix w e l l u n t i l t h e r e s i n i s dissolved. 2 . Reduce a g i t a t i o n and add t h e r e m a i n i n g i n g r e d i e n t s . S t o p a g i t a t i o n t o permit deaeration o f t h e product p r i o r t o filling off. 3 . I f t h i s p r o d u c t i s t o be c o l o r e d , a p o r t i o n o f t h e f i n a l w a t e r s h o u l d be r e s e r v e d f o r d i s s o l v i n g t h e dye. A f t e r t h e dye is t h o r o u g h l y mixed, t h e dye s o l u t i o n may be added NOTE: Use " a s i s " on c a r p e t i n g . D i l u t e 1 O : l and 5 : l w i t h water f o r u pholstery. V i n y l Dressing ( 8 ) Ingredient: Wt% Part A: M a s i l EM 250 C 18.0 M a s i l EM 10,000 C 10.0 Dei o n i zed Water 30.0 P a r t B: Macol OP-10 SP 2.0 G1 y c e r i ne 1.o D e i o n i r e d Water 38.0 Sodium Benzoate 1.o Procedure: 1 . To a m i x i n g v e s s e l , c h a r g e t h e M a s i l EM 250 C and M a s i l EM 10,000 C . S t a r t g e n t l e a g i t a t i o n . S l o w l y add t h e w a t e r so as n o t t o b r e a k t h e e m u l s i o n . 2. I n a s e p a r a t e m i x i n g v e s s e l , c h a r g e t h e Macol OP-10 SP and g l y c e r i n e t o t h e water. Mix w i t h g e n t l e a g i t a t i o n u n t i l a l l components a r e d i s s o l v e d , and t h e s o l u t i o n i s f r e e o f " f i s h e y e s " . Charge t h e sodium b e n z o a t e and m i x u n t i l d i s s o l v e d . 3 . Under g e n t l e a g i t a t i o n , add P a r t 0 t o P a r t A. C o n t i n u e m i x i n g g e n t l y t o a v o i d a i r e n t r a p m e n t . NOTE: T h i s f o r m u l a i s d e s i g n e d to b e used "as i s " . I f d e s i r e d , UV a b s o r b e r s and o t h e r compone n t s may be added t o t h e f o r m u l a t i o n . SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s

154

Advanced Cleaning Product Formulations

Carpet & Upholstery Cleaner Ingredients: Dei o n i zed Water ( H o t ) SMA-2625 R e s i n Aqua Ammonia Sodi u m L a u r y l S u l f a t e R i chami de 5725 Avanel 5-70 Dei o n i zed Water Dye, F r a g r a n c e , E t c .

Wt% 37.0 2.37 0.67 18.0 4.0 4.0 33.96 As d e s i r e d

pH (as i s ) : 8.0-9.0 Appearance: C l e a r l i q u i d S p e c i f i c G r a v i t y : 1 .016

Procedure: Charge t h e h o t w a t e r t o t h e m i x i n g v e s s e l and s t a r t a g i t a t i o n . S l o w l y s i f t i n t h e SMA-2625 r e s i n t o a v o i d c l u m p i n g . Add t h e Aqua Ammonia, a p p l y c o o l i n g and m i x w e l l u n t i l t h e r e s i n i s d i s s o l v e d . Reduce a g i t a t i o n and add t h e r e m a i n i n g i n g r e d i e n t s . I f t h e p r o d u c t i s t o be c o l o r e d , a p o r t i o n o f t h e f i n a l water s h o u l d b e r e s e r v e d f o r d i s s o l v i n g t h e d y e . A f t e r t h e dye i s t h o r o u g h l y m i x e d , t h e d y e s o l u t i o n may b e added t o t h e p r o d u c t . Stop a g i t a t i o n t o p e r m i t deaeration o f t h e product p r i o r t o filling off. Notes : T h i s i s a g e n e r a l p u r p o s e o i l y s t a i n remover. T h i s f o r m u l a t i o n i s p a r t i c u l a r l y e f f e c t i v e a t r e m o v i n g o i l s t a i n s . Use a s - i s on c a r p e t i n g . D i l u t e 1 O : l and 5 : l w i t h w a t e r f o r u p h o l s t e r y . N o t e : The dye s h o u l d b e t h o r o u g l y s c r e e n e d t o a v o i d f a b r i c staining. F o r m u l a t i o n CP-101 L i q u i d Steam C a r p e t C 1 e a n e r F o r H a r d Water Systems Ingredients: Sodium M e t a s i 1 i c a t e A Tetrapotassium Pyrophosphate Emphos PS-331 Macol NP 11 D e i o n i z e d Water Procedure: Add i n g r e d i e n t s as l i s t e d .

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s

Wt% 7.5 12.5 4.0 1.o 76.0

Rug, Floor, Carpet, Upholstery Shampoos and Cleaners

155

F1oor C l e a n e r

wtsl, 8.0

Ingredients: M a z a m i de 1281

2.0 2.0 88.0

Sodi urn T r i p o l y p h o s p h a t e T e t r a p o t a s s i u m Pyrophosphate Water Procedure: Add i n g r e d i e n t s as l i s t e d . L i q u i d F l o o r Cleaner Ingredients: Macol NP 9 . 5 Sodi urn T r i p o l yphosphate T r i s o d i urn Phosphate Sodi urn M e t a s i 1i c a t e P e n t a h y d r a t e Maphos 60A Water

Q 7.0 8.0 2.0 2.0 3.0 78.0

Procedure: A d d i n g r e d i e n t s as l i s t e d . NOTE: T h i s f o r m u l a t i o n i s s t a b l e t o 120F. F l o o r Scrubber Ingredients: Sodi urn M e t a s i 1 ic a t e Tetrasodium Pyrophosphate Emphos PS-331 D e i o n i z e d Water Mazami de 1281 Sodium H y d r o x i d e , 50%

2.0 18.0 15.0 53.95 6.0 5.05

Procedure : Add i n g r e d i e n t s as l i s t e d .

SOURCE:

PPG I n d u s t r i e s ,

Inc.:

Suggested F o r m u l a t i o n s

156

Advanced Cleaning Product Formulations

Household Carpet F r e s h e n e r / A n t i s t a t

Wt%

InQredients: P a r t A: P u f f e d Borax ( 1 0 l b s / c u f t ) Fragrance Sodi um B i c a r b o n a t e L a r o s t a t 519

1.8 0.2 15.0 3.0

P a r t 6: Sodi um B i c a r b o n a t e

80.0

Procedure: I n a r i b b o n m i x e r o r V - b l e n d e r , c h a r g e t h e p u f f e d b o r a x and f i r s t p o r t i o n o f sodium b i c a r b o n a t e . S t a r t m i x i n g and s l o w l y add t h e f r a g r a n c e . A f t e r a l l o f t h e f r a g r a n c e has been added, c o n t i n u e m i x i n g f o r 5 m i n u t e s t o c o m p l e t e a b s o r p t i o n . Add t h e L a r o s t a t 519 and t h e r e m a i n i n g sodium b i c a r b o n a t e . M i x f o r 15 m i n u t e s more. Notes : T h i s i s a powdered c o m b i n a t i o n consumer f r e s h e n e r / a n t i s t a t . The p r o d u c t i s d e s i g n e d t o b e shaken o n t o t h e c a r p e t , l i g h t l y r u b b e d i n t o t h e c a r p e t and t h e n t h e e x c e s s removed b y vacuuming. F o r m u l a t i o n SP-I01 Pump S p r a y C a r p e t A n t i s t a t Ingredients: P a r t A: Water Isopropyl Alcohol L a r o s t a t 264 A

94.3 5.0 0.7

Appearance: C l e a r , w a t e r - w h i t e S p e c i f i c G r a v i t y : 0.98

t o pale-yellow l i q u i d

Procedure: To a m i x i n g vessel, charge t h e water, f o l l o w e d by t h e i s o p r o p y l a l c o h o l and L a r o s t a t 88. M i x u n t i l c l e a r . Notes : T h i s i s a n o n - a e r o s o l , pump s p r a y c a r p e t a n t i s t a t f o r t h e removal o f n u i s a n c e s t a t i c . T o remove s t a t i c f r o m c a r p e t i n g and other surfaces, spray l i g h t l y w i t h t h i s formulation. It i s not necessary t o s a t u r a t e t h e surface. I f a d d i t i o n a l p r o t e c t i o n i s needed, i t i s p r e f e r a b l e t o have r e p e a t a p p l i c a t i o n s r a t h e r t h a n one, t o i n s u r e even t r e a t m e n t . F o r m u l a t i o n SP-102

SOURCE: PPG I n d u s t r i e s ,

Inc.:

Suggested F o r m u l a t i o n s

Rug, Floor, Carpet, Upholstery Shampoos and Cleaners

157

h i qlai d L e a t h e r . V i n v l , a n d P l a s t i c C l e a n e r and R e s t o r e r

Wt%

Inqredients: DeSonic 9N Dowanol PM G l y c o l E t h e r Isopropyl Alcohol Amy1 A c e t a t e Water

10.0

5.0 2.5 1.o 81 . 5

Blending Instructions: Combine i n g r e d i e n t s i n t h e o r d e r shown and m i x t h o r o u g h l y .

Use I n s t r u c t i o n s : A p p l y f i n i s h e d p r o d u c t t o a t o w e l o r t o w e l l e t e (Kimwipe, e t c . ) and w i p e o n t o t h e s u r f a c e t o b e c l e a n e d , t h e n r i n s e . A l t e r n a t i v e l y , s p r a y o n t o t h e s u r f a c e t o b e c l e a n e d , a l l o w t o s e t a few m i n u t e s , t h e n r i n s e o r hose o f f . Product I n f o r m a t i o n : Product: DeSonic 9N Dowanol PM G l y c o l E t h e r Amyl A c e t a t e Isopropyl Alcohol Formula 1000 L i q u i d Leather,

Benefit : Detergent and degreaser S o l v e n t and c o u p l i n g a g e n t Solvent Sol vent

Vinyl,

and P l a s t i c C l e a n e r

Wt%

InQredients: W i t c o n o l NP-100 Dowanol PM G l y c o l E t h e r Isopropyl Alcohol Amy1 A c e t a t e Water

10.0 5.0 2.5 1 .o 81.5

Blending Instructions: Combine i n g r e d i e n t s i n t h e o r d e r shown and m i x t h o r o u g h l y .

Use I n s t r u c t i o n s : A p p l y f i n i s h e d p r o d u c t t o a t o w e l o r t o w e l l e t e (Kimwipe, e t c . ) and w i p e o n t o t h e s u r f a c e t o b e c l e a n e d , t h e n r i n s e . A l t e r n a t i v e l y , s p r a y o n t o t h e s u r f a c e t o b e c l e a n e d , a l l o w t o s e t a few m i n u t e s , t h e n r i n s e o r hose o f f . Product I n f o r m a t i o n : W i t c o n o l NP-100 Dowanol PM G l y c o l E t h e r Amyl A c e t a t e I s o p r o p y l A1 coho1 Formula 1001

SOURCE: W i t c o C o r p . :

Benefit : D e t e r g e n t and d e g r e a s e r S o l v e n t and c o u p l i n g a g e n t Sol vent Sol vent

Suggested F o r m u l a t i o n s

158

Advanced Cleaning Product Formulations

Low Cost E x t r a c t i o n C a r p e t C l e a n e r Ingredients: Water, D . I . P e t r o 22 Powder EDTA Powder Perfume

91 . o 5.0 4.0 q. s .

81 e n d i n g P r o c e d u r e : B1 end i n g r e d i e n t s in t h e o r d e r 1 isteci. Use D i l u t i o n : 1-2 o z / g a l F o r m u l a 901

of w a t e r

Premium, Medium D u t y Steam E x t r a c t i o n C a r p e t C l e a n e r Inqredients: Sodi um T r i p o l y p h o s p h a t e , L i g h t D e n s i t y Sodi urn M e t a s i 1 i c a t e , P e n t a h y d r a t e P e t r o 2 2 Powder Optical Brightener

65.0 29.5 5.0 0.5

Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . Use D i l u t i o n : 1-2 o z / g a l Formula 904 Heavy D u t y Steam E x t r a c t i o n C a r p e t C l e a n e r Inqredi ents: Sodium C a r b o n a t e (Soda Ash) T r i s o d i u m Phosphate, C r y s t a l Sodium M e t a s i l i c a t e , P e n t a h y d r a t e Sodium S u l f a t e ( S a l t Cake) P e t r o 2 2 Powder B l e n d i n g Procedure:

Blend i n g r e d i e n t s i n t h e order l i s t e d

Use D i l u t i o n : 1-2 o z / g a l F o r m u l a 905

SOURCE:

Witco Corp.:

Suggested F o r m u l a t i o n s

Wt% 10.0 10.0 20.0 56.0 4.0

Rug, Floor, Carpet, Upholstery Shampoos and Cleaners

159

Low Foaming C a r p e t E x t r a c t o r D e t e r g e n t

Wt%

Component: Sodi um B i c a r b o n a t e STPP B u r c o LAF-6 Burco SZS B u r c o s p e r s e AP Powder B u r c o t a s e SP-60 ( i f d e s i r e d ) Fragrance

t o 100% t o t a l 47.0 2.5 0.25 2.5 1.o as d e s i r e d

Procedure: S p r a y LAF-6 ( a n d i f d e s i r e d ) f r a g r a n c e o n t o STPP and b l e n d u n t i l a b s o r b e d . Add B u r c o S Z S , t h e n Sodium B i c a r b o n a t e and b l e n d u n t i l u n i f o r m . Add B u r c o s p e r s e A P Powder ( a n d i f d e s i r e d ) B u r c o t a s e SP-60. B l e n d u n t i 1 u n i f o r m . Use C o n c e n t r a t i o n : 2-3 ounces p e r g a l l o n i n e x t r a c t o r . SOURCE: B u r l i n g t o n Chemical C o . ,

Inc.:

Suggested F o r m u l a t i o n s

RUQ Steam C l e a n e r (Liquid)

S o i l - Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , and p a r t i c u l a t e S u r f a c e - P o l y e s t e r and n y l o n A p p l i c a t i o n Method - Rug s c r u b b e r Manufacture - Mix t a n k w i t h p r o p e l l e r s t i r r e r Composition: Water M e t s o Beads 2048 Sodium X y l e n e S u l f o n a t e , 40% C12-Cl5 L i n e a r A l c o h o l , 12 M o l e s EO Use D i 1u t i on : 4 . 7 - 9 . 4 % bw ( 6 - 1 2 o z / g a l 1o n ) SOURCE: The PQ C o r p . :

Suggested F o r m u l a t i o n

clay

Wt% 79.6 7.0 6.7 3.9

160

Advanced Cleaning Product Formulations

No Rinse F l o o r Cleaner

\Mt%

I npredie n t s : Water, D.I. Sodi um Carbonate Rewoteric AM 8-14 Versene 100 Butyl Cellosolve

79.0

4.0 10.0 2.0 5.0

Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each addi t ion. Formula 932 Heavy D u t y F l o o r Cleaner Ingredients: Water, D.I. Varami de A-1 2 T r i sodi um Phosphate Sodium Tripolyphosphate

Wt% 78.0

7.0 10.0 5.0

81 end$ng Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . T y p i c a l Propert ies : S o l i d s : 22.0% Formula 933

No-Rinse F l o o r Cleaner Deareaser Ingredients: Deionized water Sodium carbonate Rewoteric AM V Versene 100 Butyl Cellosolve

WtO/o 79.0 4.0

10.0 2.0 5.0

Blending Procedure: Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between each a d d i t i o n . Typical Properties: S o l i d s : 8.1% pH: 10.9 V i s c o s i t y : 4 cps Formula 951

SOURCE: Witco Corp. : Suggested Formulations

161

Rug, Floor, Carpet, Upholstery Shampoos and Cleaners

Wax S t r i p p e r ( A )

Wt%

Inqredients: Oleic Acid Monoethanol ami ne Avanel S - 7 4 Potassium H y d r o x i d e , 45% Sodi um H y d r o x i d e , 50% Versene 100 Dowanol TBA Water

7.0

2.0 2.0 1 .o 1 .o 1

.o

5.0

81 . o

Procedure: Add i n g r e d i e n t s as l i s t e d . Wax S t r i p p e r ( B ) Inaredients: Oleic Acid Monoethanolamine Avanel S - 7 4 Potassium H y d r o x i d e , 45% Sodi um H y d r o x i d e , 50% Versene 1 0 0 E t h y l e n e G1 y c o l Monobutyl E t h e r Water

7.0

2.0 2.0 1 .o 1 .o 1 .o

81 . o 5.0

Procedure: Add i n g r e d i e n t s as l i s t e d . C o n c e n t r a t e d Wax S t r i p p e r Inaredients: Sodium H y d r o x i d e , Macol NP 9 . 5 EDTA, 40% Mazox LDA B a r q u a t MB-50 Monoethanolami ne Water

WtO/o 50%

6.5

1 .o 0.5 1 .o 1 .o 8.5 81 .5

Procedure: Add i n g r e d i e n t s as l i s t e d . To use, d i l u t e 1 : l O t o 1:30. Mac01 NP 1 0 . 5 can be s u b s t i t u t e d f o r t h e Macol NP 9 . 5 . Mafo CB-40 can be s u b s t i t u t e d f o r t h e Mazox LDA.

SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s

14. Miscellaneous

1 fi7

Miscellaneous

163

B a c t e r i o s t a t i c C o n c e n t r a t e w/Pine 021 I n q r e d ie n t s : Wt% Phase I : Isopropanol 10.0 Oleic Acid 8.8 5.0 Varox 1 7 7 0 Pine O i 1 12.0 Phase 11: Water, D . I . 62.2 P o t a s s i um H y d r o x i d e (87%) 2.0 81 e n d i ng P r o c e d u r e : Combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . Combine Phase I T i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o Phase 1 1 . T y p i c a l P r o p e r t i es : V i s c o s i t y , cps: 5 S o l i d s : 10.6% pH: 9 . 3 Formula 302

_ G e n~e r a ~l D _ i s_i n f _ e c t_a n _ t S_o l u_t i o_n ~

~

Ingredi e n t s : Water. D . I . V a r q u a t 5 0 MC G1 y o x a l ( 4 0 % ) R e w o t e r i c AM DML-35 Blending Procedure: Add i n g r e d i e n t s 1 n o r d e r shown and d i s s o l v e c o m p l e t e l y each add1 t ion, Typical Properties: V l s c o s l t y , cps: 4 Sol 1 d s : 1 3 . 0 % pH: 7 . 1 Formula 3 0 3

wtsl, 68.0 10.0 5.0 17.0 between

Hospital D is infectant ents: Wt% Water, D . I . 84.2 9.6 V a r i q u a t 50 MC Varox 365 4.0 Versene 100 1.5 Sod1 urn H y d r o x i d e ( 3 0 % ) 0.7 Blending Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . Typical Properties: Viscosity, cps: 4 S o l i d s : 6.7% pH: 1 2 . 2 Formula 304

-~ Ingredi

SOURCE:

Witco Corp,:

Suggestecl F o r m u l a t i o n s

I64

Advanced Cleaning Product Formulations

C u t t i n g O i l Concentrate Ingredients: Wei s h t % Aristonate M 36.00 I g e p a l CO-430 20.00 8.00 TEA, 85% Oleic A c i d 8.00 100 SUS N a p h t h e n i c O i l 28.00 Comments a b o u t t h i s f o r m u l a : 1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l . 2 . E m u l s i o n - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r . F o r m u l a t i o n SOL-003-01 Cutting Oi 1 Ingredients: Aristonate M TEA, 85% T a l l O i l A c i d , A c t i n o l FA-1 C a l a m i d e SM 100 SUS N a p h t h e n i c O i l Water Comments a b o u t t h i s f o r m u l a : E m u l s i o n - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r . F o r m u l a t i o n SOL-004-01

Wei q h t % 10.50 0.90 1.20 1.65 85.00 0.75

C o n c r e t e C 1e a n e r Ingredients: Weight% 5.00 C a l s o f t F-90 Sodi um S i 1 ic a t e 30.00 30.00 Sodium C a r b o n a t e Sodi um H y d r o x i d e 25.00 Sodi um T r i p h o s p h a t e 10.00 Comments a b o u t t h i s f o r m u l a : G r i n d m i x t u r e t o g e t h e r t o y i e l d a s l i g h t l y t a c k y w h i t e powder. F o r m u l a t i o n CON-001-01 White Wall Cleaner Wei s h t % Insredients : Water 60.20 C a l s o f t L-40 29.30 P i l o t SXS-40 2.20 Na4 EDTA 1.30 C a l o x y l a t e N-9 7.00 Comments a b o u t t h i s f o r m u l a : V i s c o s i t y o f t h e p r o d u c t i s a b o u t 160 cPs a t room t e m p e r a t u r e . F o r m u l a t i o n TIR-001-01

SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s

Miscellaneous

165

d L i monene Water1 e s s Hand C1 e a n e r

Wt%

Ingredients: Phase I : Water, D . I . T r i s o d i u m Phosphate Sodium C i t r a t e Glycerin

81 . O 1 .o 2.0 2.0

Phase 11: d - L i monene DeSonic 9N V a r o n i c T202

7.0

5.0 2.0

B l e n d i n g Procedure: I n v e s s e l fit1 combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . H e a t t o 140F. Combine Phase I1 i n g r e d i e n t s i n s e p a r a t e v e s s e l and m i x t h o r o u g h l y . Heat t o 140F. W h i l e m i x i n g r a p i d l y , add Phase 11 Po Phase I.Cool q u i c k l y t o s t a b i l i z e e m u l s i o n . Typical Properties : Appearance, Room Temp.: S o l i d s : 12.0% pH: 1 0 . 4 Formula 1120

Heavy Cream

P a s t e Hand C l e a n e r

WtS/o

Ingredients: Water, D . I . Varami de MA-1 R e w o t e r i c AM 8-15 W i t c o l a t e SE-5

70.0 10.0 10.0 10.0

81 e n d i n g P r o c e d u r e : Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i on. Typical Properties: V i s c o s i t y , c p s : 6360 S o l i d s : 19.5% pH: 8 . 7 Formula 1121

SOURCE: W i t c o C o r p . :

Suggested F o r m u l a t i o n s

166

Advanced Cleaning Product Formulations

Dipentene Microemulsion Formulations D i p e n t e n e i s d e s c r i b e d as a p r o d u c t o f f r a c t i o n a t i o n o f p i n e o i l s c o n t a i n i n g r e l a t e d monocyclic t e r p e n e hydrocarbons, predomin a n t l y d i p e n t e n e . ( S t r u c t u r a l l y , d i p e n t e n e i s t h e same as l i m onene. D-limonene i s one o f t h e 2 o p t i c a l i s o m e r s o f d i p e n t e n e . ) O t h e r components o f commercial d i p e n t e n e i n c l u d e c a r e n e and a l p h a - and b e t a - p i n e n e . Non-alkaline Formulations

&%

Ingredients: D i p e n t e n e 122 Tomah E-14-5 Tomah E-14-2 Tomah A l k a l i S u r f a c t a n t Water

5.00 6.40 0.80 0.80 87 00 ~

CPL, c : 1 1 CPH, C : 30 Emulsifier/Dipentene Ratio:

1.60

VVt.%

Ingredients: D i p e n t e n e 122 Tomah E-14-5 Tomah E-14-2 Tomah A l k a i S u r f a c t a n t Water

10.00 8.80

1.10 1.10 79.00

C P L , c : 11 CPH, C : 50 Emu1 s i f e r / D i p e n t e n e R a t i o :

1.10

Wt.%

Inaredients: D i p e n t e n e 122 Tomah E-14-5 Tomah E-14-2 Tomah A l k a l i S u r f a c t a n t Water

20.00 14.40 1.80 1 .80 62.00

CPL, c : 19 CPH, C : 41 Emulsifier/Dipentene Ratio:

0.90

Add and m i x t h e f i r s t f o u r i n g r e d i e n t s ( d i p e n t e n e and emulsi f i e r s ) . D i s s o l v e t h e sodium m e t a s i l i c a t e ( i f used) i n t h e w a t e r and add i t t o t h e e m u l s i f i e r s and d i p e n t e n e w i t h m i x i n g . C P L i s " l o w t e m p e r a t u r e c l o u d p o i n t " w h i l e CPH i s " h i g h temperature cloud p o i n t " .

SOURCE: Tomah P r o d u c t s ,

Inc.:

B u l l e t i n : Terpene M i c r o e m u l s i o n s

Miscellaneous

167

D i p e n t e n e M i c r o e m u l s i o n Formul a t i o n s ( C o n t i nued) D i p e n t e n e i s d e s c r i b e d as a p r o d u c t o f f r a c t i o n a t i o n o f p i ne o i l s c o n t a i n i n g r e l a t e d m o n o c y c l i c t e r p e n e h y d r o c a r b o n s , predomi n a n t l y d i p e n t e n e . ( S t r u c t u r a l l y , d i p e n t e n e i s t h e same a s l i m o n ene. D-limonene i s one o f t h e 2 o p t i c a l i s o m e r s o f d i p e n t e n e . ) O t h e r components o f commercial d i p e n t e n e i n c l u d e c a r e n e and a l p h a - and b e t a - p i n e n e .

A l k a l i n e Formulations

Wt.96

Ingredients: D i p e n t e n e 122

5.00

E-14-5 E-14-2 A1 k a l i S u r f a c t a n t Water Sodium M e t a s i l i c a t e P e n t a h y d r a t e

CPL, C : 15 CPH, C : 4 4 Emulsifier/Dipentene Ratio:

2.00

Ingredients: D i p e n t e n e 122 E-14-5 E-14-2 A1 k a l i S u r f a c t a n t Water Sodium M e t a s i l i c a t e P e n t a h y d r a t e CPL, c : 20 CPH, C : 46 Emulsifier/Dipentene Ratio:

8.00 0.50 1 .50 83.30 1.70

Wt.% 10.00 12.00 0.75 2.25 73.50 1.50

1 .50

Ingredients: D i p e n t e n e 122 E- 1 4 - 5 E-14-2 A1 k a l i S u r f a c t a n t Water Sodium M e t a s i l i c a t e P e n t a h y d r a t e

Wt.% 20.00 17.60 1.10 3.30 56.80 1.20

CPL, C : 18 CPH, C : 43 E m u l s i f i e r / D i p e n t e n e R a t i o : 1 .I0 Add and m i x t h e f i r s t f o u r i n g r e d i e n t s ( d i p e n t e n e and e m u l s i f i e r s ) . D i s s o l v e t h e sodium m e t a s i l i c a t e ( i f used) i n t h e w a t e r and add i t t o t h e e m u l s i f i e r s and d i p e n t e n e w i t h m i x i n g . CPL i s " l o w t e m p e r a t u r e c l o u d p o i n t " w h i l e CPH i s " h i g h temperature cloud p o i n t " .

SOURCE: Tomah P r o d u c t s , I n c . : B u l l e t i n : Terpene M i c r o e m u l s i o n s

168

Advanced Cleaning Product Formulatioris

H y d r o c a r b o n S o l v e n t M i c r o e m u l s i ons Developed i n o r d e r t o o f f e r replacements f o r expensive d - l i m o n e n e and p i n e o i l i n m i c r o e m u l s i o n c l e a n e r s . They a l l have f l a s h p o i n t s above I O O C and l o w VOC c o n t e n t . Exxsol D-I10

Formulations

Formula A: Ingredients: E x x s o l D-110 Tomah E-14-2 Tomah E-14-5 Tomah A l k a l i S u r f a c t a n t S o f t Water Formula 8 : Inaredients: E x x s o l D-110 Tomah E-14-2 Tomah E - 1 4 - 5 Tomah A l k a l i S u r f a c t a n t S o f t Water Formula C : Inqredients: E x x s o l D-110 Tomah E-14-2 Tomah E-14-5 Tomah A l k a l i S u r f a c t a n t S o f t Water

\Nt.% 20.0 11.9 5.4 4.3 58.4

Wt.% 30.0 17.9 8.1 6.5 37.5

Wt.% 40.0 23.9 10.8 8.7 16.6

Add each component i n t h e o r d e r g i v e n and m i x u n t i l homogeneous b e f o r e a d d i n g t h e n e x t component. Add t h e w a t e r i n p o r t i o n s with mixing. These m i c r o e m u l s i o n s s h o u l d be c l e a r and s t a b l e i n t h e tempe r a t u r e r a n g e f r o m 20-37C. O u t s i d e t h a t r a n g e t h e y may c l o u d o r s e p a r a t e , b u t w i l l r e g a i n c l a r i t y upon r e t u r n i n g t o room tempe r a t u r e . I f i t i s necessary t o r a i s e t h e c l o u d p o i n t temperature, a s m a l l amount o f a d d i t i o n a l Tomah A l k a l i S u r f a c t a n t s h o u l d b e added.

SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s

Miscellaneous

169

Hydrocarbon S o l v e n t Microemulsions ( C o n t i n u e d l Developed i n o r d e r t o o f f e r r e p l a c e m e n t s f o r e x p e n s i v e d - l i m o n e n e and p i n e o i l i n m i c r o e m u l s i o n c l e a n e r s . They a l l have f l a s h p o i n t s above 1OOC and l o w VOC c o n t e n t .

Isopar M F o r m u l a t i o n s I s o p a r M can b e s u b s t i t u t e d d i r e c t l y f o r t h e E x x s o l D-110 i n t h e above f o r m u l a t i o n s . I n a d d i t i o n , t w o f o r m u l a t i o n s w i t h l o w e r s o l v e n t c o n t e n t have been d e v e l o p e d . Unbui 1 t : Component: S o f t Water Sodium Metas l i c a t e P e n t a h y d r a t e Tomah E-14-2 Tomah E-14-5 Tomah A1 k a l i S u r f a c t a n t I s o p a r Wi

L i g h t l y b u i 1t : Component: S o f t Water Sodium M e t a s i l i c a t e P e n t a h y d r a t e Tomah E-14-2 Tomah E-14-5 Tomah A l k a l i S u r f a c t a n t Isopar M

Wt.% 83.0 0.0 4.7 4.7 1.6

6.0

Wt.% 79.0 1.o 5.6 5.6 1.a 7.0

S t a r t b y d i s s o l v i n g t h e sodium m e t a s i l i c a t e ( i f u s e d ) i n t h e w a t e r . Then add t h e E-14-2, E-14-5, a n d A l k a l i S u r f a c t a n t . M i x u n t i l homogeneous. F i n a l l y add t h e I s o p a r M i n p o r t i o n s w i t h m i x i n g . The m i x t u r e w i l l c l o u d , t h e n s h o u l d c l e a r a s t h e l a s t o f t h e I s o p a r M i s added. These m i c r o e m u l s i o n s w i l l b e c l e a r and s t a b l e i n t h e t e m p e r a t u r e r a n g e f r o m 20-5OC. The c l o u d p o i n t c a n be r a i s e d f u r t h e r b y a d d i n g a s m a l l amount o f a d d i t i o n a l A l k a l i Surfactant. SOURCE: Tomah P r o d u c t s ,

I n c . : Suggested F o r m u l a t i o n s

I70

Advanced Cleaning Product Formulations

. !oL

.

V i_s_cosi_tv_s_jlicon ..Emu 1-si-o~n-UsinxPemulens

resins

S i l i c o n e o i l c a n b e e m u l s i f i e d and s t a b i l i z e d v i a t h e u s e o f Pemulen r e s i n s . The r e s i n s s t a b i l i z e e m u l s i o n s v i a e l e c t r o s t a t i c s t a b i l i z a t i o n . T h i s r e l i e v e s t h e c o n s t r a i n t o f s e e k i n g an appropr i a t e surfactant emulsifier. W t"/. 83.80 0.20 0.70 15.00 0.30

Inycedi e n t l D I Water Pemulen 1622 ( 1 ) Makon 10 ( 2 ) Dow 200 S i l i c o n e F l u i d ( 3 ) Triethanolamine Physical Properties: B r o o k f i e l d V i s c o s i t y (RVT-20 Product pH: 7.3 P r o d u c t C l a r i t y : Opaque

rpm):

1,000 c p

Raw M a t e r i a1 S u p p l i e r s : ( 1 ) BFGoodrich ( 2 ) Stepan C o . ( 3 ) Dow C o r n i n g Procedure: 1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s S c r e e n t h e Pemuleri r e s i n i n t . o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r ( 8 0 0 r p m ) . A l l o w t o m i x u n t i l homogeneous and f r e e o f p o l y m e r l u m p s . 2 . Add t h e Makon 10 and m i x u n t i l homogeneous. 3 . Add t h e s i l i c o n e o i l w i t h v i g o r o u s a g i t a t i o n . M i x u n t i l uniform. 4 . Add t h e T E A . M i x u n t i l smoot.h. Total Actives: Silicone O i l : SOURCE:

15.00%

BFGoodrich S p e c i a l t y Chemicals:

DET-510

Miscellaneous

171

Lumi n i z i n g P e t C o n d i t i o n e r P h o s p h o l i p i d EFA adds s h i n e and a s i l k y t e x t u r e t o t h e a n i m a l ' s c o a t o r mane. The Monaquat TG p r o v i d e s body b u i l d i n g c o n d i t i o n i n g and d e t a n g l i n g w h i l e l e a v i n g a s o f t smooth f e e l . Monaquat I S I E S i s an e f f e c t i v e l o n g l a s t i n g a n t i s t a t t h a t controls d i r t attraction. Inaredients: Water Hydroxyethyl C e l l u l o s e Stearic acid Stearyl alcohol Monaquat TG Monaquat I S I E S ( I s o s t e a r y l E t h y l m i d o n i u m E t h o s u l f a t e ) P h o s p h o l i p i d EFA ( L i n o l e a m i d o p r o p y l PG-Dimonium C h l o r i d e Phosphate) Sodium C h l o r i d e

Wt% 85.2 0.8 2.0 2.0 7.0 0.5 2.0 0.5

Procedure: Change w a t e r w i t h a g i t a t i o n , s p r i n k l e i n h y d r o x y e t h y l c e l l u l o s e and t u r n h e a t o n . A t 50-60C add s t e a r i c a c i d , s t e a r y l a l c o h o l , Monaquat TG, Monaquat I S I E S , P h o s p h o l i p i d EFA, and sodium c h l o r i d e . Heat and m i x t o 70-75C ( a smooth c r e m e ) . Cool t o 40C. A d j u s t pH t o 4 . 5 - 5 . 0 . A d d c o l o r , f r a g r a n c e and p r e s e r v a t iv e . Package. Typical Properties: Appearance: Opaque v i s c o u s l o t i o n Recommended Use D i l u t i o n : As i s F o r m u l a t i o n F-777 P e t Shampoo A h i g h foaming, f r e s h and c l e a n .

m i l d detergent which w i l l

leave your p e t

Wt%

Ingredients: Water M o n a t e r g e 779 d - L i monene

70.0 25.0 5.0

Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . A d j u s t pH t o 7 . 0 . Add c o l o r and p r e s e r v a t i v e . Package. Typical Properties: Appearance: C l e a r y e l l o w l i q u i d Recommended Use D i l u t i o n : F o r m u l a t i o n F-774

SOURCE: Mona I n d u s t r i e s ,

1:50 w i t h water

Inc.:

Suggested F o r m u l a t i o n s

172

Advanced Cleaning Product Formulations

M i cro-Emu1 s i ons with d-Li monene

The f o l l o w i n g c o n c e n t r a t e s a r e c l e a r , m i c r o - e m u l s i o n s o f imonene and w a t e r . These f o r m u l a s a r e g e n e r a l l y used b y u t i n g i n w a t e r a r e v e r y e f f e c t i v e f o r r e m o v i n g many o i l y . .I r e s i n o u s s o i l s . The f o r m u l a t h e m s e l v e s a r e c l e a r and e x h i b i t a bloom e f f e c t upon d i l u t i o n . Formula

