Handbook of Highly Toxic Materials Handling and Management

HAZARDOUS CHEMICALS IN THE

POLYMER

INDUSTRY

Marcel Dekker, Inc.

New York. Basel Hong Kong

Lihrrry of Congress Cataloging-in-Publication Data

Cberemisinoff. Nicholas P. Hazardous chemicals in the polymer industry INicholas P. Cheremisinoff. p. cm. - (Environmental science andpollutioncontrol series; 14) ISBN 0-8247-9273-4 1. Plastics-Additives-Toxicology. 2. Polymers-Toxicology. 3. Plastics industry and trade-Safetymeasures. I. Title. 11. Series:Environmental science and pollution control; 14. RA1242.P66C48 1994 363.17’91 “dc20 94-22884 CIP

The publisher offers discounts on this book when ordered in bulk quantities. For more information, write to Special Sales/Professional Marketingat the address below. This book is printed on acid-free paper. Copyright

1995 by MARCEL DEKKER, INC.

All Rights Reserved.

Neither this book nor any part may be reproduced or transmitted in any form or by anymeans, electronic or mechanical, including photocopying,microfilming, and recording, or by any information storage and retrieval system, without permission in writing from the publisher. MARCEL DEKKER, INC. 270 Madison Avenue, New York, New York

10016

Current printing (last digit): l 0 9 8 7 6 5 4 3 2 1

PRINTED IN THE UNITED STATES OF AMERICA

Several hundred distinct chemicals are widely used in elastomer and plastics processing operations. Many of these are used almost exclusively in the rubber industry. Despite this widespreaduse,lessthan 10% of the morethan 500 chemicaladditiveshaveestablishedthresholdlimitvalues.Considerable knowledge has and is being accumulated in the industry, particularly among chemical suppliers, inmeetingright-to-know legislative requirements. This volume not only provides basic safety and toxicity data for industry users, but also points out some of the areas in which further information is needed. The underlying aim of those involved with toxicity problems in the rubber and plasticsindustries is to prevent or eliminate the risk of health hazards to those handlingor exposed to chemicals. This is a continuous learning process as new chemicals and new ways of using existing chemicals continue to be introduced. The science of relating mechanisms of the interaction of elastomeric chemical additives with human physiologyis still relatively young. On the other hand, the knowledge base is rapidly expanding. It should be further noted that control of exposure to chemicals in this industry should be a routine part of normal plant management practices and should heavily involve the industrial hygienist and process safety engineer. This volume is written as a practical reference for engineers, technicians, and elastomer/plastics compounders. Information on toxic and hazardous properties, symptoms of overexposure, safe handling and shipping, fire hazards, and spill responses for both generic and specific polymer chemicals are given. The author has made everyeffort to ensure thatthe information presentedin this A wide range of sources was used in handbook is accurateandup-to-date. compiling this information.Despite this effort, no claimsofassurance or liability for the information researched or presented is assumed by either the author or the publisher. On a personal note, theauthorwishesto express gratitude to Linda Jastrzebski for her assistance in the production of this work. Nicholas P. Cheremisinoff, Ph.D. iii

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CONTENTS

iii

Preface How to Use the Handbook Monomers of Synthetic Rubbers VulcanizingAgents 4

AcceleratorsandActivators

5

Mineral Fillers,ActivatorsandDustingAgents

6

Antioxidants, Stabilizers and Fire Retardants 417

Retarders Blowing Agents Oils,Plasticizers,Lubricants,Solventsand Mold Release Agents 10

Amines

V

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1 HOW TO USE THE HANDBOOK This handbook constitutes a database on the toxic and hazardous properties, as well as shipping, packaging, and emergency response procedures for polymeric additives. Thechemicalscovered in this volume are organized into nine categories. Section Number

Class of Chemicals

2

Monomers of Synthetic Rubbers Vulcanizing Agents

4

Accelerators and Activators

5

Mineral Fillers, Activators, and Dusting Agents Antioxidants, Stabilizers, and Fire Retardants Retarders Blowing Agents Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

10

Amines

The information gatheredfor each chemical has been extracted from several sources including NIOSH, OSHA, RTECS, CHRIS Manual, DOT regulations, the Federul Register, ACGIH, and manufacturers’ literature. 1

2

Chapter 1

Theuser will find two generalformats in whichinformation is presented. The first formatandmostdominant presentation is anexpanded information sheet. This format gives the following information a chemical: 1. General Information

Name Synonyms CAS Registration Number ChemicalFormula Wisswesser Line Notation Chemical Class 2. Physical Properties

3. RegulationsGoverning the Chemical 4.

Toxicity Data

5 . Protection and First Aid

6. Initial IncidentResponseandEmergencyAction Thesecondgeneralformatisan abbreviated Material SafetyData Sheet. In this case, either the specific chemical is proprietary in composition or only manufacturer’s information could beobtained. This format provides basic health and safety information and limited properties data only. Thefollowingisa list of the specific chemicalscovered in the handbook. The last part of this first section provides a list of definitions and abbreviations used throughout the volume.

2

Monomers of Synthetic Rubbers

15 Acrylonitrile 16 1,3-Butadiene 25 Chloroprene Ethylidene Norbornene 39 Isoprene 44 Vinyl Chloride 49 Polyethylene 57 Acrylic Monomer (Trimethylolpropane Trimethylacrylate) PolybutenePolymer (trade name,IndopolH-300) 63

60

How to Use the Handbook

3

67 Magnesium Oxide 68 Zinc Oxide 72 Hexamethylene Diamine 75 Tert-Butyl Peroxybenzoate 80 Di-Cup R (organic peroxide) 85 Di-CupC (organic peroxide) 92 Di-Cup 40kE (organic peroxide) 98 Dicumyl Peroxide (Di-Cup) 205 2,5-Dimethyl-2,5-Di(Tert-Butylperoxy)Hexyne-3 109 2,5-Dimethyl-2,5-Di(Tert Buty1peroxy)Hexane 113 Tert-Butyl PeroxymaleicAcid (trade name,LuperoxPMA) Sulfur 222 N-Oxydiethylenebenzothiazole-2-Sulfenamide (trade name, Amax) 226 Valeric Acid 230 Insoluble Sulfur, oil treated (trade name,Crystex) 134 Bis(Dimethylthiocarbamy1) Disulfide 238 Dibenzoylp-Quinonedioxime (trade name,Dibenzo GMF) 248 HexamethylenediamineCarbamate (trade name,Diak No. 1) 252

Vulcanizing Agents

n,n’-Dicinnamylidene-1,6-Hexanediamine (trade name,DiakNo. 255 Poly-Dispersion ofLead Oxides 159 VulcanizedVegetable Oil (trade name, Factice White 57) Ferro Therm-Chek6-V6A 166

4

Accelerators and Activators

263

171 Calcium Oxide 173 MagnesiumAluminumHydroxyCarbonate 279 Talc (nonasbestos form) 283 Azodicarbonamide-Aisformamide (trade names, KemporeSDA-200 Kempore (290)) Glycol Ether 293 Cupric Dimethyldithiocarbamate 298 Zinc Diethyldithiocarbamate (ZDEC) 202 NickelDibutyldithiocarbamate (trade name,NBC) 204 Bismuth Dimethyldithiocarbamate (trade name, Bismate Powder) 208 ZincDibutyldithiocarbamate (trade name,ButylZimate) 222 Zinc Dimethyldithiocarbamate, oil treated (trade name, Methyl Zimate) 225 Selenium 220 Lead Dimethyldithiocarbamate 223

4

Chapter1 TelluriumDiethyldithiocarbamate (trade name,Ethyl Tellurac) 226 Cadmium Diethyldithiocarbamate 231 Zinc Stearate 233 Di-Ortho-Tolylguanidine (trade name,DOTG Accelerator) 235 Mercaptobenzothiazole, copper salt (trade name, Cupsac Accelerator) 239 Thiuram (trade name,MOTS No. 1 Accelerator) 243 TetramethylthiuramMonosulfide (trade name,Monex) 247 Hexamine (Hexamethylene Tetramine; HMT) 251 Zinc Ethylphenyldithiocarbamate 255 Carbamic Acid 258 2-Benzothiazolethiol (MBT) 262 2-Benzothiazolethiol, Zinc Salt 265 Urea 267 Bis(Dimethylthiocarbamy1) Disulfide (TMTD) 269 1,3-Diphenyl-2-Thiourea (trade name, A-l Thiocarbanilide Rubber Accelerator) 279 Carbamide (trade name, BIK) 282 1,3-DiphenylGuanidine (trade name,DPG) 286 Polyethylene Glycol (trade name, Carbowax Polyethylene Glycol) 292

5

Mineral Fillers, Activators, and Dusting Agents HydratedAlumina (trade name,Hydral) Aluminum Hydroxide 304 Kaolin Clay 307 Carbon Black 309 CarbonicAcid,CalciumSalt 312 Calcium Stearate 314 Magnesium Stearate 328 OrganophilicClay (trade name,Bentone Silica 325

6

Antioxidants, Stabilizers, and Fire Retardants

299 300

34)

322

329 PhenolicAntioxidants (trade name,Good-rite (330), Antioxidant2246 (333)) TrimethylQuinoline (trade name, Flectol H Antioxidant) 337 Diphenylamine (trade name, Aminox) 344 Dilauryl Beta-Thiodipropionate 347 Phenylenediamine (trade name,Flexzone 6H) 350 Tetrakis(Methylene(3,5-di-tert-Butyl-4-Hydroxyhydroci~amate))Methane (trade name, Irganox 1010) 353

How to Use the Handbook

5

HinderedPhenolicAntioxidant (trade name,Irganox1035) 359 Octadecyl 3,5di-tert-Butyl-4-Hydroxyhydrocinnamate (trade name,Irganox1076) 363 Tris(3,5di-tert-Butyl-4-Hydroxybenzyl)Isocyanurate (trade name,Irganox 114) 367 n,n’-Diphenyl-p-Phenylenediamine 372 OctylatedDiphenylamine (trade name,AgeriteHP-S) 375 Mixture of OctylatedDiphenylamines (Agerite Stalite S) 379 Polymerized 1,2-Dihydro-2,2,4-Trimethylquinoline (trade name,AgeriteMA (383), AgeriteResinD (388)) Powdered PhenolicResin, Phenolic Antioxidant(trade name, Akrochem Antioxidant 33 392 AlkylatedCresol (trade name,BHT) 396 Nickel bis-(O-Ethyl(3,5-di-tert-Butyl-4-Hydroxybenzyl)Phosphonate), Light Stabilizer (trade name, Irgastab 400 BrominatedOrganicCompound (trade name,CitexBN-451) 403 Mirex 407 Antimony Oxide 412

7

Retarders

41 7

N-Nitrosodiphenylamine 41 7 Salicyclic Acid,Retarder W 420 Phthalic Anhydride 424

8

Blowing Agents

433

Formamide, l,l’-Ambis433 Dinitrosopentamethylenetetramine Benzenesulfonic Acid 439 p-Toluene Sulfonyl Semicarbazide

9

435 441

Oils, Plasticizers, Lubricants, Solvents, and MoldReleaseAgents 447 PhenolicResins (trade name,Durez) 447 Wax (trade names,EpdeneN-10,Castorwax (450), Chlorowax (454)) Di-(2-Ethyl Hexyl) Adipate (trade name, Dioctyl Adipate C-497) 458 Di-N-Octyl Phthalate 461 Petroleum HydrocarbonLubricants (trade names, A.S.T.M. Reference Oil No.1 (466), Califlux 550 (470), Cyclolube (474), Flexon 641 (478), Flexon340 (482), Flexon 391 (486), Flexon 815 (491) Soaps (trade name,Aflux42) 495

6

Chapter 1 Benzothiazole Disulfide (trade name, Altax) Castor Oil 504 Glycerin EpoxidizedSoybean Oil (trade name,Drapex) Heptane 513 n-Hexane 519 Isopropyl Alcohol 527 Methanol 535 2-Butanone 544 Asphalt 552 Aromatic Oil (trade name,Mobilsol) 557 MoldReleaseAgent (trade name,MoldWiz) Retene,RosinOil (trade name,NRosin Oil)

10

Amines 569 N-Nitrosodiphenylamine

499 509

560 564

569

N-Nitrosodi-N-Propylamine 572 Butadiene Homopolymer containing acrylate functional groups (trade name, Chemlink Oligomer) 576 ThermoplasticResin (trade name,CumarP-10) 581 PetroleumHydrocarbonResin (trade name,Escorez) 585 AromaticAmine (trade name,Naugard 445) 589 N-Octadecylamine 593 Diphenylamine-AcetoneCondensate (trade name,BLE) 595 N-Isopropyl-M-Phenyl-P-Phenylene-Diamine 599 Selenium 602 N,M-m-PhenyleneDimaleimide(HVA-2) 604

How to Use the Handbook

7

DEFINITION OF TERMS AND ABBREVIATIONS USED THROUGHOUT THE BOOK The following are definitions of the terms and abbreviations used throughoutthe handbook.

ACGIH - American Conference of GovernmentalHygienists. Publications and recommendations regarding exposureto chemicals are quoted from this source. Action - Refers to the OSHA action level concentration of the chemical. Agents - The term as used herein refers to neutralizing agents. AIT - Autoignition temperature in degrees Kelvin. AITC - Autoignition temperature in degrees Celsius. AITF - Autoignition temperature in degrees Fahrenheit. ANAL.AGENCY - Refers to the agency (NIOSH or OSHA) that is responsible for the air sampling analysis method. AQ.TOX - Abbreviation for the aquatic toxicity of the chemical. BP - Boiling point.

CARC.ACGIH - Carcinogenicity coding: A1 = confirmed human carcinogen. Substances associated withindustrial processes, recognized to have carcinogenic potential. A2 = suspected human carcinogen. Chemical substances associated with industrial processes that are suspected of inducing cancer, based either limited epidemiological evidence or demonstration of carcinogenesis in one or more animal species. CARC.IARC - IARC carcinogenicity rating: 1 = carcinogen as definedby IARC as carcinogenic to humans, with sufficient epidemiological evidence. 2A = carcinogen defined by IARC to be probably carcinogenic to humans with (usually) at least human evidence. 2B = carcinogendefined by IARC to

8

Chapter 1

be possibly carcinogenic to humans, but having (usually) no human evidence. 3 = not classified as to human carcinogenicity or probably not carcinogenic to humans. 4 = the agent is probably not carcinogenic to humans. If a "No"is indicated, then the chemical is not listed by IARC.

CAS - Chemical Abstract Service Registry number. CCA - Clean Air Act reference. CEIL - Refers to Ceiling PEL. On January 19, 1989, OSHA published in the Federal Register the final rule (29CFR 1910) for air contaminants. This rule amendedOSHA's existing air contaminants standard in 1910.100, including Tables Z-1, 2-2, and 2-3. CERCLA -Comprehensive Environmental Resource Cleanup and LiaSility Act. CHEM.REACT - Chemical reactivity. Class - Refers to chemical class or classes. CPC - chemical protective clothing. CHRIS - Chemical Hazard Response Information System. CTNR.EXC - Refers to 49 CFR Table 172.101. DOT cargo tank exceptions. CTNR.SPEC - See 49 CFR Table 172.101. DOT cargo tank specifications. CWA - Clean Water Act; means that the chemical is on one of lists: Section 307, priority pollutants list, or Section 311, chemicals considered hazardous if spilled into navigablewaterways. Section 311 chemicalshave reportable quantities (RQs). The Section 311 list reviewed comes from 40 CFR 401.15, and the Section 311 list is from 40 CFR 116.4 (revised in 54 FR 33426, August 14,1989).

Density - The weightper unit volumeof the material in gramspercubic centimeter at a given temperature or ambient.

DOT - Department of Transportation. DOT.CLASS - Refers to the DOT hazard class.

How to Use the Handbook

DOT.GUTDE - Refers to the DOT guide number. DOT.ID - The U.S. Department ofTransportation identification number. Those numbersprecededbya "UN" are associatedwith descriptions considered appropriate for international as wellasdomestic use. Thoseprecededbyan "NA" arenot recognized for international shipments exceptto and from Canada. DOT.NAME - Refers to DOT shipping name from

CFR Table

Duration - OSHA duration period for exposures where a maximumconcentration is specified. EPA.ID - EPA RCRA hazardous waste ID. FIFRA - Refers to a chemical listed by EPA's Office of Pesticides Programs on April as oneof the active ingredients subject to re-registration as required by FIFRA amendments [Section 4(c) (2) (B)].

FP - Refers to the flash point temperature of the material. GCC - Refers to the EPA Generic Classification Codes from SARA Title 111, Sec. See FR, p. June IDLH - NIOSH published concentration that is immediately dangerous to life and health. LC50 - Lethal concentration for 50% of a test population (RETCS LDS0 - Lethal dose for 50 % of a test population of rats . Dose administered orally . LD5O.RAT - The numeric value (in ml/kg) of the oral LD50 for rats. From the RETCS. LD5O.SKN.RBT - LD50 value (in mg/kg) when applied to the skin of albino rabbits. From RETCS data LEL - Lower explosion limit. LTT - Long-term toxicity.

Chapter 1

10

MAIL - Mailability informationfrom the U.S. Postal Service's "Hazardous Materials Table Postal Mailability Guide, " which is an Appendix to Publication 52, April, 1990.

-

MAX OSHA maximum allowable concentration. MAX.CARG0 - Maximum net quantity in one package. From the Department ofTransportationHazardous Materials Table172.10l-Revised,October 27, 1987. MCL - Refers to the maximumcontaminant level, that is, the maximum permissible level of a contaminant in water that is delivered to the free-flowing outlet of the ultimate user of a public water system. MCLG - Refers to maximum contaminant levelgoals. The Safe Drinking Water Act 1986 requires EPA to publish MCLGs for contaminants that may have adverse health effects and are known anticipated to occur in water systems. MCLG values allow for an adequate margin of safety.

M P - Melting point.

MUT - Mutagenic data from RTECS, 1992. Only positive mutation test results are reported in RETCS. MW - Molecular weight. NFPA - National Fire Protection Association.

NFPA.BLUE - NFPA health code (blue). NFPA.RED - NFPA flammability code (red). NFPA.SPECIAL - NFPA special code (usuallyradioactive or water reactive or oxidizer). NFPA.YELL0W - NFPA reactivity code (yellow). NIOSH - National Institute of Occupational Safety and Health. Odor - Lower odor detection limit. Note that these data are very subjective and probably vary from individual to individual.

How to Use the Handbook

11

OSHA - Occupational Safety and Health Administration. PEL - Permissible Exposure Limit. On January 19, 1989 OSHA published in the Federal Registerthe final rule (29 CFR 1910)for aircontaminants. This rule amended OSHA’s existing Air Contaminants standard in 1910.1000, including Tables 2-2, and A new Table(Z-l-A) makes more protective 212 PEL values while adding 164 new substances. Inaddition, short-term exposure limits (STEL) were added to complement the 8-hour time weighted average (TWA) limits, skin designations were established, and ceiling limits were added for some substances. POLY - Polymerization possibilities for the chemical. RCRA.NO - EPA RCRA ID number.

RE - Routes of entry. REL - NIOSH Recommended Exposure Limits. NIOSH develops and periodically revises recommendations for limiting exposure to potentially hazardous substances in the workplace.These are publishedin Criteria Documents,Current Intelligence Bulletins,SpecialHazardReviews,and Occupational Hazard Assessments. REPRO - Reproductive toxicity from1992RTECS. Effects listed include paternal effects, maternal effects, effects on fertility, effects on embryo or fetus, specific developmental abnormalities, and tumorigenic effects. RQ - Reportable quantity. CERCLA reportable quantity symbols: X, A, B, C, or D. RQs may be designated for a chemical under SARATitle 111, Section 304 (Extremely Hazardous Substances-EHS) or under CERCLA.

RTECS - Registry of Toxic Effects of Chemical Substances. SMALL.SPILL - Refers to small spill action as defined under DOTguidelines. Note that, if a “small”spill exceeds the reportable quantity (RQ) for a chemical, reporting of the spill may be required under EPA regulations. SP.GR - Specific gravity. The ratio of the density of the substance at a given temperature to that of water at a given temperature. SPILL.LEAK - Refers to the spill leakinformationfrom P5800.4.

the DOTGuide

12

Chapter 1

-

STCC Standard tariff commodity code number STEL - ACGIH short-term exposure limit. STOR - Refers to information on the generalstoragerequirements chemical.

for the

S l T - Short-term toxicity.

TARGET.ORGANS - Target organs, that is, dataderived primarily from NIOSH published sources and the CHRIS manual. TC - Toxic characteristics identification number. Found in EPA’s list of procedure, published in 55 FR 11798, March 29, 1990.

TC

TEFUT - Teratogenic data. TLV - AmericanConference ofGovernmentaland established threshold limit value.

Industrial Hygienists

TO - Target organs. TPQ - Thresholdplanning quantity. BasedonSuperfundAmendmentsand Reauthorization Act (SARA) of October 17, 1986. For solids, the lower TPQ applies onlyif the solid exists in powdered form and has a particle size less than 100 microns; or is handled in solution or in molten form; or meets the National Fire Protection Associationcriteria rating of 2, or 4 for reactivity. If the solid does not meet any of these listed criteria, then the upper TPQ applies. TQ - Threshold quantity, from 57 FR 6407,February 24, 1992. Appendix to 1910.119, List of Highly Hazardous Chemicals, Toxics, and Reactives, and chemicalsmeetingthepublishedrequirements for flammablein29CFR 1910.1200. Generally, this includes liquids with flash points less than 100°F. TWA - OSHA’s 8-hour time weighted average limits for air contaminants.

UEL - Upper explosion limits. VAP0R.DENSITY - Vapordensity (air = 1); that is, the vapor’s specific gravity. VD - Vapor density.

How to Use the Handbook

VP - Vapor pressure. WATER - Refers to water reactivity data. WATER.SOL - Refers to water solubility data. WEEL - Workplace Environmental Exposure Levels prepared by the American Industrial HygieneAssociation(AIHA) for chemicalsthathaveno current exposure guidelines published by other agencies. All WEELs are expressed as ceiling values. Different time periods are expressed, depending on the chemical. Ceiling values should not be exceeded at any time. "Skin" indicates that the chemical may be absorbed through the skin in amounts that may be toxicologically significant. WLN - Refers to Wisswesser line notation. WLN is a line-formula notation that conveys information aboutthe structural formula of a chemical compound. The WLN allows searching for special functional groups and constituents that are part of the molecule.

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2 MONOMERS OF SYNTHETIC RUBBERS Polymersused in the rubber industry generally donotcause health-related problems. The high molecular weight and chemical stability of these materials prevent significant absorption through skin contact, and they are stable and inert when in contact with fluids in medical applications such as catheter tubes and implants. On the other hand, polymers may contain trace or residual impurities derived from the manufacturing process, and they may have additives such as stabilizers. Both these classes of chemicals should be considered from the standpoint of toxic hazards. This section describes the toxic and hazardousproperties of some ofthe widelyusedmonomersemployed in synthesizing polymers.Tracesof these monomers often remain in commercial polymer supplies at levels generally less than 1 ppmbyweight.Itis unusual, but not impossible for the TLV to be reached during normal processing and fabrication operations. As an example in some operations, the author has detectedconcentrations of acrylonitrile between 2 and 3 ppm on mill rolls during the milling of nitrile rubber. Acrylonitrile is a carcinogenic material, and compounders should proceed with caution when working with nitrile rubbers to ensure that operator exposure is well below the TLV . Other polymers can contain even higher concentrations of monomers. Fabricators, compounders, and milloperators should always check to ensure that exposures to residual monomers do not exceed the TLV. Another example of a high-level exposure risk is polychloroprene latex, where several thousand ppm by weight of chloroprene monomer can occur during processing operations. Two final examples of exposure risks are the processing of polyurethane rubbers and chlorosulfonated polyethylene. Polyurethane elastomers may contain free isocynate. Chlorosulfonated polyethylene can contain carbon tetrachloride, a well-known carcinogen.

15

16

Chapter 2

Name: ACRYLONITRILE Synonyms: Acrylnitril (German, Dutch); Acrylon; Acrylonitrile; Acrylonitrile Monomer;Akrylonitryl (Polish); Carbacryl;CianuroDiVinile (Italian); Cyanoethylene;Cyanure De Vinyle (French); Ent 54; Fumigrain; Miller's Fumigrain; Nitrile Acrilico (Italian); Nitrile Acrylique (French); Propenenitrile; 2-Propenenitrile; TL 3 14; VCN;Ventox;VinylCyanide; Vinyl Cyanide, Propenenitrile CAS:107-13-1; RTECS: AT5250000 Formula: C,H,N; Mol Wt: 53.06 WLN: NClUl Chemical Class: Nitrile See other identifiers listed below under Regulations.

--

PROPERTIES

--

Physical Description: Clear, colorless to pale yellow liquid (NYDH) Boiling Point: 350.38 K; 77.2"C; 171°F Melting Point: 190.38 K; -82.8" C; -117°F Flash Point: 273.15 K;0°C; 32°F Autoignition: 898 K; 6243°C; 1156.7"F Critical Temp: 536 K;262.85"C; 505.13"F Critical Press: 4.6 kN/m*; 45.3 atm; 666 psia Heat of Vap: 265 Btu/lb; 147.17 cal/g; 6 . 1 5 8 ~E5 J/kg Heat of Comb: -14300 BtuAb; -7950 cal/g; -332x E5 J/kg mm VaporPressure:83 UEL: 17% LEL: 3 !% IonizationPotential (ev): 10.91 Vapor Density: 1.8 (air = 1) Evaporation Rate: 3.31(n-butylacetate = 1) Specific Gravity: 0.807 at 20°C Density: 0.806 Water Solubility: 7.1 !% Incompatibilities: Strong oxidizers, bromine,strongbases, copper, copper alloys, ammonia,amines Reactivity with Water: No data on water reactivity Reactivity with Common Materials: Attacks copper, copper alloys, and aluminum,penetratesleather

Monomers 17Synthetic Rubbers Stability during Transport: No data Neutralizing Agents: May occur in absence heat Polymerization Possibilities: No data

oxygen or exposure to light or

Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): 21.4 ppm (sense of smell fatigues rapidly) Odor Description: Peachseed kernels (Source:CHRIS) 100% Odor Detection: No data

- REGULATIONS -DOT hazard class: 3 FLAMMABLE LIQUID DOT guide: 30 Identificationnumber: UN1093 DOT shipping name: Acrylonitrile, inhibited Packinggroup: I Label(s)required: FLAMMABLELIQUID,POISON SpecialProvisions: B9 Packaging exceptions: 173.None Nonbulkpackaging: 173.201 Bulkpackaging: 173.243 Quantity limitations: Passenger airhail: Forbidden Cargo aircraft only: 30 L Vesselstowage:E Otherstowage provisions: 40 STCC Number: 4906420 Clean Water Act Sect. 307: Yes Clean Water Act 311: Yes Clean Air Act:CAA '90 listed EPA WasteNumber: U009 CERCLA Ref: Y RQ Designation: B100pounds (45.4 kg)CERCLA SARA TPQ Value: 10,000 pounds SARA 312 Categories: Acute toxicity: irritant. Chronic toxicity: carcinogen. Chronic toxicity: adverse effect to target organs after longperiodsof exposure.

18

Chapter

Chronic toxicity: mutagen. Chronic toxicity: reproductive toxin. Fire hazard: flammable. Listed in SARA Sect. 313: Yes De Minimus Concentration: 0.1 %

U.S. Postal Service Mailability: Hazardclass:Flammable liquid; mailable as ORM-D Mailability: Domestic surface mailonly Max per parcel: 1 qt metal; 1 pt other

NFPA Codes: (4) Full protection will notbeadequate unless HealthHazard(blue): designed specifically for this chemical.DONOTENTERAREA! Flammability (red): Thismaterialcanbe ignited underalmost all temperature conditions. Reactivity(yellow): Normally unstable and readily undergoes violent change, but does not detonate. Special: Unspecified.

--TOXICITY DATA -Short-termToxicity: Inhalation: Levelsof 16 to 100 ppm for 20 to 45 min have caused headache, eye, nose, and throat irritation, general irritability, and liver and kidney irritation. Higher levels may produce nausea, vomiting, diarrhea, tremors, unconsciousnessandchangesin the liver. Skin: Direct contact may cause irritation, redness, and blisters. Absorption is significant andmay contribute to symptoms listed above. Eyes: Maycause severe irritation andchemical bums. Ingestion: Maycause severe irritation and chemical bums of the mouth, throat, and stomach, as well as other symptoms as listed under inhalation. (NYDH) Long-term Toxicity: Levels of 5 to 20 ppm may produce headache, fatigue, nausea, weakness, anemia, and other blood abnormalities, mild liver damage and eye irritation. Acrylonitrile has been shown to cause cancer and birth defects in laboratory animals.Ithasbeen linked to an increase in cancer among occupationally exposedworkers.(NYDH) Target Organs: CVS, liver, kidneys, CNS, skin Symptoms: Similar to those of hydrogen cyanide. Vapor inhalation may cause weakness, headache, sneezing, abdominal pain, andvomiting.Similar

f

Monomers 19Synthetic Rubbers symptoms shown if large amounts of liquid are absorbed through the skin; lesser amountscause stinging andsometimes blisters; contact witheyes causes severe irritation. Ingestion produces nausea, vomiting, and abdominalpain(Source:CHRIS).

Conc IDLH 500 ppm NOSH =L: Potential occupational carcinogen1 (skin). Timeweighted averages for 8-hour exposure, 10 (skin). Ceiling exposures that shall at no time be exceeded. ACGM TLV: TLV = 2, A2 ppm (4.5, A2 mg/m3) skin ACGIH STEL: Not listed OSHA PEL: Final rule limits:TWA (skin); Consult 29 CFR 1910.1045.

= 2ppm (skin); Ceiling = 10ppm

MAK Information: Dangerofcutaneous

absorption; Carcinogenicworking material without MAK; In the Commission’s view, an animal carcinogen.

Carcinogen: Y;Status: Seebelow References: Human suspected IARC** 19, 73, 79; Animal positive IARC** 19,73,79; Human suspected IARC** 28, 151, 82;Animal suspected IARC** 28, 151, 82 Carcinogen Lists: I A R C Carcinogendefined byIARC to beprobably carcinogenic to humans with (usually) at least limited human evidence; M A K Ananimal carcinogen; NZOSH: CarcinogendefinedbyNIOSHwithno further categorization; NTP Carcinogendefined by NTPasreasonably anticipated to be carcinogenic, with limited evidence in humans or sufficient evidence in experimental animals; ACGIH Carcinogen defined by ACGIH TLV Committee as a suspected carcinogen, based on either limited epidemiological evidence or demonstration ofcarcinogenicity in experimental animals; OSHA: Cancer hazard. HumanToxicity Data: (Source:NIOSHRTECS) ihl-hmn TCLo:16 ppm/20 M INMEAF 17, 199, 48 Sense Organs Nose Other Eye Conjunctive irritation

20

Chapter 2 Lungs, Thorax, or Respiration Other changes

ihl-man LCLO: 1 gm/m3/1H ZAARAM 16, 1, 66 Behavioral Somnolence (general depressed activity) Gastrointestinal Hypermotility, diarrhea Nausea or vomiting

LDS0 Value: orl-rat LD50:78 mgkg Other Species Toxicity Data: (Source:NIOSHRTECS

1992)

orl-rat LD50:78 mgkg ihl-rat LC50:425 ppm/4H skn-rat LD50: 148 mgkg ipr-rat LD50:65 mg/kg scu-rat LD50:96 mg/kg unr-rat LDLo:200 mg/kg orl-mus LD50:27 mgkg ipr-mus LD50:46 mg/kg scu-mus LD50:25 mg/kg ihl-dog LCLo:110 ppm/4H ivn-dog LDLo:200 mg/kg ihlcat LCLO:600 ppm/4H ihl-rbt LCLO:260 ppm/4H skn-rbt LD50:250 mgkg ivn-rbt LD50.69 mg/kg orl-gpg LD50:50 mg/kg ihl-gpg LCLO:575 ppm/4H skn-gpg LD50:202 mg/kg scu-gpg LD50: 130 mg/kg

Irritation Data: (Source:NIOSHRTECS skn-hmn 500 mg nse skn-rbt 10 mg/24H eye-rbt 20 mg SEV

1992)

ReproductiveToxicity reproductive toxin.

This chemical is a mammalian

(1992 RTECS):

Monomers of Synthetic Rubbers

21

Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo:650 mgkg (6-15D preg) DOWCC* 03NOV76 Effects on Fertility Female fertility index Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Specific Developmental Abnormalities Musculoskeletal system orl-rat TDLo:650 mgkg (6-15D preg) TJADAB 17, 50A, 78 Specific Developmental Abnormalities Musculoskeletalsystem Cardiovascular (circulatory) system ihl-rat TCLo:40 ppm/6H (6-15D preg) FCTXAV 16, 547, 78 Maternal Effects Other effects on female Nutritional and Gross Metabolic See also Biochemical Weight loss or decreased weight gain ihl-rat TCLo:80 ppm/6H (6-15D preg) FCTXAV Specific Developmental Abnormalities Musculoskeletal system

16, 547, 78

ipr-mus TDLo:32 mgkg (5D preg) ZHYGAM 26, Effects on Fertility Postimplantation mortality

80

ipr-ham TDLo:641 mgkg (8D preg) TJADAB 23, 317, 81 Effects on Fertility Postimplantation mortality Specific Developmental Abnormalities Central nervous system ipr-ham TDLo:641 mg/kg (8D preg) TJADAB 23, 325, 81 Effects on Embryo or Fetus Extra embryonic features (e.g., placenta, umbilical cord) Cytological changes (including somatic cell genetic material) Fetotoxicity (except death, e.g., stunted fetus) No Significant Risk Level (Ca MS): No. 7 mg/day

Chapter 2

-PROTECTION AND FIRST AID

-

Protection Suggested from the CHRIS Manual: Air-supplies mask, industrial chemical type, with approvedcanister for acrylonitrile in low (less than 25 X) concentrations; rubber or plastic gloves; cover goggles or face mask; rubber boots; slicker suit; safety helmet.

NOSH Pocket Guide to Chemical Hazards: **Wear Appropriate Equipment to Prevent: Repeated or prolonged skin contact. **Wear Eye Protectionto Prevent: Reasonable probability of eye contact. **Exposed Personnel Should Wash: Immediately when skin becomes wet. **Remove Clothing: Immediately remove any clothing that becomes wet to avoid any flammability. **The Following Equipment Should Be Made Available: Eyewash, quick drench. **Reference: NIOSH Recommended Respiration Protection Source:NIOSH Pocket Guide(85-1 14) OSHA (Acrylonitrile) Less than or equal to 20ppm: (1) Chemical cartridge respirator with organic vapor cartridge(@and half-mask facepiece; or (2) supplied air respirator with half-mask facepiece. Less than or equal to I o 0 ppm or maximumuse concentration (MUC) Cartridges or canisters, whichever is lower: (1) Full facepiece respirator with (A) organic vapor cartridges, (B) organic vapor gas mask chin-style, or (C) organic vapor gas mask canister, front- or back-mounted; (2) supplied air respirator with full facepiece; or self-contained breathing apparatus with full facepiece. Lessthan or equal to 4000 ppm: Supplied air respirator operated in the positive pressure mode with full facepiece, helmet, suit, or hood. Greater than 4000 ppm or unknown concentration: (1) Supplied air and auxiliary self-contained breathing apparatus with full facepiece in positive pressure mode; or (2) self-contained breathing apparatus with full facepiece in positive pressure mode.

Monomers of Synthetic Rubbers

23

Escape: (1) Any organic vapor respirator; or (2) any self-contained breathing apparatus. Firejighfing: Self-containedbreathing apparatus with full facepiece in positive pressure mode.

FirstAidSource: CHRISManual1991. call physician for all cases of Skilled medical treatment isnecessary; exposure. Inhalation: Removevictim to fresh air. (Wear an oxygen or fresh-airsupplied mask when entering contaminated area.) Ingestion: Induce vomiting byadministering strong solution of salt water, but only if victim is conscious. Skin: Remove contaminated clothing and wash affected area thoroughly with soap and water. Eyes: Hold eyelids apart and wash with continuousgentle stream of water for at least 15 min. If victim is not breathing, give artificial respiration until physician arrives. If he is unconscious, crush an amyl nitrite ampule in a cloth and hold it under his nose for 15 sec every minute. Do not interrupt artificial respiration while doing this. Replace ampule when its strength is spent and continue treatment until condition improves or physician arrives. First Aid Source: DOT Emergency Response Guide 1993. Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature, Effects may be delayed; keep victim under observation.

--- INITIAL INCIDENT RESPONSE -FireExtinguishment: Dry chemical, alcohol foam,carbon dioxide. Note: Water or foam may cause frothing (CHRIS 91). U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT ShippingName: Acrylonitrile, inhibited DOT ID Number: UN1093

Chapter 2

24

ERG90

* POTENTIAL HAZARDS *

GUIDE 30

*Health Hazards Poisonous; may be fatal if inhaled, swallowed, or absorbed through skin. Contact may cause bums to skin and eyes. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Extremely flammable; may be ignited by heat, sparks, and flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion and poison hazard indoors, outdoors, or in sewers. Runoff to sewer may create fire or explosion hazard.

* EMERGENCY

ACTION

*

Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressure self-contained breathing apparatus (SCBA) and chemical protective clothing that is specifically recommended by the shipper or manufacturer may be worn. It may provide little or no thermal protection. Structural firefighter’s protective clothing is not effective for these materials. Isolate the leak or spill area immediately for at least 150 ft. in all directions. See the Table of Initial Isolation and Protective Action Distances. If you find the ID Number and the name of the material there, begin protective action. Isolate for 1/2 mile in all directions if tank, rail car, or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE.

*Fire Smallfires: Dry chemical, COz, water spray or regular foam. Largefires: Water spray, fog, or regular foam. Do not get water inside container. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire.

Monomers of Synthetic Rubbers

25

*Spill or Leak Shut off ignition sources; no flares, smoking, or flames in hazard area. Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch or walk through spilled material. Small spills: Flush area with flooding amounts of water. Large spills: Dike far ahead of liquid spill for later disposal. *First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 minutes. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature. Effects may be delayed; keep victim under observation.

--- IDENTIFIERS --Name: 1,3-BUTADIENE Synonyms: Biethylene; Bivinyl; Butadieen (Dutch); Buta- 1,2-Dieen (Dutch); Butadien (Polish); Buta-l,3-Dien (German); Butadiene; Buta-l,3-Diene; alpha-gamma-Butadiene; Divinyl; Erythrene; NCI-C50602; Pyrrolylene; Vinylethylene CAS: 106-99-0; RTECS: EI9275000 Formula: C,H,; Mol Wt: 54.09 WLN: 1U2U1 Chemical Class: Olefin See other identifiers listed below under Regulations.

--- PROPERTIES --Physical Description: Colorless liquified compressed gas with gasolinelike odor. Boiling Point: 268.7 1 K; -4 S"C; 24°F Melting Point: 164.27 K; -108.9"C; -164°F Flash Point: 196.89 K; -76.3"C; -105.3"F Autoignition: 693 K; 419.8"C; 787.7"F Critical Temp: 425 K; 151.85"C; 305.33"F

Chapter Critical Press: kN/M*; atm; psia Heat of Vap: Btu/lb; cal/g; E5 J/kg Heat of Comb: Btu/lb; cal/g; E5 J/kg Vapor Pressure: mm at UEL: LEL: IonizationPotential (ev): Vapor Density: (air = SpecificGravity: 0°C Density: at % Water Solubility: Incompatibilities: Strong oxidizers, copper,copper alloys Reactivity with Water: No data on water reactivity ReactivitywithCommonMaterials: Powerful oxidizers (Source: S A X ) Stability during Transport: Explosive decomposition when contaminated with peroxides formed by reaction with air Neutralizing Agents: No data Polymerization Possibilities: Stable when inhibitors present Toxic Fire Gases: Acrid fumes Odor Detected at (ppm): mg/m3 Odor Description: Mildlyaromatic(Source:CHRIS) 100% Odor Detection: ppm

--REGULATIONS -DOT hazard class: FLAMMABLE GAS DOT guide: Identificationnumber: UN1010 DOT shipping name: Butadienes, inhibited Label@)required: FLAMMABLEGAS Packaging exceptions: Nonbulk packaging: Bulk packaging: Quantity limitations: Passenger airhail: Forbidden Cargo aircraft only: 150 kg Vesselstowage:B Otherstowage provisions: STCCNumber:

Monomers of Synthetic Rubbers

27

Clean WaterAct Sect. No Clean WaterAct Sect. 311: No CleanAirAct: CAA listed EPAWasteNumber: None CERCLA Ref: Not listed RQDesignation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: adverse effect to target organs. Chronic toxicity: carcinogen. Chronic toxicity: mutagen. Chronic toxicity: reproductive toxin. Fire hazard: flammable. Sudden pressure: compressedgases. Reactivehazard: unstableheactive. Listed in SARA 313: Yes De Minimus Concentration: 0.1 %

U.S. Postal Service Mailability: Hazard class: Notgiven Mailability: Nonmailable Maxper parcel: 0

NFPA Codes: Health Hazard (blue): (2) Hazardous to health. Area may be entered with self-contained breathing apparatus. Flammability (red):(4) This material forms readily ignitable mixtures in air. Reactivity(yellow): (2) Normally unstable and readily undergoes violent change, but does not detonate. Special: Unspecified.

--- TOXICITY DATA -Short-termToxicity: Znhulution: Maycause irritation to the nose, throat, narcotic effects, and lungs. Concentrationsabove 8000 ppmmaycause dizziness, headache,drowsiness,and loss of consciousness. Skin: Thegas may cause irritation; the liquid may cause freezing and frostbite. Eyes: May cause irritation. Ingestion: The liquid may cause freezing and frostbite to the mouthand throat. (NYDH)

28

Chapter 2

Long-term Toxicity: Exposures to levels below 5000 ppm over long periods has caused no ill effects. Butadiene has been shown to cause cancer andbirth defects in laboratory animals. Whether it does in humans is unknown. NIOSH recommends butadienebe considered a potential occupational carcinogen, teratogen, and a possible reproductive hazard. (NYDH) TargetOrgans: Skin, mucousmembrane,eyes Symptoms: Slightanestheticeffectathigh concentration; causes "frostbite" from skin contact; slight irritation to eyes and nose at high concentrations (Source: CHRIS). Conc IDLH:

ppm

NIoSH Rel: Potential occupational carcinogen; Lowest Feasible PP@

(LOQ 0.19

ACGIH TLV: TLV = ppm.Suspectedhumancarcinogen(A2) ACGIH STEL: Notlisted

OSHA PEL: Transitional limits: PEL = lo00 PPM (2200 mg/m3); Final rule limits:TWA = ppm (2200 mg/m3)

MAK Information: CarcinogenicworkingmaterialwithoutMAK.In

the

Commission's view, an animal carcinogen.

Carcinogen: Y;Status: Seebelow Carcinogen Lists: Z C ': Carcinogendefined by IARC to be possibly carcinogenic to humans, but having (usually) no human evidence;M M : animal carcinogen; NZOSH: Carcinogen defined by NIOSH with no further categorization; NTP: Not listed; ACGIH: Carcinogendefined by ACGIH TLV Committeeas a suspected carcinogen, basedon either limited epidemiological evidenceor demonstration of carcinogenicity in experimental animals; OSHA: Not listed. HumanToxicityData: (Source: NIOSHRTECS) ihl-hmn TCLo:2000 ppm/7H JIHTAB 26, 69, 44 Sense Organs Eye Other

Monomers of Synthetic Rubbers

29

Behavioral Hallucinations, distorted perceptions

LD50 Value: orl-rat LD50:5480 mg/kg OtherSpeciesToxicity Data: (Source:NIOSHRTECS orl-rat LD50:5480 mg/kg ihl-rat LC50:285 g/m3/4H ihl-mus LC50:259 g/m3 ihl-rbt LCLo:25 pph/23M ReproductiveToxicity(1992RTECS): reproductive toxin.

1992)

This chemical is amammalian

Reproductive Toxicity Data (1992 RTECS): ihl-rat TCLo:8000 ppm/6H (6-15D preg) EPASR* 8 EHQ-0382-0441 Specific Developmental Abnormalities Musculoskeletalsystem ihl-mus TCLo:lOOO p p d 6 H (6-15D preg) EVHPAZ 86, 79, 90 Effects Fertility Postimplantation mortality Effects Embryo or Fetus Extra embryonic features e.g., placenta, umbilical cord Fetotoxicity (except death, e.g., stunted fetus) No Significant Risk Level (Ca P69: 0.4 mg/day

--PROTECTION AND FIRST AID -ProtectionSuggestedfromthe CHRIS Manual: Chemical-type safety goggles; rescue harness and safe line for those entering a tank or enclosed storage space; hose mask with hose inlet in vapor-free atmosphere; selfcontained breathing apparatus; rubber suit.

NIOSH Pocket Guide to Chemical Hazards: **Wear Appropriate Equipment to Prevent: Prevent skin freezing.

** Wear Eye Protection to Prevent:

Reasonable probability of eye contact.

**Exposed Personnel Should Wash: Immediately when skin becomes wet.

Chapter 2

**Remove Clothing: Immediately remove any clothing that becomes wet to avoid any flammability. **Reference: NIOSH RecommendedRespirationProtectionSource: NIOSHPocketGuide (85114); NIOSH (1,3-Butadiene) Greater atany detectable concentration: Anyself-contained breathing apparatus with full facepieceandoperatedinapressure-demand or other positive-pressure mode. Any supplied-air respirator with a full facepiece and operated in pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressuredemand or other positive-pressure mode. Escape: Any air-purifying full facepiece respirator (gas mask) with a chinstyle or front- or back-mounted canister providing protection against the compound of concern. Any appropriate escape-type self-contained breathing apparatus. First Aid Source: CHRIS Manual 199 1. a physician. Remove from exposure immediately. Call Inhalation: If breathing is irregular or stopped, start resuscitation, administer oxygen. Skin contact: Remove contaminated clothing and wash affected skin area. Eye contact: Irrigate with water for 15 min. FirstAidSource: DOTEmergencyResponseGuide1993. Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of frost5ite, thaw frosted parts with water. Keepvictim quiet andmaintain normal body temperature.

--- INITIAL INCIDENT RESPONSE --Fire Extinguishment: Stop flow of gas (CHRIS 91). U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOTShippingName: Butadienes, inhibited DOT ID Number: UN1010

Monomers of Synthetic Rubbers ERG90

* POTENTIAL HAZARDS *

31

GUIDE 17

*Fire or Explosion Extremelyflammable. May be ignited by heat, sparks, and flames. Vapors may travel to a source of ignition and flash back. Container may explode violently in heat of fire. Vapor explosion hazard indoors, outdoors, or in sewers. *Health Hazards May be poisonous if inhaled. Contact may cause bums to skin and eyes. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car, or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, especially if there is no local hazardous team available.

*Fire Let tank, tank car, ortank truck bum unless leak can be stopped; with smaller tanks or cylinders, extinguish or isolate from other flammables. Small fires: Dry chemical or CO2 Large fires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. For massive fire in cargo area, use unmanned hose holderor monitor nozzles; if this is impossible, withdraw from area and let fire bum. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. Cool container with water using unmanned deviceuntil well after fire is out.

32

Chapter 2

*Spill or Leak Shut off ignition sources; no flares, smoking, or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapors; but it may not prevent ignition in closed spaces. Isolate area until gas has dispersed. *First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of frostbite, thaw frosted parts with water. Keep victim quiet and maintain normal body temperature.

--IDENTIFIERS -Name: CHLOROPRENE Synonyms: 2-Chloor-l,3-Butadieen (Dutch); 2-Chlor-l,3-Butadien (German); Chlorobutadiene; 2-Chlorobuta-l,3-Diene; 2-Chloro-l,3-Butadiene; Chloropreen (Dutch); Chloropren(German, Polish); Chloroprene;betaChloroprene; 2-Cloro-1,3-Butadiene (Italian); Cloroprene (Italian); Neoprene CAS: 126-99-8; RTECS: E19625000 Formula: C,H,Cl; MolWt: 88.54 WLN: lUYGlUl ChemicalClass: Halogenatedh-carbon See other identifiers listed below under Regulations.

--- PROPERTIES -Physical Description: Colorless liquid with an etherlike odor BoilingPoint: 332.04K;58.8"C;138°F MeltingPoint: 143.16K; -13OOC;-202OF FlashPoint: 253 K;-20.2"C;-4.3OF Autoignition: VaporPressure: 179 mm UEL: 20% LEL: 4% IonizationPotential(eV): 8.83 VaporDensity: 3.0 (air = 1) SpecificGravity: .958 at 29°C

Monomers of Synthetic Rubbers Density: .958 g/cc or 8.9094 lb/gal Water Solubility: INSOL Incompatibilities: Peroxides, other oxidizers, fluorine Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: Hydrogen chloride upon decomp by heat Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: Nodata

--REGULATIONS -DOT hazard class: 3 FLAMMABLE LIQUID DOT guide:30 Identificationnumber: UN1991 DOT shipping name: Chloropropene, inhibited Packinggroup: I Label($required: FLAMMABLELIQUID, POISON Special provisions: B57,T15 Packaging exceptions: 173.None Nonbulk packaging: 173.201 Bulk packaging: 173.243 Quantity limitations: Passenger airhail: Forbidden Cargo aircraft only: 30 L Vesselstowage: D Otherstowageprovisions: 40, M2 STCCNumber:

4921414

307: No Clean Water Act Clean Water ActSect. 311: No Clean Air Act:CAA'90listed EPA Waste Number: None CERCLA Ref: Notlisted RQ Designation: Notlisted SARA TPQ Value: Not listed

33

34

Chapter 2

SARA Sect. 312 Categories: Acute toxicity: adverse effect to target organs, Chronic toxicity: mutagen. Chronic toxicity: reproductive toxin. Fire hazard: flammable. Listed in SARA Sect. 313: Yes De Minimus Concentration: 1 .O% U.S. Postal Service Mailability: Hazard class: Flammable liquid; mailable as ORM-D Mailability: Domestic surface mailonly Maxper parcel: 1 qt metal; 1 qt other

NFPA Codes: Health Hazard (blue): (2) Hazardous to health. Area may be entered with self-contained breathing apparatus. Flammability (red): Thismaterialcanbe ignited underalmost all temperature conditions. Reactivity (yellow): Stable even under fire conditions. Special: Unspecified.

--TOXICITY DATA -Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

TargetOrgans: Respiratorysystem, skin, eyes, lungs Symptoms: Irritated eyes and respiratory system, nervous, imtable; dermatitis, alopecia (Source: NIOSH) Conc IDLH

ppm

NIOSH REL: Potential occupational carcinogen at 1 ppm. Ceiling exposures that shall at no time be exceeded, mg/m3. ACGIH TLV: TLV = 10 ppm (45 mg/m3), skin ACGIH STEL: Skin

of

Monomers

35

OSHA PEL: Transitional limits: PEL - 25 ppm (90 mg/m3) (skin); Final rule limits:TWA = 10pprn(35mg/m3)(skin).

MAK Information: 10 ppm; 36 mg/m3; Substance with systemiceffects, onset of effect less than or equal to 2 hr: Peak = 2 x MAK for 30 min, 4 times per shift of 8 hr; danger of cutaneous absorption. Carcinogen: N; Status: Seebelow References: Animal indefinite IARC** 19, 131, 79; Carcinogenic determination CarcinogenLists: Z A R C Notclassified as to humancarcinogenicity or probably not carcinogenic to humans; MAK. Not listed; NZOSH Carcinogen defined by NIOSH with no further categorization; NTP Not listed; ACGZH: Not listed; OSHA: Not listed. LDS0Value: orl-rat LD50:450 mg/kg OtherSpeciesToxicityData: (Source: NIOSH RTECS1992) orl-rat LD50:450 mgkg ihl-rat LC50: 11800 mg/m3/4H scu-rat LDLo:500 mg/kg orl-mus LD50:146 mg/kg ihl-mus LC50:2300 mg/m3 scu-mus LDLo:l g/kg ihl-cat LCLo: 1290 mg/m3/8H scu-cat LDLo: 100 mg/kg ihl-rbt LCLo:3870 mg/m3/8H ivn-rbt LDLo:96 mg/kg scu-pgn LDLo:13 g/kg ReproductiveToxicity reproductive toxin.

(1992 RTECS):

This chemical is a mammalian

Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo:l mg/kg (3-4D preg) GTPZAB 19(3), 30, 75 Effects on Embryo or Fetus Fetal death orl-rat TDLo:l mgkg (11-12D preg) GTPZAB 19(3), 30, 75 Specific Developmental Abnormalities Central nervous system

36

Chapter 2

orl-rat TDLo:l mg/kg (1 1-12D preg) GTPZAB 19(7), 30, 75 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) orl-rat TDLo:l mg/kg (9-10D preg) GTPZAB 19(7), 30, 75 Specific Developmental Abnormalities Other developmental abnormalities ihl-rat TCLo:4 mg/m3/24H (3-4D preg) GTPZAB Effects on Embryo or Fetus Fetal death

19(3), 30, 75

ihl-rat TCLo:4 mg/m3/24H (11-12D preg) GTPZAB 19(3), 30, 75 Specific Developmental Abnormalities Central nervous system ihl-rat TCLo:lO p p d 4 H (3-20D preg) TXAPA9 44, 81, 78 Effects on Fertility Postimplantation mortality ihl-rat TCLo:150 mg/m3/24H (19W male) EVHPAZ Paternal Effects Spermatogenesis

17, 85, 76

ihl-rat TCLo:500 mg/m3/5H (17W pre) BEBMAE 60(7), 107, 65 Maternal Effects Menstrual cycle changes or disorders

--PROTECTION AND FIRST AID --NOSH Pocket Guide to Chemical Hazards: **WearAppropriateEquipment to Prevent: contact.

Any possibilityof

skin

**Wear Eye Protection to Prevent: Reasonable probability of eye contact. **Exposed Personnel contaminated.

Should Wash:

Promptly when

skin becomes

**Remove Clothing: Immediately remove any clothing that becomes wet to avoid any flammability.

Monomers of Synthetic Rubbers

37

**Reference: NIOSH First AidSource: CSDS. Inhalation: Leave contaminatedarea immediately; ifdifficult breathing or any other symptoms develop, seek medical attention at once, even if symptoms develop many hours after exposure. Ingestion: If convulsions are not present, give aglass or two of wateror milk to dilute the substance. Assure that the person’s airwayis unobstructed; contact a hospital or poison center immediately for advice on whether or not to induce vomiting. Skin: Flood contacted areas with water. Remove contaminatedclothing under skin. Use soap. Isolate contaminated clothing whenremoved to prevent contact by others. Eyes: Remove contacts. Flush well with water or normal saline for 20 to 30 minutes.Seekmedical attention. First AidSource: DOTEmergencyResponseGuide1993. Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature. Effects may be delayed; keep victim under observation.

--INITIAL INCIDENT RESPONSE --FireExtinguishment: Alcoholfoamrecommended for fires. Watermay be ineffective but should be used to keep fire-exposed containers cool (Note: CHRIS 91). U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT ShippingName: Chloropropene, inhibited DOT ID Number: UN1991

ERG90

* POTENTIAL HAZARDS *

GUIDE 30

*Health Hazards Poisonous; may be fatal if inhaled, swallowed, or absorbed through skin. Contact may cause bums to skin and eyes.

Chapter 2

*Fire or Explosion Extremely flammable; may be ignited by heat, sparks, and flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion and poison hazard indoors, outdoors, or in sewers. Runoff to sewer may create fire or explosion hazard.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressure self-contained breathing apparatus (SCBA)andchemical protective clothing that is specifically recommendedby the shipper or manufacturer may be worn. It may provide little or no thermal protection. Structural firefighters’ protective clothing is not effective for these materials. Isolate the leak or spill area immediately for at least 150 ft in all directions. See the Table of Initial Isolation and Protective Action Distances. If you find the ID number and the name of the material there, begin protective action. Isolate for 1/2 mile in all directions if tank, rail car, or tank truck is involved in fire. CALLCHEMTRECAT 1-800-424-9300 FOREMERGENCYASSISTANCE.

*Fire Small fires: Dry chemical, COz, water spray, or regular foam. Large fires: Water spray, fog or regular foam. Do not get water inside container. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holderor monitor nozzles; if this is impossible, withdraw from area and let fire bum. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. *Spill or Shut off ignition sources; no flares, smoking, or flames in hazard area. Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch or walk through spilled material. Small spills: Flush area with flooding amounts of water. Large spills: Dike far ahead of liquid spill for later disposal.

of

Monomers

Synthetic Rubbers

39

*First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case contact with material, immediately flush skin or eyes with running water for at least 15 min. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature. Effects may be delayed; keep victim under observation.

--IDENTIFIERS -Name: ETHYLIDEm NORBORNENE Synonyms: 5-Ethylidenebicyclo(2.2.1)Hept-2-Ene; 5-Ethylidene-2-Norbornene; 5-Ethylidenebichcyl(2.2.1)Hept-ZEne;2-Norbornene, 5-EthylideneCAS: 16219-75-3; RTECS: RB9450000 Formula: C9H,2;MolWt: 120.21 WLN:L55 A CY FUTJ CU2 See other identifiers listed below under Regulations.

--- PROPERTIES --Physical Description: White liquid with a turpentinelike odor Boiling Point: 420.75 K; 147.6"C;297.6"F MeltingPoint: 353.15 K;80°C;176°F Flash Point: 309.81 K; 36.6"C; 97.9"F Autoignition: NA UEL: NA LEL: NA VaporDensity: 4.1 (air = 1) SpecificGravity: 0.896 at 20°C Density: 0.893 Incompatibilities: Reactswithoxygen Reactivity with Water: N/R; floats on water Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data PolymerizationPossibilities: No data

40

Chapter 2

Toxic Fire Gases: Acrid smoke and fumes Odor Detected at (ppm): 0.007 ppm Odor Description: Liketurpentine(Source: 100%Odor Detection: No data

CHRIS)

REGULATIONS

--

DOT hazard class: 3 FLAMMABLE LIQUID DOT guide: 27 Identificationnumber: UN1993 DOT shipping name: FLAMMABLE LIQUID, N.O.S. Packinggroup: 111 Label($required: FLAMMABLELIQUID Special Provisions: B1,B52, T7, T30 Packaging exceptions: 173.150 Nonbulkpackaging: 173.203 Bulkpackaging: 173.242 Quantity limitations: Passenger airhail: 60 L Cargo aircraft only: 220L Vesselstowage: A STCC Number: Notlisted Clean Water Act 307: No Clean Water Act 311: No Clean Air Act:Notlisted EPA Waste Number: None CERCLA Ref: Notlisted RQ Designation: Notlisted SARA TPQ Value:Notlisted SARA Sect. 312 Categories: Acute toxicity: irritant. Acute toxicity: adverse effect to target organs.

U.S. PostalServiceMailability:

Notgiven

NFPA Codes: Health Hazard (blue):Unspecified Flammability(red): Unspecified Reactivity (yellow):Unspecified Special: Unspecifed

Monomers of Synthetic Rubbers

41

--TOXICITY DATA -Short-termToxicity:

Unknown

Long-termToxicity: Causeskidney weights in rats (Source:HCDB).

lesions andgain

in kidneyand

liver

Target Organs: Respiratory system, digestive system, eyes, skin Symptoms: Inhalation of vapors causes headache, confusion, and respiratory distress. Ingestion causes irritation of entire digestive system.Aspiration causes severe pneumonia. Contact with liquid causes irritation of eyes and skin (Source: CHRIS). Conc IDLH Unknown ACGIHTLV: TLV = 5 ppm (25 mg/m3)C ACGIHSTEL: Not listed

OSHA PEL Final Rule Limits: Ceiling = 5 ppm (25 mg/m3); enforcement of limit indefinitely stayed. MAK Information: Notlisted Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; M A K Not listed; NZOSH. Not listed; N T P Not listed; ACGZH Not listed; OSHA: Not listed. HumanToxicityData: (Source:NIOSHRTECS) ihl-hmn TCLo:6 ppm/30M TXAPA9 20, 250, 71 Sense Organs Nose Other Eye Conjunctive irritation Taste Change in function LD50 Value: orl-rat LD50:2527 mg/kg

42

Chapter

Other Species Toxicity Data: (Source:NIOSHRTECS1992) orl-rat LD50:2527 mg/kg ihl-rat LC50: 1246 ppm/4H orl-mus LD50:3250 mg/kg ihl-mus LC50:732 ppm/4H ihl-rbt LC50:3104 ppm/4H skn-rbt LD50:8189 mg/kg ihl-gpg LC50:2896 ppm/4H Irritation Data: (Source:NIOSHRTECS1992) skn-rbt 445 mg open MLD Reproductive Toxicity (1992 RTECS): This chemical has no known mammalian reproductive toxicity.

--- PROTECTION AND FIRST AID -Protection Suggested the CHRIS Manual: Organic canister or airsupplied mask; goggles or face shield; rubber gloves.

First AidSource: CHRISManual1991. Inhalation: Remove victim to fresh air; administer artificial respiration and oxygen if required; call a doctor. Ingestion: Give large amountofwaterandinducevomiting;getmedical attention at once. Skin: Wipe off, wash with soap and water. Eyes: Flush with water for at least 15 min. First Aid Source: DOT Emergency Response Guide 1993. Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

--- INITIAL INCIDENT RESPONSE -Fire Extinguishment: Dry chemical, foam, carbon dioxide. Note: Water may be ineffective (CHRIS 91).

of

43

Monomers U.S. Department of Transportation Guide to Hazardous Materials Information - Publication DOT 5800.5 (1990). DOT Shipping Name: FLAMMABLE LIQUID, N.O.S. DOT ID Number: UN1993 ERG90

* POTENTIAL HAZARDS *

Transport

GUIDE 27

*Health Hazards May be poisonous if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact may irritate or bum skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Flamrnablekombustible material; may be ignited by heat, sparks, or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors, or in sewers. Runoff to sewer may create fire or explosion hazard.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressureself-containedbreathingapparatus(SCBA)and structural firefighters’ protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car, or tank truck is involved in fire. CALLCJlEMTREC AT 1-800-424-9300 FOREMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities. *Fire Smallfires: Drychemical,CO,,water spray, or regular foam. Large fires: Water spray, fog or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holdermonitor nozzles; if this is impossible, withdraw from area and let fire bum.

Chapter 2

44

Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire.

*Spill or Leak Shut off ignition sources; no flares, smoking, or flames in hazard area. Stop leak if you can do it without risk. Waterspraymayreducevapor;butitmaynotprevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal.

*First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

--IDENTIFIERS -Name: ISOPRENE Synonyms: 1,3-Butadiene, 2-Methyl-; Isoprene (DOT); beta-Methylbivinyl; 2Methylbutadiene; 2-Methyl-l,3-Butadiene CAS: 78-79-5; RTECS: NT4037000 Formula: C5H,; MolWt: 68.1 1 WLN: lUYl ChemicalClass: Olefin See other identifiers listed below under Regulations.

--PROPERTIES -Physical Description: Colorless water liquid with a mild odor Boiling Point: 307 K;33.8"C;92.9"F MeltingPoint: 153 K;-120.2"C;-184.3"F Flash Point: 220 K; -53.2"C; -63.7"F Autoignition: 493 K;219.8"C;427.7"F Critical Temp: 484.3 K; 211.15"C; 412.07"F Critical Press: 3.79 kN/mZ; 37.3 atm; 549 psia

Monomers of Synthetic Rubbers

45

Heat of Vap: 150 Btu/lb; 83.3 cal/g; 3 . 4 8 5 ~E5 J k g Heat of Comb: -18,848 Btu/lb; -10,479 cal/g; -438x E5 J k g UEL: NA LEL: NA IonizationPotential (ev): 5.7 Vapor Density: 2.3(air = 1) SpecificGravity: 0.681 at20°C Density: 0.681 Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: Accelerated by heat and oxygen, rusty iron. Iron should be treated with reducing agent, suchas sodium nitrite, before placing in isoprene service. Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): 0.005 ppm Odor Description: Mild, aromatic(Source:CHRIS) 100% Odor Detection: No data

--REGULATIONS DOT hazard class: 3 FLAMMABLE LIQUID DOT guide: 27 Identificationnumber: UN1218 DOT shipping name: Isoprene,inhibited Packinggroup: I Label($required: FLAMMABLELIQUID Special Provisions: T20 Packaging exceptions: 173.150 Nonbulk packaging: 173.201 Bulkpackaging: 173.243 Quantity limitations: Passenger airhail: 1 L Cargo aircraft only: 30 L Vesselstowage: E

STCCNumber:

4907230

46

Chapter 2

CleanWaterAct Sect. 307: No Clean WaterAct Sect. 311: Yes Clean Air Act: Not listed EPAWasteNumber: None CERCLARef: Y RQ Designation: B; 100 lb (45.4 kg) CERCLA SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: adverse effect to target organs. Chronic toxicity: mutagen. Fire hazard:flammable. Reactive hazard: unstableheactive.

U.S. Postal Service Mailability: Hazard class: Notgiven Mailability: Nonmailable Maxper parcel: 0

NFPA Codes: Health Hazard (blue): Hazardous to health. Area may be entered with self-contained breathing apparatus. Flammability (red): (4) This material formsreadily ignitable mixtures in air. Reactivity(yellow): (2) Normally unstable and readily undergoes violent change, but does not detonate. Special: Unspecified.

--TOXICJTY DATA -Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

Target Organs: Irritator ofmucousmembranesof respiratory tract.

eyes, nose, andupper

Symptoms: Vapor produces no effects other than slight irritation of the eyes and upper respiratory tract. Liquid may irritate eyes, like gasoline (Source: CHRIS). ConcIDLH:

Unknown

NOSH REL: Not given

Monomers of Synthetic Rubbers

47

ACGM TLV Not listed ACGIHSTEL: Not listed WEEL (ACGIH): 50 ppm (8-hr OSHA PEL: Not in Table MAKInformation: Not listed Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; MAK: Not listed; NZOSH. Not listed; NTP: Not Listed; ACGZM Not listed; OSHA: Not listed. LDS0 Value: No LD50 in RTECS OtherSpeciesToxicityData: (Source:NIOSH ihl-rat LC50: g/m3/4H ihl-mus LC50: g/m3/2H

RTECS

Reproductive Toxicity (1992 RTECS): This chemical has no known mammalian reproductive toxicity.

--PROTECTION AND FIRST AID --Protection Suggested from the CHRIS Manual: Vapor-proof goggles; selfcontained breathing apparatus; leather or rubber shoes; rubber gloves. First AidSource: CHRISManual Inhalation: Remove victim promptly from irritating or asphyxiating atmosphere; if symptoms of asphyxiation persist, administer artificial respiration and oxygen; treat symptomatically thereafter; call a physician. Eyes: Flush with water for at least min. First AidSource: DOT Emergency Response Guide Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running min. Wash skin with soap and water. water for at least Remove and isolate contaminated clothing and shoes at the site.

48

Chapter 2

- INITIAL INCIDENT RESPONSE -FireExtinguishment: Drychemical,foam, may be ineffective (CHRIS 91).

or carbondioxide. Note: Water

U.S. Department of Transportation Guide to Hazardous Materials Information - Publication DOT 5800.5 (1990). DOT ShippingName: Isoprene,inhibited DOT ID Number: UN1218

ERG90

* POTENTIAL HAZARDS *

Transport

GUIDE 27

*Health Hazards May be poisonous if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact may irritate or bum skin and eyes. Fire may produce imtating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Flammable/combustible material; may be ignited by heat, sparks, or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors, or in sewers. Runoff to sewer may create fire or explosion hazard.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressureself-containedbreathingapparatus (SCBA) and structural firefighters’ protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car, or tank truck is involved in fire. CALLCHEMTREC AT 1-800-424-9300 FOREMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Smallfires: Dry chemical, CO,, water spray, or regular foam. Large fires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk.

Monomers

Synthetic Rubbers

49

Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holderor monitor nozzles; if this is impossible, withdraw from area and let fire bum. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire.

*Spill or Leak Shut off ignition sources; no flares, smoking, or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. *First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

--IDENTIFIERS -Name: VINYL CHLORIDE Synonyms: Chloroethylene; Vinyl Chloroide; Chloroethen; Chlorure De Vinyle (French); Chloro Vinyle Di (Italian); Ethylene Monochloride; Monochloroethene; Monochloroethylene (DOT); Vinyl Chloride Monomer; Vinyl C Monomer; Winylu Chlored (Polish); VCM; VCL CAS: 75-01-4; RTECS: KU9625000 Formula: C,H,Cl; Mol Wt: WLN GlUl ChemicalClass: Vinyl halide See other identifiers listed below under Regulations.

--PROPERTIES -Physical Description:

Colorless liquified compressed gas with a sweet odor

Chapter 2 Boiling Point: 259.4 K; -13.8"C;7.2"F Melting Point: 119.4 K; -153.8"C; -2443°F Flash Point: 194 K;-179.2"C;-110.5"F Autoignition: 745 K;471.8"C;881.3"F Critical Temp: 431.6 K; 158.45"C;317.21"F Critical Press: 5.34 kN/m2; 52.6 atm; 773 psia Heat of Vap: 160 Btu/lb; 88.85 cal/g; 3 . 7 1 8 ~E5 J/kg Heat of Comb: -8136 Btu/lb; -4523 cal/g; -189x E5 J/kg Vapor Pressure: 2600 mm at25°C UEL: 33% LEL:3.6% IonizationPotential (ev): 7.57 Vapor Density: 2.2 (air = 1)(air = 1) Specific Gravity: 0.969 at-13°C Density: 0.969 g/cc or 9.0117 Ib/gal Water Solubility: INSOL Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: Nodata Neutralizing Agents: No data Polymerization Possibilities: Polymerizes in presence of air, sunlight, or heat unless stabilized by inhibitors. Toxic Fire Gases: HCL and unburned toxic vapors Odor Detected at (ppm): 260 ppm Odor Description: Pleasant,sweet(Source:CHRIS) 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: 2. l FLAMMABLE GAS DOT guide: 17 Identificationnumber: UN1086 DOT shipping name: Vinyl chloride, inhibited Label($required: FLAMMABLE GAS Special Provisions: B44 Packaging exceptions: 173.306 Nonbulk packaging: 173.304 Bulk packaging: 173.314, 315 Quantity limitations: Passenger airhail: Forbidden

Monomers of Synthetic Rubbers

51

Cargo aircraft only: 150 kg Vesselstowage: B Otherstowage provisions: 40

STCCNumber: 4905792 Clean WaterAct Sect. 307: Yes CleanWaterAct 311: No National Primary Drinking Water Regulations Maximum contaminant levels (MCL): mg/L> > (01/09/89) Maximum contaminant level goals (MCLG): mg/L> > (01/09/89) Clean AirAct: CAA '90 listed EPAWasteNumber: U043, D043 CERCLA Ref: Not listed RQ Designation: X; 1 lb (0.454kg) CERCLA SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: adverse effect to target organs. Chronic toxicity: carcinogen. Chronic toxicity: adverse effect to target organs after long periods of exposure. Chronic toxicity: mutagen. Chronic toxicity: reproductive toxin. Fire hazard:flammable. Sudden pressure: compressedgases. Reactive hazard: unstable/reactive. Listed in SARA Sect. 313: Yes De Minimus Concentration: 0.1%

U.S. Postal Service Mailability: Hazardclass:Notgiven Mailability: Nonmailable Maxper parcel: 0

NFPA Codes: Health Hazard (blue): (2) Hazardous to health. Area may be entered with self-contained breathing apparatus. Flammability (red): (4) This material formsreadily ignitable mixtures in air. Reactivity(yellow): (1) Normally stable, but maybecome unstable at elevated temperature and pressures. Special: Unspecified.

Chapter 2

52

-TOXICITY DATA -Short-term Toxicity: Inhalation: Exposure at 8000 ppm for 5 min can cause a feeling of intoxication, tiredness, drowsiness, abdominal pain, numbness, and tingling in fingers and toes, pains in joints, coughing, sneezing, irritability, and loss of appetite and weight. Skin: Contact with liquid may cause frostbite; contact with vapor may cause irritation and rash. Absorption is possible through the skin. Eyes: Cancause severe andimmediate irritation. Ingestion: Nonefound.(NYDH) Long-term Toxicity: May causeclublike swelling and shortening of fingertips. Skin may become thickened andstiff with coarse, whitish patches. Bones and joints arms and legs may suffer damage. Liver and spleen damage may occur. Not all symptoms disappear after exposure stops. Vinyl chloride has caused liver cancer in occupationally exposed individuals. (NYDH) Target Organs: kidneys.

Skin, eyes, mucousmembranes,nervoussystem,

liver,

Symptoms: Inhalation: High concentrations cause dizziness, anesthesia, lung irritation. Skin: Maycause frostbite; phenol inhibitor may be absorbed through skin if large amounts of liquid evaporate (Source: CHRIS). Conc IDLH Unknown

NOSH REL: Potential occupational carcinogen (use 1910.1017) ACGIH TLV: TLV = 5 ppm; confirmed human carcinogen (Al) ACGM STEL: Not listed OSHA PEL: Final RuleLimits:TWA 29 CFR 1910.1017.

= 1 ppm; Ceiling = 5 ppm; Consult

MAK Information: Carcinogenic working material without MAK; Capable inducing malignant tumors as shown by experience with humans. Carcinogen: Y; Status: Seebelow References: Human positive IARC** 19, 377, 79; Animal positive IARC** 7, 291, 74; Human suspected IARC** 7, 291, 74; Animal positive IARC** 19, 377, 79; Human positive IARC** 28, 151, 82

Monomers Rubbers of Synthetic

53

Carcinogen Lists: I A R C Carcinogen as defined by IARC as carcinogenic to MAK: Capable of inducing humans, with sufficient epidemiological evidence; malignant tumors as shown by experience in humans; NIOSH Carcinogen defined by NIOSH with no further categorization; N T P Carcinogen defined by NTP as to be carcinogenic, with evidence from human studies; ACGZH Carcinogendefined byACGIH TLVCommittee as a confirmed human carcinogen, recognizedtohavecarcinogenic or cocarcinogenic potential; OSHA: Cancersuspect. LD50 Value: orl-rat LD50:500 mgkg OtherSpeciesToxicityData: (Source: NIOSH RTECS 1992) orl-rat LD50:500 mgkg ihl-rat LC50:18 pph/lSM ihl-mam LCLo:200 ppm/l8M ReproductiveToxicity reproductive toxin.

(1992

RTECS): Thischemicalis

a mammalian

Reproductive Toxicity Data RTECS): ihl-man TCLo:30 mg/m3 (5Y male) GTPZAB 24(5), 28, 80 Paternal Effects Spermatogenesis ihl-rat TCLo:100 ppm/6H (26W male) EESADV 10, 281, 85 Paternal Effects Testes, epididymis, sperm duct ihl-rat TCLo500 ppm/7H (6-15D preg) TXAPA9 33, 134, 75 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) ihl-rat TCLo:1500 ppm/24H (1-9D preg) TXCYAC 11, 45, 78 Effects on Fertility Postimplantation mortality ihl-rat TCLo500 ppm/7H (6-15D preg) EVHPAZ 41, 171, 81 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) SpecificDevelopmentalAbnormalities Musculoskeletalsystem

54

Chapter

ihl-rat TCLo:250 ppm/6H (55D preg) JTEHD6 Effects on Fertility Female fertility index

965, 77

ihl-mus TCLo:30000 ppm/6H (5D male) EVHPAZ 21, 71, 77 Effects on Fertility Preimplantation mortality ihl-mus TCLo500 ppm/7H (6-15D preg) EVHPAZ 41, 171, 81 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Specific Developmental Abnormalities Musculoskeletal system

No Significant Risk Level (Ca P65):

mg/day

--PROTECTION AND FIRST AID -Recommended Respiration Protection Source:NIOSH Pocket Guide(85-114) OSHA(VinylChloride) Unknown, or above 3600 ppm: Open-circuit, self-containedbreathing apparatus, pressure-demand type, with full facepiece. Not over 3600 ppm: Combination type C supplied-air respirator, pressuredemand type, with full or half facepiece, and auxiliary self-contained air supply; or Not over lo00 ppm: Combination type,. supplied-air respirator, continuousflow type, with full or half facepiece, and auxiliary self-contained air supply. Type C, supplied-air respirator, continuous-flow type, with full or half facepiece, helmet or hood. Not over I 0 0 p p m : (A) Combination type C supplied-air respirator, demand type; with full facepiece and auxiliary self-contained air supply; or (B) opencircuit self-contained breathing apparatus with full facepiece, in demand mode; or (C) type C supplied air respirator, demand type, with full facepiece. Not over 25ppm: (A) A poweredair-purifying respirator with hood, helmet, full or half facepiece, and acanister that provides aservice life of at least 4 hr for concentrations of vinyl chloride up to 25 ppm, or (B)gas mask, front- or back-mounted canister thatprovidesa service life ofat least 4 hr for concentration of vinyl chloride up to 25 ppm. Not over IOppm: (A) Combination type C supplied-air respirator, demand type, with half facepiece, and auxiliary self-contained air supply; or (B) type C supplied-air respirator, demand type, withhalf facepiece; or (C)any

f

Monomers

Synthetic Rubbers

55

chemical cartridge respirator with an organic vapor cartridge that provides a service life of at least 1 hr for concentrations of vinyl chloride up to 10 ppm.

FirstAidSource: CT HCDB. Inhalation: Move to fresh air, keep quiet and warm, call doctor, artificial respirator. Ingestion: Nonegiven Skin: Nonegiven Eyes: Nonegiven FirstAidSource: CHRISManual 1991. Inhulation: Remove patient to fresh air and keep him quiet and warm; call a doctor; give artificial respiration if breathing stops. Eyes and Skin: Flush with plenty of water for at least 15 min; for eyes, get medical attention; remove contaminated clothing. First AidSource: DOTEmergencyResponseGuide1993. Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of frostbite, thaw frosted parts withwater.Keepvictim quiet andmaintain normal body temperature.

--INlTIAL INCIDENT RESPONSE -Fire Extinguishment: For small fires use dry chemical or carbon dioxide. For large fires stop flow of gas. Cool exposed containers with water (CHRIS91). U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOTShippingName: Vinyl chloride, inhibited DOTIDNumber: UN1086 ERG90

* POTENTIAL HAZARDS *

*Health Hazards May be poisonous if inhaled. Contact may cause bums to skin and eyes. Vapors may cause dizziness or suffocation. Contact with liquid may cause frostbite. Fire may produce irritating or poisonous gases.

GUIDE 17

56

Chapter 2

*Fire or Explosion Extremelyflammable. May be ignited by heat, sparks, and flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors, or in sewers.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection. Isolate for 112 mile in all directions if tank, rail car, or tank truck is involved in fire. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, especially if there is no local hazardous team available.

*Fire Let tank, tank car, or tank truck bum unless leak can bestopped; with smaller tanks or cylinders, extinguish/isolate from other flammables. Small fires: chemical or COz. Largefires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. For massive fire in cargo area, use unmanned hose holderor monitor nozzles; if this is impossible, withdraw from area and let fire bum. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. Cool container with water using unmanned deviceuntil well after fire is out. *Spill or Leak Shut off ignition sources; flares, smoking, or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Isolate area until gas has dispersed. *First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of frostbite, thaw frosted parts with water. Keep victim quiet and maintain normal body temperature.

Monomers of Synthetic Rubbers

57

--IDENTIFIERS -Name: POLYETHYLEIW Synonyms: AC 8; AC 394; AC 1220; AC GA; ACP 6; AC 8 (Polymer); Acroart; Agilene; Alathon; Alathon 14; Alathon 15; Alathon 1560; Alathon 6600; Alathon 7026; Alathon 7040; Alathon 7050; Alathon 7140; Alathon 7511; Alathon5B;Alathon 71XHN; Alcowax 6; AldylA;Alithon 7050; Alkathene; Alkathene 17/04/00; Alkathene 22 300; Alkathene 200; Alkathene ARN 60; Alkathene WJG 11; AlkatheneWNG 14; AlkatheneXDG 33; Alkathene XJK 25; Allied PE 617; Alphex FIT 221;Ambythene;Amoco 610A4;A60-20R;A60-70R;Bakelite DFD 330; BakeliteDHDA 4080; Bakelite DYNH; Bareco Polywax 2000; Bareco Wax C 7500; Bicolene C; BPE-I; Bralen KB 2-1 l ; Bralen RB 03-23; Bulen A; Bulen A 30;Carlona 58030; Carlona 900; Carlona 18020 FA; Carlona PXB; Chemplex 3006; CIPE; Coathylene HA 1671; Courlene-X3; CPE; CPE 16; CPE25; Cryopolythene; Cry-0-Vac L; Daisolac; Daplen; Daplen 1810 H; DFD 0173; DFD 0188; DFD 2005; DFD 6005; DFD 6032; DFD 6040; DFDJ 5505; DGNB 3825; Diothene; Dixopak; DMDJ 4309; DMDJ 5140; DMDJ 7008; DQDA 1868; DQWA 0355; DXM 100; Dylan; Dylan Super; Dylan WPD 205; DYNH; DYNK 2; Eltex;Eltex 6037; Eltex A 1050; Epolene C; Epolene C10; Epolene C 11; Epolene E; Epolene E 10; Epolene E 12; Epolene N; Ethene Polymer; Etherin; EtherolE;EthyleneHomopolymer;EthylenePolymer; Ethylene Polymers (8CI); 23F203; Fabritone PE; FB 217; Fertene; Flamolin MF 15711; Flothene; FM 510; Fortiflex 6015; Fortiflex A 60/500; FP 4; 2100 GP; Grex; Grex PP 60-002; Grisolen; HFDB 4201 ; Hi-Fax; Hi-Fax 1900; Hi-Fax 4401; Hi-Fax 4601; Hizex; Hizex 5000; Hizex 5100; Hizex 3000B; Hizex3300F; Hizex 7000F; Hizex 7300F; Hizex 10915; Hizex 12915; Hizex13005;Hizex21005;Hizex22005;Hizex2100LP;Hizex 5100LP; Hizex 6100P; Hizex 3000s; Hizex 3300s; Hizex Hoechst PA 190; Hoechst WaxPA 520; Hostalen;Hostalen GD 620; HostalenGD 6250; Hostalen GF 4760; Hostalen GF 5750; Hostalen GM 5010; Hostalen GUR; Hostalen HDPE; Irax; Irrathene R; Lacqten 1020; LD 400; LD 600; LDPE 4; Lupolen4261A;Lupolen 6042D; Lupolen 1010H; Lupolen 1800H; Lupolen 1810H; Lupolen6011H;Lupolen KR 1032;Lupolen KR 1051; Lupolen KR 1257; Lupolen 601 1L; Lupolen L 6041D; Lupolen N; Lupolen 1800s; Manolene 6050; Marlex 9; Marlex 50; Marlex 60; Marlex 960; Marlex 6003; Marlex 6009; Marlex 6015; Marlex 6050; Marlex 6060; Marlex EHM 6001; Marlex M 309; Marlex TR 704; Marlex TR 880; Marlex TR 885; Marlex TR 906; Microthene;Microthene 510; Microthene 704; Microthene 710; Mecrothene F; Microthene FN 500; Microthene FN 510; Microthene MN 754-18; Mirason 9; Mirason 16; Mirason M 15; Mirason M 50; Mirason M 68; Mirason NE0 23H; Mirathen; Mirathen 1313; Mirathen

58

Chapter 2

1350;MoplenRO-QG 6015; Neopolin;Neopolin 30N; Neozex4010B; Neozex 45150; Nopol (Polymer); Novatec JUO 80; Novatec JVO 80; NVC 9025; Okiten G 23; Orizon; Orizon 805; 6020P; PA 130; PA 190; PA 520; PA 560; PAD 522; P 2010B; PE 512; PE 617; PEN 100; PEP 21 1;PES 100; PES 200; Petrothene; Petrothene LB 861; Petrothene LC 731; Petrothene LC NA 227;Petrothene XL 6301; 941; Petrothene NA 219;Petrothene P4007EU;P 4070L; Planium;Plaskon PP 60-002; Plastazote X 1016; Plastronga; Plastylene MA 2003; Plastylene MA 7007; Politen; Politen 1020; Polyaethylen (German); Poly-em 12; Poly-em 40; Poly-em41 ; Polyethylene AS; Polymist A12; PolymulCS 81; Polysion N 22; Polythene; Polywax1000; Porolen; P 2070P; PPE 2; Procene UF 1.5; Profax A 60-008; P 2020T; P2050T;P4007T;PTS 2; PVP 8T; PY 100; RCH 1000; Repoc;Rigidex; Rigidex 35; Rigidex 50; RigidexType 2; Ropol;RopotheneOB.03-110; Sanwax 161P; Sclair 59; Sclair 2911; Sclair 19A; Sclair 96A; Sclair 59C; Sclair 79D; Sclair 11K; Sclair 19x6; SDP 640; Sholex 5003; Sholex 5100; Sholex 6000; Sholex 6002; Sholex F 171;Sholex F 6050C; Sholex F 6080C; Sholex 4250HM; Sholex L 131; Sholex S 6008; Sholex Super; Sholex XMO 314; Socarex; SRM 1475; SRM 1476; StaflenE 650; Stamylan 900; Stamylan 1000; Stamylan 1700; Stamylan 8200; Stamylan 8400; Sumikathene; Sumikathene F 101-1; SumikatheneF210-3; Sumikathene F 702; Sumikathene G 201 ; Sumikathene G 202;Sumikathene G 701; Sumikathene G 801 ; Sumikathene G 806; SumikatheneHard2052;Sunwax 151; SuperDylan; Suprathen; Suprathen C 100; Takathene;Takathene P3; Takathene P 12; Telcotene;Telecothene;Tenaplas;Tenite800;Tenite 1811; Tenite 2910; Tenite 2918; Tenite 3300; Tenite 3340; Trovidur PE; Tyrin; Tyvek; Unifos DYOB S; UnifosEFD 0118; Valeron;Valspex155-53;VelustralKPA; Vestolen; Vestolen A 616; Vestolen A 6016; Wax LE; WJG 11; WNF 15; WVG 23; XL 335-1; XL 1246; XNM 68; X 0 440; Yukalon EH 30; Yukalon HE 60; Yukalon K 3212; Yukalon LK 30; Yukalon MS 30; Yukalon PS 30; Yukalon YK 30; ZF 36 CAS: 9002-88-4; RTECS: TQ3325000 Formula: (C,H,), Chemical Class: Polymer See other identifiers listed below under Regulations.

--- PROPERTIES -BoilingPoint: NA Melting Point: 403.16 to 418.16 K; 130 to 145°C; 266 to 293°F FlashPoint: NA Autoignition: NA

Monomers of Synthetic Rubbers

59

UEL: NA LEL: NA Vapor Density: Nodata SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data PolymerizationPossibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--

REGULATIONS

--

DOT hazard class: Not given Packaging exceptions: 173. Nonbulkpackaging: 173. Bulkpackaging: 173. STCC Number: Not listed Clean Water Act Sect. 307: No Clean Water Act 311: No Clean Air Act:Notlisted EPA Waste Number: None CERCLA Ref: Not listed R Q Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: No category

U.S. Postal Service Mailability:

Not given

--- TOXICITY DATA -Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

60

Chapter 2

Conc IDLH Unknown

NIOSH REL: Notgiven ACGIHTLV: Not listed ACGIHSTEL: Notlisted OSHA PEL: Not in Table Z-l-A MAKInformation: Notlisted Carcinogen: N; Status: Seebelow References: Animal positive IARC** 19, 157,79; Human indefinite IARC** 19, 157, 79 CarcinogenLists: Z A R C Notclassified to humancarcinogenicity or probably not carcinogenic to humans; MAK Not listed; NZOSH Not listed; NTP Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: No LD50 in RTECS 1992 OtherSpeciesToxicityData: orl-rat LD :> g/kg

(Source: NIOSH RTECS1992)

Reproductive Toxicity (1992 RTECS): Thischemical has noknownmammalian reproductive toxicity.

--INITIALINCIDENT RESPONSE No DOT Guide information for this compound.

--IDENTIFIERS Chemical Name and Synonyms: TRIMETHYLOLPROPANE TRIMETHYLACRYLATE; T " A Trade Name and Synonyms: ChemicalFamily:

Prespersion PLB-5405

AcrylicMonomer

o.

Monomers of Synthetic Rubbers

61

Manufacturer: Synthetic Products Co., Cleveland,Ohio

- INGREDIENTS AND COMPOSITION DATA %

Cas Material Trimethylolpropane trimethacrylate

3290-92-4

Calcium silicate carrier

1344-95-2 25

75

TLV -

25 ppm (skin)

15 mg/m3

- PHYSICAL DATA -BoilingPoint (“F): NA SpecificGravity (H,O = 1): NA VaporPressure(mm Hg): NA Percent Volatile byVolume VaporDensity(air

= 1): NA

EvaporationRate:

NA

NA

Solubility in Water: Negligible Appearance/Color/Odor: Tanwettedpowder.

--FIRE AND EXPLOSION HAZARDS -FlashPoint: 200°F FlammabilityLimits:

Unknown

Extinguishing Media: Water fog, carbon dioxide, dry chemicals, foam. SpecialFireFightingProcedures: Firefighters shouldwear self-contained breathing apparatus and protective clothing when fighting fires involving chemicals.

Chapter 2

Unusual Fire and Explosion Hazards:Excessive heat may cause polymerization.

--HEALTH HAZARD DATA -Effects of Overexposure: Prolonged or repeated skin contact may cause irritation and possible sensitization. Dust may irritate eyes, nose, and lungs. Emergency Response and First Aid: Skin: Wash with soap and water. Eyes: Irrigate with water, consult physician if irritation persists. Inhulurion: Remove victim to fresh air and consult physician if breathing difficulties arise. Ingesrion: Gastric lavage (stomach wash), consult physician.

--REACTIVITY DATA -Stability and Conditions to Avoid: Material is stable; however, you should avoid elevated temperatures. Materials to Avoid (Incompatibility): Strong oxidizing and reducing agents. Hazard Decomposition Products: Oxides of carbon, acrid smoke, and fumes. HazardousPolymerization: Willnot occur. Conditions to Avoid: Polymerization catalysts, oxygen-freeatmospheres, oxidizing and reducing agents, alkalines, amines, acids, UV radiation.

--SPILL AND EMERGENCY RESPONSE --For Spills: Sweep up or vacuum. WasteDisposalMethod: local regulations.

--

Disposeof in accordancewith federal, state, and

SPECIAL PROTECTION AND PRECAUTIONS

--

Respiratory Protection: Use OSHA-approved respirator for dust. Type of Ventilation Required: General mechanical.

Monomers of Synthetic Rubbers

EyeProtectionRequirements:

Safety goggles.

ProtectiveGlovesand Other: Wearimperviousrubber tective clothing to minimize skin contact.

gloves. Wearpro-

Storage and Handling Precautions:Store in cool, dry location away from all sources of heat, spark, and open flames. Keep partial containers closed to prevent contamination. Other Precautions: Use all standard practices for good personal hygiene.

--- IDENTIFIERS -Chemical Name and Synonyms: POLYBUTENE POLYMER,

(C,H&,

Trade Name and Synonyms: Indopol H-300 ChemicalFamily: Polybutene Manufacturer: AmocoChemicals Co., Chicago, Illinois

--INGREDIENTS AND COMPOSITION DATA -Cas No.

Material Polybutene

%

9003-29-6

--- PHYSICAL DATA -BoilingPoint (“F): NA SpecificGravity (H,O = 1): VaporPressure(mmHg):

NA

Percent Volatile by Volume (%): NA VaporDensity(air = 1): NA

TLV No exposure limit established

64

Chapter 2

EvaporationRate:

NA

Solubility in Water: Negligible, below 0.1 % Viscosity: 635 to 690 cSt at 210°F (99°C) PourPoint: 35°F(1.7"C) Appearance/Color/Odor: Clear, bright liquid.

--FIRE AND EXPLOSION HAZARDS -FlashPoint: 356"F, (185OC)ASTM D93; FlammabilityLimits: Unknown ExtinguishingMedia: Agentsapproved for Class B hazards (e.g., dry chemical, carbon dioxide, halogenated agents, foam steam) or water fog. SpecialFireFightingProcedures: Firefighters shouldwear self-contained breathing apparatus and protective clothing when fighting fires involving chemicals. Unusual Fire and Explosion Hazards:

None reported

HEALTH HAZARD DATA

--

Effects of Overexposure: None reported by manufacturer. Emergency Response and First Aid: Skin: No effects reported under normal conditions of use. No first aid data reported bymanufacturer.A similar product has apercutaneousLD50 greater than 10.25 g k g (rabbits). Eyes: No significant irritation reported. Flusheyeswith plenty ofwater should discomfort occur. A similar product produced an irritation score of 20.0/110.0 with complete disappearance of effects in 72 hr (rabbits). Inhalufion: No effects expected under normal conditions of use. No specific first aid requirements. No special protection required. Inhalation of a similar product for 4 hr at 17 mg/l producedno deaths or untowardbehavioral reactions in rats. Ingestion: This material is expected to berelatively nontoxic. No special first aid required. A similar producthasan oral LD50 greater than34.6 g k g

Synthetic Monomers of

65

(rats). A two-year rat and dog toxicity feeding study and a three-generation reproduction study with rats were conducted on polybutene and revealed no untoward effects due to feeding of polybutene in any of the test animals.

No component of this product is identified as a carcinogen by NTP, IARC or OSHA.

--REACTIVITY DATA -Stability and Conditionsto Avoid: Material is stable. No dangerous reactions are reported by the manufacturer. Materials to Avoid (Incompatibility): None reported by the manufacturer. Hazard Decomposition Products: Polymerization will not occur. Incomplete burning can produce carbon monoxide, carbon dioxide, and other harmful products. HazardousPolymerization: Willnotoccur. Conditions to Avoid: None reported by the manufacturer.

--SPILL AND EMERGENCY RESPONSE -For Spills: Remove mechanically or contain on an absorbent material. as an oil spill.

Treat

Waste Disposal Method: Disposal must be in accordance with federal, state, andlocalregulations.Determinewasteclassificationattimeof disposal. Conditions to use may render the spent productas hazardous waste. Enclosed controlled incineration is recommended unless directed otherwise by applicable ordinances. Empty Containers: The containerfor this product can presentexplosion or fire hazards,evenwhenemptied. To avoidthe risk of injury, do not cut, puncture, or weld on or near this container.

--- SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection: Nonerecommended by manufacturer. Type of Ventilation Required: General mechanical.

Chapter 2

66

EyeProtectionRequirements:

Safety goggles.

Protective Gloves and Other: None recommended by manufacturer. Storage and Handling Precautions:Store in cool, dry location away from all sources of heat, spark, and open flames. Keep partial containers closed to prevent contamination. Other Precautions: Use all standard practices for good personal hygiene.

--- REGULATORY INFORMATION --OSHA HazardCommunicationStandard: 1910.1200 (d).

DOT Proper Shipping Name (Bulk, Land):

Nothazardousper

29 CFR

Not regulated.

Miscellaneous: Various grades of this product meet FDA and USDA regulations. Information concerning compliance with a specific FDA regulation or USDA approval can be obtained directly from the manufacturer.

VULCANIZING AGENTS Vulcanization is a chemical reaction between rubber and a functional group, usually brought about by heat. The result is a product that is stronger, more elastic, more resilient, and less sensitive to temperature changes and the action of solvents than the original polymer. The first accelerators usedwere inorganic basic materials. They included basic lead carbonate, lime, magnesia, and litharge. Inorganic accelerators remained the most important typefor many years. Today they have largely been superseded by organic accelerators because the latter are more powerful and produce vulcanizates of much greater strength and higher quality and durability. Organic accelerators are most effective when combined with zinc oxide. The chemicals listed in this section are organized alphabetically by chemical family name. The following is a list of these chemicals along with trade names and manufacturer’s names. ChemicalFamily - Alkaline Earth Oxides Chemicals - Magnesium Oxide and Zinc Oxide Trade names - Liquispers MBZ Manufacturer - Basic Chemical Division, Basic Incorporated ChemicalFamily - Aliphatic Amines Chemicals - Hexamethylene Diamine Trade names - Numerous Manufacturers - Numerous ChemicalFamily - MetalOxides Chemicals - Proprietary Trade names - Maglite D and K Manufacturer - Merck & Co., Inc.

67

Chapter 3 ChemicalFamily - OrganicPeroxide Chemicals - t-Butyl Perbenzoate, Dicumyl Peroxide, Calcium Carbonate, Silica, &Butyl Peroxymaleic Acid, f-Butylperoxy Valerate Trade names - t-Butyl Perbenzoate, Di-Cup R, Di-Cup 40C, DiCup 4OKE, Luperco 130-XL, LupercoIol-XL, Luperox PMA, Luperco 230-XL Manufacturers - Pennwalt Corp., Hercules, Inc. ChemicalFamily - NonmetalsandSulfenamides Chemicals - Sulfur, N-Oxydiethylenebenthiazole-2-Sulfenamide, Insoluble Sulfur Oil treated Trade names - Amax, Crystex Manufacturers - R. T. Vanderbilt Co., Akzo Corp. ChemicalFamily - Miscellaneous Chemicals - Dibenzoyl p-Quinonedioxime, Hexamethylenediamine Carbamate, n,nY-Dicinnamylidene-1,6-Hexanediamine,Lead Oxides Trade names - Dibenzo GMF, Diak No. 1, Diak No. 3, PolyDispersion Manufacturers - UniroyalChemical, Inc., E. I. Du Pont de Nemours & Co., Wyrough and Loser, Inc., American Cyanamid Co.

--IDENTIFIERS -Name:MAGNESIUM OXIDE Synonyms: Calcined Brucite; Calcined Magnesia; Calcined Magnesite; Granmag;Magcal;Maglite;Magnesia;MagnesiaUSTA;MagnezuTlenek (Polish); Magox; Pericalse; Seawater Magnesia CAS: 1309-48-4; RTECS: OM3850000 Formula: MgO; Mol Wt: 40.31 WLN: M G O ChemicalClass: Metaloxide See other identifiers listed below under Regulations.

Vulcanizing Agents

69

--PROPERTIES PhysicalDescription: White fume Boiling Point: 3855.34 K; 3582.1"C; 6479.9"F Melting Point: 3073.13 K; 2799.9"C;5071.9"F FlashPoint: NA Autoignition: NA Vapor Pressure: About mm UEL: NA LEL: NA Vapor Density: No data Specific Gravity: No data Density: 2.580 Water Solubility: INSOL Incompatibilities: Chlorine trifluoride Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data PolymerizationPossibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100%Odor Detection: No data

- REGULATIONS -DOT hazard class: Not given Packaging exceptions: 173. Nonbulkpackaging: 173. Bulkpackaging: 173. STCC Number: Notlisted Clean Water Act Sect. 307: No Clean Water Act Sect. 311: No Clean Air Act:Notlisted EPA WasteNumber: None CERCLA Ref: Notlisted

Chapter 3 RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: adverse effect to target organs. U.S. Postal Service Mailability: Not given

NFF'A Codes: HealthHazard(blue): Unspecified Flammability(red): Unspecified Reactivity(yellow): Unspecified Special: Unspecified

--TOXICITY DATA -Short-termToxicity: Metalfume fever, irritation ofeyesand nose, flulike symptoms: fever, cough,chest pains, muscleweakness, nausea, vomiting, leucocytosis. Long-termToxicity: TargetOrgans:

Unknown

Respiratorysystem, lungs, eyes

Symptoms: Irritated eyes, nose: flulike fever, cough, chest pain (metal fume fever). (Source: NIOSH) Conc IDLH Unknown ACGM TLV: TLV = 10 mg/m3 fume, as Mg ACGIH STEL Fume,asMg

OSHA PEL Transitional Limits: PEL = total dust15mg/m3; Final Rule mg/m3. Limits: TWA = total dust MAK Information: 6 calculated as fine dust, mg/m3 Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; M A K Not listed; NZOSH Not listed; M P : Not listed; ACGZH Not Listed; OSHA: Not listed. HumanToxicity Data: (Source:NIOSHRTECS) * ihl-hmn TCLo:400 mg/m3 38MKAJ 2A, 1745, 81

Vulcanizing

71

LD50 Value: No LD50 in RTECS 1992 Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

This chemical has no known

--- PROTECTION AND FIRST AID --Recommended Respiration Protection Source:NIOSH Pocket Guide(85-1 14) ACGIH (Magnesium Oxide) I 0 0 mg/m3: Any dust, mist, and fume respirator with a full facepiece. Any supplied-air respirator. Anyself-contained breathing apparatus. 250 mg/m3: Any supplied-air respirator operated in a continuous-flow mode. Any powered air-purifying respirator with a dust, mist, and fume filter. 500 mg/m3: Any air-purifying full facepiece respirator with a high-efficiency particulate filter. Any self-containedbreathing apparatus with afull facepiece. Any supplied-air respirator with a full facepiece. Any powered air-purifying respirator with atight-fitting facepiece and a high-efficiency particulate filter. Substance reported to causeeye irritation or damage; may require eye protection. 7500 mg/m’: Any supplied-air respirator with a full facepiece and operated in a pressure-demand or other positive-pressure mode. Emergency or Planned Entry in Unknown Concentrations or IDLH Conditions: Any self-contained breathing apparatus with a full facepiece and operated in pressure-demand a or other positive-pressure mode. Any supplied-air respirator with a full facepiece and operated in a pressure-demand or other positive-pressure modeincombinationwithan auxiliary self-contained breathing apparatus operated in a pressure-demand or other positive-pressure mode. Escape: Any air-purifying full facepiece respirator witha high-efficiency particulate filter. Any appropriate escape-type self-contained breathing apparatus. FirstAidSource: NIOSH Inhalation: Artificial Respiration Ingestion: Nonegiven Skin: Nonegiven Eyes: Nonegiven

--

INITIAL INCIDENT RESPONSE

No DOT Guide Information for this compound.

---

72

Chapter 3

- IDENTIFIERS Name: ZINC OXIDE Synonyms: Flowers of Zinc; Philosopher’s Wool; Zinc White; Chinese White; Zinc Oxide Fume CAS: 1314-132; RTECS: ZH4810000 Formula: OZn; Mol Wt: 81.37 WLN: Z N O Chemical Class: Metal oxide See other identifiers listed below under Regulations.

--- PROPERTIES -Physical Description: Odorless, white or yellow powder BoilingPoint: NA MeltingPoint: B2073.15 K FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density5.47 (air = 1) SpecificGravity: No data Water Solubility: INSOL Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities:No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: data 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: Not given Packaging exceptions: 173. Nonbulkpackaging: 173. Bulk packaging: 173.

Vulcanizing Agents STCC Number: Not listed Clean Water Act Yes Clean Water Act No Clean Air Act:Not listed EPA Waste Number: None CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant. Acute toxicity: adverse effect to target organs. Chronic toxicity: reproductive toxin. Yes Listed in SARA De Minimus Concentration: 1.O% U.S. Postal Service Mailability:

Not given

NFPA Codes: Health Hazard (blue): Unspecified Flammability (red): Unspecified Reactivity (yellow):Unspecified Special: Unspecified

--- TOXICITY DATA --Short-term Toxicity: Unknown Long-term Toxicity: Unknown Target Organs: Skin, eye, respiratory system,lungs Symptoms: May cause metal fume fever with chills, fever, tightness in chest, cough, and leukocytes; metallic taste in mouth, pains in muscles and joints, marked thirst, occasionally bronchitis or pneumonia, cyanosis. (Source: MI, SAX; THIC) Conc IDLH Unknown N O S H REL: 5 mg/m3 time-weighted averages for 8-hr exposure; 15 mg/m3 ceiling exposures, which shall at no time be exceeded.

74

Chapter 3

ACGIH TLV: TLV = fume, 5 mg/m3; dust, 10 mg/m3; total dust containing no asbestos and less than 1%crystalline silica ACGIH STEL: STEL = Fume, 10 mg/m3> >total dust containing no asbestos OSHA PEL: TransitionalLimits: PEL = total dust 15 mg/m3; respirable fraction 5 mg/m3; Final Rule Limits: TWA = total dust mg/m3; respirable fraction 5 mg/m3. MAK Information: 5 calculated as fine dust mg/m3; Substance with systematic effects, onset of effect over 2 hr: Peak = lOxMAK for 30 min, once per shift of 8 hr. Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; M A E Not listed; NZOSH Not listed; N T P Not listed; ACGZP. Not listed; OSHA: Not listed. HumanToxicityData: (Source: NIOSH RTECS) * orl-hmn LDLo:500 mg/kg YAKUD5 22, 291, 80 LD50Value:

NoLD50inRTECS1992

OtherSpeciesToxicityData: orl-rat LD :> 8437 mg/kg ipr-rat LD50:240 mg/kg orl-mus LD50:7950 mgkg ihl-mus LC50:2500 mg/m3 ReproductiveToxicity reproductive toxin.

(Source: NIOSH RTECS1992)

(1992 RTECS):

Thischemical

is a mammalian

Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo:6846 mg/kg (1-22D preg) JONUAI 98, 303, 69 Specific Developmental Abnormalities Homeostasis Effects on Newborn Stillbirth Growth statistics (e.g., reduced weight gain)

Vulcanizing Agents

--

75

PROTECTION AND FIRST AID

---

Recommended Respiration Protection Source: NIOSH Pocket Guide (85-1 14) NIOSH(ZincOxide) 50 mg/td: Any dust, mist, and fume respirator with a full facepiece. Any supplied-air respirator. Anyself-contained breathing apparatus. 125 mg/m3: Any powered air-purifying respirator with a dust, mist, and fume filter. Any supplied-air respirator operated in a continuous-flow mode. 250 mg/td: Any air-purifying full facepiece respirator with a high-efficiency particulate filter. Anypowered air-purifying respirator witha tight-fitting facepiece and a high-efficiencyparticulate filter. Any self-containedbreathing apparatus witha full facepiece.Any supplied-air respirator witha full facepiece. Any supplied-air respirator with a tight-fitting facepiece operated in a continuous-flow mode. 2500 mg/m3: Any supplied-air respirator with a half-mask and operated in a pressure-demand or other positive-pressure mode. Emergency or Planned Entry inUnknown Concentrationsor IDLH Conditions: Any self-contained breathing apparatus with a full facepiece and operated in pressure-demand a or other positive-pressure mode. Any supplied-air respirator with a full facepiece and operated in a pressure-demand or other an auxiliary self-contained positive-pressure modeincombinationwith breathing apparatus operated in apressuredemand or other positive-pressure mode. Escape: Any air-purifying full facepiece respirator witha high-efficiency particulate filter. Any appropriate escape-type self-contained breathing apparatus.

--INTTlAL INCIDENT RESPONSE --No DOT Guide information for this compound.

- IDENTIFIERS -Name:HEXAMETHYLENE DIAMINE Synonyms: 1,6-Hexanediamine;1,6-Diaminohexane;Hexamethylenediamine; 1,6-Hexamethylenediamine; HMDA CAS: 124-09-4; RTECS: M01 180000 Formula: C6H&2; MO1 wt: 116.24 WLN: 2 6 2

76

Chapter 3

Chemical Class: Aliphatic amine

See other identifiers listed below under Regulations.

--PROPERTIES Physical Description: Colorless solid or watery liquid with a weak ammonia odor Boiling Point: 478 K, 204.8"C; 400.7"F Melting Point: 315.15 K; 42°C;104°F Flash Point: 354 K; 80.8"C; 177.5OF Autoignition: NA UEL: NA LEL: NA Vapor Density: Nodata SpecificGravity:0.799 60°C Density: 0.799 g/cc or 7.4307 lb/gal Water Solubility: Freely soluble Reactivity with Water: No data on water reactivity Reactivity with Common Materials: Absorbs moisture and carbonic acid gas in air; corrosive, can react with oxidizing materials (Source: SAX); this can reactwith oxidizing materials(Source: SAQXX) Stability during Transport: Nodata Neutralizing Agents: Flush withwater Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): 0.0041 Odor Description: Weak,fishy(Source:CHRIS) 100% Odor Detection: .0032 mg/m3 ppm

--REGULATIONS -DOT hazard class: 8 CORROSIVE DOT guide: Identificationnumber: UN2280 DOT shipping name: Hexamethylenediamine,solid Packinggroup: I11 Label(s)required: CORROSIVE Packaging exceptions: 173.154 Nonbulkpackaging: 173.213 Bulk packaging: 173.242

77

Vulcanizing Agents

Quantity limitations: Passenger airhail: 25 kg Cargo aircraft only: 100 kg Vesselstowage: Other stowage provisions: 12, 48 STCCNumber:4935640 CleanWaterAct No Clean Water Act Sect. 311: No Clean Air Act: Notlisted EPA WasteNumber: None CERCLA Ref: Not listed RQDesignation: Notlisted SARATPQValue: Not listed SARA Sect. 312 Categories: Acutetoxicity: corrosive. Chronic toxicity: reproductive toxin. U.S. Postal Service Mailability: Hazardclass: Corrosive material - mailable as ORM-D Mailability: Domestic service and air transportation shipper’s declaration Max per parcel: 25 lb 15% mixture

NFPA Codes: HealthHazard(blue): Unspecified Flammability (red): Unspecified Reactivity(yellow): Unspecified Special: Unspecified

--TOXICITY DATA -Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

TargetOrgans: Skin, eyes, mucousmembranes Symptoms: Vaporscause irritation ofeyesandrespiratory tract. Liquid irritates eyesand skin, may cause dermatitis; edema, hepatitis. (Source: THIC)

78

Chapter

Conc IDLH Unknown

NIOSH REL: Notgiven ACGIH TLV: Not listed ACGIH S T E L Not listed WEEL(ACGIH): 5 mg/m3 (8-hr TWA) OSHA PEL: Not in Table Z-l-A MAK Information: Not listed

Carcinogen: N; Status: Seebelow CarcinogenLists: ZARC Not listed; MAK: Not listed; NZOSH Not listed; NTP: Not listed; ACGZH Not listed; OSHA: Not listed. LDS0 Value: orl-rat LD50:750 mg/kg

OtherSpeciesToxicityData: (Source:NIOSHRTECS1992) orl-rat LD50:750 mg/kg mg/m3/4H ihl-rat LC : ihl-mus LCLo:750 mg/m3/10M ipr-mus LD50:320 mg/kg scu-mus LD50: 1300 mg/kg ivn-mus LD50: 180 mg/kg skn-rbt LD50: 11 mg/kg ReproductiveToxicity(1992RTECS): reproductive toxin.

Thischemical

is amammalian

Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo:3 g/kg (6-15D preg) JJATDK 7, 259, 87 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Specific Developmental Abnormalities Hepatobilinary system orl-rat TDLo:1840 mg/kg (6-15D preg) JJATDK 7, 259, 87 Specific DevelopmentalAbnormalities Urogenital system

79

Vulcanizing Agents orl-rat TDLo:77 g k g (multigeneration) FAATDF 16, 490, 91 Effects on Newborn Growth statistics (e.g., reduced weight gain) orl-rat TDLo:66500 mg/kg (multigeneration) FAATDF 16, 490, 91 Effects on Fertility Litter size (number of fetuses per litter; measured before birth)

--- PROTECTION AND FIRST AID --motection Suggestedfromthe protection.

CHRIS Manual: Protective clothing; eye

First Aid Source: DOT Emergency Response Guide 1993. Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min.Removeand isolate contaminated clothing andshoesat the site. Keep victim quiet and maintain normal body temperature.

--

INITIAL INCIDENT RESPONSE

---

U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOTShippingName: Hexamethylenediamine, solid DOT ID Number: UN2280 ERG90

* POTENTIAL HAZARDS *

GUIDE 60

*Health Hazards Contact causes bums to skin and eyes. If inhaled, may be harmful. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Some of these materials may bum, but none of them ignites readily. Flammable/poisonous gases may accumulate in tanks and hopper cars. Some of these materials may ignite combustibles (wood, paper, oil, etc.).

Chapter 3

80

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressureself-containedbreathingapparatus(SCBA)and structural firefighters' protective clothing will provide limited protection.

CALLCHEMTRECAT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities. *Fire Some of these materials may react violently with water. Smallfires: Dry chemical, COz, water spray, or regular foam. Largefires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks.

*Spill or Leak Do not touch spilled material; stop leak if you do it without risk. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small dry spills: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal.

*First Aid Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

- IDENTIFIERS Name:TERT-BUTYLPEROXYBENZOATE Synonyms: &Butyl Perbenzoate; Tert-Butylperbenzoan (Czech); r-Butyl Peroxy Benzoate; Perbenzoate De Butyle Tertiaire (French) CAS:614-45-9; RTECS:SD450000 Formula: CIIH,,O3 ; Mol Wt: 194.23

Vulcanizing Agents

81

Chemical Class: Organicperoxide See other identifiers listed below under Regulations.

--PROPERTIES -Physical Description: Colorless to slightly yellow liquid Boiling Point: -349.16 K at 0.2 mm; 75 to 76°C at 0.2 mm; 1683°F at

mm Melting Point: 281.15 K; 8°C;46.4"F Flash Point: 360.92 K; 87.7"C;189.9"F Autoignition: 366.15 K;93°C;199.4"F Vapor Pressure: 0.33 mm hG at 50°C UEL: NA LEL: NA Vapor Density: No data SpecificGravity: 1.0 Density: 1.02 g/ml Water Solubility: INSOL Reactivity with Water: No data on water reactivity ReactivitywithCommonMaterials: Organicmatter (Source: SAX) Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: Aromaticodor C S D S (Source:Unspecified) 100%Odor Detection: No data

- REGULATIONS -DOT hazard class: 5.2 DOT guide: 48 Identification number: UN3 103 DOT shipping name: ORGANIC PEROXIDE TYPE C, LIQUID Packinggroup: I1 Label(s)required: ORGANICPEROXIDE Packaging exceptions: 173.152 Nonbulkpackaging: 173.225 Bulkpackaging: 173.None

82

Chapter

Quantity limitations: Passenger airhail: 5 L Cargo aircraft only: 10 L Vesselstowage: D Otherstowage provisions: 12,40 STCCNumber:

4919151,4919150,4919149

Clean WaterAct 307: No CleanWaterAct 311: No CleanAirAct: Not listed EPAWasteNumber: None CERCLA Ref: Not listed RQDesignation: Not listed SARA TPQ Value: Not listed SARA Sect. Categories: Acute toxicity: irritant. Acute toxicity: adverse effect to target organs. Chronic toxicity: mutagen. Reactive hazard: organic peroxide.

U.S. Postal Service Mailability: Hazard class: Notgiven Mailability: Nonmailable Maxper parcel: 0

NFPA Codes: HealthHazard(blue): (1) Slightly hazardous to health. Asa precaution, wear self-contained breathing apparatus. Flammability(red): Thismaterialcanbe ignited underalmostall temperature conditions. Reactivity (yellow): (4) Capable ofdetonation or explosive decompositionat normal temperatures. Special: Unspecified.

--TOXICITY DATA -Short-term Toxicity: Unknown

Long-termToxicity:

Unknown

TargetOrgans: Skin, eye irritant

Vulcanizing

Symptoms: Irritation of eyes, nose, and mucous membranes. (Source: CSDS). Conc IDLH Unknown

NIOSH R E L Not given ACGIHTLV: Not listed ACGIHSTEL: Not listed

OSHA PEL: Not in Table Z-l-A

MAK Information: Not listed Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; M A K Not listed; NZOSH Not listed; NTP Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: orl-rat LD50: 1012 mg/kg OtherSpeciesToxicity Data: (Source:NIOSHRTECS1992) orl-rat LD50:1012 mg/kg orl-mus LD50:914 mg/kg Reproductive Toxicity (1992 RTECS): This chemical has malian reproductive toxicity.

known mam-

- PROTECTION AND FIRST AID --First AidSource: DOT Emergency Response Guide 1993. Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

--INITIAL INCIDENT RESPONSE -U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT (1990). DOT ShippingName: OrganicPeroxideType C, Liquid

Chapter

DOT ID Number: UN3103 ERG90

* POTENTIAL H.AZARDS *

GUIDE 48

*Health Hazards Contact causes bums to skin and eyes. Fire may produce imtating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion May be ignited by heat, sparks, and flames. Container may explode in heat of fire. May explode from heat or contamination Runoff to sewer may create fire or explosion hazard.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressureself-containedbreathingapparatus(SCBA)and structural firefighters' protective clothing will provide limited protection. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire . SmaZZfires: Dry chemical, COz, water spray, or regular foam. Large pres: Flood fire area with water. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargoarea, use unmanned hoseholder or monitor nozzles; if this is impossible, withdraw from area and let fire bum. *Spill or Leak Shut off ignition sources; no flares, smoking, or flames in hazard area. Do not touch or walk through spilled material; stop leak if you can do it without risk. Small spills: Takeupwith inert, dampnoncombustiblematerial;move containers from spill area. Large spills: Wet down with water and dike for later disposal.

Vulcanizing Agents

85

*First Aid Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

--IDENTIFIERS -Chemical Name and Synonyms: ORGANIC PEROXIDE MIXTURE Trade Name and Synonyms: Di-Cup R Organic Peroxide ChemicalFamily: OrganicPeroxide Manufacturer: Hercules Inc., Wilmington,Delaware

UN ID Number: 2121

--INGREDIENTS AND COMPOSITION DATA %

No. Cas Material Dicumyl Peroxide [peroxide, (alphabis alphadimethylbenzyl)]

99

* This

TLV established* Not

material is stated by manufacturerasnotbeingexpected to cause physiologicalimpairmentatlowconcentration.Until a specificTLV is adopted by the ACGIH or an OSHA standard is issued, the manufacturer recommendsthattheproduct be treated as a NUISANCEDUST OR PARTICULATE in accordance with the recommendations of the ACGIH.

--PHYSICAL DATA -BoilingPoint (“F): NA SpecificGravity (H,O = VaporPressure(mmHg):

0.004 mmHg at 50°C

86

Chapter

Percent Volatile by Volume (%): Negligible at 20°C VaporDensity(air

= 1): NA

Evaporation Rate: Slower than Butyl Acetate Solubilityin Water: Negligible Appearance/Color/Odor: Yellow, acrid color. Material is a granular solid at room temperature.

- FIRE AND EXPLOSION HAZARDS -FlashPoint: 127°C (260°F)SETA-CC FlammabilityLimits: Unknown Autoignition: NA Extinguishing Media: Water spray, dry chemical, carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. Useself-containedbreathingapparatus. Unusual Fire and Explosion Hazards: Exposure of containers to fire results in rapid product decomposition,containerpressure buildup, and failure, followed by vigorousburningwith flare effect.Cleanupshouldnotbe attempted until all the product has cooled completely. Refer to Reactivity, Incompatibility, and Combustion Data Sections. Hazardous Product of Combustion: Combustion products depend on other materials present in the fire and on fire conditions. In most cases, these will be carbon monoxide and carbon dioxide. Usually, carbondioxide will be the principal combustion product. In some cases, irritating partial combustion products will be formed.

--HEALTH HAZARD DATA -Effects of Overexposure: May cause mild, temporary eye, skin, and respiratory irritation. Decompositionproducts may cause eye,skin, and respiratory irritation and may beskin sensitizers. Decomposition products and

Vulcanizing

87

fumes from vulcanizing and crosslinking operations can cause eye, skin, and respiratory irritation and may be skin sensitizers.

Additional Information on Effects: Slight primary irritation but no evidence of sensitization was seen in a human patch test with DI-CUP T, which is dicumyl peroxide slightly less refined than DI-CUP R. Increased numbers of blood vessels in the nasal septum have been noted in workers exposed to dicumyl peroxide as compared to other groups examined. Emergency Response and First Aid: Skin: Wash thoroughly with soap and running water. Remove contaminated clothing and wash before reuse. Eyes: In case of contact, immediately flush with plenty of low-pressure water for at least 15 min. Remove any contact lenses to ensure thorough flushing. Call a physician. Inhalation: Removevictim to fresh air and, if indicated, give artificial respiration. If breathing is difficult, giveoxygen.Calla physician. Treat immediately. Ingestion: If conscious, the person should immediately drinklarge quantities of liquid to dilute this product. Never give liquids to an unconscious person. Call a physician. Cancer Information: Not listed as a carcinogen by NTP; not carcinogen by OSHA; not evaluated by IARC.

regulated as a

--- TOXICITY DATA -Animal Effects: Rat oral w350: 4100 mg/kg (administered as 20% solution in corn oil). Mild conjunctivitis but no corneal effects were seen in testing of a 50% solution in corn oil. Eyes returned to normal during the next 48 hr. Guineapig sensitization: Not a sensitizer; primary irritation was obtained from repeated intradermal injection of 0.1% solution of DI-CUP R. Acute inhalation study (study conducted with DI-CUP RRat 40°C, another product composedofDI-CUP absorbedontoan inert calciumcarbonate carrier): No noticeable effects in animals exposed at 21 to 224 mg dust/m3 for 6 hr. Noobservable signs of toxicity during the subsequent14-day postexposure period. Other: Dicumylperoxidehasshown negative in the Ames test. Dicumyl peroxide has been reported to cause embryotoxicity (death and/or malformations) in 3day-old chick embryos with an ED50 of 1.5 micromole(s) (weight) Per egg.

88

Chapter 3

--REACTIVITY DATA -StabilityandConditions to Avoid: Stable at room temperatures. Avoid temperaturesabove55°C (131°F) or contact with materials listed below. Highertemperatures or contact with listed materials promoteexothermic decomposition. Materials to Avoid (Incompatibility): Acids and acidic-type materials such as Friedel-Crafts catalysts, strong oxidizing catalysts, copper,copper alloys, lead, and iron. Glass and stainless steel are preferred structural materials for handling this productbecausecorrodedmetalsandacid clays may be catalytically active in causing decomposition of the peroxide. Hazard Decomposition Products:Acetophenone, cumyl alcohol, alpha-methyl styrene, methane,and ethane. Under acidic decomposition conditions, phenols may also be formed. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: If material is not contaminated, scoop it into clean containers for use. If it is contaminated, scoop it into containers for disposal. WasteDisposalMethod: Anacceptablemethodof disposal wouldbe to incinerate after diluting to 5% concentration in No. 2 fuel oil. Use an RCRAapproved incinerator. Do Not attempt to bum product in containers. Do nor mix concentrations or solutions of product with other chemical wastes. Do nor put solutions containing product into sewer systems. Refer to Regulations Section for specific federal environmental and regulatory data regarding use or disposal of this product. Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection:Appropriate respirator selected and usedin accordance with OSHA Subpart I (29 CFR 1910.134) and manufacturer’s recommendations is required if airborne dust is not adequately controlled or if excessive

89

Vulcanizing

fumes are generated from product decomposition. Self-contained breathing apparatus should be worn in high vapor and dust concentrations. dusts Type of Ventilation Required: Generalmechanical.Avoidbreathing and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Impervious gloves andclothing should be worn. Storage and HandlingPrecautions: Store in cool, dry location away from all sources of heat, spark, and open flames. Keep partial containers closed to prevent contamination. Other Precautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Product will bum.

--REGULATORY INFORMATION -SARA TITLE I11 (see footnotes): SEC. 304 Component EHS RQNo.

(1bJ

P 1

NO

SEC.302 EHS TPQ (lb)

SEC.311/312 Hazard Category

NA

HC- 1, HC-3, HC-4, HC-5

NA

NHH

SEC.313 Toxic Chemical (Yes. No) NA

CERCLA (40 CFR 302.4 Hazardous Substance and Reportable Quantities): This product may contain hazardous substances listed under 40 CFR 302.4. However,they will bepresentonlyin trace or residual quantities. Under reasonably anticipated conditions of shipmentor handling, it is highly unlikely that an accidental release would exceed the reportable quantity of the listed chemical.

90

Chapter 3

RCRA Information: This product exhibits the characteristic of reactivity (D003) as defined in hazardous waste regulations 40 CFR 261 Subpart C. Therefore, disposal of unused product must comply with hazardous waste regulations. Other: This product may release phenol upon decomposition, which is listed as a "Toxic Pollutant" under Section307 of the Clean Water Act, and specific discharge limitations on wastewaters containing it may apply. Refer to the Effluent Guidelines for your industry (40 CFR 401 through 469).

Footnotes to Regulatory Data: SEC. 302 - Threshold Planning Quantity, Extremely Hazardous Substance. (EHS) (40 CFR 355 Emergency Planning and Notification Regulations). NA - This chemicalisnotanEHS, Planning Quantity (TPQ).

Therefore, there is noThreshold

SEC. 304 - ReportableQuantityforReleasesofanEHS Appendix A).

(40 CFR 355,

SEC. 3 11/312 - 40 CFR 370 Hazardous Chemical Reporting Requirements. The "hazard categories" are: HC-1Immediate(acute)healthhazard HC-2 Delayed (chronic) health hazard HC-3 Fire hazard HC-4 Sudden release of pressure hazard HC-5 Reactive hazard NHH Not a health hazard NPHNot a physical hazard SEC. 313 - 40 CFR 372 Toxic Chemical Release Reporting Requirements: NO: This component is not subject to the reporting requirements of Section 313 of Title I11 of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 Toxic Chemical Reporting requirements. YES: This component is subject to thereportingrequirements of SecAct tion 3 13 of Title I11 of the Superfund Amendments and Reauthorization of 1986 and 40 CFR Part 372 Toxic Chemical Reporting requirements. Percent composition (or estimated range) is listed above.

Vulcanizing NA: This product is a mixture. As such, it is not listed as a Toxic 40 CFR Section reporting requirements. Chemical under Reportable constituents are listed individually where they exceed threshold concentration limits.

--- IDENTIFIERS -MIXTURE

Chemical Name and Synonyms: ORGANIC PEROXIDE Trade Name and Synonyms: DI-CUP C Organic Peroxide ChemicalFamily: carbonate

Organic Peroxide, supported on precipitatedcalcium

Manufacturer: Hercules Inc., Wilmington,Delaware

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --Material

Cas No.

Peroxide Dicumyl [(peroxide, bis (alpha, alpha-dimethylbenzyl)] carbonate Calcium

%

TLV Not established. mg/m3

Cumene

(skin) 50 ppm

as notbeingexpected to cause 'Thismaterialisstatedbymanufacturer physiological impairment at low concentration. Untila specific TLV is adopted by the ACGIH or an OSHA standard is issued, the manufacturer recommends that the product be treated as a NUISANCE DUST OR PARTICULATE in accordance with the recommendations of the ACGIH. Other Data: Recommended OSHA PEL is: Dicumyl peroxide

PEL not established

92

Chapter Calcium carbonate

PEL is 15 mg/m3

Cumene

PEL is 50 ppm (skin)

Additional Data: 10 ppm [Gage, J.C., British Journalof Industrial Medicine 27~1-18(1970)l

--PHYSICAL DATA -Boiling Point (“F): NA,Decomposes SpecificGravity (H,O = 1): 1.6 VaporPressure(mmHg):

NA

Percent Volatile by Volume (%): Negligible VaporDensity(air = FreezingPoint:

NA

NA

EvaporationRate:

NA

p H NA

Solubilityin Water: Negligible Appearance/Color/Odor: Off-white color.

--- FIRE AND EXPLOSION HAZARDS -FlashPoint:

120°C(248OF) SETA-CC

FlammabilityLimits:

Unknown

Autoignition: NA Extinguishing Media: Water spray, dry chemical, carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. Useself-containedbreathingapparatus.

Vulcanizing

Unusual Fire and Explosion Hazards: Exposure of containers to fire results in rapid productdecomposition, container pressure buildupand failure, followedbyvigorousburningwith flare effect. Cleanupshouldnotbe attempted until all the product has cooled completely. May form flammable dust-air mixtures. HazardousProducts of CombustionandDecomposition: Acetophenone, cumyl alcohol, alpha-methyl styrene, methane,and ethane. Under acidic decomposition conditions, phenols may also be formed. Combustion products often depend on other products present in the fire and on fire conditions. In most cases, these will becarbonmonoxideandcarbon dioxide. Usually, carbondioxide will be the principal combustion product. In some cases, irritating partial combustion products will be formed. Hazardous Polymerization: Will not occur.

--HEALTH HAZARD DATA -Effects of Overexposure: May cause mild, temporary eye, skin, and respiratory irritation. Decompositionproducts may cause eye, skin, and respiratory irritation and may beskin sensitizers. Decomposition products and fumes from vulcanizing and crosslinking operations can cause eye, skin, and respiratory irritation and may be skin sensitizers. Additional Information on Effects: Slight primary irritation, but no evidence of sensitization was seen in a human patch test with DI-CUP T, which is dicumyl peroxide slightly less refined than DI-CUP R. Increased numbers of blood vessels in the nasal septum have been noted in workers exposed to dicumyl peroxide as compared to other groups examined. Overexposure to cumene will cause irritation of the eyes, skin, andmucousmembranes. Headache, dizziness, slight incoordination, narcosis, and coma may also be seen. It causes irritation when inhaled at 200 ppm. Emergency Response and First Aid: Skin: Wash thoroughly with soap and running water. Remove contaminated clothing and wash before reuse. Eyes: In case of contact, immediately flush with plenty oflow-pressure water for at least 15 min.Removeany contact lenses to ensurethorough flushing. Call a physician. Inhalation: Removevictim to fresh air and, if indicated, give artificial respiration. If breathing is difficult, giveoxygen.Calla physician. Treat immediately.

94

Chapter 3

Ingestion: If conscious, the person should immediately drinklarge quantities of liquid to dilute this product. Never give liquids to anunconscious person. Calla physician. Cancer Information: Not listed as a carcinogen by NTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

- TOXICITY DATA --Animal Effects: Rat oral LD50 (studies conducted with active ingredient, DICUP T oil, 4100 mg/kg administered as 20% solution in corn). The oral LD50 of cumene was 1400 mg/kg. Rabbit eye irritation: Mild conjunctivitis but no corneal effects were seen in testing of a 50% solution of DI-CUP T in corn oil. Eyes returned to normal during the next 48 hr. Cumene was the irritant. Guinea pig sensitization: Not a sensitizer. No primary irritation was obtained from repeated intradermal injection of 0.1 % solution of DI-CUP T. Ratandrabbit: Acute inhalation study: No noticeable effects in animals exposed at 21 to 224 mg dust/m3 for 6 hr. No observable signs of toxicity during the subsequent 14-day postexposure period. Other: Dicumylperoxidehasshown negative in the Ames test. Dicumyl peroxide has been reported to cause embryotoxicity (death and/or malformations) in 3day-old chick embryos withan ED50 of 1.2 micromole(s) (weight) Per egg.

--REACTIVITY DATA -StabilityandConditions to Avoid: Stable atroom temperatures. Avoid temperaturesabove 55OC (131°F) or contact with materials listed below. Highertemperatures or contactwith listed materials promoteexothermic decomposition. Static chargesgeneratedbyemptyingpackage in or near flammable vapors may cause flash fire. Dust may form flammable dust-air mixture. Materials to Avoid (Incompatibility): Acids and acidic-type materials such as Friedel-Crafts catalysts, strong oxidizing catalysts, copper,copper alloys, lead, and iron. Glass and stainless steel are preferred structural materials for

Vulcanizing

95

handling this productbecausecorrodedmetalsandacid clays may be catalytically active in causing decomposition of the peroxide.

Hazard Decomposition Products:Acetophenone, cumylalcohol, alpha-methyl styrene, methane,and ethane. Under acidic decomposition conditions, phenols may also be formed. Hazardous Polymerization: Will not occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: If material is not contaminated, scoop it into clean containers for use. If it is contaminated, scoop it into containers for disposal. WasteDisposalMethod: Anacceptablemethodof disposal would beto incinerate after diluting to 4% concentration in No. 2 fuel oil. Use an RCRAapproved incinerator. Do not attempt to bum product in containers. Do not mix concentrations or solutions of product with other chemical wastes. Do not put solutions containing product into sewer systems. Refer to Regulations Section for specific federal environmental and regulatory data regarding use or disposal of this product. Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. avoid the risk of injury,do not cut, puncture, or weld or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS Respiratory Protection: Appropriate respirator selected and usedin accordance with OSHA Subpart I CFR 1910.134) and manufacturer’s recommendations is required if airborne dust is not adequately controlled or if excessive fumes are generated from product decomposition. Self-contained breathing apparatus should be worn in high vapor and dust concentrations. Type of VentilationRequired: Generalmechanical.Avoidbreathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible.

96

Chapter 3

Protective Gloves and Other:Impervious gloves andclothing should be worn. Storage and Handling Precautions: Store in cool, dry location away from all sources of heat, spark, andopen flames. Avoid ignition sourcessuch as sparks and flames. Ground all equipment. In addition, when emptying bags where flammable vaporsmay be present, blanket vessel withinert gas, ground operator, and pour material slowly into conductive, grounded chute. Store below 35°C (95°F) in original containers in a ventilated area out of direct sunlight and away from heat sources. Storage at higher temperatures risks melting of the products organic peroxide and the information of lumps and cakes. This material may react with acids and acid-like materials, strong oxidizing and reducingagents, oxidation catalysts, copper, copper alloys, lead, and iron and should not be stored near such materials.

OtherPrecautions: Useall standard practices for goodpersonalhygiene. Completely isolate and thoroughly clean all equipment, piping, or vessels before beginning maintenance or repairs. Keep area clean. REGULATORY INFORMATION -SARA TITLE 111 (see footnotes): Toxic SEC.313 SEC.302 304 Component No.

SEC. EHS RQ (lb)

EHS TPQ (lb)

SEC.311/312 Hazard Category

P

NA

NA

HC-l, HC-3, HC-4

1

HC-1 NA

NA

NO

2

HC-l NA

NA

NO

3

HC-

NA

1

Chemical (Yes, No) NA

YES

CERCLA (40 CFR 302.4 Hazardous Substance and Reportable Quantities): This product may contain hazardous substances listed under 40 CFR 302.4. However, they will bepresentonly in trace or residual quantities. Under reasonably anticipated conditions of shipmentor handling, it is highly unlikely

Vulcanizing

97

that an accidental release would exceed the reportable quantity of the listed chemical.

RCRA Information: Thisproductisnot

listed in federal hazardouswaste regulation 40 CFR 261.33, paragraph (e) or i.e., chemical products that are considered hazardous if they become wastes. It does not exhibit any of the hazardous characteristics listed in 40 CFR 261, Subpart C. State or local hazardous waste regulations may apply if they are different from the federal regulation.

Other: This product may release phenol upon decomposition, which is listed as a "Toxic Pollutant" under Section 307 ofthe Clean Water Act, and specific discharge limitations on wastewaters containing it may apply. Refer the Effluent Guidelines for your industry (40 CFR 401 through 469). Footnotes to Regulatory Data: SEC. 302 - Threshold Planning Quantity, Extremely Hazardous Substance. (EHS) (40 CFR 355 Emergency Planning and Notification Regulations). NA - Thischemical is notanEHS. Planning Quantity (TPQ). SEC.304 - ReportableQuantity Appendix A).

Therefore, there isnoThreshold for ReleasesofanEHS

(40 CFR 355,

SEC. 31 V312 - 40 CFR 370 Hazardous Chemical Reporting Requirements. The"hazard categories" are: HC-1Immediate(acute) health hazard HC-2 Delayed (chronic) health hazard HC-3 Fire hazard HC-4 Sudden release of pressure hazard HC-5Reactivehazard NHH Not a health hazard NPH Not a physical hazard SEC. 313 - 40 CFR 372 Toxic Chemical Release Reporting Requirements: NO: Thiscomponent is nof subject to the reporting requirementsof Section 313 of Title I11 of the Superfund Amendments and Reauthorization Act of 1986 and40 CFR Part 372 Toxic Chemical Reportingrequirements.

98

Chapter 3

YES: This component is subject to the reportingrequirementsofSection 3 13 of Title I11 the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 Toxic Chemical Reporting requirements. Percent composition (or estimated range) is listed above. This product is a mixture. As such,itisnotlistedas a Toxic Chemical under 40 CFR 372, Section 313 reportingrequirements. Reportable constituents are listed individually where they exceed threshold concentration limits.

--IDENTIFIERS Chemical Name and Synonyms: ORGANIC PEROXIDE Trade Name and Synonyms: DI-CUP 40 kE Organic Peroxide Chemical Family: Organic Peroxide, supported on a carrier silane modified clay. Manufacturer: Hercules,Inc.,Wilmington,Delaware UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --TLV Material Cas No. % 80-43-3 peroxide Dicumyl [(peroxide, bis (alpha, alpha-dimethylbenzyl)]

38.8

Not established*

mg/m3 64402-68-41 10 modified Silane clay 60 1067-53-4 98-82-8Cumene

1.2 (skin)

ppm

*Thismaterial is stated by manufacturerasnotbeingexpected to cause physiological impairment at low concentration. Untila specific TLV is adopted by the ACGIH or an OSHA standard is issued, the manufacturer recommends

Vulcanizing

99

that the product be treated as a NUISANCE DUST OR PARTICULATE in accordance with the recommendations of the ACGIH.

Other Data: Recommended OSHA PEL is: Dicumyl peroxide

PEL not established

Silane modified clay

PEL is 15 mg/m3

Cumene

PEL is 50 ppm (skin)

Additional Data: 10 ppm [Gage, J.C., British Journal of Industrial Medicine (1970)l

--

PHYSICAL DATA

---

Boiling Point (“F):NA, Decomposes SpecificGravity (H,O = 1): 1.6 VaporPressure (mm Hg): NA Percent Volatile by Weight VaporDensity(air FreezingPoint:

(%): Negligible

= 1): NA

NA

EvaporationRate: NA pH: NA Solubilityin Water: Negligible Melting Point:

to 35°C (86 to 95°F) (peroxide only)

Appearance/Color/Odor: Off-white color.

- FIRE AND EXPLOSION HAZARDS -FlashPoint:

(260°F)SETA-CC

100

FlammabilityLimits:

Chapter Unknown

AutoignitionTemperature:

NA

Extinguishing Media: Water spray, dry chemical, carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. Useself-containedbreathingapparatus. Unusual Fire and Explosion Hazards: Exposure of containers to fire results inrapidproductdecomposition,containerpressurebuildupand failure, followed by vigorous burning with flare effect. Cleanupshouldnot be attempted until all the product has cooled completely. May form flammable dust-air mixtures. HazardousProducts of CombustionandDecomposition: Acetophenone, cumyl alcohol, alpha-methyl styrene, methane,andethane.Under acidic decomposition conditions, phenols may be formed. Combustion products often depend on other products present in the fire and on fire conditions. In most cases, these will be carbonmonoxideandcarbon dioxide. Usually, carbondioxidewill be theprincipalcombustionproduct. Insomecases, irritating partial combustion products will be formed. Hazardous Polymerization: Will not occur.

- HEALTH HAZARD DATA -Effects of Overexposure: Overexposure can cause mild eye and skin irritation. Inhalation particulate clay dusts of silane modified clay have caused a low prevalence of pulmonary fibrosis in miners. Decomposition products and fumes from vulcanizing and crosslinking operations can cause eye, skin, and respiratory irritation andmay be skin sensitizers. Overexposure to cumene willcause irritation to eyes, skin, andmucousmembranes.Headache, dizziness, slight incoordination, narcosis, and coma may also occur. Dermatitis may result from prolonged or repeated contact. It causes irritation when inhaled at 200 ppm. Emergency Response and First Aid: Skin: Wash thoroughly with soap and running water. Remove contaminated clothing and wash before reuse.

Vulcanizing

Eyes: In case of contact, immediately flush with plenty oflow-pressure water for atleast 15 min.Removeany contact lenses to ensurethorough flushing. Call a physician. Inhalation: Removevictim to fresh air and, if indicated, give artificial respiration. If breathing is difficult, giveoxygen. Call a physician. Treat immediately. Ingestion: If conscious, the person should immediatelydrink large quantities of liquid to dilute this product. Never give liquids to an unconscious person. Call a physician. Cancer Information: Not listed as a carcinogen byNTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--

TOXICITY DATA

--

Animal Effects: Rat oral LD50 (studies conducted with active ingredient, DICUP T oil, 4100 mgkg administered as 20% solution in corn oil). The oral LD50 of cumene was 1400 mg/kg. Rabbit eye initatidn: Mild conjunctivitis but no corneal effects were seen in testing of a 50% solution of DI-CUP T in corn oil. Eyes returned to normal during the next 48 hr. Cumene was the irritant. Guinea pig sensitization: Not a sensitizer. No primary imtation was obtained from repeated intradermal injection of 0.1 % solution of DI-CUP T. Ratandrabbit: Acute inhalation study: No noticeable effects in animals exposed at 21 to 224 mg dust/m3 for 6 hr. No observable signs of toxicity during the subsequent 14-day postexposure period. Other: Dicumylperoxidehasshown negative in the Ames test. Dicumyl peroxide has been reported to cause embryotoxicity (death and/or malformations) in 3day-old chick embryos with an ED50 1.2 of micromole(s) (weight) Per egg.

--

REACTIVITY DATA

--

StabilityandConditions to Avoid: Stable at room temperatures. Avoid temperaturesabove55°C(131°F) or contact with materials listed below. Highertemperatures or contact with listed materials promoteexothermic decomposition. Static chargesgeneratedbyemptyingpackage in or near

102

Chapter

flammable vapors may cause flash fire. Dust may form flammable dust& mixture.

Materials to Avoid (Incompatibility): Acids and acidic-type materials such as Friedel-Crafts catalysts, strong oxidizing catalysts, copper,copper alloys, lead, and iron. Glass and stainless steel are preferred structural materials for handling this productbecausecorrodedmetalsandacid clays may be catalytically active in causing decomposition of the peroxide. Hazard Decomposition Products:Acetophenone, cumylalcohol, alpha-methyl styrene, methane,and ethane. Under acidic decomposition conditions, phenols may also be formed. HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE --For Spills: If material is not contaminated, scoop it into clean containers for use. If it is contaminated, scoop it into containers for disposal. WasteDisposalMethod: acceptablemethodof disposal would beto incinerate after diluting to 5% concentration in No. 2 fuel oil. Use an RCRAapproved incinerator. Do not attempt to bum product in containers. Do nor mix concentrations or solutions of product with other chemical wastes. Do not put solutions containing product into sewer systems. Refer to Regulations Section for specific federal environmental and regulatory data regarding use or disposal of this product. Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection:Appropriate respirator selected and usedin accordance with Subpart 1(29 CFR 1910.134) and manufacturer’s recommendations is required if airborne dust is not adequately controlled or if excessive fumes are generated from product decomposition. Self-contained breathing apparatus should be worn in high vapor and dust concentrations. Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust

O

Vulcanizing

103

concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations.

EyeProtectionRequirement: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves andOther: Impervious gloves andclothing should beworn. Storage and Handling Precautions:Store in cool, dry location away from all sources of heat, spark, andopen flames. Avoid ignition sourcessuch as sparks and flames. Ground all equipment. In addition, when emptying bags where flammable vapors may be present, blanket vessel withinert gas, ground operator, and pour material slowly into conductive, grounded chute. Store below 35°C (95°F) in original containers in a ventilated area out of direct sunlight and away from heat sources. Storage at higher temperatures risks melting of the products organic peroxide and the information of lumps and cakes. This material may react with acids and acid-like materials, strong oxidizing and reducingagents, oxidation catalysts, copper, copper alloys, lead, and iron and should not be stored near such materials. Other Precautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughlyclean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Note that this product will bum.

--REGULATORY INFORMATION --SARA TITLE I11 (see footnotes): 3 SEC.302 SEC.304SEC. EHS Component No. RQ (lbl NA

P 1 2

EHS TPQ (lb)

SEC.3111312 Hazard CatePory

NA

HC- 1, HC-3, HC-4

NO NA HC-1

NA

NA

HC-1

13 Toxic Chemical (Yes. No) NA

Chapter 3

104

ToxicSEC.313 SEC.302 304 Component No. YES

3

SEC. EHS RO (lb) HC-1

EHS TPO (lb)

SEC.311/312 Hazard Category

Chemical (Yes, No)

NA

CERCLA (40 CFR 302.4 Hazardous Substance and Reportable Quantities): This product may contain hazardous substances listed under 40 CFR 302.4. However,they will bepresentonly in trace or residual quantities. Under reasonably anticipated conditions of shipmentor handling, it is highly unlikely that an accidental release would exceed the reportable quantity of the listed chemical. RCRAInformation: Thisproduct is not listed in federal hazardouswaste regulation 40 CFR 261.33, paragraph (e) or i.e., chemical products that are considered hazardous if they become wastes. It does not exhibit any of the hazardous characteristics listed in 40 CFR 261, Subpart C. State or local hazardous waste regulations may apply if they are different from the federal regulation. Other: This product may release phenol upon decomposition, which is listed as a "Toxic Pollutant" under Section 307 of the Clean Water Act, and specific discharge limitations on wastewaters containing it may apply. Refer to the Effluent Guidelines for your industry (40 CFR 401 through 469).

Footnotes to Regulatory Data: SEC. 302 - Threshold Planning Quantity, Extremely Hazardous Substance. (EHS) (40 CFR 355 Emergency Planning and Notification Regulations). NA - Thischemical is notanEHS. Planning Quantity (TPQ).

Therefore, there is noThreshold

SEC.304 - ReportableQuantity for Releasesof Appendix A).

an EHS(40CFR

355,

SEC. 3 11/312 - 40 CFR 370 Hazardous Chemical Reporting Requirements. The "hazard categories" are: HC-1Immediate (acute) health hazard HC-2 Delayed (chronic) health hazard

Vulcanizing Agents

105

HC-3 Fire hazard HC-4 Sudden release pressure hazard HC-5Reactivehazard NHH Not a health hazard NPH Not a physical hazard SEC. 313 - 40 CFR 372 Toxic Chemical Release Reporting Requirements: NO: This component is not subject to the reporting requirements Section 3 13 of Title 111 the Superfund Amendments and Reauthorization Act of 1986 and40 CFR Part 372 Toxic Chemical Reporting requirements.

YES: This component is subject to the reportingrequirements Section 3 13 Title I11 the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 Toxic Chemical Reporting requirements. Percent composition (or estimated range) is listed above. NA: This productis a mixture. As such, it is not listed as a Toxic Chemical under 40 CFR 372, Section 313 reporting requirements. Reportable constituents are listed individually where they exceed threshold concentration limits.

- IDENTIFIERS -Name:DICUMYLPEROXIDE Synonyms: Active Dicumyl Peroxide; Bis(alpha,alpha-Dimethylbenzyl)Peroxide; Cumene Peroxide; Cumyl Peroxide; Dicumyl Peroxide; Dicumyl Peroxide (DOT);Di-alpha-CumylPeroxide;DI-CUP;Diisopropylbenzene Peroxide; Isopropylbenzene Peroxide CAS: 80-43-3; RTECS: SD8150000 Formula: C,8H2202;MolWt: 270.40 WLN: 1x1 ChemicalClass: Organicperoxide See other identifiers listed below under Regulations.

--PROPERTIES -BoilingPoint: NA Melting Point: 312.16 to 314.16 K; 39 to 41°C; 102.2 to 105.8"F FlashPoint: >383.16 K; > 10°C; >230"F

106

Chapter

Autoignition: NA UEL: NA LEL: NA Vapor Density: No data Specific Gravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: Acrid smoke and irritating fumes Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: DOT guide: 48 Identification number: UN3 DOT shipping name: Organic peroxide type F, solid Packinggroup: I1 Label(@ required: ORGANICPEROXIDE Packaging exceptions: Nonbulk packaging: Bulk packaging: None Quantity limitations: Passenger airhail: kg Cargo aircraft only: kg Vesselstowage: D Other stowage provisions: 40 Clean Water Act Sect. 307: No Clean Water ActSect. 311: No Clean Air Act:Not listed EPA Waste Number: None CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value: Not listed

107

Vulcanizing Agents

SARA Sect. 312 Categories: Reactivehazard: organic peroxide. U.S. Postal Service Mailability: Hazard class: Organic peroxide Mailability: Domestic service and air transportation shipper’s declaration Max per parcel: 1lb NFPA Codes: HealthHazard(blue): Unspecified Flammability(red): Unspecified Reactivity(yellow): Unspecified Special: Unspecified

--TOXICITY DATA -Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

ConcIDLH.

Unknown

NOSH REL: Not given ACGIHTLV: Not listed ACGIHSTEL: Not listed OSHA P E L Not in Table MAKInformation: Not listed Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; MAK: Not listed; NZOSH. Not listed; NTP: Not listed; ACGZH: Not listed; OSHA: Not listed. LDS0 Value: orl-rat LD50:4100 mg/kg OtherSpeciesToxicityData: orl-rat LD50:4100 mg/kg unr-rat LD50:3500 mg/kg

(Source:NIOSH RTECS 1992)

108

Chapter 3

Reproductive Toxicity (1992 RTECS): This chemical has no known mammalian reproductive toxicity.

--PROTECTION AND FIRST AID -First Aid Source: DOT Emergency Response Guide 1993. Move victim to fresh air; call emergency medical care. In case contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

--- INITIAL INCIDENT RESPONSE --U.S. DepartmentofTransportationGuide Hazardous Materials Transport Information Publication DOT 5800.5 (1990). DOT Shipping Name: Organic peroxide type F, solid DOT ID Number: UN3 110

-

ERG90

* POTENTIAL HAZARDS *

GUIDE 48

*Health Hazards Contact may cause bums to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion May be ignited by heat, sparks, and flames. Container may explode in heat of fire. May explode from heat or contamination. Runoff to sewer may create fire or explosion hazard.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out low areas. Positive pressureself-containedbreathingapparatus(SCBA)and structural firefighters’ protective clothing will provide limited protection. CALL CHEMTRECAT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities.

Vulcanizing

*Fire Smallfires: Dry chemical, CO2, water spray, or regular foam. Large fires: Flood fire area with water. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holderor monitor nozzles; if this is impossible, withdraw from area and let fire bum. *Spill or Leak Shut off ignition sources; no flares, smoking, or flames in hazard area. Do not touch or walk through spilled material; stop leak if you can do it without risk. Small spills: Takeupwith inert, dampnoncombustible material; move containers from spill area. Large spills: Wet down with water and dike for later disposal.

*First Aid Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

--IDENTIFIERS -Name: 2,5-DIMETHYL-2,5-DI(TERT-BUTYLPEROXY)~~-3 Synonyms: 2,5-Dimethyl-2,5-Di(t-Butylperoxy)Hexyne-3; 3-Hexyne, 2,5Dimethyl-2,5-Di (T-Buty1peroxy)CAS: 1068-27-5; RTECS: MQ750000 Formula: C,,H,O,; Mol Wt: 286.46 WLN: 1x1 ChemicalClass: Organicperoxide See other identifiers listed below under Regulations.

--- PROPERTIES -Boiling Point: 340.16 K at 2 mm; 67°C at 2 mm; 152.6"F at MeltingPoint: NA Flash Point: 358.16 K; 85°C;185°F

mm

110

Chapter 3

Autoignition: NA UEL: NA LEL: NA Vapor Density: No data SpecificGravity: No data Density: 0.881 Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents:No data Polymerization Possibilities:No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--

REGULATIONS

--

DOT hazard class: 5.2 DOT guide: 49 Identification number: UN3 103 DOT shipping name: ORGANIC PEROXIDE TYPE C, LIQUID Packinggroup: I1 Label(s)required: ORGANICPEROXIDE Packaging exceptions: 173.152 Nonbulkpackaging: 173.225 Bulkpackaging: 173.None Quantity limitations: Passenger airhail: 5 L Cargo aircraft only: 10 L Vesselstowage: D Other stowage provisions: 12, 40 STCC Number: 4919264 Clean Water Act Sect. 307: No Clean Water Act Sect. 311: No Clean Air Act:Not listed EPA Waste Number: None CERCLA Ref: Notlisted

Vulcanizing Agents

111

RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Reactive hazard: organic peroxide.

U.S. Postal Service Mailability:

Not given

NFPA Codes: Health Hazard (blue):Unspecified Flammability (red): Unspecified Reactivity (yellow):Unspecified Special: Unspecified

- TOXICITY DATA -Short-term Toxicity: Unknown Long-term Toxicity: Unknown Conc IDLH Unknown

NIOSH REL: Not given ACGIH TLV: Not listed ACGIH STEL: Not listed

OSHA PEL: Not in Table Z-l-A MAK Information: Not listed Carcinogen: N; Status: Seebelow Carcinogen Lists: Z A R C Not listed; MAK: Not listed; NZOSH Not listed; NTP Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: No LD50 in RTECS 1992 Other Species ToxicityData: ipr-mus LD50:1850 mg/kg

(Source:NIOSHRTECS

1992)

Reproductive Toxicity (1992 RTECS): This chemical has malian reproductive toxicity.

known mam-

112

Chapter

--PROTECTION AND FIRST AID -FirstAidSource: NIOSH. Inhalation: Nonegiven Ingestion: Nonegiven Skin: Nonegiven Eyes: Nonegiven First Aid Source: DOT Emergency Response Guide 1993. Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

- INITIAL INCIDENT RESPONSE U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT Shipping Name: ORGANIC PEROXIDE TYPE C, LIQUID DOT ID Number: UN3103 ERG90

* POTENTIAL HAZARDS *

GUIDE 49

*Health Hazards Contact may cause bums to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion May be ignited by heat, sparks, and flames. May bum rapidly with flare-burning effect. Container may explode in heat of fire. May explode from friction, heat, or contamination. Runoff to sewer may create fire or explosion hazard.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas.

Vulcanizing

113

Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters' protective clothing will provide limited protection. Isolate for 1/2mile in all directions if tank, rail car, or tank truck is involved in fire. CALLCHEMTRECAT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Small fires: Dry chemical, COz, water spray, or regular foam. Large fires: Flood fire area with water from a distance. Do not move cargo or vehicle if cargo has been exposed to heat. If fire can be controlled, cool container with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible, withdraw from area and let fire bum. *Spill or Leak Shut off ignition sources; no flares, smoking, or flames in hazard area. Do not touch or walk through spilled material; stop leak if you can do it without risk. Small spills: Takeupwith inert, dampnoncombustible material; move containers from spill area. Large spills: Wet down with water and dike for later disposal.

*First Aid Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

--JDENTIF'IERS -Name: 2,5-DMETHYL-2,5-DI(TERT-BUTYLPEROXY)HEXAIW CAS: 78-63-7;RTECS: M01835000 Formula: C,6H3404; Mol Wt: WLN: 1x1 ChemicalClass: Organicperoxide See other identifiers listed below under Regulations.

114

Chapter 3

--PROPERTIES --Physical Description: Colorless to light-yellow liquid Boiling Point: 523.15 K; 250°C; 482°F Melting Point: 281.15 K; 46.4"F Flash Point: NA Autoignition: NA UEL: NA LEL: NA Vapor Density:No data Specific Gravity: No data Density: 0.85 Water Solubility: INSOL Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm):Unknown Odor Description: No data 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: 5.2 DOT guide: 48 Identification number: UN3 105 DOT shipping name: ORGANIC PEROXIDE TYPE D, LIQUID Packing group: 11 Label(s)required: ORGANICPEROXIDE Packaging exceptions:173.152 Nonbulk packaging: 173.225 Bulkpackaging: 173.None Quantity limitations: Passenger airhail: 5 L Cargo aircraft only: 10L Vesselstowage: D Otherstowage provisions: 12, 40

115

Vulcanizing Agents STCC Number: 4919263 Clean Water Act Sect. 307: No Clean Water Act Sect. 311: No Clean Air Act:Notlisted EPA Waste Number: None CERCLA Ref: Not listed RQ Designation: Notlisted SARA TPQ Value: Not listed SARA Sect. 312 Categories: Reactivehazard: organic peroxide.

U.S. Postal Service Mailability:

Not given

NFPA Codes: Health Hazard (blue):Unspecified Flammability (red): Unspecified Reactivity (yellow):Unspecified Special: Unspecified

--TOXICITY DATA -Short-term Toxicity: Unknown Long-term Toxicity: Unknown Conc I D L H Unknown NIOSH REL: Notgiven ACGIH TLV: Not listed ACGM STEL: Notlisted OSHA PEL: Not in Table MAK Information: Notlisted Carcinogen: N; Status: Seebelow Carcinogen Lists: Z A R C Not listed; M M Not listed; NZUSH. Not listed; ATP: Not listed; ACGIH: Not listed; OSHA: Not listed.

116

Chapter 3

LD50 Value: No LD50 in RTECS 1992 OtherSpeciesToxicityData: (Source:NIOSHRTECS1992) ipr-mus LDLo: 1700 mg/kg Reproductive Toxicity (1992 RTECS): This chemical has no malian reproductive toxicity.

mam-

--- PROTECTION AND FIRST AID First AidSource: NIOSH. Inhalation: Nonegiven Ingestion: Nonegiven Skin: Nonegiven Eyes: Nonegiven First AidSource: DOTEmergencyResponseGuide1993. Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

--INITIAL INCIDENT RESPONSE Fire Extinguishment: Fight fire with water, spray,dry CHRIS 91).

chemical (Note:

U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT Shipping Name: ORGANIC PEROXIDE TYPE D, LIQUID DOT ID Number: UN3105 ERG90

* POTENTIAL HAZARDS *

*Health Hazards Contact may cause bums to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution.

GUIDE 48

Vulcanizing Agents

117

*Fire or Explosion May be ignited by heat, sparks, and flames. Container may explode in heat of fire. May explode from heat or contamination. Runoff to sewer may create fire or explosion hazard.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection. CALLCHEMTRECAT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Small fires: Dry chemical, CO2, water spray, or regular foam. Large fires: Flood fire area with water. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holderor monitor nozzles; if this is impossible, withdraw from area and let fire burn. *Spill or Leak Shut off ignition sources; no flares, smoking, or flames in hazard area. Do not touch or walk through spilled material; stop leak if you can do it without risk. Small spills: Take up with inert, dampnoncombustible material; move containers from spill area. Large spills: Wet down with water and dike for later disposal. *First Aid Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

118

Chapter 3

--IDENTIFIERS -Chemical Name and Synonyms: TERT-BUTYL PEROXYMALEIC ACID, C,H,,O, Trade Name and Synonyms: ChemicalFamily:

Luperox PMA

Organicperoxide

Manufacturer: Lucidol Division, Pennwalt Corp., Buffalo, NewYork UNIDNumber:

NA

--INGREDIENTS AND COMPOSITION DATA --Material

No.

Cas

t-Butyl peroxymaleic acid

NA

--

% 98

PHYSICAL DATA

--

BoilingPoint (OF):NA SpecificGravity (H,O =

NA

e): NA

VaporPressure(mm

Percent Volatile by Volume (%): NA VaporDensity(air FreezingPoint:

=

NA

NA

EvaporationRate:

NA

p H NA

Solubility in Water: NA Melting Point: 1 1 4 O to 1 16°C (with decomposition) AppearanceIColorlOdor: Fine, whitepowder.

TLV -

16 mgkg (mouse)

119

Vulcanizing Agents

--FIRE AND EXPLOSION HAZARDS --Flash Point: NA FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Foam or water spray, dry chemical, carbon dioxide. Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. Use self-contained breathing apparatus. If fire is large, evacuate area and fight fire from a safe distance. Cool surrounding area with water. If confined during exposure to a fire, can decompose with force. Material is subject to decomposition under friction or heavy shock.

Unusual Fire and Explosion Hazards: Exposure of containers to fire results in rapid productdecomposition, container pressure buildup, and failure, followed by vigorousburningwith flare effect. Cleanupshouldnotbe attempted until all the product has cooled completely. May form flammable dust-air mixtures. HazardousProducts of CombustionandDecomposition: provided by manufacturer.

Noinformation

HazardousPolymerization: Willnotoccur

--- HEALTH HAZARD DATA -Effects of Overexposure: Unknown Emergency Response and First Aid: Skin: Wash thoroughly with soap and running water. Remove contaminated clothing and wash before reuse. Eyes: In case of contact, immediately flush with plenty of low-pressure water for at least 15 min. Remove any contact lenses to ensure thorough flushing. Call a physician. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately.

Chapter

120

Ingestion: If conscious, the person should immediately drinklarge quantities of liquid to dilute this product. Never give liquids to an unconscious person. Call a physician. Cancer Information: Not listed as a carcinogen byNTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--- TOXICITY DATA -Animal Effects: LD50 for mouse reported at approximately

mg/kg.

--REACTIVITY DATA -StabilityandConditions to Avoid: Extendedexposure to 120°F or higher temperatures may lead to rapid decomposition. Do not subject dry peroxide to grinding or other sources of friction. Materials to Avoid (Incompatibility): Strong oxidizing and reducing agents, mineral acids, and accelerators. Hazard Decomposition Products: Acetophenone, cumyl alcohol, alpha-methyl styrene, methane,and ethane. Under acidic decomposition conditions, phenols may also be formed. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Spilled material may be wetted with water and/or blended with a noncombustible absorbent such as vermiculite. Sweep up with nonsparking utensils. Waste Disposal Method: Place absorbed material in shallow trench and ignite from safe distance withalong torch (6 ft minimum).Any disposal must comply with local, state, and federal regulations. Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the risk of injury,do not cut, puncture, or weld or near this container.

Vulcanizing

121

- SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection: Appropriate respirator selected and used in accordance with OSHA Subpart (29 CFR 1910.134) and manufacturer's recommendations is required if airborne dust is not adequately controlled or if excessive fumes are generated from product decomposition. Self-contained breathing apparatus should be worn in high vapor and dust concentrations. Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirement: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves andOther: Impervious gloves andclothing should be worn. Storage and Handling Precautions:Store in cool, dry location away from all sourcesof heat, spark, andopenflames.Avoid ignition sources such as sparks and flames. Ground all equipment. In addition, when emptying bags where flammable vapors may be present, blanket vessel with inert gas, ground operator, and pour material slowly into conductive, grounded chute. Store below in original containers in a ventilated area out of direct sunlight and away from heat sources. Storage at higher temperatures risks melting of the products organic peroxide and the information of lumps and cakes. Also store below 86°F to maintain active oxygen content. This material may react with acids and acid-like materials, strong oxidizing and reducingagents, oxidation catalysts, copper, copper alloys, lead, and iron and should not be stored near such materials.

OtherPrecautions: Useall standard practices for goodpersonalhygiene. Completely isolate andthoroughlyclean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Note that this product will bum.

--- REGULATORY INFORMATION -Refer to other organic peroxides reported in this section.

122

Chapter 3

--IDENTIFIERS --Name: SULFUR Synonyms: Bensulfoid;Brimstone; Collokit; Colloidal-S;Colloidal Sulfur; Colsul; CorosulD;Corosul S; Cosan;Cosan 80; Crystex; Flour Sulfur; Flowersof Sulfur; GroundVocle Sulfur; Hexasul;Kolofog;Kolospray; Kumulus; Magnetic70; Magnetic 90; Magnetic 95; Microflotox; Precipitated Sulfur; Sofril; Sperlox-S; Spersul; Spersul Thiovit; Sublimed Sulfur; Sulfidal; Sulforon; Sulfur, Solid; Sulkol; Super Cosan; Sulphur; Sulfur (DOT); Sulsol; Technetium Tc 99M Sulfur Colloid; Tesuloid; Thiolux; Thiovit CAS:7704-34-9; RTECS: WS4250000 Formula: S; Mol Wt:32.06 WLN: S Chemical Class: Nonmetal See other identifiers listed below under Regulations.