I Wt%

Inqredients: d - L i monene Monamul s e dL-1273 Water

10.0 18.0 62.0 F o r m u l a I1

Wt%

Inqredients: d - L i monene Monamulse dL-1273 Isopropanol Water

35.0 28.0 5.0 32.0 Formula I11

Wt%

Ingredients: d - L i monene Monamul se dL-1273 Water

65.0 23.0 12.0

Procedure: I n a l l c a s e s , mix s u r f a c t a n t w i t h d-Limonene u n t i l d i s s o l v e d . Add o t h e r i n g r e d i e n t s e x c e p t w a t e r . M i x u n t i l homogeneous. Add water s l o w l y w i t h s t i r r i n g . Recommended Use D i l u t i o n : 1 : 1 0 w i t h w a t e r

SOURCE: Mona I n d u s t r i e s ,

I n c . : F o r m u l a t i o n F-786

Miscellaneous

173

M i cro-Emu1 s i ons w i t h P i ne O i 1

The fol 1owi ng f o r m u l a s a r e c l e a r m i c r o e m u l s i ons o f p i ne o i 1 and w a t e r . They r e p r e s e n t t h e r a n g e o f p i n e o i l and w a t e r concent r a t i o n s commonly used. The f o r m u l a s t h e m s e l v e s a r e c l e a r and e x h i b i t a bloom e f f e c t upon d i l u t i o n . Formula 1 Inaredients: Pine O i l Monamulse TRP Water Appearance: C l e a r D i l u t i o n (1% i n t a p w a t e r ) :

&y& 35.0 20.0 45.0 Blooms Formula 2

I ngredients : Pine O i l Monamul s e TRP Isopropanol Water Appearance: C1 e a r D i l u t i o n (1% i n t a p w a t e r ) :

WtO/o 20.0 20.0

5.0 55.0 Blooms

Formula 3 Ingredients: Pine O i l Monamul se TRP Isopropanol Water Appearance: C1 e a r D i l u t i o n (1% i n t a p w a t e r ) :

Wt% 9.0 10.0 10.0 71 .O Blooms Formula 4

Inqredients: Pine O i l Monamul se TRP Water Appearance: C l e a r D i l u t i o n (1% i n t a p w a t e r ) :

WtO/o 2.0 5.0

93.0 Clear

Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package Recommended Use D i l u t i o n : 1 : l O w i t h w a t e r F o r m u l a F-785

SOURCE: Mona I n d u s t r i e s ,

Inc.:

Suggested F o r m u l a t i o n s

174

Advanced Cleaning Product Formulations

P l a s t i c B o t t l e Wash Stable i n hard water

Wt%

Inqredients: Water KOH-45% K a s i l #I STPP B u r c o HCS-5ONF

26.5 19.5 39.0 8.0 7.0

% S o l i d s : 31.0

Add components i n o r d e r l i s t e d .

B l e n d between a d d i t i o n s .

To f o r m u l a t e a l o w e r a c t i v i t y p r o d u c t , keep t h e r a t i o o f t h e components t h e same, so t h a t t h e b a l a n c e o f t h e f o r m u l a t i o n i s n o t d e s t r o y e d . End use c o n c e n t r a t i o n s w i l l depend o n d e g r e e o f s o i l t o b e removed. N o r m a l l y , a 2% end use c o n c e n t r a t i o n i s s u f f i c i e n t f o r b o t t l e cleaning.

A s l i g h t s i l i c a t e p r e c i p i t a t e may o c c u r upon l o n g s t a n d i n g . B o t t l e Wash F o r m u l a t i o n s Low Foam

y &

Inqredie n t s : 50% NaOH B u r c o BSGH-270 B u r c o HCS-50NF

To 100% T o t a l 2.5-5.0% 0.5-2.5%

Add BSGH-270 and HCS-50 NF t o 50% NaOH. M o d e r a t e Foam Inqredients: 50% NaOH B u r c o BSGH-270 B u r c o NPS-225 Water

W

O

To 100% T o t a l 2.5-5.0% 0.5-2.5% 3.0-7.5%

I t i s recommended t h a t t h e BSGH-270 and NPS-225 b e d i s s o l v e d i n an e q u a l amount o f w a t e r and t h e c a u s t i c added t o t h a t p r e m i x . T o defoam t h i s f o r m u l a t i o n use a 3/1 r a t i o o f NPS-225/Burco LAF-I 25.

SOURCE: B u r l i n g t o n Chemical Co.,

Inc.:

Suggested F o r m u l a t i o n s

Miscellaneous

175

Teroene M icroemul s i ons The f o r m u l a t i o n s g i v e n h e r e w i l l p r o d u c e c l e a r s t a b l e m i c r o e m u l s i o n s c o n t a i n i n g f r o m 15% t o 40% d - l i m o n e n e . G l i d s o l 180 ( f r o m SCM G l i d c o O r g a n i c s C o r p . ) , a p i n e o i l d e r i v a t i v e can b e s u b s t i t u t e d f o r d - l i m o n e n e i n t h e f o r m u l a t i o n s t o g i v e a f l a s h p o i n t above 1 4 0 F . N o t e t h a t o t h e r p i n e o i l s may n o t work i n t h e s e f o r m u l a t i o n s . Formula A: D-Limonene 40.0 Tomah E-14-5 22.4 Tomah E-14-2 2.8 Tomah A l k a l i S u r f a c t a n t 2.8 Water 32.0 % t o t a l s u r f a c t a n t : 28.0% Emul s i f i e r / T e r p e n e r a t i 0 : 0 . 7 0 0 F o r m u l a 5: Wt.9/o D-Li monene 30.0 Tomah E-14-5 19.2 Tomah E-14-2 2.4 Tomah A l k a l i S u r f a c t a n t 2.4 Water 46.0 % t o t a l s u r f a c t a n t : 24.0% Emul s i f ie r / T e r p e n e r a t i 0 : 0 . 8 0 0 Formula C : Wt.% D-Li monene 20.0 12.8 Tomah E - 1 4 - 5 1.6 Tomah E-14-2 Tomah A l k a l i S u r f a c t a n t 1.6 64.0 Water % t o t a l s u r f a c t a n t : 16.0% E m u l s i f i e r / T e r p e n e r a t i o : 0.800 Formula D: Wt.o/a D-Li monene 15.0 12.0 Tomah E-14-5 Tomah E-14-2 1.5 Tomah A l k a l i S u r f a c t a n t 1.5 Water 70.0 % t o t a l s u r f a c t a n t : 15.0% Emulsifier/Terpene r a t i o : 1.000 Add each component i n t h e o r d e r g i v e n and m i x u n t i l homogeneous b e f o r e a d d i n g t h e n e x t component. Add t h e w a t e r i n p o r t i o n s w i t h mixing. A t y p i c a l use l e v e l w o u l d b e a t 1 0 / 1 t o 4 0 / 1 w i t h w a t e r . About 1-2% d - l i m o n e n e a t use l e v e l i s u s u a l l y s u f f i c i e n t . Heavy g r e a s e would r e q u i r e a h i g h e r c o n c e n t r a t i o n o f d-limonene. Concentrated Formula Formula: 70.0 D-Limonene Tomah E-14-5 14.0 Monamid 7 0 5 4.0 T a l l O i l Fatty Acid 1.6 Monoethanolamine 0.4 Water 10.0 SOURCE: Tomah P r o d u c t s , I n c . : B u l l e t i n : T e r p e n e M i c r o e m u l s i o n s

176

Advanced Cleaning Product Formulatioris

Wax Emulsion U s i n g Pemulen R e s i n s T h i s wax e m u l s i o n can be c r e a t e d and s t a b i l i z e d v i a t h e use o f Pemulen r e s i n s . The r e s i n s s t a b i i z e e m u l s i o n s v i a e l e c t r o s t a t i c s t a b i l i z a t i o n . T h i s r e l i e v e s t h e c o n s t r a i n t o f s e l e c t i n g an appropriate surfactant emulsifier. vytsb 12.00

Ingredient: Bareco C-36 Wax ( 1 ) Hoechst Wax E ( 2 ) Pemulen 1622 ( 3 ) 01 Water Morphol ine

8.00 0.30 79 5 0 0.20 ~

Physical Properties : P r o d u c t C l a r i t y : Opaque Raw M a t e r i a l S u p p l i e r s : ( 1 ) P e t r o l i t e Corp. ( 2 ) American Hoechst Corp. ( 3 ) BFGoodrich Procedure: 1. M e l t t h e waxes t o g e t h e r i n a v e s s e l , a p p r o x i m a t e l y a t 9 0 C . 2 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s Screen t h e Pemulen r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 rpm). A l l o w t o mix u n t i l homogeneous and f r e e o f p o l y m e r lumps. 3 . Heat t h e Pemulen d i s p e r s i o n t o 9OC. Add t h e Pemulen d i s p e r s i o n t o t h e m e l t e d wax w i t h v i g o r o u s a g i t a t i o n . 4 . Add t h e m o r p h o l i n e and cool q u i c k l y . Total Actives: T o t a l Wax: 20.00% SOURCE: BFGoodrich S p e c i a l t y Chemicals:

DET-501

Section II sportation Cleaners and Polishes

177

15. Auto Cleaners and Polis

178

Auto Cleaners and Polishes

179

Chrome P o l i s h I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y suspended. The r e s i n a l s o p r e v e n t s "creaming" o r phase s e p a r a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s . Ingredient: D I Water Morphol ine Pumice Snow F l o s s SFSB S i l i c o n e F l u i d ( 3 5 0 ) ( 1 ) Yarmor 302 P i n e O i l ( 2 ) Oleic Acid Mineral S p i r i t s TEA l a u r y l s u l f a t e ( 3 ) Cocamide DEA ( 4 ) D I Water Carbopol EZ-2 ( 5 ) Physical Properties: B r o o k f i e l d V i s c o s i t y (RVT-20 P r o d u c t pH: 9 . 0 P r o d u c t C l a r i t y : Opaque Raw M a t e r i a l S u p p l i e r s : ( 1 ) General E l e c t r i c ( 2 ) Hercules ( 3 ) Rhone-Poul enc ( 4 ) H e n k e l : Standamid ( 5 ) BFGoodri c h

39.25 1.39 14.00 9.25 1.85 0.46 1.85 24.50 2.30 0.50 4.46 0.19

r p m ) : 10,800 c p

PO

Procedure: 1 . D i s s o l v e t h e morpholine i n t h e water. 2 . W i t h r a p i d a g i t a t i o n , add t h e pumice and Snow F l o s s . 3 . D i s s o l v e t h e s i l i c o n e o i l , p i n e o i l , and o l e i c a c i d i n t h e m i n e r a l s p i r i t s . S l o w l y add i n t o t h e above m i x t u r e w i t h rapid agitation. 4 . Add i n t h e TEA l a u r y l s u l f a t e and Standamid PD. B l e n d t h o r oughl y 5. I n a s e p a r a t e v e s s e l , d i s p e r s e 0 . 1 9 p a r t s o f Carbopol i n t o 4.48 p a r t s o f w a t e r by s i m p l y "dumping" t h e polymer i n t o t h e w a t e r . I n j u s t a few m i n u t e s , t h e polymer w i l l c o m p l e t e l y wet o u t . Add t h i s d i s p e r s i o n t o t h e above m i x t u r e . B l e n d thorough1y

.

.

T o t a l Asti ves : Silicone Fluid: Total Surfactant: Mineral S p i r i t s : T o t a l Abrasives:

1.85 4.65 24.50 23.25

FGoodrich S p e c i a l t y Chemicals:

DET-551

I80

Advanced Cleaning Product Formulations

L i q u i d Car Polish I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y suspended. The r e s i n a l s o p r e v e n t s "creaming" o r phase s e p a r a t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s . Insredient: D I Water T r i e t h a n o l ami ne Wax Emulsion ( 1 ) Morphol ine SF90 S i l i c o n e F l u i d (350) ( 2 ) Oleic Acid Kerosene Mineral S p i r i t s D I Water Carbopol EZ-2 ( 3 ) Isopropanol Mineral S p i r i t s SF1706 R e a c t i v e Amine Polymer ( 4 ) SF1705 R e a c t i v e Amine Polymer ( 4 ) Kaopolite kaolin clay (5)

Wt96 37.80 8.20 2.50 2.00 1 * 50 2.50 10.00

8.00 49.70 0.30 0.40 5.00 1.50 2.10 8.50

Physical P r o p erties: B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 3,200 cps P r o d u c t pH: 8-9 P r o d u c t C l a r i t y : Opaque Raw M a t e r i a l S u p p l i e r s : ( 1 ) see EiFGoodrich L i t e r a t u r e DET-501 ( 2 ) General E l e c t r i c ( 3 ) BFGoodrich ( 4 ) General E l e c t r i c (5) Kaopolite, I n c . Procedure: 1 . M i x t o g e t h e r t h e w a t e r , TEA, wax emulsion, and t h e m o r p h o l i n e 2 . I n a s e p a r a t e v e s s e l , mix t h e s i l i c o n e f l u i d , o l e i c a c i d , kerosene and t h e m i n e r a l s p i r i t s t o g e t h e r . Add t h i s t o t h e above m i x t u r e w i t h v i g o r o u s a g i t a t i o n . 3. I n a s e p a r a t e v e s s e l , d i s p e r s e 0.30 p a r t s o f Carbopol i n t o 19.70 p a r t s o f water by s i m p l y "dumping" i t i n . The polymer w i l l wet o u t i n a few minutes. Add t h i s d i s p e r s i o n t o t h e above m i x t u r e . M i x u n t i l homogeneous. 4 . I n a s e p a r a t e v e s s e l , mix t h e i s o p r o p a n o l , m i n e r a l s p i r i t s , and t h e t w o r e a c t i v e amine polymers t o g e t h e r . Add t o t h e above m i x t u r e . M i x u n t i l homogeneous. 5 . S l o w l y add i n t h e c l a y . M i x u n t i l homogeneous. Total Actives: T o t a l Wax : 0.50 Silicone Fluid: 1.50 Mineral S p i r i t s : 11 .oo 3.60 React ive A m i ne Polymer : Abrasive: 8.50 SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-BOO

Auto Cleaners and Polishes

181

L i q u i d Spray C l e a n e r f o r A l u m i n u m T r u c k s

Bngredi e n t s : Water Phosphoric A c i d , 75% C i t r i c Acid Macol 48 Ammoni um B i f 1u o r i de Avanel S-30

Wt% 50.0 20.0 10.0 4.0

3.0 3.0

~ r ~ c ~ d U r ~ ~ Add i n g r e d i e n t s i n o r d e r as l i s t e d . D i l u t e one p a r t c l e a n e r w i t h f i v e p a r t s w a t e r t o use. A 1 umi n u m C l e a n e r / B r i n h t e n e r

Pnaredi e n t : Phosphoric A c i d , 85% C i t r i c A c i d , 50% N i t r i c A c i d , 70% Avanel S-70 Water

Wt% 6.0 8.0 1.o

2.0 83.0

Procedure: Charge t h e w a t e r t o t h e m i x i n g v e s s e l . Under s l o w a g i t a t i o n and w i t h due c a r e , add t h e a c i d s t o t h e w a t e r . Add t h e Avanel S - 7 0 and mix f o r 10 m i n u t e s . Note: I f a d d i t i o n a l b r i g h t e n i n g i s r e q u i r e d , t h e n i t r i c a c i d may be i n c r e a s e d t o 1.5%. F o r m u l a t i o n CM-101 Non-Phosphorous A l u m i n u m C l e a n e r Inaredi ent : C i t r i c A c i d , 50% G l u c o n i c A c i d , 50% Avanel 5-70 Water, Dye

Wt% 12.0

8.0 3.0 77.0

PPOC@dUr&?: Charae t h e w a t e r , c i t r i c a c i d , g l u c o n i c a c i d and Avanel S-70 t o t h e G i x i n g v e s s e i . M i x w e l l . I f - d y e i s t o be added, p a r t of t h e water s h o u l d be h e l d o u t . Add t h e dye t o t h e w a t e r w i t h good a g i t a t i o n and t h e n add t h e w a t e r t o t h e b a t c h . Formu 1a t ion CM- 102

UWCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s

182

Advanced Cleaning Product Formulations

M i l d A b r a s i v e A u t o m o b i l e Polish I n q r e d ie n t : Part A: Masi 1 SF 1 , 0 0 0 Oleic Acid Carnauba Wax #1 Y e l l o w Isopar M Mazami de SS-1 0 P a r t B: Isopar M M a s i l 123 Part C : Isopar M Morphol ine P a r t D: Water K a o p o l i t e SF

Wt% 4.0 2.0 6.0 14.5 0.75

12.0

2.0 2.5 1.1

45.15 10.0

pH ( a s i s ) : 7 . 5 - 8 . 5 Appearance: Cream-Colored Paste Procedure: 1 . Charge t h e components i n P a r t A t o a steam-heated m i x i n g v e s s e l equipped w i t h a g i t a t i o n . S t a r t a g i t a t i o n and h e a t t o

9QC. I n s e p a r a t e v e s s e l s , charge P a r t B and P a r t C components. When P a r t A reaches 9OC and a l l t h e wax has m e l t e d , add P a r t B t o t h e v e s s e l f o l l o w e d by P a r t C . Apply c o o l i n g . 3 . I n a s e p a r a t e v e s s e l , p r e p a r e P a r t D by a d d i n g t h e K a o p o l d t e SF t o t h e w a t e r under a g i t a t i o n . Add P a r t D t o P a r t A and c o n t i n u e c o o l i n g . NOTE: The f i n i s h e d p r o d u c t i s a p a s t e . A s t i f f e r p a s t e can be p r e p a r e d by i n c r e a s i n g t h e o l e i c a c i d charge. 2.