--PROPERTIES -Boiling Point: 717.75 K;444.6"C;832.2"F Melting Point: 392.15K; 119OC;246.2OF FlashPoint: NA Autoignition: NA UEL: NA LEL: NA IonizationPotential (ev): 16.80 Vapor Density: No data Specific Gravity: No data Density: 2.070 Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

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123

--REGULATIONS -DOT hazard class: 9 CLASS 9 DOT guide: 32 Identificationnumber: NA1350 DOT shipping name: Sulfur Packinggroup: 111 Label(s)required: CLASS 9 SpecialProvisions: A1 Packaging exceptions: 173.151 Nonbulkpackaging: 173.213 Bulkpackaging: 173.240 Quantity limitations: Passenger airhail:25 kg Cargo aircraft only: 100 kg Vesselstowage: A Other stowage provisions: 19, 74 STCC Number: Not listed Clean Water Act Sect. No Clean Water Act Sect. 311: No Clean Air Act:Not listed EPA Waste Number: None CERCLA Ref: Notlisted RQ Designation: Notlisted SARA TPQ Value: Not listed SARA Sect. 312 Categories: Fire hazard:flammable.

U.S. Postal Service Mailability: Hazardclass: ORM-C Mailability: Domestic service and air transportation shipper’s declaration Max per parcel: 25 lb NFPA Codes: Health Hazard (blue): (2) Hazardous to health. Area may be entered with self-contained breathing apparatus. Flammability (red): (1) This material must be preheated before ignition can occur. Reactivity (yellow): Stable even under fire conditions. Special: Unspecified.

124

Chapter

--TOXICITY DATA -Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

Symptoms: Human eye irritant at 6 ppm; chronic inhalation can causeirritation mucousmembrane; conjunctivitis, inflammation of skin, irritation respiratory tract (Source:SAX;THIC). Conc IDLH Unknown NIOSHREL: Not given ACGIH TLV:Not listed ACGIHSTEL: Not listed OSHA PEL: Not in Table Z-l-A MAKInformation:

Not listed

Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; MAK Not listed; NZOSH Not listed; N T P Not listed; ACGZH Not listed; OSHA: Not listed. HumanToxicityData:

(Source:NIOSHRTECS)

LDS0Value: No LD50 in RTECS 1992 OtherSpeciesToxicity Data: (Source:NIOSHRTECS1992) ivn-rat LDLo:8 mg/kg ivndog LDLo:10 mgkg orl-rbt LDLo: 175 mgkg ivn-rbt LDLo:5 mg/kg ipr-gpg LDLo:55 mg/kg IrritationData: (Source:NIOSHRTECS1992) eye-hmn 8 ppm Reproductive Toxicity (1992 RTECS): This chemical has malian reproductive toxicity.

known mam-

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125

- PROTECTION AND FIRST AID -FirstAidSource: DOTEmergencyResponseGuide1993. Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush eyes with running waterfor at least 15 min. Removal of solidified molten material from skin requires medical assistance. Remove and isolate contaminated clothing and shoes at the site.

- INITIAL INCIDENT RESPONSE U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOTShippingName: Sulfur DOT ID Number: NA1350 ERG90

* POTENTIAL HAZARDS *

GUIDE 32

*Health Hazards Contact may cause bums to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Flammable/combustible material; may be ignited by heat, sparks, or flames. May bum rapidly with flare-burning effect.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection. CALLCHEMTRECAT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Smallfires: Dry chemical, sand, earth, water spray, or regular foam. Largefires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks.

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For massive fire in cargoarea, use unmanned hoseholder or monitor nozzles; if this is impossible, withdraw from area and let fire bum. Magnesiumfires: Use dry sand, Met-L-X R powder, or G-lgraphite powder.

*Spill or Leak Shut off ignition sources; no flares, smoking, or flames in hazard area. not touch or walk through spilled material; stop leak if youcan do it without risk. Small dry spills: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Wet down with water and dike for later disposal.

*First Aid Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush eyes with running water for at least 15 min. Removal of solidified molten material from skin requires medical assistance. Remove and isolate contaminated clothing and shoes at the site.

- IDENTIFIERS -Chemical Name and Synonyms: N-OXYDIETHYLENEBENZOTHIAZOLE-Z-SULFENAMIDE,C,H$NCSNC4H,O Trade Name and Synonyms: Amax ChemicalFamily:

Sulfenamide

Manufacturer: R. T. Vanderbilt Co., Inc., Norwalk,Connecticut

UN ID Number: NA

--

INGREDIENTS AND COMPOSITION DATA

Cas Material N-Oxydiethylenebenzothiazole-2-Sulfenamise

No. NA

% 98 min.

---

TLV Acute oral,

LD50, 4000 mgkg mice

127

Vulcanizing Agents

--- PHYSICAL DATA -BoilingPoint (“F): NA SpecificGravity (H,O = 1): VaporPressure(mmHg):

NA

Percent Volatile by Volume (%): NA = 1): NA

VaporDensity(air FreezingPoint:

NA

EvaporationRate:

NA

pH: NA Solubilityin Water: Negligible MeltingPoint:

NA

Appearance/Color/Odor: Tan flakes.

--

FIRE AND EXPLOSION HAZARDS ---

FlashPoint: NA FlammabilityLimits: NA AutoignitionTemperature:

NA

Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. Use self-contained breathing apparatus. If fire is large, evacuate area and fight fire from a safe distance. Cool surrounding area with water. If confined during exposure to a fire, can decompose with force. Material is subject to decomposition under friction or heavy shock.

Unusual Fire and Explosion Hazards: Exposure of containers to fire results in rapid productdecomposition, container pressure buildupand failure,

Chapter

128

followedbyvigorousburningwith flare effect. Cleanupshouldnot be attempted until all the product has cooled completely. May form flammable dust-air mixtures.

HazardousProductsofCombustionandDecomposition: Toxicfumes of sulfur and nitrogen oxides at decomposition temperatures. HazardousPolymerization: Willnot occur.

- HEALTH HAZARD DATA -Effects of Overexposure: Unknown Emergency Response and First Aid: Skin: Wash thoroughly with soap and running water. Remove contaminated clothing and wash before reuse. Eyes: In case of contact, immediately flush with plenty of low-pressure water for at least 15 min. Remove any contact lenses to ensure thorough flushing. Call a physician. Inhalation: Removevictim to fresh air and, if indicated, give artificial respiration. If breathing is difficult, giveoxygen. Call a physician. Treat immediately. Ingestion: If conscious, the person should immediately drinklarge quantities of liquid to dilute this product. Never give liquids to an unconscious person. Call a physician. Cancer Information: Not listed as a carcinogen byNTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research Cancer).

--TOXICITY DATA --Animal Effects: LD50 for mouse reported at approximately 4000 mg/kg.

--REACTIVITY DATA -Stability and Conditions to Avoid: None reported by manufacturer. Materials to Avoid(Incompatibility): conditions.

Avoid contact with acids or acidic

Vulcanizing Agents

HazardDecompositionProducts:

129

Unknown

Hazardous Polymerization: Will not occur.

--

SPILL AND EMERGENCY RESPONSE

--

For Spills: Sweep spillage; wash residuals with soap and water and transfer to a closed container. Waste Disposal Method: Same as for organic chemicals. Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the riskof injury, donot cut, puncture, or weld on or near this container.

- SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: Appropriate respirator selected and used in accordance with OSHA Subpart I (29 CFR 1910.134) and manufacturer’s recommendations is required if airborne dust is not adequately controlled or if excessive fumes are generated from product decomposition. Self-contained breathing apparatus should ,be worn in highvaporand dust concentrations. Under normal use, manufacturer recommends a dust mask. Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves andOther: Impervious gloves andclothing should be worn. Manufacturer recommends rubber gloves be used. Storage and Handling Precautions:Store in cool, dry location away from all sources of heat, spark, andopenflames.Avoid ignition sourcessuch as sparks and flames. This material may react with acids and acid-like materials and strong oxidizing and reducing agents and should not be stored near such materials.

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OtherPrecautions: Useallstandardpractices for goodpersonalhygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels before beginningmaintenance or repairs. Keepareaclean.Note that this product will bum.

--REGULATORY INFORMATION --No information found.

Name: VALERIC ACID, 4,4-BIS(tert-BUTnPEROXY)-, BUTYLESTER Synonyms: 4,4-Bis(tert-Butylperoxy)Valeric AcidButyl Ester; n-Butyl-4,4Di(tert-Butylperoxy)Valerate, technicalpure (DOT); PentanoicAcid, 4,4Bis(( 1,I-Dimethylethy1)Dioxy)-, ButylEster;Trigonox 17/40; UN 2140 (DOT) CAS: 995-33-5; RTECS: YV6191200 Formula: C,7H3406; MolWt: 334.51 Chemical Class: Ester See other identifiers listed below under Regulations.

--PROPERTIES --BoilingPoint: NA MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA VaporDensity: No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data StabilityduringTransport: No data NeutraliringAgents: No data PolymerizationPossibilities: No data

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131

Toxic Fire None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--- REGULATIONS -DOT hazard class: 5.2 DOT guide: 48 Identification number: UN3 103 DOT shipping name: ORGANIC PEROXIDE TYPE C, LIQUID Packinggroup: I1 Label(s)required: ORGANICPEROXIDE Packaging exceptions: 173.152 Nonbulkpackaging: 173.225 Bulkpackaging: 173.None Quantity limitations: Passenger airhail: 5 L Cargo aircraft 10 L Vesselstowage:D Otherstowage provisions: 12, 40

STCC Number: Not listed Clean Water Act Sect. 307: No Clean Water Act Sect. 311: No Clean Air Act:Not listed EPA Waste Number: None CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value:Not listed SARA Sect. 312 Categories: No category

U.S. Postal Service Mailability:

Not given

--TOXICITY DATA --Short-term Toxicity:

Unknown

Long-term Toxicity: Unknown Conc IDLH: Unknown

132

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NIOSH REL: Not given ACGM TLV: Not listed ACGM STEL: Notlisted

OSHA PEL: Not in Table Z-l-A MAK Information: Notlisted Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; MAK: Not listed; NZOSH Not listed; hTP Not listed; ACGZH: Not listed; OSHA: Not listed. LD50 Value: No LD50 in RTECS 1992 Reproductive Toxicity (1992 RTECS): This chemical has no known malian reproductive toxicity.

ma-

--- PROTECTION AND FIRST AID -FirstAidSource: DOT Emergency Response Guide 1993. Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

--INITIAL INCIDENT RESPONSE --U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT (1990). DOT Shipping Name: ORGANIC PEROXIDE TYPE C, LIQUID DOT ID Number: UN3103 ERG90

* POTENTIAL HAZARDS *

*Health Hazards Contact may cause bums to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution.

GUIDE 48

Vulcanizing Agents

133

*Fire or Explosion May be ignited by heat, sparks, and flames. Container may explode in heat of fire. May explode from heat or contamination. Runoff to sewer may create fire or explosion hazard.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection. CALLCHEMTRECAT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Small fires: Dry chemical, COz, water spray, or regular foam. Large fires: Flood fire area with water. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire incargo area, use unmanned hose holderor monitor nozzles; if this is impossible, withdraw from area and let fire bum. *Spill or Leak Shut off ignition sources; no flares, smoking, or flames in hazard area. Do not touch or walk through spilled material; stop leak if you can do it without risk. Small spills: Take up with inert, dampnoncombustible material; move containers from spill area. Large spills: Wet down with water and dike for later disposal. *First Aid Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

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--

IDENTIFIERS --

ChemicalNameandSynonyms: AND RUBBER PROCESS OIL Trade Name and Synonyms: ChemicalFamily:

OFINSOLUBLE SULFUR

Crystex

Polymeric Sulfur

Manufacturer: AkzoChemicals,Inc.,

Chicago, Illinois

UN ID Number: UN1350

--INGREDIENTS AND COMPOSITION DATA Material

No.

Cas

%

Polymeric sulfur

9035-99-8

72

Sulfur

7704-34-9

8

Naphthenic oils

64741-96-41 20 64742-52-5

--

PHYSICAL DATA

TLV Not established

--

Boiling Point ("F):560°F (293°C) oil fraction; 832°F (444°C) sulfur fraction Specific Gravity (H,O = 1): 1.57 at 68"F/68"F (2O"C/2O0C) VaporPressure(mm Hg): NA Percent Volatile by Volume VaporDensity(air FreezingPoint:

p H NA

= 1): NA

NA

EvaporationRate:

(%): NA

NA

135

Vulcanizing

Solubilityin Water: Not in water. Oil fraction soluble inmostorganic solvents; sulfur fraction slightly soluble in organic solvents. Sulfur fraction is soluble up to 10% in carbon disulfide. MeltingPoint: NA Appearance/Color/Odor: Yellowpowder.

--FIRE AND EXPLOSION HAZARDS -FlashPoint: NA FlammabilityLimits: NA Autoignition: NA Extinguishing Media: Foam or water spray, dry chemical, carbon dioxide. Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontained breathing apparatus andimpervious protective clothing such as gloves, hoods, suits, and rubber boots. Use water fog, drychemicals, or carbon dioxide to extinguish fires involving this material. Solid streamsofwatershouldnotbeusedbecauseof the possibility of dispersing dust clouds of sulfur in the air, possibly causing an explosion. Cool the surrounding area withwaterfog prevent ignition. Fires will rekindle before the mass is cooled down below 428°F (220°C).

Unusual Fire and Explosion Hazards: Sulfur dust is considered flammable anda fire hazard. Sulfur dust that is suspendedin air ignites easily and results in anexplosion in confined areas. Ignition canbecausedbyheat sources, friction, and static electricity developed by the movement of sulfur dust in the air. Supports combustion and decomposes under fire conditions to give off toxic sulfur dioxide. Do not use welding or cutting torch or near any container of this material, even empty, because an explosion could occur. Do not use, pour, spill, or store near heat or open flame.

136

HazardousProducts dioxide.

Chapter 3

of CombustionandDecomposition:

Toxic sulfur

HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA -Effects of Overexposure: Principal routes of exposure are skin contact and inhalation. Exposure to large amounts ofthe dust may cause eye andrespiratory irritation accompaniedbycoughing, sneezing, and tears. If ignited, the material generates toxic fumes of sulfur dioxide, large quantities of which are capable of producing irritation of the skin, eyes, and mucous membranes. Serious cases may result in pulmonary edema and may be fatal. Ingestion of the product in large quantities may cause milddigestive disorders, including diarrhea. There are no data available that address medical conditions that are generally recognized as beingaggravatedbyexposure to this product. Refer to the section Toxicology Data.

Emergency Response and First Aid: Skin: Flushallaffected areas with plenty ofwater for several minutes. Removeandcleananycontaminated clothing and shoes. Seekmedical attention if skin imtation occurs. Eyes: Flush the eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If swallowed, immediately give several glasses of water and induce vomiting by gagging the victimwitha finger placed the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth.

--TOXICITY DATA -Animal Effects: Ingestion: The acute oral LD50 is approximately 4640 mgkg in male rats. Skin contad: Nonirritant to rabbit skin following a 4-hr exposure.

Vulcanizing Agents

Eye conrucr: Mild irritant to rabbit eyes.

--REACTIVITY DATA -Stability and Conditions to Avoid: Heat, open flames. Materials to Avoid(Incompatibility): Material is corrosive to copper and copper alloys. In the presence of water, sulfur will attack steel. Carbon steel is the most common material of construction for process equipmentfor the dry product, although stainless steels are sometimes used. Material is incompatible with chlorates, nitrates, oxidizing agents, amines, strong bases. HazardDecompositionProducts:

Sulfur dioxide

Hazardous Polymerization: Will not occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Sweep spillage; wash residuals with soap and water and transfer to a closed container. Waste Disposal Method:

Same as for organic chemicals.

Empty Containers: The container for this product can presentexplosion or fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS "Respiratory Protection: Appropriate respirator selected and usedin accordance with OSHA Subpart I (29 CFR 1910.134) and manufacturer's recommendations is required if airborne dust is not adequately controlled or if excessive fumes are generated from product decomposition. Self-contained breathing apparatus should be worn in high vaporanddust concentrations. Under normal use, manufacturer recommends a dust mask. Type of Ventilation Required: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations.

Chapter 3

138

EyeProtectionRequirements: Chemicalgoggles.Eyewashfountainsand safety showers should be easily accessible. Protective Gloves and Other:Impervious gloves and clothing should be worn. Manufacturer recommends rubber gloves be used. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup and dispersion. Separate from chlorates, nitrates, and other oxidizing agents. Store away from basic amines and other strong bases. This material may react with acids and acid-like materials and strong oxidizing and reducing agents and should not be stored near such materials.

Other Precautions: Use all standardpractices for goodpersonal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keeparea clean. Note that this product will bum.

--- REGULATORY lNJ?ORMATION -Refer to DOT shipping regulations.

--IDENTJFIERS -Name: BIS(DIMETHYL"HI0CARBAMYL) DISULFIDE Synonyms: Thiram; Bis((Dimethy1amino)Carbonothioyl) Disulphide; Disolfuro Di Tetrametiltiourame (Italian); Disulfure De Tetramethylthiourame; Alpha,Alpha'-Dithiobis(Dimethylthi0) Formamide; N,N"(Dithiodicarborothioyl)Bis(N-Methyl-Methanamine); MethylThiuramdisulfide;Tetramethyl Thiuram Disulfide; TetramethylDiurane Sulfite; Tetramethylene Thiuram Disulfide; Tetramethylthiocarbamoyl Disulfide; Tetramethylthioperoxydicarbonic Diamide; Tetramethyl Thioram Disulfide (Dutch); Tetramethylthiram Disulfid (German); Tetramethylthiuram Bisulfide; Tetramethylthiuram Disulfide; N,N,K ,N"Tetramethyl Thiuram Disulfide; Tetramethyl Thiurane Disulfide; Tetramethylthiuram Disulfide; Thiram; Tiuram (Polish); USAF B30; USAF EK-2089;USAF P-5;TMTD; ENT 987; SQ 1489; NSC 1771;

Vulcanizing

139

Thiurad; Thiosan; Thylate; Tiuramyl; Thiuramyl; Duralyn; Fernasan; Nowergan; Pezifilm; Tersan; Tuads; Tulisan; Arasan; HCDB CAS:137-26-8; RTECS:J01400000 Formula: C6HI2N,S,; Mol Wt: 240.44 WLN: 1N1 Chemical Class: Organic sulfide See other identifiers listed below under Regulations.

- PROPERTIES -PhysicalDescription: Colorless to cream solid (somecommercialproducts dyed blue) BoilingPoint: Decomposes Melting Point: 413.15 K; 140°C;284°F Flash Point: 362 K;88.8"C;191.9"F Autoignition: NA Vapor Pressure: About mm UEL: NA LEL: NA Vapor Density: No data SpecificGravity: 1.43 at20°C Density: 1.43 g/cc or 13.299 lb/gal Water Solubility: INSOL Incompatibilities: Strong oxidizers, strong acids, oxidizablematerials Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data PolymerizationPossibilities: No data Toxic Fire Gases: Oxides of nitrogen, oxides of sulfur Odor Detected at (ppm): Data not available Odor Description: Datanotavailable(Source:CHRIS) 100% Odor Detection: No data

--REGULATIONS --DOT hazard class: 9 CLASS 9 DOT guide: 31 Identificationnumber: UN3077

140

Chapter 3

DOT shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. Packinggroup: 111 Label(s)required: CLASS 9 Special Provisions: 8, B54 Packaging exceptions: 173.155 Nonbulk packaging: 173.213 Bulk packaging: 173.240 Quantity limitations: Passenger airhail: None Cargo aircraft only: None Vesselstowage:A STCC Number: 4921632, 4921631, 4921634, 4921633 Clean Water Act Sect. 307: No 311: No Clean Water Act Clean Air Act: Not listed EPA Waste Number: U244 CERCLARef: Y RQ Designation: A; 10 lb (4.54 kg) CERCLA SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: toxic. LD50 > 50 and < = 500 mgkg (oral rat). Acute toxicity: irritant. Acute toxicity: adverse effect to target organs. Chronic toxicity: adverse effect to targetorgans after long periods of exposure. Chronic toxicity: reproductive toxin.

U.S. Postal Service Mailability: Hazard class: ORM-A Mailability: Domestic service and air transportation; shipper’s declaration Max per parcel: 70 lb; 5 lb (air) NFPA Codes: HealthHazard (blue):Unspecified Flammability (red): Unspecified Reactivity (yellow):Unspecified Special: Unspecified

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141

--TOXICITY DATA Short-termToxicity: Inhalation: Noinformation on humanexposure is available. Animal studies indicate that irritation of the nose and throat may occur at levels above 5 mg/m3. Eyes: Maycause irritation, tearing, and sensitivity to light. Skin: Exposure to spray containing 45 % thiram resulted in irritation and skin sensitization. Ingestion: No information available human exposure. In animal studies, 38 ppm in food caused nausea, vomiting, diarrhea, hyperexcitability, weakness, and loss of muscle control. Death may occur from ingestion of approximately one teaspoonful. (NYDH) Long-term Toxicity: Occupational exposuresto 0.03 mg/m3 over a5-yr period hascausedmild irritation of the noseand throat. Prolonged contact has causedeye irritation, tearing, increased sensitivity to light, reduced night vision, and blurred vision. Thiramhascaused birth defects in laboratory animals. Whether it has this effect in humans is not known. (NYDH) Target Organs: Skin, mucous membranes, kidneys, respiratory system, lungs. Symptoms: Inhalation of dust may cause respiratory irritation. Liquid irritates eyesand skin andmaycause allergic eczema in sensitive individuals. Ingestion causes nausea,vomiting,and diarrhea, all ofwhich may be persistent; paralysis maydevelop.(Source:CHRIS) Conc IDLH 1500 mg/m3 ACGIH TLV: TLV = 1 mg/m3 ACGIHSTEL: Not listed OSHA PEL: Transitional Limits: PEL = 5 mg/m3; Final Rule Limits: TWA = 5 mg/m3

MAK Information: 5 calculated as total dust mg/m3; substance with systemic effects, onset of effect less than or equal to 2 hr: Peak = 5xMAK for 30 min. 2 times per shift of 8 hr. Carcinogen: N; Status: See below References: Animal indefinite IARC** 12,225,76;Human indefinite IARC** 12, 225, 76

142

Chapter

CarcinogenLists: Z A R C Not classified as to human carcinogenicity or probably not carcinogenic to humans; MAK: Not listed; NZOSH Not listed; NTP: Not listed; ACGZH Not listed; OSHA: Not listed. HumanToxicityData: (Source:NIOSHRTECS) ihl-hmn TCLo:30 mg/m3/5Y-I VRDEAS (lo), 136, 71 Sense Organs Eye Conjunctive irritation Cardiac Other changes Lungs, Thorax, or Respiration Structural of function changes in trachea or bronchi LD50 Value: orl-rat LD50:560 mg/kg OtherSpeciesToxicityData: (Source:NIOSHRTECS1992) orl-rat LD50:560 mg/kg ihl-rat LC50500 mg/m3/4H skn-rat LD50: >5 g/kg ipr-rat LD50: 138 mg/kg scu-rat LD50:646 mg/kg unr-rat LD50:740 mg/kg orl-mus LD50: 1350 mg/kg ipr-mus LD50:70 mg/kg scu-mus LD50: 1109mgkg unr-mus LD50: 1150 mg/kg orl-cat LDLo:230 mg/kg orl-rbt LD50:210 mg/kg skn-rbt LDLo:l g k g unr-rbt LD50:210 mglkg unr-ckn LD50:840 mg/kg unrdom LD50:225 mg/kg unr-mam LD50:400 mg/kg orl-bwd LD50:300 mg/kg ReproductiveToxicity reproductive toxin.

(1992 RTECS):

Thischemical

is amammalian

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143

Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo:1200 mg/kg (7-12D preg) TXAPA9, 35, 83, 76 Effects on Fertility Preimplantation mortality Postimplantation mortality Litter size (number of fetuses per litter; measured before birth) orl-rat TDLo:300 mgkg (15D preg) GISAAA 43(6), 37, 78 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Fetal death Specific Developmental Abnormalities Other developmental abnormalities orl-rat TDLo: 1190 mg/kg (16-22D preg/21D post) TXAPA9 35, 83, 76 Effects on Newborn Growth statistics (e.g., reduced weight gain) orl-rat TDLo:550 mg/kg (1-22D preg) AEEDDS 2, 215, 76 Effects on Newborn Behavioral orl-rat TDLo:420 mgkg (1-20D preg) GISAAA 51(6), 23, 86 Specific Developmental Abnormalities Cardiovascular (circulatory) system par-rat TDLo:400 mgkg (4-llD preg) BEXBAN 93, 107, 82 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Fetal death par-rat TDLo:800 mgkg (2D male/2D pre) BEXBAN 93, 107, 82 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Fetal death orl-mus TDLo: 100 mgkg (6-15D preg) ATXKA8 30, 251, 73 Specific Developmental Abnormalities Craniofacial (including nose and tongue) Musculoskeletalsystem

144

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orl-mus TDLo:300 mgkg (6-15D preg) ATXKA8 30, 251, 73 Effects on Fertility Postimplantation mortality orl-mus TDLo:80 mgkg (3D male) FCTOD7 25, 709, 87 Paternal Effects Spermatogenesis scu-mus TDLo:90 mg/kg (6014D preg) NTIS** PB223-160 Effects on Fertility Preimplantation mortality Litter size (number of fetuses per litter; measured before birth) Effects Embryo or Fetus Extra embryonic features (e.g., placenta, umbilical cord) scu-mus TDLo:1035 mgkg (6-14D preg) NTIS** PB223-160 Effects Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) orl-ham TDLo:125 mgkg (7D preg) TXAPA9 15, 152, 69 SpecificDevelopmentalAbnormalities Musculoskeletalsystem orl-ham TDLo:250 mgkg (8D preg) TXAPA9 15, 152, 69 SpecificDevelopmentalAbnormalities Craniofacial (including nose and tongue) orl-ham TDLo:250 mgkg (7D preg) TXAPA9 15, 152, 69 SpecificDevelopmentalAbnormalities Body wall orl-ham TDLo:300 mgkg (7D preg) TXAPA9 15, 152, 69 SpecificDevelopmentalAbnormalities Central nervous system

--- PROTECTION AND FIRST AID -NIOSH Pocket Guide to Chemical Hazards: **Wear Appropriate Equipmentto Prevent: Reasonable probability ofskin contact. **Wear Eye Protectionto Prevent: Reasonable probability of eye contact.

Vulcanizing

**Exposed Personnel Should Wash: contaminated.

145

Promptly when

skin becomes

**Exposed Clothing Should be Changed Daily: If there is any reasonable possibility that the clothing may be contaminated. **Remove Clothing:Promptly remove nonimperviousclothing that becomes contaminated. **Reference: NIOSH Recommended Respiration Protection Source: NIOSH Pocket Guide(85-1 14) OSHA (Bis(Dimethylthiocarbamy1)Disulfide) 50 mg/m3: Any chemical cartridge respirator with organic vapor cartridge(s) in combination with adust, mist and fumefilter. Substance reported to cause eye irritation or damage may require eye protection. Any supplied airrespirator. Substance reported to cause eye irritation or damage may require eye protection. Any self-contained breathing apparatus. Substance reported to cause eye irritation or damage may require eye protection. 125 mg/m3: Anypowered air-purifying respirator withorganicvapor cartridge(s) in combinationwitha dust, mist, andfume filter. Substance reported to cause eye irritation or damage may require eye protection. Any supplied-air respirator operated in acontinuousflowmode.Substance reported to cause eye irritation or damage may require eye protection. 250 mg/m’: Any self-contained breathing apparatus with a full facepiece. Anychemical cartridge respirator with a full facepiece andorganicvapor cartridge(s) in combinationwithahigh-efficiency particulate filter. Any supplied-air respirator witha full facepiece.Anypowered air-purifying respirator witha tight-fitting facepieceandorganicvapor cartridge(s) in combination with a high-efficiency particulate filter. Substance reported to cause eye irritation or damage may require eye protection. Any air-purifying full facepiece respirator (gasmask)witha chin-style or front- or backmounted organic vapor canister having a high-efficiency particulate filter. 1500 m g / d : Any supplied-air respirator with a full facepiece and operated in a pressure-demand or other positive-pressure mode. Emergency or Planned Entry in Unknown Concentrations or IDLH Conditions: Any self-contained breathing apparatus with a full facepiece and operated in pressure-demand a or other positive-pressure mode. Any supplied-air respirator with a full facepiece and operated in a pressure-demand or other positive-pressure mode in combinationwithan auxiliary self-contained breathing apparatus operated in a pressuredemand or other positive-pressure mode.

146

Chapter

Escape: Any air-purifying full facepiece respirator (gas mask) with a chinstyle or front- or back-mountedorganicvapor canister havingahighefficiency particulate filter. Any appropriate escape-type self-contained breathing apparatus. FirstAidSource: HCDB. Inhalation: Removevictimfromexposure.If breathing has stopped or is difficult, give artificial respiration and call physician. Ingestion: Call physician; inducevomitingandflowwith gastric lavage; treatment thereafter is symptomatic and supportive; avoid fats, oils, and lipid solvents, which enhance absorption; rigorously prohibit ethyl alcohol in all forms for at least 10 days; inform doctor if patient has used alcohol within 48 hr. Skin: Wash with water; if irritation persists, consult a physician. Eyes: Wash with water; if irritation persists, consult a physician. FirstAidSource: CHRISManual1991. Inhalation: Removevictimfromexposure;if breathing has stopped or is difficult, give artificial respiration and call physician. Eyes or skin: Wash with water; if irritation persists, consult a physician. Ingestion: Call physician; induce vomiting and follow with gastric lavage; treatment thereafter is symptomatic and supportive; avoid fats, oils, and lipid solvents, which enhance absorption; rigorously prohibit ethyl alcohol in all forms for at least 10 days; inform doctor if patient has used alcohol within 48 hr. FirstAidSource: DOT Emergency Response Guide 1993. In case of contact with material, immediately flush eyes with running water for at least 15 min.Wash skin withsoapand water. Removeand isolate contaminated clothing and shoes at the site.

--- INITIAL INCIDENT RESPONSE -FireExtinguishment: Water, dry chemical,carbon dioxide. (CHRIS91) U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. DOT ID Number: UN3077

Vulcanizing ERG90

147

* POTENTIAL HAZARDS *

GUIDE

*Health Hazards Contact may cause bums to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Some of these materials may bum, but none of them ignites readily.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Positive-pressure self-contained breathing apparatus (SCBA) and structural firefighters' protective clothing will provide limited protection. CALLCHEMTREC AT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Small fires: Dry chemical, COz, water spray, or regular foam. Large fires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. Do not scatter spilled material with high-pressure water streams. Dike fire-control water for later disposal. *Spill or Leak Stop leak if you can do it without risk. Small dry spills: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. Cover powder spill with plastic sheet or tarp to minimize spreading. *First Aid In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

Chapter

148

--IDENTIFIERS -Chemical Name and Synonyms: DIBENZOYL p-QUINONEDIOXIME Trade Name and Synonyms: ChemicalFamily:

Dibenzo GMF

Vulcanizingagent

Manufacturer: UniroyalChemicalCo.,Naugatuck,Connecticut UN IDNumber: NA

--INGmDIENTS AND COMPOSITION DATA -No.

%

Cas Material Dibenzoyl p quinonedioxime

NA

99.9

PHYSICAL DATA

TLV -

Not established

--

BoilingPoint (“F): NA SpecificGravity (H,O = 1): 1.34 Vapor Pressure (mm Hg): NA Percent Volatile by Volume

Not volatile

VaporDensity(air = 1): NA FreezingPoint:

NA

EvaporationRate: NA p H Not corrosive Solubility in Water: Insoluble in water and organic solvents MeltingPoint: Decomposesabove175°F Appearance/Color/Odor: Brownishgreypowder.

Vulcanizing Agents

149

--FIRE AND EXPLOSION HAZARDS FlashPoint: Over 175OF (Decomposes) FlammabilityLimits: NA Autoignition: NA Extinguishing Media: Foam or water spray, dry chemical, carbon dioxide. Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuatenonessential personnel from the fire area. Firefighters shouldwear full-face, selfcontainedbreathingapparatusandimperviousprotective clothing such as gloves, hoods, suits, and rubber boots. Use water fog, dry chemicals, or carbon dioxide to extinguish fires involving this material.Solidstreamsofwatershouldnot be usedbecauseof the possibility of dispersing dust clouds of sulfur in the air, possibly causing an explosion.Coolthe surrounding areawithwater fog to prevent ignition. Fires will rekindle before the mass is cooled down below 428OF (220°C). Note that this product will bum in the absence of air once it is ignited. Use water to coolbelow the autoignitiontemperature. Fires involving several containers should be approached with caution because of violent burning as containers rupture.

Unusual Fire and Explosion Hazards:Do not use weldingor cutting torch on or near any container ofthis material, even empty, because an explosion could occur. Do not use, pour, spill, or store near heat or open flame. Hazardous Products of Combustion and Decomposition: Toxic fumes. HazardousPolymerization: Willnot occur.

- HEALTH HAZARD DATA Effects of Overexposure: Principal routes of exposure are skin contact and inhalation. Slight irritation potential reported by the manufacturer. Ingestion of the product inlarge quantities may cause milddigestive disorders, including diarrhea.

Chapter

150

There are no data available that address medicalconditions that are generally recognized as being aggravated by exposure to this product.

Emergency Response and First Aid: Skin: Flushallaffectedareaswith plenty ofwater for several minutes. Removeand clean anycontaminated clothing and shoes. Seekmedical attention if skin irritation occurs. Eyes: Flush the eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If swallowed, immediately giveseveral glasses of water and induce vomitingbygagging the victimwitha finger placed on the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth.

--TOXICITY DATA -AnimalEffects: Notoxicology studies reported, butproducthasbeen commercial use for over 25 years. REACTIVITY DATA

in

--

Stability and Conditions to Avoid: Heat, open flames. Materials to Avoid (Incompatibility): None reported by the manufacturer. HazardDecompositionProducts:

Unknown.

HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Sweep spillage; wash residuals with soap and water and transfer to a closed container. Waste Disposal Method:

Same as for organic chemicals.

Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container.

Vulcanizing Agents

151

--SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection:Appropriate respirator selected and usedin accordance with OSHA Subpart I (29 CFR 1910.134) and manufacturer’s recommendations is required if airborne dust is not adequately controlled or if excessive fumes are generated from product decomposition. Self-contained breathing apparatus shouldbeworn in highvaporanddust concentrations. Under normal use, manufacturer recommends a dust mask. Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves andOther: Impervious gloves andclothing should be worn. Manufacturer recommends rubber gloves be used. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup and dispersion. OtherPrecautions: Use all standard practices for goodpersonalhygiene. Completely isolate and thoroughly clean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Note that this product will bum.

--REGULATORY INFORMATION --Refer to DOT shipping regulations.

Chapter

152

--IDENTIFIERS -Chemical Name and Synonyms: HEXAMETHYLENJZDIAMINE CARBAMATE Trade Name and Synonyms: ChemicalFamily:

Diak No. 1

VulcanizingAgent

Manufacturer: E. I. du Pont de Nemours & Co.,

Wilmington, Delaware

UN ID Number: NA

--

JNGREDIENTS AND COMPOSITION DATA

Material Not

No.

Cas

%

100 Hexamethylenediamine NA carbamate

BoilingPoint (“F):NA SpecificGravity (H,O = 1): 1.28 NA

Percent Volatile by Volume (%): NA VaporDensity(air = 1): NA FreezingPoint:

NA

EvaporationRate:

NA

p H NA

Solubility in Water:

TLV established

--- PHYSICAL DATA --

VaporPressure(mmHg):

---

Soluble in water

MeltingPoint: Above154°C (309°F)

Vulcanizing

153

Appearance/Color/Odor: Very fine whitepowder. Slight amine odor.

--FJRE AND EXPLOSION HAZARDS -(30O0F,open cup method)

Flash Point: Above FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Foam or water spray, dry chemical, carbon dioxide, standard fire extinguishers. Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontainedbreathing apparatus andimpervious protective clothing such as gloves, hoods, and suits. Unusual Fire and Explosion Hazards:Do not use welding or cutting torch on or near anycontainer of this material, even empty, because an explosion could occur. Do nor use, pour, spill, or store near heat or open flame. May form flammable dust-air mixture. Keep dust awayfrom heat, sparks, andopen flames. Use only in areas provided with grounded equipment. Hazardous Products of Combustion and Decomposition: Toxic fumes. HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA -Effects of Overexposure: Principal routes of exposure are skin contact and inhalation. Causes irritation to skin and eyes. Harmfulifswallowed. Emergency Response and First Aid: Skin: Flushallaffected areas withplentyofwater for several minutes. Removeandcleananycontaminated clothing and shoes. Seekmedical attention if skin irritation occurs. Eyes: Flush the eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs.

Chapter

154

Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If swallowed, immediately giveseveral glasses of water and induce vomitingbygagging the victimwitha finger placed the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting give anything by mouth. Cancer Information: Not listed as a carcinogen byNTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research Cancer).

--TOXICITY DATA --Animal Effects: No toxicology studies reported.

--REACTIVITY DATA -Stability and Conditions to Avoid: Heat,open flames. Undernormal use, this material is stable. Materials to Avoid (Incompatibility): None reported by the manufacturer. HazardDecompositionProducts:

Unknown

HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Do not sweep because this may create a dust hazard. Instead, up in oil dry or absorbent material. Flush spill area with water. Waste Disposal Method: Dispose of in accordance withfederal, state, and local regulations. Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the riskof injury, donot cut, puncture, or weld or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: Appropriate respirator selected and used in accordancewithOSHASubpart I CFR andmanufacturer’s

Vulcanizing

155

recommendations is required if airborne dust is not adequately controlled or if excessive fumes are generated from product decomposition. Self-contained breathing apparatus should be worn in high vapor and dust concentrations. Under normal use, manufacturer recommends a dust mask.

Type of Ventilation Required: Generalmechanical.Avoidbreathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemicalgoggles.Eyewash safety showers should be easily accessible.

fountains and

Protective Gloves andOther: Impervious gloves andclothing should be worn. Manufacturer recommends rubber gloves be used. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Note that this product will bum.

--REGULATORY INFORMATION -Refer to DOT shipping regulations. v

v

v

v

v

v

v

v

v

v

v

v

--- IDENTIFIERS -Chemical Name and Synonyms: n,n'-DICINNAMYLIDENJ"6HEXANEDIAMINE Trade Name and Synonyms: Diak No. ChemicalFamily: VulcanizingAgent

v

v

Chapter

156

Manufacturer: E. I. du Pont de Nemours & Co., Inc., Wilmington, Delaware

UN ID Number: NA

No.

Cas

--INGREDIENTS AND COMPOSITION DATA -Material % m

Disk No. 3

NA

established Not

- PHYSICAL DATA -Boiling Point ("F): NA SpecificGravity (H,O =

1.09

VaporPressure(mm Hg): NA Percent Volatile by Volume VaporDensity(air =

NA

NA

Reezing Point: NA EvaporationRate:

NA

pH: NA Solubilityin Water: Insoluble MeltingPoint:

180" to

190°F

Appearance/Color/Odor: Tan powder.Cinnamon

odor.

- FIRE AND EXPLOSION HAZARDS Flash Point: Over 300"F, open cup method FlammabilityLimits:

NA

Extinguishing Media: Foam or water spray, dry chemical, carbon dioxide, standard fire extinguishers.

Vulcanizing

157

Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontainedbreathing apparatus andimpervious protective clothing such as gloves, hoods, and suits. Unusual Fire and Explosion Hazards:Do not use welding or cutting torch or near anycontainer of this material, even empty, becausean explosion could occur. Do not use, pour, spill, or store near heat or open flame. May form flammable dust-air mixture. Keep dust awayfrom heat, sparks, andopen flames. Use only in areas provided with grounded equipment. Hazardous Products of Combustion and Decomposition: Toxic fumes. HazardousPolymerization: Willnot occur.

- HEALTH HAZARD DATA Effects of Overexposure: Principal routes of exposure are skin contact and inhalation. Causes irritation to skin and eyes. Harmfulifswallowed. Emergency Response and First Aid: Skin: Flush all affected areas withplentyofwater for several minutes. Removeand clean anycontaminated clothing and shoes. Seekmedical attention if skin imtation occurs. Eyes: Flush the eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye imtation occurs. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If swallowed, immediately giveseveral glasses of water and induce vomitingbygagging the victimwitha finger placed on the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Not listed as a carcinogen byNTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

158

Chapter

--TOXICITY DATA -Animal Effects: Lethal concentration of inhaled dust for rats is 6.2 mg/l of air for 4 hr of exposure.

--REACTIVITY DATA -Stability and Conditions to Avoid: Heat, openflames. this material is stable.

Under normal use,

Materials to Avoid (Incompatibility): None reported by the manufacturer. HazardDecompositionProducts:

Unknown

Hazardous Polymerization: Will not occur.

--- SPILL AND EMERGENCY RESPONSE --For Spills: Do not sweep because this may create a dust hazard. Instead, up in oil dry or absorbent material. Flush spill area with water. Waste Disposal Method: Dispose of in accordance with federal, state, and local regulations. Empty Containers: The container for this product can presentexplosion or fire hazards,evenwhenemptied. To avoid the risk of injury, do not cut, puncture, weld or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: Respiratory Protection: Appropriate respirator selected and usedin accordance with OSHA Subpart 1(29 CFR 1910.134) and manufacturer’s recommendationsis required if airborne dust is not adequately controlled or if excessive fumes are generated from product decomposition. Self-contained breathing apparatus should be worn in high vapor and dust concentrations. Under normal use, manufacturer recommends a dust mask.

of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations.

.

159

Vulcanizing

EyeProtectionRequirements: Chemicalgoggles.Eyewashfountainsand safety showers should be easily accessible. Protective Gloves and Other:Impervious gloves andclothing should be worn. Manufacturer recommends rubber gloves be used. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. OtherPrecautions: Useallstandardpractices for goodpersonalhygiene. Completelyisolateandthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keepareaclean.Notethat this product will bum.

--REGULATORY INFORMATION --Refer to DOT shipping regulations.

--- IDENTIF'IERS -Chemical Name and Synonyms: POLY-DISPERSION OF LEAD OXIDES Trade Name and Synonyms: Poly-Dispersion (TLD-90 and ERD-90) Chemical Family: Dispersion of Lead Oxide Manufacturer: WyroughandLoser,

Inc., Trenton, New Jersey

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA--%

Cas Material Proprietary Dispersion

NA

TLV -

established Not

160

Chapter

--PHYSICAL DATA -BoilingPoint (“F): Specific Gravity (H,O = 1): Over VaporPressure(mmHg): Percent Volatile byVolume (%): VaporDensity(air = 1): FreezingPoint: EvaporationRate: pH

Solubility inWater:

Slight

MeltingPoint: Appearance/Color/Odor: Yellow or Red-Rubbery Solid with little or no odor.

--- FIRE AND EXPLOSION HAZARDS --Flash Point: Over 400°F, open cup method FlammabilityLimits: AutoignitionTemperature: Extinguishing Media: Foam or water spray, dry chemical, carbon dioxide, standard fire extinguishers. Special Fire Fighting Procedures: in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontained breathing apparatus andimpervious protective clothing such as gloves, hoods, and suits.

Vulcanizing

161

Unusual Fire and Explosion Hazards:Do not use welding or cutting torch or near anycontainer of this material, even empty, because an explosion could occur. Do not use, pour, spill, or store near heat or open flame. May form flammable dust-air mixture. Keep dust awayfrom heat, sparks, andopen flames. Use only in areas provided with grounded equipment. Hazardous Products of Combustion and Decomposition: Toxic fumes. Hazardous Polymerization: Will not occur.

--HEALTH HAZARD DATA -Effects of Overexposure: The form of the material is a dispersion in polymer matrix, and hence normal handling precludes conditions of overexposure. Emergency Response and First Aid: Skin: Flush all affected areas with plenty ofwater for several minutes. Removeand clean anycontaminated clothing and shoes. Seekmedical attention if skin irritation occurs. Eyes: Flush the eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If swallowed, immediately giveseveral glasses of water and induce vomitingbygagging the victim witha finger placed the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Not listed as a carcinogen byNTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--TOXICITY DATA --AnimalEffects: None reported.

--REACTIVITY DATA -StabilityandConditions to Avoid: Heat, open flames. Undernormal use, this material is stable. Avoid contact with mineral acids.

162

Chapter

Materials to Avoid (Incompatibility): None reported by the manufacturer. Hazard Decomposition Products: 800°C.

Lead and lead oxide at temperatures over

HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE

--

For Spills: No special proceduresrecommended. Waste Disposal Method: Dispose of in accordance with federal, state, and local regulations. Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. avoid the risk of injury, do not cut, puncture, or weld on or near this container.

- SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: Wear dust and/or appropriate fume respirator. Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves andOther: Impervious gloves andclothing should be worn. Manufacturer recommends rubber gloves be used. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughlyclean all equipment, piping, or vessels

Vulcanizing before beginningmaintenance or repairs. Keepareaclean.Notethat product will bum.,

- REGULATORY INFORMATION -Refer to DOT shipping regulations.

--IDENTIFIERS Chemical Name and Synonyms: VULCANIZED VEGETABLE Trade Name and Synonyms: ChemicalFamily:

OIL

Factice White 57

NA

Manufacturer: AmericanCyanamid Co., BoundBrook,NewJersey

UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA -%

No. Cas Material NA

established

--PHYSICAL DATA -BoilingPoint (“F‘): NA SpecificGravity (H,O = 1): 1.28 VaporPressure(mm Hg): NA Percent Volatile byVolume (%): Negligible VaporDensity(air FreezingPoint:

= 1): NA

NA

EvaporationRate:

NA

TLV Not

this

Chapter

164

p H NA Solubilityin Water: Negligible MeltingPoint:

NA

Appearance/Color/Odor: Whitepowder, slight oily odor.

--FIRE AND EXPLOSION HAZARDS FlashPoint: NA FlammabilityLimits: NA Autoignition: NA Extinguishing Media: Foam or water spray, dry chemical, carbon dioxide, standard fire extinguishers. Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuatenonessential personnel from the fire area. Firefighters shouldwearfull-face,selfcontainedbreathingapparatusandimperviousprotective clothing such as gloves, hoods, and suits. Do not use high-pressure water streamas air-borne dust creates an explosion hazard. Unusual Fire and Explosion Hazards:Do not use weldingor cutting torch on or near any containerof this material, evenempty, because an explosion could occur. Do not use, pour, spill, or store near heat or open flame. May form flammabledust-airmixture. Keep dust away from heat, sparks, andopen flames. Use only in areas provided with grounded equipment. The hazard is similar to that of any organic solid including sawdust. Hazardous Products of Combustion and Decomposition: Sulfur dioxide may be formed under fire conditions. Hazardous Polymerization: Will not occur.

--HEALTH HAZARD DATA Effects of Overexposure: None expected.

Vulcanizing

165

Emergency Response and First Aid: Skin: Nonerecommended. Eyes: Nonerecommended. Inhalation: None recommended, but author advisesa minimum protection of dust mask. Ingestion: If swallowed, immediately give several glasses of water and induce vomitingbygaggingthevictimwith a fingerplaced on the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Not listed as a carcinogen by NTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--TOXICITY DATA -AnimalEffects: None reported.

--REACTIVITY DATA -Stability and Conditions to Avoid: Heat, open flames. Under normal use, this material is stable. Materials to Avoid (Incompatibility): None reported by the manufacturer. Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide, carbon dioxide, and/or sulfur dioxide. Hazardous Polymerization: Will not occur.

--- SPILL AND EMERGENCY RESPONSE --For Spills: Sweep up and place in a waste disposal container. Flush area with water. Waste Disposal Method: Dispose of in accordance with federal, state, and local regulations. Empty Containers: The containerfor this product can present explosionor fire hazards, evenwhenemptied.Toavoid the risk of injury, do not cut, puncture, or weld on or near this container.

166

Chapter

--SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection:

Wear dust and/or appropriate fume respirator

Type of VentilationRequired: Generalmechanical.Avoidbreathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemicalgoggles.Eyewash safety showers should be easily accessible.

fountains and

Protective Gloves and Other:Impervious gloves andclothing should beworn. Manufacturer recommends rubber gloves be used. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. OtherPrecautions: Useallstandardpractices for goodpersonalhygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keepareaclean.Notethat this product will bum.

- REGULATORY KNFORMATION Refer to DOT shipping regulations.

--IDENTIFIERS -Chemical Name and Synonyms: Trade Name and Synonyms: ChemicalFamily:

NONE; PROPRIETARY MIXTURE

Ferro Therm-Chek 6-V6A

Barium,Cadmium, Zinc Compound

Manufacturer: Ferro Corp., Bedford,Ohio

Vulcanizing

167

UN ID Number: NA

--

INGREDIENTS AND COMPOSITION DATA

Material

No.

Cas

%

m Not established

Unknown

phenol

--

5.6

Not established

Aromatic solvent

NA

Aliphatic solvent

NA

20

500 ppm

Alkyl

NA

<4

Not established

<3

Not established

<5

Not established

Cadmium Barium

NA

Alkyl-aryl phosphate esters

NA

30

--- PHYSICAL DATA --BoilingPoint ("F): >300"F SpecificGravity (H,O = 1): 1.03 VaporPressure(mm Hg): NA Percent Volatile by Volume (%): 36 = 1): 3.9

VaporDensity(air FreezingPoint:

NA

EvaporationRate:

NA

p H NA

SolubilityinWater: MeltingPoint:

NA

Negligible

Not established

Chapter

168

Appearance/Color/Odor: Clear, amber liquid with mineral spirits odor.

- FIRE AND EXPLOSION HAZARDS -FlashPoint:

120°F (TOC)

FlammabilityLimits: LEL 0.9; UEL: AutoignitionTemperature:

NA

Extinguishing Media: Foam or water spray, dry chemical, carbon dioxide, standard fire extinguishers. Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke, fumes, or products of combustion.Evacuatenonessential personnel from the fire area. Firefighters shouldwear full-face, selfcontained breathing apparatus and impervious protective clothing such as gloves, hoods, and suits. Unusual Fire and Explosion Hazards:Do not use weldingor cutting torch on or near any container of this material, even empty, because an explosion could occur. Do not use, pour, spill, or store near heat or open flame. HazardousProducts of CombustionandDecomposition: barium will be in ash.

Cadmiumand

Hazardous Polymerization: Will not occur.

--HEALTH HAZARD DATA Effects of Overexposure: Solvent vapors have a TLV of 500 ppm. Nonvolatile portions are toxic if ingested. Overexposure effects includenarcosis from solvent vapors. Skin contact can cause dermatitis. Emergency Response and First Aid: Skin: Wipe well withcloth dampened in alittle mineral oil, followed by soap and water wash. Eyes: Flush eyes with lots of water. If irritation persists, consult aphysician. Inhalation: Give victim fresh air or oxygen.Consultphysician. Material should be used in a well-ventilated area. Ingestion: If swallowed, immediatelygive several glassesof water and induce vomiting by gagging the victim with a finger placed on the backof the

Vulcanizing

169

victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Immediately consult a physician to treat as barium and cadmium poisoning.

Cancer Information: Not listed as a carcinogen byNTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--TOXICITY DATA Animal Effects: Numerous effects reported for heavy metal poisoning, such as barium and cadmium. Consult CHRIS, NIOSH, OSHA.

--REACTIVITY DATA -Stability and Conditions to Avoid: Heat,openflames.Undernormal this material is stable.

use,

Materials to Avoid (Incompatibility): None reported by the manufacturer. Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide and carbon dioxide. Cadmium and barium residuals in ash. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE For Spills: Use appropriate absorbent to stabilize andsweep into disposal container. Waste Disposal Method: Dispose of in accordance with federal, state, and local regulations. Empty Containers: The container for this product can present explosionor fire hazards, evenwhenemptied. To avoid the risk of injury, donot cut, puncture, or weld on or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: respirator.

Wear NIOSH-approved chemical

cartridge-type

Chapter

170

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves andOther: Impervious gloves and clothing should be worn. Manufacturer recommends rubber gloves be used. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Notethat this product will bum.

- REGULATORY INFORMATION -None reported.

4 ACCELERATORS AND ACTIVATORS The types of chemicals coveredin this section are listed below. The information in this section is organized by chemical name, as in other parts of this book.

CHEMICAL NAME/

CHEMICAL FAMILY

TRADE NAMES

SYNONYMS Calcium oxide, lime, quicklime

Alkaline earth

Desical P

Magnesium aluminum hydroxy carbonate

Alkaline earth

Hysafe 510

Talc, hydrous magnesium Silicate

Silicates

Mistron Compound

Azodicarbonamideazobisformamide

Azo amide

Kempore-200

Azodicarbonamideazobisformamide

Azo amide

Kempore 60

Diethylene glycol

Dihydroxyethyl ether

Diglycol

Cupric dimethyldithiocarbamate

Dithiocarbamate

Cumate

Zinc diethyldithiocarbamate

Dithiocarbamate

Ethyl Zimate

171

172

Chapter 4

Nickel dibutyldithiocarbamate

Dithiocarbamate

NBC

Bismuth dimethyldithiocarbamate

Dithiocarbamate

Bismate

Zinc dibutyldithiocarbamate

Dithiocarbamate

Butyl Zimate

Zinc dimethyldithiocarbamate

Dithiocarbamate

Methyl Zimate

Selenium dimethyldithiocarbamate

Dithiocarbamate

Methyl Selenac

Lead dimethyldithiocarbamate

Dithiocarbamate

Methyl Ledate

Tellurium diethyldithiocarbamate

Dithiocarbamate

Ethyl Tellurac

Cadmium diethyldithiocarbamate

Dithiocarbamate

Ethyl Cadmate

Zinc salt of stearic acid

Metal soap

U.S.P. S-l271 DE-IO, DLG-20 Zinc Stearate

Di-ortho-tolylguanidine

Guanidine

DOTG Accelerator

Copper mercaptobenzothiazole

Thiazole

Cupsac Accelerator

Thiram

Thiuram

MOTS No. 1 Accelerator

Tetramethylthiuram

Thiuram

Monex

Hexamine

Aliphatic amine

Accelerators

173

TRADE NAMES

CHEMICAL NAME/ CHEMICAL FAMILY SYNONYMS Zinc ethylphenyldithiocarbamate

Organic acid

salt

Cadmium diethyldithiocarbamate

Organic acid

salt

Azole 2-Benzothiazolethiol

Captax, MBT

2-Benzothiazolethiol, acid Organic zinc salt

salt

Bis(Dimethylthiocarbamy1) Sulfide Organic disulfide

ZMBT TETD

..

1,3-Diphenyl-2-thiourea accelerator Rubber A-l Carbamide

BIK

Zinc dibenzyldithiocarbamate Arazate Accelerator 1,3-Diphenyl DPG Guanidine guanidine

--IDENTIFIERS -Name:CALCIUM OXIDE Synonyms: BurntLime;Calcia;CalciumOxide(DOT);Calx;Lime;Lime, Burned; Lime, Unslaked (DOT); Oxyde De Calcium (French); Quicklime; Quicklime (DOT); Wapniowy Tlenek (Polish); Pebble Lime CAS: 1305-78-8; RTECS: EW3100000 Formula: CaO; Mol Wt: 56 WLN: CA ChemicalClass: Metaloxide See other identifiers listed below under Regulations.

174

Chapter

--

PROPERTIES

---

Physical Description: White, gray, or yellowpowder.Colordepends amountof impurities present. (NYDH) Boiling Point: 3123.13 K;2849.9"C;5161.9"F Melting Point: 2843.13 K;2569.9"C; 4657.9"F FlashPoint: NA Autoignition: NA VaporPressure: 0 mm UEL: NA LEL: NA Vapor Density:No data Specific Gravity: 3.3 at 20°C Density: 3.300 Water Solubility: Reacts,producingheat Incompatibilities: Water

on

Reactivity with Water: Heatmaycause ignition of combustibles. Material swells during reaction. Reactivity with Common Materials: No reaction unless water present; then chief effect is that of heat liberated. Stability during Transport: No data Neutralizing Agents:No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors. Odor Detected at (ppm): Not pertinent Odor Description: Odorless(Source:CHRIS) 100% Odor Detection: No data

--REGULATIONS --DOT hazard class: 8 CORROSIVE DOT guide: 60 Identificationnumber: UN1910 DOT shipping name: Calcium oxide Packinggroup: 111 Label($required: CORROSIVE Packaging exceptions:173.154 Nonbulk packaging: 173.213 Bulkpackaging: 173.240

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175

Quantity limitations: Passenger airhail: 25 kg Cargo aircraft only: 100 kg Vesselstowage:A STCCNumber:4944515 CleanWaterAct Sect. 307: No Clean WaterAct Sect. 311: No CleanAirAct: Not listed EPAWasteNumber: None CERCLA Ref: Not listed RQDesignation: Not listed SARATPQValue: Not listed SARA Sect. 312 Categories: Acute toxicity: adverse effect to target organs. Reactive hazard: water reactive. U.S. Postal Service Mailability: Hazard class: ORM-B Mailability: Domestic service and air transportation; shipper’s declaration Max per parcel: 25 lb; 5 lb

NFPA Codes: HealthHazard(blue): (1) Slightly hazardous to health. Asa precaution wear self-contained breathing apparatus. Flammability (red): Thismaterialdoesnot readily bum. Reactivity(yellow):(1) Normally stable, butmaybecome unstable at elevated temperature and pressures. Special: Unspecified.

- TOXICITY DATA -Short-termToxicity: Inhalation: Maycause sneezing, coughing,inflammation of respiratory system, bronchitis, pneumonia, and mouth and nosesores. May cause both heat bums and chemical bums to the nose and throat. Skin: Maycauseboth heat andchemical bums, sores, and scarring. Severity of symptoms increased if skin is wet. Eyes: May cause both heat and chemical bums, sores, scarring, holes, irritation, andpermanent injury. Ingestion: May cause both heat and chemical bums to the mouth, throat, and stomach. Estimated lethal dose is g (1.2 (NYDH)

Chapter 4

176

Long-term Toxicity: May cause thickening, scaling, and cracking of the skin, brittleness and cracking of fingernails; eye irritation, bronchitis and pneumonia. (NYDH) Target Organs: Respiratorysystem, skin, eyes. Symptoms: Causes bums on mucous membrane and skin. Inhalation of dust causessneezing.(Source:CHRIS) Conc IDLH Unknown ACGIHTLV: TLV = 2 mg/m3 ACGIHSTEL: Not listed

OSHA PEL: Transitional Limits: PEL = 5 mg/m3; Final Rule Limits: TWA = 5 mg/m3. The final rule limit TWA of 5 mg/m3 is in effect as a RES. MAK Information: 5 calculated as total dust mg/m3; Local 2xMAK for 5 min., 8 times per shift.

irritant: Peak =

Carcinogen: N CarcinogenLists: Z A R C Not listed; M A K Not listed; NZOSH Not listed; M P : Not listed; ACGZE Not listed; OSHA: Not listed. LD50 Value: NoLD50inRTECS Reproductive Toxicity (1992 RTECS): This chemical has no known mammalian reproductive toxicity.

--- PROTECTION AND FIRST AID -Protection Suggested from the CHRIS Manual: Protective gloves, goggles, and any type of respirator prescribed for fine dust. NIOSH Pocket Guide to Chemical Hazards: **Wear Appropriate Equipment to Prevent: Reasonable probability ofskin contact. **Wear Eye Protection to Prevent: Any possibility of eye contact.

Accelerators and Activators

**Exposed Personnel Should Wash: Promptly when contaminated and at the end of each work shift.

177

skin becomes

**Work Clothing Should Be ChangedDaily: If there is any reasonable possibility that the clothing may be contaminated. **Remove Clothing:Promptly remove nonimperviousclothing that becomes contaminated. **The Following Equipment Should Be Made Available: Eyewash, quick drench. **Reference: NIOSH Recommended Respiration Protection Source: NIOSH Pocket Guide(85-1 14) ACGIH(Calcium oxide) I0 m g / d : Any dust and mist respirator. 20 mg/m3: Any dust and mist respirator except single-use and quarter-mask respirators. Any supplied-air respirator. Any self-contained breathing apparatus. 50 m g / d : Any powered air-purifying respirator withahigh-efficiency particulate filter. Any supplied-air respirator operated in a continuous-flow mode. ZOO m g / d : Any air-purifying full facepiece respirator with a high-efficiency particulate filter. Any self-containedbreathing apparatus with afull facepiece. Any supplied-air respirator with a full facepiece. Any powered air-purifying respirator with atight-fitting facepiece and a high-efficiencyparticulate filter. 250 mg/m3: Any supplied-air respirator with a half-mask and operated in a pressure demand or other positive-pressure mode. Emergency orplanned entry in unknown concentrations or IDLH conditions: Any self-contained breathing apparatus with a full facepiece and operated in pressure-demand a or other positive-pressure mode. Any supplied-air respirator with a full facepiece and operated in a pressure-demand or other positive-pressure mode in combinationwith an auxiliary self-contained breathing apparatus operated in a pressuredemand or other positive-pressure mode. Escape: Any air-purifying full facepiece respirator witha high-efficiency particulate filter. Any appropriate escape-type self-contained breathing apparatus.

178

Chapter 4

FirstAidSource: CHRISManual1991. Ingestion: If victim is conscious, havehimdrinkwater or milk. Do not induce vomiting. Skin and Eyes: Flush with water and seek medical help. FirstAidSource: DOT Emergency Response Guide 1993. Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min.Removeand isolate contaminated clothing andshoes at the site. Keep victim quiet and maintain normal body temperature.

--INITIAL INCIDENT RESPONSE -Fire Extinguishment: Extinguish adjacent fires with dry chemical or carbon dioxide. Note: Donotusewater adjacent fires. (CHRIS91) U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOTShippingName: CALCIUMOXIDE DOT ID Number: UN1910

ERG90

* POTENTIAL HAZARDS *

GUIDE 60

*Health Hazards Contact causes bums to skin and eyes. If inhaled, may be harmful. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Some of these materials may bum, but none of them ignites readily. Flammable/poisonous gases may accumulate in tanks and hopper cars. Some of these materials may ignite combustibles (wood, paper, oil, etc.).

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection.

Accelerators and Activators

179

CALLCHEMTRECAT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities. *Fire Some of these materials may react violently with water. Small fires: Dry chemical, COz, water spray, or regular foam. Lurgefires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. *Spill or Leak Do not touch spilled material; stop leak if you can do it without risk. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small dry spills: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal.

*First Aid Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

--IDENTIFIERS --Chemical Name and Synonyms: MAGNESIUM ALUMINUM HYDROXY CARBONATE Trade Name and Synonyms: Hysafe 510 ChemicalFamily: AlkalineEarth Manufacturer: Havre de Grace,Maryland UN ID Number: NA

Chapter 4

INGREDIENTS AND COMPOSITION DATA Material

Cas No.

TLV

%

Magnesium Aluminum Hydroxy Carbonate

-

Not established

--PHYSICAL DATA BoilingPoint (“F): NA SpecificGravity (H20= 1): VaporPressure(mmHg):

NA

Percent Volatile by Volume (%): NA VaporDensity(air = FreezingPoint:

NA

NA

EvaporationRate:

NA

p H NA Solubilityin Water: Insoluble MeltingPoint:

NA

Appearance/Color/Odor: Whitepowder, no odor.

--FIRE AND EXPLOSION H A Z A R D S -FlashPoint: None(Thermallydegradesattemperatures FlammabilityLimits:

NA

AutoignitionTemperature:

NA

Extinguishing Media: Foam or water spray, dry chemical, carbon dioxide, standard fire extinguishers.

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181

Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontained breathing apparatus andimpervious protective clothing such as gloves, hoods, and suits. Unusual Fire and Explosion Hazards:

None reported by manufacturer.

Hazardous Products of Combustion and Decomposition: Reacts with acids, forming carbon dioxide. Manufacturer provides no information on products of combustion. Hazardous Polymerization: Will not occur.

- HEALTH HAZARD DATA -Effects of Overexposure: This is an experimental product and no health data have been reported by the manufacturer. It has been noted that prolonged contact with this material may cause irritation to skin and mucous membranes. There are no other known medical conditions aggravatedbyprolonged exposure at this time.

Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Givevictim fresh air or oxygen.Consult physician. Material should be used in a well-ventilated area. Ingestion: If swallowed, immediately giveseveral glasses of water and induce vomitingbygagging the victim witha finger placed the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Not listed as a carcinogen byNTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--TOXICITY DATA -Animal Effects: No toxicity data could be found on this product.

Chapter 4

--REACTIVITY DATA --Stability and Conditions to Avoid: Heat,openflames.Undernormal use, this material is stable. Productwillreactwith acids, producingcarbon dioxide gas. Materials to Avoid (Incompatibility): Acids. Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide and carbon dioxide. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE --ForSpills: Use appropriate absorbent to stabilize andsweep into disposal container. Waste Disposal Method: Sweep up and remove as for any inert solid material, such as sand or soil. Empty Containers: The container for this product canpresent explosion fire hazards, evenwhenemptied. avoid the riskof injury, do not cut, puncture, or weld on or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection: Dust respirator as appropriate. Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemicalgoggles.Eyewash safety showers should be easily accessible.

fountains and

Protective Gloves andOther: Impervious gloves andclothing should be worn, although manufacturer makes no specific recommendation. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of

Accelerators and Activators

183

heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Do not mix or expose to acids. Other Precautions: Useallstandardpractices for goodpersonal hygiene. Completely isolate and thoroughly clean all equipment, piping, or vessels before beginningmaintenance or repairs. Keep area clean. withany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--

REGULATORY INFORMATION

---

None reported.

--- IDENTIFIERS -Name: TALC (NONASBESTOS FORM) Synonyms: Hydrous Magnesium Silicate; Steatite Talc; Non-Fibrous Talc; Non-Asbestiform Talc CAS:14807-96-6; RTECS: VV8790000 Formula: H,O,Si.3/4 Mg; Mol Wt:295 WLN: .MG4.SI-03*3 See other identifiers listed below under Regulations.

--PROPERTIES --PhysicalDescription: Odorless solid BoilingPoint: MeltingPoint: 1173.15 K; 900°C;1652°F FlashPoint: NA Autoignition: NA Vapor Pressure: About 0 mm UEL: NA LEL: NA Vapor Density: No data SpecificGravity: No data Water Solubility: INSOL Incompatibilities: Nonehazardous

Chapter 4

184

Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire None reported other than possible unburned vapors. Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: Not given Packaging exceptions: Nonbulkpackaging: Bulkpackaging: 173. STCC Number: Not listed Clean Water ActSect. 307: No Clean Water ActSect. 311: No Clean Air Act:Not listed EPA WasteNumber: None CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant.

U.S. Postal Service Mailability:

Notgiven

NFPA Codes: Health Hazard (blue):Unspecified Flammability(red): Unspecified Reactivity (yellow):Unspecified Special: Unspecified

--TOXICITY DATA --Short-termToxicity:

Unknown

185

Accelerators and Activators

Long-termToxicity:

Unknown

Symptoms: Fibriotic Pneumoconiosis.(Source:NIOSHP) Conc IDLH Unknown ACGIH TLV: TLV = 2 mg/m3 respirable dust (no fibers) ACGIHSTEL: Not listed

OSHA PEL: Transitional Limits: PEL = 20 MPPCF ppm; Final Rule Limits: TWA = (respirable dust), 2 mg/m3. MAK Information:

calculated as fine dust, mg/m3

Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not classified as to human carcinogenicity or probably not carcinogenic to humans; MAK: Not listed; NZOSH Not listed; N T P Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: No LD50 in RTECS 1992 Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

This chemical has

known

- PROTECTION AND FIRST AID -Recommended Respiration Protection Source: NIOSH Pocket Guide(85-1 14) ACGIH (Talc (Nonasbestos Form)) I0 mg/m’: Any dust and mist respirator. 20 m g / d : Any dust and mist respirator except single-use and quarter-mask respirators. Any supplied-air respirator. Any self-contained breathing appafatus. 50 mg/m3: Any powered air-purifying respirator with a dust and mist filter. Any supplied-air respirator operated in a continuous-flow mode. I O 0 mg/m3: Any air-purifying full facepiece respirator with a high-efficiency particulate filter. Anypowered air-purifying respirator witha tight-fitting facepiece and a high-efficiencyparticulate filter. Any self-containedbreathing apparatus witha full facepiece.Any supplied-air respirator witha full facepiece. Any supplied-air respirator with a tight-fitting facepiece operated in a continuous-flow mode.

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186

2000 mg/m3: Any supplied-air respirator with a half-mask and operated in a pressure-demand or other positive-pressure mode. 4000 mg/m3: Any supplied-air respirator with a full facepiece and operated in a pressuredemand or other positive-pressure mode. Emergency orplanned entry in unknown concentrationsor IDLH conditions: Any self-contained breathing apparatus with a full facepiece and operated in pressure-demand a or other positive-pressure mode. Any supplied-air respirator with a full facepiece and operated in a pressuredemand or other an auxiliary self-contained positive-pressure modeincombinationwith breathing apparatus operated in a pressuredemand or other positive-pressure mode. Escape: Any air-purifying full facepiece respirator witha high-efficiency particulate filter. Any appropriate escape-type self-contained breathing apparatus.

First AidSource: NIOSH Inhalation: Nonegiven Ingestion: Nonegiven Skin: Nonegiven Eyes: Irrigate immediately

--- INITIAL INCIDENT RESPONSE -No DOT Guide information for this product.

--IDENTIFIERS ChemicalNameandSynonyms: MAMIDE, CzH40zN4 Trade Name and Synonyms: ChemicalFamily:

AZODICARBONAMIDE-AZOBISFORKempore

Azo amide

Manufacturer: StepanChemicalCo.,Wilmington,Massachusetts

UN ID Number: NA

187

Accelerators and Activators

--- INGREDIENTS AND COMPOSITION DATA -Material

No.

Cas

TLV

% !

Azo amide

Not established

- PHYSICAL DATA -Boiling Point

447.8”F

SpecificGravity (H20= 1): NA Vapor Pressure (mm Hg):

1.2 at 200°C

Percent Volatile by Volume (%): NA VaporDensity(air FreezingPoint:

= 1):

NA

Evaporation Rate: NA p H NA

Solubilityin Water: Negligible MeltingPoint:

NA

Appearance/Color/Odor: No description givenbymanufacturer’sMSDS.

--FIRE AND EXPLOSION HAZARDS --FlashPoint: 170°F (TCC) FlammabilityLimits: NA Autoignition: NA Extinguishing Media:Foam or water spray, dry chemical,carbon dioxide, standard fire extinguishers.

Chapter 4

188

Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontainedbreathing apparatus andimpervious protective clothing such as gloves, hoods, and suits. Unusual Fire and Explosion Hazards: None reported by manufacturer. Hazardous Products of Combustion and Decomposition: Cyanuric acid. HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA -Effects of Overexposure: Maycause allergic reactions in extra-sensitive persons. Material is irritating to the eyes if contact is made. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Givevictim fresh air or oxygen.Consult physician. Material should be used in a well-ventilated area. Ingestion: If swallowed, immediately giveseveral glasses of water and induce vomitingbygagging the victimwitha finger placed on the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Not listed as a carcinogen byNTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--- TOXICITY DATA --Animal Effects: No toxicity data could be found on this product. Manufacturer states that the product is nontoxic.

- REACTIVITY DATA Stability and Conditions to Avoid: Heat, open flames. Undernormal use, this material is stable. Product will react with oxidizing agents. Materials to Avoid (Incompatibility): Oxidizing agents.

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189

Hazard Decomposition Products:Thermal decomposition may produce carbon monoxide and carbon dioxide. Hazardous Polymerization: Will not occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Sweep up and discard in an appropriate container. Waste Disposal Method: Sweep up and removeas for any inert solid material, such as sand or soil. Empty Containers: The container for this product can present explosionor fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: Dust respirator as appropriate. of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations.

EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Manufacturer makes no specific recommendation. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Do not mix or expose to acids. OtherPrecautions: Useall standard practices for goodpersonalhygiene. Completely isolate and thoroughly clean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

190

Chapter 4

--- REGULATORY INFORMATION --None reported.

--IDENTIFIERS -ChemicalNameandSynonyms: "E C,ZH4OZN4

AZODICARBONAMIDE-AZOBISFOR-

Trade Name and Synonyms: Kempore ChemicalFamily: Azoamide Manufacturer: StepanChemical Co., Wilmington,Massachusetts

UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA -No.

%

Cas Material

Azo amide

123-77-3

established

- PHYSICAL DATA --Decomposition Point CC):195 to 200 SpecificGravity (H,O = 1): 1.65 VaporPressure(mmHg):

None

Percent Volatile byVolume (%): NA VaporDensity(air = FreezingPoint:

NA

EvaporationRate: pH: NA

NA

NA

Not

191

Accelerators and Activators

Solubility inWater:

Insoluble

MeltingPoint: NA Appearance/Color/Odor: Yellow, odorless powder.

--- FIRE AND EXPLOSION H A Z A R D S --Flash Point: NA (Material does not support combustion andis self-extinguishing when the source of flame is removed). FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Foam or water spray, dry chemical, carbon dioxide, standard fire extinguishers. Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontained breathing apparatus andimpervious protective clothing such as gloves, hoods, and suits. Unusual Fire and Explosion Hazards:

None reported by manufacturer.

Hazardous Products of Combustion and Decomposition: Cyanuric acid. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA -Effects of Overexposure: Maycause allergic reactions in extra-sensitive persons. Material is irritating to the eyes if contact is made. Emergency Response and First Aid: Skin: Wash with lots clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Givevictim fresh air or oxygen.Consult physician. Material should be used in a well-ventilated area. Ingestion: If swallowed, immediately give several glasses of water and induce vomitingbygagging the victimwitha finger placed on the back of the

Chapter 4

192

victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth.

Cancer Information: Not listed as a carcinogen by NTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer). TOXICITY DATA Animal Effects: No toxicity data could be found er states that the product is nontoxic.

--this product. Manufactur-

--- REACTIVITY DATA --StabilityandConditions to Avoid: Heat, openflames.Undernormal this material is stable. Product will react with oxidizing agents.

use,

Materials to Avoid (Incompatibility): Oxidizing agents. Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide and carbon dioxide. HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE --For Spills: Sweep up and discard in an appropriate container. Waste Disposal Method: Sweep up and removeas for any inert solid material, such as sand or soil. Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: Dust respirator as appropriate. TypeofVentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust

Accelerators and Activators

193

concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations.

EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Manufacturer makes no specific recommendation. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Do not mix or expose to acids. OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughly clean allequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--- REGULATORY INFORMATION --None reported.

--- IDENTIFIERS -Name:GLYCOLETHER Synonyms: Bis(2-Hydroxyethyl) Ether; Brecolane NDG; Deactivator E; Deactivator H; DEG; Dicol; Diglycol; beta,beta’-Dihydroxydiethyl Ether; Dissolvant APV; Ethanol 2,2’-0xydi-; Ethylene Diglycol; Glycol Ether; GlycolEthyl Ether; 3-Oxapentane-l,5-Diol;3-0xa-1,5-Pentanediol; 2,2’Oxybisethanol; 2,2’-Oxydiethanol; T U N ; Diethylene Glycol; 2,2Dihydroxydiethyl Ether CAS: 111-46-6; RTECS: ID5950000 Formula: C,HloO,; MolWt: 106.14 WLN: 4 2 0 2 4 ChemicalClass: Glycol ether See other identifiers listed below under Regulations.

Chapter 4

194

--PROPERTIES -Boiling Point: 518.95 K;245.8"C; 474.4"F Melting Point: 265.15 K; -8°C;17.6"F Flash Point: 416.15 K; 143°C;289.4"F Autoignition: 418.15 K; 145°C;293°F Critical Temp: 681 K; 407.85"C;766.13"F Critical Press: 4.7 kN/m2; 46.3 atm; 680 psia Heat of Vap: 270 Btu/lb; 149.95 d / g ; 6 . 2 7 4 ~E5 J k g Heat of Comb: -9617 BtuAb; -5346 cal/g; -223x E5 J/kg Vapor Pressure: 1 mm at 9 1.8"C UEL: 10.8% LEL: 1.6% Vapor Density: 3.66 (air = 1) EvaporationRate:<0.01 (n-butylacetate = 1) Specific Gravity: No data Density: 1.1 18at 20/20 Water Solubility: Freely miscible Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: Acrid smoke and in fumes Odor Detected at (ppm): Not pertinent Odor Description: Practically odorless (Source:CHRIS) 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: Not given Packaging exceptions: 173. Nonbulk packaging: 173. Bulkpackaging: 173. STCC Number:

Not listed

Clean Water Act Sect. Clean Water ActSect. Clean Air Act:Notlisted

No No

195

Accelerators and Activators

EPAWasteNumber: None CERCLA Ref: N RQDesignation: Not listed SARA TPQValue: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant. Acute toxicity: adverse effect to target organs. Chronic toxicity: adverse effect to target organs after longperiodsof exposure. Chronic toxicity: reproductive toxin. U.S. Postal Service Mailability:

Not given

NFPA Codes: HealthHazard(blue): (1) Slightly hazardous to health. Asa precaution, wear self-contained breathing apparatus. Flammability (red): (1) This material must be preheated before ignition can occur. Reactivity (yellow): Stable evenunder fire conditions. Special: Unspecified.

--

TOXICITY DATA

Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

--

Target Organs: Skin, eyes, liver, kidneys Symptoms: Ingestion of large amounts may cause degeneration of kidney and liver andcause death. Liquid may cause slight skin irritation. (Source: CHRIS) Conc IDLH Unknown NIOSH REL: Not given

ACGIHTLV: Not listed ACGIHSTEL: Not listed WEEL(ACGIH): 50 ppm, total; 10 mg/m3, aerosol only (8-hr TWA) OSHA PEL: Not in Table

196

Chapter 4

MAK Information: Not listed Carcinogen: N; Status: Seebelow CarcinogenLists: ZARC: Not listed; M A E Not listed; NZOSH Not listed; NTP Not listed; ACGZH: Not listed; OSHA: Not listed. HumanToxicity Data: (Source:NIOSHRTECS) * orl-hmn LDLo:l g k g JIHTAB 21, 173, 39 LDS0Value: orl-rat LD50:12565mg/kg Other Species ToxicityData: (Source:NIOSH orl-rat LD50: 12565 mg/kg ipr-rat LD50:7700 mg/kg scu-rat LD50: 18800 mg/kg ivn-rat LD50:6565 mg/kg ims-rat LDLo:7826 mg/kg unr-rat LD50: 15650 mg/kg orl-mus LD50:23700 mg/kg ihl-mus LCLo: 130 mg/m3/2H ipr-mus LD50:9719 mg/kg scu-mus LDLo5 g/kg unr-mus LD50: 13300mgkg orldog LD50:9 g/kg orl-cat LD50:3300 mg/kg orl-rbt LD50:4400 mglkg skn-rbt LD50:11890 mg/kg ivn-rbt LDLo:2236 mg/kg ims-rbt LDLo:4472 mg/kg unr-rbt LD50:2688 mg/kg orl-gpg LD50:7800 mg/kg unr-gpg LD50:14 g/kg

RTECS 1992)

IrritationData: (Source:NIOSHRTECS1992) skn-hmn 112 mg/3D-I MLD eye-rbt 50 mg MLD ReproductiveToxicity reproductive toxin.

(1992 RTECS):

Thischemical

is amammalian

197

Accelerators and Activators

Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo:50 g/kg (1-20D preg) OYYAA2, 27, 801, 84 Specific Developmental Abnormalities Musculoskeletalsystem orl-rat TDLo:76420 mg/kg (6-15D preg) EPASR*8EHQ-0291-1175 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) orl-rat TDLo:38212 mg/kg (6-15D preg) EPASR*8EHQ-0291-1175 Specific Developmental Abnormalities Musculoskeletalsystem orl-mus TDLo:343 g/kg (multigeneration) FAATDF 14, 622, 90 Maternal Effects Parturition Effects Embryo or Fetus Fetal death Effects Newborn Sex ratio

- PROTECTION AND FIRST AID First Aid Source: CHRISManual1991. Inhalation: Noproblem likely. If any ill effects do develop, get medical attention. Ingestion: Induce vomiting ifingested. No known antidote; treat symptomatically. Eye and skin: Flushwith water. Ifany ill effects occur, get medical attention.

- INITIAL INCIDENT RESPONSE --FireExtinguishment: Alcoholfoam,carbon dioxide, dry chemical. Note: Water or foam may cause frothing. (CHRIS 91) No DOT Guide information for this product. v

v

v

v

v

v

v

v

v

v

v

v

v

v

198

Chapter 4

--JDE-RS

--

Chemical Name and Synonyms: CUPRIC DIMETHYLDITHIOCARBAMATE, CU[SC(S)N(CH&J, Trade Name and Synonyms: Cumate ChemicalFamily:

Dithiocarbamate

Manufacturer: R. T. Vanderbilt

Inc., Norwalk,Connecticut

UN ID Number: NA

- INGREDIENTS AND COMPOSITION DATA --%

No. Cas Material

Acute 98 min.

dimethylNACupric dithiocarbamate

oral

LD50 (mice), 11,383 mg/kg

--

PHYSICAL DATA

BoilingPoint (“F): NA SpecificGravity (H20= 1): 1.75 VaporPressure(mmHg):

NA

Percent Volatile byVolume (%): NA VaporDensity(air = FreezingPoint:

TLV

NA

NA

EvaporationRate:

NA

p H NA Solubility inWater: Melting Point: NA

Negligible

--

Accelerators and Activators

Appearance/Color/Odor: described.

199 Dark brown powder. No

characteristic odor

--FIRE AND EXPLOSION HAZARDS FlashPoint: NA FlammabilityLimits: NA Autoignition: NA Extinguishing Media: Foam, dry chemical, carbon dioxide. Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontained breathing apparatus andimpervious protective clothing such as gloves, hoods, and suits. Unusual Fire and Explosion Hazards:

None reported by manufacturer.

Hazardous Products of Combustion and Decomposition:CuO, amines, CS,, CO,. HazardousPolymerization: Willnot occur.

--

HEALTH HAZARD DATA

--

Effects of Overexposure: Maycause allergic reactions in extra-sensitive persons. Material is irritating to the eyes if contact is made. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Givevictim fresh air or oxygen.Consult physician. Material should be used in a well-ventilated area. Ingestion: If swallowed, immediately giveseveral glasses of water and induce vomitingbygagging the victimwith a finger placed on the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth.

200

Chapter 4

Cancer Information: Not listed as a carcinogen by NTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--TOXICITY DATA -Animal Effects: Acute oral LD50 in mice reported

to be

mgkg.

--REACTJYITY DATA -Stability and Conditions to Avoid: Heat, open flames. Under normal use, this material is stable. Product will react with acids. Materials to Avoid (Incompatibility): Acids, acidic conditions. Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide, carbon dioxide, CuO, amines, and CS,. HazardousPolymerization: Willnotoccur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Sweep up and discard in an appropriate container. Wash area with soap and water. Waste Disposal Method As per organic compounds. Empty Containers: The containerfor this product can presentexplosion hazards,evenwhenemptied. To avoid the risk of injury, donot puncture, or weld on or near this container.

--

SPECIAL PROTECTION AND PRECAUTIONS

fire cut,

--

RespiratoryProtection: Dust respirator as appropriate. Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemicalgoggles.Eyewash safety showers should be easily accessible.

fountains and

Accelerators and Activators

1

Protective Gloves and Other: Rubber gloves and apron. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Do not mix or expose to acids. OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. As withany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

- REGULATORY INFORTVIATION -None reported.

- IDENTIFIERS --Chemical Name and Synonyms: ZINC DIETHYLDITHIOCARBAMATE, ZDEC, ZINC, BIS(DIETHYLCARBAMODITFlIOAT0-&S’)Trade Name and Synonyms: Ethyl Zimate ChemicalFamily:

NA

Manufacturer: R. T. Vanderbilt Co., Inc., Norwalk,Connecticut

UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA --Material ZDEC

No.

Cas

% OSHA TWA: 5 mg/m3 (respirable dust) mg/m3 (total dust) ACGIH TWA: mg/m3 (total dust)

202

Chapter 4

--PHYSICAL DATA --BoilingPoint (“F):NA SpecificGravity (H20= 1): 1.48 VaporPressure(mm Hg): NA Percent Volatile by Volume (%): NA VaporDensity(air = 1): NA FreezingPoint:

NA

EvaporationRate: NA p H NA Solubilityin Water: Negligible MeltingPoint:

NA

Appearance/Color/Odor: White powder with no distinctive odor.

- FIRE AND EXPLOSION HAZARDS -Hash Point: NA FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Foam, drychemical,carbon

dioxide.

SpecialFireFightingProcedures: As in any fire, prevent human exposure tofire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontained breathing apparatus andimpervious protective clothing such as gloves, hoods, and suits. Unusual Fire and Explosion Hazards: None reported by manufacturer.

Accelerators

203

Hazardous Products of Combustion and Decomposition: When exposed to flames, emits acrid fumes. Oxides of carbon, sulfur, nitrogen, and zinc upon combustion. HazardousPolymerization: Willnotoccur.

--HEALTH HAZARD DATA -Effects of Overexposure: May irritate or sensitize skin. Do notingest alcoholic beverages immediately before or after handling (Antabuse effect). May cause eye, skin, and upper respiratoryirritation with prolonged exposure to the dust. Continuous skin contact could lead to dermatitis and possible skin sensitization. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Givevictimfresh air or oxygen.Consultphysician.Material should be used in a well-ventilated area. Ingestion: If swallowed, immediately give several glasses of water and induce vomitingbygaggingthevictimwith a fingerplaced the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Not listed as a carcinogen by NTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--TOXICITY DATA -Animal Effects: Acute oral LD50 3530 mg/kg in rats. Acute dermal LD50 >3160 mgkg in rabbits. Chronic effects are not known.

--- REACTIVITY DATA -StabilityandConditions to Avoid: To prevent formation of suspect carcinogenic nitrosamines, do not use with nitrosating agents. Under dusty conditions, static electricity may cause an explosion. Avoid contact with skin and eyes.

Chapter 4

204

Materials to Avoid(Incompatibility): agents.

Acids,acidic conditions, nitrosating

Hazard Decomposition Products: Seeabovesections. Hazardous Polymerization: Will not occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Sweep up and discard in an appropriate container. Wash area with soap and water. Waste Disposal Method: As per organic compounds.

Empty Containers: The containerfor this product can present explosion or fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container.

--IDENTIFIERS -Chemical NameandSynonyms:NICKELDIBUTYLDITHIOCARBAMATE Trade Name and Synonyms:

NBC

ChemicalFamily: RubberAccelerator Manufacturer: E. I. du Pont de Nemours & Co., Inc., Wilmington, Delaware

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA -%

No. Cas Material NBC

NA established

- PHYSICAL DATA -Boiling Point (“F): NA

TLV Not

Accelerators and Activators

SpecificGravity (H,O = VaporPressure(mmHg):

205 1.26 NA

Percent Volatile by Volume (%): NA VaporDensity(air FreezingPoint:

= 1): NA

NA

EvaporationRate:

NA

pH: NA Solubilityin Water: Negligible MeltingPoint (“F):187 Appearance/Color/Odor: Dark green flakes with mild odor.

--FIRE AND EXPLOSION H A Z A R D S Flash Point: 505°F FlammabilityLimits:

(263°C) open cup NA

AutoignitionTemperature:

NA

Extinguishing Media: Foam, dry chemical, carbon dioxide, water, regular fire extinguishers. Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontained breathing apparatus andimpervious protective clothing such as gloves, hoods, and suits. Unusual Fire and Explosion Hazards:

None reported by manufacturer.

Hazardous Products of Combustion and Decomposition: When exposed to flames, emits acrid fumes. Oxides of carbon, sulfur, nitrogen, and zinc upon combustion.

Chapter 4

Hazardous Polymerization: Will not occur.

--HEALTH HAZARD DATA -Effects of Overexposure: May irritate or sensitize skin, although generally not considered a skin sensitizer. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots water. If irritation persists, consult a physician. Inhalation: Give victim fresh air or oxygen.Consult physician. Material should be used in a well-ventilated area. Ingestion: If swallowed, immediately giveseveral glasses of water and induce vomitingbygagging the victimwitha finger placed on the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Not listed as a carcinogen by NTP(National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research Cancer).

--TOXICITY DATA -Animal Effects: Approximate lethal dose (ADL) is greater than 17,000 mg/kg body weight for male rat.

--REACTIVITY DATA -Stability and Conditions to Avoid: None reported by manufacturer other than minimize skin exposure. Materials to Avoid (Incompatibility): None reported by manufacturer. HazardDecompositionProducts:

None reported.

HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Sweep up and discard in an appropriate container. Wash area with soap and water.

Accelerators and Activators

Waste Disposal Method:

per organic compounds.

Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container. Dusty environments can cause conditions of spontaneous combustion.

--SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection: Dust respirator as appropriate. Type of Ventilation Required: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Rubber or PVC gloves. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from container. OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughly clean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--REGULATORY INFORMATION -None reported. V

V

T

V

T

V

V

V

V

V

V

V

V

V

208

Chapter 4

--IDENTIFIERS --ChemicalNameandSynonyms:BISMUTHDIMETHYLDITHIOCARBAMATE Trade Name and Synonyms: Bismate Powder ChemicalFamily: RubberAccelerator Manufacturer: R. T. Vanderbilt Co., Inc., Norwalk,Connecticut UN ID Number: NA

--INGREDIJ3NTS AND COMPOSITION DATA -No.

%

Cas Material Bismuth dimethyl21260-46-8 dithiocarbamate

35

Mixed petroleum Process oil Proprietary 800983-5004P ingredient

No.

38

6474 1-96-4 6474 1-97-5

Not established

NJTSR

Not established

- PRYSICAL DATA -BoilingPoint ("F): NA SpecificGravity (H,O = 1): 2.04 VaporPressure(mm Hg): NA Percent Volatile byVolume (%): NA VaporDensity(air = 1): NA FreezingPoint:

NA

EvaporationRate:

NA

OSHATWA: 5 mdm3 (respirable dust) 15 mg/m3 (total dust)

Accelerators and Activators

p H NA Solubility inWater:

Negligible

Melting Point (“C): Above Fineness

mesh):

with decomposition minimum

Appearance/Color/Odor: Lemonyellowpowder.

- FIRE AND EXPLOSION H A Z A R D S -FlashPoint: NA FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Foam,dry chemical, carbon dioxide. Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontained breathing apparatus andimpervious protective clothing such as gloves, hoods, and suits. UnusualFireandExplosionHazards: hazardous (see data below).

Decompositionproducts

may be

HazardousProducts of CombustionandDecomposition: Bismuth oxide, carbon and sulfur dioxide, and carbon disulfide at decomposition temperatures. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA -Effects of Overexposure: None listed in available literature. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots water. If irritation persists, consult a physician.

210

Chapter 4

Inhalation: Givevictim fresh air or oxygen.Consult physician. Material should be used in a well-ventilated area. Ingestion: If swallowed, immediately giveseveral glasses of water and induce vomitingbygagging the victimwitha finger placed on the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Not listed as a carcinogen by NTP(National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--TOXICITY DATA -Animal Effects: RTEC: Scu-mus TDLo lo00 mg/kg. National Technical Information Service Reference. This effect is listed as inconclusive due to insufficient study data or method.NCI carcinogenesis study reflects no significant increase in tumors. Manufacturer Studies: Toxicity Toxic). Humanpatch test, negative.

mg/kgacute

oral rat (not OSHA

- REACTIVITY DATA -Stability and Conditionsto Avoid: None reported by manufacturer other than to minimize skin exposure. Materials to Avoid (Incompatibility): Acids and oxidizing agents. Hazard Decomposition Products: Bismuth oxide, carbon and sulfur dioxide, and carbon disulfide. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Vacuum or moisten material prior to sweeping.Place container for disposal.

in closed

Waste Disposal Method: Not classified as a RCRA hazardous waste. Dispose of according to applicable environmental regulations.

211

Accelerators and Activators

Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container. Dusty environments can cause spontaneous combustion conditions.

--SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: Dust respirator as appropriate. Type of Ventilation Required: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Not typically recommended. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughlyclean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--REGULATORY INFORMATION --None reported.

--- IDENTIFIERS --Chemical Name and Synonyms: ZINC DIBWYLDITHIOCARBAMATE Trade Name and Synonyms: Butyl Zimate

Chapter 4

212

ChemicalFamily:

RubberAccelerator

Manufacturer: R. T. Vanderbilt Co., Inc., Norwalk,Connecticut

UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA Material

Cas No.

Zinc compound containing zinc dibutyldithiocarbamate

136-23-2 13

%

to 15% zinc Not established

- PHYSICAL DATA -Boiling Point (“F):NA Specific Gravity (HzO = 1): 1.21 Vapor Pressure (mm H& NA Percent Volatile by Volume (%): NA VaporDensity(air FreezingPoint:

= 1): NA

NA

EvaporationRate:

NA

pH: NA Solubilityin Water: Negligible MeltingPoint(“C): NA Appearance/Color/Odor: White to cream color.

- FIRE AND EXPLOSION HAZARDS Flash Point: NA

TLV

Accelerators and Activators

213

FlammabilityLimits: NA AutoignitionTemperature: ExtinguishingMedia:

NA

Foam, dry chemical, carbon dioxide.

Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuatenonessential personnelfromthe fire area. Firefighters shouldwearfull-face,selfcontainedbreathingapparatusandimperviousprotective clothing such as gloves, hoods, and suits. Manufacturer recommends positive-pressure selfcontained breathing apparatus. UnusualFireandExplosionHazards: hazardous.

Decompositionproducts

Hazardous Products of Combustion and Decomposition: nitrogen, carbon, and zinc at combustion temperatures.

may be

Oxides of sulfur,

Hazardous Polymerization: Willnotoccur.

--HEALTH HAZARD DATA --Effects of Overexposure:

None listed in available literature.

Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Give victimfresh air or oxygen.Consultphysician.Material should be used in a well-ventilated area. Ingestion: None reported by manufacturer. Cancer Information: Not listed as a carcinogen by NTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--TOXICITY DATA -Animal Effects: For Butyl Zimate: acute oral LD50 (rats) > 16,000 mgkg. In a 92-day study, 50 mg/kg per day producedno effect in rats. In a 17-week study, the no-untoward-effect level was 500 ppm in diet the of rats, providing

Chapter 4

214

an intake of between 41 and 47 mg/kg/day. Ames test was negative. There are known medical conditions that are aggravated by exposure.

--REACTIVITY DATA -Stability and Conditionsto Avoid: None reported by manufacturer other than to minimize skin exposure. Materials to Avoid (Incompatibility): Acids and oxidizing agents. Hazard Decomposition Products: Oxides of sulfur, nitrogen, carbon, and zinc at combustion temperatures. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE ---

Waste Disposal Method:

As per any organic chemical.

Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container.

--SPECIAL PRO'IECTION AND PRECAUTIONS --Respiratory Protection: Dust respirator as appropriate. Type of Ventilation Required: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Not typically recommended. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of

Accelerators and Activators heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate and thoroughly clean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--REGULATORY INFORMATION None reported.

--IDENTIF’IERS -Chemical Name and Synonyms: ZINC DIMETHYLDITHIOCARBAMATE Trade Name and Synonyms:

Methyl Zimate

ChemicalFamily: RubberAccelerator Manufacturer: R. T. Vanderbilt Co., Inc., Norwalk,Connecticut

UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA -Material

No.

Zinc compound containing zinc dimethyldithiocarbamate

Cas

% to

OSHA - TWA/PEL ACGIH - TWA/TLV - STEL

zinc Not established

5 mg/m3 mg/m3 mg/m3

--PHYSICAL DATA -Boiling Point (“F): NA

TLV

216

Chapter 4

SpecificGravity (H20=

1.71

VaporPressure(mmHg): Percent Volatile by Volume (%): NA VaporDensity(air = 1): FreezingPoint: EvaporationRate: pH Solubilityin Water: Negligible MeltingPoint(“C): Appearance/Color/Odor: Whitepowder, slight characteristic odor.

--FIRE AND EXPLOSION HAZARDS --FlashPoint: FlammabilityLimits: AutoignitionTemperature: Extinguishing Media: Foam, dry chemical, carbon dioxide, water. SpecialFireFightingProcedures: in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontainedbreathing apparatus andimpervious protective clothing such as gloves, hoods, and suits. Manufacturer recommends positive-pressure selfcontained breathing apparatus. UnusualFireandExplosionHazards: hazardous.

Decompositionproductsmay

be

Hazardous Products of Combustion and Decomposition: Oxides of sulfur, nitrogen, carbon, and zinc at combustion temperatures.

Accelerators and Activators

217

HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA -Effects of Overexposure: Maycause eye, skin, andupper respiratory tract irritation prolonged exposure to dust. Continuous skin contact could lead to dermatitis and possible skin sensitization.

Do not ingest alcoholic beverages immediately before or after handling this material (Antabase effect). MAY BE FATAL IF INHALED. May irritate eyes and skin. May sensitize skin. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Givevictim fresh air or oxygen.Consult physician. Material should be used in a well-ventilated area. Ingestion: If swallowed, drink promptly alarge quantity milk, egg whites, or gelatin solution, or if these are not available, large quantities of water. Consult a physician immediately. Cancer Information: IARCGroup

SeeToxicityDatabelow.

--TOXICITY DATA --Animal Effects: For Ziram: Acute oral D 5 0 (rats): 1400 mg/kg and in second study mg/kg. Acute dermal D 5 0 (rabbits): >2000 mg/kg (low toxicity). Eye irritation (rabbits): Irritant. Severe ocular lesions wereproduced. Skin irritation (rabbits): slight. Inhalation LC50 (rats): 81 mg/m3/4 hr (highly toxic). Four groups of 10 rats were exposed to 21, 90 and 124 mg/m3 ziram for 4 hr. The animalswereobserved for 14 days. All rats thatdiedspontaneously exhibited lung discoloration and effects of the digestive tract, in particular distended stomachs and intestinal tracts. Similar symptoms were observed in the surviving rats, but some appeared normal.

Chapter 4

218

A teratogenic study using rats indicated that under the test conditions the productisnot teratogenic at dose levels as high as 140mg/kg/day.A rabbit study found no teratogenic effects at dose levels up to 15 mg/kg/day (mm.tested). A reproductive study indicated no adverse effects in three generations at 29.6 mg/kg/day for male rats and 33.8 mg/kg/day for female rats.

Mutagenicity: L5178Y mouse,lymphoma:

negative.

Amutagenicstudy(Salmonellamicrosome)showed positive results at 5 mg/plate. In a second bacterial mutation study with five dose levels of 0.5, 1.5, 5, 15, and 50 mg/plate, ziram was mutagenic only at dose levels above 50 mg/plate. Ziram failed to show evidence of DNA-damaging activity in cultured rat hepatocytes in vitro. IARCGroup 3 (not classifiable as to their carcinogenicity to humans). Inadequate evidence in animals. Ziram failed to show clastogenic activity in Chinese Hamster ovary cells, in vitro, with or without metabolic activation. NTP conducted acarcinogenesis bioassay of ziram(NTP Technical Reports Series No. 238). C-cell carcinomas of the thyroid gland were reported in 2 out of 49 male F344/N rats at a daily dose of 11 mg/kg and in 7 out of 49 at a daily dose of 22 mg/kg. Female B6C3F1 mice showed some lung adenomas, but the study was complicated by an intercurrent Sendai virus infection. No carcinomas were shown under the same test conditions for female rats and male mice. NTP does not list ziram in its Fifth Annual Report on Carcinogens (1989). Ziram is not included in the chemicals proposed for addition to the Sixth AnnualReport on Carcinogens.There is noknownhumancarcinogen association after more than 30 years of application. A long-term feeding study (2 yr) showed no carcinogenic response in rats fed a daily diet of 0.025% ziram (250 ppm). A short-term feeding study (90 days) showedno liver, lung, spleen, or kidney damage in rats fed a daily diet of 20 mg of ziram.

Accelerators

219

In a study comparing seven dithiocarbamate fungicides for skin sensitization, ziram was ranked as a moderate allergic skin sensitizer, being less active in this regard than most of the other dithiocarbamates tested.

Medical Conditions Generally Aggravated by Exposure: Unknown.

--REACTIVITY DATA --Stability and Conditionsto Avoid: None reported by manufacturer other than to minimize skin exposure. Materials to Avoid (Incompatibility): Acids and oxidizing agents. Hazard Decomposition Products: Oxides of sulfur, nitrogen, carbon, and zinc at combustion temperatures. HazardousPolymerization: Willnotoccur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Sweepup.Washresidualswithsoapandwater. closed container. Waste Disposal Method:

Transfer to a

As per any organic chemical.

Empty Containers: The container for this product present explosionor fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container.

- SPECIAL PROTECTION AND PRECAUTIONS --RespiratoryProtection: NIOSH-approvedchemical cartridge for organic vapors and acid gases, in combination with a dust prefilter. Type of Ventilation Required: Generalmechanical.Avoidbreathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm.

Chapter 4

220

EyeProtectionRequirements: Chemical goggles. Eyewashfountainsand safety showers should be easily accessible. Protective Gloves and Other:

Rubber gloves, goggles.

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containersclosed. Store in a cool, dry place. Use with adequate ventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useallstandardpractices for goodpersonalhygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels before beginningmaintenance or repairs. Keepareaclean. withany powder or dust-like material, improperhandlingcanlead to spontaneous combustion (dust explosions).

- REGULATORY INFORMATION None reported.

--IDENTIFIERS -Name:SELENIUM, TETRAKIS@IMETHYLDI"IIOCARBAMATO)Synonyms: MethylSelenac;SeleniumDimethyldithiocarbamate; Tetrakis(Dimethylcarbamodithioato-S,S')Selenium CAS: 144-34-3; RTECS: VT0780000 Formula: C,2H,N,S8 . MolWt: 559.84 WLN 1N1 See other identifiers listed below under Regulations.

Accelerators and Activators

22

--PROPERTIES BoilingPoint: NA MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density: No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents:No data Polymerization Possibilities: No data Toxic Fire Gases: Oxides of nitrogen Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--REGULATIONS --DOT hazard class: Not given Packaging exceptions: 173. Nonbulkpackaging: 173. Bulkpackaging: 173. STCC Number: Not listed Clean Water Act Sect. 307:Yes Clean Water ActSect. 311: No by category Clean Air Act: CAA EPA Waste Number: DO10 CERCLA Ref: Not listed RQ Designation: Notlisted SARA TPQ Value: Not listed SARA Sect. 312 Categories: Nocategory

Chapter 4

Listed in SARA 313: Yes De Minimus Concentration:

U.S. Postal Service Mailability: Not given

--TOXICITY DATA -Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

Conc IDLH Unknown

NIOSH REL: Not given ACGIH TLV: TLV = 0.2 mg/m3 as selenium ACGIHSTEL: selenium OSHAPEL: TransitionalLimits: TWA = 0.2 mg/m3.

PEL =

mg/m3;FinalRuleLimits:

MAKInformation: Notlisted Carcinogen: N; Status: See below CarcinogenLists: IARC Notclassified tohumancarcinogenicity or probably not carcinogenic to humans; M A K Not listed; NIOSH Not listed; NTP: Not listed; ACGIH Not listed; OSHA: Not listed. LD50 Value: No LD50 in RTECS Reproductive Toxicity (1992 RTECS): malian reproductive toxicity.

This chemical has no known mam-

--- INITIAL INCIDENT RESPONSE -No DOT Guide information for this product.

Accelerators and Activators

--IDENTIFIERS -Chemical Name and Synonyms: LEAD DIMETHYLDJTHIOCARBAMATE Trade Name and Synonyms: ChemicalFamily:

Methyl Ledate

MetalDithiocarbamate

Manufacturer: R. T. VanderbiltCo., Inc., Norwalk,Connecticut UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA -Material

Cas No.

Lead dimethyldithiocarbamate

NA

96

TLV

95 established Not

--PHYSICAL DATA -BoilingPoint (“F): NA SpecificGravity (H,O = 1): 2.41 VaporPressure(mmHg):

NA

Percent Volatile by Volume (%): NA VaporDensity(air = 1): NA Freezing Point:

NA

EvaporationRate:

NA

p H NA

Solubility in

Water: Negligible

MeltingPoint(“C): NA AppearancelColorlOdor: White powder, no odor

reported.

Chapter 4

224

FIRE AND EXPLOSION HAZARDS --FlashPoint: NA FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Foam, dry chemical, carbon dioxide. Special Fire Fighting Procedures: in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontainedbreathing apparatus andimpervious protective clothing such as gloves, hoods, and suits. Manufacturer recommends positive-pressure selfcontained breathing apparatus. UnusualFireandExplosionHazards: hazardous.

Decompositionproductsmay

HazardousProducts of CombustionandDecomposition: sulfur, and nitrogen at decomposition temperatures.

be

Oxides of lead,

HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA -Effects of Overexposure: Inhalation of dust is harmful; may affect the central nervous system and cause neuromuscular, genitourinary, and hematopoietic complications. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Give victim fresh air or oxygen. Consult physician regarding the necessityofbloodand urine tests. Material shouldbeusedina wellventilated area. Ingestion: Nonerecommended.Consult physician immediately. CancerInformation: IARCGroup 3.

Accelerators and Activators

225

--TOXICITY DATA -Animal Effects: See RTECS studies for lead poisoning.

--REACTIVITY DATA --Stability and Conditionsto Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. Materials to Avoid (Incompatibility): Acids and oxidizing agents. Hazard Decomposition Products: Highly toxic oxides of lead, nitrogen, and sulfur. HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE -For Spills: Sweep up. Wash residuals withsoapand closed container.

water. Transfer to a

Waste Disposal Method: According to RCRA 40 CFR Section 261.24. Empty Containers: The container for this product canpresent explosion or fire To avoid the risk of injury, do not cut, hazards, evenwhenemptied. puncture, or weld on or near this container.

--SPECIAL PROTEXTION AND PRECAUTIONS -RespiratoryProtection: Dustmask. Type of Ventilation Required: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Rubber gloves, goggles.

Chapter 4

226

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequate ventilation. Wash thoroughly after handlingbefore eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useallstandardpractices for goodpersonalhygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep areaclean. As withany dust-like material, improperhandlingcanleadtospontaneous powder combustion (dust explosions).

--

REGULATORY ITWORMATION

--

RCRA 40 CFR Section 261.24.

--- IDENTIFIERS -Chemical Name and Synonyms: TELLURIUM DIETRYLDITHIOCARBAMATE AND MIXED PETROLEUM PROCESS OIL Trade Name and Synonyms: Ethyl Tellurac ChemicalFamily: RubberAccelerator Manufacturer: R.T.Vanderbilt

UN ID Number: NA

Co., Inc., Norwalk,Connecticut

227

Accelerators and Activators

--INGREDIENTS AND COMPOSITION DATA -Cas No.

Material Tellurium diethyldithiocarbamate

20941-65-5

Mixed petroleum Process oil

6474 1-96-4and 64741-97-5

%

For Tellurium: ACGIH and OSHA TWA For Particulates (NOC): OSHA TWA (total dust) ACGIH TWA (total dust)

Not established

0.10 mg/m3/8hr 5 mg/m3 10 mg/m3

--PHYSICAL DATA -BoilingPoint (“F):NA SpecificGravity (HzO = VaporPressure(mmHg):

1.44

NA

Percent Volatile by Volume (%): NA VaporDensity (air = FreezingPoint:

NA

NA

EvaporationRate:

NA

p H NA Solubilityin Water: Negligible MeltingPoint: NA Appearance/Color/Odor: reported.

Orangeyellowpowder;

no characteristic odor

228

Chapter 4

--FIRE AND EXPLOSION HAZARDS -FlashPoint: NA FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Foam, dry chemical, carbon

dioxide.

Special Fire Fighting Procedures: As in any fire, prevent human exposure to fire, smoke,fumes, or productsofcombustion.Evacuatenonessential personnel from the fire area. Firefighters shouldwearfull-face, selfcontainedbreathingapparatusandimperviousprotective clothing such as gloves, hoods, and suits. Manufacturer recommends positive-pressure selfcontained breathing apparatus. Unusual Fire and Explosion Hazards: combustion.

Dust may cause spontaneous

Hazardous Products of Combustion and Decomposition: Oxides of tellurium, nitrogen, sulfur, and carbon at combustion temperatures. HazardousPolymerization: Willnotoccur.

--- HEALTH HAZARD DATA

---

Effects of Overexposure: May cause irritation to eyes. Garlic odor of breath and sweat. Possible (but very remote) symptoms are somnolence, anorexia, and nausea. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes with lotsof water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: IARCGroup

Accelerators and Activators

--- TOXICITY DATA Animal Effects: Acute dermal LD50 (rabbits): > mgkg Acute oral LD50(mice): > mgkg Acute oral LD50 (rats): mgkg Acute inh. LC50 (rats): 0.51 mg/L (maximum attenuation) When excess tellurium exists, a garlic odor to the breath, dryness of the mouth, anorexia, and occasional nausea may be experienced (evenTe atlevels below the established standard). Slightly irritating to the eyes ofrabbits under unrinsedtest conditions. Guinea pig sensitization and rabbit skin irritation tests werenegative.Ames mutagenicitytestwithandwithout activation was negative. Someanimal studies are reported to indicate a probability of increased incidence of mesotheliomas in male rats and adenomas ofthe lacrimal gland of the eyes in mice of both sexes (NIH NCI concluded that data are insufficient to establish carcinogenicity.

- REACTIVITY DATA Stability and Conditionsto Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. Materials to Avoid (Incompatibility): Acids and oxidizing agents. Hazard Decomposition Products: Highly toxic oxides of lead, nitrogen, and sulfur. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE --For Spills: Sweep up. Wash residuals withsoapand closed container. Waste Disposal Method:

water. Transfer to a

According to RCRA 40 CFR Section

Empty Containers: The container for this product can present explosionor fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container.

Chapter 4

--- SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection: Dustmask. Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemicalgoggles.Eyewash safety showers should be easily accessible. Protective Gloves and Other:

fountains and

Rubber gloves, goggles.

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate and thoroughly clean allequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dust-like material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--REGULATORY INFORMATION --Carcinogenic IngredientslOSHA/NTP/IARC: None. SARA Title III Section 313 Ingredients: None.

Accelerators and Activators

23 l

--IDENTIFIERS -Name: CADMIUMDIETHYLDITHIOCARBAMATE Synonyms: DiethyldithiocarbamateDeCadmium CAS:14239-68-0; RTECS: EU9850000 Formula: C,,,H&dN,S, WLN: 2N2 Chemical Class: Organicacid salt See other identifiers listed below under Regulations.

--PROPERTIES -BoilingPoint: NA MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density: No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data PolymerizationPossibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--- REGULATIONS --DOT hazard class: Not given Packaging exceptions: 173. Nonbulkpackaging: 173. Bulkpackaging: 173. STCC Number: Not listed

Chapter 4 Clean Water. Act 307: Yes Clean Water ActSect. 311: No Clean Air Act: CAA by category EPA WasteNumber: D006 CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Chronic toxicity: carcinogen. Chronic toxicity: mutagen. Listed in SARA 313: Yes De Minimus Concentration: 0.1 %

U.S. Postal Service Mailability:

-Short-termToxicity:

Not given

TOXICITY DATA

---

Unknown

Long-term Toxicity: Unknown Conc IDLH Unknown NIOSH REL: Not given ACGIH TL\’: TLV = dust 0.05 mg/m3 as cadmium ACGIH STEL: Ascadmium

OSHA PEL: Transitional Limits: PEL = (fume) 0.1 mg/m3; (dust) 0.2 mg/m3; Ceiling = (fume) 0; Final Rule Limits: TWA = (fume) 0.1 mg/m3; (dust) 0.2 mg/m3; Ceiling = (fume) 0.3 mg/m3; (dust) 0.6 mg/m3. MAK Information: Not listed Carcinogen:Y;Status:

Seebelow

CarcinogenLists: ZARC: Not listed; M A K Not listed; NZOSH Not listed; NTP Carcinogen defined by NTPas reasonably anticipated be carcinogenic, with limited evidence in humans or sufficient evidence in experimental animals; ACGZH Not listed; OSHA: Not listed.

233

Accelerators and Activators LD50 Value: No LD50 in RTECS 1992 Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

This chemical has no known

- INITIAL INCIDENT RESPONSE -No DOT Guide information for this product.

--IDENTIFIERS Name: ZINCSTEARATE CAS:557-05-1; RTECS: ZH5200000 Formula: C,H,O,Zn Chemical Class: Organicacid salt See other identifiers listed below under Regulations.

--PROPERTIES -Boiling Point: NA Melting Point: K; 119.8"C;247.7"F Flash Point: NA Autoignition: NA UEL: NA LEL: NA Vapor Density: No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents:No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

Chapter

--RJ3GULATIONS -DOT hazard class:Notgiven Packaging exceptions: Nonbulkpackaging: Bulkpackaging: STCC Number: Notlisted Clean Water Act Sect. 307: Yes Clean Water Act Sect. 311: No Clean Air Act:Notlisted EPA Waste Number: None CERCLA Ref: Not listed RQ Designation: Notlisted SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acutetoxicity: irritant. Listed in SARA Sect. 313: Yes De Minimus Concentration: 1.O%

U.S. Postal Service Mailability:

Not given

NFPA Codes: Health Hazard (blue): Unspecified Flammability (red): Unspecified Reactivity (yellow):Unspecified Special: Unspecified

--TOXICITY DATA Short-term Toxicity: Unknown Long-term Toxicity: Unknown Symptoms: Inhalation has beenreported (Source: SAX) ConcIDLH:

Unknown

ACGIH TLV: Notlisted ACGIH STEL: Not listed

as causingpulmonary

fibrosis.

Accelerators

OSHAPEL: TransitionalLimits: PEL = totaldust15mg/m3;respirable fraction 5 mg/m3;FinalRuleLimits:TWA = total dust 10 mg/m3; respirable fraction 5 mg/m3. MAK Information: Not listed Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; "C Not listed; NZOSR. Not listed; h T P Not listed; ACGZH Not listed; OSHA: Not listed. LDS0 Value: No LD50 in RTECS 1992 OtherSpeciesToxicityData: itr-rat LDLo:250 mg/kg

(Source:NIOSHRTECS1992)

Reproductive Toxicity (1992 RTECS): This chemical has noknownmammalian reproductive toxicity.

--- INITIAL INCIDENT RESPONSE -No DOT Guide information for this product.

--IDENTIFIERS --Chemical Name and Synonyms: DI-ORTHO-TOLYLGUANIDINE, C15H1'1N3 Trade Name and Synonyms: ChemicalFamily:

DOTG Accelerator

Guanidine

Manufacturer: AmericanCyanamid,BoundBrook,

New Jersey

--INGREDIENTS AND COMPOSJTION DATA -%

No. Cas Material DOTG

established NA

TLV Not

Chapter 4

--PHYSICAL DATA -BoilingPoint (“F):NA SpecificGravity (H,O = 1): VaporPressure(mmHg):

NA

Percent Volatile by Volume (%): Less than 1 = 1): NA

VaporDensity(air FreezingPoint:

NA

EvaporationRate:

NA

p H NA Solubilityin Water: Negligible MeltingPoint: NA Appearance/Color/Odor: Whitepowder, practically odorless.

- FIRE AND EXPLOSION HAZARDS -FlashPoint:

NA

FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Foam, dry chemical, carbon dioxide, or water. Special Fire Fighting Procedures: As in any fire, prevent human exposure fire, smoke,fumes, or productsofcombustion.Evacuate nonessential personnelfrom the fire area. Firefighters shouldwear full-face, selfcontained breathing apparatus andimpervious protective clothing such as gloves, hoods, and suits. Manufacturer recommends positive-pressure selfcontained breathing apparatus. Do nul use high-pressure water stream. Airborne dust creates an explosion hazard.

Accelerators and Activators

237

Unusual Fire and Explosion Hazards: Dust may be explosive if mixed with air in critical proportions and in the presence of a source of ignition. The hazard is similar to that of any organic solid including sawdust. Maintain normal good housekeeping for control of dust. Hazardous Productsof Combustionand Decomposition:Thermal decomposition may produce carbon monoxide and/or carbon dioxide. HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA -Effects of Overexposure: Dust causes eye burns. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Giveartificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

--- TOXICITY DATA -Animal Effects: None reported.

--REACTIVITY DATA --Stability and Conditions to Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. Materials to Avoid(Incompatibility): None. Hazard Decomposition Products:

Carbon dioxide and carbon monoxide.

HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE --For Spills: Sweep up. Wash residuals withsoapand closed container.

water. Transfer to a

Chapter 4

238

Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. avoid the risk of injury, do not cut, puncture, or weld on or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS --RespiratoryProtection: Dustmask.

Type of VentilationRequired: Generalmechanical.Avoid

breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm.

EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves andOther: Rubber gloves, goggles. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for goodpersonalhygiene. Completely isolate andthoroughly clean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dust-like material, improperhandlingcanlead to spontaneous combustion (dust explosions).

Accelerators

--REGULATORY INFORMATION Carcinogenic IngredientslOSHAlNTPlIARC: None SARA Title III Section 313 Ingredients: None v

v

v

v

v

v

v

v

v

v

v

v

v

--- IDENTIFIERS --ChemicalNameandSynonyms:COPPERMERCAPTOBENZOTHIAZOLE Trade Name andSynonyms: CUPSAC Accelerator ChemicalFamily:

Thiazole

Manufacturer: AmericanCyanamid,BoundBrook,

New Jersey

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --Material

%

TLV

55.5

mg/m3

Cas No.

Mercaptobenzothiazole,copper Mineral oil

5 mg/m3

--PHYSICAL DATA -BoilingPoint (“F):NA SpecificGravity (H,O = 1): VaporPressure(mmHg):

NA

Percent Volatile by Volume (%): Negligible VaporDensity(air = 1): NA

v

Chapter 4

240

FreezingPoint:

NA

EvaporationRate:

NA

p H NA Solubility inWater:

Negligible

MeltingPoint(“C):

165 to 175

Appearance/Color/Odor: Yellow-orange powder; no odor description given.

--- FZRE AND EXPLOSION HAZARDS --FlashPoint: NA FlammabilityLimits:

NA

AutoignitionTemperature: DecompositionTemperature:

NA 350°C

Extinguishing Media: Foam, dry chemical, carbon dioxide,

water.

SpecialFireFightingProcedures: withmany solids, any dustthatis generated may be explosive if mixed withair in critical proportions and in the presence a source ignition. Use water, carbon dioxide, dry chemical to extinguish fires. Wear self-contained, positive-pressure breathing apparatus. Unusual Fire and Explosion Hazards: Dust may be explosive mixed with air in critical proportions and in the presence of a source ignition. The hazard is similar to that any organic solid including sawdust. Maintain normal good housekeeping for control of dust. Hazardous Productsof Combustion and Decomposition:Thermal decomposition may produce carbon monoxide andlor carbon dioxide. HazardousPolymerization: Willnot occur.

Accelerators

24 1

--HEALTH HAZARD DATA -Effects of Overexposure: Overexposure to this material is not likely to cause significant acute toxic effects. Inhalation of dusts and mists of copper salts can resultin irritation of nasal mucous membranes, sometimes of the pharynx, and, on occasion, ulceration with perforation of the nasal septum. If copper salts in sufficient concentration reach the gastrointestinal tract, theyact as irritants, producing salivation, nausea, vomiting, gastric pain, hemorrhagic gastritis, and diarrhea. Chronic exposures may resultinananemia,but chronic poisoning as from lead does not occur.On the skin, copper salts also act as irritants, producing itching eczema, and on the eye, conjunctivitis or even ulceration and turbidity of the cornea. Overexposure to the mineral oil inthisproduct significant acute toxic effects.

is notlikely

to cause

Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

--- TOXICITY DATA --Animal Effects: The acute oral (rat) and acute dermal (rabbit) LD50 values for this material are greater than 10 g k g and greater than 5 g/kg, respectively. The material causedno significant skin and no eye irritation in rabbit primary irritation studies.

--REACTIVITY DATA -Stability and Conditions to Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. This material is considered stable. Materials to Avoid (Incompatibility): Strong oxidizing agents. Hazard Decomposition Products: Carbon dioxide, carbon monoxide, and/or oxides sulfur.

Chapter 4

242

Hazardous Polymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE --For Spills: Sweepup.Washresidualswithsoapand closed container.

water. Transfer to a

Empty Containers: The containerfor this product can present explosionor fire hazards, evenwhenemptied.Toavoid the risk of injury, donot cut, puncture, or weld on or near this container.

--SPECIAL PRO'IZCTION AND PRECAUTIONS -RespiratoryProtection: Dustmask.

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemicalgoggles.Eyewashfountainsand safety showers should be easily accessible. Protective Gloves and Other:

Rubber gloves, goggles.

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequate ventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

Accelerators and Activators

243

OtherPrecautions: Use all standard practices for goodpersonalhygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dust-like material, improperhandlingcan lead to spontaneous combustion (dust explosions).

- REGULATORY INFORMATION -Proper Shipping Name:

Not applicablehot regulated

HazardClass: Not applicable UN/NA: Not applicable DOT Hazardous Substances: (Report Quantity of Product) Not DOT Label Required:

applicable

Not applicable

TSCAInformation: Thisproduct is manufactured in compliancewithall provisions of the Toxic Substances Control Act, 15 U.S.C.

--IDENTIFIERS --Chemical Name and Synonyms:THTURAM, MIXTURE OF THIURAMAS Trade Name and Synonyms: MOTS No. 1 Accelerator ChemicalFamily: Thiuram Manufacturer: AmericanCyanamid,BoundBrook,New

Jersey

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --%

No. Cas Material Thiuram

NA

TLV mg/m3

244

Chapter 4

- PHYSICAL DATA BoilingPoint (“F): NA = 1): 1.44

SpecificGravity VaporPressure(mm

Hg): NA

Percent Volatile by Volume (%): Negligible VaporDensity(air = 1): NA FreezingPoint:

NA

EvaporationRate:

NA

p H NA

Solubilityin Water: Negligible MeltingPoint(“C): NA Appearance/Color/Odor: Greypowder;practically

odorless.

- FIRE AND EXPLOSION HAZARDS -FlashPoint:

NA

FlammabilityLimits: NA AutoignitionTemperature: DecompositionTemperature: ExtinguishingMedia:

NA

NA

Foam, dry chemical,carbon dioxide, or water.

SpecialFireFightingProcedures: As with many solids, any dust that is generated may be explosive if mixed withair in critical proportions and inthe presence a source of ignition. Use water, carbon dioxide, or dry chemical to extinguish fires. Wear self-contained, positive-pressure breathing apparatus.

245

Accelerators

Unusual Fire and Explosion Hazards: Dust may be explosive if mixed with air in critical proportions and in the presence of a source of ignition. The hazard is similar to that of any organic solid including sawdust. Maintain normal good housekeeping for control of dust. Hazardous Productsof Combustion and Decomposition:Thermal decomposition may produce carbon monoxide and/or carbon dioxide. Hazardous Polymerization: Willnotoccur.

- HEALTH HAZARD DATA -Effects of Overexposure: Dust causes eye irritation. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: Nonereported.

--TOXICITY DATA -Animal Effects: None reported by manufacturer.

--REACTIVITY DATA -Stability and Conditions to Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. This material is considered stable. Materials to Avoid (Incompatibility): No specific incompatibility. Hazard Decomposition Products: Carbon dioxide, carbon monoxide, and or oxides of sulfur. Hazardous Polymerization: Willnotoccur.

Chapter 4

246

--SPILL AND EMERGENCY RESPONSE -ForSpills: Sweep up. Wash residuals withsoapand closed container.

water. Transfer to a

Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the risk of injury, donot cut, puncture, or weld on or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection: Dustmask. Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 @m. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other:

Rubber gloves, goggles.

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughlyclean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany

247

Accelerators and Activators powder or .dust-like material, improperhandlingcanlead combustion (dust explosions).

to spontaneous

--REGULATORY INFORMATION -None reported.

--IDENTIFIERS -ChemicalNameandSynonyms:TETRAMETHYL-MONOSULFIDE Trade NameandSynonyms:

Monex

ChemicalFamily: Thiuram Manufacturer: UniroyalChemicalCo.,Middlebury,Connecticut

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA -%

No. Cas Material Thiuram

97-74-5

--PHYSICAL DATA -BoilingPoint (“F):NA = 1): 1.38

SpecificGravity

VaporPressure(mmHg):

NA

Percent Volatile by Volume (%): Low VaporDensity(air = FreezingPoint:

NA

NA

TLV Not established

248

Chapter 4

EvaporationRate: p H NA Solubility inWater: Insoluble in water. Solublein acetone, benzene,and ethylene dichloride. MeltingPoint(“C):

106

Appearance/Color/Odor: Yellow pellets or powder with characteristic odor.

- FIRE AND EXPLOSION HAZARDS --FlashPoint: 355°F (179°C)TCC FlammabilityLimits: AutoignitionTemperature: DecompositionTemperature: Extinguishing Media: Foam, dry chemical, carbon dioxide, or water. SpecialFireFightingProcedures: withmany solids, any dust that is generated may be explosive if mixed with air in critical proportions and in the presence of a source of ignition. Use water, carbon dioxide, or dry chemical to extinguish fires. Wear self-contained, positive-pressure breathing apparatus. Unusual Fire and Explosion Hazards: Dust may be explosive if mixed with air in critical proportions and in the presence of a source of ignition. The hazard is similar to that of any organic solid including sawdust. Maintain normal good housekeeping for control of dust. Hazardous Productsof Combustion andDecomposition:Thermal decomposition may produce carbon monoxide and/or carbon dioxide. HazardousPolymerization: Willnot occur.

Accelerators and Activators

249

--HEALTH HAZARD DATA -Effects of Overexposure: Dust causes eyeirritation. Repeated minimal contact with skin may cause sensitization. Exposure can producean adverse reaction when alcohol is consumed and can affect the activity of certain prescription drugs; consult physician. Emergency Response and First Aid: Skin: Wash with lots clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consult physician immediately. CancerInformation: None reported.

--TOXICITY DATA -Animal Effects: Oral toxicity: LD50 (rats), 1.3 g/kg D e m l toxicity: LD50 (rabbits), >2g/kg Irritation: eye (rabbits), moderate skin (rabbits), negative Sensitization: skin-positive based on human experience Genotoxicity: Ames Salmonella, positive L5 178Y mouse lymphoma, negative Balb13T3, cell transformation, negative Chronic: The feeding to miceofup to 337ppm for 18 months did not produce an increased tumor incidence.

--REACTIVITY DATA -Stability and Conditionsto Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. This material is considered stable. Materials to Avoid (Incompatibility): Strong oxidizing agents. Hazard Decomposition Products:Carbon dioxide, carbon monoxide,nitrogen, and/or oxides sulfur. HazardousPolymerization: Willnot occur.

Chapter 4

--

SPILL AND EMERGENCY RESPONSE

For Spills: Sweepup.Wash closed container.

residuals withsoapand

---

water. Transfer to a

Empty Containers: The container for this product can present explosionor fire hazards, evenwhenemptied. avoid the risk of injury, do not cut, puncture, or weld on or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection: Dustmask.

Type of Ventilation Required: Generalmechanical.Avoid

breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm.

EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other:

Rubber gloves, goggles.

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughlyclean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany

Accelerators and Activators

1

25

powder or dust-like material, improperhandlingcanlead combustion (dust explosions).

to spontaneous

--REGULATORY INFORMATION --None reported. v

v

v

v

v

v

v

v

v

v

v

v

v

v

--IDENTIFIERS --Name: HEXAMINE Synonyms: Methanamine; 1,3,5,7-Tetraazatricyclo[3.3.1.1 3,7]-Decane; 1,3,5,7-Tetraazaadamantane; Hexamethylene Tetramine; HMT; HMTA; Hexamethylenamine; Aminoform; Ammoform; Cystamin; Cystogen; Formin; Uritone; Urotropin; Ammonioformaldehyde; Formamine; Hexaform; Hexilmethylenamine;Methenamine;Urotropine CAS: 100-97-0; RTECS: MN4725000 Formula: C6HH12N.,; MolWt: 140.22 WLN: T66 B6 A B- C 1B I BN DN FN HNTJ ChemicalClass: Aliphatic amine See other identifiers listed below under Regulations.

--PROPERTIES --Boiling Point: 553 K; 279.8"C;535.7"F Melting Point: 563 K;289.8OC; 553.7"F FlashPoint: 523 K; 249.8"C; 481.7OF Autoignition: NA UEL: NA LEL: NA VaporDensity: No data SpecificGravity: Nodata Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data NeutralizingAgents: No data PolymerizationPossibilities: No data

252

Chapter 4

Toxic Fire None reported other than possible unburned vapors Odor Detected at (ppm): Not pertinent Odor Description: Mild, ammonia-like(Source:CHRIS) 100% Odor Detection: Nodata

- REGULATIONS -DOT hazard class: 4.1 FLAMMABLE SOLID DOT guide: 32 Identificationnumber: UN1328 DOT shipping name: HEXAMINE Packing group: III Label@)required: FLAMMABLESOLID Special Provisions: A1 Packaging exceptions: 173.151 Nonbulk packaging: 173.213 Bulk packaging: 173.240 Quantity limitations: Passenger airhail: 25 kg Cargo aircraft only: 100 kg Vesselstowage: A STCC Number: Notlisted Clean Water Act Sect. 307:No 311:No Clean Water Act Clean Air Act:Notlisted EPA Waste Number: None CERCLA Ref: Notlisted RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: adverse effect to target organs. Fire hazard: flammable.

U.S. Postal Service Mailability:

Not given

NFPA Codes: Health Hazard (blue): Unspecified Flammability (red): Unspecified Reactivity (yellow): Unspecified Special: Unspecified

Accelerators and Activators

253

--TOXICITY DATA Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

TargetOrgans: Skin, eyes, mucousmembranes Symptoms: Prolonged and repeatedcontact may cause skin irritation. (Source: CHRIS) Conc IDLH Unknown

NOSH REL: Not given ACGIHTLV: Not listed ACGIH STEL: Not listed OSHA PEL Not in Table Z-l-A

MAK Information: Not listed Carcinogen: N; Status: See below CarcinogenLists: Z A R C Not listed; Not listed; NZOSH Not listed; N T P Not listed; ACGZH Not listed; OSHA: Not listed. LDS0 Value: No LD50 in RTECS 1992 OtherSpeciesToxicityData: scu-rat LDLo:200 mg/kg ivn-rat LD50:9200 mg/kg par-rat LDLo:200 mg/kg scu-mus LD50:215 mg/kg par-mus LDLo:450 mg/kg scu-cat LDLo:200 mg/kg par-cat LDLo:200 mg/kg scu-gpg LDLo:300 mg/kg par-mam LDLo:300 mg/kg

(Source:NIOSHRTECS1992)

Reproductive Toxicity (1992 RTECS): This chemical has no known malian reproductive toxicity.

mm-

Chapter 4

254

--

PROTECTION AND FIRST AID

--

FirstAidSource: CT THIC Eye: Flushwithwater. Skin: Wash with soap and water. Inhalation: None given. Ingestion: Gastric lavage followed by saline catharsis.

First AidSource: CHRISManual1991. Wash skin or eyes thoroughly with water. Call a physician.

First Aid Source: DOT Emergency Response Guide 1993. Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min. Removal of solidified molten material from skin requires medical assistance. Remove and isolate contaminated clothing and shoes at the site.

--- INITIAL INCIDENT RESPONSE -Fire Extinguishment: (CHRIS 91)

Water, foam, carbon

dioxide, dry chemical.

U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT ShippingName: HEXAMINE DOT ID Number: UN1328 ERG90

* POTENTIAL HAZARDS *

GUIDE 32

*Health Hazards Fire may produce irritating or poisonous gases. Contact may cause bums to skin and eyes. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Flammablekombustible material; may be ignited by heat, sparks, or flames. May bum rapidly with flare-burning effect.

Accelerators and Activators

255

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection. CALLCHEMTRECAT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Small fires: Dry chemical, sand, earth, water spray, or regular foam. Large fires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holderor monitor nozzles; if this is impossible, withdraw from area and let fire bum. Magnesiumfires: Use dry sand, Met-L-X R powder,or G-lgraphite powder. *Spill or Leak Shut off ignition sources; no flares, smoking, or flames in hazard area. Do not touch or walk through spilled material. Small dry spills: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Wet down with water and dike for later disposal. *First Aid Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min. Removal of solidified molten material from skin requires medical assistance. Remove and isolate contaminated clothing and shoes at the site.

--- IDENTIFIERS -Name:ZINC ETHnPHENYLDITHIOCARBAMATE Synonyms: Accelerator EFK;Fenyl-EthyldithiokarbaminanZinfonaty (Czech); Hermat Fedk; Vulkacit P Extra N; Zinc, Bis(Ethylpheny1carbamodithioato(T-4)- (9CI); Zinc Ethylphenyldithiocarbamate; ZincEthylphenylthiocarbamate

Chapter 4

256 CAS:14634-93-6; RTECS: ZH0890000 Formula: C,,H,N,S,Zn; MolWt: 458.01 Chemical Class: Organicacid salt See other identifiers listed below under Regulations.

--PROPERTIES -BoilingPoint: NA MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density:No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities:No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--- REGULATIONS -DOT hazard class: Not given Packaging exceptions: 173. Nonbulk packaging: 173. Bulkpackaging: 173. STCC Number: Not listed Clean Water Act Sect. 307: Yes Clean Water Act Sect. 311: No Clean Air Act:Not listed EPA Waste Number: None CERCLA Ref: Not listed

Accelerators and Activators

257

RQDesignation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant. Chronic toxicity: mutagen. Listed inSARA Sect. 313: Yes De Minimus Concentration: 1.O%

U.S. Postal Service Mailability:

Not given

--- TOXICITY DATA --Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

Conc IDLH Unknown NIOSHREL: Not given ACGIHTLV: Not listed ACGIHSTEL: Not listed OSHAPEL: Not in Table MAK Information: Notlisted Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; MAK: Not listed; NZOSH. Not listed; N T P Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: orl-rat LD50:10800mg/kg OtherSpeciesToxicityData: (Source:NIOSHRTECS1992) orl-rat LD50: 10800 mg/kg ipr-mus LD50:533 mg/kg Reproductive Toxicity (1992 RTECS): This chemical has no known malian reproductive toxicity.

mam-

258

Chapter 4

--- PROTECTION AND FIRST AID --Recommended Respiration Protection Source:NIOSH Pocket Guide(85-114) OSHA(Zinc Ethylphenyldithiocarbamate) 2000 ppm: Any supplied-air respirator. Any self-contained breathing apparatus. 5000ppm: Any supplied-air respirator operated in a continuous-flow mode. 10,000ppm: Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. Any supplied-air respirator with a tight-fitting facepiece operated in a continuous-flow mode. 25,000ppm: Any supplied-air respirator with a full facepiece and operated in a pressure-demand or other positive-pressure mode. Emergency orplanned entry in unknown concentrationsor IDLH conditions: Any self-contained breathing apparatus with a full facepiece and operated in pressure-demand a or other positive-pressure mode. Any supplied-air respirator with a full facepiece and operated in a pressure-demand or other positive-pressure modeincombinationwith an auxiliary self-contained breathing apparatus operated in a pressure-demand or other positive-pressure mode. Escape: Any appropriate escape-typeself-contained breathing apparatus.

--

INITIAL INCIDENT RESPONSE

---

No DOT Guide information for this product.

Name:CARBAMICACID, DIMETHYLDITHIO-, COPPER (11)SALT Synonyms: Compound4018; Copper, Bis(Dimethy1dithiocarbamato)-; Copper Dimethyldithiocarbamate; Cumate; Dimethyldithiocarbamic Acidcopper Salt; Wolfen CAS: 137-29-1; RTECS: FA0175000 Formula: C,H,,N,S, .Cu; Mol Wt: 303.98 WLN: SUYSHNl ChemicalClass: Organicacid salt See other identifiers listed below under Regulations.

Accelerators and Activators

--PROPERTIES -Boiling Point: NA Melting Point: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density:No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: Oxides of nitrogen Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--REGULATIONS --DOT hazard class: Not given Packaging exceptions: Nonbulk packaging: Bulkpackaging: STCC Number:

Not listed

Clean Water ActSect. Yes Clean Water Act Sect. 311: No Clean Air Act:Not listed EPA Waste Number: None CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value: Not listed Categories: SARA Sect. Chronic toxicity: adverse effect to target organs after longperiodsof exposure. Chronic toxicity: mutagen.

Chapter 4

ListedinSARA 313: Yes De Minimus Concentration: 1.O % U.S. Postal Service Mailability: Not given

--TOXICITY DATA Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

ConcIDLH. Unknown

NOSH REL: Not given ACGIHTLV: TLV = fume, 0.2 mg/m3; dust and mists, 1 mg/m3 as copper ACGIHSTEL: copper

OSHA PEL: Transitional limits: PEL = (fume) 0.1 mg/m3; (dust and mists) 1mg/m3; Final Rule Limits: = (fume) 0.1 mg/m3; (dust and mists) 1 mg/m3.

MAK Information: Not listed Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; M A K Not listed; NZOSH: Not listed; NTP: Not listed; ACGZH Not listed; OSHA: Not listed.

LD50 Value: No LD50 in RTECS 1991 Other SpeciesToxicity Data: (Source: NIOSH RTECS 1992)

ihl-rat LCLo:210 mg/m3/4H ipr-rat LDLo:25 mg/kg ipr-mus LDLo:7800 rngkg

ReproductiveToxicity (1993 RTECS): Thischemical reproductive toxicity.

--

INITIAL INCIDENT RESPONSE NO DOT Guide information this product.

has

--

mammalian

Accelerators and Activators

26 1

--IDENTIFIERS Name: 2-BENZOTHIAZOLETHIOL Synonyms: Captax; MBT; 2-Mercaptobenzothiale; NCI-C56519; Rotax; Sul Fadene; USAF GY-3; USAF XR-29 CAS:149-30-4; RTECS: DL6475000 Formula: C,H,NS,; Mol Wt: 167.25 WLN: T56 BNDSJCSH Chemical Class: Azole See other identifiers listed below under Regulations.

- PROPERTIES -BoilingPoint: NA Melting Point: 443 K; 169.8"C; 337.7OF FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density: No data SpecificGravity: No data Density: 1.42 at25°C Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents:No data PolymerizationPossibilities: Nodata Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

- REGULATIONS -DOT hazard class: 6.1 POISON DOT guide: 53 Identification number: UN2811

Chapter 4 DOT shipping name: POISONOUS SOLIDS, N.O.S. Packinggroup: I11 Label(@ required: KEEP FROMFOOD Packaging exceptions: Nonbulk packaging: Bulkpackaging: Quantity limitations: Passenger airhail: kg Cargo aircraft only: kg Vesselstowage: STCC Number: Not listed 307: No Clean Water Act Clean Water Act Sect. 311: No Clean Air Act:Not listed EPA WasteNumber: None CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: toxic. LD50 > 50 and Chronic toxicity: mutagen. Chronic toxicity: reproductive toxin.

U.S. Postal Service Mailability:

< = 500 mg/kg (oral rat).

Not given

--TOXICITY DATA Short-term Toxicity: Unknown Long-term Toxicity: Unknown Conc IDLH Unknown

NIOSH REL: Not given. ACGIH TLV: Not listed ACGIH STEL: Not listed

OSHA P E L Not in Table

Accelerators and Activators

263

MAK Information: Not listed Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; M A K Not listed; NZOSH Not listed; M P : Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: orl-rat LD50:lOO mgkg OtherSpeciesToxicityData: (Source:NIOSHRTECS orl-rat LD50: 100 mg/kg ihl-rat LC50: > 1270 mg/m3 ipr-rat LD50:300 mg/kg orl-mus LD50: 1851 mgkg ipr-mus LD50: 100 mg/kg scu-mus LD50: 1158 mg/kg skn-rbt LD50: > 7940 mg/kg ReproductiveToxicity(1992RTECS): reproductive toxin.

1992)

Thischemicalisamammalian

Reproductive Toxicity Data (1992 RTECS): par-rat TDLo:800 mg/kg (2D male/2D pre) BEXBAN 93, 107, 82 Effects on Fertility Post-implantation mortality Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Fetal death par-rat TDLo:400 mgkg (4-1 1D preg) BEXBAN 93, 107, 82 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Fetal death

--PROTECTION AND FIRST AID -FirstAidSource: DOTEmergencyResponseGuide 1993. Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min. Remove and isolate contaminated clothing and shoes at the site.

Chapter 4

--INITIAL INCIDENT RESPONSE -U S . Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOTShippingName: POISONOUS SOLIDS, N.O.S. DOT ID Number: UN281 1

ERG90

53

* POTENTIAL HAZARDS *

*Health Hazards Poisonous if swallowed. Inhalation of dust poisonous. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Someof these materials may bum, butnoneofthem

ignites readily.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters' protective clothing will provide limited protection. CALLCHEMTRECAT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Smallfires: Dry chemical, COz, water spray, or regular foam. Large fires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. *Spill or Leak not touch or walk through spilled material; stop leak if you can do it without risk. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small dry spills: With clean shovel, place material into clean, dry container and cover; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal.

Accelerators and Activators

265

*First Aid Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min. Remove and isolate contaminated clothing and shoes at the site.

- IDENTIFIERS -Name:2-BENZOTHIAZOLETHIOL,ZINCSALT Synonyms: Bis(2-Benzothiazoly1thio)Zinc; Bis(Mercaptobenzothiazo1ato)Zinc; Hermat Zn-MBT; 2-Mercaptobenzothiazole Zinc Salt; OXAF; Pennac ZT; Tisperse MB-58; USAF GY-7;Vulkacit ZM; Zenite; Zenite Special; Zetax; Zinc 2-Benzothiazolethiolate; Zinc Benzothiazolyl Mercaptide; Zinc Benzothiazol-2-Ylthiolate; Zinc Benzothiazyl-2-Mercaptide; Zinc, Bis(2Benzothiazolethio1ato)-; Zinc Mercaptobenzothiazolate; Zinc Mercaptobenzothiazole;ZincMercaptobenzothiazole Salt; ZMBT;ZnMB CAS: 155-04-4; RTECS: DL7000000 Formula: C,,H,N,S, . Zn; MolWt: WLN: T56 BN DSJ CSH ChemicalClass: Organicacid salt See other identifiers listed below under Regulations.

--PROPERTIES -BoilingPoint: NA MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA VaporDensity: No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data PolymerizationPossibilities: No data

Chapter 4 Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--REGULATIONS --DOT hazard class: Not given Packaging exceptions: 173. Nonbulk packaging: 173. Bulkpackaging: 173. STCC Number: Not listed Clean Water Act Sect. 307: Yes Clean Water Act Sect. 311: No Clean Air Act:Notlisted EPA Waste Number: None CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value: Not listed SARASect. 312 Categories: Nocategory Listed in SARA Sect. 313: Yes De Minimus Concentration: 1.O%

U.S. Postal Service Mailability:

Not given

--TOXICITY DATA --Short-term Toxicity: Unknown Long-term Toxicity: Unknown Conc IDLH Unknown NOSH REL: Notgiven ACGIH TLV: Not listed ACGIH STEL: Not listed OSHA PEL: Not in Table Z-l-A

Accelerators and Activators

267

MAKInformation: Not listed Carcinogen: N; Status: Seebelow CarcinogenLists: I A R C Not listed; MAK: Not listed; NIOSH Not listed; A T P Not listed; ACGIH Not listed; OSHA: Not listed. LD50Value: orl-rat LD50540 mg/kg OtherSpeciesToxicityData: orl-rat LD50:540 mgkg ipr-mus LD50:200 mg/kg

(Source: NIOSH RTECS1992)

Reproductive Toxicity (1992 RTECS): malian reproductive toxicity.

--

This chemical has no

INITIAL INCIDENT RESPONSE

known mam-

---

No DOT Guide information for this product.

--IDENTIFIERS -Name:UREA,1,3-DIETHYL-2-THIOSynonyms: N,N'-Diethylthiocarbamide; N,N'-Diethylthiourea; 1.3-Diethylthiourea; 1,3-Diethyl-2-Thiourea;NCI-C03816; Pennzone E; Thiate H; Thiourea, N,N'-Diethyl-; U 15030; USAF EK-1803 CAS: 105-55-5; RTECS: YS9800000 Formula: C5H,2NZS;Mol Wt: 132.25 WLN: SUYMl See other identifiers listed below under Regulations.

--- PROPERTIES -BoilingPoint: NA Melting Point: 349.16 TO 351.16 K; 76 to 78°C; 168.8 to 172.4"F FlashPoint: NA Autoignition: NA UEL: NA LEL: NA

Chapter 4

268

Vapor Density: No data Specific Gravity: Nodata Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--REGULATIONS --DOT hazard class: Not given Packaging exceptions: 173. Nonbulkpackaging: 173. Bulkpackaging: 173. STCC Number: Not listed Clean Water Act Sect. 307: No Clean Water Act Sect. 311: No Clean Air Act:Notlisted EPAWasteNumber: None CERCLA Ref:Notlisted RQ Designation: Notlisted SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: toxic. LD50 > 50 and Chronic toxicity: mutagen. U.S. Postal Service Mailability:

< = 500 mg/kg(oral

Not given

- TOXICITY DATA -Short-term Toxicity: Unknown Long-termToxicity:

Unknown

rat).

269

Accelerators and Activators

ConcIDLH:

Unknown

NIOSH REL: Not given ACGIHTLV: Not listed ACGIHSTEL: Notlisted OSHA PEL: Not in Table Z-l-A MAK Information: Notlisted Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; MAK: Not listed; NZOSH Not listed; N T P Not listed; ACGZH Not listed; OSHA: Not listed. LDS0Value: orl-rat LD50:316 mg/kg Other Species ToxicityData: (Source: NIOSHRTECS1992) orl-rat LD50:316 mg/kg orl-mus LDLo:62 mg/kg ipr-mus LD50:500 mg/kg Reproductive Toxicity (1992 RTECS): This chemical has no known mammalian reproductive toxicity.

- INITIAL INCIDENT RESPONSE --No DOT Guide information for this product.

--IDENTIFIERS -Name: BIS(DMETHYLTFIIOCARBAMYL)DISULFIDE Synonyms: Thiram; Bis((Dimethy1amino)Carbonothioyl)Disulphide; Disolfuro Di Tetrametiltiourame (Italian); Disulfure De Tetramethylthiourame; Alpha, Alpha’-Dithiobis(Dimethylthi0) Formamide; N,N”(Dithiodicarborothioyl)Bis(N-Methyl-Methanamine);MethylThiuramdisulfide;TetramethylThiuram Disulfide; Tetramethyl DiuraneSulphite;Tetramethylene Thiuram Disulphide; Tetramethylthiocarbamoyl Disulphide; Tetramethylthioperoxydicarbonic Diamide; Tetramethyl Thioram Disulfide (Dutch); Tetramethyl-Thiram

270

Chapter

Disulfid (German); Tetramethylthiuram Bisulfide; Tetramethylthiuram Disulfide; N,N,N',N'-Tetramethyl Thiuram Disulfide; Tetramethyl Thiurane Disulfide; Tetramethylthiuram Disulfide; Thiram; Tiuram (Polish); USAF B30; USAFEK-2089;USAF P-5; TMTD; ENT 987; SQ 1489; NSC 1771; Thiurad; Thiosan; Thylate; Tiuramyl; Thiuramyl; Duralyn; Fernasan; Nowergan; Pezifilm; Pomarsol; Tersan; Tuads; Tulisan; Arasan; HCDB CAS:137-26-8; RTECS:J01400000 Formula: C,H,,N,S,; Mol Wt:240.44 WLN: 1N1 Chemical Class: Organic sulfide See other identifiers listed below under Regulations.

--PROPERTIES PhysicalDescription: Colorless to cream solid (somecommercialproducts dyed blue) Boiling Point: Decomposes Melting Point: 413.15 K;140°C;284°F Flash Point: 362 K; 88.8"C;191.9"F Autoignition: NA Vapor Pressure: About mm UEL: NA LEL: NA Vapor Density: No data Specific Gravity: 1.43 at 20°C Density: 1.43 g/cc or 13.299 lb/gal Water Solubility: INSOL Incompatibilities: Strong oxidizers, strong acids, oxidizable materials Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: Oxides of nitrogen, oxides of sulfur Odor Detected at (ppm): Data not available Odor Description: Datanot available (Source:CHRIS) 100% Odor Detection: No data

Accelerators and Activators

27 1

--REGULATIONS --DOT hazard class: CLASS 9 DOT guide: 31 Identificationnumber: UN3077 DOT shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. Packinggroup: I11 Label(s)required: CLASS 9 SpecialProvisions: 8, B54 Packaging exceptions: 173.155 Nonbulkpackaging: 173.213 Bulkpackaging: 173.240 Quantity limitations: Passenger airhail: None Cargo aircraft only: None Vesselstowage:A STCC Number: 4921632, 4921631, 4921634, 492133 Clean Water Act 307: No Clean Water Act Sect. 311: No Clean Air Act:Not listed EPA Waste Number: U244 CERCLARef: Y R Q Designation: A, lb (4.54 kg) CERCLA SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: toxic. LD50 > 50 and < = 500 mg/kg (oral rat). Acute toxicity: irritant. Acute toxicity: adverse effect to target organs. Chronic toxicity: adverse effect to targetorgans after long periods of exposure. Chronic toxicity: reproductive toxin. U.S. Postal Service Mailability: Hazardclass:ORM-A Mailability: Domestic service and air transportation; shipper’s declaration Max per parcel: 70 lb; 5 lb (air)

Chapter 4

NFPA Codes: HealthHazard (blue): Unspecified Flammability(red): Unspecified Reactivity (yellow): Unspecified Special: Unspecified

- TOXICITY DATA -Short-termToxicity: Inhalation: No informationonhumanexposure is available. Animal studies indicate that irritation of the nose and throat may occur at levels above 5 mg/m3. Eyes: May cause irritation, tearing, and sensitivity to light. Skin: Exposure to spray containing 45 % thiram resulted in irritation and skin sensitization. Zngesrion: No information available human exposure. In animal studies, ppm in food caused nausea, vomiting, diarrhea, hyperexcitability, weakness, and loss of muscle control. Death may occur from ingestion of approximately one teaspoonful. (NYDH) Long-term Toxicity: Occupational exposure to 0.03 mg/m3 over a 5-yr period hascausedmild irritation of the noseand throat. Prolonged contact has causedeye irritation, tearing, increased sensitivity to light, reduced night vision, and blurred vision. Thiramhascaused birth defects in laboratory animals. Whether it has this effect in humans is not known. (NYDH) Target Organs: Skin, mucous membranes, kidneys, respiratory system, lungs. Symptoms: Inhalation of dust may cause respiratory irritation. Liquid irritates eyesand skin andmaycause allergic eczema in sensitive individuals. Ingestion causes nausea,vomiting,and diarrhea, allofwhichmaybz persistent; paralysis may develop. (Source:CHRIS) Conc IDLH 1500 mg/m3 ACGIH TLV:TLV = 1 mg/m3 ACGIH STEL: Not listed

OSHA PEL: Transitional Limits: PEL = 5 mg/m3; Final Rule Limits: TWA = 5 mg/m3.

MAK Information: 5 calculated as total dust, mg/m3; Substance with systemic effects; onset of effect less than or equal to 2 hr: Peak = 5xMAK for 30 min. 2 times per shift of 8 hr.

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273

Carcinogen: N; Status: Seebelow References: Animal indefinite IARC** 12,225,76;Human indefinite IARC** 12, 225, 76 CarcinogenLists: ZARC: Not classified as to human carcinogenicity or probably not carcinogenic to humans; MAK. Not listed; NIOSH. Not listed; N T P Not listed; ACGIH. Not listed; OSHA: Not listed. HumanToxicityData: (Source:NIOSHRTECS) ihl-hmn TCLo:30 mg/m3/5Y-I VRDEA5 (lo), 136, 71 Sense Organs Eye Conjunctive irritation Cardiac Other changes Lungs, Thorax, or Respiration Structural or functional changes in trachea or bronchi LDS0 Value: orl-rat LD50:560 mg/kg

OtherSpeciesToxicityData: (Source:NIOSHRTECS1992) orl-rat LD50:560 mgkg ihl-rat LC50500 mg/m3/4H skn-rat LD50: >5 g/kg ipr-rat LD50: 138 mg/kg scu-rat LD50:646 mg/kg unr-rat LD50:740 mg/kg orl-mus LD50: 1350 mg/kg ipr-mus LD50:70 mg/kg scu-mus LD50: 1109 mgkg unr-mus LD50: 1150 mgkg orl-cat LDLo:230 mg/kg orl-rbt LD50:210 mg/kg skn-rbt LDLo:l g/kg unr-rbt LD50:210 mg/kg unr-ckn LD50:840 mg/kg unr-dom LD50:225 mg/kg unr-mam LD50:400 mg/kg orl-bwd LD50:300 mg/kg ReproductiveToxicity reproductive toxin.

(1992 RTECS):

Thischemical

is amammalian

274

Chapter 4

Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo:1200 mg/kg (7-12D preg) TXAPA9 35, 83, 76 Effects on Fertility Preimplantation mortality Postimplantation mortality Litter size (number of fetuses per litter; measured before birth) orl-rat TDLo:300 mg/kg (15D preg) GISAAA 43(6), 37, 78 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Fetal death Specific Developmental Abnormalities Other developmental abnormalities TDh:1190 mg/kg (16-22D preg/21D post) TXAPA9 35, 83, 76 Effects on Newborn Growth statistics (e.g., reduced weight gain)

0d-m

orl-rat TDLo:550 mgkg (1-22D preg) AEEDDS 2, 215, 76 Effects on Newborn Behavioral orl-rat TDLo:420 mgkg (1-20D preg) GISAAA 51(6), 23, 86 Specific Developmental Abnormalities Cardiovascular (circulatory) system par-rat TDLo:400 mgkg (4-1 1D preg) BEXBAN 93, 107, 82 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Fetal death par-rat TDLo:800 mgkg (2D male/2D pre) BEXBAN 93, 107, 82 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Fetal death orl-mus TDLo:100 mg/kg (6-15D preg) ATXKA8 30, 251, 73 Specific DevelopmentalAbnormalities Craniofacial (including nose and tongue) Musculoskeletal system

Accelerators

275

orl-mus TDLo:300 mg/kg (6-15D preg) ATXKA8 30, 251, 73 Effects Fertility Postimplantation mortality orl-mus TDLo:80 mg/kg (3D male) FCTOD7 25, 709, 87 Paternal Effects Spermatogenesis

~

i

scu-mus TDLo:90 mg/kg (6-14D preg) NTIS** PB223-160 Effects on Fertility Preimplantation mortality Litter size (number of fetuses per litter; measured before birth) Effects Embryo or Fetus Extra embryonic features (e.g., placenta, umbilical cord) scu-mus TDLo: 1035 mg/kg (6-14D preg) NTIS** PB223-160 Effects Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) orl-ham TDLo:125 mg/kg (7D preg) TXAPA9 15, 152, 69 Specific Developmental Abnormalities Musculoskeletalsystem orl-ham TDLo:250 mg/kg (8D preg) TXAPA9 15, 152, 69 Specific Developmental Abnormalities Craniofacial (including nose and tongue) orl-ham TDLo:250 mg/kg (7D preg) TXAPA9 15, 152, 69 Specific Developmental Abnormalities Body wall orl-ham TDLo:300 mg/kg (7D preg) TXAPA9 15, 152, 69 Specific Developmental Abnormalities Central nervous system

--- PR0"ION

AND FIRST AID

--

NOSH Pocket Guide to Chemical Hazards: **WearAppropriate Equipmentto Prevent: Reasonable probability of skin contact.

**WearEye Protection to Prevent: Reasonable probability of eye contact.

276

**Exposed Personnel Should Wash: contaminated.

Chapter 4 Promptly when

skin becomes

**Work Clothing Should be Changed Daily: If there is any reasonable possibility that the clothing may be contaminated. **Remove Clothing:Promptly remove nonimperviousclothing that becomes contaminated. **Reference: NIOSH Recommended Respiration Protection Source:NIOSH Pocket Guide(85-1 14) OSHA (Bis(Dimethylthiocarbamy1) Disulfide) 50 mg/m3: Any chemical cartridge respirator with organic vapor cartridge(s) in combination witha dust, mist, and fume filter. Substance reportedto cause eye irritation or damage; may requireeye protection. Any supplied-air respirator. Any self-containedbreathingapparatus. 125 m g / d : Any poweredair-purifying respirator with organic vapor cartridge(s) in combination with a dust, mist, and fume filter. Any suppliedair respirator operatedin a continuous-flowmode.Substancereported to cause eye imtation or damage; may require eye protection. 250 mg/m3: Any selfcontained breathing apparatus with a full facepiece. Any chemical cartridge respirator with a full facepiece and organic vapor cartridge@) incombinationwith a high-efficiencyparticulate filter. Any supplied-air respirator with a full facepiece. Any powered air-purifying respirator with a tight-fittingfacepieceand organic vapor cartridge(s) in combination with a high-efficiency particulate filter. Substance reported to cause eye irritation or damage; may require eye protection. Any air-purifying full facepiece respirator (gasmask)with a chin-style or front- or backmounted organic vapor canister having a high-efficiency particulate filter. 1500 m g / d : Any supplied-air respirator with a full facepiece and operated in a pressure-demand or other positive-pressure mode. Emergency or planned entry in unknown concentrations or ZDLH conditions: Any self-contained breathing apparatus with a full facepiece and operated in a pressure-demand or other positive-pressuremode. Any supplied-air respirator with a full facepiece and operated in a pressuredemand or other positive-pressuremodeincombinationwithanauxiliaryself-contained breathing apparatus operated ina pressuredemand orother positive-pressure mode.

Accelerators and Activators

277

Escape: Any air-purifying full facepiece respirator (gas mask) with a chinstyle or front- or back-mountedorganicvapor canister havingahighefficiency particulate filter. Any appropriate escape-type self-contained breathing apparatus.

First AidSource: HCDB Eye: Wash with water; if irritation persists, consult a physician. Skin: Wash with water; if irritation persists, consult a physician. Inhalation: Remove victim from exposure. If breathing has stopped or is difficult, give artificial respiration and call physician. Ingestion: Call physician; inducevomitingandflowwith gastric lavage; treatment thereafter is symptomatic and supportive; avoid fats, oils, and lipid solvents, which enhance absorption; rigorously prohibit ethyl alcohol in all days; inform doctor if patient has used alcohol within forms for at least 48 hr.

First AidSource: CHRISManual1991. Inhalation: Removevictimfromexposure;if breathing has stopped or is difficult, give artificial respiration and call physician. Eye and skin: Wash with water; if irritation persists, consult a physician. Ingestion: Call physician; induce vomiting and follow with gastric lavage; treatment thereafter is symptomatic and supportive; avoid fats, oils, and lipid solvents, which enhance absorption; rigorously prohibit ethyl alcohol in all forms for at least 10 days; inform doctor if patient has used alcohol within 48 hr. First Aid Source: DOT Emergency Response Guide 1993. In case of contact with material, immediately flush eyes with running water for at least 15 min.Wash skin withsoapandwater.Removeand isolate contaminated clothing and shoes at the site.

- INITIAL INCIDENT RESPONSE -FireExtinguishment: Water, dry chemical, carbon dioxide. (CHRIS91) U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. DOT ID Number: UN3077

Chapter 4

278

ERG90

GUIDE 31

* POTENTIAL HAZARDS *

*Health Hazards Contact may cause bums to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Someof these materials may bum, butnoneofthem

ignites readily.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters' protective clothing will provide limited protection. CALLCHEMTRECAT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Smallfires: Dry chemical, COz, water spray, or regular foam. Lm-gefires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. Do not scatter spilled material with high-pressure water streams. Dike fire-control water for later disposal. *Spill or Leak Stop leak if you can do it without risk. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Small dry spills: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal. Cover' powder spill with plastic sheet or tarp to minimize spreading.

*First Aid In case of contact with material, immediately flush skin or eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

Accelerators and Activators

--IDENTIFIERS -ChemicalNameandSynonyms:1,3-DIPHENYL-2-THIOUREA Trade NameandSynonyms:

Thiocarbanilide

ChemicalFamily: Rubber Accelerator Manufacturer: Monsanto Co., Akron, Ohio UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA -Material

No. Cas

Product Not

%

TLV

NA

established

--PHYSICAL DATA BoilingPoint (“F):NA Specific Gravity (H20= 1): 1.32 VaporPressure(mmHg):

NA

Percent Volatile by Volume (%): Low VaporDensity(air FreezingPoint:

= 1):

NA

EvaporationRate: NA p H NA

Solubility in Water: Negligible MeltingPoint(“C):

NA

Appearance/Color/Odor: Greypowder,aromatic

odor.

Chapter 4

--- FJRE AND EXPLOSION HAZARDS -FlashPoint: FlammabilityLimits: Autoignition Temperature: DecompositionTemperature:

NA

Extinguishing Media: Foam, dry chemical, carbon dioxide, or water. SpecialFireFightingProcedures: withmany solids, any dust that is generated may be explosive if mixed with air in critical proportions andin the presence of a source of ignition. Use water, carbon dioxide, or dry chemical to extinguish fires. Wear self-contained, positive-pressure breathing apparatus. Unusual Fire and Explosion Hazards: Dust may be explosive if mixed with air in critical proportions and in the presence of a source of ignition. The hazard is similar to that of any organic solid including sawdust. Maintain normal good housekeeping for control of dust. Hazardous Productsof Combustion and Decomposition:Thermal decomposition may produce carbon monoxide and/or carbon dioxide. Hazardous Polymerization: Will not occur.

- HEALTH HAZARD DATA -Effects of Overexposure: Dust causes eyeirritation. Repeated minimal contact with skin may cause sensitization. Exposure can produce an adversereaction when alcohol is consumed and can affect the activity of certain prescription drugs; consult physician. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately.

Accelerators and Activators

28

CancerInformation: None reported.

--TOXICITY DATA -Animal Effects: None reported by manufacturer

--REACTIVITY DATA -Stability and Conditionsto Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. This material is considered stable. Materials to Avoid (Incompatibility): None reported by manufacturer. Hazard Decomposition Products:Carbon dioxide, carbon monoxide,nitrogen, and/or oxides of sulfur. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE -ForSpills: Sweep up. Wash residuals withsoapand closed container.

water. Transfer to a

Empty Containers: The container for this product can present explosionor fire hazards, evenwhenemptied. To avoid the risk of injury,do not cut, puncture, or weld or near this container.

--- SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection:

Dustmask.

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves andOther: Rubber gloves, goggles.

282

Chapter 4

Storage andHandlingPrecautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause anexplosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for goodpersonalhygiene. Completely isolate andthoroughlyclean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dust-like material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--

REGULATORY INFORMATION

--

None reported.

ChemicalNameandSynonyms:CARBAMIDE TradeNameandSynonyms:

BIK

ChemicalFamily: Rubber Accelerator Manufacturer: UniroyalChemical Co., Naugatuck,Connecticut

UN ID Number: NA

-Material Product Not

INGREDIENTS AND COMPOSITION DATA Cas No. NA

-TLV established

Accelerators and Activators

--- PHYSICAL DATA --Boiling Point (“F):Boils at 310’F (no flash) SpecificGravity (H,O = 1): 1.30 VaporPressure(mmHg):

NA

Percent Volatile by Volume (%): NA = 1): NA

VaporDensity(air FreezingPoint:

NA

EvaporationRate:

NA

p H NA Solubilityin Water: Partially MeltingPoint CC): Appearance/Color/Odor: White, free-flowing powder.