SOURCE:

PPG I n d u s t r i e s , I n c . : F o r m u l a t i o n S A - 1 0 1

0

r and Truck Wash Compounds

183

184

Advanced Cleaning Product Formulations

Car Shampoo C o n c e n t r a t e T h i s f o r m u l a t i o n produces c o p i o u s amounts o f foam w h i l e c l e a n i n g a u t o m o t i v e f i n i s h e s . I t i s m i l d t o b o t h t h e u s e r and t h e automotive f i n i s h .

Wt%

Ingredient: Part A: Dei o n i zed Water Sodi um C i t r a t e

30.0 0.5

P a r t 8: Mafo CSB-50 5.0 7.5 W i t c o n a t e 60 T L i q u i d Macol TD-12 4.0 T r i e t h a n o l ami ne, 85% 1.o D e i o n i z e d Water 52.0 pH ( a s i s ) : 8 . 0 - 9 . 0 Appearance: C l e a r , l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1.00 Procedure: 1 . Charge t h e f i r s t p o r t i o n o f w a t e r t o a m i x i n g v e s s e l and d i s s o l v e t h e sodium c i t r a t e i n i t . 2 . Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d . S t o p a g i t a t i o n and p e r m i t t h e p r o d u c t t o d e a e r a t e p r i o r t o f i l l i n g o f f . NOTE: Use c o n c e n t r a t i o n i s 1-2 ounces p e r g a l l o n o f warm w a t e r . A u t o m a t i c Car Wash C o n c e n t r a t e

w.t% I n a r e d ie n t s : 50.0 Dei o n i zed Water 6.0 Maphos 60-A 3.0 P o t a s s i um H y d r o x i d e 2.0 T e t r a p o t a s s i u m Pyrophosphate 2.0 Sodium M e t a s i l i c a t e , Anhydrous 2.0 Macol LF 120 Mazamide 00 2.0 Sodium X y l e n e S u l f o n a t e , 40% 3.0 Macol 48 3.0 D e i o n i z e d Water 27.0 pH ( a s i s ) : 12.5-13.5 Appearance: C l e a r , l i g h t - y e l l o w l i q u i d S p e c i f i c Gravity: 1 .06 Procedure: Charge t h e f i r s t p o r t i o n o f w a t e r t o t h e m i x i n g v e s s e l and s t a r t a g i t a t i o n . Add t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d and mix u n t i l c l e a r . NOTE: T h i s i s a h i g h l y a l k a l i n e c l e a n e r d e s i g n e d t o be used i n commercial a u t o m a t i c c a r washes a t a d i l u t i o n r a t e o f 1-2 ounces p e r g a l l o n . Do n o t use d i r e c t l y on a u t o m o t i v e f i n i s h e s F o r m u l a t i o n CA-102 SOURCE:

PPG I n d u s t r i e s ,

Inc.:

Suggested F o r m u l a t i o n s

1

Car and Truck Wash Compounds

Car Wash ( C a l s o f t LAS-gg-Basedl Ingredients: Water NaOH, 50% D i e t h a n o l ami ne C a l s o f t LAS-99 Calamide C P i l o t SXS-40 Cal foam EA-603 Ammonium C h l o r i d e Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-008-01 Car Wash ( C a l s o f t LAS-99-Based) Ingredients: Water NaOH, 50% Cal s o f t LAS-99 Calamide C P i l o t SXS-40 C a l foam EA-603 C a l o x y l a t e N-9 Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s in o r d e r 1 is t e d F o r m u l a t i o n CWC-007-01 Car Wash ( C a l s u d s A-Based) Ingredients: Water Calsuds A C a l foam EA-603 C a l s u d s CD-6 Ammonium C h l o r i d e Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-006-01 Car Wash ( C a l s o f t T-60-Based) Ingredients : Water C a l s o f t T-60 Pi l o t sxs-40 C a l o x y l a t e N-9 Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-005-01 SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s

185

Weight% 72.50 2.40 0.50 10.10 3.70 7.00 2.80 1.oo

Wei q h t % 59.80 4.35 16.30 2.05 12.50 3.00 2.00

Wei a h t % 64.20 28.00 2.80 4.00 1 .oo

Weight% 70.00 20.00 5.00 5.00

186

Advanced Cleaning Product Formulatioris

Car Wash Readi l y removes a w i d e v a r i e t y o f r o a d s o i 1 s . Ingredients: Water Monaterge ALX-100s (Cocamide DEA ( a n d ) DEA D o d e c y l benzenesulfonate (and) Diethanolamine)

70.0 30.0

Procedure: Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . A d j u s t pH t o 7 . 0 . Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e . Package. Typi c a l P r o p e r t i e s : Appearance: C l e a r y e l l o w l i q u i d Recommnded Use D i l u t i o n : 1 : 2 0 w i t h w a t e r F o r m u l a t i o n F-772 P a s t e Car Wax T h i s e a s i l y a p p l i e d a u t o m o b i l e p a s t e wax f o r m u l a w i l l p r o v i d e i m p r o v e d c l e a n i n g , d e p t h o f g l o s s , l a s t i n g b e a u t y and s h i n e t o new and o l d e r a u t o m o b i l e f i n i s h e s . M o n a s i l PCA w i l l p r o v i d e s h i n e and d e t e r g e n t r e s i s t a n c e t o any p a s t e wax f o r m u l a .

We96

Ingredients: P a r t I: M o n a s i l PCA Dimethicone (12,500 c s t ) Carnauba Wax #1 Y e l l o w T a l l O i l Fatty Acid Isopar K Kaopol it e 11 5 2

4.5 2.0 6.0 3.0 24.0 10.0

P a r t 11: Water TEA (99%)

50.0 0.5

Procedure: P r e p a r e each phase s e p a r a t e l y , h e a t t o 70C. Add P a r t I I s l o w l y t o P a r t I w i t h good a g i t a t i o n . S t i r coo t o 40-50C and package. F o r m u l a t i o n F-826

SOURCE: Mona I n d u s t r i e s ,

Inc.:

Suggested Formu a t i o n s

Car and Truck Wash Compounds

187

Car Wash w / A m p h o t e r i c

wt%

Ingredients: Water, D . I . Sodi um T r i p o l y p h o s p h a t e R e w o t e r i c AM 8-14 V a r o n i c DM-55 Sodi um H y d r o x i d e , 30% W i t c o 1298SA

55.0 4.0 10.0 2.0 9.0 20.0

B1 e n d i ng

Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e compl e t e l y between each a d d i t i o n . Typical Properties: V i s c o s i t y , c p s : 290 S o l i d s : 29.5% pH: 8 . 9 F o r m u l a 630 W i n d s h i e l d Washer C o n c e n t r a t e

Wt%

Ingredients: Water, D . I . Isopropanol P e t r o BAF Powder DeSophos 5AP EDTA, 38%

56.0

30.0 1.o 0.5 2.5

B l e n d i n g Procedure:

Blend i n g r e d i e n t s i n t h e order l i s t e d .

Use " a s i s " i n w i n t e r ;

d i l u t e up t o 2 9 : l

f o r summer u s e .

F o r m u l a 666 W i n d s h i e l d Washer F o r m u l a t i o n

Wt%

Inqredi ents: W i t c o n a t e 1240 Isopropanol Water

51 e n d i ng P r o c e d u r e : D i s s o l v e W i t c o n a t e 1240 in w a t e r , F o r m u l a 867

1.o 39.0 60.0 t h e n add i s o p r o p a n o l

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s

188

Advanced Cleaning Product Formulations

Car Wash C o n c e n t r a t e w / A l c o h o l

Ethoxylate

I n q r e d ie n t s : Water, D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y P e t r o LBA L i q u i d DeSonic 81-6 W i t c a m i d e 128T B l e n d i n g Procedure:

64.9 8.3 16.7 1.3 5.0 3.8

Blend ingredients i n t h e order l i s t e d

Typical Properties: V i s c o s i t y , c p s : 210 A c t i v e s , %: 2 3 . 7 F o r m u l a 61 1 Car Wash C o n c e n t r a t e w / A l c o h o l

Ethoxylate

Ingredients: Water, D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y P e t r o LBA L i q u i d DeSonic 81-6 W i t c a m i d e 128T

W S 43.3

13.9 27.8 5.0 7.0 3.0

Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . T y p i c a l P r o p e r t ie s : V i s c o s i t y , c p s : 335 A c t i v e s , %: 37.5 F o r m u l a 611 Car Wash C o n c e n t r a t e w / A l c o h o l

Ethoxylate

I n a r e d ie n t s : Water, D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y P e t r o LBA L i q u i d DeSonic 81-6 W i t c a m i d e 128T

36.0 15.0 30.0 6.0 8.0 5.0

B l e n d i n g P r o c e d u r e : B1 end i n g r e d i e n t s i n t h e o r d e r 1 is t e d . Typical Properties: V i s c o s i t y , c p s : 315 A c t i v e s , %: 4 3 . 0 F o r m u l a 611 SOURCE: W i t c o C o r p . :

Suggested F o r m u l a t i o n s

Car and Truck Wash Compounds

C a r and T r u c k Wash F o r m u l a Ingredients: C a l f a x DB-45 C a l s o f t L-40 T r i s o d i um Phosphate Water

Wei q h t % 19.83 24.95 10.02 45.18

Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-001-01 Car a n d T r u c k Wash F o r m u l a Ingredients: C a l f a x DB-45 C a l s o f t L-40 D i s o d i um Phosphate Water

Wei q h t % 20.00 25.17 10.04 44.76

Comments a b o u t t h i s f o r m u l a : 1 . T h i s i s l o w e r p H f o r m u l a t h e n CWC-001-01. 2 . H e a t i n g i s n e c e s s a r y t o homogenize. F o r m u l a t i o n CWC-002-01 Car Wash [Powder) Ingredients: Sodi um T r i p o l y p h o s p h a t e C a l s o f t F-90 Cal o x y l a t e N-9

Wei q h t % 85.00 5.00 10.00

Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-003-01

C a r Wash ( C a l s u d s A-Based) Inqredients: Calsuds A C a l foam EA-603 C a l o x y l a t e N-9 Water Comments a b o u t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-004-01 SOURCE: B1 io t Chemi c a l Co. : Suggested F o r m u l a t i o n s

Wei g h t % 50.00 3.00 2.00 45.00

189

190

Advanced Cleaning Product Formulations

Car Wash and Care Car Shampoo with Water-Repellent Effect Wt%

Ingredients: Autopur WK 4332 Amphotensid 0 4 Water Formula CT 0 4 - 0 3 - 0 2

45.0 5.0 50.0

Rinse-off ARent (Water-Repellent) wtu/, 17.0 6.0 6.0 3.0 8.0 60.0

Ingredients: Autopoon GK 4004 Mulsifan RT 1 Produkt 2058 Pine oil Butyl di glycol Water Formula CT 0 4 - 0 5 - 0 7

Rinse-off Aqent (Water-Repellent) Without Hydrocarbons Wt%

Ingredients: Autopoon GK 4008 Mulsifan RT 1 Produkt 2058 Butyl di glycol Water Formula CT 04-05-03

17.0 6.0 6.0 8.0 63.0

Windshield-Cleaner (Summer) Wt%

Inqredi ents: Water Ethanol Zusol at 1 0 0 5 / 8 5 Zusolat 1 0 0 8 / 8 5 Formula CT 0 4 - 0 6 - 0 1

67.9 20.0 5.2 6.9

Innredi ents: Water Zetesol NL Zusol at 1 0 0 8 / 8 5 Isopropanol Formula CT 0 4 - 0 6 - 0 4

23.7 64.0 1.3 11 . o

SOURCE: Zschimmer & Schwarz GmbH &

Wt%

Co.: Suggested Formulations

Car and Truck Wash Compounds

Car Wash and C a r e Windshield-Cleaner

(Winter)

Wtl

Ingredients: Water Isopropanol Z e t e s o l 2056 F o r m u l a CT 04-06-07

29.5 70.0 0.5

I n s e c t Remover

Wt%

Inqredi ents: S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 Trilon A liquid Monoethanol ami ne Butyl d i g l ycol Water F o r m u l a CT 04-07-01

4.0 2.0 2.0 4.0 4.0 5.0 79.0

Wheel C 1 e a n e r

. A 1 k a l in e

Ingredients: Water Tetrapotassium pyrophosphate Lumorol 4192 Z u s o l a t 1005/85 Butyl diglycol Orange t e r p e n e F o r m u l a CT 0 4 - 1 1 - 0 4

Wt% 77.5 3.0 10.0 4.0 5.0 0.5

T a r Remover Inqredients: M u l s i f a n K 326 S p e z i a l Whi t e - s p i r i t n-butanol Oleic acid Water F o r m u l a CT 04-13-02

SOURCE:

Zschimmer & Schwarz GmbH & C o . :

Wt% 15.0 60.0 7.0 3.0 15.0

General Formulations

191

192

Advanced Cleaning Product Formulations

Car Wax

Wt%

Ingredient: Part A: Morphol ine Water

0.8 44.2

P a r t B: Wax S Oleic Acid M i n e r a l Spi r i t s Kerosene

8.0

1.o 18.0

9.0

Part C: M a s i l EM 250 C M a s i l EM 1 0 , 0 0 0 C Snow F l o s s Kaopol it e SF Carbopol 941 ( 1 % i n w a t e r )

10.0 3.0 3.0

3.0 As needed

Procedure: 1 . Add t h e m o r p h o l i n e t o t h e w a t e r w i t h h i g h speed m i x i n g . 2 . I n P a r t B , add t h e o l e i c a c i d , m i n e r a l s p i r i t s , kerosene, and Wax S w i t h h i g h speed m i x i n g . Add P a r t B t o P a r t A w i t h h i g h shear m i x i n g . 3 . Add t h e M a s i l EM 250 C and M a s i l EM 10,000 C f r o m P a r t C t o t h e c o n c e n t r a t e w i t h s l o w m i x i n g . Add t h e Snow F l o s s and K a o p o l i t e S F . T h i c k e n w i t h t h e Carbopol 941 s o l u t i o n . A u t o Wipe B S h i n e P o l i s h Ingredient; Part A: M a s i l SF 100 A-C 617A Oleic Acid M i n e r a l O i 1 , 70 SUS

3.5

2.0 1.5

5.6

Part 0 : Morphol ine Carbopol 934 Triethanolamine Water

1.4 0.2 0.2 85.6

Procedure: 1 . Add t h e i n g r e d i e n t s i n P a r t A as l i s t e d and h e a t t o 9OC. 2 . F o r P a r t B, h e a t t h e w a t e r t o 85C. D i s p e r s e t h e Carbopol 934 i n t h e w a t e r . When c o m p l e t e l y d i s s o l v e d , add t h e t r i e t h a n o l amine. Then, add t h e m o r p h o l i n e . 3. Add P a r t A t o P a r t 0 and b l e n d .

SOURCE: PPG I n d u s t r i e s ,

I n c . : Suggested F o r m u l a t i o n s

Car and Truck Wash Compounds

193

Concentrated T r a f f i c F i l m Removers Two f o r m u l a t i o n s were d e v e l o p e d w h i c h c o n t a i n 50% t o t a l w a t e r , i n c l u d i n g t h e w a t e r i n t h e sodium m e t a s i l i c a t e p e n t a h y d r a t e . One c o n t a i n s n o n i o n i c , t h e o t h e r h a s no n o n i o n i c b u t has more AO-14-2 and A l k a l i S u r f a c t a n t , t h e c o m b i n a t i o n o f w h i c h s h o u l d do as w e l l as t h e n o n i o n i c f o r h a r d s u r f a c e c l e a n i n g . Mix i n t h e order given: Formula 1: Component: Water Versene 1 0 0 Sodium M e t a s i l i c a t e P e n t a h y d r a t e Tomah A l k a l i S u r f a c t a n t Tomah AO-14-2 Tomah Q-17-2

Wt% 22.00

38.00 8.00 16.00 8.00 8.00

% anhydrous b u i l d e r :

19.00 S u r f a c t a n t / b u i l d e r r a t i o : 1.68

Mix i n t h e order given: Formula 2 : Component: Water Versene 100 Sodium M e t a s i l i c a t e P e n t a h y d r a t e Tomah A l k a l i S u r f a c t a n t Tomah AO-14-2 Tomah Q-17-5 Noni o n i c NP-9.5

Wt.% 36.20 19.70 4.10 10.00 10.00 10.00 10.00

% anhydrous b u i l d e r : 9.82% S u r f a c t a n t / b u i l d e r r a t i o : 4.07

N o t e t h a t sodium m e t a s i l i c a t e p e n t a h y d r a t e i s a c t u a l l y a b o u t 57% sodium m e t a s i l i c a t e on an anhydrous b a s i s . Versene 100 i s a b o u t 38% t e t r a s o d i u m EDTA on an a n h y d r o u s b a s i s . Thus t h e s e f o r m u l a t i o n s a r e a b o u t 50% t o t a l w a t e r when c a l c u l a t e d on an a n h y d r o u s b u i l d e r b a s i s . The s u r f a c t a n t s were c o n s i d e r e d on an a s - i s b a s i s , and n o t c o r r e c t e d f o r t h e w a t e r c o n t e n t . Anhydrous sodium m e t a s i l i c a t e and a n h y d r o u s t e t r a s o d i u m EDTA a r e r e a d i l y a v a i l a b l e ; a n h y d r o u s a m p h o t e r i c s and amine o x i d e s are not. These f o r m u l a t i o n s were made up and f o u n d t o b e f r e e z e - t h a w s t a b 1 e. F o r m u l a 1 was d i l u t e d 1/20 w i t h w a t e r t o 2.5% a c t i v e s , and t e s t e d b y s p r a y i n g on a d i r t y c a r . It was compared w i t h F o r m u l a t i o n T-107 T r a f f i c F i l m Remover a l s o a t 2.5% a c t i v e s . No s i g n i f i c a n t d i f f e r e n c e s were seen, so t h e absence o f n o n i o n i c d i d n o t adversely a f f e c t t h e performance o f t h e concentrated f o r m u l a t i on. SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s

194

Advanced Cleaning Product Formulatioris

Foamy B r u s h Car Wash,

Liquid

Inqredients: Water, D . I . * C a u s t i c Soda, 50% W i t c o 1298SA W i t c o l a t e SE-5 P e t r o BAF L i q u i d W i t c a m i d e 128T Formal i n Sodi um C h l o r i d e

Wtg

79.75 1.40 5.00 7.00 3.00 3.00 0.10

0.75

Blending Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d . used t o a d j u s t v i s c o s i t y o f t h e p r o d u c t .