-- FIRE AND EXPLOSION HAZARDS --FlashPoint: NA FlammabilityLimits: NA AutoignitionTemperature: DecompositionTemperature:

NA NA

Extinguishing Media: Foam, dry chemical, carbon dioxide, or water. SpecialFireFightingProcedures: Aswithmany solids, any dust that is generated may be explosive if mixed with air in critical proportions and in the presence of a source of ignition. Use water, carbon dioxide, or dry chemical to extinguish fires. Wear self-contained, positive-pressure breathing apparatus.

Chapter 4

284

Unusual Fire and Explosion Hazards: Dust may be explosive if mixed with air in critical proportions and in the presence of a source of ignition. The hazard is similar to that of any organic solid including sawdust. Maintain normal good housekeeping for control of dust. Hazardous Productsof Combustion and Decomposition: Thermal decomposition may produce carbon monoxide and/or carbon dioxide. HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA Effects of Overexposure: Dust causes eye irritation. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots water. If irritation persists, consult a physician. Inhalation: Expose fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

--TOXICITY DATA -Animal Effects: None reported by manufacturer.

--REACTIVITY DATA -Stability and Conditions to Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. This material is considered stable. Materials to Avoid (Incompatibility): None reported by manufacturer. Hazard Decomposition Products:Carbon dioxide, carbon monoxide,nitrogen, and/or oxides of sulfur. HazardousPolymerization: Will not occur.

Accelerators and Activators

285

- SPILL AND EMERGENCY RESPONSE For Spills: Sweep up. Wash residuals withsoapand closed container.

water. Transfer to a

Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection:

Dustmask.

of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other:

Rubber gloves, goggles.

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate and thoroughly clean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany

Chapter 4

286

powder or dust-like material, improperhandlingcanlead combustion (dust explosions).

to spontaneous

--- REGULATORY INFORMATION --None reported.

--IDENTIFIERS -N,W-

ChemicalNameandSynonyms:1,S-DIPHENYLGUANIDINE; DIPHENYLGUANIDINE Trade Name and Synonyms: DPG ChemicalFamily: Rubber Accelerator Manufacturer: MonsantoChemicalCo.,

St. Louis, Missouri

UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA --Material

No. Cas

Product

%

102-06-7

--- PHYSICAL DATA -BoilingPoint (“F‘):NA SpecificGravity (H,O = 1): 1.2 VaporPressure(mmHg):

NA

Percent Volatile byVolume (%): NA VaporDensity(air FreezingPoint:

= 1): NA

NA

TLV Not established

Accelerators and Activators

EvaporationRate:

NA

p H NA Solubility in Water: Insoluble in water; soluble in acetone MeltingPoint (“C): 143 AppearancelColorlOdor: Off-white powder and pellets; oiled and nondusting powder. Has anaromatic odor.

--FIRE AND EXPLOSION HAZARDS -Flash Point: 315°F (Cleveland closed cup) FlammabilityLimits: NA AutoignitionTemperature: DecompositionTemperature:

NA NA

Extinguishing Media: Water spray or other Class A extinguishing media. SpecialFireFightingProcedures: Aswithmany solids, any dust that is generated may be explosive if mixed withair incritical proportions and in the presence of a source ofignition. Use water, carbon dioxide, or dry chemical to extinguish fires. Wear self-contained, positive-pressure breathing apparatus. Unusual Fire and Explosion Hazards: Dust may be explosive if mixed with air in critical proportions and in the presence of a source of ignition. The hazard is similar to that of any organic solid including sawdust. Maintain normal good housekeeping for control of dust. Hazardous Productsof Combustion andDecomposition:Thermal decomposition may producecarbonmonoxideand/orcarbondioxideandnitrogen oxides. Tetraphenylmelamine, aniline, triphenyldicarbimide and triphenylmelamine may also be liberated during a fire. HazardousPolymerization: Willnot occur.

Chapter 4

288

--HEALTH HAZARD DATA Effects of Overexposure: Dermal contact and inhalationare the primary routes occupational exposure. Occupational exposure to this material has not been reported to cause significant adverse human healtheffects. However, repeated or prolonged exposure to diphenylguanidine may causean allergic skin response in susceptible individuals. Emergency Response and First Aid: Skin: Wash with lots clean water for at least 15 min. Eyes: Flush eyes with lots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: None recommended. Consult physician immediately. CancerInformation: None reported.

--

TOXICITY DATA

--

Animal Effects: Data from Monsantostudiesand from the available scientific literature indicate the following: Oral LD50 (rat): 350 mg/kg, moderately toxic Dermal LD50 (rabbit): >794 mg/kg, moderately toxic Eye Irritation (rabbit):(FHSA) 20.2 on ascaleof 110.0, moderately irritating Skin Irritation (rabbit): (FHSA) 0.0 on a scale of 8.0, nonirritating Patch testing of 49 human volunteers with70 % DPG acceleratorin petrolatum produced no positive reactions following initial application; 19 of the 49 subjects displayed positive reactions during subsequent exposures. Four subjects exhibited positive reactions upon rechallenge 2 weeks later. Under the conditions this test, diphenylguanidine was consideredto be a potential skin sensitizer, and aweak cumulative irritant, but was not considered a primary irritant. Rats were given DPG accelerator at concentrations of 0, 300,500,800, 1500 and 3000 ppm in the diet for 2 weeks. Increases in mortality, reductions in body weight gain, piloerection, and ataxia were exhibited by the high-dosegroup animals. dose-relatedreduction in bodyweight gain and food consumption was also observed; the reductions were significant at dosages 500 ppm and above.

Accelerators and Activators

289

DPG accelerator was administered in the diet at concentrations of 0, 50, 150 or 500 ppm to groups of rats for 90 days. A reduction in body weight gain, alongwithreducedfoodconsumption,andchanges in organweightand organhody weight ratios wereobservedin the high-dose animals. No increases in mortality or abnormal clinical signs were observed. No increases in the incidences of gross or microscopic lesions were observed in treated animals. The no-effect level in this study was considered to be 150 ppm. teratology study was conducted in which mice were given diphenylguanidine by oral intubation at concentrations of 0.25, 1.0, 4.0 or 10.0 mg/kg days 0 through 18 of gestation. significant reduction in the mean number of implants in the high-dose group was observed. No adverse effects fetuses in the lower-dose groups were observed, and no teratogenic effects were noted in the study. Decreasedsperm counts, alterations in spermmorphology,microscopic changes in testicular tissue, and reduced fertility (in mice) were reported for miceandhamstersfollowingcontinuous(ad libitum) administration of diphenylguanidine at dietary concentrations equivalent to 4 or 8 mg/kg body weight. Testicular weightsweredecreased after 5 weeks of treatment. Changes in sperm were noted after 7 weeks of treatment. DPG accelerator was evaluated in the L5178Y TK mouse lymphoma mutation assay and in microbial mutagenicity assays. The microbial assays, both with and without microsomal activation, used five strains of Salmonella and one yeast strain. No mutagenic effects were observed. Environmental Toxicity Information: 96-hr LC50 Bluegill: 9.6 mg/l, moderately toxic 96-hrLC50 Trout: 11 mg/l, slightly toxic 96-hr LC50 Fathead Minnow: 4.2 mg/l, moderately toxic 96-hr EC50 Algae, cell count: 1.7 mg/l, moderately toxic 48-hr LC50 Daphnia: 17 mg/l, slightly toxic

--REACTIVITY DATA --Stability and Conditionsto Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. This material is considered stable. If strongly heated, may catch fire and give off toxic fumes. The material is stable to 160°F.

Chapter

Materials to Avoid (Incompatibility): None reported by manufacturer. Hazard Decomposition Products:Carbon dioxide, carbon monoxide,nitrogen, and/or oxides of sulfur. HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE -For Spills: Sweep up. Wash residuals withsoapand closed container.

water. Transfer to a

Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. avoid the risk of injury, do not cut, puncture, weld on or near this container.

--- SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection: Avoid breathing dust. Use NIOSH/OSHA approved equipment when airborne exposure is excessive. Full facepiece equipment is recommended and, if used, replaces the need for chemical splash goggles. Consult respirator manufacturer to determine appropriate type of equipment for given application. The respirator use limitations specified by NIOSH/MSHA or the manufacturermustbeobserved.High airborne concentrations may require the use of self-contained breathing apparatus or a supplied-air respirator. Respiratory protection must be in compliance with

CFR Although OSHA and ACGIH have established not specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PELB-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGZH ZZV/8-hr TKA: Total 10 mg/m3, respirable 5 rng/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 $m.

Accelerators and Activators

29 1

EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Rubber gloves, goggles. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause anexplosion. Keep containers closed. Store in a cool, dry place. Use with adequate.ventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughlyclean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dust-like material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--- REGULATORY INFORMATION -FDA Information: Diphenylguanidine is regulatedunder the FederalFood, Drug and Cosmetic Act, andapplicable regulations issued thereunder for use as a substance in the preparation of Rubber Articles Intended for Repeated Use,under 21 CFR177.2600,subject to the provisions, conditions and limitations in that regulation.

DOT Proper Shipping Name:

ORM-A, N.O.S. (via air on oiled product)

DOT Hazard C1asslI.D. No.: ORM-A/ NA1693 (via air on oiled product) DOTLabel: Not applicable

U.S. SurfaceFreightClassification:

Rubber accelerator, N.O.I.B.N.

Chapter 4

292

Reportable Quantity (RQ) (40 CFR Part 117) Under Clean Water Act Regulations:

Not applicable

This substance is identified as a hazardous chemical under the criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200).

--- IDENTIFIERS -HO-

Chemical Name and Synonyms: POLYETHYLENE GLYCOL, (CH,CH,O),-H Trade Name and Synonyms: Carbowax Polyethylene Glycol 3350 ChemicalFamily: OxyalkylenePolymer Manufacturer: UnionCarbide Corp., Akron,Ohio UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --Cas Material

No.

Poly(0xy-l,2,ethanedyl), a-hydrow-hydroxy

25322-68-3

% 100

--- PHYSICAL DATA -Boiling Point (OF):392, decomposes SpecificGravity (H,O = 1): 1.072 VaporPressure(mm Hg): Nil Percent Volatile by Volume (%): NA VaporDensity (air = 1):

>1

TLV See toxicity

Accelerators and Activators

FreezingPoint:

293

NA

EvaporationRate: Nil p H NA Solubility in Water:

at20°C

Melting Point (“C): 54 to 58 Appearance/Color/Odor: White solid (flake, powder, or molten); mild odor.

--FIRE AND EXPLOSION H A Z A R D S -FlashPoint: >350”F, Pensky-Martensclosedcup

ASTM D93

FlammabilityLimits: NA AutoignitionTemperature: DecompositionTemperature:

NA NA

ExtinguishingMedia: Applyalcohol-type or all-purpose-typefoamsby manufacturers’ recommended techniques for large fires. Use carbon dioxide or dry chemical media for small fires. Special Fire Fighting Procedures: Do not direct a solid stream of water or foam into hot, burning pools; this may cause frothing andincrease fire intensity. Use self-contained breathing apparatus and protective clothing. UnusualFireandExplosionHazards: Avoiddispersionof reduce potential for dust ignition and explosion.

dust in air to

Hazardous Products of Combustion and Decomposition: Carbon monoxide andlor carbon dioxide. HazardousPolymerization: Willnotoccur.

--- HEALTH HAZARD DATA -Effects of Overexposure: This material may contribute to nuisance dusts and possibly to respirable dusts; avoid breathing dusts. Overexposure to vapors

294

Chapter

generatedathightemperatures may result in eyeand respiratory tract irritation and in the inhalation of harmful amounts of material.

Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: Thisproduct may contain trace amountsof ethylene oxide, which is consideredbyOSHA,IARC,andNTP a potential carcinogen for humans. See toxicity section also.

--TOXICITY DATA -Animal Effects: Manufacturer reports that toxicology studies have shown this material to be very low acute toxicity and nonirritating. There is specific antidote. Treatmentofoverexposureshouldbe directed at the control of symptoms and the clinical condition. This productmay contain trace amounts ofethylene oxide (CAS No.75-21-8), a condition that creates the potential for accumulation of ethylene oxide inthe head space of shipping and storage containers and in enclosed areas where the product is being handledor used. Ethylene oxide is considered as a potential carcinogen for humans.Ethyleneoxide may also present reproductive, mutagenic, genotoxic, neurologic, and sensitizationhazards in humans. If this product is handledwithadequate ventilation, the presenceof these trace amounts is not expected to result in any short- or long-term hazards. This product may not be exempt from OSHA’s ethylene oxide standard 29 CFR1910.1017.Usersshouldcomplywithall applicable provisions. Personnel should be monitored to determine levels of exposure to ethylene oxide. If necessary, protective measures should be taken. The OSHA PEL for ethylene oxide is 1 ppm TWA, 8 hr. The action level is 0.5 ppm TWA, 8 hr. The ACGIH TLV is 1 ppm TWA, 8 hr, and OSHA has proposed an excursion limit of 5 ppm (15-min average).

Accelerators and Activators

--REACTIVITY DATA --Stability and Conditionsto Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. This material is considered stable. If strongly heated, may catch fire and give off toxic fumes. Materials to Avoid (Incompatibility): None reported by manufacturer. Hazard Decomposition Products:

Carbon dioxide and carbon monoxide.

HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Sweep up. Wash residuals withsoapand closed container.

water. Transfer to a

WasteDisposalMethod: Potential for a dust explosion exists ifattempt is made to incinerate organic powders. If incineration is desired, dissolve in a suitable solvent and incinerate as a solution. Empty Containers: The container for this product canpresent explosion or fire To avoid the risk of injury, do not cut, hazards, evenwhenemptied. puncture, or weld on or near this container.

--- SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection: Avoid breathing dust. Use NIOSHIOSHA-approved equipment when airborne exposure is excessive. Full facepiece equipment is recommended and, if used, replaces the need for chemical splash goggles. Consult respirator manufacturer to determine appropriate type of equipment for given application. The respirator use limitations specified by NIOSHMSHAor the manufacturermustbeobserved.High airborne concentrations may require useofself-contained breathing apparatus or supplied-air respirator. Respiratory protection must be in compliance with CFR Although OSHA and ACGIH have not established specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PEL/8-hr T W ! : Total ACGZH TLV/8-hr TWA: Total

mg/m3, respirable 5 mg/m3. mg/m3, respirable 5 mg/m3.

Chapter 4 These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Type of Ventilation Required: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Rubber gloves, goggles. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughly clean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dust-like material, improperhandlingcanlead to spontaneous combustion (dust explosions).

REGULATORY INFORMATION --Status on Substance Lists:The concentrations shown are maximum or ceiling levels (weight %) to be used for calculations for regulations. Trade Secrets are indicated by "TS". Federal EPA: ComprehensiveEnvironmentalResponse,Compensation,and Liability Act 1980 (CERCLA) requires notification of the National

Accelerators and Activators Response Center of release ofquantities of Hazardous Substances equal to or greater than the reportable quantities (RQs) in CFR Components present in this product at a level which could require reporting under the statute are: UPPER BOUND %

NUMBER CHEMICAL CONCENTRATION CAS Ethylene Oxide Dioxane

.Om5

Superfund Amendments and Reauthorization Actof 1986 (SARA) Title m: Requires emergency planning based Threshold PlanningQuantities (TPQs) and release reporting based on Reportable Quantities (RQs) in CFR (used for SARA and Component present in this product at a level which could require reporting under the statute are: *** NONE ***.

Superfund Amendments and Reauthorization Actof 1986 (SARA)Title m: Requiressubmissionofannual reports ofrelease of toxic chemicals that appear in 40 CFR (for SARA This information must be included in all MSDSs that are copied and distributed for this material. Components present in this product at a level which could require reporting under the statute are: *** NONE ***.

State Right-to-Know CALIFORNIA Proposition 65: This product contains trace levels of ACETALDEHYDE, DIOXANE, ETHYLENE OXIDE AND FORMALDEHYDE which the state of California has found to cause cancer, birth defects or other reproductive harm. MASSACHUSMTS Right-to-Know, Substance List (MSL) Hazardous Substances and Extraordinarily Hazardous Substances the MSL must be identified when present in products.

1

298

Chapter 4

Components present in this product at a level which could require reporting under the statute are: EXTRAORDINARILY HAZARDOUS SUBSTANCES( = > 0.0001 X) UPPER BOUND NUMBER CHEMICAL CONCENTRATION CAS

%

75-07-0

Acetaldehyde Dioxane 75-21-8 Oxide Ethylene Formaldehyde PENNSKVANIA Right-to-Know, HazardousSubstance List Hazardous Substances and Special Hazardous Substances the List must be identified when present in products.

Components present in this product at a level which could require reporting under the statute are: *** NONE ***.

Toxic Substances Control Act (TSCA) Status: The ingredients of this product are the TSCA inventory. California SCAQMD Rule 443.1 VOC’S: Not presently available.

Clay

5 MINERAL FILLERS,ACTIVATORS, AND DUSTING AGENTS The following chemicals are covered in this section: CHEMICAL NAME

OR NAME TRADE TYPE

Alcoa Aluminas: Hydrals, Hydrated Alumina

Hydrated Alumina or Aluminum Hydroxide BlackCarbon

Black Pearls, Mogul,Elftex, Monarch, Regal, Sterling, Vulcan, Acetylene Black

Calcium Carbonate, Whiting, Omyalite Chalk, Calcite (Limestone)

95T

Calcium Stearate

Calcium Stearate

Kaolin Hydrous Magnesium Silicate, Talc, Steatite, Soapstone

Vapor Mistron

Magnesium Stearate

Magnesium Stearate

Organophilic Amorphous Hydrated Dioxide

Silicon

Hi-Si1

299

300

Chapter 5

Chemical Name and Synonyms: HYDRATED ALUMINA,A1,0,-3H,O Trade Name and Synonyms: Alcoa Aluminas, Hydral705,710, n o s , C33, C331, C333

~31,

ChemicalFamily: MetalSalt Manufacturer: AluminumCompany of America, Pittsburgh, Pennsylvania UN ID Number: NA

--

INGREDIENTS AND COMPOSITION DATA

Material Composition No.

Cas

(mm)

Antimony

NA

1

Arsenic

NA

1

Bismuth

NA

1

Boron

NA

2

Cadmium

NA

1

Chromium

NA

5

Copper

NA

5

Lead

NA

10

Manganese

NA

5

Mercury

NA

No detectable levels of the following materials: Amines (low molecular weight) Cyanides (inorganic) Phenols (monomeric)

--

PPb

Mineral Fillers, Activators, and Dusting Agents

30 1

- PHYSICAL DATA BoilingPoint (“F):NA =

Specific Gravity

VaporPressure(mmHg):

0.8 to 0.22 for hydrals to 1.3 for C-products Nil

Percent Volatile by Volume (%): NA VaporDensity(air = 1): NA FreezingPoint:

NA

EvaporationRate: Nil p H Noncorrosive Solubility in Water: Insoluble in water. Soluble in acids and

alkalies.

MeltingPoint (“F): 3700 Appearance/Color/Odor: White crystalline powder;

odor.

--FIRE AND EXPLOSION HAZARDS -FlashPoint:

NA

FlammabilityLimits:

NA

AutoignitionTemperature: DecompositionTemperature:

NA NA

ExtinguishingMedia: Applyalcohol-type or all-purpose-typefoams by manufacturers’ recommended techniques for large fires. Use carbon dioxide or dry chemical media for small fires. Special Fire Fighting Procedures: Do not direct a solid stream of water or foaminto hot, burningpools;this may cause frothing andincrease fire intensity. Use self-contained breathing apparatus and protective clothing.

302

Chapter 5

UnusualFireandExplosionHazards: Avoid dispersion of dust in air to reduce potential for dust ignition and explosions. Hazardous Products of Combustion and Decomposition: Carbon monoxide and/or carbon dioxide. HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA -Effects of Overexposure: "By ingestion negligible. By inhalation low," according to the "Hygienic Guide Series--Aluminum and Aluminum Oxides, " issued by the American Industrial Hygiene Association. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consult physician immediately. CancerInformation: None reported.

--TOXICITY DATA -Animal Effects: Threshold limit value for "inert" or nuisance particulates is 10 mg/m3 or 30 mppcf, whichever is lower, per ACGIH Threshold Limit Values of Airborne Contaminants, Notice of Intended Changes, 1971. Food Additives AmendmentStatus Alcoa Hydral705, Hydra1 710, C31, C33, C331, and C333 considered "Generally Recognized as Safe" (GRAS) for use infoods or foodpackagingmaterials as definedin the Food additives Amendment of 1958 the Federal Food, Drug, and Cosmetic Act.

--REACTIVITY DATA --Stability and Conditionsto Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. This material is considered stable. If strongly heated, may catch fire and give off toxic fumes. Materials to Avoid (Incompatibility): None reported by manufacturer.

Mineral Fillers, Activators, Agents Dusting and

Hazard Decomposition Products:

Carbon dioxide and carbon monoxide.

HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE --For Spills: Sweep up. Wash residuals withsoapand closed container. WasteDisposalMethod:

water. Transfer to a

No specific recommendations.

Empty Containers: The container for this product can present explosionor fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld or near this container.

--

SPECIAL PROTECTION AND PRECAUTIONS

---

Respiratory Protection: Avoid breathing dust. Use NIOSH/OSHA-approved equipment when airborne exposure is excessive. Full facepiece equipment is recommended and, if used, replaces the need for chemical splash goggles. Consult respirator manufacturer to determine appropriate type of equipment for given application. The respirator use limitations specified by NIOSH/MSHA or the manufacturermustbeobserved.High airborne concentrations may require useofself-contained breathing apparatus or supplied-air respirator. Respiratory protection must be in compliance with CFR Although OSHA and ACGIH have not established specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PEL/8-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGZH ZZV/8-hr TWA: Total 10 mg/m3, respirable 5 mg/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to fpm.

304

Chapter 5

EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other:

None recommended.

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequate ventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate and thoroughly clean all equipment, piping, or vessels beforebeginningmaintenance repairs. Keep area clean. Aswithany powder or dust-like material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--- REGULATORY INFORMATION -None reported.

Name: A L U " HYDROXIDE Synonyms: AF 260; Alcoa 331; Alcoa C 30BF; Alumigel; Alumina Hydrate; Alumina Hydrated; AluminaTrihydrate; alpha-Alumina Trihydrate; Aluminic Acid; Aluminium Hydroxide; Aluminum Hydrate; Aluminum (111) Hydroxide; Aluminum Hydroxide Gel; Aluminum Oxide-3H20; Aluminum Oxide Hydrate;AluminumOxide Trihydrate; Aluminum Trihydrat; Aluminum Trihydroxide; Alusal; Amberol ST 140F; Amphojel; Baco AF 260; British Aluminum AF 260; C 31; C 33; C 31C; C 4D;C 31F; C-31-F; C.I. 77002; GHA 331; GHA 332; H 46; Higilite; Higilite H 32; Higilite H 42; Higilite

Mineral Fillers, Activators, 305 Agents Dusting and H 31s; Hychol705; Hydral 705; Hydral 710; Hydrated Alumina; Martinal; P 30BF; Trihydrated Alumina; Trihydroxyaluminum CAS: 21645-51-2; RTECS: BD0940000 Formula:AIH303; Mol Wt:78.01 WLN: .AL..H3.03 Chemical Class: Metaloxide See other identifiers listed below under Regulations.

--PROPERTIES -Boiling Point: NA MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density:No data SpecificGravity: Nodata Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: Not given Packaging exceptions: 173. Nonbulk packaging: 173. Bulk packaging: 173. STCC Number:

Not listed

Clean Water Act Sect. 307: No Clean Water Act Sect. 311: No

Chapter 5

Clean AirAct: Not listed EPAWasteNumber: None CERCLA Ref: Not listed RQDesignation: Notlisted SARATPQValue: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant.

U.S. Postal Service Mailability: Not given

--- TOXICITY DATA --Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

Conc IDLH Unknown MOSH REL: Notgiven ACGIH TLV: TLV = 10 mg/m3metal dust ACGIHSTEL: Metal dust OSHAPEL: Transitional Limits: PEL = (total dust) 15 mg/m3; (respirable fraction) 5 mg/m3; Final RuleLimits:TWA = (total dust) mg/m3; (respirable fraction) 5 mg/m3. MAK Information: 6F ppm Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; MAK: Not listed; NZOSH Not listed; NTP: Not listed; ACGZH Not listed; OSHA: Not listed. Human ToxicityData: (Source:NIOSHRTECS) orl-chd TDLo:79 g/kg/2Y-I PEDIAU 71, Behavioral Changes in motor activity (specific assay) Muscle contraction or spasticity Musculoskeletal Osteomalacia

Mineral Fillers, Activators, and Dusting Agents

307

orl-chd TDLo:122 g/kg/4D JOPDAB 92, 592, 78 Gastrointestinal Other changes Nutritional and Gross Metabolic Changesin:bodytemperatureincrease

LD50 Value: No LD50 in RTECS 1992 OtherSpeciesToxicityData: ipr-rat LDLo: 150 mgkg

(Source:NIOSHRTECS1992)

Reproductive Toxicity (1992 RTECS): This chemical has malian reproductive toxicity.

known mam-

--- IDENTIFIERS --Name: KAOLIN Synonyms: Argilla; Bolusalba; China Clay; Porcelain Clay; WhiteBole CAS: 1332-58-7; RTECS: GF1670500 Formula: AlH08Si3.K See other identifiers listed below under Regulations.

--- PROPERTIES -Physical Description: White or yellowish-white, earthy mass or white powder BoilingPoint: NA MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density: No data SpecificGravity: No data Water Solubility: INSOL Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data

Chapter 5 Neutralizing Agents: No data Polymerization Possibilities:Nodata Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

- REGULATIONS DOT hazard class:Notgiven Packaging exceptions: Nonbulkpackaging: Bulkpackaging: 173. STCC Number: Notlisted Clean Water Act Sect. 307: No Clean Water Act Sect. 311: No Clean Air Act: Notlisted EPA Waste Number: None CERCLA Ref: Notlisted RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Chronic toxicity:reproductivetoxin.

U.S. Postal Service Mailability: Not given

NFPA Codes: Health Hazard (blue): Unspecified Flammability (red): Unspecified Reactivity (yellow):Unspecified Special: Unspecified

--TOXICITY DATA -Short-term Toxicity: Unknown Long-term Toxicity: Unknown Conc IDLH Unknown

Mineral Fillers, Activators, and Dusting Agents

309

NOSH REL: Not given

ACGIHTLV: TLV = 10mg/m3 ACGIHSTEL: Not listed OSHAPEL: Transitional Limits: PEL = (total dust) 15 mg/m3; (respirable fraction) 5 mg/m3; Final Rule Limits: TWA = (total dust) 10mg/m3; (respirable fraction) 5 mg/m3. MAK Information: Not listed Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; M M Not listed; NIOSH: Not listed; NTP: Not listed; ACGZH Not listed; OSHA: Not listed. LDS0Value: No LD50 in RTECS 1992 Reproductive Toxicity (1992 RTECS): This chemical is a mammalian reproductive toxin. Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo590 g/kg (37D pre/l-22D preg) JONUAI 107, 2020, 77 Effects Newborn Growth statistics (e.g., reduced weight gain) INITIAL INCIDENT RESPONSE --No DOT Guide information for this product.

--- IDENTIFIERS --Name:CARBONBLACK Synonyms: ChannelBlack;LampBlack;FurnaceBlack;ThermalBlack; Acetylene Black CAS: 1333-86-4; RTECS: FF5800000 Formula: C; MolWt: 12 ChemicalClass: Nonmetal See other identifiers listed below under Regulations.

Chapter 5

--PROPERTIES -Physical Description: Dark brown to black powder, pellets or paste. (NYDH) Boiling Point: NA Melting Point: NA FlashPoint: NA Autoignition: NA Vapor Pressure: About 0 mm UEL: NA LEL: NA Vapor Density:No data Specific Gravity: No data Water Solubility: INSOL Incompatibilities: Strong oxidizers such as chlorates, bromates, nitrates Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--- REGULATIONS --DOT hazard class: Not given Packaging exceptions: Nonbulk packaging: Bulkpackaging: STCC Number:

Not listed

Clean Water ActSect. 307: No Clean Water Act Sect. 311:No Clean Air Act: Not listed EPA Waste Number: None CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value: Not listed

Mineral Fillers, Activators, and Dusting Agents

I

SARA 312 Categories: Acute toxicity: irritant. Chronic toxicity: mutagen.

U.S. Postal Service Mailability:

Not given

NFPA Codes: HealthHazard(blue): Unspecified Flammability(red): Unspecified Reactivity(yellow): Unspecified Special: Unspecified

--- TOXICITY DATA -Short-termToxicity: Inhalation: Maycause irritation to nose, mouth,and throat. Skin: Maycause irritation. Eyes: Maycause irritation. Ingestion: Animal studies show that toxic effects are unlikely. (NYDH) Long-termToxicity: Exposure to levels wellabove 3.5 mg/m3 for several months may result indamage to the skin and andtemporary or permanent damage to the lungs and breathing passages and may adversely affect the heart. Carbon black containing PAH greater than 0.1 % should be considered a suspect carcinogen. (NYDH) Symptoms: Conjunctivitis, corneal hypoplasia, eczema, bronchitis, pneumatotumor. (Source: THIC) ConcIDLH:

Unknown

NOSH REL: Potential occupational carcinogen 3.5 mg/m3.Time-weighted averages for 8-hr exposure 0.1 in presence mg/m3 of PAHS.

ACGIH TLV: TLV = mg/m3 ACGIH STEL: Not listed OSHA PEL: Transitional Limits: PEL = 3.5 mg/m3; Final Rule Limits: TWA = 3.5 mg/m3. MAKInformation: Notlisted Carcinogen: N; Status: Seebelow

Chapter 5

312

CarcinogenLists: Z A R C Not classified as to human carcinogenicity or probably not carcinogenicto humans; M A K Not listed; NZOSH Carcinogen defined by NIOSH with no further categorization; h T P Not listed; ACGZH Not listed; OSHA: Not listed. LDS0Value: No LD50 in RTECS 1992 Reproductive Toxicity (1992 RTECS): malian reproductive toxicity.

This chemical has no known mam-

--- PROTECTION AND FIRST AID -NOSH Pocket Guide to Chemical Hazards: **Wear Eye Protection to Prevent: Reasonable probability of eye contact. **Exposed Personnel Should Wash:

At the end of each work shift.

**Reference: NIOSH FirstAidSource: NIOSHPFAM Inhalation: Make victim blow nose but discourage sniffling. Ingestion: Inducevomiting;then administer 1 tbsp. mineral oil (nujol) or half-glass peanut oil. Skin: Remove contaminated clothes; wash skin with soap and water. Eyes: Irrigate promptly. INITIAL INCIDENT RESPONSE No DOT Guide information for this product.

--

IDENTIFIERS

Name:CARBONICACID,CALCIUMSALT Synonyms: Atomit;CalciumCarbonate CAS: 471-34-1;RTECS: FF9335000 Formula: CO,.Ca; MolWt: 100.09 ChemicalClass: Mineralacid salt

-(1:l)

See other identifiers listed below under Regulations.

---

Mineral Fillers, Activators, and Dusting Agents

--PROPERTIES -BoilingPoint: NA MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density: No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data PolymerizationPossibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data REGULATIONS --DOT hazard class:Notgiven Packaging exceptions: 173. Nonbulkpackaging: 173. Bulkpackaging: 173. STCC Number: Not listed Clean Water Act Sect.307:No Clean Water ActSect. 311: No Clean Air Act:Not listed EPA WasteNumber: None CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant. U.S. Postal Service Mailability:

Not given

313

314

Chapter 5

--- TOXICITY DATA --Short-term Toxicity: Unknown Long-termToxicity:

Unknown

Conc IDLH Unknown NIOSHREL: Not given ACGIHTLV: Not listed ACGIH STEL Not listed OSHA PEL Not in Table

MAK Information: Not listed Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; MAK: Not listed; NZOSH Not listed; N T P Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: orl-rat LD50:6450 mgkg OtherSpeciesToxicityData: orl-rat LD50:6450 mg/kg

(Source:NIOSHRTECS

1992)

Reproductive Toxicity (1992 RTECS): Thischemicalhas malian reproductive toxicity.

--

INITIAL INCIDENT RESPONSE

no knownmam-

--

No DOT Guide information for this product.

--- IDENTIFIERS -Chemical Name and Synonyms: CALCIUM STEARATE, Ca(CH3(CH316

...),

Trade Name and Synonyms: Calcium Stearate

Mineral Fillers, Activators, Dusting Agents and

3 15

ChemicalFamily: MetalSoap Manufacturer: TennecoChemicals, Inc., Piscataway, New Jersey

UN ID Number: NA

--

INGREDIENTS AND COMPOSITION DATA

%

No. Cas Material Calcium stearate

NA

established

-TLV

Not

--- PHYSICAL DATA --BoilingPoint (“F):NA SpecificGravity (H,O =

1.03

Vapor Pressure (mm Hg): NA Percent Volatile by Volume (%): 2 Vapor Density (air =

NA

Freezing Point: NA EvaporationRate:

Nil

pH: Noncorrosive Solubility: Negligible Melting Point (“F):NA Appearance/Color/Odor: White, fluffy, fine powder, slight fatty acid odor.

--FIRE AND EXPLOSION HAZARDS --FlashPoint:

NA

FlammabilityLimits:

NA

Chapter 5 Autoignition Temperature: NA Decomposition Temperature: NA Extinguishing Media: Water spray, foam, carbon dioxide, or dry chemical. Special Fire Fighting Procedures: Water or foam may cause frothing. Unusual Fire and Explosion Hazards: Avoid dispersion of dust in air to reduce potential for dust ignition and explosion. Hazardous Products of Combustion and Decomposition: Carbon monoxide and/or carbon dioxide. Hazardous Polymerization: Willnot occur.

--HEALTH HAZARD DATA -Effects of Overexposure: Nonereported Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. Cancer Information:

None reported.

--- TOXICITY DATA Animal Effects: Nonereported

- REACTIVITY DATA -Stability and Conditions to Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. This material is considered stable. Materials to Avoid (Incompatibility): Strong oxidizing materials. Hazard Decomposition Products: Carbon dioxide and carbon monoxide.

Mineral Fillers, Activators, and Dusting Agents

HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Sweep up. Wash residuals withsoapand closed container. WasteDisposalMethod:

water. Transfer to a

No specific recommendations.

Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container.

--- SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have not established specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PEL/8-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGZH ZZV/8-hr TWA: Total 10 mg/m3, respirable 5 mg/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Nonerecommended. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container.

Chapter 5 Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dust-like material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--

REGULATORY INFORMATION --

None reported.

--- IDENTIFIERS -Chemical Name and Synonyms: MAGNESIUM STEARATE, Mg(C,,H35032 Trade Name and Synonyms: Magnesium Stearate ChemicalFamily: MetalSoap Manufacturer: DiamondShamrockChemicalCo.,Cleveland,Ohio

UN ID Number: NA

- INGREDIENTS AND COMPOSITION DATA -Material

No.

Magnesium stearate

Cas

%

TLV Not established

Mineral Fillers, Activators, and Dusting Agents

--

PHYSICAL DATA

3 19

---

BoilingPoint (“F):NA SpecificGravity (H,O = 1): NA

m):NA

VaporPressure(mm

Percent Volatile by Volume =

VaporDensity(air FreezingPoint:

NA NA

NA

EvaporationRate:

Nil

p H Noncorrosive Solubility: Negligible MeltingPoint(“C):

145

AppearanceKolorlOdor: Odorlesswhitepowder.

--- FloRE AND EXPLOSION HAZARDS -FlashPoint:

NA

FlammabilityLimits:

NA

AutoignitionTemperature: DecompositionTemperature:

NA NA

Extinguishing Media: Foam, carbon dioxide, or dry chemical. SpecialFireFightingProcedures:

None reported.

UnusualFireandExplosionHazards: Avoid dispersion of dust in air to reduce potential for dust ignition and explosion.

Chapter 5

320

Hazardous Products of Combustion and Decomposition: Carbon monoxide and/or carbon dioxide. Hazardous Polymerization: Willnotoccur.

- HEALTH HAZARD DATA Effects of Overexposure: None reported Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. Cancer Information:

None reported.

--TOXICITY DATA -Animal Effects: Nonereported

--- REACTIVITY DATA -Stability and Conditionsto Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. This material is considered stable. Materials to Avoid (Incompatibility): Strong oxidizing materials. Hazard Decomposition Products: Carbon dioxide and carbon monoxide. Hazardous Polymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE --For Spills: Sweep up. Wash residualswithsoapand closed container. Waste Disposal Method: No specific recommendations.

water. Transfer to a

Mineral Fillers, Activators, Dusting Agents and

1

Empty Containem: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have not established specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PEL/8-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGIH IZV/8-hr TWA: Total 10 mg/m3, respirable 5 mg/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Wear rubber gloves and goggles. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequate ventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels

o.

Chapter 5 beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder dust-like material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--- REGULATORY INFORMATION --None reported.

--IDENTIFIERS -Chemical Name and Synonyms: ORGANOPHILIC CLAY Trade Name and Synonyms:

Bentone 34

ChemicalFamily: ClayProduct Manufacturer: NL Industries, Inc., Hightstown, New Jersey UN IDNumber: NA

--- INGREDIENTS AND COMPOSITION DATA --Cas

% -

Material Cristobalite

NA


--- PHYSICAL DATA --BoilingPoint (“F‘):NA SpecificGravity (H,O = 1): 1.7 VaporPressure(mmHg):

NA

Percent Volatile byVolume (%): NA VaporDensity (air = 1): NA FreezingPoint:

NA

TLV Not established

Mineral Fillers, Activators, and Dusting Agents

EvaporationRate:

Nil

p H Noncorrosive Solubility: Negligible MeltingPoint(“C):

NA

Appearance/Color/Odor: Odorlesswhitepowder.

--- FIRE AND EXPLOSION HAZARDS --FlashPoint:

NA

FlammabilityLimits:

NA

AutoignitionTemperature: DecompositionTemperature:

NA NA

Extinguishing Media: NFPA Class A agents acceptable: dry chemical, foam COz, water (fog). SpecialFireFightingProcedures:

None reported.

UnusualFireandExplosionHazards: Avoid dispersion of dust in air to reduce potential for dust ignition and explosion. Hazardous Products of Combustion and Decomposition: Carbon monoxide and/or carbon dioxide and traces of ammonia. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA -Effects of Overexposure: Threshold limit value, 13.5 mppcf. The prolonged inhalation of dusts may result in shortness ofbreathanddecreasedchest expansion, but with absence fever. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician.

Chapter 5

Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

--

TOXICITY DATA

---

AnimalEffects: Nonereported

--REACTIVITY DATA -Stability and Conditionsto Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. This material is considered stable. Materials to Avoid (Incompatibility): Strong oxidizing materials. Hazard Decomposition Products: Carbon dioxide and carbon monoxide. HazardousPolymerization: Willnotoccur

--- SPILL AND EMERGENCY RESPONSE --ForSpills: Sweep up. Wash residuals withsoapand closed container. WasteDisposalMethod:

water. Transfer to a

No specific recommendations.

Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the riskof injury, do not cut, puncture, or weld on or near this container. ”-

SPECIAL PROTECTION AND PRECAUTIONS

--

Respiratory Protection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have not established specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PEL/8-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGIH IZV/8-hr TWA: Total mg/m3, respirable 5 mg/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Mineral Fillers, Activators, Agents Dusting and

325

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Wear rubber gloves and goggles. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughly clean allequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany spontaneous powder or dust-like material, improperhandlingcanlead combustion (dust explosions).

--- REGULATORY INFORMATION --None reported.

--

IDENTIFIERS ---

Name:SILICA,AMORPHOUS Synonyms: AmorphousFused Silica; FusedQuartz;Fused Silica; Quartz Glass; SG-67; Silica, Fused; Silicon Dioxide; Silicone Dioxide; Suprasil;

326

Chapter 5

VitreousQuartz; Diatomite; Silicon Dioxide (Amorphous); Diatomaceous Earth; Diatomaceous Silica; Colloidal Silica CAS:60676-86-0; RTECS: VV7320000 Formula: SiOz; Mol Wt: 60.09 WLN: SI Chemical Class: Nonmetal oxide See other identifiers listed below under Regulations.

--PROPERTIES -Physical Description: Colorless to gray, odorless powder Boiling Point: NA Melting Point: 1977.58 K; 1704.4"C;3099.9"F FlashPoint: NA Autoignition: NA Vapor Pressure: About mm UEL: NA LEL: Vapor Density: No data Specific Gravity: No data Density: 2.600 Water Solubility: INSOL Incompatibilities: Fluorine, oxygen difluoride, chlorine trifluoride Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--- REGULATIONS --DOT hazard class:Notgiven Packaging exceptions: 173. Nonbulk packaging: 173. Bulk packaging: 173.

Mineral Fillers, Activators, and Dusting Agents STCC Number: Not listed Clean Water Act Sect. 307: No Clean Water Act Sect. 311: No Clean Air Act: CAA by category EPA WasteNumber: None CERCLARef: N RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: adverse effect to target organs. U.S. Postal Service Mailability:

Notgiven

NFPA Codes: Health Hazard (blue): Unspecified Flammability (red): Unspecified Reactivity (yellow):Unspecified Special: Unspecified

-Short-term Toxicity:

TOXICITY DATA

---

Unknown

Long-term Toxicity: Unknown Target Organs: Respiratorysystem,lungs Symptoms: Pneumoconiosis(Source:NIOSHP) Conc IDLH Unknown NIOSH REL: Potential occupational carcinogen 0.05 mg/m3. Time-weighted averages for 8-hr exposure. ACGIH TLV: TLV = 0.1 mg/m3 respirable dust ACGIH STEL: Respirable dust

OSHA PEL: Transitional Limits: PEL = see table Limits: TWA = respirable dust, 0.1 mg/m3. MAK Information:

mg/m3

ppm; Final Rule

Chapter 5

Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not classified as to human carcinogenicity or probably not carcinogenic to humans; MAK: Not listed; NZOSH Carcinogen defined by NIOSH with no further categorization; ZVTP Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: No LD50 in RTECS OtherSpeciesToxicityData: ipr-rat LDLo:400 mg/kg itr-rat LDLo: mg/kg ipr-mus LDLo:40 mg/kg ivn-cat LDLo:5 mg/kg ivn-rbt LDLo:35 mg/kg

(Source: NIOSHRTECS

Reproductive Toxicity (1992 RTECS): This chemical has no known mammalian reproductive toxicity.

--- PROTECTION AND FIRST AID --FirstAidSource: NIOSH Inhalation: Nonegiven Ingestion: Nonegiven Skin: Nonegiven Eyes: Irrigate immediately

6 ANTIOXIDANTS,STABILIZERS, AND FIRE RETARDANTS Three classes

chemicals are covered in this section: CHEMICAL FAMILY/NAME NAMES TRADE

Antioxidants Phenolic Antioxidants

Good-Rite TMQ Antioxidant Aminox

Dilaury/Thiodipropionate Flexzone Irganox Agerite DPPD and HP-S, MA, Resin D vanox Akrochem Antioxidant Stabilizers

Alkylated Cresol

BHT

Flame Retardants

Brominated Organic Compounds

Citex BN-451

Chlorinated Organics

Dechlorane

Metal Oxide, Antimony

Fire Shield

Trioxide

Antimony Oxide

Antimony Trioxide

Thermoguard S

330

Chapter 6

--IDENTIFIERS -Chemical Name and Synonyms: TRIS(3,5-di-f-BUTn-4-HYDROXYBENZYL)ISOCYANURATE,CJ-I,&O, Trade Name and Synonyms: Good-Rite 3 114 ChemicalFamily: PhenolicAntioxidant Manufacturer: BF GoodrichChemical Co., Cleveland, Ohio UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA -Cas Material

No.

Product

%

NA

TLV Not established

Note: Good-rite 31 14 has FDA approval under Regulation 178.2010* for use in polyolefins in contact with fatty and nonfatty foods.

--- PHYSICAL DATA --BoilingPoint

(W:NA

SpecificGravity (H,O = 1): 1.03 VaporPressure(mmHg):

NA

Percent Volatile by Volume (%): NA VaporDensity(air = FreezingPoint:

NA

NA

EvaporationRate:

Nil

pH: Noncorrosive

Solubility in Water: 0.002 g/100 g at

Antioxidants, Stabilizers, and Fire Retardants

33 1

MeltingPoint ("C): NA Appearance/Color/Odor: Whitepowder, negligible odor.

--- FIRE AND EXPLOSION HAZARDS --FlashPoint: 553"F, FlammabilityLimits: NA AutoignitionTemperature: DecompositionTemperature:

NA NA

Extinguishing Media: NFPA Class A agents acceptable: dry chemical, foam COz, water (fog). SpecialFireFightingProcedures:

None reported.

UnusualFireandExplosionHazards: Avoid dispersion of dust in air to reduce potential for dust ignition and explosion. Hazardous Products of Combustion and Decomposition: Carbon monoxide and/or carbon dioxide and traces of ammonia. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA --Effects of Overexposure: None reported; see toxicity data below. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consult physician immediately. CancerInformation: None reported.

Chapter 6

--TOXICITY DATA Animal Effects: Threshold limit value, LD50 single oral dose in rats is greater than 6800 mgkg. Acutedermal LD50 for rabbits is greater than 10,000 mg/kg of body weight.Slight eye irritation without corneal damage produced in rabbits with direct application. No deaths among rats following exposure to dust at a concentration of 66.5 mg/liter of air.

--REACTIVITY DATA -Stability and Conditionsto Avoid: None reported by manufacturer other than to minimize skin exposure and inhalation. This material is considered stable at temperatures up to 500°F. Materials to Avoid (Incompatibility): Strong oxidizing materials. Hazard Decomposition Products:

Carbon dioxide and carbon monoxide.

HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE --For Spills: Sweep up. Wash residuals withsoapand closed container. WasteDisposalMethod:

water. Transfer to a

No specific recommendations.

Empty Containers: The container for this product can present explosionor fire hazards, evenwhenemptied. To avoidtheriskof injury, donot cut, puncture, or weld on or near this container.

--- SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have notestablished specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PEL/8-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGZH ZV/8-hr TWA: Total 10 mg/m3, respirable 5 mg/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Antioxidants, Stabilizers, and Fire Retardants

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Wear rubber gloves and goggles. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughly clean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean.Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--- REGULATORY INFORMATION -None reported.

- IDENTIFIERS ChemicalNameandSynonyms: 2,2'"ETHYLENEBIS(4-METHYL-6TERTIARYBUTYL PHENOL, C,H,,O,

Chapter 6

334 Trade Name and Synonyms: ChemicalFamily:

Antioxidant 2246

Phenol

Manufacturer: AmericanCyanamid Co., BoundBrook, New Jersey

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --%

No. Cas Material Product

TLV

NAestablished

Not

--PHYSICAL DATA --BoilingPoint (“F):NA SpecificGravity (H,O = 1): 1.08 VaporPressure (mm Hg): NA Percent Volatile byVolume (%): Negligible VaporDensity(air = 1): NA FreezingPoint:

NA

EvaporationRate: NA pH: NA Solubility inWater: MeltingPoint(“C):

Negligible NA

Appearance/Color/Odor: Whitepowder;mildphenolic

odor.

-- FIRE AND EXPLOSION HAZARDS FlashPoint: NA

Antioxidants, Stabilizers, and Fire Retardants

FlammabilityLimits: NA AutoignitionTemperature: DecompositionTemperature:

NA NA

Extinguishing Media: Carbon dioxide, dry chemical, or water. Special Fire Fighting Procedures: Do not use high-pressure water stream. Airborne dust creates an explosion hazard. Unusual Fire and Explosion Hazards: Dust may be explosive if mixed with air in critical proportions and in the presence of a source of ignition. The hazard is similar to that of any organic solid including sawdust. Maintain normal good housekeeping for control of dust. Hazardous Products of Combustion and Decomposition: This material, if ignited, can give off nitrogen oxides and carbon monoxide gases. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA --Effects of Overexposure: None expected. Emergency Response and First Aid: Skin: Wash with lots o f clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consult physician immediately. CancerInformation: None reported.

- TOXICITY DATA -AnimalEffects: None reported.

--- REACTIVITY DATA -Stability and Conditions to Avoid: No specific incompatibility.

Chapter 6

Materials to Avoid (Incompatibility): None. Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide and/or carbon dioxide. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Vacuum or sweep up and place into dry, clean, covered container for disposal. Keep this material out of watersheds and waterways. Waste Disposal Method:No specific recommendations made by manufacturer. Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemical landfill accordance with all applicable local, state, and federal laws and regulations.

--SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have not established specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PELB-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGZH Z,V/8-hr TWA: Total 10 mg/m3, respirable 5 mg/m3.

These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Wear rubber gloves and goggles.

Antioxidants, Stabilizers, and Fire Retardants

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Use all standard practices for goodpersonalhygiene. Completely isolate andthoroughlyclean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. withany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--

REGULATORY INFORMATION

-

None reported.

--- IDENTIFIERS -ChemicalNameandSynonyms:POLYMERIZED1,2-DIFIYDRO-2,2,4TRIMETHYLQUINOLINE, AND 1,2-DIHYDRO-2,2,4”l’RIMETHYLQUINOLINE Trade Name and Synonyms: TMQ, Flectol H Antioxidant ChemicalFamily: Rubber Preservative Manufacturer: MonsantoChemicalCo.,

UN ID Number: NA

St. Louis, Missouri

338

Chapter 6

--INGREDIENTS AND COMPOSITION DATA -Cas Material

No.

Product

%

NA

TLV Not established

--PHYSICAL DATA --BoilingPoint (“F):NA SpecificGravity (H,O =

1.01 to 1.08

VaporPressure(mmHg):NA Percent Volatile byVolume (%): NA VaporDensity(air

= 1): NA

FreezingPoint:NA EvaporationRate:NA p H NA Solubility inWater: 0.005 Melting Point (“C):85

ml at25°C

130

Appearance/Color/Odor: Light brown powder or flakes.

--- FIRE AND EXPLOSION HAZARDS --Flash Point: 239 to 302OF; Cleveland open cup Flammability Limits: (Dust cloud) LEL:

to 200 mg/l

AutoignitionTemperature:NA DecompositionTemperature:

NA

Extinguishing Media: Waterspray, foam, drychemical,carbondioxide,or any Class B extinguishing agent.

Antioxidants, Stabilizers, and Fire Retardants

Special Fire Fighting Procedures: Firefighters or others exposed to products of combustion (see Hazardous Decomposition Products below) should wear full protective clothing including self-contained breathing apparatus. Equipment should be thoroughly decontaminated after use. UnusualFireandExplosionHazards: Productsofdecomposition include hazardouscarbonmonoxideand nitrogen oxides. Powder or dust of this material whenmixed in sufficient quantities in air canformexplosive mixtures. Hazardous Products of CombustionandDecomposition: This material, if ignited, can give off nitrogen oxides and carbon monoxide gases. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA --Effects of Overexposure: Dermal contact and inhalation are expected to be the primary routes of occupationalexposure to Flectol H antioxidant. Occupational exposure to this material has not beenreported to cause significant adverse human health effects. Testing in human subjects witha closely related polymeric, 1,2-dihydro-2,2,4-trimethylquinoline, indicated a lowpotential for dermal sensitization. Following exposure to Flectol H antioxidant, workers have reported staining and discoloration garments contacting the skin. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

--- TOXICITY DATA -Animal Effects: Data from Monsantostudies and the available scientific literature indicate the following: OralLD50 (rat): DermalLD50 (rabbit):

mgkg, practically nontoxic mg/kg, practically nontoxic

340

Chapter 6 Eye Irritation (rabbit): (FHSA) 1.3 on a scale of 110.0, practically nonirritating Skin Irritation (rabbit): (FHSA) 0.0 on a scale of 8.0, nonirritating A polymerized 1,2dihydro-2,2,4-trimethylquinolinesimilar to Flectol H antioxidant was tested on human volunteers. Tested as a 75% preparation in petrolatum, this material produced irritation responses in 9 of the 5 1 test subjects after initial application; 6 of the 51 volunteers exhibited mild to moderate cumulative irritation. During the challenge phase of the study. sensitization was observed in one subject, with a possible response in two others. This material was considered to be a potential skin sensitizer. Flectol H antioxidant was evaluated in a 4-week dust inhalation study in which groups of 5 female and 5 male rats were exposed to atmospheric concentrations of 0, 15, 40, 90 or 150 mg/m3 6 hr per day, 5 days per week. Significant elevations in liver weights were noted for animals of the two highest exposure level groups, with lesser increases in liver weights seen for males at lower exposure levels. In a13-week dust inhalation study, rats wereexposed to Flectol H antioxidant at concentrations of 15, 49 and 148 mg/m3 for 6 hr per day, 5 daysperweek.Treatment-related effects in certain hematologicaland clinical chemistry parameters were found at all dose levels. Dose-related increases in liver weights were noted. Microscopic examination of livers indicated an increased incidence of cloudy swelling and vacuolation of the liver cell cytoplasm in high-dose animals. Based on the findings of this study, a no-effect level was not determined.

Polymeric 1,2-dihydro-2,2,4-trimethylquinolinehas been evaluatedin a series of chronic toxicity studies: Rats were given 0.01, 0.1, or 1.5% polymeric 1,2dihydro-2,2,4trimethylquinoline (reported as Flectol H, but later determined to be of nonMonsanto origin) in the diet for years. Slight decreases in growth rate and food consumption and an increase in the occurrence ofcholangiofibrosis wereobservedin the high-dosegroup. Increases in lymphomasand adenomaswereobserved.Based on the results of this study, the FDA classified this quinoline polymer as "at least a probable carcinogen" and removed it from the list ofrubber additives approved for indirect food contact. Polymeric 1,2dihydro-2,2,4-trimethylquinolinewas administeredto groups of rats at concentrations of 0.01, 0.1, 1.5, or 3.0% in the diet for years.

Antioxidants, Stabilizers, and Fire Retardants

34 1

Animals administered in the test did not survive beyond 3 weeks; only 20% of the animals administered 1.5% survived to the end of the study. Liver enlargement was present in high-dose animals. Alterations of hepatic cells, liver necrosia, and biliary duct hyperplasia were observedin the highdose group. Only minimaleffects were reported for those animals receiving 0.01 and 0.1% of the test material in the diet. Mice were treated with either a single subcutaneous injection of 10-mg polymeric 1,2-dihydro-2,2,4-trimethylquinoline, or weekly skin application of 0.1 mg or 10 mgof the test material. All animals were observed for their lifetimes. No tumors were observed atthe sites of application and no effects on survival times were noted. However, focal hepatic necrosis was observed in two female mice that received weekly dermal applications of 10 mg of the test material. Groups of three dogs were given polymeric 1,2-dihydro-2,2,4trimethylquinoline (reported as Flectol H, but later determined to be of nonMonsanto origin) in the diet at concentrations of 0.008,0.03, or0.15% for a 1 year period. Secondary hepatic cell degeneration was observed in two of the high-dose animals. No tumors were observed. Flectol H antioxidant was evaluated for mutagenic or genotoxic potential in the following systems: microbial assays with five S . tvphimurium strains and one yeast strain, with and without activation; in vitro Chinese hamster ovary (CHO) cell point mutation assays; and in vivo/in vitro rat hepatocyte/DNA repair assays. No evidence of mutagenicity or genotoxicity was observed in any of the assays. Environmental Toxicity Information: 96-hr LC50 Trout: 50 mg/l, slightly toxic 96-hr LC50 Bluegill: 54 mg/l, slightly toxic 96-hr LC50 Fathead Minnow: 64 mg/l, slightly toxic 48-hr LC50 Daphnia: 5.8 mg/l, moderately toxic 96-hr EC50 Algae, Cell Count: > 1000 mg/l, nontoxic

--REACTIVITY DATA Stability and Conditions to Avoid: Thermally stable. Materials to Avoid (Incompatibility): None

Chapter 6

HazardDecompositionProducts: This material, if ignited, cangive nitrogen oxides and carbon monoxide gases.

off

HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE -For Spills: Vacuum or sweep up and place into dry, clean, covered container for disposal. Keep this material out of watersheds and waterways. Waste Disposal Method: "Waste disposal" as that term is defined in CFR "Identification and Listing of Hazardous Waste. " Bum in an approved incinerator or dispose of in an approved chemicallandfill in accordance with all applicable local, state, and federal lawsand regulations. Consultyour attorney or appropriate regulatory officials for information on such disposal. Empty Containers: Bum containers in an approved incinerator dispose of in an approved chemicallandfill in accordance with allapplicable local, state, and federal laws and regulations.

--- SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have not established specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PEL/8-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGZH Z V B - h r TWA: Total mg/m3, respirable 5 mg/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. Eye ProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Wear rubber gloves and goggles.

Antioxidants, Stabilizers, and Fire Retardants

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequate ventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--- REGULATORY INFORMATION -DOTProperShippingName:

NA

DOTHazard Clasd1.D. No: NA

DOT Label: Not applicable U.S. SurfaceFreightClassification:

Rubber Preservative, N.O.I.B.N.

Reportable Quantity (RQ) under DOT (49 CFR) and CERCLARegulations: NA SARA Hazard Notification: Hazard Categories under criteria of SARA Title 111 rules Delayed Section HazardousChemical(s): NA

CFR Part

Hazardous Chemical(s) under OSHA Hazard Communication Standard: This substance is identified as a hazardous chemical under the criteria of the OSHA Hazard Communication Standard CFR

Chapter 6

344

--IDENTIFIERS --

Chemical Name and Synonyms: DIPHENYLAMINE temperature reaction product TradeNameandSynonyms:

Acetone low-

Aminox

Chemical Family: Antioxidant for rubber Manufacturer: UniroyalChemicalCo.,Naugatuck,Connecticut UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA -Material

No.

Cas

Product Not

%

NA

--

PHYSICAL DATA

established

--

BoilingPoint (“F):NA SpecificGravity (H,O = 1): 1.16 VaporPressure (mm Hg): NA Percent Volatile byVolume (%): Nonvolatile VaporDensity (air = 1): NA FreezingPoint:

NA

EvaporationRate: NA pH. Noncorrosive Solubility: Insoluble in water; soluble in acetone and benzene MeltingPoint(“C):

m

85 min.

AppearanceKolorlOdor: Greenishbrownpowder.

Antioxidants, Stabilizers, and Fire Retardants

345

--FIRE AND EXPLOSION HAZARDS --FlashPoint: 355OF (TCC) FlammabilityLimits:

NA

Autoignition Temperature: DecompositionTemperature:

In excess of normal processing temperatures NA

Extinguishing Media: Carbon dioxide, dry chemical, or water. Special Fire Fighting Procedures: Do not use high-pressure water stream. Airborne dust creates an explosion hazard. Unusual Fire and Explosion Hazards: Dust may be explosive if mixed with air in critical proportions and in the presence of a source of ignition. The hazard is similar to that of any organic solid including sawdust. Maintain normal good housekeeping for control of dust. Hazardous Products of Combustion and Decomposition:

Unknown.

HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA -Effects of Overexposure:None expected; however, manufacturer recommends that user avoid excessive skin contact and observe good personal hygiene. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalalion: Expose fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

--

TOXICITY DATA

---

AnimalEffects: Noadversemedical history based on over 20 years of productionand use. Oral LD50 (rats): >5 gkg.

346

Chapter 6

--REACTIVITY DATA -Stability and Conditions to Avoid: No specific incompatibility. Materials to Avoid (Incompatibility): None. Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide and/or carbon dioxide. HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE --For Spills: Vacuum or sweep up and place into dry, clean, covered container for disposal. Keep this material out of watersheds and waterways. Waste Disposal Method:No specific recommendations made by manufacturer. Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemicallandfill in accordance with allapplicable local, state, and federal laws and regulations.

--- SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have not established specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PELB-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGZH ZZV/8-hr TWA: Total mg/m3, respirable 5 mg/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible.

Antioxidants, Stabilizers, and Fire Retardants

347

Protective Gloves and Other: Wear rubber gloves and goggles. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcan lead to spontaneous combustion (dust explosions).

--REGULATORY INFORMATION --None reported.

--- IDENTIF’IERS --Name:DILAURYLBETA-THIODIPROPIONATE Synonyms: Advastab 800; Antioxidant AS; Antioxidant LTDP; Bis(Dodecy1oxycarbonylethyl) Sulfide; Carstab DLTDP; Cyanox LTDP; Didodecyl 3,3’Thiodipropionate; Dilaurylester Kyseliny beta’,beta’-Thiodipropionove (Czech); Dilauryl Thiodipropionate; Dilauryl beta-Thiodipropionate; Dilauryl beta’,beta’-Thiodipropionate;Dilauryl3,3’-Thiodipropionate;DLT, DLTDP; DLTP; DMPTP; Ipognox 89; Irganox PS 800; Lauryl3,3’-Thiodipropionate; Lusmit;Milban F; NeganoxDLTP;PlastanoxLTDP;Plastanox LTDP Antioxidant; Propanoic Acid,3,3’-Thio-bis-, Didodecyl Ester; Stabilizer DLT; Thiobis (Dodecyl Proprionate); Tyox B CAS: 123-28-4; RTECS: UF8000000 Formula: C&I,,O,S; Mol Wt: 514.94

Chapter 6

R N : 12OV2S2VO12 Chemical Class: Ester See other identifiers listed below under Regulations.

--PROPERTIES -BoilingPoint: NA MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density: No data Specific Gravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents:No data Polymerization Possibilities: No data Toxic Fire None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--

REGULATIONS

DOT hazard class: Not given Packaging exceptions: Nonbulkpackaging: Bulkpackaging: STCC Number: Not listed Clean Water Act Sect. 307: No Clean Water Act Sect. 311: No Clean Air Act:Not listed EPA Waste Number: None CERCLA Ref: Not listed RQ Designation: Notlisted

--

Antioxidants, Stabilizers, and Fire Retardants

SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acutetoxicity:

irritant.

U.S. Postal Service Mailability: Not given

- TOXICITY DATA -Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

Conc IDLH Unknown NIOSH REL: Not given ACGIH TLV: Notlisted ACGIH STEL Not listed OSHA PEL: Not in Table Z-l-A MAK Information: Not listed Carcinogen: N; Status: Seebelow CarcinogenLists: IARC: Not listed; M A K Not listed; NZOSH Not listed; N T P Not listed; ACGZH Not listed; OSHA: Not listed. LDS0 Value: No LD50 in RTECS 1992 Other Species ToxicityData: (Source: NIOSH RTECS 1992) unr-mam LD50:> 15 g/kg Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

--

This chemical has

INITIAL INCIDENT RESPONSE

No DOT Guide information for this product.

--

known

Chapter 6

--IDENTIFIERS --Chemical Name and Synonyms: PHENYLENEDIAMINE

N-PHENYL-W-CYCL0HEXYL-pFlexzone 6H

Trade NameandSynonyms: ChemicalFamily:

Antiozonant/Antioxidant

Manufacturer: UniroyalChemical Co., Naugatuck,Connecticut

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --Material

No. Cas

%

Product

TLV established

--- PHYSICAL DATA --BoilingPoint (“F):NA SpecificGravity (H,O = 1): 1.18 VaporPressure(mmHg):

NA

Percent Volatile byVolume (%): Nonvolatile VaporDensity(air = 1): NA FreezingPoint:

NA

EvaporationRate:

NA

p H Noncorrosive Solubility: acetone.

Slightly soluble water in

MeltingPoint(“C):

100 min.

and hydrocarbons; soluble in

1

Antioxidants, Stabilizers, and Fire Retardants

AppearanceKolorlOdor: Purplepowder.

--

FIRE AND EXPLOSION HAZARDS

--

FlashPoint: NA FlammabilityLimits:

NA

Autoignition Temperature: Abovenormalprocessingtemperatures DecompositionTemperature:

NA

Extinguishing Media: Carbon dioxide, dry chemical, or water. Special Fire Fighting Procedures: Do not use high-pressure water stream. Airborne dust creates an explosion hazard. Unusual Fire and Explosion Hazards: Dust may be explosive if mixed with air in critical proportions and in the presence a source ignition. The hazard is similar to that any organic solid including sawdust. Maintain normal good housekeeping for control dust. Hazardous Products of Combustion and Decomposition:

Unknown

HazardousPolymerization: Willnotoccur

--- HEALTH HAZARD DATA --Effects of Overexposure: Some skin irritation potential. Avoid breathing dust or vapors. Avoid skin and eye contact. Wash thoroughly after use. Emergency Response and First Aid: Skin: Wash with lots clean water for at least 15 min. Eyes: Flush eyes withlots water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

Chapter 6

352

TOXICITY DATA

--

AnimalEffects: OralLD50 (rats): over 2 g/kg. Human patch testing and experience have not indicated the material to cause irritation or sensitization. However, as with any phenylenediamine derivative, care should be used in handling. People sensitized to otherp-phenyldiamines may encounter dermatitis problems.

- REACTIVITY DATA --Stability and Conditions to Avoid: No specific incompatibility. Materials to Avoid(Incompatibility): None. Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide and/or carbon dioxide. HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE

-

For Spills: Vacuum or sweep up and place into dry, clean, covered container for disposal. Keep this material out of watersheds and waterways. Waste Disposal Method: No specific recommendations made by manufacturer. Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemicallandfill in accordance withall applicable local, state, and federal laws and regulations.

--- SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have not established specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PEL/8-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGIH TLV/8-hr TWA: Total 10 mg/m3, respirable 5 mg/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Antioxidants, Stabilizers, and Fire Retardants of VentilationRequired: Generalmechanical.Avoid.breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm.

EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Wear rubber gloves and goggles. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Use all standard practices for goodpersonalhygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--REGULATORY INFORMATION --None reported.

--IDENTIFIERS --Chemical Name and Synonyms: TETRAKIS(MET€€YLENE(3,5-DI-TERTBUTYL-4-HYDROXYHYDROCINNAMA'IE)) METHANE

-19-8

Chapter 6

354

Trade Name and Synonyms: Irganox 1010 ChemicalFamily:

Antioxidant/Stabilizr

Manufacturer: Ciba-Geigy Corp., Hawthorne,New York UN ID Number: NA ” -

INGREDIENTS AND COMPOSITION DATA

Material

No.

Cas

%

Product

--TLV -

established

--

PHYSICAL DATA

---

BoilingPoint (“F):NA SpecificGravity (H,O = 1): 1.15 Vapor Pressure (mm Hg): 1 x 10l2 mm Hg Percent Volatile byVolume (%): < O S VaporDensity(air FreezingPoint:

= 1): NA

NA

EvaporationRate:

NA

p H NA Solubility inWater:

1ppm

MeltingPoint (“C): 110 to 125 Appearance/Color/Odor: White to off-white, crystalline powder.

--- FIRE AND EXPLOSION HAZARDS --FlashPoint: 567°F (Marcusson)

Antioxidants, Stabilizers, and Fire Retardants

FlammabilityLimits:

355

NA

AutoignitionTemperature: Abovenormalprocessingtemperatures DecompositionTemperature:

NA

Extinguishing Media: Carbon dioxide, dry chemical, or water. SpecialFireFightingProcedures:

Useself-contained breathing apparatus.

Unusual Fire and Explosion Hazards: The product can form an explosive dust/air mixture. Avoid dust formation and control ignition sources; employ grounding, venting, and explosion-relief provisions in accord with accepted engineering practices in process operations capable of generating dust and/or static electricity. Hazardous Products of Combustion and Decomposition: Thermal decomposition and burning may produce carbon monoxide and carbon dioxide. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA --Effects of Overexposure: This material is not intended for use in products for which prolonged contact with mucous membranes abraded skin or implantation within the humanbody is specifically intended, unless the finished product has been testedin accordance with the Food and Drug Administration and/or other applicable safety testing requirements. Primary routes of exposure: Dermal, ingestion and inhalation ThresholdLimitValue:none established.

Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

Chapter 6

356

--TOXICITY DATA -Animal Effects: Oral LDSO: (Rats) >5OOO mgkg DermalLDSO: (Rabbits) > mg/kg Skin Irritation: (Rabbits) None (Draize score 018) Eye Irritation: (Rabbits) None (Draize score 0/110) Sensitization: RIPT(humans):not a primary irritant and no evidence of sensitization under the conditions of the study, which involved testing of a 0.5% W/V solution in dimethyl phthalate. Inhalation LC50: (Rats) > 46 mg/l air for a l-hr dust exposure. (Rats) exposure for 4 hr to thefumes and vapors emitted when product was heated to 316°C resulted in no deaths or untoward behavioral reactions for an average nominal concentration of 0.1 l mg/l air. Teratogenicity: (Rats andmice)No teratogenic effects. Mutagenicity: AmesTest:negative. Dominant lethal, mice: no evidence of a dominant lethal effect. Nucleusanomaly test, Chinese hamster: negative. Chromosome studies insomatic cells, Chinesehamster: negative. Signs and Symptoms of Exposure (Acute): no identified health effects. Signs and Symptomsof Exposure (Chronic): no identified health effects. Medical Conditions Aggravated by Exposure: none known.

--REACTIVITY DATA -Stability and Conditions to Avoid: No specific incompatibility. Materials to Avoid (Incompatibility): Strong oxidizing agents. Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide and/or carbon dioxide. Hazardous Polymerization: Will not occur.

- SPILL AND EMERGENCY RESPONSE -For Spills: Sweep or vacuum and place into closable container for disposal. Wear protective equipment specified below. Thoroughly flush residue with water.

Antioxidants, Stabilizers, and Fire Retardants

357

Waste Disposal Method: Incinerate in chemical incinerator equipped with an afterburner and scrubber. Follow all federal, state, andlocal regulations. EfluenfDafa-Bod: AerobicsewageOECDcoupled units test No. 303A: Average elimination measured by specific analysis was 45.2% of the initially measured concentration. Efluenf Dafa-Cod: 2.38 G COD/G Irganox 1010. Sewage Bacterial Toxicity: Inhibitory concentration on respiration of aerobic wastewaterbacteria:IC20,IC50,IC80 > ppm. Fish toxicity: Zebra Fish, LC50 96 H: > 100ppm. InvertebrateToxicity: DaphniaMagna, EC50 24 H: >86 ppm. Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemical landfill in accordance with all applicable local, state, and federal laws and regulations.

--- SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have not established specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PEL/8-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGZH 7LV/8-hr TWA: Total 10 mg/m3, respirable 5 mg/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemicalgoggles.Eyewash safety showers should be easily accessible.

fountains and

Protective Gloves and Other: Wear rubber gloves and goggles. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution toprevent damage to or leakage from the container.

358

Chapter 6

Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--REGULATORY INFORMATION --DOT Proper Shipping Name: Not regulated as a hazardous material by the U.S.Departmentof Transportation (DOT) 49 CFR172.101Hazardous Materials Table. DOTClass: None. DOTNumber: None. RCRA Status: Not a hazardous waste under RCRA CFR 261). CERCLAStatus: Not listed. SARA/Title In-Toxic Chemicals List: This product does notcontain a toxic chemical for routine annual'ToxicChemicalReporting'underSec. 313 (40 CFR 372). TSCA Inventory Status: Chemical components listed on TSCA inventory. CaliforniaProposition 65: Thisproductdoesnotcontainanychemicals currently the California List of known carcinogens and reproductive toxins. New Jersey Right-to-Know Labeling Information:This product contains the following: Chemicalname: Tetrakis(Methylene(3,5-Di-Tert-Butyl-4-Hydroxyhydrocinnamate))Methane Casnumber:6683-19-8 Chemicalname: Pentaerythritol Tris Ester with 3-(3,5-Di-Tert-Butyl-4Hydroxypheny1)Propionic Acid Casnumber:84633-54-5 Percent: Impurity

Antioxidants, Stabilizers, and Fire Retardants

359

Pennsylvania Right-to-Know Act: The following is required composition information. Chemicalname:BenzenepropanoicAcid, 3,5-Bis(l,l-Dimethylethyl)-4Hydroxy-, 2,2-Bis((3-(3,5-Bis(l,I-Dimethylethyl)-4-Hydroxyphenyl)-lOxopropoxy)Methyl)-l,3-Propanediyl Ester Casnumber:6683-19-8 Common name: Tetrakis(Methylene(3,5-Di-Tert-Butyl-4-Hydroxyhydrocinnamate))Methane; 3,5-Di-Tert-Butyl-4-Hydroxyhydrocinnamic Acid, Neopentanetetrayl Ester; P Entaerythritol Tetrakis(3,5-Di-Tert-Butyl-4Hydroxyhydrocinnamate);Irganox1010 Comments:NotonPennsylvaniaHazardousSubstance List.

--IDENTIFIERS --Chemical Name and Synonyms: HINDERED PHENOLIC ANTIOXIDANT Trade NameandSynonyms:

Irganox1035

ChemicalFamily: HinderedPhenolicAntioxidant Manufacturer: Ciba-Geigy Corp., Hawthorne, New York UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --Material

No.

Cas

%

Product

TLV -

established

--- PHYSICAL DATA -BoilingPoint (“F):147min. SpecificGravity (H,O = 1): NA VaporPressure(mm Hg): NA Percent Volatile byVolume (%): NA

Chapter 6

VaporDensity (air = FreezingPoint:

NA

NA

EvaporationRate:

NA

p H NA % at 22°C

Solubility:

MeltingPoint(“C):

NA

Appearance/Color/Odor: Crystalline, free-flowing powder; odorless.

--- FIRE AND EXPLOSION HAZARDS -FlashPoint: NA FlammabilityLimits: NA Autoignition Temperature: Above normal processing temperatures DecompositionTemperature:

NA

Extinguishing Media: Carbon dioxide, dry chemical, or water. SpecialFireFightingProcedures:

Nonerecommendedbymanufacturer.

Unusual Fire and Explosion Hazards: None recommended by manufacturer. Hazardous Productsof Combustion and Decomposition: Thermal decomposition and burning may produce carbon monoxide and carbon dioxide. HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA --Effects of Overexposure: No effects reported bymanufacturer;however, should be treated as any nuisance dust.

Antioxidants, Stabilizers, and Fire Retardants Primary routes of exposure: Dermal, ingestion, and inhalation ThresholdLimitValue:none established.

Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

--

TOXICITY DATA

--

Animal Effects: Acute oral LD50 in (male and female) mice 4556 mgkg; not a primary irritant, fatiguing agent, or sensitizer in human test subjects.

--REACTIVITY DATA -Stability and Conditions to Avoid: No specific incompatibility. Materials to Avoid (Incompatibility): Strong oxidizing agents. Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide and/or carbon dioxide. Hazardous Polymerization: Will not occur.

--SPILL AND EMERGENCY RESPONSE For Spills: Sweep or vacuum and place into closable container for disposal. Wear protective equipment specified below. Thoroughly flush residue with water. Waste Disposal Method:

Normal plant water, bury, or incinerate.

Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemicallandfill in accordance with allapplicable local, state, and federal laws and regulations.

Chapter

--- SPECIAL PROTECTION AND PRECAUTIONS RespiratoryProtection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have established not specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PEL/8-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGZH iZV/8-hr TWA: Total mg/m3, respirable 5 mg/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Type of VentilationRequired: Generalmechanical.Avoidbreathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other:

Wear rubber gloves and goggles.

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughly clean allequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

Antioxidants, Stabilizers, and Fire Retardants

363

--REGULATORY INFORMATION -None reported.

--- IDENTIF’IERS -ChemicalNameandSynonyms:OCTADECYL HYDROXYHYDROCINNAMATE

3,5-DI-TERT-BUTYL4-

Trade Name and Synonyms: Irganox 1076 ChemicalFamily: RubberAntioxidant Manufacturer: Ciba-Geigy Corp., Hawthorne,New York

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA -Material

No.

%

Cas

Product

established

--- PHYSICAL DATA --BoilingPoint (“F):NA SpecificGravity (H,O = 1): 1.02 VaporPressure(mm

Hg): 2x

Percent Volatile by Volume (%): VaporDensity(air = 1): FreezingPoint:

NA

EvaporationRate: NA pH: NA

mm Hg at 20°C

<1

Chapter 6

Solubility: Insoluble Melting Point (“C):

to 55

Appearance/Color/Odor: White to off-white crystalline powder.

--FlRE AND EXPLOSION HAZARDS -FlashPoint: 523°F (Marcusson) FlammabilityLimits: NA Autoignition Temperature: Above normal processing temperatures DecompositionTemperature:

NA

Extinguishing Media: Carbon dioxide, dry chemical, or water spray. SpecialFireFightingProcedures: UnusualFireandExplosionHazards: products may be toxic.

Use self-contained breathing apparatus. Decompositionandcombustion

Hazardous Productsof Combustion and Decomposition: Thermal decomposition and burning may produce carbon monoxide and carbon dioxide. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA Effects of Overexposure: This material will not be sold for use in products for which prolongedcontact with mucous membranesor abraded skin or implantation within the human body is specifically intended. Primary routes of exposure: Dermal, ingestion, and inhalation ThresholdLimitValue:none established.

Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician.

Antioxidants, Stabilizers, and Fire Retardants

Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

--TOXICITY DATA -Animal Effects: Primary Routes of Exposure: dermal, ingestion, and inhalation. Oral LD50: (Rats) > mg/kg Intraperitoneal LDSO: (Rats) > 1000mg/kg DermalLD50: (Rabbits) mg/kg SkinIrritation: (Rabbits) Minimal(Draize score 0.95/8) Phototoxicity: negative. Eye Irritation: (Rabbits) Minimal(Draize score 4/110) Sensitization: (Guinea pigs) Considered to possess no skin sensitizing potential. RIPT (humans) in 4 separate studies, a total of of 183 subjects exhibited reactions indicative sensitization; concentrations rangedfrom 25% in petrolatum (25 subjects), 0.5% in dimethyl phthalate (58 subjects), to neat material (100 subjects). Inhalation LCSO: (Rats) > 1.8 mg/l air for a 4-hr dust exposure with approximately 9 0 % particles C7 mm diameter. Teratogenicity: (Rats andmice)No teratogenic effect seen. Mutagenicity: AmesTest: negative. Dominant lethal test (mouse): no evidence of a dominant lethal effect. Signs and Symptoms of Exposure (Acute): Caution!! May cause irritation to skin, especially after prolonged or repeated exposure, and especially in body areas of heavy perspiration, based upon use experience. Signs and Symptoms of Exposure (Chronic): no identified health effects.

--- REACTIVITY DATA -Stability and Conditions to Avoid: No specific incompatibility. Materials to Avoid (Incompatibility): Strong oxidizing agents.

Chapter 6

Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide and/or carbon dioxide. HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE -For Spills: Prewetmaterialwithwater to avoid dust formation. Sweep or vacuumandplace in closable container for disposal. Wear protective equipment specified below. Flush residue with water. Waste Disposal Method: Dispose in accordance with federal, state, and local regulations. Efluent Dura-BOD: (Sturn test) Partially biodegradable. Fish toxicity: Bluegill LC50 (96 hr): > ppm. Invertebrate toxicity: Daphnia Magna EC50 (24 hr): > 100 ppm. Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemical landfill in accordance with allapplicable local, state, and federal laws and regulations.

--

SPECIAL PR0"ION

AND PRECAUTIONS --

Respiratory Protection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have notestablished specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PEL/8-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGZH lZV/8-hr TWA: Total 10 mg/m3, respirable 5 mg/m3. These limits are statedonly to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other:

Wear rubber gloves and goggles.

Antioxidants, Stabilizers, and Fire Retardants

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking, Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughlyclean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--- REGULATORY INFORMATION -DOT Proper Shipping Name: Not regulated as a hazardous material by the CFR Hazardous U.S.Department of Transportation (DOT) Materials Table. DOTClass: None. DOTNumber: None. RCRA Status: Not a hazardous waste under RCRA CFR CERCLAStatus: Not listed. TSCA Inventory Status: Chemical components listed TSCA inventory.

--- IDENTIFIERS -Chemical Name and Synonyms: TRIS(3,5-DI-TERT-BUTYL-4HYDR0XYBENZYL)ISOCYAATE Trade Name and Synonyms: Irganox ChemicalFamily: RubberAntioxidant

368

Chapter 6

Manufacturer: Ciba-Geigy Corp., Hawthorne, New York

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA -Material established Product

No. Cas Not

-

TLV

27676-62-6

- PHYSICAL DATA -BoilingPoint (“F):NA SpecificGravity (H,O =

1.03

Vapor Pressure (mm Hg): Not determined, but very low PercentVolatilebyVolume VaporDensity(air FreezingPoint:

=

(%): cO.01

NA

NA

EvaporationRate:

NA

p H NA

Solubility: Insoluble MeltingPoint(“C): 220 Appearance/Color/Odor: Fine white crystalline powder with odor.

discernable

--FIRE AND EXPLOSION HAZARDS -Flash Point: 552°F (Cleveland closed cup) FlammabilityLimits:

NA

AutoignitionTemperature:

Abovenormalprocessingtemperatures

Antioxidants, Stabilizers, and Fire Retardants

DecompositionTemperature:

369

NA

Extinguishing Media: Carbon dioxide, dry chemical, or water spray. Special Fire Fighting Procedures:

Use self-contained breathing apparatus.

UnusualFireandExplosionHazards: Decompositionandcombustion products may be toxic. When this product was heatedto various temperatures and rats exposed for 4-hr to the emittedfumesand vapors, the following results were observed: 1. ExposureTemperature316°C:Adversebodyweight 2. ExposureTemperature316°C: ExposureTemperature288°C:No

gains

100%Mortality after 1 day

reactions

The manufacturernotes that the differing results at 3 16°C cannot explained. be

Hazardous Productsof Combustion and Decomposition:Thermal decomposition and burning may produce carbon monoxide and carbon dioxide, nitrogen oxides, and small amounts of aromatic and aliphatic hydrocarbons. HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA -Effects of Overexposure: This material will not be sold for use in products for which prolongedcontact with mucous membranesor abraded skin or implantation within the human body is specifically intended. There are reported medical conditions aggravated by exposure. Primary routes of exposure: Dermal, ingestion, and inhalation ThresholdLimitValue:none established.

Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consult physician immediately.

Chapter 6

CancerInformation: None reported.

- TOXICITY DATA Animal Effects: Oral LD50: (Rats) > 6800 mg/kg; >5000 mgkg DermalLD50: (Rabbits) > mg/kg SkinIrritation: (Rabbits) Slight erythema,which cleared after 24 hr (OECD 404) EyeIrritation: (Rabbits) (1) Nonirritant; (Rabbits) (2) Slight irritation, which cleared after 7 days (OECD 405) Sensitization: (Guinea pigs) No animal sensitized in maximization test. RIPT (humans) not a primary irritant, fatiguing agent, or sensitizer in any of 200 individuals. Tested as a slurry (concentration not specified). Inhalation LC50: (Rats) >66.6 mg/l air for a 1-hr dust exposure Mutagenicity: Ames Test: negative.

--- REACTIVITY DATA --Stability and Conditions to Avoid: No specific incompatibility. Materials to Avoid (Incompatibility): Strong oxidizing agents. Hazard DecompositionProducts: Thermal decompositionmay produce carbon monoxide and/or carbon dioxide. HazardousPolymerization: Will not occur.

--- SPILL AND EMERGENCY RESPONSE -ForSpills: Prewetmaterialwithwater to avoid dust formation. Sweep or vacuumand place in closable container for disposal. Wear protective equipment specified below. Flush residue with water. Waste Disposal Method: Dispose in accordance with federal, state, and local regulations. Efluent Dutu-BOD: (Sturm test) Partially biodegradable. Fish roxicity: Bluegill LC50 (96 hr): > 100 ppm. Invertebrate toxicity: Daphnia Magna EC50 (24 hr): > 100 ppm.

Antioxidants, Stabilizers, and Fire Retardants

1

Empty Containers: Burn containers in an approved incinerator or dispose of in an approved chemical landfill in accordance with allapplicable local, state, and federal laws and regulations.

- SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have not established specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PELB-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGZH ZZVB-hr TWA: Total 10 mg/m3, respirable 5 mg/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts. Type of VentilationRequired: Generalmechanical.Avoidbreathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Wear rubber gloves and goggles. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause anexplosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Use all standard practices for goodpersonalhygiene. Completely isolate andthoroughlyclean all equipment, piping, or vessels

372

Chapter 6

beforebeginningmaintenance or repairs. Keepareaclean.Aswithany powder dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

- REGULATORY INF'ORMATION -DOT Proper Shipping Name: Not regulated as a hazardous material by the U.S. DepartmentofTransportation(DOT) 49 CFR 172.101Hazardous Materials Table. DOTClass: None. DOTNumber: None. RCRA Status: Not a hazardous waste under RCRA (40 CFR 261). CERCLAStatus: Not listed. TSCA Inventory Status: Chemical components listed on TSCA inventory.

--IDENTLFIERS Name: N,N"DIPHENYL-p-P€IENYLENEDIAMINE Synonyms: Agerite;Agerite DPPD; 1,4-Bis(Phenylamino)Benzene; N,NDifenyl-p-Fenylendiamin (Czech); Diphenyl-p-Phenylenediamine; N N Diphenyl-p-Phenylenediamine;DPPD; Flexamine G ; JZF; Nonox DPPD; p Phenylaminodiphenylamine;4-Phenylaminodiphenylamine;USAFGY-2 CAS: 74-31-7; RTECS ST2275000 Formula: C,8H,6NZ;Mol Wt: 260.36 WLN: RMRDMR ChemicalClass: Aromaticamine See other identifiers listed below under Regulations.

--PROPERTIES -Boiling Point: -498.16 K at 0.5 mm; 0 to 225°Cat 0.5 8 to 437°F at 0.5 mm Melting Point: 419.16 to 421.16 K; 146 to 148°C; 294.8 to 298.4"F FlashPoint: NA Autoignition: NA UEL: NA LEL: NA VaporDensity: No data SpecificGravity: No data

Antioxidants, Stabilizers, and Fire Retardants Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities:No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

- REGULATIONS -DOT hazard class: Not given Packaging exceptions: Nonbulk packaging: Bulkpackaging: STCC Number: Notlisted Clean Water Act Sect. 307: No Clean Water Act 311: No Clean Air Act:Notlisted EPA Waste Number: None CERCLA Ref: Notlisted RQ Designation: Notlisted SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acutetoxicity: irritant. Chronic toxicity: mutagen. Chronic toxicity:reproductive toxin. U.S. Postal Service Mailability:

Not given

--TOXICITY DATA -Short-term Toxicity: Unknown Long-term Toxicity: Unknown Conc IDLH Unknown

374

Chapter 6

NOSH REL: Not given ACGIHTLV: Not listed ACGIHSTEL: Notlisted OSHA PEL: Not in Table Z-l-A

MAK Information: Notlisted Carcinogen: N; Status: Seebelow Carcinogen Lists: Z A R C Not listed; MAK: Not listed; NIOSH: Not listed; N T P Not listed; ACGIH Not listed; OSHA: Not listed. LDS0Value: orl-rat LD50:2370mg/kg Other SpeciesToxicity Data: (Source: NIOSHRTECS1992) orl-rat LD50:2370 mg/kg orl-mus LD50: 18 g/kg ipr-mus LD50:300 mg/kg

ReproductiveToxicity reproductive toxin.

(1992 RTECS):

This chemical is amammalian

Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo:450 mg/kg (14D pre/l-22D preg) JAFCAU 4, 796, 56 Maternal Effects Parturition Effects Newborn Stillbirth orl-rat TDLo:2500 mg/kg (1-22D preg) AJANA2, 110, 29, 62 Effects on Fertility Postimplantation mortality

--- INITIAL INCIDENT RESPONSE -No DOT Guide information for this product.

Antioxidants, Stabilizers, and Fire Retardants

375

--IDENTIFIERS --Chemical Name and Synonyms: OCTYLATED DIPHENYLAMINE

AND

N"DIPHENYL-p-PHENYLENEDIAMINJ3 Trade NameandSynonyms:

Agerite HP-S

ChemicalFamily: RubberAntioxidant Manufacturer: R. T. Vanderbilt Co., Inc., Norwalk,Connecticut

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA -Material

No. Cas

%

Not Octylated diphenlamine 1-46-1 6841

TLV established

N,N"Diphenyl-p1-7 74-3 phenylenediamine

Not established

--PHYSICAL DATA --BoilingPoint ("F):NA Specific Gravity (H,O = 1): 1.l1 Vapor Pressure (mm Hg):

Not determined, but very low

Percent Volatile byWeight (?h): 1.0 max. VaporDensity(air = 1): NA FreezingPoint:

NA

EvaporationRate: NA pH: NA Solubility: Negligible in water; soluble in acetone, toluene, chloroform, carbon disulfide; slightly soluble in gasoline.

Chapter 6

Melting Point (“C): 80 to 100 Appearance/Color/Odor: Tan to brown powder with slight phenolic odor.

- FIRE AND EXPLOSION HAZARDS -FlashPoint: NA FlammabilityLimits: NA AutoignitionTemperature: Abovenormalprocessingtemperatures DecompositionTemperature:

NA

Extinguishing Media: Carbon dioxide, dry chemical, or water spray. Carbon dioxide may be ineffective larger fires due to lack cooling capacity, which may result in reignition. Special Fire Fighting Procedures:Use positive-pressureSCBA (self-contained breathing apparatus). Inenclosed or poorly ventilated areas, useSCBA during cleanup immediately after a fire and during fire fighting. UnusualFireandExplosionHazards: Decompositionandcombustion products may be toxic. Dust suspended in the air in critical proportions and in the presence of an ignition source may present an explosion hazard. Hazardous Productsof Combustion and Decomposition: Thermal decomposition and burningmay produce carbon monoxide and carbon dioxide, nitrogen oxides, and small amounts of aromatic and aliphatic hydrocarbons. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA --Effects of Overexposure: None expected for product. Heating may generate vapors, which can irritate the eyes and respiratory passages. Primary routes of exposure: Dermal, ingestion, and inhalation. ThresholdLimitValue:none established.

Antioxidants, Stabilizers, and Fire Retardants

377

Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consult physician immediately. CancerInformation: None reported.

--TOXICITY DATA -Animal Effects: For Octylated Diphenylamine: Acute oral LD50 mg/kg in rats. For N,N'-Diphenyl-p-phenylenediamine: Acute oral LD50 ca. 10,000 mg/kg in rats. REACTIVITY DATA

--

StabilityandConditions thermally stable.

--

to Avoid:

Thisproductis

described as being

Materials to Avoid(Incompatibility): Strong oxidizing agents such as hydrogen peroxide, permanganates, and perchlorates. Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide and/or carbon dioxide, small amounts of aromatic and aliphatic hydrocarbons, as well as oxides of nitrogen. HazardousPolymerization: Willnot occur.

--

SPILL AND EMERGENCY RESPONSE

--

For Spills: Prewetmaterialwithwater to avoid dust formation. Sweep or vacuumand place in closable container for disposal. Wear protective equipment specified below. Flush residue with water. Waste Disposal Method: Dispose in accordance with federal, state, and local regulations. EfJluent Data-BOD: (Sturm test) Partially biodegradable. Fish toxicify: Bluegill LC50 hr): > 100 ppm. Invertebrate roxicify: Daphnia Magna EC50 (24 hr): > ppm.

Chapter 6

Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemical landfill in accordance with all applicable local, state, and federal laws and regulations.

--

SPECIAL PROTECTION AND PRECAUTIONS

--

Respiratory Protection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have not established specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PEL/8-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGZH 2ZV/8-hr TWA: Total mg/m3, respirable 5 mg/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable to nuisance dusts.

Type of Ventilation Required: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Wear rubber gloves and goggles. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause anexplosion. Keep containers closed. Store in a cool, dry place. Use with adequate ventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels

Antioxidants, Stabilizers, and Fire Retardants beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--REGULATORY INFORMATION -DOT Proper Shipping Name: Not regulated as a hazardous material by the U.S. Department of Transportation(DOT) CFR Hazardous Materials Table. DOTClass: None. DOTNumber: None. RCRA Status: Not a hazardous waste under RCRA CFR CERCLAStatus: Not listed. TSCA Inventory Status: Chemical components listed on TSCA inventory.

--- IDENTIFIERS --Chemical Name and Synonyms: DIPHENYLAMINES

MIXTURE OF OCTYLATED

Trade Name and Synonyms: Agerite" Stalite* S ChemicalFamily:

NA

Manufacturer: R. T. Vanderbilt Co., Inc., Norwalk,Connecticut UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA --Material

No.

Cas

Agerite

?!6 established

--

PHYSICAL DATA

BoilingPoint ("F):NA SpecificGravity CH,O = 1):

TLV Not

--

Chapter 6

VaporPressure(mmHg):

NA

Percent Volatile by Weight VaporDensity(air FreezingPoint:

1.5 mm.

= 1): NA

NA

EvaporationRate: NA p H NA Solubility: Insoluble in water; soluble in toluene, alcohol, and gasoline. MeltingPoint(“C): NA Appearance/Color/Odor: Lighttan to brown friable powder, slight amine odor.

--- FIRE AND EXPLOSION HAZARDS FlashPoint: 213°C(COC) FlammabilityLimits: NA AutoignitionTemperature: DecompositionTemperature:

Abovenormalprocessingtemperatures NA

ExtinguishingMedia: Foam, drychemical,water.Carbon dioxide may be ineffective on large fires due to lack of cooling capacity, which may result in reignition. SpecialFireFightingProcedures: Useself-containedbreathing apparatus (SCBA). In enclosed or poorly ventilated areas, wear SCBA during cleanup immediately after a fire and during fire fighting. Unusual Fire and Explosion Hazards:

None known.

Hazardous Productsof Combustion and Decomposition: Oxides of nitrogen and carbon, small amounts of aromatic and aliphatic hydrocarbons.

Antioxidants, Stabilizers, and Fire Retardants

HazardousPolymerization: Willnot occur.

- HEALTH HAZARD DATA -Effects of Overexposure: None expected for product. Heating may generate vapors, which can irritate the eyes and respiratory passages. For Diphenylamines: In general, may be irritating to the mucous membranes. Heating may generate vapors, whichcan irritate eyesand the respiratory passages. Primary Routes of Exposure: Dermal, ingestion, and inhalation. Rreshold Limit Value: None established. Emergency Response and First Aid: Skin: Wash with lots clean water for at least 15 min. Eyes: Flush eyes withlots water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported. TOXICITY DATA

--

Animal Effects: For Residual Diphenylamines (*I.O% OSHATWA: 10 mg/m3 ACGIHTLV-TWA: mg/m3 Acute Oral LD50 (rats): mgkg Ames Test: Negative Thirteen-Week Feeding Studies in Rats and Dogs: Daily administration in the diet of rats produced some toxic effects at levels as low as ppm. In dogs, no discernible toxic effects at ppm were reported. High levels of this material in the diet caused degenerative changes in the liver, kidney, adrenal medulla, and thyroid of rats and a decrease in blood prothrombin content in the rats and dogs.

Medical Conditions Generally Aggravated By Exposure: Unknown.

Chapter 6

-StabilityandConditions thermally stable.

REACTIVITY DATA to Avoid:

--

Thisproduct

is described as being

Materials to Avoid(Incompatibility): Strong oxidizing agents such as hydrogen peroxide, permanganates, and perchlorates. Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide and/or carbon dioxide, small amounts of aromatic and aliphatic hydrocarbons, as well as oxides of nitrogen. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE --For Spills: Vacuum or sweep into a closed container for disposal. Avoid dust generation. Do not flush chemical into public sewer or water system. Waste Disposal Method: Not classified as a RCRA hazardous waste. Dispose of according to applicable environmental regulations. Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemicallandfill in accordance withall applicable local, state, and federal laws and regulations.

--- SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection: Avoid breathing dust. Dust respirator recommended. Although OSHA and ACGIH have not established specific exposure limits for this material, they have established the following limits for nuisance dusts: OSHA PEL/8-hr TWA: Total 15 mg/m3, respirable 5 mg/m3. ACGZH 1ZV/8-hr TWA: Total mg/m3, respirable 5 mg/m3. These limits are stated only to indicate the least stringent airborne dust exposure levels applicable nuisance dusts. Type of VentilationRequired: Generalmechanical.Avoidbreathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations.

Antioxidants, Stabilizers, and Fire Retardants Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm.

EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Wear rubber gloves and goggles. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause anexplosion. Keep containers closed. Store a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--REGULATORY INFORMATION --None reported.

--IDENTIFIERS -ChemicalNameandSynonyms:POLYMERIZED 1,2-DIHYDR0-2,2,4TRIMETHYLQUINOLINE, POLYMERIZED TRIMETHYL DIHYDROQUINOLINE Trade Name and Synonyms: Agerite* MA (pellets, pastilles, and powder) ChemicalFamily:

NA

Chapter 6

384

Manufacturer: R. T.Vanderbilt Co., Inc., Norwalk,Connecticut

UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA --Cas Material

No.

Agerite Not

%

NA

TLV established

--- PHYSICAL DATA -Boiling Point (“F): NA SpecificGravity (H,O = l): 1.06 VaporPressure (mm Hg): NA Percent Volatile by Weight VaporDensity(air FreezingPoint:

1.0 mm.

= 1): NA

NA

EvaporationRate:

NA

pH. NA Solubility: Very soluble in acetone, toluene, chloroform, and carbon disulfide. Slightly soluble in petroleum hydrocarbons. Practically insoluble in water. MeltingPoint(“C):

105 C min.

Appearance/Color/Odor: Amber or cream to yellow pellets, pastilles, or powder;no odor. Powder: slight amine odor.

--FIRE AND EXPLOSION HAZARDS FlashPoint: 204°C (COC) FlammabilityLimits:

NA

Antioxidants, Stabilizers, and Fire Retardants

AutoignitionTemperature: DecompositionTemperature:

385

Abovenormalprocessingtemperatures NA

ExtinguishingMedia: Foam,dry chemical, water. Carbondioxidemay be ineffective on large fires due tolack of cooling capacity, which may result in reignition. SpecialFireFightingProcedures: Useself-contained breathing apparatus (SCBA). In enclosed or poorly ventilated areas, wear SCBA during cleanup immediately after a fire and during fire fighting. Unusual Fire and Explosion Hazards:

None known.

Hazardous Products of Combustion and Decomposition:Oxides of nitrogen and carbon, small amounts of aromatic and aliphatic hydrocarbons. HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA --Effects of Overexposure: None expected for product. Heating may generate vapors, which can irritate the eyes and respiratory passages. ForDiphenylamines: In general, may be irritating to the mucous membranes. Heating may generate vapors, whichcan irritate eyesand the respiratory passages. PrimaryRoutes oflikposure: Dermal, ingestion, and inhalation. 77zresholdLimit Value: None established. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If imtation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

Chapter 6

--- TOXICITY DATA -Animal Effects: For Assessing Exposure, Nuisance Dust Standard Recommended: OSHATWA: 15 mg/m3, total dust; 5 mg/m3, respirable dust ACGIHTWA: 10 mg/m3, total dust; 5 mg/m3, respirable dust Acute Oral D 5 0 (rats): 4900 mg/kg Acute Dermal D 5 0 (rabbits): mg/kg No skin or eye irritation observed in rabbits. The results of a 2-yr chronic toxicity/carcinogenicity rat feeding study, a lifetime hamster intratracheal, and mouseskin painting study were negative. AmesTest:

Negative

--- REACTIVITY DATA --Stability and Conditions to Avoid: Stable. Materials to Avoid(Incompatibility): Strong oxidizing agents such as hydrogen peroxide, permanganates, and perchlorates. Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide and/or carbon dioxide, small amounts of aromaticand aliphatic hydrocarbons, as well as oxides of nitrogen. HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE --For Spills: Vacuum or sweep into a closed container for disposal. Avoid dust generation. Do not flush chemical into public sewer or water system. Waste Disposal Method: Not classified as a RCRA hazardous waste. Dispose of according to applicable environmental regulations. Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemical landfill in accordance with allapplicable local, state, and federal laws and regulations.

Antioxidants, Stabilizers, and Fire Retardants

87

--- SPECIAL PROTECTION AND PRECAUTIONS RespiratoryProtection: Not typically required. If dusty conditions, wear NIOSH-approved respirator according to OSHA CFR Type of Ventilation Required: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Wear rubber gloves and goggles. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequate ventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--- REGULATORY INFORMATION -None reported.

Chapter 6

- IDENTIFIERS -ChemicalNameandSynonyms:POLYMERIZED TRIMETHYLQUINOLINE, QUINOLINE

1,2-DIHYDR0-2,2,4-

Trade Name and Synonyms:Agerite* Resin* D (pellets, pastilles, flakes, and powder) ChemicalFamily:

NA

Manufacturer: R. T. Vanderbilt Co., Inc.,Norwalk,Connecticut

UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA %

Cas No.

Material Quinoline

established

- PHYSICAL DATA --Boiling Point (“F): NA SpecificGravity (H,O =

Hg): NA

Vapor Pressure

Percent Volatile by Weight VaporDensity(air FreezingPoint:

to 1.09

= 1): NA

NA

EvaporationRate:

NA

p H NA

Solubilityin Water: Insoluble MeltingPoint(“C):

NA

1.0 mm.

m Not

Antioxidants, Stabilizers, and Fire 389 Retardants

Appearance/Color/Odor: Amber to cream to yellow to tan pastilles, powder, flakes, or pellets. No odor.

--FIRE AND EXPLOSION HAZARDS FlashPoint: 204°C (COC) FlammabilityLimits: NA Autoignition Temperature: Abovenormalprocessingtemperatures DecompositionTemperature:

NA

ExtinguishingMedia: Water,foam, dry chemical.Carbondioxidemaybe ineffective. SpecialFireFighting Procedures: Useself-contained breathing apparatus (SCBA). In enclosed or poorly ventilated areas, wear SCBA during cleanup immediately after a fire and during fire fighting. UnusualFireandExplosionHazards: Dustsuspended in air in critical proportions and in the presence an ignition source presents an explosion hazard. The following characteristics apply to powder and, also, are expected to apply to dust from pastilles, flakes, pellets or if these forms are reduced to a powder. Minimumexplosive concentration: 0.03 0z/ft3 Minimum ignition energy: 0.15 J (dust cloud) Maximum rate of pressure rise: 16,800 psi/sec at 0.1 oz/ft3 Maximum pressure of explosion: 72 psig at 0.5 0z/ft3 Explosion severity: 4.0 (severe) Ignition sensitivity: Notdetermined Explosibility index: Notdetermined Volume resistivity: 3.92x 10 17ohm-cm National Fire Protection AssociationStandard497M rating (1986 edition): Class 11, Group G

+

Dust is very sensitive to electrostatic discharge. Dustmaybe ignited by electrostatic discharge, electrical arcs, sparks, welding torches, open flame, or other significant heat sources. Bond, ground, and properly vent containers, conveyors, dust control devices, and other transfer equipment. Prohibit flow powder or dustthroughnonconductive ducts or pipes, etc.; onlyuse

Chapter 6 grounded, electrically conductive transfer lines when pneumatically conveying product. Prevent accumulation of dust (e.g., use well-ventilated conditions, promptly vacuum spills, clean overhead horizontal surfaces, etc.). Eliminate ignition sources such as sparks or static buildup (e.g., use humidification). A properly engineeredexplosionsuppressionsystemmustbeconsideredwhere large amountsofproduct are handled. See standards such as the National Fire Protection AssociationNFPA "Standard for the PreventionofDust Explosionsin the Plastics Industry"; NFPA "ExplosionPrevention Systems";NFPA "ExplosionVenting Protection"; NFPA 77, "Static Electricity"; and other standards as the need exists. Implement other measures as the need exists.

Hazardous Products of Combustion and Decomposition: Carbon monoxide, carbon dioxide, oxides of nitrogen, and aromatic and aliphatic hydrocarbons. HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA --Effects of Overexposure: None expected for product. Heating may generate vapors, which can irritate the eyes and respiratory passages. Primary Routes of Exposure: Dermal, ingestion, and inhalation. ThresholdLimitValue: None established. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consult physician immediately. CancerInformation: None reported.

--TOXICITY DATA --Animal Effects: For Assessing Exposure, Nuisance Dust Standard Recommended: OSHATWA: mg/m3, total dust; 5 mg/m3, respirable dust ACGIHTWA: mg/m3,total dust; 5 mg/m3, respirable dust Acute Oral LD50 (rats): mg/kg

Antioxidants, Stabilizers, and Fire Retardants

Acute Dermal D 5 0 (rabbits): >20,000 mglkg No skin or eye irritation observed in rabbits. 2-yr chronic feedingstudy in rats showed evidence of carcinogenicity. Mouse skin painting tests were negative. AmesTest:

Negative

Medical Conditions Generally Aggravated By Exposure: Unknown.

--REACTIVITY DATA -Stability and Conditions to Avoid: Stable. Materials to Avoid(Incompatibility): Strong oxidizing agentssuch hydrogen peroxide, permanganates, and perchlorates.

as

Hazard Decomposition Products:Thermal decompositionmay produce carbon monoxide and/or carbon dioxide, small amounts of aromatic and aliphatic hydrocarbons, as well as oxides of nitrogen. HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE --ForSpills: Sweep or wetmop into a closed container for disposal. Avoid generation of dust. Do not flush chemical into public sewer water system. Waste Disposal Method: Not classified as a RCRA hazardous waste. Dispose of according to applicable environmental regulations. Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemicallandfill accordance with allapplicable local, state, and federal laws and regulations.

--- SPECIAL PROTECTION AND PRECAUTIONS --RespiratoryProtection: Nottypically required. If dusty conditions, wear NIOSH-approved respirator according to OSHA CFR Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the

Chapter 6

392

ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm.

EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other:

Wear rubber gloves and goggles.

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequate ventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Aswithany powder or dustlike material, improperhandlingcanlead to spontaneous combustion (dust explosions).

--REGULATORY INFORMATION --None reported. v

v

v

v

v

v

v

v

v

v

v

v

v

v

--IDENTIFIERS -Chemical Name and Synonyms: POWDERED PHENOLIC Trade Name and Synonyms: Akrochem Antioxidant 33 ChemicalFamily: PhenolicAntioxidant

RESIN

Antioxidants, Stabilizers, and Fire Retardants

Manufacturer: AkronChemical Co., Akron,Ohio UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --Cas No.

Material phenolic Powdered

resin

TLV

%

NA

Not established

--PHYSICAL DATA -BoilingPoint (“F): NA SpecificGravity (H,O = 1): 1.04 VaporPressure(mmHg):

NA

Percent Volatile byWeight (%): NA VaporDensity(air = 1): NA FreezingPoint:

NA

EvaporationRate:

NA

pH: NA Solubility inWater:

Negligible

MeltingPoint (“C): 105 AppearancelColorlOdor: White powder; little odor at room temperature.

--FIRE AND EXPLOSION HAZARDS -FlashPoint:

>200°F

FlammabilityLimits: NA Autoignition Temperature: Above normal processing temperatures

Chapter 6

394

DecompositionTemperature:

NA

ExtinguishingMedia: Water,foam,dry ineffective.

chemical. Carbondioxidemaybe

SpecialFireFightingProcedures: Use self-contained breathing apparatus (SCBA). In enclosed or poorly ventilated areas, wear SCBA during cleanup immediately after a fire and during fire fighting. Unusual Fire and Explosion Hazards: high concentration could result in explosive mixture.

dust in the air

Hazardous Productsof Combustion and Decomposition: Carbon monoxide, carbon dioxide, and oxides of nitrogen. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA --Effects of Overexposure: Occasional reaction on persons with extreme skin sensitivity or allergic tendencies. Primary Routes of Exposure: Dermal, ingestion, and inhalation. ThreshoZd Limit Value: None established. Emergency Response and First Aid: Skin: Wash with lots clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consult physician immediately. CancerInformation: None reported.

--- TOXICITY DATA --Animal Effects: No information reported by manufacturer.

--- REACTIVITY DATA -Stability and Conditions to Avoid: Stable.

Antioxidants, Stabilizers, and Fire Retardants

395

Materials to Avoid(Incompatibility): Strong oxidizing agents suchas hydrogen peroxide, permanganates, and perchlorates. Hazard Decomposition Products:Thermal decomposition may produce carbon monoxide and/or carbon dioxide, small amounts of aromatic and aliphatic hydrocarbons, as well as oxides of nitrogen. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE --For Spills: Sweep or wetmop into a closed container for disposal. Avoid generation of dust. Do not flush chemical into public sewer or water system. Waste Disposal Method: Not classified as a RCRA hazardous waste. Dispose of according to applicable environmental regulations. Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemicallandfill in accordance with allapplicable local, state, and federal laws and regulations.

--- SPECIAL PROTECTION AND PRECAUTIONS --RespiratoryProtection: Not typically required. If dusty conditions, wear NIOSH-approved respirator according to OSHA 29 CFR 1910.134. Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. Local exhaust ventilation is recommended with a capture velocity of 150 to 200 fpm. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other:

Wear rubber gloves and goggles.

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container.

Chapter 6 Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containersclosed. Store in a cool, dry place. Use with adequate ventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: Useallstandardpractices for goodpersonalhygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. As with any powder or dustlike material,improperhandlingcanlead to spontaneous combustion (dust explosions).

--REGULATORY INFORMATION -Contains no concentration.

Title 111 chemicalspresentat

or abovethe de minimus

--IDENTIFIERS --Chemical Name and Synonyms: (C.i&)Z(CH,)OH

2,6-DI-TERT-BU"p-CRESOL,

Trade Name and Synonyms: BHT (butylated hydroxy toluene) ChemicalFamily: AlkylatedCresol Manufacturer: Koppers Co., Inc., Pittsburgh, Pennsylvania

UN ID Number:

--INGREDIENTS AND COMPOSITION DATA --Cas Material % TLV BHT

10 mg/m3

C6Hz

Antioxidants, Stabilizers, and Fire Retardants

--

PHYSICAL DATA

--

BoilingPoint (“F): 510 SpecificGravity (H,O = 1): 1.01 VaporPressure(mm

Hg):

Percent Volatile by Weight VaporDensity(air FreezingPoint:

<1 (%): NA

= 1): 7.6

NA

EvaporationRate: NA p H NA Solubilityin Water: Negligible MeltingPoint (“C):NA Appearance/Color/Odor: White crystalline solid with typical alkylated cresol odor.

- FIRE AND EXPLOSION HAZARDS FlashPoint: 245OF (closedcup) FlammabilityLimits:

NA

AutoignitionTemperature: DecompositionTemperature:

NA NA

ExtinguishingMedia: Water,foam, dry chemical. Carbondioxide may be ineffective. SpecialFireFightingProcedures: Useself-contained breathing apparatus (SCBA). In enclosed or poorly ventilated areas, wear SCBA during cleanup immediately after a fire and during fire fighting.

Chapter 6

Unusual Fire and Explosion Hazards:Sealed (closed) containers can build up pressure if exposed to heat (fire). Water can be used to cool containers. Hazardous Productsof Combustion and Decomposition: Carbon monoxide, carbon dioxide, and oxides of nitrogen. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA -Effects of Overexposure: Dust or vapors may cause irritation to eyes, nose, and throat. Contactof dust or vaporswith skin may cause irritation. P r i m l y Routes of Exposure: Dermal, ingestion, and inhalation. Threshold Limit Value: None established. Emergency Response and First Aid: Skin: Washwith lots of clean water for atleast 15 min. For bums from molten BHT, treat as a thermal bum. Call a physician. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consult physician immediately. CancerInformation:

None reported.

--TOXICITY DATA --Animal Effects: No information reported by manufacturer.

--REACTIVITY DATA --Stability and Conditions to Avoid: Stable. Materials to Avoid(Incompatibility): Strong oxidizing agents such as hydrogen peroxide, permanganates, and perchlorates. Hazard Decomposition Products: No information reported by manufacturer. HazardousPolymerization: Willnot occur.

Antioxidants, Stabilizers, and Fire Retardants

399

--- SPILL AND EMERGENCY RESPONSE --For Spills: Remove sources of ignition. Avoid breathing dust or vapors. Avoid contact of eyes or skin with dust or vapors. Use protective measures outlined below. Solidified BHT may be picked up with a shovel and placed in container for disposal. Waste Disposal Method: Use either approved sanitary landfill or incineration. (Donot incinerate closed containers.) Disposalmustbe carried out in accordance with local, state, and federal regulations. Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemicallandfill in accordance with all applicable local, state, and federal laws and regulations.

--- SPECIAL PROTECTION AND PRECAUTIONS "RespiratoryProtection: Use full face unit perOSHA manufacturer's "Instructions" and "Warnings. "

regulations and

Type of Ventilation Required:Use adequate ventilation to keep inhalation and flammable concentrations to a minimum. EyeProtectionRequirements: Chemical goggles, face shields. Eyewash fountains and safety showers should be easily accessible. ProtectiveGlovesand Other: Wearrubber gloves and goggles. Coveralls and/or rubber apron. Rubber shoes or boots. Storage and Handling Precautions: Store in tightly closed, properly labeled containers in cool, well-ventilated area away from all ignition sources. Avoid prolonged and/or repeated contact with skin. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

08CwH,,

Chapter 6

400

OtherPrecautions: Do not take internally. NIOSH-approved respiratory units canbeusedifoxygenlevel is above 19.5%. Otherwise,use selfcontained units. -- REGULATORY INFORMATION

---

No information reported by manufacturer.

- IDENTIFIERS -BIS(O-ETHYL(3,5-DI-TERTBUTYL-4-HYDROXYBENZYL)PHOSPHONATE,NI PZO8CBHS

Chemical Name and Synonyms: NICKEL TradeNameand Synonyms: Irgastab ChemicalFamily: Light Stabilizer

Manufacturer: Ciba-Geigy Corp., Ardsley,NewYork

UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA -Cas No.

Material

%

Ni

established

--- PHYSICAL DATA -BoilingPoint ("F): NA SpecificGravity (HzO = 1): NA VaporPressure (mm Hg): NA Percent Volatile byWeight (%): NA VaporDensity(air = 1): NA FreezingPoint:

TLV -

NA

Antioxidants, Stabilizers, and Fire Retardants

EvaporationRate:

40 1

NA

p H NA Solubilityin Water: Negligible MeltingPoint (“C): NA Appearance/Color/Odor: Light

free-flowing powder.

--FIRE AND EXPLOSION HAZARDS -FlashPoint: NA FlammabilityLimits: NA AutoignitionTemperature: DecompositionTemperature:

NA NA

Extinguishing Media: Water, foam, drychemical.Carbondioxidemaybe ineffective. Special Fire Fighting Procedures:

None reported by manufacturer.

Unusual Fire and Explosion Hazards:

None reported by manufacturer.

Hazardous Products of Combustion and Decomposition: Carbon monoxide, carbon dioxide, and oxides of nitrogen. Hazardous Polymerization:

Will not

occur.

--HEALTH HAZARD DATA -Effects of Overexposure: None reported by manufacturer. Refer to toxicity section. Primary Routes Exposure: Dermal, ingestion, and inhalation. nreshold Limit Value: None established. Emergency Response and First Aid: Skin: Washwith lots of clean water for at least 15 min. For bums from molten BHT, treat as a thermal bum. Call a physician.

Chapter 6

402

Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

--- TOXICITY DATA --Animal Effects: Acute Oral LD50 (rats): mglkg Acute Oral LD50 (mice): 965 mglkg

--REACTIVITY DATA --Stability and Conditions to Avoid: Stable. Materials to Avoid (Incompatibility): No information reported. Hazard Decomposition Products: No information reported by manufacturer. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: Sweep up promptly. Wear an approved WasteDisposalMethod:

dust respirator.

Normalplant waste, bury or incinerate.

Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemical landfill in accordance with all applicable local, state, and federal laws and regulations.

--- SPECIAL PROTECTION AND PRECAUTIONS --RespiratoryProtection: Approved dust respirator. Type of Ventilation Required: Useadequate ventilation to keep inhalation concentrations to a minimum. EyeProtectionRequirements: Chemical goggles, face shields. Eyewash fountains and safety showers should be easily accessible.

Antioxidants, Stabilizers, and Fire Retardants

403

ProtectiveGlovesand Other: Wearrubberglovesand and/or rubber apron. Rubber shoes or boots.

goggles. Coveralls

Storage and Handling Precautions: Store in tightly closed, properly labeled containers in cool,well-ventilated area away from all ignition sources. Avoid prolonged and/or repeated contact with skin. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

Other Precautions: In accord with good industrial practice, avoid unnecessary personal contact. Employbonding,ground, venting, and explosion-relief provisions in accord with accepted engineering practices in process operations capable of generating dust and/or static electricity.

--- REGULATORY INFORMATION --No information reported by manufacturer.

--IDENTIFIERS --Chemical Name and Synonyms: BROMINATED ORGANIC COMPOUND Trade Name and Synonyms: Citex BN-451 ChemicalFamily: FlameRetardantAdditive Manufacturer: Cities Service Co.,Cranbury,New

UN ID Number: NA

Jersey

A

404

Chapter 6

- INGREDIENTS AND COMPOSITION DATA --Material

Cas No.

% -

organicBrominated

TLV established

--PHYSICAL DATA BoilingPoint (“F): NA SpecificGravity (H20= 1): 2.07 VaporPressure(mmHg):

NA

Percent Volatile byWeight

NA

VaporDensity (air = 1): NA FreezingPoint:

NA

EvaporationRate:

NA

pH: NA

Solubilityin Water: Negligible MeltingPoint (“C): NA Appearance/Color/Odor: White to off-white solid; odorless.

--FIRE AND EXPLOSION H A Z A R D S FlashPoint: NA FlammabilityLimits: NA AutoignitionTemperature: DecompositionTemperature:

NA NA

Extinguishing Media: Noinformation carbon dioxide.

reported. In absenceof

data, use

Antioxidants, Stabilizers, and Fire Retardants

405

Special Fire FightingProcedures: Hydrogen bromide or possibly other toxic gases may be givenoff at elevatedtemperatures;self-contained breathing equipment may be necessary. Unusual Fire and Explosion Hazards:

None reported by manufacturer.

Hazardous Productsof Combustion and Decomposition: Carbon monoxide, carbon dioxide, and oxides of nitrogen. HazardousPolymerization: Willnotoccur.

- HEALTH HAZARD DATA -Effects of Overexposure: None reported by manufacturer. Refer to toxicity section. Primary Routes of Exposure: Dermal, ingestion, and inhalation. l3reshoM Limit Value: None established. Emergency Response and First Aid: Skin: Washwith lots of cleanwater for atleast 15 min. For bums from molten BHT, treat as a thermal bum. Call a physician. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmandquiet.Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: Nonereported.

--TOXICITY DATA -AnimalEffeets: LD50

>

10,000 mg/kgbodyweight.

- REACTIVITY DATA Stability and Conditions to Avoid: Stable. Materials to Avoid (Incompatibility): No information reported. Hazard Decomposition Products:

Hydrogen bromide gas.

Hazardous Polymerization: Will not occur.

Chapter 6

406

--SPILL AND EMERGENCY RESPONSE --For Spills: Sweepuppromptly.Wearanapproveddust Waste Disposal Method:

respirator.

Normal plant waste, bury, or incinerate.

Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemicallandfill in accordance with allapplicable local, state, and federal laws and regulations.

--SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection: Approved dust respirator. Type of VentilationRequired: Use the guidelines recommendedby the American Conference of Governmental Industrial Hygienists in the current edition of "Industrial Ventilation," considering the TLV, lowerexplosive (Flammable) limit and conditions under which this product is used. EyeProtectionRequirements: Chemical goggles, face shields. Eyewash fountains and safety showers should be easily accessible. ProtectiveGlovesandOther: Wearrubberglovesand and/or rubber apron. Rubber shoes or boots.

goggles. Coveralls

Storage and Handling Precautions: Store in tightly closed, properly labeled containers in cool, well-ventilated area away from all ignition sources. Avoid prolonged and/or repeated contact with skin. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

OtherPrecautions: In accordance with good industrial practice, avoid unnecessary personal contact. Employ bonding, ground, venting, and explosion-relief provisions in accordance with accepted engineeringpractices in process operations capable of generating dust and/or static electricity.

Antioxidants, Stabilizers, and

Fire 407 Retardants

--REGULATORY INFORMATION -No information reported by manufacturer.

--- IDENTWIERS -Name: MIRJ3X Synonyms: Bichlorendo;CG-1283;Cyclopentadiene, Hexachloro-, Dimer; Decane,Perchloropentacyclo-; Dechlorane;Dechlorane 5 15; Dechlorane 4070; Dechlorane Plus; Dechlorane Plus5 15; Dodecachlorooctahydro-1,3,4Metheno-2H-Cyclobuta(C,D)Pentalene; Dodecachloropentacyclodecane;Dodecachloropentacyclo(3.2.2.O(Sup 2,6),O(Sup 3,9),O(Sup 5,lO))Decane; Ent 25, 719; Ferriamicide; GC 1283; Hexachlorocyclopentadiene Dimer; 1,2,3,4,5,5-Hexachloro-l,3-Cyclopentadiene Dimer; HRS L276; 1,3,4Metheno-lH-Cyclobuta(CD)Pentalene, Dodecachlorooctahydro-; Mirex; NCI-C06428;Perchlorodihomocubane; Perchloropentacyclodecane; Perchloropentacyclo(5.2.1.O(Sup 2,6).O(Sup 3,9).O(Sup 5,8))Decane CAS: 2385-85-5; RTECS: PC8225000 Formula: C,&; Mol Wt: 545.50 WLN: L545 B4 C5 D 4ABCE JTJ-/G 1 2 ChemicalClass: Halogenatedh-carbon See other identifiers listed below under Regulations.

- PROPERTIES -Physical Description: White crystals. Maybe dissolvedinpetroleum-based solvent. (NYDH) Boiling Point: 758.15 K dec; 485°C dec; 905°F dec Melting Point: 758.15 K dec; 485°C dec; 905°F dec FlashPoint: NA Autoignition: NA UEL: NA LEL: NA VaporDensity: No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data

I

Chapter 6

408

Neutralizing Agents:No data Polymerization Possibilities:No

data

Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: None(Source:NYDH) 100% Odor Detection: No data

--REGULATIONS DOT hazard class: Not given Packaging exceptions: 173. Nonbulkpackaging: 173. Bulk packaging: 173. STCC Number: Not listed Clean Water Act Sect. 307: No Clean Water Act Sect. 311: No Clean Air Act: Not listed EPA WasteNumber: None CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Chronic toxicity: carcinogen. Chronic toxicity: mutagen. Chronic toxicity: reproductive toxin.

U.S. Postal Service Mailability:

Not given

- TOXICITY DATA Short-termToxicity: Inhalation: Noinformationfound. Skin: Cancause irritation. Eyes: No informationfound. Ingestion: No cases ofhuman toxicity reported. Possible symptoms include nausea, vomiting, restlessness, tremor, weight loss, nervous system and liver abnormalities, skin rash, ind reproductive system disorders. Long-term Toxicity: Mirex has caused cataracts, cancer, and birth defects in both rats and mice. Whether it does so in humans is not known. (NYDH)

Antioxidants, Stabilizers, and Fire Retardants

409

Conc IDLH Unknown

NOSH REL: Not given. ACGM TLV: Not listed ACGIH STEL: Not listed

OSHA PEL: Not in Table Z-l-A MAKInformation:

Not listed

Carcinogen: Y;Status: Seebelow References: Animal positive IARC**20,283,79; Animal positive IARC** 5, 203, 74 CarcinogenLists: Z A R C CarcinogendefinedbyIARC to be possibly carcinogenic to humans, but having (usually) no human evidence; MAK: Not listed; NZOSH Not listed; NTP Carcinogen defined by NTP as reasonably anticipated to be carcinogenic, with limited evidence in humans or sufficient evidenceinexperimental animals; ACGZE Not listed; OSHA: Not listed. LDS0 Value: orl-rat LD50:235 mgkg OtherSpeciesToxicityData: orl-rat LD50:235 mg/kg skn-rat LD50: > 2 g/kg skn-rbt LD50:800 mg/kg orl-ham LD50: 125 mg/kg orl-dck LD50:2400 mg/kg ihl-brd LC50: 1400 ppm

(Source:NIOSHRTECS1992)

ReproductiveToxicity(1992RTECS): reproductive toxin.

Thischemical

Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo:50 mg/kg (5-9D preg) TJADAB 27, 401, 83 Maternal Effects Ovaries, fallopian tubes Uterus, cervix, vagina Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus)

is amammalian

410

Chapter 6

orl-rat TDLo:23750 mg/kg (4-22D preg) TOLED5 4, 263, 79 Effects on Newborn Stillbirth Weaning or lactation index (number alive at weaning per numberalive at day 4) orl-rat TDLo:60 mg/kg (6-15D preg) FCTXAV 14, 25, 76 Effects on Fertility Litter size (number of fetuses per litter; measured before birth) Specific Developmental Abnormalities Homeostasis Musculoskeletalsystem orl-rat TDLo:56 mg/kg (8-15D preg) TJADAB 22, 167, 80 Effects on Fertility Postimplantation mortality Specific DevelopmentalAbnormalities Cardiovascular (circulatory) system Other developmental abnormalities orl-rat TDLo:48 mg/kg (8-15D preg) TJADAB 21, 40A, 80 Specific Developmental Abnormalities Blood and lymphatic systems (including spleen and marrow) Homeostasis orl-rat TDLo:60 mg/kg (10D male) FCTXAV 14, 25, 76 Effects on Fertility Male fertility index orl-rat TDLo:18750 mg/kg (1-15D post) TOLED5 4, 263, 79 Specific Developmental Abnormalities Eye, ear orl-rat TDLo:lO mg/kg (1-8D post) TOLED5 4, 263, 79 Effects on Newborn Growth statistics (e.g., reduced weight gain) scu-rat TDLo: 10 mg/kg (2D pre) ENVRAL 16, 131, 78 Maternal Effects Uterus, cervix, vagina

Antioxidants, Stabilizers, and Fire Retardants

41 1

scu-rat TDLo:2 mgkg (1D pre) PSEBAA 148, 414, 75 Effects on Fertility Other measures of fertility unr-rat TDLo:8 mgkg (8-15D preg) TJADAB 26(3), 17A, 82 Specific Developmental Abnormalities Cardiovascular (circulatory) system Respiratory system Effects on Newborn Weaning or lactation index (number alive at weaningper number alive at day 4) unr-rat TDLo:48 mg/kg (8-15D preg) TJADAB 26(3), 17A, 82 Effects on Newborn Stillbirth Viability index (number alive at day 4 per number born alive) orl-mus TDLo:22 mgkg (1-21D preg) FEPRA7, 37, 938, 78 Effects on Newborn Growth statistics (e.g., reduced weight gain) Behavioral orl-mus TDLo:58 mg/kg (4W male/4W pre-2W post) TXAPA9 10, 54, 67 Effects on Fertility Other measures of fertility orl-mus TDLo:37500 mgkg (8-12D preg) JTEHD6 10, 541, 82 Effects on Newborn Live birth index (number of fetuses per litter) Viability index (number alive at day 4 per number born alive) Growth statistics (e.g., reduced weight gain) orl-mus TDLo:1775 mgkg (8-12D preg) TCMUD8 7, 7, 87 Effects on Newborn Live birth index (number of fetuses per liter) Viability index (number alive at day 4 per number born alive) unr-mam TDLo:7 mgkg (15-21D preg) TJADAB 25(2), 44A, 82 Specific Developmental Abnormalities Eye, ear Cardiovascular (circulatory) system Respiratory system

412

Chapter 6

--IDENTIFTERS Name: ANTIMONY OXIDE Synonyms: A 1530; A 1582; A 1588LP; Antimonious Oxide; Antimony(3+) Oxide;AntimonyPeroxide;AntimonySesquioxide;Antimony Trioxide; Antimony Trioxide (ACGIH,DOT);AntimonyWhite;Antox; AP 50; Chemetron Fire Shield; C.I. 77052; C.I. Pigment White 11; Dechlorane A-0; Diantimony Trioxide; Exitelite; Extrema; Flowers of Antimony; NA 9201 (DOT);NCPC55152; Nyacol A 1530;Senarmontite;Thermoguard B; Thermoguard S; Timonox; Valentinite; Weisspiessglanz (German) CAS: 1309-64-4; RTECS: CC565oooO Formula: O,Sb,; Mol Wt: 291.50 WLN: .SB2.03 ChemicalClass: Metal oxide See other identifiers listed below under Regulations.

--PROPERTIES -BoilingPoint: NA MeltingPoint: 928.16 K; 655°C;1211°F FlashPoint: NA Autoignition: NA UEL: NA LEL: NA VaporDensity: No data SpecificGravity:No data Density: 5.200 Reactivity withWater: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data NeutralizingAgents: No data PolymerizationPossibilities: No data Toxic Fire None reported other than possible unburned vapors Odor Detected at (ppm): Odorless OdorDescription: None(Source:CHRIS) 100% OdorDetection: No data

Antioxidants, Stabilizers, and Fire Retardants

413

- REGULATIONS DOT hazard class:

CLASS DOT guide: 31 Identificationnumber: UN3077 DOT shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. Packing group: 111 Label(s)required: CLASS SpecialProvisions: 8, B54 Packaging exceptions: 173.155 Nonbulkpackaging: 173.213 Bulkpackaging: 173.240 Quantity limitations: Passenger airhail: None Cargo aircraft only: None Vesselstowage:A STCC Number: Not listed Clean Water Act Sect. 307: Yes Clean Water Act 311: Yes Clean Air Act: CAA by category EPA Waste Number: None CERCLA Ref: >510 RQ Designation: C lo00 lb (454 kg) CERCLA SARA TPQ Value: Not listed SARA Sect. 312 Categories: Chronic toxicity: carcinogen. Chronic toxicity: mutagen. Chronic toxicity: reproductive toxin. Listed in SARA Sect. 313: Yes De Minimus Concentration: 1 U.S. Postal Service Mailability:

Not given

TOXICITY DATA Short-term Toxicity: Long-termToxicity:

Unknown Unknown

--

Chapter 6

414

Symptoms: Inhalation causesinflammationofupperandlower respiratory tract, including pneumonitis. Ingestion causes irritation of the mouth, nose, stomach and intestines; vomiting, purging with bloodystools; slow pulse and low blood pressure; slow, shallow breathing; comaand convulsions, sometimesfollowedby death. Contactwitheyes causes conjunctivitis. Contactwith skin causes dermatitis and rhinitis. (Source: CHRIS) Conc IDLH 80 mg/m3

NIOSH REL: Not given. ACGIH TLV: TLV = 0.5 mg/m3 handling and use as antimony. Production of: Suspecthuman carcinogen. ACGIH STEL Handling and use as antimony. Production Suspect human carcinogen.

OSHA PEL: Transitional Limits: PEL = 0.5 mg/m3; Final Rule Limits: TWA = 0.5 mg/m3. MAKInformation: CarcinogenicworkingmaterialwithoutMAK; Commission’s view, an animal carcinogen.

inthe

Carcinogen: Y;Status: Seebelow References: 3VOlJ6OL60 ihl-rat TCLo:4200 mg/m3/52W-I AIHAM* 20, 1, 80 3V03J6OL60 ihl-rat TC:4 mg/m3/lY-I PESTC* 8, 16, 80 3V02L60R60 ihl-rat TC:1600 mg/m3/52W-I AIHAM* 20, 1, 80 2VOlJ60 ihl-rat TC:50 mg/m3/7H/52W-I JTEHD6 18, 607, 86 CarcinogenLists: IARC: Not listed; M A K Ananimal carcinogen; NIOSH Not listed; h T P Not listed; ACGIH: Carcinogen defined by ACGIH TLV Committee as a suspectedcarcinogen, based on either limited epidemiological evidence or demonstration ofcarcinogenicity in experimentalanimals; OSHA: Not listed. LDS0 Value: orl-rat LD50: >20 g/kg OtherSpeciesToxicityData: orl-rat LD50: >20 g/kg ipr-rat LD50:3250 mg/kg ipr-mus LD50: 172 mg/kg ivn-dog LDLo:3 mg/kg

(Source:NIOSHRTECS1992)

Antioxidants, Stabilizers, and Fire Retardants

415

scu-rbt LDLo:2500 mgkg scu-mam LD :> 120 mg/kg

ReproductiveToxicity reproductive toxin.

(1992 RTECS):

Thischemicalismammalian a

Reproductive Toxicity Data (1992 RTECS): ihl-rat TCLo:270 mg/m3 (1-21D preg) GISAAA 52(10), 85, 87 Effects on Fertility Postimplantation mortality Effects Embryo or Fetus Fetal death ihl-rat TCLo:82 mg/m3 (1-21D preg) GISAAA 52(10), 85, 87 Effects on Fertility Preimplantation mortality Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus)

--

PROTECTION AND FIRST AID

--

FirstAidSource: CHRISManual1991. If any of the symptoms of poisoning, even slight, are noticed, the affected individual should be removed from contact with the chemical and placed under care of a physician. Ingestion: Inducevomiting. Skin: Wash well with soap and water. Eyes: Flush with water for at least 15 min. First Aid Source: DOTEmergencyResponseGuide1993. In case of contact with material, immediately flush eyes with running water for at least 15 min.Wash skin withsoapand water. Removeand isolate contaminated clothing and shoes at the site.

--INITIAL INCIDENT RESPONSE U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. DOT ID Number: UN3077

Chapter 6

416

ERG90

* POTENTIAL HAZARDS *

*Health Hazards Contact may cause bums to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Some of these materials may bum, but none of them ignites readily.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Positivepressure self-contained breathing apparatus (SCBA) and structural firefighters’ protective clothing will provide limited protection. CALL CHEMTREC AT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Smalljires: Dry chemical, CO,, water spray, or regular foam. Large fires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. Do not scatter spilled material with high-pressure water streams. Dike fire-control water for later disposal. *Spill or Leak Stop leak if you can do it without risk. Small dry spills: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. Cover powder spill with plastic sheet or tarp to minimize spreading.

*First Aid In case of contact with material, immediately flush eyes with running water for at least 15 min.Wash skin withsoapand water. Removeand isolate contaminated clothing and shoes at the site.

7 RETARDERS

--IDENTIFIERS -Name: iV-NITROSODIPHENYLAMINJ3 Synonyms: Benzenamine,N-Nitroso-N-Phenyl- (9CI); CuretardA;Delac J; Diphenylnitrosamin(German);Diphenylnitrosamine;DiphenylN-Nitrosoamine; N,N-Diphenylnitrosamine; Naugard TJB; NCI-C02880; NDPA; NDPhA; N-Nitrosodifenylamin (Czech); Nitrosodiphenylamine; NNitrosodiphenylamine; N-Nitroso-N-Phenylaniline;Nitrous Diphenylamide; Redax; Retarder J; TJB; Vulcalent A; Vulcatard; Vulcatard A; Vulkalent A (Czech); Vultrol CAS: 86-30-6; RTECS: JJ9800000 Formula: C,2H,0N20;MolWt: 198.24 WLN: ONNR ChemicalClass: Nitrocompound;aromaticamine See other identifiers listed below under Regulations.

--PROPERTIES -BoilingPoint: NA Melting Point: 418 K; 144.8"C;292.7"F FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density: No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data

417

Chapter 7

418

Neutralizing Agents: No data PolymerizationPossibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--- REGULATIONS --DOT hazard class: Not given Packaging exceptions: 173 Nonbulkpackaging: 173 Bulkpackaging: 173 STCC Number: Not listed Clean Water Act Sect. 307: Yes Clean Water Act 311: No Clean Air Act:Not listed EPA Waste Number: None CERCLARef: Y RQ Designation: B, 100 lb (45.4 kg) CERCLA SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: adverse effect to target organs. Listed in SARA Sect. 313: Yes De Minimus Concentration: 1

U.S. Postal Service Mailability: Not given

NFPA Codes: Health Hazard (blue):Unspecified Flammability(red): Unspecified Reactivity (yellow):Unspecified Special: Unspecified

--- TOXICITY DATA -Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

419

Retarders

TargetOrgans:

Eyes

Symptoms: Aneye irritant (Source: SAX) ConcIDLH.

Unknown

NOSH REL: Notgiven ACGIHTLV: Not listed ACGIHSTEL: Not listed OSHA PEL: Not in Table Z-l-A MAK Information: Not listed Carcinogen: N; Status: Seebelow References: Animal suspected IARC** 27,213, 82; Animal Positive IARC** 28, 151, 82; Human Indefinite IARC** 27, 213, 82 CarcinogenLists: Z A R C Not classified as to human carcinogenicity or probably not carcinogenic to humans; MAK: Not listed; NZOSH. Not listed; N T P Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: orl-rat LD50:2500 mgkg OtherSpeciesToxicityData: (Source:NIOSHRTECS1992) orl-rat LD50:2500 mg/kg unr-rat LD50:3000 mg/kg orl-mus LD50:3850 mg/kg ipr-mus LD50: 1000 mg/kg IrritationData: (Source:NIOSHRTECS1992) eye-rbt 500 mg/24H SEV Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

This chemical has no known

No Significant Risk Level (Ca P65): N80 mg/day

Chapter 7

420

--IDENTIFIERS -Name: SALICYCLIC ACID Synonyms: 0-Hydroxybenzoic Acid;Retarder W CAS: 69-72-7; RTECS:V00525000 Formula: C,H,O,; Mol Wt: 138.13 WLN:QVR BQ Chemical Class: Organic acid See other identifiers listed below under Regulations.

--PROPERTIES Physical Description: Whiteneedlelike crystals or powder. (NYDH) Boiling Point: 484.16 K at 20 mm; 21 1°C at 20 mm; 411.8"F at 20 mm Melting Point: 430 K; 156.8"C; 314.3"F FlashPoint: Autoignition: NA UEL: NA LEL: NA Vapor Density:Nodata Specific Gravity: 1.44 at 20°C Density: 1.44 g/ccor 13.392 lb/gal Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: Stable Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: Irritating vapors unburned material and phenol may in fire. Odor Detected at (ppm): Data not available. Odor Description: None (Source: CHRIS) 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: Not given Packaging exceptions: 173 Nonbulk packaging: 173 Bulk packaging: 173

42 1

Retarders

STCCNumber: Not listed Clean WaterAct Sect. No CleanWaterActSect. 311: No Clean Air Act: Not listed EPAWasteNumber: None CERCLARef: Not listed RQDesignation: Not listed SARATPQValue: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant. Chronic toxicity: mutagen. Chronic toxicity: reproductive toxin.

U.S. Postal Service Mailability: Not given NFPA Codes: Health Hazard (blue): No unusual health hazard. Flammability (red): (1) This material must be preheated before ignition can occur. Reactivity (yellow): Stable even under fire conditions. Special: Unspecified.

--TOXICITY DATA -Short-term Toxicity: Inhalation: Maycause ringing in the ears, confusion, rapid pulse and breathing, headache, dizziness, nausea and vomiting. Eyes: Maycause severe irritation. Skin: May be very irritating andcause skin sores. Ingestion: Tengrams may causeheadache, dizziness, nausea, and vomiting. Death may occur from ingestion ofabout 1 ounce. (NYDH) Long-termToxicity: Repeated large doses may cause, in addition to the symptoms listed above,abdominal pain, loss of appetite, heartburn, poor digestion, stomach ulcers, bleeding of the stomach, irondeficiency anemia, acnelike skin sores, restlessness, incoherent speech, tremor, kidney damage, coma, convulsions, and death. (NYDH)

I

TargetOrgans: Skin, eyes. Symptoms: Inhalation of dust imtates nose and throat. Vomiting may occur spontaneously if large amounts are swallowed.Contactwitheyes causes irritation, marked pain, and corneal injury, which should heal. Prolonged or

422

Chapter 7

repeated skin contact may causemarked (Source: CHRIS)

irritation or even a mild bum.

ConcIDLH: Unknown NOSH REL: Not given ACGJHTLV: Not listed ACGIHSTEL: Not listed OSHA PEL: Not in Table Z-l-A

MAK Information: Notlisted Carcinogen: N; Status: Seebelow Carcinogen Lists: Z A R C Not listed; M A K Not listed; NZOSH: Not listed; N T P Not listed; ACGZH Not listed; OSHA: Not listed. HumanToxicityData: (Source:NIOSHRTECS) skn-man TDLo:57 mg/kg JAMAAP 244, 660, 80 Sense Organs Ear Tinnitus LDS0Value: orl-rat LD50:891mg/kg OtherSpeciesToxicityData: orl-rat LD50:891 mg/kg scu-rat LD50: 1250 mg/kg orl-mus LD50:480 mg/kg ipr-mus LD50:300 mg/kg scu-mus LD60:520 mg/kg ivn-mus LD50: 184 mg/kg orl-cat LD50:400 mg/kg orl-rbt LD50:1300 mg/kg scu-rbt LDLo:6 g/kg ReproductiveToxicity reproductive toxin.

(Source:NIOSHRTECS1992)

(1992 RTECS):

Thischemicalismammalian a

Retarders

Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo:40 mg/kg (20-21D preg) PRGLBA 4, 93, 73 Maternal Effects Parturition orl-rat TDLo:1050 mgkg (8-14D preg) SEIJBO 13, 73, 73 Maternal Effects Uterus, cervix, vagina Effects Fertility Postimplantation mortality Litter size (number of fetuses per litter; measured before birth) orl-rat TDLo:1050 mg/kg (8-14D preg) SEIJBO 13, 73, 73 Specific DevelopmentalAbnormalities Central nervous system Craniofacial (including nose and tongue) Musculoskeletalsystem orl-rat TDLo:700 mg/kg (8-14D preg) SKEZAP 14, 549, 73 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Specific Developmental Abnormalities Musculoskeletalsystem orl-rat TDLo:350 mg/kg (8-14D preg) SKEZAP 14, 549, 73 Effects on Embryo or Fetus Extra embryonic features (e.g., placenta, umbilical cord) scu-rat TDLo:380 mgkg (9D preg) BCPCA6 22, 407, 73 Effects on Fertility Postimplantation mortality Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Specific DevelopmentalAbnormalities Other developmental abnormalities orl-mus TDLo:l g/kg (17D preg) APTOA6 35, 107, 74 Effects Fertility Postimplantation mortality Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus)

423

424

Chapter 7

--PROTECTION AND FYRST AID Protection Suggested from the CHRIS Manual: Gloves; goggles; respirator for dust; clean body-covering clothing. FirstAidSource: CHRISManual,1991 Inhalation: Move to fresh air. Ingestion: Induce vomiting and get medical attention promptly. Skin: Wash with soap and water. Eyes: Promptly flush with water for 15 min and get medical attention.

--

INITIAL INCIDENT RESPONSE

--

FireExtinguishment: Water,foam,dry chemical, carbon dioxide. Note: Water or foam may cause frothing. (CHRIS 91) No DOT Guide information for this product.

--IDENTIFIERS -Name:PHTHALICANHYDRIDE Synonyms: Anhydride Phtalique (French); Anidride Ftalica (Italian); 1,2BenzenedicarboxylicAcidAnhydride;1,3-Dioxophthalan;Esen;Ftalowy Bezwodnik(Po1ish);Ftaalzuuranhydride (Dutch); Isobenzofuran,1,3-Dihydro1,3-Dioxo-; 1,3-Isobenzofurandione; NCI-C03601; Phthalandione; 1,3Phthalandione; Phthalic AcidAnhydride;Phthalsaeureanhydrid(German); Retarder AK; Retarder Esen; Retarder PD; PAN CAS: 85-44-9; RTECS: TI3150000 Formula: C,H,03; MolWt: 148.12 WLN: T56 BVOVJ ChemicalClass: Organicanhydride See other identifiers listed below under Regulations.

--PROPERTIES -Physical Description: Colorless or pale yellow solid flakes or liquid (heated) with a choking odor Boiling Point: 545.93K;272.7"C;523°F MeltingPoint: 404.26 K; 131.1"C;267.9"F

425

Retarders Flash Point: 424 K; 150.8"C;303.5"F Autoignition: 843 K; 569.8"C;1057.7"F Vapor Pressure: mm UEL: 10.4% LEL: 1.7% Vapor Density: No data SpecificGravity:1.20;1.53 at135°C;20°C Water Solubility: 0.62% Incompatibilities: Strong oxidizers ReactivitywithWater: Solid has veryslow reaction; spatters when in contact with water. Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: Water and sodium bicarbonate Polymerization Possibilities: No data

hazard. Liquid

Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): 0.32 to 0.72 Odor Description: Characteristic choking odor; choking, acrid. (Source: CHRIS) 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: 8 CORROSIVE DOT guide: 60 Identificationnumber: UN2214 DOTshippingname: Phthalic anhydride (with more than anhydride) Packing group: 111 Label(s)required: CORROSIVE Special Provisions: 'K', T38 Packaging exceptions: 173.154 Nonbulk packaging: 173.213 Bulkpackaging: 173.240 Quantity limitations: Passenger airhail:25 kg Cargo aircraft only: 100 kg Vesselstowage: A

maleic

Chapter 7

426

STCCNumber: Not listed CleanWaterAct 307: No CleanWaterActSect.311: No CleanAirAct: CAA listed EPA WasteNumber: U190 CERCLARef: Y RQ Designation: D lb (2270 kg)CERCLA SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: corrosive. Acute toxicity: irritant. Chronic toxicity: adverse effect to target organ after long period of exposure. Chronic toxicity: reproductive toxin. Listed in SARA Sect 313: Yes De Minimus Concentration: 1 .O%

U.S. Postal Service Mailability: Not given NFPA Codes: Health Hazard (blue): (2)Hazardous to health. Area may be entered with self-contained breathing apparatus. Flammability (red): (1) This material must be preheated before ignition can occur. Reactivity (yellow): Stable even under fire conditions. Special: Unspecified.

--TOXICITY DATA --Short-termToxicity: Inhalation: Maycause irritation of nose, throat, and mouthwith sneezing, and excessive discharge andbleedingfrom nose. Studies suggest that this will occur at about 4 ppm. Eyes: May cause severe irritation and chemical bums on contact or at dust levels above 5 ppm. Skin: Rapid chemical bums may occur on contact with wet skin. Molten material may cause severe bums. Ingestion: May cause severe irritation to mouth and throat. Animal studies suggest that death may occur from ingestion of 4 to 8 (NYDH) Long-term Toxicity: May cause irritation nose, mouth, throat, and lungs. Allergy may develop in sensitive individuals, which can lead to bronchial asthma. (NYDH)

Retarders

427

Target Organs: Skin, eye, upper respiratory tract, mucous membrane, liver, kidneys. Symptoms: Solid irritates skin and eyes, causingcoughingand Liquid causes severe thermal burns. (Source:CHRIS)

sneezing.

Conc IDLH 10,000ppm ACGM TLV: TLV = 1 ppm (6 mg/m3) ACGIH STEL: Not listed OSHA PEL: Transitional Limits: PEL = 2ppm (12 mg/m3); Final Rule Limits: TWA = 1ppm (6 mg/m3)

MAK Information: 5 calculated as total dust mg/m3 Local irritant: Peak = 2xMAK for 5 min, 8 times per shift. Causes allergic reactions Carcinogen: N; Status: Seebelow CarcinogenLists: IARC: Not listed; M A K Not listed; NIOSH Not listed; MP Not listed; ACGIH: Not listed; OSHA: Not listed. LD50 Value: orl-rat LD50:4020 mg/kg Other SpeciesToxicityData:

l

(Source:NIOSHRTECS1992)

orl-rat LD50:4020 mg/kg unr-rat LD50: 1100 mg/kg orl-mus LD50: 1500 mg/kg orl-cat LD50:800 mg/kg ipr-gpg LD50: 100 mg/kg

IrritationData: (Source:NIOSHRTECS1992) skn-rbt 500 mg/24H eye-rbt 100 mg ReproductiveToxicity reproductive toxin.

(1992 RTECS):

Thischemical

is amammalian

-

Chapter 7

428

Reproductive Toxicity Data (1992 RTECS): ihl-rat TCLo:l mg/m3 (45Dmale) GISAAA 35(1), 105, 70 Paternal Effects Spermatogenesis Testes, epididymis, sperm duct

--PROTECTION AND FIRST AID -NIOSH Pocket Guide to Chemical Hazards: **Wear Appropriate Equipment to Prevent: Repeated or prolonged skin contact. **Wear Eye Protectionto Prevent: Reasonable probability of eye contact. **Exposed Personnel Should Wash: contaminated.

Promptly when

skin becomes

**WorkClothingShouldBeChangedDaily: If there is any reasonable possibility that the clothing may be contaminated. **Remove Clothing:Promptly remove nonimperviousclothing that becomes contaminated. **Reference: NIOSH Recommended Respiration Protection Source:NIOSH Pocket Guide (85-114) ACGIH (Phthalic Anhydride) Sppm: Any dust and mist respirator except single-use respirators. Substance reported to cause eye irritation or damage; may require eye protection. 10 ppm: Any dust and mist respirator except single-use and quarter-mask respirators. Any supplied-air respirator. Any self-contained breathing apparatus. Substance reported to cause eye irritation or damage may require eye protection. 25 ppm: Any supplied-air respirator operated in a continuous-flow mode. Any powered air-purifying respirator with a dust and mist filter. Substance reported to cause eye irritation damage may require eye protection. 50ppm: Any supplied-air respirator with a full facepiece. Any self-contained breathingapparatuswith a full facepiece. Any air-purifying full facepiece respirator with a high-efficiency particulate filter. 2000ppm: Any supplied-air respirator with a full facepiece and operated in a pressuredemand or other positive-pressure mode.

Retarders

429

Emergency or Planned Entry inUnknown Concentrations or IDLH Conditions: Any self-contained breathing apparatus with a full facepiece and operated in pressure-demand a or other positive-pressure mode. Any supplied-air respirator with a full facepiece and operated in a pressuredemand or other positive-pressure modeincombinationwithan auxiliary self-contained breathing apparatus operated in apressuredemand or other positive-pressure mode. Escape: Any air-purifying full facepiece respirator withahigh-efficiency particulate filter. Any appropriate escape-type self-contained breathing apparatus. FirstAidSource: None given.

NIOSH

FirstAidSource: CHRISManual1991. Inhalation: Gargle with water and use a sedative cough mixture. Ingestion: Induce vomiting and give water, milk, or vegetable oil. Skin or Eye Contact: Flushwithwater for at least 15min;if burnedby molten material, remove as much solid as possible, soak off the remainder in cold water, and then treat the bum. First Aid Source: DOT Emergency Response Guide 1993. Move victim to fresh air; call emergency medical care. In case contact with material, immediately flush skin or eyes with running water for at least 15min.Removeand isolate contaminated clothing andshoes at the site. Keep victim quiet and maintain normal body temperature.

--- INITIAL INCIDENT RESPONSE -FireExtinguishment: Water, fog, dry chemical, carbon dioxide, or foam. Note: Water may cause frothing. (CHRIS91) U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT ShippingName: Phthalic anhydride (with morethan maleic anhydride) DOT ID Number: UN2214

Chapter 7

430

ERG90

* POTENTIAL HAZARDS *

GUIDE 60

*Health Hazards Contact causes bums to skin and eyes. If inhaled, may be harmful. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Some of these materials may bum, but none of them ignites readily. Flammable/poisonous gases may accumulate in.tanks and hopper cars. Some of these materials may ignite combustibles (wood, paper, oil, etc.).

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection. CALLCHEMTREC AT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Some of these materials may react violently with water. Smallfires: Dry chemical, COz, water spray, or regular foam. Large fires: Water spray, fog, or regular foam. Move container from fire area if you’can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. *Spill or Leak Do nottouch spilled material; stop leak ifyoucan do it without risk. Small spills: Take up with sand, or other noncombustible absorbent material and place into containers for later disposal. Small dry spills: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. Large spills: Dike far ahead of liquid spill for later disposal.

Retarders

43 1

*First Aid Move victim to fresh air; call emergency medical care. In case of contact with material, immediately flush skin or eyes with running water for at least 15 min. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain body temperature.

This Page Intentionally Left Blank

8 BLOWING AGENTS

--IDENTIFIERS -Name:FORMAMIDE, l,l'-AZOBISSynonyms: 1,l "Azobiscarbamide;Azobiscarbonamide;Azobiscarboxamide; 1,l '-Azobis(Formamide);Azodicarbamide;Azodicarboamide;Azodicarbonamide; Azodicarboxamide; Azodicarboxylic Acid Diamide; delta(1,l"Biurea; Celosen AZ; ChKhZ 21; ChKhZ 21R; Diazenedicarboxamide; Genitron AC; Genitron AC 2; Genitron AC 4; Kempore; Kempore 125; Kempore R 125; Lucel ADA; NCI-C55981; Nitropore; Pinhole AK 2; Porofor 505; Porofor ADC/R; Porofor ChKhZ 21; Porofor ChKhZ 21R; Unifoam AZ; Uniform AZ; Yunihomu AZ CAS: 123-77-3; RTECS: LQ1040000 Formula: C2H,N402; MolWt: 116.10 WLN: ZVNUNVZ ChemicalClass: Amide See other identifiers listed below under Regulations.

--PROPERTIES -BoilingPoint: NA MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA VaporDensity: No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data 433

Chapter 8 Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

- REGULATIONS -DOT hazard class: Notgiven Packaging exceptions: Nonbulk packaging: Bulkpackaging: STCC Number: Notlisted Clean Water ActSect. 307: No Clean Water Act Sect. 311: No Clean Air Act: Not listed EPA Waste Number: None CERCLA Ref: Notlisted RQ Designation: Notlisted SARA TPQ Value: Not listed SARA Sect. 312 Categories: Chronictoxicity:mutagen. U.S. Postal Service Mailability:

Not given

--TOXICITY DATA -Short-term Toxicity: Unknown Long-term Toxicity: Unknown Conc IDLH: Unknown

NOSH REL: Not given ACGIH TLV: Notlisted ACGIH STEL. Not listed

435

Blowing Agents

OSHA PEL: Not in Table Z-l-A MAK Information: Not listed Carcinogen: N; Status: See below Carcinogen Lists: ZARC. Not listed; MAK Not listed; NZOSH Not listed; NTP: Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: No LD50 in RTECS 1992

Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

This chemical has no known

--N IT I A ILINCIDENT RESPONSE --No DOT Guide information for this product.

--

IDENTIFLERS --

Name: DINITROSOPENTAMETHYLENETETRAMINE Synonyms: Aceto DNPT Aceto DNPT 80; Aceto DNPT 100; CHKHZ 18; Dinitrosopentamethylenetetramine; N,N-Dinitrosopentamethylenetetramine; N(supl),N(sup 3)-Dinitrosopentamethylenetetramine;N,N”Dinitrosopentamethylenetetramine; 3,4-Di-N-Nitrosopentamethylenetetramine; 3,7-Di-N-Nitrosopentamethylenetetramine; 3,7-Dinitroso-l,3,5,7-Tetraazabicycl0-(3,3,1)Nonane; DNPMT; DNPT; 1,5-Endomethylene-3,7-Dinitroso-l,3,5,7Tetraazacyclooctane; 1,5-Methylene-3,7-Dinitroso-l,3,5,7-Tetraazacyclooctane; Micropor; Mikrofor N; NSC 73599; Opex; Pentamethylenetetramine, Dinitroso-; Porofor CHKHC-18; Porophor B; Unicel-ND; UnicelNDX; Vulcacel B-40; Vulcacel BN CAS: 101-25-7; RTECS: XA5250000 Formula: C,H,,N,O,; Mol Wt: 186.21 WLN: T66 A BNDN FN HNTJ DNO HNO ChemicalClass: Nitro compound;Aliphaticamine See other identifiers listed below under Regulations.

436

Chapter 8

--PROPERTIES -BoilingPoint: NA MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density: No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents:No data Polymerization Possibilities:No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

- REGULATIONS -DOT hazard class: 4.1 FLAMMABLE SOLID DOT guide: 71 Identificationnumber: UN2972 DOT shipping name: N,N’-Dinitrosopentamethylenetetramine (not more than 82%! with phlegmatizer) Packinggroup: I1 Label@) required: FLAMMABLE SOLID, EXPLOSIVE SpecialProvisions: 41, 53 Packaging exceptions: 173.None Nonbulkpackaging: 173.224 Bulkpackaging: 173.None Quantity limitations: Passenger airhail: Forbidden Cargo aircraft only: Forbidden Vesselstowage: D Other stowage provisions: 12, 61 STCC Number: Not listed

437

Blowing Agents

Clean Water Act Sect. 307: No CleanWaterAct 311: No CleanAirAct: Not listed EPAWasteNumber: None CERCLARef: Not listed RQDesignation: Not listed SARATPQValue: Not listed SARA Sect. 312 Categories: Chronic toxicity: mutagen.

U.S. Postal Service Mailability:

Not given

--TOXICITY DATA -Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

ConcIDLH:

Unknown

NOSH REL: Not given

ACGIH TLV: Not listed ACGIHSTEL: Not listed OSHA PEL: Notin Table Z-l-A MAKInformation: Not listed Carcinogen: N; Status: See below CarcinogenLists: Z A R C Notclassified as to human carcinogenicity or probably not carcinogenic to humans; MAK Not listed; NZOSH Not listed; NTP Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: orl-rat LD50:940 mgkg Other Species ToxicityData: (Source:NIOSH RTECS 1992) orl-rat LD50:940 mgkg ipr-rat LD50:220 mgkg scu-rat LD50:220 mgkg ipr-mus LD50: mg/kg

Chapter 8

438 scu-mus LD50: 140 mgkg ivn-mus LD50: 120 mg/kg ivn-rbt LD50: 130 mg/kg Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

This chemical has

known

--- PROTECTION AND FIRST AID --First Aid Source: DOT Emergency Response Guide 1993. Move victim to fresh air. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

--- INITIAL INCIDENT RESPONSE -U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT (1990). DOT Shipping Name: N,N’-Dinitrosopentamethylenetetramine(not more than with phlegmatizer) DOT ID Number: UN2972 ERG90

* POTENTIAL HAZARDS *

*Health Hazards Contact may cause burns to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion May be ignited by heat, sparks, or flames. May bum rapidly. Container may explode violently in heat of fire. May explode from friction, heat, or contamination.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas.

71

Blowing

439

Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection. CALLCHEM33WC AT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire small fires: Dry chemical, COz, water spray, or regular foam. Large fires: Flood fire area with water. Fight fire from maximum distance. Stay away from ends Of tanks. If fire can be controlled, cool container with water from U ~ a n n e dhose holder or monitor nozzles until Well after fire is Out. If this is impossible, withdraw from fire area and let fire bum. *Spill or Leak Shut off ignition sources; no flares, smoking, or flames in hazard area. Do not touch or walk through spilled material. Spills: Moisten material with water and place it into loosely covered plastic or fiberboard containers for later disposal. *First Aid Move victim to fresh air. case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature.

--IDENTIFIERS -Name:BENZENESULFONICACID, 4,4’-0XYBIS-, DIHYDRAZIDE Synonyms: BenzenesulfonicAcid,Oxybis-,Dihydrazide (9CI); Cellmic S; Celogen OT; CenitronOB;NitroporeOBSH;OBSH;p,p’-Oxybisbenzene Disulfonylhydrazide; Oxybis(Benzenesulfony1hydrazide); p . p ’-Oxybis(Benzenesulfonyl Hydrazide) CAS: 80-5 1-3; RTECS: DB7321000 Formula: C,2H,4N405S2; Mol Wt: 358.42 WLN: ZMSWRDORDSWMZ ChemicalClass: Organicacid salt See other identifiers listed below under Regulations.

Chapter 8

440

--PROPERTIES BoilingPoint: NA Melting Point: 3.16 to 434.16 K dec; 160 to 161°C dec; 320 to 321.8"F FlashPoint: NA Autoignition: NA UEL: LEL: NA Vapor Density: Nodata Specific Gravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: Nodata Stability during Transport: Nodata Neutralizing Agents: No data Polymerization Possibilities: Nodata Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: Nodata

--REGULATIONS -DOT hazard class: Notgiven Packaging exceptions: 173 Nonbulk packaging: 173 Bulkpackaging: 173 STCC Number:

Not listed

Clean Water ActSect. 307: No Clean Water ,Act Sect. 311: No Clean Air Act:Notlisted EPA Waste Number: None CERCLA Ref: Notlisted RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Chronic toxicity:mutagen.

dec

44 1

Blowing Agents U.S. Postal Service Mailability: Not given

--TOXICITY DATA -Short-termToxicity:

Unknown

Long-termToxicity:

Unknown

Conc IDLH Unknown

NIOSH REL: Not given ACGIHTLV: Not listed ACGIH STEL Not listed OSHAPEL: Not in Table Z-l-A MAKInformation: Notlisted Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; M A K Not listed; NZOSH Not listed; NTP: Not listed; ACGZE Not listed; OSHA: Not listed. LD50 Value: No LD50 in RTECS 1992 Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

This chemical has no known

--INITIAL INCIDENT RESPONSE --No DOT Guide information for this product. v

v

v

v

v

v

v

v

v

v

v

v

--IDENTIFIERS -Chemical Name and Synonyms: p-TOLUENE SULFONYL SEMICARBAZIDE Trade Name and Synonyms:

Celogen RA

v

Chapter 8

442

Chemical Family: Blowing Agent for Rubbers and Other Polymers Manufacturer: UniroyalChemical Co., Naugatuck,Connecticut

UN ID Number: NA

--

INGREDIENTS AND COMPOSITION DATA

Material

No. Cas

p-Toluene sulfonyl Not

%

NA

--TLV established

--PHYSICAL DATA -BoilingPoint (“F): NA Specific Gravity (H,O = 1): 1.44 at 25°C VaporPressure (mmHg):

NA

Percent Volatile by Weight (%): Relatively nonvolatile below decomposition temperature VaporDensity(air = 1): NA FreezingPoint:

NA

EvaporationRate:

NA

p H Noncorrosive Solubility: Relatively insoluble in organic solvents and water. Soluble in aqueous bases. Melting Point (“C): Decomposes at about 225. Appearance/Color/Odor: Whitepowder

--- FIRE AND EXPLOSION HAZARDS -FlashPoint: NA

Blowing

FlammabilityLimits:

NA

Autoignition Temperature: Decomposes at about 430°F withoutignition when diluted or in small amounts. Large amounts may ignite at this temperature due to heat buildup from decomposition. DecompositionTemperature:

430°F

Extinguishing Media: Water in copious amounts. SpecialFireFightingProcedures:

Use self-contained breathing apparatus.

UnusualFireandExplosionHazards: Fires involving large amountsof material should not be approached becauseindividual containers may rupture abruptly causing a fireball effect. In case of fire in nearby materials, containers with water. Fires involving Celogen RA should be fought only with fixed automatic protection equipment. DO NOT AiTEMPT MANUAL FIRE FIGHTING. Hazardous Products of Combustion and Decomposition: Carbon monoxide, carbon dioxide, and oxides of nitrogen. HazardousPolymerization: Willnot occur.

- HEALTH HAZARD DATA --Effects of Overexposure: None reported by manufacturer. Primry Routes of Exposure: Dermal, ingestion, and inhalation. Threshold Limit Value: None established. Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keepwarmand quiet. Give artificial respiration if necessary, Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

Chapter 8

444

--TOXICITY DATA -Animal Effects: Oral, LD50 (ruts): Over 10 gkg. Skin, LD50 (rabbits): No evidence of systemic toxicity or irritation effects. Manufacturer notes that there are no health problems associated with normal handling and use.

--REACTIVITY DATA --Stability and Conditions to Avoid: Stable. Materials to Avoid (Incompatibility): Oxidizing agents; e.g., peroxides will reduce decomposition temperature. Hazard Decomposition Products: Gaseous decomposition products nitrogen, carbon dioxide, and carbon monoxide.

are

HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE -For Spills: Sweep up promptly. Wear an approved Waste Disposal Method:

dust respirator.

Bum cautiously in a remote, open area.

Empty Containers: Store in cool, dry place in closed containers. Keep away from heat, sparks, and open flames. Separate from combustible storage by 8 ft aisles or isolate in a detachedbuilding. Do not store over 4 ft high unless sprinklers are hydraulically designed to produce a density of 0.5 GP" over the entire area of the building.

--SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection: Approved dust respirator. Type of VentilationRequired: Use the guidelines recommendedby the American Conference of Governmental Industrial Hygienists in the current edition of "Industrial Ventilation," considering the TLV, lowerexplosive (Flammable) limit, and conditions under which this product is used.

Blowing

445

EyeProtection Requirements: Chemical goggles, face shields. Eyewash fountains and safety showers should be easily accessible. Protective Gloves andOther: Wearrubberglovesand and/or rubber apron. Rubber shoes or boots.

goggles. Coveralls

Storage and Handling Precautions: Store in tightly closed, properly labeled containers in cool, well-ventilated area away from allignition sources. Avoid prolonged and/or repeated contact with skin. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

Other Precautions: In accord with goodindustrial practice, avoid unnecessary personal contact. Employbonding,ground, venting, and explosion-relief provisions in accord with accepted engineeringpractices in process operations capable of generating dust and/or static electricity. Avoid excessive heat and pressure buildup during any mixing or processing operations.

--REGULATORY INFORMATION No information reported by manufacturer.

This Page Intentionally Left Blank

9 OILS,PLASTICIZERS,LUBRICANTS, SOLVENTS, AND MOLD RELEASE AGENTS

--JDENTIF’IERS --Chemical Name andSynonyms: THERMOPLASTIC PHENOLICRESINS Trade Name and Synonyms: Durez 12686 Chemical Family: PhenolicResins Manufacturer: New York

HookerChemicals

& Plastics

North Tonawanda,

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --Material

%

No. Cas

Phenolic resins

established

NA

--PHYSICAL DATA -Boiling Point (“F): NA SpecificGravity (H,O = 1): 1.05 Vapor Pressure (mm Hg): NA Percent Volatile by Weight (%): NA Vapor Density (air = 1): NA

447

TLV Not

448

FreezingPoint:

Chapter 9 NA

EvaporationRate: NA pH: NA Solubilityin Water: Negligible MeltingPoint(“C):

NA

Appearance/Color/Odor: Available inflake or crushed form; phenolicin odor.

--FIRE AND EXPLOSION HAZARDS -FlashPoint: NA FlammabilityLimits: NA AutoignitionTemperature: DecompositionTemperature:

NA NA

Extinguishing Media: Water fog, carbon dioxide, dry chemical. SpecialFireFightingProcedures: UnusualFireandExplosionHazards:

Useself-contained breathing apparatus. Ignition temperature of

cloud

> Hazardous Products of Combustion and Decomposition: Carbon monoxide, carbon dioxide, and oxides of nitrogen. HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA -Effects of Overexposure: None reported by manufacturer. Primary routes of exposure: Dermal, ingestion, and inhalation. Threshold Limit Value: None established.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

449

Emergency Response and First Aid: Skin: Wash with lots of clean water for at least 15 min. Call a physician. Eyes: Flush eyes withlots of water. If irritation persists, consult a physician. Inhalation: Expose to fresh air. Keep warmand quiet. Give artificial respiration if necessary. Ingestion: Nonerecommended.Consultphysicianimmediately. CancerInformation: None reported.

--TOXICITY DATA -Animal Effects: No data reported.

--REACTIVITY DATA -Stability and Conditions to Avoid: Stable. Materials to Avoid (Incompatibility): No information reported. Hazard Decomposition Products:

No information reported.

Hazardous Polymerization: Will not occur.

--

SPILL AND EMERGENCY RESPONSE

For Spills: Sweep up promptly. Wear an approved Waste Disposal Method:

---

dust respirator.

Normal plant waste, bury, or incinerate.

Empty Containers: Bum containers in an approved incinerator or dispose of in an approved chemical landfill in accordance with allapplicable local, state, and federal laws and regulations.

--SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection: Approved dust respirator. TypeofVentilationRequired: Use the guidelines recommendedby the American Conference Governmental Industrial Hygienists in the current edition of "Industrial Ventilation," considering the TLV, lowerexplosive (flammable) limit, and conditions under which this product is used.

Chapter 9

450

Eye Protection Requirements: Chemical goggles, face shields. Eyewash fountains and safety showers should be easily accessible. ProtectiveGlovesand Other: Wearrubberglovesand and/or rubber apron. Rubber shoes or boots.

goggles. Coveralls

Storage and Handling Precautions: Store in tightly closed, properly labeled containers in cool, well-ventilated area away from allignition sources. Avoid prolonged and/or repeated contact with skin. Prevent inhalation of dust. Prevent contact with eyes and skin. Under dusty conditions, static electricity may cause an explosion. Keep containers closed. Store in a cool, dry place. Use with adequateventilation. Wash thoroughly after handling before eating and smoking. Work clothing should be frequently laundered and not worn away from work premises.

Other Precautions: In accordance with good industrial practice, avoid unnecessary personal contact. Employ bonding, ground, venting, and explosion-relief provisions in accordance with accepted engineeringpractices in process operations capable of generating dust and/or static electricity.

--REGULATORY INI?ORMATION --No information reported by manufacturer.

Chemical Name and Synonyms:

SYNTHETIC WAX ADDITIVE

Trade Name and Synonyms: Castorwax ChemicalFamily:

NA

Manufacturer: NL Industries, Hightstown,New Jersey

UN ID Number: NA

Oils, Plasticizers, Lubricants, Solvents, and MoldReleaseAgents

45 1

--- INGREDIENTS AND COMPOSITION DATA --Cas No.

Material

%

NA

Synthetic wax additive

mpp cf or 10 mg/m3

--- PHYSICAL DATA --BoilingPoint (“F):NA SpecificGravity (H,O =

1.01

VaporPressure (mm Hg):NA Percent Volatile byWeight (%): NA VaporDensity(air = 1): NA FreezingPoint:

NA

EvaporationRate:

NA

pH: Solubilityin Water:NA MeltingPoint: NA Appearance/Color/Odor: Dust or powdery material.

--- FIRE AND EXPLOSION HAZARDS --FlashPoint:NA FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Foam or water spray, dry chemical, carbon dioxide.

Chapter 9

452

Special Fire Fighting Procedures: Use water to keep fire-exposed containers cool. Use self-contained breathing apparatus. If fire is large, evacuate area and fight fire from a safe distance. Cool surrounding area with water.

If confined during exposure to a fire, decompose with force. Material is subject to decomposition under friction or heavy shock. Unusual Fire and Explosion Hazards: Exposure of containers to fire results in rapid productdecomposition, container pressure buildup, and failure, followedbyvigorousburningwith flare effect. Cleanupshouldnotbe attempted until all the product has cooled completely. May form flammable dust-air mixtures. HazardousProductsofCombustionandDecomposition: provided by manufacturer.

Noinformation

HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA -Effects of Overexposure: material.

Unknown; thisis

notconsideredahazardous

Emergency Response and First Aid: Skin: Wash thoroughly with soap and running water. Remove contaminated clothing and wash before reuse. Eyes: In case of contact, immediately flush with plenty of low-pressure water for at least 15 min. Remove any contact lenses to ensure thorough flushing. Call a physician. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If conscious, the person should immediately drinklarge quantities of liquid to dilute this product. Never give liquids to an unconscious person. Call a physician. Cancer Information: Not listed as a carcinogen by NTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--- TOXICITY DATA --Animal Effects: Noinformation reported.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

453

- REACTIVITY DATA -Stability and Conditions to Avoid: No information reported. Materials to Avoid (Incompatibility): No information reported. HazardDecompositionProducts:

No information reported.

HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE -For Spills: No special requirements reported. Waste Disposal Method: Dispose of in accordance with federal, state, and local regulations. Empty Containers: The container for this product canpresent explosion or fire hazards, evenwhenemptied. To avoid the risk of injury, do not cut, puncture, or weld on or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection: Where TLV is exceeded,useofanapproved respirator is recommended (U.S. Bureau Mines).

dust

Type of Ventilation Required: Provide ventilation as required to keep TLV at or below 30 mpp cf or 10 mg/m3 (nuisance dust). EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves and Other: Impervious gloves andclothing should be worn. Storage and Handling Precautions:Store in cool, dry location away from all sources heat, spark, andopenflames.Avoid ignition sources such as sparks and flames. Ground all equipment. In addition, when emptying bags where flammable vaporsmay be present, blanket vessel withinert gas, ground operator, and pour material slowly into conductive, grounded chute.

Chapter 9

454

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughly clean all equipment, piping, or vessels before beginning maintenance or repairs. Keep area clean.

--- REGULATORY INFORMATION -No information reported.

--IDENTIFIERS --Chemical Name and Synonyms: SYNTHETIC WAX ADDITIVE, C24~ZEC~zz Trade Name and Synonyms: ChemicalFamily:

Chlorowax

NA

Manufacturer: DiamondShamrockChemical

Co., Cleveland, Ohic

UN IDNumber: NA

--- INGREDENTS AND COMPOSITION DATA --Material

No.

%

Cas

Wax

established

--- PHYSICAL DATA -Boiling Point (“F):None known, decomposes Specific Gravity (H,O = 1): Approximately Vapor Pressure (mm Hg): Essentially nonvolatile Percent Volatile by Weight (%): VaporDensity(air FreezingPoint:

at 70°F

= 1): Essentially zero

Essentially nonvolatile

at 25/25”C

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

455

Evaporation Rate: Essentially zero (relative to butyl acetate) pH: NA Solubility inWater:

Negligible

MeltingPoint: NA Appearance/Color/Odor: White to tan powder with characteristic odor.

--- FIRE AND EXPLOSION HAZARDS --Flash Point: None under 400°F FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Foam or water spray, dry chemical, carbon dioxide. Although not considered flammable, liquid chlorowax products flow freely when hot and should, therefore, be treated as an oil when exposed in a fire area. Special Fire Fighting Procedures:

Treat as a hot oil.

UnusualFireandExplosionHazards: Gaseousdecompositionproducts generatedwithexcess heat, whichcould result in rupture ofnonvented containing vessel. Hazardous Productsof Combustion and Decomposition: Hydrogen chloride and traces of fragmented short-chain hydrocarbons. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA --Effects of Overexposure: Noneknown. Emergency Response and First Aid: Skin: Wash thoroughly with soap and running water. Remove contaminated clothing and wash before reuse.

Chapter 9

456

Eyes: In case ofcontact, immediately flush with plenty of low-pressure water for at least 15 min. Remove any contact lenses to ensure thorough flushing. Call a physician. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If conscious, the person should immediately drink large quantities of liquid to dilute this product. Never give liquids to an unconscious person. Call a physician. Cancer Information: Not listed as a carcinogenby NTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--TOXICITY DATA --Animal Effects: Clinical laboratory tests have indicated that Chlorowax 70 is notacutely toxic as definedin the Regulationsof the FederalHazardous Substances Labeling Act. Test Results Oral: Based on laboratory toxicological investigations, the LD50 for white rats is assumed to be approximately 50 g/kg and 25 g/kg for guinea pigs. Dermal: Patch tests on 200 unselectedhuman subjects (100 maleand 100 female) indicated that Chlorowax 70 is neither a primary imtant nor a sensitizer and may be used safely in contact with human skin, Whether the test material is classed as toxic as this term is defined in the Regulations could not be determined since a sufficiently high dosage concentration for LD50and LDlOO could not be attained before death would be caused due to mechanical injury and not toxicity. 2. Smyth Laboratories, Philadelphia, Pennsylvania 1.

Other Studies

Clinical Toxicology of Commercial Productsby Gleason, Gosselin, and Hodge, published by Williams & Wilkins Co. (1963). Chlorowax type products are rated Class "no injury in test animals short of doses which produce intestinal obstruction" and "do not appear tobeimtants or sensitizers." Class I is practically nontoxic with probable lethal dose for humans beinggreater than 1 qt (above g/kg), page 90.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

457

--REACTIVITY DATA -StabilityandConditions to Avoid: Temperaturesexceeding 40OOF; strong bases. Materials to Avoid (Incompatibility): Metals of the third and fourth periods of the periodic chart, when hot, especially in finely divided free state. HazardDecompositionProducts:

Unknown

HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE -ForSpills: dispose.

Cover liquid with oil-absorbent-type materials; sweepupand

Waste Disposal Method: Follow federal, state, and local regulations for health and pollution. EmptyContainers: Storagetemperaturesshouldnotexceed for more than several hours in vented containers. Storagetemperaturesshouldnot exceed 4OoC in contained vessels. Aqueous systems of finely divided metals of the third and fourth periods of the periodic chart, strongly basic chemicals in undiluted, aqueous form and especially in concentrated organic solvent solutions.

--- SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection: Utilization of respiratory protection equipment when working in aerosol mist of liquid chlorowax. Type of Ventilation Required: Not necessary unless overheated. EyeProtectionRequirements: Chemicalgoggles.Eyewash safety showers should be easily accessible.

fountains and

Protective Gloves andOther: Impervious gloves andclothing should be worn. Manufacturer recommends rubber gloves be used.

458

Chapter 9

Storage and Handling Precautions:Store in cool, dry location away from all sources of heat, spark, andopen flames. Avoid ignition sources such as sparks and flames. This material may react with acids andacidlike materials and strong oxidizing and reducing agents and should not be stored near such materials.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate and thoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Notethat this product will bum.

--REGULATORY INFORMATION --No information found.

--- IDENTIFIERS -Chemical Name and Synonyms: DI-(ZETHYL HEXYL)

ADIPATE

Trade Name and Synonyms: Dioctyl Adipate C497 ChemicalFamily:

Ester

Manufacturer: C. P. HallCo.,Chicago,

Illinois

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --Material Di-(2ethyl hexyl) adipate

Cas

%

NA

--- PHYSICAL DATA --Boiling Point (“F): 210 to 221 at 4 mm Hg SpecificGravity (H,O = 1): 0.923

TLV Not established

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

459

Vapor Pressure (mm Hg): C0.15 at Percent Volatile by Weight (%): Nonvolatile Vapor Density (air = FreezingPoint:

NA

NA

EvaporationRate:

NA

p H NA Solubility inWater:

CO.01

MeltingPoint: NA Appearance/Color/Odor: Mild, oxatyl type

--- FIRE AND EXPLOSION H A Z A R D S --Flash Point:

400°F

FlammabilityLimits:

NA

AutoignitionTemperature:

NA

Extinguishing Media: Foam or water spray, dry chemical, carbon dioxide. Special Fire Fighting Procedures: None reported. Unusual Fire and Explosion Hazards: None reported. Hazardous Products of Combustion and Decomposition: None reported. Hazardous Polymerization: Will not occur.

-- HEALTH HAZARD DATA -Effects of Overexposure: Noneknown.

Chapter 9

460

Emergency Response and First Aid: Skin: Wash thoroughly with soap and running water. Remove contaminated clothing and wash before reuse. Eyes: In case of contact, immediately flush with plenty of low-pressure water for at least 15 min. Remove any contact lenses to ensure thorough flushing. Call a physician. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If conscious, the person should immediatelydrink large quantities of liquid dilute this product. Never give liquids to an unconscious person. Call a physician. Cancer Information: Not listed as a carcinogen byNTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--- TOXICITY DATA -Animal Effects: None reported.

--REACTIVITY DATA StabilityandConditions to Avoid: Temperaturesexceeding 400OF; strong bases. Materials to Avoid (Incompatibility): None reported. HazardDecompositionProducts:

Unknown

HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE --For Spills: Cover liquid with oil-absorbent-type materials; sweep up and dispose. Waste Disposal Method: Follow federal, state, and local regulations for health and pollution. EmptyContainers: Storagetemperaturesshouldnotexceed for more than several hours in vented containers. Storagetemperaturesshouldnot exceed in contained vessels.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

461

Aqueous systems of finely divided metals of the third and fourth periods of the periodic chart, strongly basic chemicals in undiluted, aqueous form and especially in concentrated organic solvent solutions.

--SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: Utilization of respiratory protection equipment when working in aerosol mist of liquid chlorowax. Type of Ventilation Required: Not necessary unless overheated.

EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves andOther: Impervious gloves andclothing should be worn. Manufacturer recommends rubber gloves be used. Storage and Handling Precautions:Store in cool, dry location away from all sourcesof heat, spark, andopen flames. Avoid ignition sources such as sparks and flames. This material may react with acids andacidlike materials and strong oxidizing and reducing agents and should not be stored near such materials.

OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughlycleanallequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Note that this product will bum.

--- REGULATORY INFORMATION -No information found.

--IDENTIFIERS -Name:DI-N-OCTYLPHTHALATE Synonyms: 1,2-Benzenedicarboxylic acid, Di-N-Octyl Ester; Dioctyl Phthalate CAS: 117-84-0; RTECS: TI1925000 Formula: C&& Mol Wt: 390.54 WLN: 80VRBV08

462

Chapter 9

Chemical Class: Ester See other identifiers listed below under Regulations.

--- PROPERTIES --Boiling Point: 657 K;383.8"C;722.9"F Melting Point: 223 K; -58.3"F Flash Point: 480 K;206.8"C; 404.3"F Autoignition: NA UEL: NA LEL: NA Vapor Density:No data Specific Gravity: No data Density: 0.981 Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100%Odor Detection:No data

--- REGULATIONS --DOT hazard class: 9 CLASS 9 DOT guide: 31 Identificationnumber: UN3077 DOT shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. Packinggroup: 111 Label(s)required: CLASS9 Special Provisions: 8 , B54 Packaging exceptions: 173.155 Nonbulk packaging: 173.213 Bulkpackaging: 173.240 Quantity limitations: Passenger aidrail: None

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents Cargo aircraft only:None Vesselstowage:A STCC Number: Not listed Clean Water Act Sect. Yes Clean Water Act No Clean Air Act:Not listed EPA Waste Number: U107 CERCLA Ref: Y RQ Designation: D, lb kg) CERCLA SARA TPQ Value: Not listed SARA Sect. Categories: Acute toxicity: irritant. Chronic toxicity: carcinogen. Chronic toxicity: reproductive toxin. Yes Listed in SARA Sect. De Minimus Concentration: 1 U.S. Postal Service Mailability:

Not given

--- TOXICITY DATA -Short-term Toxicity:

Unknown

Long-term Toxicity: Unknown Conc IDLH Unknown NIOSH REL: Not given ACGIH TLV: Not listed ACGIH STEL: Not listed OSHA PEL: Not in Table 2-l-A

MAK Information: Not listed Carcinogen: Y; Status: Seebelow

463

464

Chapter 9

CarcinogenLists: Z A R C Not classified as to human carcinogenicity or probably not carcinogenic to humans; M A K Not listed; NZOSH Carcinogen defined by NIOSH with further categorization; NTP: Carcinogen defined by NTP as reasonably anticipated to be carcinogenic, with limited evidence in humans or sufficient evidence in experimentalanimals; ACGZH Not listed; OSHA: Not listed.

LD50 Value: orl-rat LD50: > 15 g k g OtherSpeciesToxicity Data: (Source:NIOSHRTECS orl-rat LD50: > 15 g/kg orl-mus LD50:6513 mgkg ipr-mus LD50:65 g k g Skn-gpg LD50: >5 g/kg ReproductiveToxicity reproductive toxin.

(1992 RTECS):

Thischemical

1992)

is amammalian

Reproductive Toxicity Data (1992 RTECS): ipr-rat TDLo5 g/kg (5-15D preg) JPMSAE 61, 51, 72 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) Specific Developmental Abnormalities Eye, ear Other developmental abnormalities orl-mus TDLo:78 g/kg (7-14D preg) NTIS** PB85-220143 Effects Newborn Live birth index (number of fetuses per litter) Growth statistics (e.g., reduced weight gain)

--PROTECTION AND FIRST AID -Recommended Respiration Protection Source: NIOSH Pocket Guide(85-1 14) NIOSH(Di-N-Octyl Phthalate) Greater atany detectable concentration: Anyself-containedbreathing apparatus with a full facepiece and operated in a pressuredemand or other positive-pressure mode. Any supplied-air respirator with a full facepiece and operated in a pressure-demandor other positive-pressuremode in combination with an auxiliary self-contained breathing apparatus operated in a pressuredemand or other positive-pressure mode.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

465

Escape: Any air-purifying full facepiece respirator witha highefficiency particulate filter. Any appropriate escape-type self-contained breathing apparatus. FirstAidSource: DOT Emergency Response Guide 1993. In case of contact with material, immediately flush eyes with running water for at least 15 min.Wash skin withsoapand water. Remove and isolate contaminated clothing and shoes at the site.

- INITIAL INCIDENT RESPONSE -U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT (1990). DOTShippingName: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. DOT ID Number: UN3077 ERG90

* POTENTIAL HAZARDS *

GUIDE 31

*Health Hazards Contact may cause bums to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Some of these materials may bum, but none of them ignites readily.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection. CALLCHEMTRECAT 1-800-424-9300 FOREMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Smallfires: Dry chemical, CO,, water spray, or regular foam. Largefires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. Do not scatter spilled material with high-pressure water streams. Dike fire-control water for later disposal.

Chapter 9

466

*Spill or Leak Stop leak if you can do it without risk. Small dry spills: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. Cover powder spill with plastic sheet or tarp to minimize spreading. *First Aid In case of contact with material, immediately flush eyes with running water for at least 15 min.Wash skin withsoapand water. Removeand isolate contaminated clothing and shoes at the site.

IDENTIFIERS

---

Chemical Name and Synonyms: PETROLEUM HYDROCARBON LUBRICANT Trade Name and Synonyms:

Penreco A.S.T.M. Reference

Oil No. 1

ChemicalFamily: PetroleumHydrocarbonProduct Manufacturer: PENRECO, Los Angeles, California

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --Material Petroleum hydrocarbon lubricant

No.

Cas

%

NA

PHYSICAL DATA BoilingPoint (“F): SpecificGravity (H,O = 1): 0.882

Not established

---

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

VaporPressure (mmHg):

467

<0.0001

Percent Volatile byWeight (%): NA VaporDensity(air = 1): FreezingPoint:

>1

NA

Evaporation Rate: <0.01 pH. NA Solubility inWater:

Soluble in hydrocarbons; insoluble in water.

MeltingPoint: NA Appearance/Color/Odor: Petroleumhydrocarbon odor.

--F'IRE AND EXPLOSION HAZARDS -FlashPoint:

,

>500°F (COC)

FlammabilityLimits: NA AutoignitionTemperature:

> 600°F

Extinguishing Media: Use dry chemical, foam, or carbon dioxide. Special Fire Fighting Procedures: Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid. Unusual Fire and Explosion Hazards: Dense smoke may be generated while burning.Carbonmonoxide,carbon dioxide, and other oxides may be generated as products of combustion. Hazardous Products of Combustion and Decomposition: HazardousPolymerization: Willnot occur.

None reported.

Chapter 9

468

- HEALTH HAZARD DATA --Effects of Overexposure: On rare occasions, prolonged and repeated exposure to oil mist poses a risk of pulmonary disease such as chronic lung inflammation. This condition is usually asymptomatic as a result of repeated small aspirations. Shortness of breath and cough are the most common symptoms. Aspiration maylead to chemicalpneumonitis,whichis characterized by pulmonary edema and hemorrhage and may be fatal. Signs of lung involvement include increased choking and gagging and are often noted at the time of aspiration. Gastrointestinaldiscomfort may develop, followed by vomiting, with a further risk of aspiration. Emergency Response and First Aid: Skin: Removecontaminated clothing. Washcontaminated area thoroughly with soap and water. If redness or irritation occurs, seek medical attention. If material is hot, submerge injured area in cold water. If victim is severely burned, remove to a hospital immediately. Eyes: Immediately flush eyeswith large amounts of waterandcontinue flushing for 15 min. If material is hot, treat for thermal bums and take victim to hospital immediately. Inhalation: This material has a low vapor pressure and is not expected to present an inhalation exposure at ambient conditions. If vapor or mist is generatedwhen the materialisheated or handled,removevictimfrom breathing hasstopped or is irregular, administer artificial exposure. respiration and supply oxygen if it is available. If victim is unconscious, remove to fresh air and seek medical attention. Ingestion: Do notinducevomiting.Seekmedical attention. Cancer Information: Not listed as a carcinogen by NTP(National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--TOXICITY DATA -Animal Effects: None reported.

--REACTIVITY DATA -Stability and Conditions to Avoid: Stable. Materials to Avoid (Incompatibility): None reported.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents 469

HazardDecompositionProducts:

Unknown.

Hazardous Polymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE --For Spills: Consult health effect informationsection, personal health protection information section, fire protectionsection,andreactivitydata.Notify appropriate authorities of spill. Contain spill immediately. Do not allow spill to enter sewers or watercourses.Removeallsourcesof ignition. Absorb with appropriate inert material such as sand and clay. Large spills may be picked up using vacuum pumps, shovels, buckets, or other means and placed in drums or other suitable containers. Waste Disposal Method: All disposals must comply with federal, state, and local regulations. The material, if spilled or discarded, may be a regulated waste.Referto state andlocalregulations. Caution: If regulated solvents are used to clean up spilled material, the resulting waste mixture maybe regulated. Department of Transportation (DOT) regulations may apply for transporting this material when spilled. Waste material may be landfilled or incinerated at an approved facility. Materials should be recycled if possible. Empty Containers: Storage temperatures should not exceed 66°C for more than several hours in vented containers. Storage temperatures should not exceed 40°C in contained vessels. Aqueous systems of finely divided metals of the third and fourth periods of the periodic chart, strongly basic chemicals in undiluted, aqueous form and especially in concentrated organic solvent solutions.

--SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection:Respiratory protection is not required underconditions normal use. If vapor or mist is generated when the material is heated or handled,usean organic vapor respirator with a dustandmist filter. All respirators mustbeNIOSH certified. Do notusecompressedoxygenin hydrocarbon atmospheres. ~

Type of Ventilation Required: If vapor or mist is generatedwhen the material is heated or handled, adequate ventilation in accordance with good engineering practicemust be provided to maintainconcentrationsbelowthespecified exposure or flammable limits.

Chapter 9

470

Eye Protection Requirements: Eye protection not required under conditions of normal use. I f material is handled such that it could be splashedinto eyes, wear plastic face shield or splash-proof safety goggles. Protective Gloves and Other: No skin protection is required for single, shortdurationexposures. For prolonged or repeated exposures, useimpervious synthetic rubber clothing (boots, gloves, aprons, etc.) over parts of the body subject to exposure. If handling hotmaterial, use insulatedprotective clothing (boots, gloves, aprons, etc.). Storage and Handling Precautions: Store in cool,dry location away from all sourcesof heat, spark, andopenflames.Avoid ignition sourcessuch as sparks and flames. This material may react with acids andacidlike materials and strong oxidizing and reducing agents and should not be stored near such materials.

OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughly clean allequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Note that this product will bum. REGULATORY INF'ORMATION

--

---

not transfer to unmarked containers. Store in closed containers away from heat, sparks, open flame, or oxidizing materials. This product is not classified as hazardous under DOT regulations. Fire extinguishers should be keptreadily available. SeeNFPA 30 andOSHA 1910.106 FlammableandCombustible Liquids.

--

IDENTmRS

---

Chemical Name and Synonyms: PETROLEUM HYDROCARBON Trade Name and Synonyms:

Califlux 550

ChemicalFamily: PetroleumHydrocarbon Manufacturer: WitcoChemical Corp., Oildale, California

UN ID Number: NA

Oils, Plasticizers, Lubricants, Solvents, andMoldReleaseAgents

47 1

--- INGREDIENTS AND COMPOSITION DATA -Material

No. Cas

Dibenzoyl p - Not quinonedioxime

%

NA

TLV established

--- PHYSICAL DATA --BoilingPoint (“F): NA SpecificGravity (H,O = 1): 1.02 Vapor Pressure (mmHg): NA Percent Volatile byWeight (%): Not volatile VaporDensity(air = 1): NA FreezingPoint:

NA

EvaporationRate: NA p H Not corrosive Solubilityin Water: Insoluble MeltingPoint: NA AppearancelColorlOdor: Oily mobile (viscous)liquid; no objectionable odor.

--FIRE AND EXPLOSION HAZARDS --FlashPoint: 465°F (COC) FlammabilityLimits: NA AutoignitionTemperature:

NA

ExtinguishingMedia: Foam, water fog, CO,, dry chemical, vaporizing-liquidtype extinguishing agent.

Chapter 9

472

Special Fire Fighting Procedures:

Standard petroleum procedures.

Unusual Fire and Explosion Hazards: Do not use welding or cutting torch on near any container of this material, even empty, because an explosion could occur. Do not use, pour, spill, or store near heat or open flame. Hazardous Products of Combustion and Decomposition:

Toxic fumes.

Hazardous Polymerization: Will not occur.

--- HEALTH HAZARD DATA -Effects of Overexposure: Principal routes of exposure are skin contact and inhalation. Slight irritation potential reported by the manufacturer. Ingestion of the product in large quantities may cause milddigestive disorders, including diarrhea. There are no data available that address medical conditions that are generally recognized as being aggravated by exposure to this product.

Emergency Response and First Aid: Skin: Flush all affectedareas with plenty of water for several minutes. Removeandcleananycontaminated clothing and shoes. Seekmedical attention if skin irritation occurs. Eyes: Flush eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If swallowed, immediatelygive several glasses water and induce vomiting by gagging the victim witha finger placed on the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Not listed as a carcinogen by NTP (National Toxicology Program): not regulated as a carcinogen by OSHA: not evaluated by IARC (International Agency for Research on Cancer).

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

--- TOXICITY DATA -AnimalEffects: Observe current ACGIHTLVof 5 mg/m3 for oil mists. Dermatitis in very sensitive individuals after extended exposure (days).

--REACTIVITY DATA -Stability and Conditions to Avoid: Heat, open flames. Materials to Avoid (Incompatibility): None reported by the manufacturer. HazardDecompositionProducts:

Unknown

HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE --For Spills: Sweep spillage; wash residuals with soap and water and transfer to a closed container. Waste Disposal Method:

Same as for organic chemicals.

Empty Containers: The container for this product can present explosionor fire hazards, evenwhenemptied. To avoid the risk of injury,do not cut, puncture, or weld on or near this container.

--- SPECIAL PROTECTION AND PRECAUTIONS --Respiratory Protection:Appropriate respirator selected and used accordance with OSHA Subpart I (29 CFR 1910.134) and manufacturer’s recommendations is required if airborne dust is not adequately controlled or if excessive fumes are generated from product decomposition. Self-contained breathing apparatus shouldbeworn in highvaporand dust concentrations. Under normal use, manufacturer recommends a dust mask. Type of VentilationRequired: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible.

Chapter 9

474

Protective Gloves andOther: Impervious gloves andclothing should be worn. Manufacturer recommends rubber gloves be used. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. OtherPrecautions: Useall standard practices for goodpersonalhygiene. Completely isolate andthoroughly clean allequipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Note that this product will bum.

--- REGULATORY INFORMATION -None reported.

--IDENTIFIERS --Chemical Name and Synonyms: PETROLEUM HYDROCARBON Trade Name and Synonyms:

Cyclolube

ChemicalFamily: PetroleumHydrocarbon Manufacturer: WitcoChemical Corp., Oildale, California

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA -Material NAhydrocarbon Petroleum

Cas No.

%

TLV established

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

475

--- PHYSICAL DATA --BoilingPoint (“F):NA SpecificGravity (H,O = 1): 0.92 VaporPressure(mmHg):

NA

Percent Volatile by Weight (%): Not volatile =

VaporDensity(air FreezingPoint:

NA

NA

EvaporationRate: pH: Not corrosive SolubilityinWater: MeltingPoint:

Insoluble

NA

Appearance/Color/Odor: Oilymobile liquid light odor.

--FIRE AND EXPLOSION HAZARDS --FlashPoint:440°F

(COC)

AutoignitionTemperature:

NA

Extinguishing Media: Foam, water fog, type extinguishing agent. Special Fire Fighting Procedures:

dry chemical, vaporizing liquid-

Standard petroleum procedures.

Unusual Fire and Explosion Hazards: Do nor use welding or cutting torch or near anycontainer of this material, even empty, because an explosion could occur. Do nor use, pour, spill, or store near heat or open flame.

Chapter 9

476

Hazardous Products of Combustion and Decomposition: Toxic fumes. HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA --Effects of Overexposure: Principal routes of exposure are skin contact and inhalation. Slight irritation potential reported by the manufacturer. Ingestion of the product in large quantities may cause milddigestive disorders, including diarrhea. There are data available that address medical conditions that are generally recognized as being aggravated by exposure to this product.

Emergency Response and First Aid: Skin: Flush all affected areas with plenty ofwater for several minutes. Removeandcleananycontaminated clothing and shoes. Seekmedical attention if skin irritation occurs. Eyes: Flush eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If swallowed, immediately giveseveral glasses of water and induce vomitingbygagging the victim witha finger placed the back the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Not listed as a carcinogen by NTP(National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research Cancer).

--TOXICITY DATA --Animal Effects: No data listed. REACTIVITY DATA

--

Stability and Conditions to Avoid: Heat, open flames. Materials to Avoid (Incompatibility): None reported by the manufacturer.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

HazardDecompositionProducts:

477

Unknown

HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE For Spills: Sweep spillage; wash residuals with soap and water and transfer to a closed container. Waste Disposal Method:

Same as for organic chemicals.

Empty Containers: The container for this product can present explosionor fire hazards, evenwhenemptied. avoid the risk of injury, do not cut, puncture, or weld on or near this container.

--SPECIAL PROTECTION AND PRECAUTIONS Respiratory Protection:Appropriate respirator selected and usedin accordance with OSHA Subpart I CFR 1910.134) and manufacturer’s recommendations is required if airborne dust is not adequately controlled or if excessive fumes are generated from product decomposition. Self-contained breathing apparatus should be worninhighvaporand dust concentrations. Under normal use, manufacturer recommends a dust mask. Type of Ventilation Required: Generalmechanical.Avoid breathing dusts and vapors. Adequate ventilation should be provided to keep mist and dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air-pollution regulations,

EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves andOther: Impervious gloves andclothing should be worn. Manufacturer recommends rubber gloves be used. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup.

478

Chapter 9

OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughly clean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Note that this product will bum.

- REGULATORY INFORMATION -None reported.

--- IDENTIFIERS -Chemical Name and Synonyms: PETROLEUM HYDROCARBON

OIL

ChemicalFamily: RubberProcessOil Manufacturer: ExxonCompany,Houston,Texas

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA -%

No. Cas Material hydrocarbon Petroleum

Not

NA

--- PHYSICAL DATA --Boiling Point (“F):545 to 884 SpecificGravity (H20= 1): 0.898 VaporPressure(mmHg):

<0.01 at100°F

Percent Volatile by Weight (%): 2.5 (3 hr at 325°F) VaporDensity(air =

> 12

TLV established

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

FreezingPoint:

479

NA

EvaporationRate: NA p H Not corrosive Solubility inWater:

Negligible

MeltingPoint: NA Appearance/Color/Odor: Clear light straw-colored oil; bland odor.

--- FIRE AND EXPLOSION RhZARDS --FlashPoint: 275°F (COC) Flammability Limits: LEL, 1% ; UEL, 6% AutoignitionTemperature:

NA

Extinguishing Media:Foam, water fog, COz, drychemical, vaporizing liquidtype extinguishing agent. Special Fire Fighting Procedures: Use air-supplied breathing equipment for enclosed areas. Cool exposed containers with water spray. Avoid breathing vapor or fumes. Unusual Fire and Explosion Hazards: Do not mix or store with strong oxidants like liquid chlorine or concentrated oxygen. Do not use, pour, spill, or store near heat or open flame. Hazardous Products of Combustion and Decomposition: Toxic fumes. Hazardous Polymerization: Will not occur.

--HEALTH HAZARD DATA -Effects of Overexposure: Prolonged or repeated skin contact may cause mild skin irritation.

Chapter 9

480

Emergency Response and First Aid: Skin: Flushallaffected areas with plenty ofwater for several minutes. Removeand clean anycontaminated clothing and shoes. Seekmedical attention if skin irritation occurs. Eyes: Flush eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If swallowed, immediately give several glasses of water and induce vomitingbygagging the victimwitha finger placed on the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Not listed as a carcinogen byNTP (National Toxicology Program); not regulated as a carcinogen by OSHA; not evaluated by IARC (International Agency for Research on Cancer).

--

TOXICITY DATA

--

Animal Effects: None reported.

--REACTIVITY DATA -StabilityandConditions considered stable.

to Avoid: Heat,open

flames. This product is

Materials to Avoid (Incompatibility): Strong oxidizers like liquid chlorine, concentrated oxygen, sodium, or calcium hypochlorite. Hazard Decomposition Products:Fumes, smoke, carbon monoxide, and sulfur oxides, in the case of incomplete combustion. Hazardous Polymerization: Will not occur.

--- SPILL AND EMERGENCY RESPONSE

---

For Spills: Recover free liquid. Add absorbent (sand, earth, sawdust, etc.) to spill area. Keep petroleum productsout of sewers and watercourses by diking or impounding.Advise authorities ifproducthas entered or may enter sewers, watercourses, extensive land areas.

48 1

Oils, Plasticizers, Lubricants, Solvents, andMoldReleaseAgents

Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal site or facility. Empty Containers: Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants.

--- SPECIAL PROTECTION AND PRECAUTIONS --RespiratoryProtection: Normallynotneeded.Use protection confined or enclosed spaces.

supplied-air respiratory

Type of Ventilation Required: Use local exhaustto capture fumes andvapors. Provide greater than 60-fpm hood or face velocity for confined spaces. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible. Protective Gloves andOther: Impervious gloves andclothing should be worn. Manufacturer recommends rubber gloves be used. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. OtherPrecautions: Useall standard practices for good personal hygiene. Completely isolate andthoroughly clean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Nore that this product will bum.

--REGULATORY INFORMATION --None reported. v

v

v

v

v

v

v

v

v

v

v

v

v

v

482

Chapter 9

--IDENTIFIERS -Chemical Name and Synonyms: PETROLEUM HYDROCARBON Trade Name and Synonyms:

OIL

Flexon 340

ChemicalFamily: Rubber ProcessOil Manufacturer: ExxonCompany, Houston, Texas UN ID Number: NA

--- JNGREDIEN"S AND COMPOSITION DATA --%

Cas No.

Material

Extracts (petroleum), 64742-11-6 heavy naphthenic distillate solvent

established Not

--- PHYSICAL DATA --Boiling Point ("F): IBP approximately 251°C (485°F) by ASTM D 2887 SpecificGravity (H,O = 1): (15.6"C/15.6"C) VaporPressure(mm Hg): <0.01 at20°F Percent Volatile by Weight 38°C (100°F) VaporDensity(air FreezingPoint:

Negligible from open container in 4 hr at

= 1): > 5

NA

Evaporation Rate: At 1 atm and 25°C(77°F) (n-butyl acetate = 1) <0.01 p H Essentiallyneutral Solubility in Water: Negligible:lessthan

0.1 %

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

MeltingPoint/Pour ASTM D

or CongealingPoint:

483

-33°C (-28OF), pour point by

Viscosity: 12 SSU at100°F Appearance/Color/Odor: Cleardarkorange odor.

liquid; mild, blandpetroleum

--FIRE AND EXPLOSION HAZARDS --FlashPoint: NA FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media:Foam, water fog, COz, drychemical, vaporizing liquidtype extinguishing agent. Special Fire Fighting Procedures: Use air-supplied breathing equipment for enclosed areas. Cool exposed containers with water spray. Avoid breathing vapor or fumes. Unusual Fire and Explosion Hazards: Do not mix or store with strong oxidants like liquid chlorine or concentrated oxygen. Do nof use, pour, spill, or store near heat or open flame. Hazardous Products of Combustion and Decomposition: Toxic fumes. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA --Effects of Overexposure: None recognized. Emergency Response and First Aid: Skin: Flushallaffected areas withplentyofwater for several minutes. Removeand clean anycontaminated clothing and shoes. Seekmedical attention if skin irritation occurs.

Chapter 9

484

Eyes: Flush eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Znhalution: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Zngesrion: If swallowed, immediately giveseveral glasses of water and induce vomitingbygagging the victimwitha finger placedon the backof the victim's tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Long-term, repeated exposure may cause skin cancer.

--TOXICITY DATA -Animal Effects: Prolonged or repeated skin contact with this product tends to remove skin oils, possibly leading to irritation and dermatitis; however, based on human experience and available toxicological data, this product is judged to be neither a "corrosive" nor an "irritant" by OSHA criteria. Product contacting the eyes may cause eye irritation. Contains greater than 45% aromatichydrocarbons boiling above600°F. Lifetime skin painting studies conducted by Exxon andothers, and reports by IARC, have shown that this type of product causesskin cancer in test animals. The substance was applied to the shaved backs of mice at regular intervals, without cleanup between applications. In view of these findings, there may be a potential risk of skin cancer in humans from prolonged or repeated skin contact with this product in the absence of good personal hygiene. Limited studies on oils that are very active carcinogenshaveshown that washing the animals' skin with soap and water between applications greatly reducestumor formation. These studies demonstrate the effectiveness of cleansing the skin after contact. Potential risks to humans can be minimized by observing good work practices andpersonalhygieneprocedures generally recommended for petroleum products. See Section I for recommended protection and precautions. Product has a low order of acute oral and dermaltoxicity, but minute amounts aspirated into the lungs duringingestion or vomiting may cause mildto severe pulmonary injury and possibly death.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

485

This product is judged to have an acute oral LD50 (rat) greater than 5 g k g of body weight and an acute LD50 (rabbit) greater than g/kg of body weight.

--REACTIVITY DATA StabilityandConditions considered stable.

to Avoid: Heat, open flames. Thisproduct

is

Materials to Avoid (Incompatibility): None reported. Hazard Decomposition Products:Fumes, smoke, carbon monoxide, and sulfur oxides, in the case of incomplete combustion. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE --For Spills: Recover free liquid. Add absorbent (sand, earth, sawdust, etc.) to spill area. Keep petroleum productsout of sewers and watercourses by diking or impounding.Advise authorities if producthas entered or may enter sewers, watercourses, or extensive land areas. Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal site or facility. Empty Containers: Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants.

--- SPECIAL PR0"ION

AND PRECAUTIONS ---

RespiratoryProtection: Normallynotneeded.Use protection in confined or enclosed spaces.

supplied-air respiratory

Type of Ventilation Required: Use local exhaust to capture fumes andvapors. Provide greater than 60-fpm hood or face velocity for confined spaces. EyeProtectionRequirements: Chemical goggles. Eyewash fountains and safety showers should be easily accessible.

486

Chapter 9

Protective Gloves andOther: Impervious gloves andclothing should be Manufacturer recommends rubber gloves be used. StorageandHandlingPrecautions: Containers should be stored ina cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. OtherPrecautions: Use all standard practices for good personal hygiene. Completely isolate andthoroughlyclean all equipment, piping, or vessels beforebeginningmaintenance or repairs. Keep area clean. Note that this product will bum.

--REGULATORY INFORMATION --Transportation Incident Information:For further information relative to spills resulting from transportation incidents, refer to latest Department of TransportationEmergencyResponseGuidebook for Hazardous Materials Incidents, DOT P 5800.3.

DOT Identification Number: Not applicable.

Chemical Name and Synonyms: RUBBER PROCESS OIL TradeNameandSynonyms:

Flexon

ChemicalFamily: PetroleumHydrocarbonOil Manufacturer: ExxonCompany,Houston,Texas UN ID Number: NA

AND EXTENDER

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents 487

--- INGREDIENTS AND COMPOSITION DATA --No.

%

Cas Material

approximately Contains NA established Not 66 % aromatic hydrocarbons

100

--- PHYSICAL DATA -Boiling Point (“F):

to 950 (IBP-FBP)

SpecificGravity (H,O = 1): 0.975 VaporPressure (mmHg):

1.2E-5 at100°F

Percent Volatile by Weight (%): 0.21 VaporDensity(air = 1): FreezingPoint:

hr at 325°F)

> 12

NA

EvaporationRate:

CO.01 (n-butylacetate = 1)

l

l

p H NA Solubility in Water: Negligible Melting Point/Pour or Congealing Point: NA Viscosity: NA AppearancelColorlOdor: Clear, orange-red oil; bland odor.

--- FIRE AND EXPLOSION HAZARDS -Flash Point: 420°F (Cleveland open cup) Flammability Limits: LEL, 1%; UEL, 6% AutoignitionTemperature:

NA

Chapter 9

488

Special Fire Fighting Procedures: Use air-supplied breathing equipment for enclosed areas. Cool exposed containers with water spray. Avoid breathing vapor or fumes. Unusual Fire and Explosion Hazards: Do not mix or store with strong oxidants like liquid chlorine or concentrated oxygen. Hazardous Products of Combustion and Decomposition:

Toxic fumes.

Hazardous Polymerization: Will not occur.

--- HEALTH HAZARD DATA -Effects of Overexposure: Prolonged or repeated skin contact may cause skin irritation or more serious skin disorder. Emergency Response and First Aid: Skin: Flushallaffected areas withplenty water for several minutes. Removeand clean anycontaminated clothing and shoes. Seekmedical attention if skin irritation occurs. Eyes: Flush eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If swallowed, immediately give severalglasses of water and induce vomitingbygagging the victimwith a finger placed the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Refer to toxicity data.

--TOXICITY DATA -Threshold Limit Value: CFR 1910.1000).

5 mg/m3 for oil mist

air

Regulation 29

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

489

AnimalEffects: Contains greater than 45% aromatichydrocarbons boiling above 600°F. Lifetime skin painting studies conducted by Exxon andothers, and reports by IARC, have shown thatthis type of productcauses skin cancer mice at in test animals. The substance was applied to the shaved backs regular intervals, withoutcleanupbetween applications. In viewof these findings, there maybea potential risk of skin cancer in humansfrom prolonged or repeated skin contact with this product in the absence of good personal hygiene. Limited studies on oils that are very active carcinogenshaveshown that washing the animals’ skin with soap and water between applications greatly reducestumor formation. These studies demonstrate the effectiveness of cleansing the skin after contact. Potential risks to humans can be minimized by observing good work practices and personal hygieneprocedures generally recommended for petroleum products. See Section for recommended protection and precautions. Product has a low order of acute oral and dermal toxicity, but minute amounts aspirated into the lungs duringingestion or vomiting may cause mildto severe pulmonary injury and possibly death.

--REACTIVITY DATA -StabilityandConditions considered stable.

to Avoid: Heat,openflames.Thisproduct

is

Materials to Avoid (Incompatibility): Strong oxidants like liquid chlorine, concentrated oxygen, sodium, or calcium hypochlorite. Hazard Decomposition Products:Fumes, smoke, carbon monoxide, and sulfur oxides, in the case of incomplete combustion. HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE --For Spills: Recover free liquid. Add absorbent (sand, earth, sawdust, etc.) to spill area. Keep petroleum productsout of sewers and watercourses by diking or impounding.Advise authorities ifproducthas entered or may enter sewers, watercourses, or extensive land areas.

Chapter 9

490

Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal site or facility. Empty Containers: Keep containers closed when not in use. or store near heat, sparks, flame, or strong oxidants.

not handle

--SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection: Normallynotneeded. protection in confined or enclosed spaces.

Use supplied-air respiratory

Type of Ventilation Required:Use local exhaust to capture fumes and vapors. Provide greater than 60-fpm hood or face velocity for confined spaces. EyeProtectionRequirements: contact may occur.

Use splash goggles or face shield when eye

ProtectiveGlovesand Other: Use chemical-resistantgloves to avoid skin contact. Use chemical-resistant apron or other clothing ifneeded to avoid skin contact. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. Other Precautions: Avoid breathing oil mist. Remove oil-soiled clothing and launder before reuse. Discard oil-soaked shoes. Wash skin thoroughly with soap and water after handling.

--- REGULATORY INFORMATION -Transportation Incident Information:For further information relative to spills resulting from transportation incidents, refer to latest Department of TransportationEmergencyResponseGuidebook for Hazardous Materials Incidents, DOT P 5800.3.

DOT Identification Number: Not applicable. V

V

V

V

V

V

V

V

V

V

T

V

V

V

waxed

Oils, Plasticizers, Lubricants, Solvents, andMoldReleaseAgents

49 1

--- IDENTIFIERS -Chemical Name and Synonyms: PETROLEUM PROCESS Trade Name and Synonyms:

OIL

Flexon 815

ChemicalFamily: PetroleumHydrocarbonOil Manufacturer: ExxonCompany,Houston,Texas UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA -Material

No.

%

Cas

Hydrotreated 64742-57-0 residual 100 oil, petroleum or 1910.1000, Solvent residual oil

5 mg/m3 (OSHA 29 CFR

or

--PHYSICAL DATA -Boiling Point ("F): 700 (371°C) IBP by ASTM D 2887 SpecificGravity CH,O = VaporPressure(mmHg):

0.90 (15.6"C/15.6"C) <0.01 at20°C

Percent Volatile by Weight (%): Negligible from open container in 4 hr at 38°C (100°F) VaporDensity(air FreezingPoint:

= 1): >5

NA

Evaporation Rate: CO.01 at 1atmand25°C(77°F)

(n-butyl acetate = 1)

p H Essentially neutral Solubility inWater:

Negligible: <0.1% at1atmand25°C(77°F)

492

Chapter

MeltingPointrPour ASTM D 97

or CongealingPoint:

-9°C(15"F),pour

point by

Viscosity: 153 SSU at Appearance/Color/Odor: Clear, dark brown liquid; bland petroleum odor.

--- FIRE AND EXPLOSION HAZARDS Flash Point: 420°F (Cleveland open cup) FlammabilityLimits: LEL, 1%; UEL, 6% AutoignitionTemperature: Extinguishing Media: Foam, dry chemical, carbon dioxide, or water fog or spray. Special Fire Fighting Procedures: Use air-supplied breathing equipment for enclosed areas. Cool exposed containers with water spray. Avoid breathing vapor or fumes. Unusual Fire and Explosion Hazards: Do nor mix or store with strong oxidants like liquid chlorine or concentrated oxygen. Hazardous Products of Combustion and Decomposition:

Toxic fumes.

HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA Effects of Overexposure: Prolonged or repeated skin contact may cause skin imtation. Health studies have shown that many petroleum hydrocarbonsand synthetic lubricants pose potential human health risks, which may vary from person to person. a precaution, exposure to liquids, vapors, mists or fumes should be minimized. Emergency Response and First Aid Skin: Flush all affected areas with plenty of water for 15 min. Removeand clean anycontaminated clothing and shoes. Seekmedical attention if skin imtation occurs.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

493

Eyes: Flush eyes with plenty of running water for at least min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If swallowed, immediately give severalglasses of water and induce vomitingbygagging the victim witha finger placed on the back the victim's tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Refer to toxicity data.

-Threshold Limit Value: CFR

TOXICITY DATA

--

mg/m3 for oil mist in air (OSHA Regulation 29

Animal Effects: In accordance withthe current OSHA Hazard Communication standard criteria, this product does notrequire a cancer hazard warning. This is because the product is formulatedfrombase stocks that are severely hydrotreated, severely solvent extracted, and/or processed by mild hydrotreatment and extraction. Alternatively, it may consist of components not otherwise affected byIARC criteria, such as atmosphere distillates or synthetically derived materials, and as such is not characterized by current IARC classification criteria. Prolonged or repeated skin contact with this product tends to remove skin oils, possibly leading to irritation and dermatitis; however,based on human experience andavailable toxicological data, this product is judged to be neither a "corrosive" nor an "irritant" by OSHA criteria. Product contacting the eyes may cause eye irritation. Product has a low order of acute oral and dermal toxicity, but minute amounts aspirated into the lungs duringingestion or vomiting may cause mildto severe pulmonary injury and possibly death. This product is judged to have an acute oral LD50 (rat) greater than 5 g/kg of body weight and an acute LD50 (rabbit) greater than glkg of body weight.

Chapter 9

494

--REACTMTY DATA -StabilityandConditions considered stable.

to Avoid: Heat, open flames. Thisproduct

is

Materials to Avoid(Incompatibility): Strong oxidants like liquid chlorine, concentrated oxygen, sodium, or calcium hypochlorite. Hazard Decomposition Products:Fumes, smoke, carbon monoxide, andsulfur oxides, in the case of incomplete combustion. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE --For Spills: Recover free liquid. Add absorbent (sand, earth, sawdust, etc.) to spill area. Keep petroleum productsout of sewers and watercourses by diking or impounding.Advise authorities ifproducthas entered or may enter sewers, watercourses, or extensive land areas. Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal site or facility. Empty Containers: Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants.

--- SPECIAL PROTECTION AND PRECAUTIONS --RespiratoryProtection: Normallynotneeded.Use protection in confined or enclosed spaces.

supplied-air respiratory

Type of Ventilation Required: Use local exhaustto capture fumes and vapors. Provide greater than 60-fpm hood or face velocity for confined spaces. Eye Protection Requirements: contact may occur.

Use splash goggles or faceshieldwheneye

ProtectiveGlovesand Other: Usechemical-resistantgloves to avoid skin contact. Use chemical-resistant apron or other clothing if needed to avoid skin contact.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

495

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. Other Precautions: Avoid breathing oil mist. Remove oil-soiled clothing and launder before reuse. Discard oil-soaked shoes. Wash skin thoroughly with soap and water after handling.

--- REGULATORY INF'ORMATION --Transportation Incident Information:For further information relative to spills resulting from transportation incidents, refer to latest Department of TransportationEmergencyResponseGuidebook for Hazardous Materials Incidents, DOT P 5800.3. DOT Identification Number: Not applicable.

--- IDENTIFIERS -Chemical Name and Synonyms: BLEND OF HYDROCARBONS, HIGHER ALCOHOLS, ESTERS AND SOAPS WITH SURFACE-ACTIVE PROPERTIES Trade Name and Synonyms: Aflux 42 ChemicalFamily:

Plasticizer

Manufacturer: MobayChemicalCorporation,

Pittsburgh, Pennsylvania

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --Material Product Not

Cas No. NA

%

TLV established

496

Chapter 9

--PHYSICAL DATA -BoilingPoint (“F):NA SpecificGravity (H,O = 1): 0.91 VaporPressure(mmHg):NA Percent Volatile byWeight (%): NA VaporDensity (air = FreezingPoint:

NA

NA

EvaporationRate: NA p H NA

Solubilityin Water: Slightly Melting Point/Pour or Congealing Point: NA Viscosity: NA Appearance/Color/Odor: Light brown lenticular pellets; slight odor.

--- FIRE AND EXPLOSION HAZARDS --FlashPoint:

>2OO0C

FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Foam, dry chemical, carbon dioxide, spray.

water fog or

Special Fire Fighting Procedures: Use air-supplied breathing equipment for enclosed areas. Cool exposed containers with water spray. Avoid breathing vapor or fumes.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

Unusual Fire and Explosion Hazards:

497

None reported by manufacturer.

Hazardous Products of Combustion and Decomposition: Toxic fumes. HazardousPolymerization: Willnot occur.

- HEALTH HAZARD DATA --Effects of Overexposure: None reported by manufacturer. Emergency Response and First Aid: Skin: Flush all affected areas with plenty of water for 15 min. Removeandcleananycontaminated clothing and shoes. Seekmedical attention if skin irritation occurs. Eyes: Flush eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If swallowed, immediately giveseveral glasses of water and induce vomitingbygagging the victimwitha finger placedon the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: Refer to toxicity data.

--TOXICITY DATA --Animal Effects: Noinformation reported.

--REACTIVITY DATA --StabilityandConditions considered stable.

to Avoid: Heat, open flames. Thisproduct

is

Materials to Avoid(Incompatibility): Strong oxidants like liquid chlorine, concentrated oxygen, sodium, or calcium hypochlorite. Hazard Decomposition Products:Fumes, smoke, carbon monoxide, and sulfur oxides, in the case of incomplete combustion. HazardousPolymerization: Willnot occur.

Chapter 9

498

--SPILL AND EMERGENCY RESPONSE -For Spills: Recover free liquid. Add absorbent (sand, earth, sawdust, etc.) to spill area. Keep petroleum products out of sewers and watercourses by diking or impounding.Advise authorities ifproducthas entered or may enter sewers, watercourses, or extensive land areas. Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal site or facility. Waste material may be incinerated under conditions which meet federal, state, and local environmental control regulations. Empty Containers: Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants.

--SPECIAL PROTECTION AND PRECAUTIONS --RespiratoryProtection: Normallynotneeded.Use protection in confined or enclosed spaces.

supplied-air respiratory

Type of Ventilation Required:Use local exhaustto capture fumes andvapors. Provide greater than 60-fpm hood or face velocity for confined spaces. Eye Protection Requirements: contact may occur.

Use splash goggles or face shield when eye

ProtectiveGloves andOther: Usechemical-resistantgloves to avoid skin contact. Use chemical-resistant apron or other clothing ifneeded to avoid skin contact. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to'prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. Note: This product has a l-yr shelf life. Other Precautions: Avoid breathing oil mist. Remove oil-soiled clothing and launder before reuse. Discard oil-soaked shoes. Wash skin thoroughly with soap and water after handling.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

--REGULATORY INFORMATION --Transportation Incident Information: For further information relative to spills resulting from transportation incidents, refer to latest Department TransportationEmergencyResponseGuidebook for Hazardous Materials Incidents, DOT P 5800.3. DOT Identification Number: Not applicable.

- IDENTIFIERS -Chemical Name and Synonyms: MBTS, BENZOTHIAZOLE DISULFIDE, DITHIOBISBENZOTHIAZOLE Trade Name and Synonyms: Altax ChemicalFamily:

Plasticizer

Manufacturer: R. T. VanderbiltCo.,Norwalk,Connecticut

UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --Material

96

No. Cas

TLV

Benzothiazole

Not established

Zinc stearate

Not established or

Petroleum process oil

--PHYSICAL DATA --BoilingPoint (“F): NA SpecificGravity (H,O = VaporPressure(mmHg):

NA

Not established

500

Chapter 9

Percent Volatile byWeight (%): NA VaporDensity(air = 1): NA EreezingPoint:

NA

EvaporationRate:

NA

p H NA Solubilityin Water: Negligible Melting Point/Pour or Congealing Point: NA Viscosity: NA Appearance/Color/Odor: Gray-white to cream powder or pellets; little odor.

FIRE AND EXPLOSION H A Z A R D S

--

FlashPoint: 271°F (COC) FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Foam, dry chemical, carbon dioxide, or water fog or spray. SpecialFireFightingProcedures: Use NIOSH-approved positive-pressure self-contained respirator and protective clothing. Unusual Fire and Explosion Hazards: When exposed to flame, emits acrid fumes. Dust may explosive mixture with air. Hazardous Products of Combustion and Decomposition: Oxides of carbon, sulfur, and nitrogen upon combustion. Hazardous Polymerization: Will not occur.

Oils, Plasticizers, Lubricants, Solvents, andMoldReleaseAgents

501

--- HEALTH HAZARD DATA Effects of Overexposure: Maycause allergic skin reaction. Inhalation may irritate upper respiratory tract. May irritate eyes. In laboratory animals fed relatively high amounts of product, mutagenic, teratogenic, and embryotoxic effects were observed, but carcinogenic effects were shown.

Emergency Response and First Aid: Skin: Flush all affected areas with plenty of water for 15 min. Remove and clean any contaminated clothing andshoes.Seekmedical attention if skin irritation occurs. Eyes: Flush the eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Znhalaticn: Remove to fresh air and, if indicated, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Treat immediately. Ingestion: If swallowed, immediately give several glasses of water and induce vomitingbygagging the victim witha finger placed the backof the victim’s tongue. Give fluids until vomitus is clear. If victim is unconscious or convulsing, do not induce vomiting or give anything by mouth. Cancer Information: None listed under OSHNNTPIIARC.

--

TOXICITY DATA

--

Acute oral LDS0 (rats): 7000 mgkg

-

For Product Ames Test: negative E. coli WP 2 UVRA: negative Celltransformation (BALB/3T3) assay: negative CH0 chromosomeaberration assay: negative Mouse lymphoma L51 78Y assay: positive E. coli pol A+/A- assay: indefinite wlwo activation Feeding of large amounts to laboratory animals has been reported to cause mutagenic effects.

Carcinogenicity: The NationalToxicologyProgram(NTP),a coordinating body for federal health agencies, reported its results (1987) ofMBT toxicology and carcinogenicity studies. In the NTP studies, MBT in corn oil was force fed through a stomach tubeto rats and mice for 2 yr. An increased incidence of tumors in a number of tissues was seen in rats. No increase

Chapter 9

502

the incidence of tumors (i.e., no effect) was observed in mice. The strength of the data wasevaluated as "some," "equivocal," "no,"or "inadequate" evidence carcinogenicity. Because only a limited response occurred, NTP interpreted these studies as showing "some" evidence carcinogenicity. The nature of the tumor response (e.g., effect in mice; some effect in rats) and other concernsabout the conductof these studies (e.g., force feedingan amount of MBTthat may have exceeded the maximum tolerable dose) makes it difficult to clearly assess the significance of the results to those who work withMBT.Werecommendthatworkerexposure to MBTshouldbe minimized.

Reproductive Toxicity: Teratology study in rats with mercaptobenzothiazole (MBT) showed negative results. Medical Conditions Generally Aggravated By Exposure: Unknown.

--- REACTIVITY DATA --Stability and Conditions to Avoid: The thermal stability of this material is ratedby the manufacturer as stable. However,theynote:Contactwith strong oxidizing agents will generate heat. Contact with acids will produce toxic sulfur compounds. Materials to Avoid (Incompatibility): Strong oxidants like liquid chlorine, concentrated oxygen, sodium, calcium hypochlorite. Hazard Decomposition Products:Fumes, smoke, carbon monoxide, andsulfur oxides, in the case of incomplete combustion. Hazardous Polymerization: Will not occur.

--- SPILL AND EMERGENCY RESPONSE -For Spills: Recover free liquid. Add absorbent (sand, earth, sawdust, etc.) to spill area. Keep petroleum productsout of sewers and watercourses by diking or impounding.Advise authorities ifproducthas entered may enter sewers, watercourses, or extensive land areas.

Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal site or facility. Wastematerialmaybe incinerated under conditions that meet

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

503

federal, state, and local environmental control regulations. At present this is not classified as a RCRA hazardous waste.

Empty Containers: Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants.

--SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection: Normallynotneeded.Use protection in confined or enclosed spaces.

supplied-air respiratory

Type of Ventilation Required:Use local exhaust to capture fumes and vapors. Provide greater than 60-fpm hood or face velocity for confined spaces. Eye Protection Requirements: contact may occur.

Use splash goggles or face shield when eye

ProtectiveGlovesand Other: Usechemical-resistantgloves to avoid skin contact. Use chemical-resistant apron or other clothing ifneeded to avoid skin contact. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. Note: This product has a l-yr shelf life. Other Precautions: Avoid breathing oil mist. Remove oil-soiled clothing and launder before reuse. Discard oil-soaked shoes. Wash skin thoroughly with soap and water after handling.

--REGULATORY INFORMATION --Transportation Incident Information: For further information relative to spills resulting from transportation incidents, refer to latest Department of TransportationEmergencyResponseGuidebook for Hazardous Materials Incidents, DOT P 5800.3.

DOT Identification Number: Not applicable. T

V

V

V

V

V

V

V

V

V

V

V

V

V

504

Chapter 9

Name: CASTOR OIL Synonyms: Aromatic Caster Oil; Castor Oil Aromatic; Cosmetol; Crystal 0; Gold Bond; NCI-C55163; Neoloid; Oil of Palma Christi; Phorbyol; Ricinus Oil; Ricirus Oil; Tangantangan Oil CAS: 8001-79-4; RTECS: F14100000 Chemical Class: Ester See other identifiers listed below under Regulations.

--PROPERTIES -Boiling Point: 586.16 K; 313°C;595.4"F MeltingPoint: NA Flash Point: > 383.16 K; > 110°C; >230"F Autoignition: NA UEL: NA LEL: NA Vapor Density:No data Specific Gravity: No data Density: 0.961 Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents:No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: Notgiven Packaging exceptions: 173. Nonbulk packaging: 173. Bulk packaging: 173. STCC Number: Notlisted

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

505

Clean Water Act Sect. 307: No Clean Water Act Sect. 311: No Clean Air Act:Not listed EPA Waste Number: None CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant.

U.S. Postal Service Mailability:

Not given

--TOXICITY DATA -Short-term Toxicity: Unknown Long-term Toxicity: Unknown ConcIDLH:

Unknown

NIOSH REL: Not given ACGIH TLV: Not listed ACGIH STEL: Not listed

OSHA PEL: Not in Table Z-l-A MAK Information: Not listed Carcinogen: N; Status: Seebelow Carcinogen Lists: ZARC Not listed; “C Not listed; NZOSH Not listed; MP Not listed; ACGZR Not listed; OSHA: Not listed. LDS0 Value: No LDS0

in RTECS 1992

Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

This chemical has

--INITIAL INCIDENT RESPONSE -No DOT Guide information for this product.

known

506

Chapter

Name: GLYCERIN Synonyms: Glycerol; Glycerin; Glycerin, Anhydrous; Glycerin, Synthetic; Glycerine; Glycyl Alcohol; 1,2,3-Propanetriol; Synthetic Glycerin; 90 Technical Glycerin; Trihydroxypropane;1,2,3-Trihydroxypropane CAS:56-81-5; RTECS: MA8050000 Formula: C3H,0,; Mol Wt: 92.11 WLN: QlYQlQ Chemical Class: Alcohol See other identifiers listed below under Regulations.

--- PROPERTIES --Physical Description: Colorless odorless oily liquid Boiling Point: 455 K; 181.8"C;359.3"F Melting Point: 293 K; 19.8"C;67.7"F Flash Point: 433 K; 159.8"C;319.7"F Autoignition: 643 K; 369.8"C;697.7"F UEL: NA LEL: NA IonizationPotential (eV): 10.51 Vapor Density:No data Specific Gravity: 1.261, 20°C Density: 1.261 Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Not pertinent Odor Description: Odorless(Source:CHRIS) 100% Odor Detection: No data

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

--REGULATIONS -DOT hazard class:Notgiven Packaging exceptions: Nonbulkpackaging: Bulkpackaging: STCC Number: Not listed Clean Water Act 307: No Clean Water Act Sect. 311: No Clean Air Act:Not listed EPA Waste Number: None CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant. Acute toxicity: adverse effect to target organs. Chronic toxicity: mutagen. Chronic toxicity: reproductive toxin.

U.S. Postal Service Mailability:

Not given

NF'PA Codes: Health Hazard (blue): Slightly hazardous to health. Asa precaution, wear self-contained breathing apparatus. Flammability (red): (1) This material must be preheated before ignition can occur. Reactivity (yellow): Stable evenunder fire conditions. Special: Unspecified.

--TOXICITY DATA -Short-term Toxicity: Unknown Long-term Toxicity: Unknown Target Organs: Eyes, respiratory tract Symptoms: No hazard(Source:CHRIS)

Chapter 9

508

Conc IDLH Unknown ACGIHTLV: TLV = 10 mg/m3 as mist ACGIH STEL Not listed OSHA PEL: Transitional Limits: PEL = total dust, 15 mg/m3; respirable fraction, 5 mg/m3; Final Rule Limits: TWA = total dust, 10 mg/m3; respirable fraction, 5 mg/m3. MAK Information: Notlisted Carcinogen: N; Status: See below CarcinogenLists: Z A R C Not listed; M A K Not listed; NZOSH Not listed; NTP: Not listed; ACGZH Not listed; OSHA: Not listed. HumanToxicity Data: (Source: NIOSH RTECS) orl-hmn TDLo:1428 mg/kg 34ZIAG - 288, 69 Behavioral Headache Gastrointestinal Nausea or vomiting

LD50 Value: orl-rat LD50:12600 mg/kg OtherSpeciesToxicityData: orl-rat LD50: 12600mgkg ipr-rat LD50:4420 mg/kg scu-rat LD50: 100mg/kg ivn-rat LD50:5566 mg/kg orl-mus LD50:4090 mglkg ipr-mus LD50:8700 mg/kg scu-mus LD50:91 mg/kg ivn-mus LD50:4250 mg/kg orl-rbt LD50:27 g k g ivn-rbt LD50:53 g/kg orl-gpg LD50:7750 mg/kg ReproductiveToxicity reproductive toxin.

(Source:NIOSHRTECS1992)

(1992 RTECS): This chemicalisamammalian

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

509

Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo:100 mg/kg (ID male) TGANAK 19, 436, 85 Effects on Fertility Postimplantation mortality itt-rat TDLo:280 mgkg (2D male) CCPTAY 29, 291, 84 Paternal Effects Spermatogenesis Testes, epididymis, sperm duct itt-rat TDLo:1600 mgkg (1D male) CCPTAY 29, 291, 84 Effects on Fertility Male fertility index itt-rat TDLo:862 mgkg (1D male) LIFSAK 34, 1747, 84 PaternalEffects Spermatogenesis

--PROTECTION AND FIRST AID -Protection Suggested from the CHRIS Manual: FirstAidSource: No hazard

Rubber gloves, goggles.

CHRISManual 1991.

--INITIAL INCIDENT RESPONSE -Fire Extinguishment: Alcohol foam, dry chemical, carbon dioxide, water fog. Nore: Water or foam may cause frothing. (CHRIS 91) No DOT Guide information for this product.

- IDENTIFIERS -Chemical Name and Synonyms: EPOXIDIZED SOYBEAN Trade Name and Synonyms: ChemicalFamily:

Epoxies

Drapex 6.8

OIL

Chapter 9

510

Manufacturer: ArgusChemicalCorp.,Brooklyn,NewYork UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA --Material

No. Cas

Product (proprietary) Not

%

NA

TLV established

--PHYSICAL DATA -Boiling Point (“F‘): Not distillable = 1): 0.992

SpecificGravity

VaporPressure(mm Hg): < 1 PercentVolatile byVolume (%): <0.1 VaporDensity (air = 1): NA FreezingPoint:

NA

EvaporationRate:

pH. NA Solubility inWater:

Negligible

Melting PointPour or Congealing Point: NA Viscosity: NA Appearance/Color/Odor: Almost colorless liquid with a faint fatty acid odor.

--FIRE AND EXPLOSION HAZARDS --Flash Point: 575°F (COC) FlammabilityLimits: NA

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

AutoignitionTemperature:

511

NA

Extinguishing Media: Foam, dry chemical, carbon dioxide, or water fog or spray. SpecialFireFightingProcedures: UseNIOSH-approved positive-pressure self-contained respirator and protective clothing. Unusual Fire and Explosion Hazards: When exposed to flame, emits acrid fumes. Dust may form explosive mixture with air. Hazardous Products of Combustion and Decomposition: None reported by manufacturer. Hazardous Polymerization:

Will not

occur.

--- HEALTH HAZARD DATA --Effects of Overexposure: No effects fromoverexposure reported by the manufacturer. This product has been cleared by FDA under Section 181.22 of the “Food Additives Regulations.” Emergency Response and First Aid: Skin: Flush all affected areas with plenty of water for 15 min. Remove and clean anycontaminated clothing and shoes. Seekmedical attention if skin irritation occurs. Eyes: Flush eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: There are no effects or recommendations reported. Ingestion: Consultphysicianimmediately. Cancer Information: None listed under OSHA/NTP/IARC.

-No information reported.

TOXICITY DATA

---

Chapter 9

512

--REACTIVITY DATA -Stability and Conditions to Avoid: Manufacturer recommends pumping this product at Use low-pressure steam to avoid hot spots that might cause polymerization. Materials to Avoid (Incompatibility): Strong acids and excessive heat. HazardDecompositionProducts: Fumes,smoke,carbonmonoxide,and carbon dioxide, in the case of incomplete combustion. Hazardous Polymerization: Will not occur except above 40°C.

--

SPILL AND EMERGENCY RESPONSE

--

For Spills: Use any inert absorbent such as sand, earth, or vermiculite. The product is described as being slippery. Use proper safety equipment during cleanup. Disposeofinamannerthat is consistent with local, state, and federal regulations. Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal site facility. Waste material may be incinerated under conditions thatmeet federal, state, and local environmental control regulations. At present this is not classified as a RCRA hazardous waste. Empty Containers: Keep containers closed when not in use. Do not handle store heat, sparks, flame, or strong oxidants.

--- SPECIAL PROTECTION AND PRECAUTIONS --RespiratoryProtection: Normallynotneeded.Use protection in confined or enclosed spaces.

supplied-air respiratory

Type of Ventilation Required: Use local exhaustto capture fumes andvapors. Provide greater than 60-fpm hood or face velocity for confined spaces. EyeProtectionRequirements: contact may occur.

Use splash goggles or faceshield wheneye

ProtectiveGlovesandOther: chemical goggles.

Useneoprene gloves, neoprene apron, and

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

513

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. Note: This product has a 1-yr shelf life. Other Precautions: Avoid breathing oil mist. Remove oil-soiled clothing and launder before reuse. Discard oil-soaked shoes. Wash skin thoroughly with soap and water after handling.

--REGULATORY INFORMATION --Transportation Incident Information: This product is unregulated by DOT at present. DOT Identification Number: Not applicable.

--IDENTIF'IERS -Name: HEPTANE Synonyms: DipropylMethane;Eptani (Italian); Heptan (Polish); n-Heptane; Heptane(DOT);Heptanen (Dutch); HeptylHydride;DipropalMethane; Neptanen (Dutch); Normal Heptane CAS: 142-82-5; RTECS: MI7700000 Formula: C7HI6;MolWt: 100.23 WLN: 7H ChemicalClass: Paraffin See other identifiers listed below under Regulations.

--PROPERTIES -Physical Description: Colorless watery liquid with a gasolinelike odor Boiling Point: 371.49 K; 98.3"C; 209°F MeltingPoint: 182.04 K; -91.2"C;-132°F FlashPoint: 269.1 K; -4.1"C;24.7"F Autoignition: 495 K;221.8"C;431.3"F Critical Temp: 540 K; 266.85"C;512.33"F Critical Press: 2.7 kN/m*; 26.6 atm; 391 psia

5 14

Chapter

Heat of Vap: 136.1 Btu/lb; 75.58 cal/g; 3 . 1 6 2 ~E5 J/kg Heat of Comb: -19,170 Btu/lb; -10,658 cal/g; -446x E5 J/kg Vapor Pressure: 40 mm at 22.3 UEL: 6.7% LEL: 1.1% IonizationPotential (eV): 9.90 Vapor Density: No data Evaporation Rate: 3.18 (n-butyl acetate = Specific Gravity: 0.6838 at20°C Density: 0.684 Water Solubility: % Incompatibilities: Strong oxidizers Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (pprn): 220 ppm Odor Description: Gasoline(Source:CHRIS) 100% Odor Detection: 200 ppm

--- REGULATIONS --DOT hazard class: 3 FLAMMABLE LIQUID DOT guide: 27 Identificationnumber: UN1206 DOT shipping name: Heptanes Packinggroup: I1 Label(s)required: FLAMMABLELIQUID Special Provisions: 72 Packaging exceptions: 173.150 Nonbulk packaging: 173.202 Bulkpackaging: 173.242 Quantity limitations: Passenger airlrail: 5 L Cargo aircraft only: 60 L Vesselstowage: B STCCNumber:

4909190

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

515

CleanWaterActSect. 307: No CleanWaterActSect.311: No CleanAirAct: Not listed EPAWasteNumber: DO01 CERCLA Ref: N RQDesignation: Not listed SARA TPQValue: Not listed SARA Sect. 312 Categories: Fire hazard: flammable. U.S. Postal Service Mailability: Hazardclass:Flammable liquid; mailable as ORM-D Mailability: Domestic surface mailonly Maxper parcel: 1 qt metal; 1 pt other

NFPA Codes: HealthHazard(blue): (1) Slightly hazardous to health. Asa precaution wear self-contained breathing apparatus. Flammability(red): Thismaterialcanbe ignited underalmost all temperature conditions. Reactivity (yellow): Stable evenunder fire conditions. Special: Unspecified.

--- TOXICITY DATA --Short-termToxicity: Lightheadedness, giddy, stupor, no appetite, nausea, dermatitis, chemical pneumonia and unconsciousness. Long-term Toxicity: Paralysis by high concentrations. Symptoms: Inhalation: Irritation of respiratory tract, coughing, depression, cardiac arrhythmias. Aspiration: Severelung irritation, pulmonaryedema,mildexcitement followed by depression. Ingestion: Nausea,vomiting, swelling of abdomen, depression, headache. (Source: CHRIS) Conc IDLH

ppm

516

Chapter

NIOSH REL: 85 ppm time-weighted averages for 8-hr exposure; 350 mg/m3 time-weighted averages for 8-hr exposure; 440 ppm ceiling exposures which shall at no time be exceeded or 1800 mg/m3 ceiling exposures which shall at no time be exceeded. ACGIH TLV: TLV = 400 ppm (1600 mg/m3) ACGIH STEL: STEL = ppm (2000 mg/m3)

OSHA PEL: Transitional Limits: PEL = 500 ppm (2000 mg/m3); Final Rule Limits: TWA = 400 ppm (1600 mg/m3); STEL = 500 ppm (2000 mg/m3) MAK Information: ppm; 5 min, 8 times per shift.

mg/m3; local irritant: peak = 2xMAK for

Carcinogen: N; Status: Seebelow CarcinogenLists: ZARC: Not listed; M A K Not listed; NZOSH: Not listed; MP Not listed; ACGZH Not listed; OSHA: Not listed. Human ToxicityData: (Source: NIOSH RTECS) ihl-hmn TCb:lOOO ppm/6M BMRII* 2979, - , 29 Behavioral Hallucinations, distorted perceptions LDS0 Value: No LD50 in RTECS 1992 OtherSpeciesToxicityData: ihl-mus LC50:75 g/m3/2H ivn-mus LD50:222 mg/kg

(Source:NIOSHRTECS1992)

Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

This chemical has no known

--PROTECTION AND FIRST AID --ProtectionSuggestedfromthe similar to gasoline.

CHRIS Manual: Safety glasses; gloves;

NIOSH Pocket Guide to Chemical Hazards: **WearAppropriate Equipment to Prevent: Repeated or prolonged skin contact.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

517

**Wear Eye Protection to Prevent: Reasonable probability of eye contact. **Exposed Personnel Should Wash:

Promptly when skin becomes wet.

**Remove Clothing: Immediately remove any clothing that becomes wet to avoid any flammability. **Reference: NIOSH Recommended Respiration Protection Source: NIOSH Pocket Guide(85-1 14) NIOSH (Heptane) 850ppm: Any chemical cartridge respirator with organic vapor cartridge@). Any supplied-air respirator. Any self-contained breathing apparatus. I O 0 0 pprn: Anypowered air-purifying respirator withorganicvapor cartridge(s). Anychemical cartridge respirator witha full facepiece and organic vapor cartridge(s). 2125 ppm: Any supplied-air respirator operated in a continuous-flow mode. 425Oppm: Any air-purifying full facepiece respirator (gas mask) with achinstyle or front- or back-mountedorganicvapor canister. Any supplied-air respirator with afull facepiece. Any supplied-air respirator with atight-fitting facepiece operated in a continuous-flow mode. Emergency or Planned Entry in Unknown Concentrations or IDLH Conditions: Any self-contained breathing apparatus with a full facepiece and operated in a pressuredemandor other positive-pressure mode. Any supplied-air respirator with a full facepiece and operated in a pressure-demand or other positive-pressure mode in combinationwithan auxiliary self-contained breathing apparatus operated in a pressure-demand or other positive-pressure mode. Escape: Any air-purifying full facepiece respirator (gas mask) with a chinstyle or front- or back-mountedorganicvapor canister. Any appropriate escape-type self-contained breathing apparatus. First AidSource: CHRISManual1991. Inhalation: Maintain respiration; give oxygen if needed. Aspiration: Enforce bed rest; administer oxygen. Ingestion: Do nor induce vomiting. Skin or Eyes: Remove contaminated clothing, wipe and wash skin area with soap and water; wash eyes with plenty of water. First AidSource: DOTEmergencyResponseGuide1993. Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of

518

Chapter 9

contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

--- INITIAL INCIDENT RESPONSE --FireExtinguishment: Foam,dry chemical, carbon dioxide. (CHRIS 91) U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT DOTShippingName: Heptanes DOT ID Number: UN1206 ERG90

* POTENTIAL HAZARDS *

GUIDE 27

*Health Hazards May be poisonous if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact may imitate or bum skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution.

*Fire or Explosion Flammable/combustible material; may be ignited by heat, sparks, or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors, or in sewers. Runoff to sewer may create fire or explosion hazard.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car, or tank truck is involved in fire. CALLCHEMTRECAT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

519

*Fire Smallfires: Dry chemical, COz, water spray, or regular foam. Largepres: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. For massive fire in cargoarea, use unmanned hose holderor monitor nozzles; if this is impossible, withdraw from area and let fire bum. Withdraw immediately in case of rising sound of ventingsafety device or any discoloration of tank due to fire. *Spill or Leak Shut off ignition sources; flares, smoking, or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapor; but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. *First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

--IDENTIFERS --Name: n-HEXANE Synonyms: Esani (Italian); Heksan (Polish); n-Hexane;N-Hexane;Hexane (DOT); Hexanen (Dutch); NCLC60571;HexylHydride;NormalHexane; Hexanen (Dutch) CAS: 110-54-3; RTECS: MN9275000 Formula: C,H,,; Mol Wt: 86.17 WLN: 6H ChemicalClass: Paraffin See other identifiers listed below under Regulations.