Sodium C h l o r i d e i s

T y p i c a l P r o p e r t i es : S p e c i f i c G r a v i t y : 1.015 Wt./Gal. l b s . : 8.46 pH, a s i s : 9 . 8 V i s c o s i t y , cps: 410 D i l u t i o n R a t i o a t Wand=l : 4 0 * I f u n s o f t e n e d t a p w a t e r i s used, t o counteract hardness. F o r m u l a 621

add 0 . 2 5 % l i q u i d EDTA,

40%

Low C o s t Car=

Wt%

Ingredients: Water. D . I . P e t r o LBA Powder W i t c o l a t e SE-5 W i t c a m i d e 128T Formal in Sodi um C h l o r i d e Perfume, Dye

89.9 1 .o 6.0 3.0 0.1 4.s. 4.s.

Blending Procedure: Blend t h e i n g r e d i e n t s i n t h e order l i s t e d . A d j u s t t h e p H = 7 . 5 - 8 . 0 . The Sodium C h l o r i d e i s used t o a d j u s t t h e v i s c o s i t y o f the f i n a l product. F o r m u l a 609

SOURCE: W i t c o C o r p . :

Suggested F o r m u l a t i o n s

Car and Truck Wash Compounds

195

G e n e r a l Purpose C a r Wash T h i s i s a c o p i o u s - f o a m i n g , a l l - p u r p o s e c a r wash f o r m u l a t e d t o b e s a f e on c a r f i n i s h e s , y e t e f f e c t i v e i n t h e removal o f r o a d g r i m e and o t h e r s o i l s . Insredient : D e i o n i z e d Water Mazon 98 Macol TD-3 W i t c o l a t e WACLA Mazamide 80 Macol 48 Triethanolamine, D e i o n i z e d Water

w b 50.0 9.5 1.5 2.5 3.0 1.o 1.5 31 . O

85%

pH ( a s i s ) : 8 . 5 - 9 . 5 Appearance: C l e a r , l i g h t - y e l l o w S p e c i f i c G r a v i t y : 1.02

liquid

Procedure: Charge t h e f i r s t p o r t i o n o f w a t e r t o a m i x i n g v e s s e l and s t a r t slow a g i t a t i o n (excessive a g i t a t i o n w i l l produce a f o a m i n g p r o b l e m ) . Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d and m i x u n t i l c l e a r . NOTE: Use c o n c e n t r a t i o n i s 1-2 ounces p e r g a l l o n o f warm w a t e r . F o r m u l a t i o n CA-103

L i q u i d Car Wash

NtS

Ingredient: Water W i t c o n a t e 60 T L i q u i d Macol OP-10 SP Mazamide 80 Hexyl Carbi t o 1 Methanol

34.0 30.0 10.0 6.0 10.0 10.0

Procedure: Add i n g r e d i e n t s i n o r d e r a s l i s t e d .

~

B o a t Wash & CarPCleaner ~~

~~~~

vvt%

Ingredient: Water Mazamide 80 Macol NP 9 . 5 W i t c o n a t e 60 T L i q u i d

39.0 11 . o 5.0 45.0

Procedure: Add i n g r e d i e n t s i n o r d e r as l i s t e d . SOURCE: PPG I n d u s t r i e s ,

I n c . : Suggested F o r m u l a t i o n s

196

Advanced Cleaning Product Formulatiom

Heavy D u t y T r u c k Wash, L i q u i d Inqredients: Water, D . I . T r i s o d i um Phosphate, C r y s t a l C a u s t i c Soda Beads W i t c o 1298 S o f t A c i d P e t r o BAF L i q u i d Sodium S i l i c a t e 40 Be' ( S t a r ) W i t c o l a t e SE-5 E t h y l e n e G l y c o l M o n o b u t y l E t h e r (EB) Emcol 6744

70.0 2.0 2.0 10.0 3.0 3.0 3.0 3.0 4.0

Blending Procedure: B l e n d i n g r e d i e n t s in o r d e r 1 i s t e d . Typical Properties: S p e c i f i c G r a v i t y : 1.042 Wt./Gal. l b s . : 8.69 pH, a s i s : 1 2 . 7 D i l u t i o n R a t e : D i l u t e 1 : 4 0 a t Wand F o r m u l a 603

Heavy D u t y T r u c k Wash,

Powder

Inqredients: Sodi um C a r b o n a t e (Soda A s h ) , L i g h t D e n s i t y Sodium T r i p o l y p h o s p h a t e , L i g h t D e n s i t y DeSophos 5AP DeSonic 9N Sodium M e t a s i l i c a t e , Anhydrous Sodium S u l f a t e ( S a l t Cake) C a u s t i c Soda Beads Dye*

wtd/, 47.25 55.00 2.90 7.50 5.00 10.00 2.30 0.05

B1 e n d i ng P r o c e d u r e : P r e m i x Soda Ash and T r i p o l y t o g e t h e r and s l o w l y add DeSophos 5AP w h i l e m i x i n g . M i x u n t i l p r o d u c t i s u n i f o r m i n a p p e a r a n c e . Add DeSonic 9 N w h i l e m i x i n g . M i x u n t i l t h e p r o d u c t l o o k s d r y ( 4 - 5 m i n u t e s ) . Add M e t a s i l i c a t e , S a l t Cake and t h e n C a u s t i c Soda beads. * I f d y e i s used, m i x w i t h t h e DeSonic 9N. F o r m u l a 604 SOURCE: W i t c o C o r p . :

Suggested F o r m u l a t i o n s

Car and Truck Wash Compounds

197

Premium Car Wash C o n c e n t r a t e

Wt%

Ingredients: Water, D . I . Ethanol Varox 1 7 7 0 W i t c o n a t e AOS L i q u i d W i t c o l a t e SE-5

11.7

5.9 17.6 46.8 17.6

B l e n d i ng P r o c e d u r e : Add a l l i n g r e d i e n t s e x c e p t W i t c o l a t e SE-5, i n o r d e r shown and d i s s o l v e completel’y between each a d d i t i o n . Add W i t c o l a t e SE-5 l a s t i n s m a l l a l i q u o t s a l l o w i n g c o m p l e t e d i s s o l u t i o n between additions. T y p i c a l P r o p e r t i es : V i s c o s i t y , c p s : 160 S o l i d s : 35.4% pH: 8.4 Formula 629 Car Wash Ingredients: Water T e t r a p o t a s s i um Pyrophosphate, W i t c a m i de 6445

Wt% 60%

91.67 3.33 5.00

51ending Procedure: Blend i n g r e d i e n t s i n o r d e r l i s t e d . T y p i c a l P r o p e r t i es : V i s c o s i t y , cps: 2100 S o l i d s : 6.8% pH, as i s : 9 . 3 Formula 615 A u t o Shampoo C o n c e n t r a t e

P n g r e d ie n t s : Water, D . I . R e w o t e r i c AM KSF-40 W i t c o l a t e SE-5

Wt% 80.0 15.0 5.0

Blending Procedure: Add in g r e d i e n t s in o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n . Typical Properties: V i s c o s i t y , cps: 4.0 S o l i d s : 9.0% ptl: 9 . 5 Formula 628 SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s

198

Advanced Cleaning Product Formulations

T o u c h l e s s V e h i c l e Wash D e t e r a e n t l Z e r o Phosphate, Powder) Soil-Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s , road f i l m Surface-Painted metal surface, Polymeric A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) M a n u f a c t u r e - D r y B1 end/Aggl o m e r a t i on Composition: \nrt36 Sodium C a r b o n a t e 25-30 M e t s o Beads 2048 20-25 *Sodium P o l y a c r y l a t e (92% s o l i d s ) 1.0- 3.0 5-1 0 Surfactant T u r b o b r i t e A1 umi n o s i 1 ic a t e 25-35 F i 1l e r s Balance D i l u t i o n : 1.0-2.0% by weight ( 0 . 1 - 0 . 2 pounds/gallon) Add 0 . 1 - 0 . 2 pounds o f d e t e r g e n t p e r g a l l o n o f w a t e r o u t p u t t o t h e s p r a y n o z z l e . M i x powder d e t e r g e n t i n t a n k and m e t e r i n t o c a r wash s y s t e m . M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f T u r b o b r i t e i s e x t r e m e l y e f f e c t i v e i n h i g h p r e s s u r e s p r a y wash systems f o r r e m o v i n g o i l and w a t e r d e p o s i t s , p a r t i c u l a t e s o i l s , and haze f r o m body p a r t s and w i n d s h i e l d s . C o n s t a n t a g i t a t i o n i n t a n k i s n e c e s s a r y t o keep T u r b o b r i t e suspended. V e h i c l e Wash D e t e r g e n t (Low pH) ( Z e r o Phosphate. Powder) Soil-Grease, o i l , s a l t , water deposits, c l a y , p a r t i c u l a t e s , road f i l m . Surface-Painted metal surface, Polymeric A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) Manufacture-Dry blend/Agglomeration Composi t i on : Wt% Sodium C a r b o n a t e 27.9 B r i t e s i 1 H20 Hydrous Sodi um P o l y s i 1 i c a t e 21 . o * A c u s o l 445ND Sodi um Pol y a c r y l a t e (92% s o l id s ) 3.0 **Liquid Nonionic Surfactant 12.0 36.1 V a l f o r 100 Z e o l i t e A * D i l u t i o n : 1 . 5 % by w e i g h t ( 0 . 1 2 5 p o u n d s / g a l l o n ) Add 0 . 1 2 5 pounds o f d e t e r g e n t p e r g a l l o n o f w a t e r o u t p u t t o t h e s p r a y n o z z l e . D i s s o l v e powder d e t e r g e n t i n t a n k and m e t e r i n t o c a r wash s y s t e m . M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f V a l f o r 100 i s e x t r e m e l y e f f e c t i v e i n h i g h p r e s s u r e s p r a y wash s y s t e m s f o r r e m o v i n g o i l and w a t e r d e p o s i t s , p a r t i c u l a t e s o i l s , and haze f r o m body p a r t s and w i n d s h i e l d s . C o n s t a n t a g i t a t i o n i n t a n k i s n e c e s s a r y t o keep V a l f o r 100 suspended i n s o l u t i o n . Rohm & Haas Low Foam: Rhone-Poulenc A n t a r o x BL-330 ( 3 moles E O ) H i g h Foam: S h e l l Chemical Neodol 23-6.5 o r Neodol 25-7

*

**

SOURCE: PQ C o r p . :

Detergent F o r m u l a t i o n Guide

Car and Truck Wash Compounds

199

Truck/Bus Wash % by Weight 7

Components: Burco TME B u r c o s o l v TM Neodol 91-6

5 20 5 2

TEA 85%

Burcene 1 0 0 Water

8 a l ance

D i l u t e 50:l t o 1OO:l depending on degree o f s o i l t o be removed Economy Truck/Bus Wash % by Weight

Components: Water Burco TME Meodol 1.5 C i t r i c A c i d L i q u i d 50% KOH. 45% Ammonyx LO

76

TEA 85%

D i l u t e 20:l t o 50:l depending on degree o f s o i l t o be removed.

SOURCE:

B u r l i n g t o n Chemical Co.,

I n c . : Suggested F o r m u l a t i o n s

Car Shampoo I n g r e d ien t s : Z e t e s o l 2056 Lumo WW 75 Z u s o l a t 1008/85 P u r t o n CFD Water Formula D 1 1 / 1 0

% by Wei a h t

15.0 10.0

3.0

1. o 75.0

Car Wash and Wax Shampoo Ingredients: Zusol a t 1008/85 Wachsemul s i on 1864 Isopropanol Water, p r e s e r v a t i v e Formula D 12/2

SOURCE:

Zschimmer & Schwarz GmbH & Co.:

% by Weiqht 10.0 10.0 2.0 q . s . t o make 1 0 0 . 0

Suggested F o r m u l a t i o n s

200

Advanced Cleaniris Product Formulations

V e h i c l e Wash D e t e r g e n t e h o s p h a t e . Powder1 Soil-Grease, o i l , s a l t , water deposits, c l a y , p a r t i c u l a t e s , road f i l m Surface-Painted metal surface, Polymeric A p p l i c a t i o n Method-High p r e s s u r e s p r a y Manufacture-Dry blend/Agglomeration Composition A : We9/0 Metso Beads 2048 20.0 *STPP 40.0 *TSP 5.0 *Sodi um C a r b o n a t e 20.0 **Sodium A 1 k y l a r y l Sul f o n a t e Powder (90%) 5.0 * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-10; 6 Moles EO) 10.0 Composition 8: Wt% Metso Pentabead 20 30.0 *STPP 44. 0 *Sodi um C a r b o n a t e 10. 0 CMC 1 0 **Sodium A l k y l a r y l S u l f o n a t e Powder (90%) 5 0 5 0 * * * * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 7-8 Moles EO *****Octylphenoxy P o l y e t h o x y e t h a n o l , 5 Moles EO 5 0 Use D i l u t i o n : 1 . 5 % b y w e i g h t ( 0 . 1 2 5 p o u n d s / g a l l o n ) D i s s o l v e i n s t o c k t a n k and meter i n t o wash system. Compos P i on 6 can be u t i l i z e d i n h i g h p r e s s u r e s p r a y carwash systems and s u p p l i e s adequate s o i l r e m o v a l . FMC Witco Rhone-Poulenc Rhodasurf 91-6 Rhone-Poulenc I g e p a l CA-620 Rhone-Poulenc I g e p a l CA-520

* ** *** ****

*****

V e h i c l e Wash D e t e r g e n t ( L i q u i d , low foam) Soil-Grease, o i l , s a l t , water deposits, c l a y , p a r t i c u l a t e s , road f i l m Surface-Painted metal surface, Polymeric A p p l i c a t i o n Method: H i g h p r e s s u r e s p r a y (700-1400 p s i ) Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composi t i on : Wt% Water 79.0 2.0 Metso Beads 2048 *Sodium P o l y a c r y l a t e (40%) 5.0 **Sodium X y l e n e S u l f o n a t e (40%) 8.0 * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 6 Moles EO) 3.0 3.0 * * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles € 0 ) Use D i l u t i o n : 10% bw ( 1 3 o z / g a l l o n ) Rhone-Poulenc C o l l o i d 226/35 (40%) Stepan, W i t c o Rhone-Poulenc R h o d a s u r f 91-6 Rhone-Poulenc Rhodasurf A-24 SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide

* ** ***

****

Car and Truck Wash Compounds

201

V e h i c l e Wash D e t e r g e n t (Low PH) ( Z e r o Phosphate, L i q u i d ) Soil-Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s , road f i l m Surface-Painted metal s u r f a c e , Polymeric Appl ic a t i on Method-Hi gh p r e s s u r e s p r a y (700-1400 p s i ) Manufacture-Mix t a n k w i t h p r o p e l l e r spray Composi t i on : Wt% Water 51.66 Carbopol 674 0.5 D L i q u i d Sodium S i l i c a t e 8.1 *Acusol 445N Sodi um P o l y a c r y l a t e (45% s o l i d s ) 1.84 9.1 Sodium Carbonate T u r b o b r i t e A 1 umi n o s i 1 ic a t e 24.5 * * L i q u i d Nonionic Surfactant 4.3 D i l u t e l i q u i d d e t e r g e n t w i t h w a t e r ( 1 g a l l o n d e t e r g e n t : 64 g a l l o n s w a t e r ) and d e l i v e r t o h i g h p r e s s u r e s p r a y wash system. M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f T u r b o b r i t e i s e x t r e m e l y e f f e c t i v e i n removing o i l , p a r t i c u l a t e s o i l s , w a t e r d e p o s i t s , and haze f r o m body p a r t s and w i n d s h i e l d . Rohm & Haas Low Foam: Rhone-Poulenc A n t a r o x BL-240 H i g h Foam: S h e l l Chemical Neodol 23-6.5 o r Neodol 25-7

* **

T o u c h l e s s V e h i c l e Wash B o o s t e r / A d d i t i v e L Z e r o Phosphate, L i q u i d ) Soil-Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s , road f i l m Surface-Painted metal s u r f a c e , Polymeric A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r Composition: Wt% T u r b o b r i t e L (25 w t . % a c t i v e T u r b o b r i t e A l u m i n o s i l i c a t e S1u r r y ) 100.0 D i l u t e l i q u i d T u r b o b r i t e L a t h i g h p r e s s u r e pump w i t h w a t e r ( 1 g a l l o n d e t e r g e n t : 128 g a l l o n s w a t e r ) and d e l i v e r t o h i g h p r e s s u r e s p r a y wash system. M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f T u r b o b r i t e i s e x t r e m e l y e f f e c t i v e i n removing o i l , p a r t i c u l a t e s o i l s ( c l a y s , c a r b o n b l a c k , b r a k e d u s t ) , w a t e r d e p o s i t s , and haze f r o m body p a r t s and w i n d s h i e l d . T u r b o b r i t e L can be used as an a d d i t i v e o r b o o s t e r f o r conv e n t i o n a l t o u c h l e s s , h i g h p r e s s u r e carwash o r f l e e t w a s h d e t e r gents. O r make a d e t e r g e n t by b l e n d i n g T u r b o b r i t e L w i t h 1-2% lowfoaming n o n i o n i c s u r f a c t a n t t o make f o r b e s t c l e a n i n g r e s u l t s . D i l u t e T u r b o b r i t e L / s u r f a c t a n t b l e n d a t h i g h p r e s s u r e pump w i t h w a t e r (128: 1 ) . T u r b o b r i t e L a l s o works i n waxes, p o l i s h e s , and o t h e r d e t a i l ing p r o d u c t s .

SOURCE:

PQ C o r p . : D e t e r g e n t F o r m u l a t i o n G u i d e

17. Whitewall Tire Cleaners

202

Whi tena 1 1 Ti.r&C!ean.ey

1z e ro

.P.b-s phate -?.w&cl

Soil-Clay, p a r t i c u l a t e , o i l , grease Surface-Whitewal 1 t i r e s Application Method-High pressure s p r a y / b r u s h / w i p e M a n u f a c t tire - D r y b 1 end/Agg 1 o m e r a t i On

Nt%

c_q.m3osi t i . o n l

35.0

Valfor 100 Zeolite A

* A c u s o l 4 4 5 N D Sodium P o l y a c r y l a t e ( 9 2 % Solids) * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cll; 6 M o l e s E D ) Sodium A l k y l a r y l S u l f o n a t e M e t s o Beads 2 0 4 8 Sodium Carbonate Rohm & Haas Rhone-Pou 1 e n c R h o d a s u r f 91 - 6

* **

wi j.t.ew a n-T i.r,e

2.0

8.0 10.0

35.0 12.0

C L Y C ~e 1:

1Pbes?batePowde.!’l

Soil-Clay, p a r t i c u l a t e , o i l , g r e a s e Surface-Whi tewal1 t i r e s Application M e t h o d s - H i g h

pressure spray/brush/wipe

Manufacture-Dry blend

Y!%.t

Cs-mmeo s.i.t j P.V :.

*STPP

**tiquid

Noninnic Surfactant

(C9-Cll; 6 nroles € 0 )

GTSP

Sodium A l k y l a r y l Sulfonate Met50 B e a d s 2 0 4 8

*

45.0 5.0 10.0 10.0

30.0

FMC

* a R h o n e - P o u l e n c Rhodasurf 91 -6

WRitewal..1..Ti re,&!ea_n_er (.Lictuj.d). Soil-Clay, p a r t i c u l a t e , o i l , p r e a s e Surface-Whi tewall tires A p p l i c a t i o n Method-High p r e s s u r ’ e s p r a y / b r u s h / w i p e M a n u f a c t u r e - M i x t a n k w i t h propeller s t i r r e r C o m q . ~!.f.bn: S

Water Potassium H y d r o x i d e 145%) N C l e a r o r S t a r Sodium Silicate S o d i uni A 1 k y l a r y l Sulfonate ( 6 0 % ) * L i q u i d N o n i o n i c S u r f a c t a n t (CS-Cll; 6 m o l e s E O ) * R h o n e - P o u l e m R h o d a s u r f 91 - 6

S O U R C E : FQ Corp. : D e t e r g e n t F o r m u l a t i o n G u i d e

flL?b 70.0 16.0 10.0 2.0 2.0

18. Miscellaneous

204

Miscellaneous

205

A i r c r a f t Cleaner (Reduced Phosphate. Powder) Soi 1 - P a r t i c u l a t e s , c a r b o n b l a c k , p e t r o l e u m o i 1 and grease Surface-Aluminum, m e t a l A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) Manufacture-Dry b l e n d / A g g l o m e r a t i on Composi t i on : Metso Pentabead 20 V a l f o r 100 Z e o l i t e A Ammoni u m B i f 1u o r ide TSPP *Sodi um A1 k y l naphtha1 ene Sul f o n a t e **Sodium A l k y l a r y l S u l f o n a t e Powder (90%) Use D i l u t i o n :

*

**

1.5-6.096

bw (2-8

Wt% 30.0 30.0

8.0 20.0

8.0 4.0

oz/gallon)

Rhone-Poulenc S u p r a g i l N K Witco

N o t e : C o n s t a n t a g i t a t i o n i s r e q u i r e d i n s t o c k t a n k t o keep V a l f o r 100 suspended i n s o l u t i o n . May use 0.25% w t Carbopol 647 (BFGoodrich) as a suspending a g e n t .

A i r c r a f t 61 eaner (Phosphate, Powder) S o i l - P a r t i c u l a t e s , c a r b o n b l a c k , p e t r o l e u m o i l and grease Surface-Metal A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) M a n u f a c t u r e - D r y b l end/Aggl o m e r a t i on Composi t i on : Metso Pentabead 20 *STPP Ammonium B i f l u o r i d e *TSPP **Sodium A1 k y l n a p h t h a l e n e S u l f o n a t e ***Sodi um A1 k y l a r y l Sul f o n a t e Powder (90%) Use D i l u t i o n : 1 . 5 - 6 . 0 % bw ( 2 - 8 o z / g a l l o n )

* ** *%Xc

FMC DeSoto, Witco

Inc.

OURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide

Wt% 30.0 30.0

8.0 20.0 8.0 4.0

206

Advanced Cleaning Product Formulations

A u t o Care:

I n t e r i o r / E x t e r i o r Rubber B V i n y l P r o t e c t a n t

F u n c t i ons 8 Benef it s : Pemul an 1622 : *Primary e m u l s i f i e r f o r s i l i c o n e o i l *NO s u r f a c t a n t s and no s o l v e n t s r e q u i r e d e q u a l s z e r o VOC *Imparts y i e l d value f o r v e r t i c a l c l i n g * E x c e l l e n t w e t t i n g f o r " s p r a y and no-wipe" a p p l i c a t i o n s *Improved d u r a b i l i t y and w a t e r - r e s s t a n c e Good-Rite K-752: * R e d u c t i o n i n emu1s i on v i s c o s i t y w t h o u t l o s s i n s t a b i l i t y

Wtl

I n q r e d ient : D I water Pemulen 1622* 1000 c S t s i l i c o n e o i l * * DC Q2-5211*** T r i e t h a n o l a m i n e (99%) Good-Rite K-752 (63%)****

78.55 0.20 20.00 0.50 0.25 0.50

* E m u l s i f i e r : BFGoodrich * * P r o t e c t a n t : DC 200 F l u i d : Dow C o r n i n g * * * S u p e r - w e t t i n g a g e n t : DC (12-5211: Dow C o r n i n g * * * * V i s c o s i t y r e d u c t i o n : BFGoodrich Physical Properties: B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 150 CP P r o d u c t pH: 5.5-6.0 P r o d u c t C l a r i t y : Opaque Procedure: 1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n t h e Pemulen r e s i n i n t o t h e D I w a t e r . Mix t h e s l u r r y f o r appr o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogeneous. 2. Add t h e s i l i c o n e f l u i d w i t h good a g i t a t i o n . 3. Add t h e DC Q2-5211 s u p e r - w e t t i n g a g e n t w i t h moderate a g i t a t i o n 4 . Add t h e t r i e t h a n o l a m i n e w i t h moderate a g i t a t i o n . 5 . Reduce a g i t a t i o n and add t h e Good-Rite K-752 p o l y m e r . The v i s c o s i t y w i l l d r o p f r o m a b o u t 3,000 CP t o <200 CP w i t h t h i s addition. 6. A d j u s t t h e pH w i t h a d d i t i o n a l t r i e t h a n o l a m i n e , i f n e c e s s a r y . 7 . Add f r a g r a n c e and c o l o r , as d e s i r e d .

SOURCE: BFGoodrich S p e c i a l t y Chemicals:

DET-512

Miscellaneous

207

Boat Polish I n a d d i t i o n t o t h i c k e n i n g , Carbopol r e s i n s i m p a r t y i e l d v a l u e a l l o w i n g p a r t i c l e s , such as a b r a s i v e s , t o become p e r m a n e n t l y suspended. The r e s i n a l s o p r e v e n t s "creaming" o r phase separa t i o n by suspending and s e p a r a t i n g t h e o i l d r o p l e t s .

Wt%

Inqredi ent :

37.80 0.20 2.50 2.00 1.50 2.50 10.00 6.00 5.00 1.50 8.50

#I Water Carbopol EZ-2 ( 1 ) Morphol ine SF96 S i l i c o n e F l u i d (350) ( 2 ) V i s c a s i l F l u i d (10,000) ( 2 ) Oleic Acid Mineral S p i r i t s Hoechst Wax E (3) M i n e r a l Spi r i t s SF1 706 React ive A m i ne Polymer Kaopolite kaolin clay (4) Physical P r o p erties: B r o o k f ie l d V i s c o s i t y (RVT-20 rpm) : 7,200 cps P r o d u c t pH: 9.00 P r o d u c t C l a r i t y : Opaque Raw M a t e r i a l S u p p l i e r s : ( 1 ) BFGoodrich ( 2 ) General E l e c t r i c ( 3 ) Hoechst Celanese (4) Kaopolite, Inc.

Procedure: 4 . D i s p e r s e t h e Carbopol i n t o t h e w a t e r by s i m p l y "dumping" i t i n . The polymer w i l l wet o u t i n a few m i n u t e s . 2 . Add t h e m o r p h o l i n e , m i x w i t h good a g i t a t i o n . Heat t o 60-65C. 3 . I n a s e p a r a t e v e s s e l , combine t h e s i l i c o n e f l u i d , V i s c a s i l , o l e i c a c i d , and t h e wax i n t h e m i n e r a l s p i r i t s . Heat t o 90-95C u n t i l t h e wax m e l t s and t h e m i x t u r e appears homogeneous. Add to t h e above m i x t u r e w i t h good m i x i n g . 4 . When homogeneous, c o o l t o 60-65C. 5. I n a s e p a r a t e v e s s e l , combine t h e m i n e r a l s p i t i t s and t h e r e a c t i v e amine p o l y m e r . Add t o t h e above m i x t u r e w i t h h i g h shear m i x i n g . 6. S l o w l y add i n t h e c l a y . M i x u n t i l homogeneous. Total Actives: 1.50 T o t a l Wax : Total Silicone Fluid: 4.50 R e a c t i v e A m i ne Polymer : 2.00 Mineral S p i r i t s : 13.00 Abrasive: 12.00 $

~ BFGoodrich ~ ~S p e c i a~l t y Chemicals: ~ :

DET-520

208

Advanced Cleaning Product Formulations

C o n c r e t e Cleaner/Deqreaser

WtB

I n g r e d ie n t s : Water, D . I . Sodium T r i p o l y p h o s p h a t e T r i s o d i um Phosphate Varami de A-83 V a r o n i c DM55

81 . O 2.0 1.o

6.0 10.0

B l e n d i n g Procedure: Add i n g r e d i e n t s in o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t ion. T y p i c a l P r o p e r t i es : V i s c o s i t y , cps: 0 S o l i d s : 19.0% Formula 937 Garage F l o o r C1eaner

Wt%

I n s r e d ie n t s : Water T r i s o d i um Phosphate Emphos PS-236 W i t c o n a t e 45 L i q u i d

82.0 8.0 4.0 6.0

B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . A l l o w f o r complete b l e n d i n g between a d d i t i o n s . Formula 941 A c i d Rust Remover I n q r e d ients: Water, D . I . Phosphoric A c i d , C i t r i c Acid Varox 365

\Me% 86%

81 . O 15.0 3.0 1.o

B l e n d i n g Procedure: Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between each a d d i t i o n .

T y p i c a l P r o p e r t ies : V i s c o s i t y , cps: 4 S o l i d s : 16.2% pH: 1.3 Formula 1116

SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s

209

Miscellaneous

Concrete/Driveway

Cleaners

F o r l e a f and o t h e r t a n n i n s t a i n s - u s e as i s . Wet s p o t . S p r i n k l e FB Sodium P e r c a r b o n a t e o n t o s p o t . S c r u b i n and r i n s e w i t h hose when s p o t i s removed.

For O t h e r S t a i n s

Wt%

Component: Soda Ash (Dense) B r i t e s i 1 H-24 TSP Anhydrous B u r c o s p e r s e AP Powder Dry S u r f a c t a n t * FB-Sodi um P e r c a r b o n a t e

25 15 20 5 5 30

Wet s p o t . S p r i n k l e c l e a n e r o n t o a r e a . S c r u b i n and a l l o w t o s t a n d . R i n s e w i t h hose. *Sodium L a u r y l S u l f a t e , Sodium Dodecylbenzene S u l f o n a t e o r Sodium Cocoyl T a u r a t e s can b e used.

SOURCE:

B u r l i n g t o n Chemical C o . :

Suggested F o r m u l a t i o n

Neavv D u t y C o n c r e t e C l e a n e r ( P h o s p h a t e F r e e ) F o r m u l a 1C

Wt% 75.0 0.5 2.0 1.5 6.5 1.5 3.0 4.0 2.5 1.5 2.0

Water, D . I . EDTA, 38% Sodium M e t a s i l i c a t e , P e n t a h y d r a t e Sodium C a r b o n a t e (Soda Ash) W i t c a m i d e S-780 W i t c o n o l NP-120 B u t y l Cel l o s o l v e Mineral S p i r i t s KOH, 45% W i t c o n a t e SXS L i q u i d Pine O i l Blending Procedure: Blend i n g r e d i e n t s i n order l i s t e d , addition. Typical Properties: S p e c i f i c G r a v i t y : 1 .022 Wt./Gal. I b s . : 8.52 pH, as i s : 1 3 . 1 8 3 Freeze/Thaw C y c l e s : Passed 1 Week @ 52C: Passed 4 Weeks Room Temp: Passed S o l i d s : 13.5% Use D i l u t i o n : As s t r o n g as needed, SOURCE:

Witco Corp.:

F o r m u l a 949

m i x i n g w e l l a f t e r each

d e p e n d i n g on t y p e o f s o i l .

210

Advanced Cleaning Product Formulations

__ V i n y l Dressing

~Wt%

In g r e d i& Part A: M a s i l EM 250 C Dei o n i zed Water

30.0 30.0

P a r t 8: M a c o l NP 9 . 5 G1 y c e r i n e D e i o n i z e d Water Sodium B e n z o a t e

1.5 1.5 36.9 0.1

Procedure: 1 . To a m i x i n g v e s s e l , c h a r g e t h e M a s i l EM 250 C and s t a r t g e n t l e a g i t a t i o n . S l o w l y add t h e w a t e r s o a s n o t t o b r e a k t h e emu1 s i o n . 2 . I n a s e p a r a t e m i x i n g v e s s e l , c h a r g e t h e Macol NP 9 . 5 a n d g l y c e r i n e t o t h e water. Mix w i t h g e n t l e a g i t a t i o n u n t i l a l l components a r e d i s s o l v e d , and t h e s o l u t i o n i s f r e e o f " f i s h e y e s " . Charge t h e sodium b e n z o a t e a n d m i x u n t i l d i s s o l v e d . 3 . Under g e n t l e a g i t a t i o n , c h a r g e P a r t B t o P a r t A . C o n t i n u e m i x i n g g e n t l y t o a v o i d a i r e n t r a p m e n t . NOTE: T h i s f o r m u l a i s d e s i g n e d t o be u s e d " a s i s " as a d r e s s i n g f o r r u b b e r and v i n y l p r o d u c t s . I f d e s i r e d , UV a b s o r b e r s a n d o t h e r components may be added t o t h e f o r m u l a t i o n . F o r m u l a t i o n SV-101

Inqredient: M a s i l EM 1 0 , 0 0 0 M a s i l EM 2 5 0 C Macol NP 9 . 5 Glycerine B a r q u a t MB-50 Water

&% 10.0 18.0

C

2.0 1.5 0.1 68.4

Procedure: Add t h e s i l i c o n e e m u l s i o n t o a b l e n d e r . S l o w l y a d d a p o r t i o n o f t h e w a t e r and a g i t a t e . Add t h e M a c o l NP 9 . 5 and g l y c e r i n e . M i x f o r 10 m i n u t e s . Add t h e b a l a n c e o f t h e w a t e r a n d m i x f o r 15 minutes.

SOURCE:

PPG I n d u s t r i e s ,

Inc.:

Suggested F o r m u l a t i o n s

Section Ill demarked Raw Materials

211

212

Advanced Cleaning Product Formulations

A-C

617A

RAW MATERIAL

SOURCE

CHEMICAL DESCRIPTION Polyethylene

Allied

Acid Thickener

Cationi c surfactant

Tomah

A c r y s o l AS€-108

P o l y a c r y l a t e (40%)

Rohm&

Actinol

Tall o i l f a t t y acid

A r i zon

A c u s o l 445ND

Sodium p o l y a c r y l a t e (92% s o l i d s )

Rohm&

Acusol

Sodium p o l y a c r y l a t e

RohmB

Adogen 66

Anti-static

Witco

A 1 ip a l CO-128

Anionic surfactant

Rho ne -

A1 ip a l CO-436

Anionic surfactant

Rhone-

FA-I

479ND

Alkylaryl Alpha-Step

agent

Witco

S u l f o n i c A c i d (98%)

Stepan

MC-48

Alpha s u l f o methyl e s t e r

A 1 p h a - S t e p ML-40

Alpha s u l f o methyl e s t e r

Ammonyx LO

Amine o x i d e

Stepan

AMP-95

A m i nomethyl p r o p a n o l

Angus

A m p h o t e n s i d 84

Amphoteric s u r f a c t a n t

Zschim

A m p h o t e r i c SC

A m p h o t e r i c (35% a c t i v e )

Tomah

A m p h o t e r i c TC

Hydrotrope

Tomah

A n t a r o n FC-34

Amphoteric s u r f a c t a n t

Rhone-

A n t a r o x BL-240

L i q u i d nonion c s u r f a c t a n t

Rhone-

A n t a r o x BL-330

L i q u i d nonion c s u r f a c t a n t

Rhone-

A n t a r o x LF-330

Surfactant

Rhone-

Aristonate M

P e t r o l e u m s u l f o n a t e (61%)

Pi l o t

A r i s t o n a t e M-LF

Petroleum s u l fonate

Pilot

A r o m a t i c 150

Sol v e n t

Exxon

(37%)

Stepan

Aquamoll i n BC Powder

Trademarked Raw Materials

213

RAW MATERIAL Autopoon GK4004

CHEMICAL DESCRIPTION Blend o f s u r f a c t a n t s

SOURCE

Autopoon GK4008

Blend o f s u r f a c t a n t s

Zschim

A u t o p u r WK4332

Blend o f s u r f a c t a n t s

Zschim

Avanel S-30

Anionic surfactant

PPGMaz

Avanel S-70

Sodium l i n e a r a l k y l p o l y e t h e r

PPGMaz

Avanel S-74

Anionic surfactant

PPGMaz

Amine o x i d e (30%)

Lonza

B a r q u a t NIB-50

Q u a t e r n a r y ammonium compound

Lonza

BiQSOft D-62

Sodium a l k y l benzene s u l f o n a t e ( 6 0 % ) Stepan

B i o s o f t s-100

Alkylbenzene s u l f o n i c a c i d ,

B i o t e r g e AS-40

Sodium o l e f i n s u l f o n a t e (40%)

Stepan

B i o t e r g e PAS-8S

P r i m a r y a l k a n e s u l f o n a t e (40%)

Stepan

5;mrlOX

83-120

12

Zschim

linear

b q u i d Sodi um S i 1 ic a t e

Stepan

PO

B r i j 96

Surfactant

ICI

B r i t e s i 1 c20

Hydrous sodium p o l y s 1 i c a t e

PQ

B r i t e s i I H20

Hydrous sodium p o l y s 1 ic a t e

PQ

B r i t e s i 1 H24

Hydrous sodium p o l y s 1 i c a t e

PQ

Burl i n

Burcene I00 Burco BSGH-270

Proprietary t e x t i l e auxiliary

Burl i n

Burco WCS-SONF

Proprietary t e x t i l e auxiliary

Burl i n

NPS-225

Proprietary t e x t i l e auxiliary

Burl i n

NPS-816

Proprietary t e x t i l e auxiliary

Burl i n

SZS

Proprietary t e x t i l e auxiliary

Burl i n

Proprietary t e x t i l e auxiliary

Burl i n

LAF-6

21 4

Advanced Cleaning Product Formulations

RAW M A T E R I A L B u r c o l 117

CHEMICAL D E S C R I P T I O N Proprietary t e x t i l e auxiliary

SOURCE Burli n Burlin

B u r c o l i t e BSGH-255 B u r c o s o l v TM

Water s o l u b l e s o l v e n t m i x t u r e

Burli n

B u r c o s p e r s e AP Powder

S o d i um p o l y a c r y l a t e

B u r l in

B u r c o s p e r s e LP

Sodium p o l y a c r y l a t e s o l u t i o n

Burli n

B u r c o s p e r s e SP-60

Sodium p o l y a c r y l a t e

B u r l in

B u r c o t a s e LL-100

P r o p r i e t a r y d e t e r g e n t enzyme

Burl i n

B u r c o t a s e EP-60

P r o p r i e t a r y d e t e r g e n t enzyme

B u r l in

B u r c o t a s e SL-160

P r o p r i e t a r y d e t e r g e n t enzyme

Burli n

B u r c o t e r g e DG-40

Detergent concentrate

Burlin

B u r c o TME

Proprietary t e x t i l e a u x i l i a r y

Burl i n

B u r c o t r o p e 1250

Burlin

B u r c o w h i t e BBH-20

B u r l in

Burdac-114 Butyl Carbi t o 1

I n d u s t r i a1 s o l v e n t

UnCarb

Butyl Cellosolve

Ethylene g l y c o l monobutyl e t h e r

UnCarb

Calamide C

C o c o n u t d e r i v e d ami de

Pilot

C a l a m i d e CW-100

Coconut d i e t h a n o l a m i d e 100%

Pilot

C a l a m i d e CWT

Super ami de

Pilot

C a l a m i d e SM

Non-DEA 1 iq u i d ami d e

Pilot

C a l f a x DB-45

Sodium a l k y l ( b r a n c h e d ) d i p h e n y l o x i d e d i s u l f o n a t e 45%

Mona

C a l f a x 1OL-45

S o d i um a1 k y l ( 1 in e a r ) d i p h e n y l o x i d e d i s u l f o n a t e 45%

Mona

C a l foam EA-603

Liquid detergent

Pilot

Trademarked Raw Materials

215

RAW MATERIAL Cal foam ES-303

CHEMICAL DESCRIPTION Sodium l a u r y l e t h e r s u l f a t e (30%)

SOURCE

Cal foam SLS-30

Sodium l a u r y l s u l f a t e 30%

Pi l o t

Gal i mu1 se PRS

Emu1s i f ie r

Pilot

Caloxylate M-9

Nonyl p h e n o l e t h o x y l a t e ( 9 M o l e EO) P i l o t

C a l s o f t F-90

L i n e a r a1 k y l a t e s u l f o n a t e

Pilot

C a l s o f t L-40

Sodi um 1 inear a1 k y l benzene s u l f o n a t e 1 i q u i d 40%

Pilot

C a l s o f t L-60

Sodi um 1 inear a1 k y l benzene s u l f o n a t e p a s t e 60%

Pilot

Cal s o f t LAS- 99

L i n e a r a1 k y l benzene s u l f o n a c i d 99%

C a l s o f t T-60

TEA l i n e a r a l k y l benzene su f o n a t e 60%

Pilot

Calsuds A

Conc. b l e n d o f a n i o n i c d e t e r g e n t s and amides

Pilot

Calsuds CD-6

M o d i f i e d c o c o n u t diethanolamidelOO% P i l o t

Calsuds 8 1

Conc. b l e n d o f a n i o n i c d e t e r g e n t s and amides

Pilot

Carbi t o 1 Solvent

I n d u s t r i a l solvent

UnCarb

Carbopol 672

T h i c k e n i n g agent

BFGood

Carbopol 674

T h i c k e n i n g agent

BFGood

Carbopo 1 676

T h i c k e n i n g agent

BFGood

Ca r b o p o l 69 1

Suspension a i d

BFGood

Ca rbopo 1 934

Thickening agent

BFGood

Carbopol 940

Thickening agent

BFGood

Carbopol 941

T h i c k e n i n g agent

BFGood

Carbopol ETD 2623

Resin v i scosi t y m o d i f i e r

BFGood

Ca rbopol ETD 2691

Resin v i s c o s i t y m o d i f i e r

BFGood

C

Pilot

Pi l o t

216

Advanced Cleaning Product Formulations

RAW MATERIALS Carbopol EX-473

CHEMICAL DESCRIPTION (30%)

SOURCE:

V i s c o s i t y modi f i e r

BF600d

modi f ie r

BFGood

Carbopol EZ-2

V i scosi t y

C a r d i s 36 Wax

O x i d i z e d m i c r o c r y s t a l l i n e wax

Petrol

CDB C l e a r o n

C h l o r i n a t e d is o c y a n u r a t e

01 i n

C o l l o i d 225/35

P o l y a c r y l a t e (40%)

RAOPa@

Col 1o i d 226/35

P o l y a c r y l a t e (40%)

Rhone

Contraspum 300

G l y c o l e t h e r defoamer

Zschi e

S u p e r - w e t t i n g agent

DowCor

Dequest 2000

Organophosphorous p r o d u c t

I\iiCN7san

DeSonic LFD-97

Nonionic s u r f a c t a n t

DeSoto

DeSonic 5N

Nonioni c s u r f a c t a n t

DeSoto

DeSonic 9N

Detergent/degreaser

DeSoto

DeSonic 11N

Nonionic s u r f a c t a n t

DeSoto

DeSonic 81-6

Nonionic s u r f a c t a n t

DeSoto

DeSophos 5AP

Phosphate e s t e r

DeSoto

Cublen D50

DC (22-5211

Decanol

Diatomaceous E a r t h

Kaopol

D L i q u i d Sodium S i l i c a t e

PQCorp

D i p r o p y l e n e G l y c o l Monoethyl E t h e r S o l v e n t

Dow or Arc0

Dodigen 226 Dowanol DPM

Glycol ether

Dow

Dowanol DPnB

Glycol ether

Bow

Trademarked Raw Materials

21 7

RAW MATERIAL Dowanol EB

CHEMICAL DESCRIPTION Ethylene glycol n-butyl ether

SOURCE

Dowanol PM

P r o p y l e n e g l y c o l methy

Dow

Dowanol PnB

Glycol ether

Dow

Dowanol TBA

Glycol ether

Dow

Dowanol TPM

T r i p r o p y l e n e g l y c o l me

ether

ether

Dow

Dow DowCor

Dow C o r n i n g 20 R e l e a s e C o a t i n g Dowfax 382

S o d i um n - d e c y l d i p h e n y l o x d e d i s u l f o n a t e (45%)

Dow

Dowicide A

Sodium o - P h e n y l p h e n a t e

Dow DowCor

Dow 200 S i l i c o n e F l u i d ( 1 0 0 0 c S t ) Dowfax 2A1

S o d i um d o d e c y l d i p h e n y l o x i de d i s u l f o n a t e (45%)

Dow

Dowfax 382

Anionic surfactant

Dow

D r e s i n a t e 91

R o s i n soap

Hercul

E L i q u i d Sodium S i l i c a t e

PQ W itco

Emcol 4500

W e t t i n g agent

Emcol 6744

Surface-active

E m e r s o l 213

Oleic acid

Henkel

Emphos PS-236

Phosphate e s t e r s u r f a c t a n t

Witco

Emphos PS-331

Phosphate e s t e r s u r f a c t a n t

W itco

Emphos 5AP

Phosphate e s t e r s u r f a c t a n t

Witco

E m u l s i f i e r F o u r HF

D i a1 k y l q u a t e r n a r y ( 7 5 % a c t i v e )

Tomah

Emul s i f ie r 827

Mixed d i a l k y l

Tomah

agent

q u a t e r n a r y (75% a c t )

Witco

Emul s i o n C340

Tomah

Epsom S a l t

PQ

218

Advanced Cleaning Product Formulations

RAW MATERIAL Ethylene G l y c o l n-Butyl

CHEMICAL DESCRIPTION SOURCE Ether Solvent Dow or Union @ a r b

E u p e r l a n PK-771

P e a r l iz i ng a g e n t (47%)

Henkel

Foam B o o s t e r 14

Def oamer

Tornah

Gafac RE-40

Anionic surfactant

Rhone

Gafamide CDD 518

Ethanolamide

Rhone

Genagen LAB

C12C14 a l k y l d i m e t h y l b e t a i n e

Hoechs

Genapol OA-80

Alcohol ethoxylate

Hoechs

Genapol UD-030

C11 0x0 e t h o x y a t e ( 3 moles EO)

H Q ~ C ~ S

Genapol UD-080

A l c o h o l ethoxy a t e

Hoechs

Genapol ZRO l i q u i d

Alkyltriglycol

Genapol 2908

Alcohol ethoxylate

Hoechs

G e o r g i a M a r b l e W h i t e #8 c a l c i u m c a r b o n a t e

GaMarb

G l u c o n i c A c i d S o l u t i o n (50%)

Ashlan

G1 ucopon 425CS

C8-16 a l k y l p o l y g l y c o s i d e (50%)

Henkel

Good-Ri t e K-752

V i s c o s i t y reducer

BFGood

Good-Rite K-7058

5800 MW p o l y a c r y l i c a c i d

BFGood

ether sulfate soln

Hoechs

G l y c o l E t h e r DPM G l y c o l E t h e r PM

GP-RA-159

S i 1 icone P o l ish A d d i t i v e

Genes

GP-121 S i l i c o n e P o l i s h A d d i t i v e

Genes

GP-227 S i l i c o n e S u r f a c t a n t S o l u t i o n

Genes

Trademarked Raw Materials

CHEMICAL D E S C R I P T I O N

RAW MATERIAL H-7892 d-Limonene

219

SOURCE A r y l es

Hampene 100

T e t r a s o d i um EDTA

Grace

Hexyl C a r b i t o 1

I n d u s t r ia1 s o l v e n t

UnCarb

H i t e c E-515

Ethyl

Hoe S3924

Hoechs

Hoechst Wax E

Wax

Hoechs

Hoechst Wax S

Wax

Hoechs

Hostapur

0s

Hoechs

Liquid

Hostapur SAS6O

Secondary a l k a n e s u l f o n a t e

Hoechs

Hyamine 1 O X

Q u a t e r n a r y ammonium compound

Lonza

Hypure N

Secondary h y p o c h l o r i t e , 10% s o l n

I g e p a l CA-520

O c t y l p h e n o x y p o l y e t h o x y e t h a n o l . 5 EO Rhone-

I g e p a l CA-620

O c t y l p h e n o x y p o l y e t h o x y e t h a n o l , 8 EO Rhone-

Pgepal CA-630

O c t y l p h e n o x y p o l y e t h o x y e t h a n o 1 , g EO Rhone-

I g e p a l CA-720

Octylphenoxy p o l y e t h o x y e t h a n o l , 12-13 moles EO

Rhone-

I g e p a l CO-430

Nonionic ethoxylat e s u r f a c t a n t

Rhone-

I g e p a l CO-530

A1 k o x y l a t e d 1 in e a r a1 coho1 n o n i o n i c s u r f a c t a n t (low foam)

Rhone-

I g e p a l 60-630

Nonylphenoxy p o l y e t h o x y e t h a n o l , 9-10 moles € 0

Rhone-

Pndopol H-100

Viscous polybutene

Amoco

I n h i b i t o r 4000

A1 kanolami ne b o r a t e

Zschim

Isopar K

I s o p a r a f f i n solvent

Exxon

M

I s o p a r a f f i n solvent

Exxon

Isopar

220

Advanced Cleaning Product Formulations

RAW MATERIAL Kaopol it e

CHEMICAL DESCRIPTION Kaolin clay

SOURCE Kaopol

K a o p o l i t e SF

A n h y d r o u s a l u m i num s i 1 ic a t e

Kaopol

Kaopol it e 1 152

A n h y d r o u s a l u m i n u m s i 1i c a t e

Kaopol

K a s i l #1

P o t a s s i um s i 1 i c a t e

PQ

K a s i l #6

P o t a s s i um s i 1 ic a t e

PQ

K a t h o n CG

Fungicide (biocide)

Rohrn&

K e l zan

Xan h a n gum

Kel co Kerr-

Kerr-McGee M i n e r a l S e a l O i K o m p e r l a n KD

L a r o s t a t 88

Ant s t a t

PPGMaz

L a r o s t a t 264A

Antistat

PPGMaz

L a r o s t a t 519

Anti stat

PPGMaz

L a u n d r y A d d i t i v e LA-5

Tomah

Lonzabac-1230

Lonza

Lumo WW 75

Zschim

Lumorol 4154

Surfactant blend

Zschirn

L u m o r o l 4192

Surfactant blend

Zschim

L y t r o n 295

Opacifier.

Morton

Polystyrene emulsion

Macol NP 9 . 5 & NP-11 & P o l y o x y e t h y l e n e f a t t y e t h e r OPlOSP & TD-3 & T D - 1 2 & 2LF & 48 & 5100

PPGMaz

M a f o CSB

Amphoteric s u r f a c t a n t

PPGMaz

M a f o 13 MOD 1

Amphoteric s u r f a c t a n t

PPGMaz

Trademarked Raw Materials

221

RAW MATERIAL Makon 10

CHEMICAL DESCRIPTION A l k y l phenol e t h e r

SOURCE

Makon 12

A l k y ? pheno7 e t h e r

Stepan

Maphos 58

Phosphate e s t e r

PPGMaz

Maphos 60A

Phosphate e s t e r

PPGMaz

Maphos 8135

Phosphate e s t e r

PPGMaz

M a s i l EM250C & Silicone fluids EM10,OOOC & SF-10 & SF-100 & SF-1,000 & 123

PPGMaz

M a s l i p 500 & 501A & 501 Base

Synthetic lubricant additives

PPGMaz

S p e c i a l t y alkanolamides

PPGMaz

Mazawet 77

Surfactant

PPGMaz

Mazon R I 4A & R I 6 & RI 8A & R I 88 & 98

Specialty proprietaries

PPGMaz

Mazox LDA

F a t t y amine o x i d e

PPGMaz

Mazu DF 210 SX

Def oamer

PPGMaz

Metso Beads 2048

Anhydrous sodium m e t a s i l i c a t e

PQ

Metso Pentabead 20

Sodium m e t a s i l i c a t e p e n t a h y d r a t e

PQ

M i r a n o l CPM-SF Conc.

D i s o d i um cocoamphodi p r o p i o n a t e

Rhone-

Mazamide SS-10 80 & 1281

& 65 &

Stepan

M e d i a l a n KA Conc.

M i r a n o l J E M Conc.(34%) Sodium mixed C8-amphocarboxylate

Rhone-

Monacor BE

Corrosion i n h i b i t o r

Mona

Monacor 4000

Corrosion i nhi bi t o r

Mona

Monalube 110 & 205 & Synthetic lubricants 210 & 215 & 220 & 225 & 310 & 315 & 320 & 325 Ik 605 & 610

Mona

Monamid 150-ADD

Mona

Cocamide DEA

222

Advanced Cleaning Product Formulations

SOURCE Mona

RAW MATERIAL Monamine CF-100M & 1-76

2 : 1 f a t t y a1 k a n o l a m i d e s

Monamulse dL-1273

P r o p r i e t a r y emu1 s i f ie r / s o l u b i 1 iz e r s Mona

Mona NF-10 & N F - 2 0

Surfactants

Mona

Monamulse TRP & 653-83D

L i q u i d e m u l s i f i e r and s o l u b i l i z e r

Mona

Monaquat I S I E S

I s o s t e a r y l e t h y l d i m o n i urn e t h o sulfate

Mona

Monayuat TG

Q u a t e r n a r y p h o s p h o l i p i d compound

Mona

CHEMICAL DESCRIPTION

Mona

M o n a s i l PCA M o n a t e r g e ALX-100s

Cocami de DEA & DEA-Dodecyl benzenes u l f o n a t e & diethanolamine

Mona

Monaterge 779

DEA-Laureth s u l f a t e

Mona

M o n a t e r i c CM-36s

Sodium c o c o a m p h o a c e t a t e

Mona

M o n a t e r i c CyNa-50

1 - H y d r o x y e t h y l e n e - 2 - c a p r y l im i d a z o l i fie ( 5 0 % a c t iv e )

Mona

M o n a t e r i c EH

M i I d amphoteric detergent/emulsifier

Mona

Mona

Monat r o p e 1 2 5 0 M-Pyrol

n-Methyl-2-pyrrolidone

ISP

M u l s i f a n K326 S p e z i a l

Emulsifier for solvents

Zschim

M u l s i f a n RTI

Fatty acid ethoxylate.

Emulsifier.

Zschim

Nacconol 9 0 G

Linear alkylbenzene sulfonate(LAS)

Stepan

N C l e a r Sodium S i l i c a t e Sodium m e t a s i l i c a t e

PQ

N e k a l WT-27

A n i o n i c w e t t i n g agent

Rhone-

Neodol 1 . 5

Ethoxylate. Linear primary alcohol

Shell

Trademarked Raw Materials

223

SOURCE Shel 1

RAW MATERIAL Neodol 23-6.5

CHEMICAL DESCRIPTION C12-13 l i n e a r a l c o h o l . 6 . 5

Neodol 25-3

Cf2-15

l i n e a r a l c o h o l . 3 moles EO

Shel 1

Neodol 25-7

C12-15 l i n e a r a l c o h o l . 7 moles EO

Shel 1

Neodol 25-12

Linear primary alcohol

Shel 1

Neodol 91-6

Linear primary alcohol. Ethoxylate

Shel 1

N i n o l 11-CWI

Coconut d i e t h a n o l a m i d e ,

Stepan

N i n o l 30-LL

A1 k y l o l a m i d e

Stepan

N i n o l 40-CO

Cocamide DEA

Stepan

P a r o i l 160

Chlor nated p a r a f f i n

Dover

Pemulen 1622

Resin

BFGood

P e t r o BW L i q u L i q u i d & BAF LBA L i q u i d & ULF L i q u i d &

moles EO

modified

d & BAF A n i o n c s u r f a c t a n t / d s p e r s a n t Powder & LBA Powder & 22 Powder

DeSoto

P h o s f e t a l 201

Phosphoric a c i d e s t e r

Zschi m

Phosphol ip i d EFA

L i ndeamidopropyl PE-Dimoni um c h l o r i d e phosphate

Mona

P i l o t SXS-40

Sodi um x y l e n e s u l f o n a t e 40%

Pilot

P l u r a f a c C-17

A1 k o x y l a t e d f a t t y a1 coho1

BASF

P l u r a f a c 0-25

Linear alcohol ethoxylate.

P o l y t e r g e n t S-305LF

Alkoxylated l i n e a r alcohol nonionic O l i n s u r f a c t a n t ( l o w foam)

MW:930

PQ Epsom S a l t

BASF

PQ

P r i f a c 2922

Lauric acid

Uni che

P r o d u k t 2058

Fatty alcohol f a t t y acid ester

Zschi m

P r o p e t a l 99

A1 k y l p o l y a l k y l e n e g l y c o l e t h e r

Zschi m

224

Advanced Cleaning Product Formulations

RAW MATERIAL P r o p e t a l 241

CHEMICAL DESCRIPTION A1 k y l p o l y a l k y l e n e g l y c o l e t h e r

SOURCE

P r o p e t a l 281

A1 k y l p o l y a l k y l e n e g l y c o l e t h e r

Eschirn

P u r t o n CFD

F a t t y a c i d alkanolamide

Zschi m

PVP K-15

P o l y v i n y l p y r r o l i d o n e polymer

Rhone-

Renex 2 0

Surfactant

ICI

R e w o t e r i c AM 8-14

Grease c u t t e r & foam b o o s t e r

Wi t c o

R e w o t e r i c AM B-15 & AM DML 35 & AM HC & AM KSF 40 & AM TEG & AMV

Surfactants

w i eco

Rhodafac RA-600

Linear alcohol ethoxylate

RhOne-

Rhodafac RE-600

Phosphate e s t e r

RhOn@-

Rhodafac RE-61 0

Phosphate e s t e r

Rhone-

Rhodasurf A-24

L i q u i d nonionic surfactant. moles EO

2.5

Rhone-

Rhodasurf LA-7

L i q u i d nonionic surfactant. moles EO

7-9

Rhone-

Rhodasurf LA-9

L i q u i d nonionic surfactant. moles EO

9

Rhone-

Rhodasurf LA-12

L i q u i d nonionic surfactant. moles EO

12

Rhone-

Rhodasurf 91 -6

Liquid nonionic surfactant. moles EO

6

Rhodaterge SMC

Cleaner c o n c e n t r a t e

Rhone-

Rhodopol 23

Xanthan gum

Rhone-

Rhodopol 50MD

Xanthan gum

Rhone-

Zschirn

R i chami de 5725

Richar

RU L i q u i d Sodium S i l i c a t e c o r r o s i o n i n h i b i t o r

PO

Trademarked Raw Materials

RAW M A T E R I A L SF96 S i l i c o n e F l u i d

CHEMICAL DESCRIPTION Polydimethyl s i l i c o n e f l u i d

225

SOURCE GE

S F I 705 R e a c t i ve S i 1 icone Polymer

GE

S F I 706 R e a c t i v e S i 1icone Polymer

GE

S h e l l f e x 213

Rubber p r o c e s s o i l

Shel 1

S h e l l S o l 135

Solvent

Shel 1

SM2133 S i 1 icone Emu1s i on

GE

SM2135 S i l i c o n e Emulsion

GE

SMA-2625 R e s i n

Cop01ymer r e s i n

Arco

S-Mar

Sorbitan f a t t y ester

PPGMaz

M i n e r a l f i 1l e r

JM

80

Snow F l o s s

Sodium A l k y l a r y l S u l f o n a t e Powder (99%)

W itco

Sodium A l k y l n a p h t h a l e n e S u l f o n a t e

DeSoto

Sodium B i c a r b o n a t e (Grades 1 & 5 )

Church

Sodium Carbonate

FMC

Sodium D i c h l o r o i s o c y a n u r a t e , 2H20

Olin

Sodi um T r ipol yphosphate

FMC

Sodium Xylene S u l f o n a t e (40%)

Stepan, W i t c o

Sokalan CP5 B HP22 Standamid PD

Cocamide DEA

Hen k e l

Standapol A

A n i o n i c s u r f a c t a n t . Ammonium l a u r y l s u l f a t e (30%)

Stepan

Standapol ES-3

A n i o n i c s u r f a c t a n t . Sodium l a u r y l e t h e r s u l f a t e (30%)

Stepan

Star

Sodium s i 1 i c a t e 4QBe'

PQ

Starso

L i q u i d sodium s i l i c a t e

PO

Steal CS-330

Alcohol ether s u l f a t e

Stepan

226

Advanced Cleaning Product Formulations

RAW MATERIAL S t e p a n o l WA-Extra

CHEMICAL DESCRIPTION Hydrotrope

SOURCE Stepan

Stoddard S o l v e n t

Exxon

STPP

FMC

S u l f e t a l 4069

Fatty alcohol s u l f a t e . Anionic surfactant

Zschim

S u l f e t a l 4105

Fatty alcohol s u l f a t e . Anionic surfactant

Zschim

Sul f o n a t e OA5

W e t t i n g agent

Tennes

Super F l o s s

Diatomaceous e a r t h

JM

S u p r a g i l NK

Sodium a l k y l n a p h t h a l e n e s u l f o n a t e

Rhone-

S u r f o n i c N-150

S u r f a c e a c t i v e agent

Texaco

Rhone-

TEA L a u r y l S u l f a t e

T e r g i t o l NP

UnCarb

Nonoxynol

Thermphos

Hoechs

Thermphos NW

Hoechs

T i n o p a l 5BM

F l u o r e s c e n t w h i t e n i n g agent

Tomah A l k a l i S u r f a c t a n t Amphoteric

(35% a c t i v e )

C i ba-

Toma h

M i I d surfactant

Tomah

E t h e r amine o x i d e (50% a c t i v e

Tomah

Amine o x i d e - h i g h foaming (50% a c t 1

Tomah

Tomah Q-14-2

Quaternary

Toma h

Tomah Q-17-2

Quaternary

Tomah

Tomah Amphoteric

L

Tomah AO-14-2 Tomah A0-728

Special

Zschim

T r i l o n A Liquid T r i t o n DF-16 & N-101 & x-45

Nonionic surfactants

Rohm

Trademarked Raw Materials

227

R A W MATERIAL Tur b o b r i t e

CHEMICAL DESCRIPTION Aluminosilicate

SOURCE

Turbobrite L

Aluminosilicate slurry

PQ

Tween 40

P o l y s o r b a t e 40

ICI

Zeolite A builder

PQ

PO

T y l o s e CBR 10000 U b a t o l TR1138 V a l f o r 100

Van Gel B & C & ES & 0 Magnesium aluminum s i l i c a t e s

RTVan

Vanseal NACS-30

RTVan

Sodi um 1a u r o y l s a r c o s i n a t e

Vanseal NALS-30

RTVan

Varami de A-1 0 & A - 1 2 & A-83 & MA-1

D e t e r g e n t a1 kanolami des

W itco

V a r o n i c DM-55 & K205 8 T202 & T202SR

Nonionic w e t t i n g agents

witCO

Varox 365 8 1770

W e t t i n g agents

W itco

V a r q u a t 50MC

S p e c i a l t y quaternary,

Veegum & Veegum T

Magnesi um a1 umi num s i 1 ic a t e s

Versene 100 & 220

C h e l a t i n g agents

V i scasi

a

germicide

F l u i d ( 1 0 , O O O ) S i 1 icone

w itco RTVan Dow GE

Wachsemulsion 1864

Zschim

Witcamide S-780 & 128T A l k a n o l a m i d e s u r f a c t a n t s

W i tco

& 6445

W i t c o 12986

W itco

W i t c o 1298SA

Soft acid

W i tco

W i t c o l a t e ES-3 & LES-6OA & LES-6OC & S E - 5 & WAC-LA & 2310

Sulfated surfactants

witco

228

Advanced Cleaning Product Formulations

SOUWGE

RAW MATERIAL W i t c o n a t e AOS & SXS & 30DS & 45 L i q u i d & 60T L i q u i d & 1240 & 1260 S l u r r y

CHEMICAL D E S C R I P T I O N Surfactants

\Mi ~ C O

W i t c o n o l NP-100

Detergents & degreasers

w i tco

& NP-120 Wessalith P

Zeolith P

Ya rmor 3 02

Pine o i l

Hercul

Z e t e s o l 2056

Fatty alcohol ether s u l f a t e

Zschim

Z e t e s o l NL

Fatty alcohol ether s u l f a t e

Pschi I

Zusol a t 1005/85

A1 k y l p o l y e t h y l e n e g l y c o l e t h e r

Zschim

Zusol a t 1008/85

Alkyl polyethylene glycol ether

Zschi rn

2 . l r Potassium s i l i c a t e (39%)

PQ

2 . 4 r Sodium s i l i c a t e (52%)

BQ

Section IV pliers' Addresses

230

Advanced Cleaning Product Formulations

A1 1 ied-Si g n a l , I n c . P . O . Box 2332R M o r r i s t o w n , NJ 07962

Dover Chemical Corp W15 & D a v i s

(201)-455-2000/(800)-526-0717

P.O. Box 40 Dover, OH 44622

(800)-321 -8805 Amoco Chemical Co. 200 E. Randolph D r . Chicago, I L 60601

(312)-856-3200/(800)-621-8888

Dow Chemical USA M i d l a n d , M I 48674 (8 0 0 )-2 5 8 - C H E M

Angus Chemical Co. 2211 Sanders Rd. N o r t h b r o o k , I L 60062

Dow C o r n i n g Corp. Box 0994 M i d l a n d , M I 48686

(708)-498-6700/(800)-323-6209 A r c o Chemical Co. 3801 West C h e s t e r P i k e Newtown Square, PA 19073

(517)-496-4000 E t h y l Corp. 451 F l o r i d a Baton Rouge,

(215)-359-2000

LA 70801 (504)-388-7556/(800)-535-3030

A r izona Chemical Co. 1001 E . B u s i n e s s Hwy 98 Panama C i t y , FL 32401

Exxon Chemical Americas 13501 K a t y Frwy Houston, TX 77079

(904)-785-6700/(800)-526-5294

(713)-870-6000/(800)-231-6f333

Ash1 and Chemical Co. P . O . Box 2219 Columbus, OH 43216

2000 Market S t .

FMC Corp.

(614)-889-3333/(800)-848-7485

Philadelphia,

PA 19103 (215)-299-6000/(800)-526-3649

BASF Corp. 100 C h e r r y H i l l Rd. P a r s i p p a n y , N J 07054

GE S i l i c o n e s 260 Hudson R i v e r Rd. W a t e r f o r d , NY 12188

(201)-316-3000/(800)-526-1072

(518)-237-3330/(800)-255-8886

B u r l i n g t o n Chemical Co. P . O . Box 1 1 1 615 Huffman M i l l Rd. B u r l i n g t o n , NC 27215

Genesee Polymers Corp. Fenton Rd./P.O. Box 7047 F l i n t , M I 48507

Inc.

(313)-238-4966

(919)-584-0111/(800)-672-5888 C i ba-Gei gy Corp. 7 Skyline Drive Hawthorne, NY 10532

Georgia Marble Co. 1201 R o b e r t s B l v d . Kennesaw, GA 30144

(404)-421-6500

(914)-374-4700/(800)-431-1900 B.F. G o o d r i c h G o . DeSoto I n c . 1700 S . M t . P r o s p e c t Rd. Des P l a i n e s , I L 60018

(312)-391-9000

991 1 B r e c k s v i 1 1 e Rd , B r e c k s v i l l e , OH 44141 (216)-447-5000/(800)-331-1~44

Suppliers' Addresses

Grace 8 Co. 55 Hayden Ave. L e x i n g t o n , MA 02173 ( 6 1 7 )-861 -6600

W.R.

Henkel Corp. 5325 S . N i n t h Ave. LaGrange, I L 60525

(708)-530-7300/(800)-543-7370

Mona I n d u s t r i e s I n c . 76 E . 24 S t . P . O . Box 425 P a t e r s o n , N3 07544 (201)-345-8220/(800)-553-6662 Monsanto Chemical Co. 800 N. L i n d b e r g h B l v d . S t . L o u i s , MO 63167

(314)-694-1000/(800)-325-43 blercul es I n c . H e r c u l e s P1aza W i l m i n g t o n , DE 19894 (800)-247-4372

Morton I n t e r n a t i o n a l 100 N. R i v e r s i d e P l a z a Chicago, I L 60606

(312)-807-2000/(800)-367-33 Woechst Celanese Corp. 801 Water S t . Portsmouth, V A 23704 (804)-393-3100/(800)-368-2822 I C I Specialties Concord P i k e & New Murphy Rd. W i 1m i n g t o n , DE 19897 (302)-886-3000/(800)-822-8215

Johns-Manvi 11e Ken C a r y l Ranch Denver, CO 80217 Kaopolite, Inc. 2444 M o r r i s Ave. Union, W J 07083 (9081-789-0609 Kel c o D i v i s i on Merck & Co., I n c . 8355 Aero D r i v e San Diego, CA 92123 (61 9)-292-4900 Kerr-McGee Chemical Corp. Kerr-McGee C t r . P . O . 80x 25861 Oklahoma C i t y , OK 73125 (405)-270-1313/(800)-654-3911 Lonfa I n c . 1717 R t a 208 F a i r Lawn, NJ 07410 (201)-794-2400/(800)-777-1875

O l i n Corp. 120 Long Ridge Rd. P . O . Box 1355 Stamford, CT 06904 (203)-356-2000/(800)-243-9171 P e t r o l i t e Corp. 6910 E. 1 4 S t . T u l s a , OK 74112 (918)-836-1601 P i l o t Chemical Co. 11756 Burke S t . Santa Fe S p r i n g s , CA 90670 (310)-723-0036 PPG/Mazer One PPG P l a c e P i t t s b u r g h , PA 15272 (412)-434-3131/(800)-243-6774 PQ Corp. P . O . Box 840 V a l l e y Forge, PA 19482 (215)-293-7200 Quest I n t e r n a t i o n a l Fragrances 400 I n t e r n a t i o n a l D r i v e Mount O l i v e , NJ 07828 (201 )-691-7100

231

232

Advanced Cleaning Product Formulatioris

Rhone-Poul enc P r o s p e c t P l a i n s Rd. Cranbury, N J 08512 (609)-860-4000/(800)-626-2613

Tomah P r o d u c t s , I n c . 1012 T e r r a D r i v e M i 1t o n , W I 53563

Richardson Co. 2400 East Devon Ave. Des P l a i n e s , I L 60018

Uni chema Chemicals I n c . 4650 S . Racine Ave. Chicago, I L 60609 (312)-376-9000/(800)-833-2884

Rohm & Haas Co. Independence M a l l West P h i l a d e l p h i a , PA 19105 (215)-592-3000 S h e l l Chemical Co. P . O . Box 2463 Houston, TX 77252 (713)-241-6161 Stepan Co. 22 W . F r o n t a g e Rd. N o r t h f i e l d , I L 60093 (708)-446-7500/(800)-745-7837 Tennessee Chemical Co. 3400 Peachtree Rd NE A t l a n t a , GA 30326

(404)-239-6700/(800)-241-1912 Texaco Chemical Co. 3040 Post Oak 8 l v d . Houston, T X 77056 (713)-961-3711 3M 3M Center S t . P a u l , MN 55144 (612)-733-5454

(608)-868-68ll/(800)-441-0708

Union C a r b i d e Corp. 39 O l d Ridgebury Rd. Danbury, CT 06817 (203)-794-2000 R . T . V a n d e r b i l t Co., P . O . Box 5150 30 W i n f i e l d S t . Norwalk, CT 06856

Inc.

(203)-853-1400/(800)-243-6084 W i t c o Corp. 520 Madison Ave. New York, NY 10022

(212)-605-3941/(800)-634-4010 Zschimmer & Schwarz Max-Schwarz-Strabe 3-5 D-56112 L a h n s t e i n/RH D 26 21/120