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520

--PROPERTIES -Physical Description: Colorless liquid with a mild gasolinelike odor Boiling Point: 342.04 K;68.8"C; 156°F Melting Point: 178.16 K;-95°C;-139°F Flash Point: 250 K;-23.2"C; -9.7"F Autoignition: 498 K;224.8"C; 436.7"F Critical Temp: 507.4 K;234.25"C; 453.65"F Critical Press: 3.01 kN/m2; 29.6 atm; 436 psia Heat of Vap: 144 Btu/lb; 79.97 cal/g; 3.346~E5 J/kg Heat of Comb: -19,246Btu/lb; cal/g; -447x E5 J k g Vapor Pressure: 124 mm UEL: 7.5% LEL: 1.1% IonizationPotential(ev): 10.18 Vapor Density: 3.0 (air = 1) Evaporation Rate: 6.82 (n-butyl acetate = 1) Specific Gravity: 0.659 at 20°C Density: 0.659 Water Solubility: 0.014% Incompatibilities: Strong oxidizers Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents:No data Polymerization Possibilities: No data Toxic Fire None reported other than possible unburned vapors Odor Detected at (ppm): 130 ppm Odor Description:Mild, gasolinelike (Source:NYDH) 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: 3 FLAMMABLE LIQUID DOT guide: 27 Identificationnumber: UN1208 DOT shipping name: HEXANES Packinggroup: I1 Label(s)required: FLAMMABLELIQUID Special Provisions: T8

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52 1

Packagingexceptions:173.150 Nonbulkpackaging: 173.202 Bulkpackaging: 173.242 Quantity limitations: Passenger airhail: 5 L Cargo aircraft only: 60 L Vesselstowage: E STCCNumber:4908183 CleanWaterAct Sect. 307: No CleanWaterAct Sect. 311: No Clean Air Act: CAA '90 listed EPAWasteNumber: DO01 CERCLA Ref: Not listed RQDesignation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant. Acute toxicity: adverse effect to target organs. Chronic toxicity: mutagen. Chronic toxicity: reproductive toxin. Fire hazard: flammable. U.S. Postal Service Mailability: Hazard class: Flammable liquid - mailable as ORM-D Mailability: Domestic surface mailonly Max per parcel: 1 qt metal; 1 pt other

NFPA Codes: HealthHazard(blue): (1) Slightly hazardous health. Asaprecaution wear self-contained breathing apparatus. Flammability(red): (3) Thismaterialcanbe ignited underalmost all temperature conditions. Reactivity(yellow): Stable evenunder fire conditions. Special: Unspecified.

--- TOXICITY DATA --Short-termToxicity: Inhalation: Exposure to levels above 500 ppm may causeheadache,abdominalcramps,aburning feeling of the face, and numbness and weakness ofthe fingers and toes. Levels above 1300 ppm may

Chapter 9 cause the above plus nauseaand irritation of the noseand throat. Levels above 1500 ppm may cause the above plus blurred vision, loss of appetite, and loss ofweight.Mostsymptoms disappear withinafewmonthsif exposureceases.Breathing liquid into the lungs may causeachemical pneumonia. Skin: Contact may cause irritation, redness, swelling, blisters, and pain. Skin exposure may contribute to symptoms listed under inhalation. Eyes: Levels over 880 ppm may cause irritation. Ingestion: May contribute to symptoms listed under inhalation. Estimated lethal dose is 1 to 1 pt. (NYDH)

Long-term Toxicity: May cause symptoms listed under inhalation. Exposure to levels above 650 ppm for 2 to 4 monthscan result inweaknessand numbness of the and legs. Symptoms go away within a few months if exposure stops. (NYDH) TargetOrgans: Eyes, respiratory system Symptoms: Inhalation: Causes irritation of respiratory tract, cough, mild depression, and cardiac arrhythmias. Aspiration: Causes severe lung irritation, coughing,pulmonaryedema; excitement followed by depression. Ingestion: Causes nausea, vomiting, swelling of abdomen, headache, depression. (Source: CHRIS)

Conc IDLH

ppm

NIOSH REL: 100 ppm time-weighted averages for 8-hr exposure; 350 mg/m3 time-weighted averages for 8-hr exposure ACGIH TLV: TLV = ACGIHSTEL: STEL =

ppm ppm

OSHA PEL: Final Rule Limits: TWA = 500 ppm(1800mg/m3);STEL 1000 ppm (3600 mg/m3)

=

MAK Information: 50 ppm; 180 mg/m3 Substance with systemic effects, onset of effect less than or equal to 2 hr: Peak = 2xMAK for 30 min, 4 times per shift of 8 hr. There is no reason fear a risk of damage to the developing embryo or fetus when MAK values are adhered to.

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Carcinogen: N; Status: Seebelow CarcinogenLists: IARC Not listed; "C Not listed; NZOSH Not listed; hTP Not listed; ACGZH Not listed; OSHA: Not listed. HumanToxicityData: (Source: NIOSH RTECS) ihl-hmn TCLo: 190 ppm/8W AJIMD8 10, 111, 86 Peripheral Nerve and Sensation Structural change in nerve or sheath LDS0Value: orl-rat LD50:28710 mg/kg OtherSpeciesToxicityData: orl-rat LD50:28710 mg/kg ipr-rat LDLo:9100 mg/kg ihl-mus LCLo: 120 g/m3 ivn-mus LDLo:831 mg/kg ivn-rbt LDLo: 132 mg/kg

(Source:NIOSHRTECS1992)

IrritationData: (Source: NIOSHRTECS 1992) eye-hmn 5 ppm ReproductiveToxicity reproductive toxin.

(1992 RTECS):

This chemical is amammalian

Reproductive Toxicity Data (1992 RTECS): ihl-rat TCLo:lOOOO ppm/7H (15D pre/l-l8D preg) TOXID9 1, 152, 81 Effects Newborn Behavioral ihl-rat TCLo:lOOO ppm/6H (8-16D preg) TJADAB 19, 22A, 79 Effects Newborn Growth statistics (e.g., reduced weight gain) ihl-rat TCLo:5000 ppm/20H (6-19D preg) NTIS** DE88-006812 Effects Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) ihl-rat TCLo:l pph/6H (65D male) FAATDF 4, 191, 84 Paternal Effects Testes, epididymis, sperm duct

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524

ihl-rat TCL0:l pph/6H (65D male) FAATDF 4, 191, 84 Paternal Effects Testes, epididymis, sperm duct

- PROTECTION AND FIRST AID -ProtectionSuggestedfromtheCHRISManual: gasoline).

Eyeprotection

(as for

NIOSH Pocket Guide to Chemical Hazards: **Wear Appropriate Equipment to Prevent: Repeated or prolonged skin contact.

**WearEye Protection to Prevent: Reasonable probability of eye contact. **Exposed Personnel Should Wash:

Promptly when skin becomes wet.

**Remove Clothing: Immediately remove any clothing that becomes wet to avoid any flammability. **Reference: NIOSH Recommended Respiration Protection Source:NIOSH Pocket Guide(85-1 14) NIOSH @-Hexane) I O 0 0 ppm: Any supplied-air respirator. Any self-containedbreathing apparatus. Substance reported to cause eye irritation damage may require eye protection. 2500ppm: Any supplied-air respirator operated in a continuous-flow mode. Substancereportedtocauseeye irritation or damage may require eye protection. 5 W p p m : Any self-contained breathing apparatus witha full facepiece. Any supplied-air respirator with a full facepiece. Emergency or Planned Entry in Unknown Concentrations or IDLH Conditions: Any self-contained breathing apparatus with a full facepiece and operated in a pressure-demand other positive-pressure mode. Any supplied-air respirator with a full facepiece and operated in a pressure-demand other positive-pressuremodeincombinationwithanauxiliaryself-contained breathing apparatus operatedin a pressure-demand or other positive-pressure mode. Escape: Any air-purifying full facepiece respirator (gas mask) with a chinstyle or frontback-mounted organic vaporcanister. Any appropriate escape-type self-contained breathing apparatus.

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First AidSource: CHRISManual1991. Call a doctor. Inhalation: Maintain respiration; give oxygen if needed. Aspiration: Enforce bed rest; give oxygen if needed. Ingestion: Do not induce vomiting. Skin or Eyes: Wipe off; wash skin withsoapandwater;washeyeswith copious amounts of water.

First AidSource: DOTEmergencyResponseGuide1993. Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

- INITIAL INCIDENT RESPONSE -FireExtinguishment: Foam,dry chemical, carbon dioxide. (CHRIS 91) U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT ShippingName: Hexanes DOT ID Number: UN1208 ERG90

* POTENTIAL HAZARDS *

GUIDE 27

*Health Hazards May be poisonous if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact may irritate or bum skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Flammablekombustible material; may be ignited by heat, sparks, or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors, or in sewers. Runoff to sewer may create fire or explosion hazard.

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* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection. Isolate for 112 mile in all directions if tank, rail car, or tank truck is involved in fire. CALLCHEMTRECAT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Smallfires: Dry chemical, COz, water spray, or regular foam. Large fires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargoarea, use unmanned hose holderor monitor nozzles; if this is impossible, withdraw from area and let fire bum. Withdraw immediately in case ofrising sound of venting safety device or any discoloration of tank due to fire. *Spill or Leak Shut off ignition sources; flares, smoking, or flames in hazard area. Stop leak if you can do it without risk. Water spray mayreducevapor;but it maynot prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. *First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

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--IDENTIF'IERS -Name: ISOPROPYLALCOHOL Synonyms: Alcool Isopropilico (Italian); Alcool Isopropylique (French); Avantine; Dimethylcarbinol; Isohol; Isopropanol; Iso-Propylalkohol (German); Lutosol; Petrohol; Propropan-2-01;2-Propanol; i-Propanol (German);secPropyl Alcohol; i-Propylalkohol CAS:67-63-0; RTECS: NT8050000 Formula: C,H,O; Mol Wt: 60.11 WLN: QYl Chemical Class: Alcohol See other identifiers listed below under Regulations.

--- PROPERTIES -Physical Description: Colorless liquid with a sweet odor Boiling Point: 355.65K;82.5"C;180.5"F Melting Point: 184.27K;-88.9"C;-128°F Flash Point: 294.15 K;21°C;69.8"F Autoignition: 672.15K;399°C;750.2"F Vapor Pressure: 89.26 mm at 56.77"C UEL: 12.7% LEL: 2.3% IonizationPotential (ev): 10.15 Vapor Density: 2.07 (air = 1) Evaporation Rate: 1.70 (n-butyl acetate = Specific Gravity: 0.785 at 20°C Density: 0.785 Water Solubility: Miscible Incompatibilities: Keep away from heat and open flame; reacts vigorously with oxidizing materials. Reactivity with Water: No data on water reactivity Reactivity with Common Materials:Reacts violently with Nitroform, Oleum, Phosgene, Potassium, Tert-Butoxide, Aluminum, A1 Triisopropoxide, Crotonaldehyde,Oxidants(Source:SAX) Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data

Chapter Toxic Fire Gases: NA Odor Detected at (ppm): 90 mg/m#L3 Odor Description: Nonresidual(Source:CHRIS) 100% Odor Detection: No data

--

REGULATIONS

--

DOT hazard class: 3 FLAMMABLE LIQUID DOT guide: 26 Identificationnumber: UN1219 DOT shipping name: Isopropanol or isopropyl alcohol Packinggroup: I1 Label(s)required: FLAMMABLELIQUID SpecialProvisions: T1 Packaging exceptions: Nonbulkpackaging: Bulkpackaging: Quantity limitations: Passenger airhail: 5 L Cargo aircraft only: 60L Vesselstowage: B

STCC Number: Clean Water Act Sect. 307: No Clean Water ActSect. 311: No Clean Air Act: Not listed EPA Waste Number: None CERCLA Ref: N RQ Designation: Notlisted SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant. Acute toxicity: adverse effect to target organs. Chronic toxicity: mutagen. Chronic toxicity: reproductive toxin. Fire hazard: flammable. Listed in SARA Sect 313: Yes De Minimus Concentration: 0.1 %

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529

U.S. Postal Service Mailability: Hazard class: Flammable liquid - mailable as ORM-D Mailability: Domestic surface mailonly Maxper parcel: 1 qt metal; 1 pt other

NFPA Codes: HealthHazard (blue): (1) Slightly hazardous to health. Asaprecaution wear self-contained breathing apparatus. Flammability(red): Thismaterialcanbe ignited underalmost all temperature conditions. Reactivity (yellow): Stable evenunder fire conditions. Special: Unspecified.

--TOXICITY DATA --Short-term Toxicity: Inhalation: Irritation of the nose and throat may occur at 400 ppm and above. Skin: 5% solution may cause irritation and dryness. Eyes: Vapor levels of 20 ppm or above may result in irritation. Liquid may cause corneal bums and eye damage. Ingestion: 22.5 02) has caused salivation, reddening of face, stomach pain, depression, dizziness, headache, vomiting, and unconsciousness. Ingestion of (3 oz) has caused death. (NYDH) Long-termToxicity: No reported long-termexposure effects. (NYDH) Target Organs: Eyes, skin, respiratory system Symptoms: Vapors cause mild irritation of eyes and upper respiratory tract; high concentrations may be anesthetic. Liquid irritates eyes and may cause injury; harmless to skin; if ingested, causesdrunkennessandvomiting. (Source: CHRIS) ConcIDLH:

12,000ppm

NOSH REL: 400 ppm time-weighted averages for 8-hr exposure; 984 mg/m3 time-weighted averages for 8-hr exposure; 800 ppm ceiling exposures, which shall at time be exceeded or 1968 mg/m3ceiling exposures, which shall at time be exceeded ACGIH TLV: TLV = 400 ppm (980 mg/m3) ACGIH STEL: STEL = ppm (1225 mg/m3)

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Chapter 9

OSHA PEL: Transitional Limits: PEL = 400ppm (980 mg/m3; Final Rule Limits: TWA = 400 ppm (980 mg/m3); STEL = 500 ppm (1225 mg/m3) MAK Information: 400 ppm; mg/m3 Substance with systemic effects, onset of effect less than or equal to 2 hr: Peak = 2xMAK for 30 min, 4 times per shift of 8 hr. Carcinogen: N; Status: Seebelow References: Human suspected IARC** 15,223,77;Animal indefinite IARC** 15, 223, 77 CarcinogenLists: ZARC: Not classified as to human carcinogenicity or probably not carcinogenic to humans; MAK. Not listed; NZOSH Not listed; NTP: Not listed; ACGZH Not listed; OSHA: Not listed. HumanToxicityData: (Source:NIOSHRTECS) orl-man TDLo:14432 mg/kg NEJMAG 277, 699, 67 Behavioral Coma Vascular BP lowering not characterized in autonomic section Lungs, Thorax, or Respiration Dyspnea orl-hmn TDLo:223 mg/kg JLCMAK 12, 326, 27 Behavioral Hallucinations, distorted perceptions Cardiac Pulse rate decreased with fall in BP Vascular BP lowering not characterized in autonomic section orl-man LDLo5272 mglkg AJCPAI 38, 144, 62 Behavioral Coma Vascular BP lowering not characterized in autonomic section. Lungs, Thorax, or Respiration Chronic pulmonary edema or congestion

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents orl-hmn LDLo:3570 mg/kg 34ZIAG -,339, 69 Behavioral Coma Lungs, Thorax, or Respiration Respiratory depression Gastrointestinal Nausea or vomiting

LD50 Value: orl-rat LD50:5045 mg/kg OtherSpeciesToxicityData: (Source: NIOSHRTECS1992) orl-rat LD50:5045 mg/kg ihl-rat LCLo: 16000 ppm/4H ipr-rat LD50:2735 mg/kg ivn-rat LD50: 1088 mg/kg orl-mus LD50:3600 mg/kg ihl-mus LCLo: 12800 ppm/3H ipr-mus LD50:4477 mg/kg scu-mus LDLo:6 g/kg ivn-mus LD50: 1509 mg/kg orl-dog LDLo: 1537 mg/kg ivn-dog LDLo: 1024 mg/kg ivn-cat LDLo: 1963 mg/kg orl-rbt LD50:6410 mg/kg skn-rbt LD50: 12800 mg/kg ipr-rbt LD50:667 mg/kg ivn-rbt LD50: 1184 mg/kg ipr-gpg LD50:2560 mg/kg ipr-ham LD50:3444 mg/kg par-frg LDLo:20 g/kg scu-mam LDLo:6 mgkg ReproductiveToxicity(1992RTECS): reproductive toxin.

Thischemicalisamammalian

Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo:11340 mg/kg (45D pre) GISAAA 43(1), 8, 78 Maternal Effects Menstrual cycle changes or disorders

53 1

532

Chapter 9

orl-rat TDLo:5040 mgkg (1-20D preg) GISAAA 43(1), 8, 78 Effects on Fertility Litter size (number of fetuses per litter; measured before birth) orl-rat TDLo:20160 mg/kg (1-20D preg) GISAAA 43(1), 8, 78 Effects on Fertility Preimplantation mortality orl-rat TDLo:32400 mgkg (26W pre) GISAAA 43(1), 8, 78 Effects on Embryo or Fetus Fetal death orl-rat TDLo:6480 mg/kg (26W male/26W pre) GISAAA 43(1), 8, 78 Effects on Newborn Growth statistics (e.g., reduced weight gain) ihl-rat TCLo:3500 ppm/7H (1-19D preg) FCTOD7 26, 247, 88 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) ihl-rat TCLo:lOOOO ppm/7H (1-19D preg) FCTOD7 26, 247, 88 Effects on Fertility Preimplantation mortality Postimplantation mortality Effects on Embryo or Fetus Fetal death

--PROTECTION AND FIRST AID -Protection Suggested from the CHRIS Manual: Organic vapor canister or air-supplied mask; chemical goggles or face splash shield.

NOSH Pocket Guide to Chemical Hazards: **Wear Appropriate Equipment to Prevent: Repeated or prolonged skin contact. **Wear Eye Protectionto Prevent: Reasonable probability of eye contact. Personnel Should Wash: Promptly when skin becomes wet.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

**Remove Clothing: Immediately remove any clothing that becomes wet to avoid any flammability. **Reference: NIOSH Recommended Respiration Protection Source:NIOSH Pocket Guide(85-1 NIOSH (Isopropyl Alcohol) 1OOO ppm: Any powered air-purifying respirator withorganicvapor cartridge(s). Substancecauseseye irritation or damage;eye protection needed. Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). 10,000ppm: Any supplied-air respirator operated in a continuous-flow mode. Substance causes eye irritation or damage; eye protection needed. 20,OOO ppm: Any air-purifying full facepiece respirator (gas mask) with a chin-style or front- or back-mountedorganicvapor canister. Any selfcontained breathing apparatus witha full facepiece.Any supplied-air respirator with a full facepiece. Emergency or Planned Ently in Unknown Concentrations or IDLH Conditions: Any self-contained breathing apparatus with a full facepiece and operated in pressure-demand a or other positive-pressure mode. Any supplied-air respirator with a full facepiece and operated in a pressure-demand or other positive-pressure mode in combinationwith an auxiliary self-contained breathing apparatus operated in a pressure-demand or other positive-pressure mode. Escape: Any air-purifying full facepiece respirator (gas mask) with a chinstyle or front- or back-mountedorganicvapor canister. Any appropriate escape-type self-contained breathing apparatus. FirstAidSource: CHRISManual Inhalation: If victim is overcomeby vapors, removefromexposure immediately; call a physician; if breathing is irregular or has stopped, start resuscitation and administer oxygen. Eyes: Flush with water for at least 15 min. First Aid Source: DOT EmergencyResponseGuide Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

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Chapter 9

--- INITIAL INCIDENT RESPONSE --FireExtinguishment: Alcoholfoam,dry chemical, carbon dioxide. Note: Water may be ineffective. (CHRIS 91) U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT Shipping Name: Isopropanol or isopropyl alcohol DOT ID Number: UN1219 ERG90

* POTENTIAL HAZARDS *

26

*Health Hazards May be poisonous if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Flammable/combustible material; may be ignited by heat, sparks, or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors, or in sewers. Runoff to sewer may create fire or explosion hazard.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car, or tank truck is involved in fire. CALLCHEMTRECAT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Smallfires: Dry chemical, CO, or Halon, water spray, or alcohol-resistant foam.

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535

Large pres: Water spray, fog, or alcohol-resistant foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargoarea, use unmanned hose holderor monitor nozzles; if this is impossible, withdraw from area and let fire bum. Withdraw immediately in case of rising sound of venting safety deviceor any discoloration of tank due to fire. *Spill or Leak Shut off ignition sources; flares, smoking, or flames in hazard area. Stop leak if you can do it without risk. Water spray mayreducevapor;but it may not prevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal.

*First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

Name: METHANOL Synonyms: Alcool Methylique (French); Alcool Metilico (Italian); Carbinol; Colonial Spirit; Columbian Spirit; Columbian Spirits (DOT); Methanol (DOT); Metanolo (Italian); Methyl Alcohol; Methyl Alcohol (DOT); Methylol; Methylalkohol (German); Methyl Hydroxide; Metylowy Alkohol (Polish); Monohydroxymethane;Pyroxylic Spirit; WoodAlcohol;Wood Naphtha; Wood Spirit CAS:67-56-1; RTECS: PC1400000 Formula: CH,O; Mol Wt: WLN: Q1 ChemicalClass: Alcohol See other identifiers listed below under Regulations.

536

Chapter 9

--PROPERTIES -Physical Description: Clear, colorless, flammable, poisonous liquid withslight alcoholic odor Boiling Point: 337.65 K; 64.5"C;148.1"F Melting Point: 175.38 K; -97.8"C;-144°F Flash Point: 288.65 K; 15.5"C;59.9"F Autoignition: 737.15 K;464°C;867.2"F Vapor Pressure: 92 mm at20°C UEL: 36.5% LEL:6.0% IonizationPotential (ev): 10.84 Vapor Density: 1.l1 (air = 1) Evaporation Rate: 2.10(n-butylacetate = 1) Specific Gravity: 0.792 at20°C Density: 0.7915 g/ml at20°C Water Solubility: Miscible Incompatibilities: Strongoxidizers Reactivity with Water: No data on water reactivity Reactivity with CommonMaterials: Oxidizingmaterials(Source:SAX) Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases:Nonereported other thanpossibleunburnedvapors Odor Detected at (ppm): ppm Odor Description: Faintlysweet; characteristic, pungent(Source:CHRIS) 100% Odor Detection: No data

--REGULATIONS -lIOT hazard class: 3 FLAMMABLE LIQUID 1IOT guide: 28 I:dentification number: UN 1230 IIOT shipping name: Methanol or methyl alcohol I'acking group: I1 I,abet($ required: FLAMMABLELIQUID, POISON Cipecial Provisions: T8 I?ackaging exceptions: 173.None rVonbulk packaging: 173.202 13ulk packaging: 173.243

'

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

537

Quantity limitations: Passenger airhail: 1 L Cargo aircraft only: 60 L Vesselstowage:B Otherstowage provisions: 40 STCCNumber:

4909230

Clean Water ActSect. 307: No Clean Water Act Sect. 311: No Clean Air Act:CAA listed EPA WasteNumber: U154 CERCLARef: Y RQ Designation: D lb (2270 kg)CERCLA SARA TPQ Value:Not listed SARA Sect. 312 Categories: Acute toxicity: irritant. Acute toxicity: adverse effect to target organs. Chronic toxicity: mutagen. Chronic toxicity: reproductive toxin. Fire hazard: flammable. Listed in SARA Sect 313: Yes De Minimus Concentration: 1 .O%

U.S. Postal Service Mailability: Hazardclass:Flammable liquid - mailable as ORM-D Mailability: Domestic service and air transportation Max per parcel: 1 qt metal; 1 pt other NFPA Codes: Health Hazard (blue): (1) Slightly hazardous to health. As a precaution wear self-contained breathing apparatus. Flammability (red): (3) Thismaterialcanbeignitedunderalmost all temperature conditions. Reactivity (yellow): Stable evenunder fire conditions. Special: Unspecified.

--TOXICITY DATA -Short-term Toxicity: Inhalation: Below 500 ppm, symptoms are rarely felt. Can cause headache, vomiting,irritation of the nose andthroat, dilation of the pupils, feeling of intoxication, loss muscle coordination, excessive

538

Chapter 9

sweating, bronchitis, and convulsions. Veryhighexposuresmay result in stupor, cramps and visual difficulties such as spotted vision, sensitivity to light, eye tenderness, and blindness. Recovery is not always complete and symptoms may recur without additional exposure. Skin: Can cause dry and cracked skin irritation and reddening. Skin absorption canbeenough to contribute to symptoms described under inhalation. Eyes: Can cause irritation of eye. Zngesrion: Symptoms are similar to those under inhalation, plus damage to liver, kidneys, and heart. Nerve damage may occur causing loss of coordination and blindness. Recovery is not always complete. Death may occur. Usual fatal dose is about to 250 but death from ingestion (about 1 02). (NYDH) has occurred from as little as 30

Long-term Toxicity: Exposure to low levels may cause many of the symptoms listed above.Becausemethylalcohol is slowly eliminated from the body, repeated low exposures may build up to high levels, causing severe symptoms. Recovery is not always complete. Methanol has been found to cause changes in the genetic material of some test animals. Whether it does in humans is unknown. (NYDH) Target Organs: Eyes, skin, central nervoussystem, gastrointestinal. Symptoms: Exposure to excessive vapor causes eye irritation, headache, fatigue, anddrowsiness.High concentrations canproduce central nervous system depression and optic nerve damage. 50,000 ppm will probably cause death in 1 to hr. Canbeabsorbedthrough skin. Swallowing may cause death or eyedamage.(Source:CHRIS) Conc IDLH: 25,000 pprn

NIOSH REL: 200 ppm time-weighted averages for 8-hr exposure; 262 mg/m3 time-weighted averages for 8-hr exposure; 800 ppmceiling exposures, which shall at no time be exceeded; 1048 mg/m3 ceiling exposures, which shall at no time be exceeded. ACGM TLV: TLV = ppm SKIN ACGIH STEL: STEL = 250 ppm> >SKIN OSHA PEL: Transitional Limits: PEL = 200 ppm (260 mg/m3) (skin); Final Rule Limits: TWA = ppm(260mg/m3) (skin); STEL = ppm (325 mg/m3) (skin)

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

539

MAK Information: 200 ppm; 260 mg/m3 Substance with systemic effects, onset of effect less than or equal to 2 hr: Peak = 2xMAK for 30 min, 4 times per shift of 8 hr. Danger of cutaneous absorption Carcinogen: N; Status: Seebelow CarcinogenLists: Z A R C Not listed; MAK Not listed; NZOSH Not listed; N T P Not listed; ACGZH Not listed; OSHA: Not listed. HumanToxicity Data: (Source:NIOSHRTECS) orl-man LDLo:6422 mg/kg CMAJAX 128, 14, 83 Brain and Coverings Changes in circulation (hemorrhage, thrombosis, etc.) Lungs, Thorax, or Respiration Dyspnea Gastrointestinal Nausea or vomiting orl-man TDLo:3429 mgkg AMSVAZ 212, 5, 82 Sense Organs Eye Visual field changes orl-hmn LDLo:428 mgkg NPIRI* 1, 74, 74 Behavioral Headache Lungs, Thorax, or Respiration Other changes orl-hmn LDLo:143 mg/kg 34ZIAG -,382, 69 Sense Organs Eye Optic nerve neuropathy Lungs, Thorax, or Respiration Dyspnea Gastrointestinal Nausea or vomiting

540 orl-wmn TDLo:4 g/kg AMSVAZ 212, 5, 82 Sense Organs Eye Visual field changes Lungs, Thorax, or Respiration Dyspnea Gastrointestinal Nausea or vomiting ihl-hmn TCLo:86000 mg/m3 AGGHAR 5, 1, 33 Sense Organs Eye Lacrimation Lungs, Thorax, or Respiration Cough Other changes ihl-hmn TCLo:300 ppm NPIRI* 1, 74, 74 Sense Organs Eye Visual field changes Behavioral Headache Lungs, Thorax, or Respiration Other changes

LD50 Value: orl-rat LD50:5628 mglkg Other Species Toxicity Data: (Source:NIOSHRTECS1992) orl-rat LD505628 mg/kg ihl-rat LC50:64000 ppm/4H ipr-rat LD50:7529 mg/kg ivn-rat LD50:213 1 mg/kg orl-mus LD50:7300 mg/kg ihl-mus LCLo:50 g/m3/2H ipr-mus LD50: 10765 mg/kg scu-mus LD50:9800 mg/kg ivn-mus LD50:4710 mg/kg orl-dog LDLo:7500 mg/kg orl-mky LD50:7 g/kg ihl-mky LCLm1000 ppm skn-mky LDLo:393 mg/kg

Chapter 9

Oils, Plasticizers, Lubricants, Solvents, andMoldReleaseAgents

541

ihl-cat LCLo:44000 mg/m3/6H ivn-cat LDLo:4641 mg/kg orl-rbt LD50: 14200 mg/kg skn-rbt LD50: 15800 mg/kg ipr-rbt LD50: 1826 mg/kg ivn-rbt LD50:8907 mg/kg ipr-gpg LD50:3556 mg/kg ipr-ham LD50:8555 mg/kg par-frg LDLo:59 g/kg

IrritationData: (Source:NIOSHRTECS1992) eye-hmn 5 ppm skn-rbt 500 mg/24H MOD eye-rbt 40 mg MOD ReproductiveToxicity(1992RTECS): reproductive toxin.

Thischemical

is amammalian

Reproductive Toxicity Data (1992 RTECS): orl-rat TDLo:7500 mg/kg (17-19D preg) TJADAB 33, 259, 86 Effects Newborn Behavioral orl-rat TDLo:35295 mg/kg (1-15D preg) ONGZAC 22(1), 71, 91 Effects on Fertility Female fertility index Preimplantation mortality Postimplantation mortality orl-rat TDLo:35295 mgkg (1-15D preg) ONGZAC 22(1), 71, 91 Effects on Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus) ihl-rat TCLo:20000 ppm/7H (1-22D preg) TJADAB 29(2), 48A, 84 Specific Developmental Abnormalities Musculoskeletal system Cardiovascular (circulatory) system Urogenital system

542

Chapter

ihl-rat TCLo:20,000 p p d 7 H (7-15D preg) FAATDF 5 , 727, 85 SpecificDevelopmentalAbnormalities Musculoskeletalsystem Endocrine system ihl-rat TCLo:10,000 p p d 7 H (7-15D preg) FAATDF 5, 727, 85 Effects Embryo or Fetus Fetotoxicity (except death, e.g., stunted fetus)

--PROTECTION AND FIRST AID -Protection Suggested from the CHRIS Manual: Approved canister mask for high vapor concentrations; safety goggles; rubber gloves. NIOSH Pocket Guide to Chemical Hazards: **Wear Appropriate Equipment to Prevent: Repeated or prolonged skin contact. **Wear Eye Protection to Prevent: Reasonable probability of eye contact.

**Exposed Personnel Should Wash:

Promptly when skin becomes wet.

**Remove Clothing: Immediately remove any clothing that becomes wet to avoid any flammability. **Reference: NIOSH FirstAidSource: CHRISManual1991. Remove victim from exposure and applyartificial respiration if breathing has ceased. Ingestion: Induce vomiting; then give 2 teaspoons of baking sodain glass water. Call a physician. Skin or Eyes: Flush with water for 15 min. FirstAidSource: DOTEmergencyResponseGuide1993. Move victim to fresh air and call emergency medical care: if not breathing, give artificial respiration; if breathing is difficult, give oxygen. case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature. Effects may be delayed; keep victim under observation.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

543

--- INITIAL INCIDENT RESPONSE -FireExtinguishment: Alcoholfoam, dry chemical, carbon dioxide. Note: Water may beineffective.(CHRIS 91) U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT Shipping Name: Methanol or methyl alcohol DOT ID Number: UN1230 ERG90

* POTENTIAL HAZARDS *

GUIDE 28

*Health Hazards Poisonous; may be fatal if inhaled, swallowed, or absorbed through skin. Contact may irritate or bum skin and eyes. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Flammablekombustible material; may be ignited by heat, sparks, or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion and poison hazard indoors, outdoors, or in sewers. Runoff to sewer may create fire or explosion hazard.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressure self-contained breathing apparatus (SCBA)andchemical protective clothing that is specificallyrecommendedby the shipper or manufacturer may be worn. It may provide little or thermal protection. Structural firefighter’s protective clothing is effective for these materials. Isolate for 1/2 mile in all directions if tank, rail car, or tank truck is involved fire. in CALLCHEMTRECAT 1-800-424-9300 FOREMERGENCYASSISTANCE.

*Fire Small fires: Dry chemical, CO,, water spray, or alcohol-resistant foam. Largeflres: Water spray, fog, or alcohol-resistant foam. Move container from fire area if you can do it without risk.

544

Chapter 9

Dike fire-control water for later disposal; do not scatter the material. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case ofrising sound of venting safety deviceor any discoloration of tank due to fire.

*Spill or Leak Shut off ignition sources; flares, smoking, or flames in hazard area. Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with fire. Do not touch or walk through spilled material; stop leak if you can do it without risk. Water spray mayreduce vapor; but it maynotprevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. *First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature. Effects may be delayed; keep victim under observation.

Name: 2-BUTANONE Synonyms: Acetone, Methyl-; Aethylmethylketon (German); Butanone; Butanone 2 (French); EthylMethylCetone (French); Ethylmethylketon (Dutch); Ethyl Methyl Ketone; Ethyl Methyl Ketone (DOT); Ketone, Ethyl Methyl;Meetco;MethylAcetone;MethylAcetone(DOT);MethylEthyl Ketone; Methyl Ethyl Ketone (DOT); Metiletilchetone (Italian); Methyloetyloketon (Polish); 2-Butanone; MEK CAS: 78-93-3; RTECS: EL6475000 Formula: C,H,O; Mol Wt: 72.12

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

545

WLN: 2V1 Chemical Class: Ketone See other identifiers listed below under Regulations.

--PROPERTIES -Physical Description: Clear colorless liquid with a fragrant, mintlike, moderately sharp odor Boiling Point: 352.72 K; 795°C; 175.2"F Melting Point: 187.04 K;-86.2"C;-123°F Flash Point: 267.4 K; -53°C; 21.6"F Autoignition: 788.7 K;515.5"C;959.9"F Critical Temp: 535.7 K; 2623°C; 504.59"F Critical Press: 4.15 kN/m*; 40.9 atm; 601 psia Heat of Vap: 191 Btu/lb; 106.07 cal/g; 4 . 4 3 8 ~E5 J/kg Heat of Comb: -13,480 Btu/lb; -7494 cal/g; -313x E5 J k g Vapor Pressure: 71.2 mm at 20°C UEL: 11.5% LEL: 1.8% IonizationPotential (ev): 6.7 Vapor Density:2.42 (air = 1) Specific Gravity: 0.806 at 20°C Density: g/mlat20°C Water Solubility: 27 % Incompatibilities: Very strong oxidizers, chlorosulfonic acid, oleum, potassium-tert-butoxide,heat or flame, chloroform, hydrogenperoxide, nitric acid Reactivity with Water: No data on water reactivity Reactivity with CommonMaterials: Noreaction(Source: Stability during Transport: No data Neutralizing Agents:Not pertinent (Source:SAX) Polymerization Possibilities: Not pertinent (Source:SAX)

SAX)

Toxic Fire Gases:Unburnedvapors Odor Detected at (ppm): 10ppm Odor Description: Like acetone; pleasant; pungent.(Source:CHRIS) 100% Odor Detection: 6.0 ppm

546

Chapter 9

--REGULATIONS -DOT hazard class: 3 FLAMMABLE LIQUID DOT guide:26 Identification number: UN1 193 DOT shipping name: Ethyl methyl ketone or methyl ethyl ketone Packinggroup: I1 Label($required: FLAMMABLELIQUID Special Provisions: T8 Packaging exceptions: 173.150 Nonbulk packaging: 173.202 Bulkpackaging: 173.242 Quantity limitations: Passenger airhail: 5 L Cargo aircraft only: 60 L Vesselstowage:B STCCNumber:

4909243

Clean Water Act Sect. 307: No Clean Water Act Sect. 311: No Clean Air Act:CAA '90listed EPA Waste Number: U159,D035 CERCLARef: Y RQ Designation: D lb (2270kg)CERCLA SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant. Acute toxicity: adverse effect to target organs. Chronic toxicity: mutagen. Chronic toxicity: reproductive toxin. Fire hazard: flammable. Listed in SARA Sect 313: Yes De Minimus Concentration: 1.O %

U.S. Postal Service Mailability: Hazard class: Flammable liquid - mailable as ORM-D Mailability: Domestic surface mailonly Maxperparcel:1 qt metal; 1 pt other

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

547

NFPA Codes: HealthHazard(blue): (1) Slightly hazardous to health. Asa precaution, wear self-contained breathing apparatus. Flammability(red): (3) Thismaterialcanbeignitedunderalmost all temperature conditions. Reactivity(yellow): Stable evenunder fire conditions. Special: Unspecified.

--- TOXICITY DATA --Short-term Toxicity: Inhalation: Human exposure to levels above 350 ppm caused irritation of the nose and throat. Numbness in fingers, and legs accompanied by headache, nausea, vomiting, and fainting have occurred after exposure to levels of 300 600 ppm. Skin: Contact with liquid or vapor at levels of 300 to 600 ppm caused severe irritation. Liquid is absorbed readily and may cause numbing of fingers and arms. Eyes: Exposure to levels of 200 ppm produced irritation. Ingestion: Can cause irritation of the mouth, throat, and stomach, the severity of which will depend amount swallowed. Symptoms of poisoning include nausea, vomiting, stomachpain, and diarrhea. Death can occur from ingestion of as little as 1 oz. (NYDH) Long-termToxicity: Hasbeenimplicatedin certain nervous disorders characterized by weakness,fatigue, heaviness inchest, and numbness of hands andfeet.Thesesymptomsmaydevelop after 1 yr ofexposure to vapor concentrations of 50 to 200 ppm. Improvement is gradual and maytake years after exposure is discontinued. (NYDH) Target Organs: Central nervous system, lungs. Peripheral nervoussystem. Eye irritation at 350 ppm. Symptoms: Liquidcauseseye bum. Vapor irritates eyes, nose, and throat; can cause headache, dizziness, nausea, weakness, and loss of consciousness. (Source: CHRIS) Conc IDLH 3000 ppm NOSH REL: 200 ppm time-weighted averages for 8-hr exposure; 590 mg/m3 time-weighted averages for 8-hr exposure. ACGIH TLV: TLV = ppm (590 mg/m3) ACGIHSTEL: STEL = 300ppm

548

Chapter 9

OSHA PEL: Transitional Limits: PEL = 200 ppm (590 mg/m3); Final Rule Limits: = 200 ppm (590 mg/m3); STEL = 300 ppm (885 mg/m3) MAK Information: 200 ppm; mg/m3 Substance with systemic effects, onset of effect less than Peak = 2xMAK for 30 min, 4 times per shift of 8 hr.

or equal to

hr:

Carcinogen: N; Status: Seebelow CarcinogenLists: I A R C Not listed; M M Not listed; NIOSH Not listed; NTP Not listed; ACGIH Not listed; OSHA: Not listed. HumanToxicityData: (Source:NIOSHRTECS) ihl-hmn TCLo:100 ppm/5M JIHTAB 25, 282, 43 Sense Organs Nose Other Eye Conjunctive irritation Lungs, Thorax, or Respiration Other changes LD50Value: orl-rat LD50:2737 mgkg OtherSpeciesToxicityData: (Source:NIOSHRTECS orl-rat LD50:2737 mg/kg ihl-rat LC50:23500 mg/m3/8H ipr-rat LD50:607 mg/kg orl-mus LD50:4050 mg/kg ihl-mus LC50:40 g/m3/2H ipr-mus LD50:616 mg/kg skn-rbt LD50:6480 mg/kg ipr-gpg LDL.4~2000mg/kg ihl-mam LC50:38 g/m3 IrritationData: (Source:NIOSHRTECS eye-hmn 350 ppm skn-rbt 500 mg/24H MOD skn-rbt 402 mg/24H MLD skn-rbt 13780 mg/24H open MLD eye-rbt 80 mg

1992)

1992)

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

ReproductiveToxicity(1992RTECS): reproductive toxin.

Thischemical

549 is amammalian

Reproductive Toxicity Data (1992 RTECS): ihl-rat TCLo:3000 p p d 7 H (6-15D preg) TXAPA9 28, 452, 74 Specific Developmental Abnormalities Craniofacial (including nose and tongue) Urogenital system Homeostasis

--PROTECTION AND FIRST AID --Protection Suggested from the CHRIS Manual: Organic canister or air pack; plastic gloves; goggles or face shield.

NIOSH Pocket Guide to Chemical Hazards: **WearAppropriate Equipment to Prevent: Repeated or prolonged skin contact.

**Wear Eye Protection to Prevent: Reasonable probability of eye contact. **Remove Clothing:Promptly remove nonimperviousclothing that becomes contaminated. **Reference: NIOSH Recommended Respiration Protection Source: NIOSH Pocket Guide(85-114) NIOSH (2-Butanone) lo00 ppm: Anypowered air-purifying respirator withorganicvapor cartridge@). Substancecauseseye irritation or damage;eye protection needed. Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). 3000ppm: Any air-purifying full facepiece respirator (gas mask) with achinstyle or front- or back-mountedorganicvapor canister. Any supplied-air respirator operated in a continuous-flow mode. Substance causes eye imtation or damage; eye protection needed.Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. Emergency or Planned Entry in Unknown Concentrationsor IDLH Conditions: Any self-contained breathing apparatus with a full facepiece and operated in pressure-demand a or other positive-pressure mode. Any supplied-air

550

Chapter 9

respirator with a full facepiece and operated in a pressure-demand or other positive-pressure modeincombinationwith an auxiliary self-contained breathing apparatus operated in a pressure-demand or other positive-pressure mode. Escape: Any air-purifying full facepiece respirator (gas mask) with a chinstyle or front- or back-mountedorganicvapor canister. Any appropriate escape-type self-contained breathing apparatus.

FirstAidSource: CHRISManual1991. Inhalation: Removevictim to fresh air; if breathing is irregular or has stopped, start resuscitation and administer oxygen. Eyes: Wash with plenty of water for at least 15 min and call physician. First Aid Source: DOTEmergencyResponseGuide1993. Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

--- INITIAL INCIDENT RESPONSE -FireExtinguishment: Alcoholfoam, dry chemical, carbon dioxide. Note: Water may be ineffective. (CHRIS91) U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT Shipping Name: Ethyl methyl ketone or methyl ethyl ketone DOT ID Number: UN1 193 ERG90

* POTENTIAL HAZARDS *

GUIDE

*Health Hazards May be poisonous if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Flammable/combustible material; may be ignited by heat, sparks, or flames. Vapors may travel to a source of ignition and flash back.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

55 1

Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors, or in sewers. Runoff to sewer may create fire or explosion hazard.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressure self-contained breathing apparatus(SCBA)and structural firefighters’ protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car, or tank truck is involved in fire. CALLCHEMTRECAT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Smallfires: Dry chemical, CO2or Halon, water spray, or alcohol-resistant foam. Large fires: Water spray, fog, or alcohol-resistant foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargoarea, use unmanned hose holderor monitor nozzles; if this is impossible, withdraw from area and let fire bum. Withdraw immediately in case of rising sound of ventingsafety device or any discoloration of tank due to fire. *Spill or Leak Shut off ignition sources; flares, smoking, or flames in hazard area. Stop leak if you can do it without risk. Waterspray may reduce vapor; but it maynotprevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal.

*First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

552

Chapter 9

Name: ASPHALT CAS:8052-42-4; RTECS: C19900000 See other identifiers listed below under Regulations.

--PROPERTIES -Physical Description: Dark brown to black thick liquid with a tar odor; softens to viscous liquid >9O"C. Boiling Point: >973.15 K Melting Point: NA Flash Point: 422.03 K to 3°C to 560.92 .9"F to 560.92 Autoignition: NA UEL: NA LEL: Vapor Density: No data Specific Gravity: 1 at 20°C Density:1 or 9.3 lb/gal Water Solubility: Unknown Incompatibilities: Unknown Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: None reported other than possible unburned vapors Odor Detected at (ppm): Data not available Odor Description: Tany (Source:CHRIS) 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: 3 FLAMMABLE LIQUID DOT guide: 27 Identificationnumber: NA1999 DOT shipping name: Asphalt (at or above its flashpoint) Packing group: 111

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

553

Label(s)required: None Packaging exceptions: 173.150 Nonbulkpackaging: 173.203 Bulkpackaging: 173.242 Quantity limitations: Passenger airhail: Forbidden Cargo aircraft only: Forbidden Vesselstowage: D Otherstowage provisions: M4 STCC Number: Not listed Clean Water Act 307: No Clean Water Act 311: No Clean Air Act:Not listed EPAWasteNumber: None CERCLA Ref: Not listed RQ Designation: Not listed SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: adverse effect to target organs. Chronic toxicity: carcinogen. Chronic toxicity: mutagen.

U.S. Postal Service Mailability: Hazardclass:Notgiven Mailability: Nonmailable Maxper parcel: 0 NFPA Codes: Health Hazard (blue): (0) No unusual health hazard. Flammability (red): (1) This material mustbe preheated before ignition can occur. Reactivity (yellow): (0) Stable evenunder fire conditions. Special: Unspecified.

--TOXICITY DATA -Short-term Toxicity: Inhalation: Symptoms listed here are from reports of industrial accidents. No levels were reported. Can cause irritation of the nose, throat, and lungs; increase in coughing and spitting; burning sensation in throat and chest; hoarseness, headache and runny nose. Skin: Can cause

Chapter 9

554

heat bums and irritation. Eyes: Can cause information available. (NYDH)

irritation. Ingestion: No

Long-termToxicity: Cancause acnelike sores, thickening, and yellow discoloration of the skin. Symptoms similar to those under inhalation may be seen. (NYDH) TargetOrgans:

Skin, eyes, respiratory tract.

Symptoms: Contactwith skinmay cause dermatitis. Inhalation vapors may causemoderate irritation ofnoseand throat. Hot liquid bums skin. (Source: CHRIS) Conc IDLH Unknown

NIOSH REL: Potential occupational carcinogen, 5 mg/m3 ceiling exposures, which shall at time be exceeded. ACGIHTLV: TLV = 5 mg/m3 ACGIH STEL: Not listed OSHA PEL: Not in Table

MAK Information: Carcinogenic working material without compound that is justifiably suspected of having carcinogenic potential. Carcinogen: Y; Status: Seebelow CarcinogenLists: Z A R C Not listed; M M A compoundthatis justifiably suspected of having carcinogenic potential; NIOSH Carcinogen defined by NIOSH with further categorization; NTP Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: No LD50 in RTECS Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

This chemical has no

known

--- PROTECTION AND FIRST AID --Protection Suggested from theCHRIS Manual: Protective clothing; face and eye protection when handling hot material.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

555

FirstAidSource: NIOSH Eye: Nonegiven Skin: Nonegiven Inhalation: Nonegiven Ingestion: Nonegiven FirstAidSource: CHRISManual1991. Severe bums may result fromcontactwithhot asphalt. If molten asphalt strikes the exposed skin, cool the skin immediately by quenching with cold water. A bum shouldbecoveredwitha sterile dressing, and the patient should be taken immediately to a hospital. FirstAidSource: DOTEmergencyResponseGuide1993. Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

--- INITIAL INCIDENT RESPONSE --Fire Extinguishment: Water spray, dry chemical, foam or carbon dioxide. Note: Water or foam may cause frothing. (CHRIS91) U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOT Shipping Name: Asphalt (at or above its flashpoint) DOTIDNumber: NA1999 ERG90

* POTENTIAL HAZARDS *

27

*Health Hazards May be poisonous if inhaled or absorbed through skin. Vapors may cause dizziness or suffocation. Contact may irritate or bum skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Flammable/combustible material; may be ignited by heat, sparks, or flames. Vapors may travel to a source of ignition and flash back.

Chapter 9

556

Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors, or in sewers. Runoff to sewer may create fire or explosion hazard.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Positive-pressure self-contained breathing apparatus (SCBA) and structural firefighters’ protective clothing will provide limited protection. Isolate for 1/2 mile in all directions if tank, rail car, tank truck is involved in fire. CALL CHEMTReC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. If water pollution occurs, notify the appropriate authorities.

*Fire Smallfires: Dry chemical, COz, water spray, or regular foam. Large fires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holderor monitor nozzles; if this is impossible, withdraw from area and let fire bum. Withdraw immediately in caseof rising sound of venting safety device or any discoloration of tank due to fire. *Spill or Leak Shut ignition sources; no flares, smoking, or flames in hazard area. Stop leak if you can do it without risk. Waterspray mayreduce vapor; but it may notprevent ignition in closed spaces. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. *First Aid Move victim to fresh air and call emergency medical care; if not breathing, give artificial respiration; if breathing is difficult, give oxygen. In case of contact with material, immediately flush eyes with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

557

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

- IDENTIF’IERS Chemical Name and Synonyms:

MIXTURE OF PETROLEUM HYDROCARBONS

Trade Name and Synonyms: Mobilsol K ChemicalFamily: Aromatic Oil Manufacturer: Mobil Oil Company, New

York, New York

UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA -Material

No.

High-boiling aromatic

Cas oil

%

NA

5 mg/m3

--PHYSICAL DATA -Boiling Point (“F): 90% at 660 to 925 SpecificGravity (H,O = 1): 0.995 Vapor Pressure (mm Hg):

at 80°F

Percent Volatile byVolume (%): Nil VaporDensity(air = 1): Nil FreezingPoint:

NA

EvaporationRate: p H NA

Solubilityin Water: Negligible Melting PointlPour or Congealing Point: NA Viscosity: NA

TLV

558

Chapter 9

Appearance/Color/Odor: Lightmineral oil FIRE AND EXPLOSION HAZARDS

---

FlashPoint: 410'F (COC) FlammabilityLimits: NA AutoignitionTemperature: NA Extinguishing Media: Foam, dry chemical, carbon dioxide, or water fog or spray. Special Fire Fighting Procedures: No special procedures are recommended by the manufacturer. Unusual Fire and Explosion Hazards:

None reported.

Hazardous Products of Combustion and Decomposition: None reported by manufacturer. HazardousPolymerization: Willnot occur.

--- HEALTH HAZARD DATA -Effects of Overexposure: Primary skin irritation index, 0.25. This product is a high-boiling aromatic oil. After prolongedandrepeated skin contact, irritation or more serious skin disorders may result.

Emergency Response and First Aid: Skin: Flush all affected areas with plenty of water for 15 min. Remove and clean any contaminated clothing and shoes. Seekmedical attention if skin irritation occurs. Eyes: Flush the eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: There are no effects or recommendations reported. Ingestion: Consultphysicianimmediately. Cancer Information: None listed under OSHA/NTP/IARC.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

559

--TOXICITY DATA -No information reported.

--

REACTMTY DATA

--

Stability and Conditions to Avoid: Avoid open flames and hot surfaces. Materials to Avoid (Incompatibility): Strong oxidizing agents and excessive heat. HazardDecompositionProducts: Fumes,smoke,carbonmonoxide,and carbon dioxide, in the case incomplete combustion.. HazardousPolymerization: Willnot occur.

--- SPILL AND EMERGENCY RESPONSE --For Spills: Useany inert absorbent such as sand, earth, or vermiculite. The product is described as being slippery. Use proper safety equipment during cleanup. Disposeofinamannerthat is consistent with local, state, and federal regulations. Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal site or facility. Wastematerial may be incinerated under conditions that meet federal, state, and local environmental control regulations. At present this is not classified as a RCRA hazardous waste. The manufacturer recommends mixing with more flammable solvent and incinerating. Empty Containers: Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants.

--- SPECIAL PROTECTION AND PRECAUTIONS --RespiratoryProtection: Normallynotneeded.Use protection in confined or enclosed spaces.

supplied-air respiratory

Type of Ventilation Required: Use local exhaust to capture fumes and vapors. Provide greater than 60-fpm hood or face velocity for confined spaces.

Chapter 9

560

Eye Protection Requirements: contact may occur.

Use splash goggles or face shield when eye

ProtectiveGlovesandOther: chemical goggles.

Useneoprene gloves, neoprene apron, and

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. Note: This product has a shelf life of 1 yr. Other Precautions: Avoid breathing oil mist. Remove oil-soiled clothing and launder before reuse. Discard oil-soaked shoes. Wash skin thoroughly with soap and water after handling.

- REGULATORY INFORMATION -Transportation Incident Information: This product is unregulated by DOT at present. DOT Identification Number: Not applicable.

--IDENTIFIERS -Chemical Name and Synonyms: RELEASE AGENT

INTERNAL LUBRICANT, MOLD

Trade Name and Synonyms: Mold Wiz Chemical Family: Condensation product of synthetic resins, glycerides, and organic acid derivatives Manufacturer: New York

Axel Plastics Research Laboratories, Inc., Woodside,

UN ID Number: NA

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

561

- INGREDIENTS AND COMPOSITION DATA --Material

%

Cas No.

mixture Product

TLV ~ “ x i c

NA

--PHYSICAL DATA -Boiling Point (“F):220 Specific Gravity (H20=

0.956 at 25°C

VaporPressure(mm Hg): NA Percent Volatile by Volume (%): None at 25°C VaporDensity(air FreezingPoint:

=

NA

NA

Evaporation Rate: Noneat 25°C pH: NA Solubility in Water: Insoluble Melting Point/Pour or Congealing Point:

NA

Viscosity: NA Appearance/Color/Odor: Amber color, withaliphatic odor

--FLRE AND EXPLOSION HAZARDS FlashPoint: 280°F (COC) FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Foam, dry chemical, carbon dioxide, or water fog or spray.

Chapter 9

562

Special Fire Fighting Procedures: No special procedures are recommended by the manufacturer. Unusual Fire and Explosion Hazards:

None reported.

Hazardous Products of Combustion and Decomposition: None reported by manufacturer. Hazardous Polymerization: Will not occur.

--- HEALTH HAZARD DATA --Effects of Overexposure: None reported. The manufacturer states that the product is totally inoffensive and nontoxic. There is no regulated TLV value for this material. Emergency Response and First Aid: Skin: Flush all affected areas with plenty of water for 15 min. Remove and clean any contaminated clothing and shoes. Seek medical attention if skin irritation occurs. Eyes: Flush the eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: There are no effects or recommendations reported. Ingestion: Consultphysicianimmediately. Cancer Information: None listed under OSHA/NTP/IARC.

--TOXICITY DATA --No information reported.

--REACTIVITY DATA --Stability and Conditionsto Avoid: This productis stable but should bestored away from open flames. Materials to Avoid (Incompatibility): Avoid contact with water. HazardDecompositionProducts: Fumes,smoke,carbonmonoxide,and carbon dioxide, in the caseofincompletecombustion.This material has similar properties to that of any organic chemical.

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

563

HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE --For Spills: Use any inert absorbent such as sand, earth, or vermiculite. The product is described as being slippery. Use proper safety equipment during cleanup. Disposeof in amannerthatis consistent with local, state, and federal regulations. After absorbent is applied, the area can be washed off with detergent.

Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal site or facility. Wastematerialmaybe incinerated under conditions that meet federal, state, and local environmental control regulations. At present this is not classified as a RCRA hazardous waste. The manufacturer recommends mixing with more flammable solvent and incinerating. Empty Containers: Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants.

--- SPECIAL PROTECTION AND PRECAUTIONS --RespiratoryProtection: Normallynotneeded. Type of Ventilation Required: Use local exhaustto capture fumes andvapors. Provide greater than 60-fpm hood or face velocity for confined spaces. Eye Protection Requirements: contact may occur. ProtectiveGlovesand gloves.

Use splash goggles or face shield wheneye

Other: Use polysulfide or polyethylene protective

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. Note: This product has a shelf life of 1 yr.

Chapter 9

Other Precautions: Avoid breathing oil mist. Remove oil-soiled clothing and launder before reuse. Discard oil-soaked shoes. Wash skin thoroughly with soap and water after handling.

- REGULATORY INFORMATION -Transportation Incident Information: This product is unregulated by DOT at present,

DOT Identification Number: Not applicable.

--IDENTIFIERS -Chemical Name and Synonyms: RETENE, ROSIN

OIL

Trade Name and Synonyms: "N" Rosin Oil ChemicalFamily: Decarboxylated Abietic Acid Manufacturer: Natrochem,Inc.Savannah,Georgia UN ID Number: NA

No.

--INGREDIENTS AND COMPOSITION DATA --Cas Material % TLV Decarboxylated abietic NAacid

Not established

--PHYSICAL DATA -BoilingPoint ("F):NA SpecificGravity (H,O = 1): 1.00 Vapor Pressure (mm Hg):

NA

Percent Volatile byVolume VaporDensity(air

= 1): NA

3

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

FreezingPoint:

565

NA

EvaporationRate:

NA

p H NA Solubilityin Water: Insoluble Melting Point/Pour or Congealing Point: NA Viscosity: NA AppearanceKolorlOdor: Amber, terpenic oil

--FIRE AND EXPLOSION HAZARDS --FlashPoint: 300°F (COC) FlammabilityLimits: NA AutoignitionTemperature:

NA

Extinguishing Media: Steam, water fog, dry chemical, carbon dioxide. Special Fire Fighting Procedures: No special procedures are recommended by the manufacturer. Unusual Fire and Explosion Hazards:

None reported.

Hazardous Products of Combustion and Decomposition: None reported by manufacturer. HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA -Effects of Overexposure: None reported bymanufacturer;however, this product should be handled as any hydrocarbon vapor, i.e., limit excessive exposure to fumes and skin contact.

Chapter 9

566

Emergency Response and First Aid: Skin: Flush all affected areas with plenty of water for 15 min. Remove and clean any contaminated clothing and shoes. Seekmedical attention if skin irritation occurs. Eyes: Flush the eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: There are no effects or recommendations reported. Ingestion: Consult physician immediately. Cancer Information: None listed under OSHA/NTP/IARC.

--TOXICITY DATA -No information reported.

--- REACTIVITY DATA -Stability and Conditionsto Avoid: This product is stable but should be stored away from open flames. Materials to Avoid (Incompatibility): None reported by manufacturer. HazardDecompositionProducts: Fumes,smoke,carbonmonoxide,and carbon dioxide, in the caseofincompletecombustion.This material has similar properties to that of any organic chemical. Hazardous Polymerization: Will not occur.

--- SPILL AND EMERGENCY RESPONSE -For Spills: Useany inert absorbent such product is described as being slippery. cleanup. Disposeofin a mannerthat federal regulations. After absorbent with detergent.

as sand, earth, or vermiculite. The Use proper safety equipment during is consistent with local, state, and applied, the area can be washed off

Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose absorbed material at an approved waste disposal site or facility. Wastematerialmaybe incinerated under conditions thatmeet federal, state, and local environmental control regulations. At present this is

567

Oils, Plasticizers, Lubricants, Solvents, and Mold Release Agents

not classified as a RCRA hazardous waste. The manufacturer recommends mixing with more flammable solvent and incinerating.

Empty Containers: Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants.

--- SPECIAL PROTECTION AND PRECAUTIONS --RespiratoryProtection: Normallynotneeded. of Ventilation Required: manufacturer.

No recommendations

are given by

Eye Protection Requirements: Use splash goggles or face shield when eye contact may occur. Protective Gloves and Other: Use polyethylene protective gloves. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. Note: This product has a shelf life of 1 yr. Other Precautions: Avoid breathing oil mist. Remove oil-soiled clothing and launder before reuse. Discard oil-soaked shoes. Wash skin thoroughly with soap and water after handling.

--- REGULATORY INFORMATION --Transportation Incident Information: This product is unregulated by at present. DOT Identification Number: Not applicable.

DOT

This Page Intentionally Left Blank

10 A M I N E S

--IDENTIFIERS -Name: N-NITROSODIPHENYLAMINE Synonyms: Benzenamine,N-Nitroso-N-Phenyl- (9CI); CuretardA;Delac J; Diphenylnitrosamin(German);Diphenylnitrosamine;DiphenylN-Nitrosoamine; N,N-Diphenylnitrosamine; Naugard TJB; NCI-C02880; NDPA; NDPhA; N-Nitrosodifenylamin (Czech); Nitrosodiphenylamine; NNitrosodiphenylamine; N-Nitroso-N-Phenylaniline;Nitrous Diphenylamide; Redax; Retarder J; TJB; Vulcalent A; Vulcatard; Vulcatard A; Vulkalent A (Czech); Vultrol CAS: 86-30-6; RTECS: JJ9800000 Formula: C,2H,0N20;MolWt: 198.24 WLN: ONNR ChemicalClass: Nitrocompound;aromaticamine See other identifiers listed below under Regulations.

--PROPERTIES -BoilingPoint: NA MeltingPoint: 418 K; 144.8OC;292.7"F FlashPoint: NA Autoignition: NA UEL: NA LEL: NA VaporDensity: No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity withCommonMaterials: No data Stability during Transport: No data NeutralizingAgents: No data 569

570

Chapter

PolymerizationPossibilities: No data Toxic Fire None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--

REGULATIONS

--

DOT hazard class: Not given Packaging exceptions: 173 Nonbulkpackaging: 173 Bulkpackaging: 173 STCC Number: Not listed Clean Water Act Sect. 307: Yes Clean Water ActSect. 311: No Clean Air Act: Not listed EPA WasteNumber: None CERCLA Ref: Y RQ Designation: B, 100 lb (45.4 kg) CERCLA SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: adverse effect to target organs. Listed in SARA Sect. Yes De Minimus Concentration: 1 .O% U.S. Postal Service Mailability:

Not given

NFPA Codes: Health Hazard (blue):Unspecified Flammability(red): Unspecified Reactivity (yellow):Unspecified Special: Unspecified

--- TOXICITY DATA -Short-term Toxicity: Long-termToxicity:

Unknown Unknown

571

Amines

Target Organs: Eyes Symptoms: Eye irritant (Source: SAX) Conc IDLH Unknown

NIOSH REL: Not given ACGIHTLV: Not listed ACGIHSTEL: Notlisted OSHA PEL: Not in Table Z-l-A MAKInformation: Not listed Carcinogen: N; Status: Seebelow References: Animal suspected IARC** 27,213.82; Animal positive IARC** 28, 151, 82; Human indefinite IARC** 27, 213, 82 CarcinogenLists: I A R C Not classified as to human carcinogenicity or probably not carcinogenic to humans; MAK: Not listed; NZOSH. Not listed; N T P Not listed; ACGIH. Not listed; OSHA: Not listed. LDS0Value: orl-rat LD50:2500 mg/kg OtherSpeciesToxicityData: orl-rat LD50:2500 mg/kg unr-rat LD50:3000 mg/kg orl-mus LD50:3850 mg/kg ipr-mus LD50: 1000 mg/kg

(Source:NIOSHRTECS1992)

IrritationData: (Source:NIOSHRTECS1992) eye-rbt 500 mg/24H SEV Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

This chemical has no known

No Significant Risk Level (Ca P65): N80 mg/day

572

Chapter 10

--IDENTIFIERS -Name: N-NITROSODI-N-PROPYLAMINE Synonyms: Dipropylnitrosamine; Di-n-Propylnitrosamine; DPN; DPNA; NDPA; N-Nitrosodi-n-Propylamine; N-Nitroso-N-Propyl-1-Propanamine; Propanamine,N-Nitroso-N-Propyl-;Propylamine,N-Nitroso-N-Di-;Di-NPropylnitrosamine CAS: 621-64-7; RTECS: JL9700000 Formula: C&I,.,NZO; MolWt:130.22 WLN: ONN3 Chemical Class: Nitro compound; aliphatic amine See other identifiers listed below under Regulations.

- PROPERTIES -Boiling Point: 479 K;205.8"C; 402.5"F MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density: No data SpecificGravity: No data Density: 0.9163, 20/4 Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: Toxic fumes of oxides of nitrogen Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--REGULATIONS --DOT hazard class: 9 CLASS 9 DOT guide: 31 Identificationnumber: UN3077

Amines

573

DOT shipping name: Environmentally hazardous substances, solid, N.O.S. Packing group: 111 Label(s)required: CLASS 9 Special Provisions: 8, B54 Packaging exceptions: 173.155 Nonbulkpackaging: 173.213 Bulkpackaging: 173.240 Quantity limitations: Passenger airhail: None Cargo aircraft only: None Vesselstowage: A STCC Number: Notlisted Clean Water Act Sect. 307: Yes 311: No Clean Water Act Clean Air Act:Notlisted EPA Waste Number: U1 11 CERCLARef: Y RQ Designation: A, 10 lb (4.54 kg) CERCLA SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: toxic. LD50 > 50 and < = 500 mgkg (oral rat). Chronic toxicity:carcinogen. Chronic toxicity:mutagen. 313: Yes Listed in SARA De Minimus Concentration: 0.1 %

U.S. Postal Service Mailability:

Not given

NFPA Codes: Health Hazard (blue): Unspecified Flammability (red): Unspecified Reactivity (yellow):Unspecified Special: Unspecified

- TOXICITY DATA -Short-term Toxicity:

Unknown

Long-term Toxicity: Unknown

574

Chapter 10

Conc IDLH Unknown

NIOSH REL: Not given ACGIHTLV: Not listed ACGIHSTEL: Notlisted OSHA PEL: Not in Table

MAK Information: Carcinogenic working material without MAK. In the Commission’s view, an animal carcinogen. Carcinogen: Y ; Status: Seebelow CarcinogenLists: I A R C Carcinogendefined by IARC to be possibly carcinogenic to humans, but having (usuaUy) no human evidence; MAK: animal carcinogen; NZOSH Not listed; NTP Carcinogen defined by NTP as reasonably anticipated tobe carcinogenic, with limited evidence in humans or sufficient evidence in experimental animals. ACGZH Not listed; OSHA: Not listed. LD50 Value: orl-rat LD50:480 mgkg

Other SpeciesToxicity Data: (Source:NIOSHRTECS1992) orl-rat LD50:480 mg/kg scu-rat LD50:487 mg/kg scu-mus LD50:689 mg/kg orl-ham LD50: >400 mg/kg scu-ham LD50:600 mg/kg Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

This chemical has no known

No Significant Risk Level (Ca P65): 0.1 mg/day

--PROTECTION AND FlRST AID -First Aid Source: DOT Emergency Response Guide 1993. In case of contact with material, immediately flush eyes with running water for at least15min.Wash skin with soap and water. Removeand isolate contaminated clothing and shoes at the site.

575

Amines

--

INITIAL INCIDENT RESPONSE

--

U.S. Department of Transportation Guide to Hazardous Materials Transport Information - Publication DOT 5800.5 (1990). DOTShippingName: Environmentally hazardous substances, solid, N.O.S. DOT ID Number: UN3077

ERG90

* POTENTIAL HAZARDS *

GUIDE 31

*Health Hazards Contact may cause bums to skin and eyes. Fire may produce irritating or poisonous gases. Runoff from fire control or dilution water may cause pollution. *Fire or Explosion Some of these materials may bum, but none of them ignites readily.

* EMERGENCY ACTION * Keep unnecessary people away; isolate hazard area and deny entry. Positive-pressure self-contained breathing apparatus (SCBA)and structural firefighters’ protective clothing will provide limited protection. CALLCHEMTREC AT 1-800-424-9300 FOREMERGENCYASSISTANCE. If water pollution occurs, notify the appropriate authorities,

*Fire Smallfires: Dry chemical, CO2, water spray, or regular foam. Lurgefires: Water spray, fog, or regular foam. Move container from fire area if you can do it without risk. not scatter spilled material with high-pressure water streams. Dike fire-control water for later disposal. *Spill or Leak Stop leak if you can do it without risk. Small dry spills: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. Small spills: Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Large spills: Dike far ahead of liquid spill for later disposal. Cover powder spill with plastic sheet or tarp to minimize spreading.

576

Chapter 10

*First Aid In case of contact with material, immediately flush eye with running water for at least 15 min. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site.

--- IDENTIFIERS --Chemical Name and Synonyms: BUTADIENE HOMOPOLYMER containing Acrylate Functional Groups Trade Name and Synonyms: Chemlink 5000 Oligomer Chemical Family: Acrylated Functional Groups on Butadiene Manufacturer: Arc0 Chemical Co., West Chester, Pennsylvania UN ID Number: NA

--- INGREDIENTS AND COMPOSITION DATA --Material

Cas No.

%

TLV

Acrylate terminated polybutadiene

NA

99 +

Not established

Catalyst

NA

<0.1

Not established

Inhibitor (BHT)

NA

<0.1

Not established

--- PHYSICAL DATA --Boiling Point ("I?): NA Specific Gravity (H,O = 1): 0.91 (25"C/20°C) Vapor Pressure (mm Hg): NA Percent Volatile by Volume (%): Negligible Vapor Density (air = 1): NA

Amines

577

Freezing Point: NA Evaporation Rate: NA pH: NA Solubility in Water: Negligible Melting Point/Pour or Congealing Point: NA Viscosity: 5000 CPS at 25°C (Brookfield) Appearance/Color/Odor: hydrocarbon odor.

Clear yellow, viscous liquid with penetrating

--- FIRE AND EXPLOSION HAZARDS --Flash Point: 300°F (COC) Flammability Limits: NA Autoignition Temperature: NA Extinguishing Media: Foam, dry chemical, carbon dioxide, water spray/fog . Special Fire Fighting Procedures: Do not enter confined spaces without proper protection. Heat may cause decomposition, build pressure, and rupture containers, spreading fire and increasing risk of serious injury. Fight fire from safe distance and protected location. Apply aqueous extinguishing media carefully to prevent steam explosion from contact with hot liquid. Avoid contact with hot liquid to prevent serious burns. Unusual Fire and Explosion Hazards: On exposure to high temperature, this material may decompose, releasing toxic and flammable gases, which when mixed with air in proper proportions may ignite and explode. The gases released are often heavier than air and may travel long distances before reaching a source of ignition and flash back to the vapor source. Hazardous Products of Combustion and Decomposition: Incomplete combustion will generate highly poisonous carbon monoxide, perhaps other toxic vapors, and a minor amount of metal oxide dust.

518

Chapter 10

Hazardous Polymerization:This product can polymerize when exposed to high heat or energy sources that deactivate the inhibitor.

- HEALTH HAZARD DATA -Effects of Overexposure: Note the following CAUTION statements provided by the manufacturer: CAUTZON: Moderate Skin hazard. May cause sensitization reaction. This material may be absorbed through the skin. CAUTION: Moderateeyehazard. CAUTION: Slightinhalationhazard. CAUTION: Slightingestionhazard. The primary hazard withthis product is by direct liquid contact withthe skin or eyes. This product may cause a potentially serious sensitizationreaction susceptible persons in addition to eye and skin reaction.

in

Emergency Response and First Aid: Skin: Immediately remove and discard contaminated clothing. Wash affected areaswithsoapandwater. If sticky, usewaterlesscleaner first. Prompt if irritation persists. action is essential. Seek medical attention Note: Following extensive, repeated andlor prolonged contact, this material may cause skin irritation leading to dermatitis or more serious skin disorders. In liquid or solution form, this material may be absorbed throughintact skin andproduceserious toxic effects if exposure is prolonged or extensive. Eyes: In caseof eye contact, immediately flush eyes with clean,low-pressure water for at least 15 min, occasionally lifting eyelids. Obtain immediate medical attention. Note: Upon direct contact, this material may cause moderate eye irritation, but no irreversible damage. Inhalation: If overcome by exposure, immediately move victim to fresh air. Keepvictimquiet.Administeroxygen or artificial respiration as needed. Obtain medical attention immediately.

579

Amiies

Note: Exposure to excessive concentration of this material in either vapor or mist form may result in toxic effects. Ingestion: If a large quantity of this material is swallowed, administer warm water (quart) and obtain medical attention immediately. notinduce vomitingbecause aspiration into lungs will increase the risk ofchemical pneumonia. Note: This material may be toxic if swallowed in large quantity. Cancer Information: None listed under OSHA/NTP/IARC .

--TOXICITY DATA --No information reported.

--REACTIVITY DATA --Stability and Conditions to Avoid: Elevated temperatures, radiation sources (ultraviolet light, etc.), oxygen-free atmosphere (deactivates polymerization inhibitor).

HazardDecompositionProducts: Fumes,smoke,carbonmonoxide,and carbon dioxide, in the case of incomplete combustion. Hazardoils Polymerization: This product will polymerize.

--SPILL AND EMERGENCY RESPONSE --For Spills: Materialcanpolymerize,causing it to release heat andbecome progressively thicker, leading ultimately to a solid form. If heat is not dissipated, closed containers maybecome hot, overpressured, and rupture. Evacuate unnecessary personnel. Extinguish ignition sources including electric supply. Shut off leakif possible withoutundue risk. Notify fire/pollution/water supply authorities. Blanket spill with water spray/fog or foam. On land, dike or impound large spill for recycle or recovery and prevent drainage to public waters. For small spill, absorbonto inert solids and transfer into suitable containers for transport or disposal. On water, material is insoluble and will float. Contain with booms, skim, or adsorb. If solid

Chapter 10 polymerforms,use solids removalequipment.Assure that anyclosed containers used to store spill cleanup residue are properly vented to prevent overpressure if residue continues to react and generate heat. The National if this material is released Response Center should be notified at to the environment.

Waste Disposal Method: Monomers are self-reacting chemicals that polymerize, liberating heat. Unless properly inhibited, such polymerization may result in formation of rigid or rubbery solids. In storage, this process may generate sufficient heat to raise internal temperature and pressure and rupture a container or vessel. Check weekly to confirm inhibitor polymer content. If inhibitor is below recommended level, take immediate steps to add supplemental inhibitor and mix well to make certain it is effective. Store in tightly closed or properly vented containers away from heat, sparks, open flame, or strong oxidizing agents. Do not store under inert atmosphere (deactivates inhibitor). The manufacturer recommends using the material within 6 months of purchase. Empty Containers: Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants.

- SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: If this material is handled at elevated temperature or under mist-forming conditions, NIOSH/MSHA-approved self-contained breathing apparatus operated in positive-pressure mode should be used. Type of Ventilation Required: Use only in well-ventilated area. Eye Protection Requirements: Eye protection, such as chemical splash goggles and/or face mask, must be worn when any possibility exists for eye contact due to splashing or spraying liquid. Contact lenses should not be worn. Protective Gloves and Other: When handlingthis material, protective clothing including gloves, apron, sleeves, boots, and head andface protection must be worn. This equipment must be cleaned thoroughly after each use. Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet facilities. Take a shower after work, using plenty of soap and water.

Amines

581

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. Note: This product has a 6-month shelf life. Other Precautions: Avoid breathing oil mist. Remove oil-soiled clothing and launder before reuse. Discard oil-soaked shoes. Wash skin thoroughly with soap and water after handling.

--REGULATORY INFORMATION --Transportation Incident Information: This product is unregulated by DOT at present. DOT Identification Number: Not applicable.

--IDENTIFIERS -Chemical Name and Synonyms: COUMARONE-INDENE Trade Name and Synonyms:

RESIN

Cumar P-IO

ChemicalFamily: ThermoplasticResin Manufacturer: Neville ChemicalCo., Pittsburgh, Pennsylvania UN ID Number: NA

- INGREDIENTS AND

%

No. Cas Material Cumar P-l0

COMPOSITION DATA --

NA

100

- PHYSICAL DATA BoilingPoint (“F‘):NA

TLV Not established

582

Chapter 10

Specific Gravity (H20= 1): 1.04 Vapor Pressure (mm Hg):NA Percent Volatile by Volume (%): Nonvolatile Vapor Density (air = FreezingPoint:

NA

NA

EvaporationRate: NA p H NA SolubilityinWater:

Negligible

Melting PointPour or Congealing Point: NA Viscosity: NA Appearance/Color/Odor: Light straw colored material with mild odor.

- FIRE AND EXPLOSION HAZARDS -Hash Point: 450°F (COC) Flammability Limits: NA Autoignition Temperature: NA Extinguishing Media: Chemical foam, water Special Fire Fighting Procedures: Wear protective clothing and mask. Unusual Fire and Explosion Hazards: None reported. Hazardous Products of Combustion and Decomposition: Carbon dioxide Hazardous Polymerization: Willnot occur.

583

Amines

- HEALTH HAZARD DATA -Effects of Overexposure: Manufacturer recommends avoiding skin andeye contact and to avoid excessive inhalation of dust. This material may cause skin irritation to people with allergic conditions. Emergency Response and First Aid: Skin: Flush all affected areas with plenty of water for 15 min. Remove and clean any contaminated clothing andshoes.Seekmedicalattention if skin irritation occurs. Eyes: Flush the eyes with plenty of running water for at least 15 min. Hold the eyelids apartduring the flushing to ensure rinsing the of surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: There are no effects or recommendations reported. Ingestion: Consultphysicianimmediately. Cancer Information: None listed under OSHA/NTP/IARC.

--TOXICITY DATA -No information reported.

--REACTIVITY DATA -Stability and Conditionsto Avoid: This product isstable but should bestored away from open flames. Materials to Avoid (Incompatibility): Excessive heat and open flames. HazardDecompositionProducts: Fumes,smoke, carbon monoxide,and carbon dioxide, inthecase of incompletecombustion. This materialhas similar properties to that of any organic chemical. HazardousPolymerization: Willnot occur.

--SPILL AND EMERGENCY RESPONSE --For Spills: Use any inert absorbent such as sand, earth, or vermiculite. The product is described as being slippery. Use proper safety equipment during cleanup.Disposeofin a mannerthat is consistentwith local, state, and federal regulations. After absorbent is applied, the area can be washed off with detergent.

Chapter

584

Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal site or facility. Wastematerialmaybe incinerated under conditions that meet federal, state, and local environmental control regulations. At present this is not classified as a RCRA hazardous waste. The manufacturer recommends mixing with more flammable solvent and incinerating. Empty Containers: Keep containers closed when not in use. Do not handle or store near heat, sparks, flames, or strong oxidants.

--- SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection: Normallynotneeded. Type of Ventilation Required: No recommendations are given by manufacturer. Local exhaust systems should use explosion-proof motors. EyeProtectionRequirements: contact may occur. Protective Gloves and Other:

Use splash goggles or face shield when eye

Use polyethylene protective gloves.

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. Note: This product has a 1 yr shelf life. Other Precautions: Avoid breathing oil mist. Remove oil-soiled clothing and launder before reuse. Discard oil-soaked shoes. Wash skin thoroughly with soap and water after handling.

--- REGULATORY INFORMATION --

DOT Identification Number: Not applicable.

Amines

585

--IDENTIFIERS -Chemical Name and Synonyms: PETROLEUM HYDROCARBON FAMILY,BLEND Trade Name and Synonyms: ChemicalFamily:

Escorez 2000 Series

PetroleumHydrocarbonResin

Manufacturer: ExxonChemical Co., Houston,Texas UN ID Number: NA

--INGREDIENTS AND COMPOSITION DATA --Material

Cas No.

%

Escorez 68527-25-3 2000

established Not

--PHYSICAL DATA -BoilingPoint (“F):NA SpecificGravity (H,O = 1): 1.02 VaporPressure(mmHg):

NA

Percent Volatile by Volume VaporDensity(air

=

NA NA

Freezing Point: 65 to 100°C (150 to 212°F) EvaporationRate: NA p H NA

Solubilityin Water: Insoluble Melting Point/Pour or Congealing Point: NA

Chapter 10

586

Viscosity: NA Appearance/Color/Odor: Pale yellow amber solid, flakes, or molten liquid.

--FIRE AND EXPLOSION HAZARDS -FlashPoint: 430°F(COC) FlammabilityLimits: NA AutoignitionTemperature:

NA

ExtinguishingMedia: Chemicalfoam,water Special Fire Fighting Procedures:

Wear protective clothing and mask.

Unusual Fire and Explosion Hazards:

None reported.

Hazardous Products of Combustion and Decomposition: Carbon dioxide Hazardous Polymerization: Will not occur.

--HEALTH HAZARD DATA --Effects of Overexposure: Material is described by manufacturer as posing the following hazards: Eye contact: Slightly irritating, but does not injure eye tissue. Skin contact: Frequent or prolonged contact may irritate. The material is described as having a low order of toxicity. Inhalation: Negligible hazard at ambient temperature (-18 to 38°C; 0 to 100°F). Dust may be irritating to eyes and respiratory tract. Ingestion: Minimaltoxicity. Themanufacturerrecommendsthefollowingoccupationalexposurelimit (OEL): 10 mg/m3 total dust for nuisance dust.

Emergency Response and First Aid: Skin: Flush all affected areas with plenty of water for 15 min. Remove and clean any contaminated clothing andshoes.Seekmedicalattentionifskin irritation occurs.

Amines

587

Eyes: Flush the eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: There are no effects or recommendations reported. Ingestion: Consult physician immediately. Manufacturer notes that first aid is normally not required. Cancer Information: None listed under OSHA/NTP/IARC.

--TOXICITY DATA -No information reported.

--REACTIVITY DATA -Stability and Conditions to Avoid: Do not heat above 200°C. Materials to Avoid (Incompatibility): Excessive heat and open flames. HazardDecompositionProducts: Fumes,smoke,carbonmonoxide,and carbon dioxide, in the caseofincompletecombustion.This material has similar properties to that of any organic chemical. HazardousPolymerization: Willnotoccur

--SPILL AND EMERGENCY RESPONSE -For Spills: Land spill: Eliminatesourcesof ignition. Prevent additional dischargeof material if possible to do so without hazard. For small spills, implement cleanup procedures; for large spills, implement cleanup procedures and, if in public area, keep public away and advise authorities. Also, if this product is subject to CERCLA reporting, notify the National Response Center. Recover spilled material and place in suitable containers for recycle or disposal. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. Water spill: Prevent additional discharge of material, if possible to do so without hazard. Advise authorities if floating material enters a watercourse or sewer. If possible, try to contain floating material. Skim from surface.

Chapter 10

588

Consult an expert disposal of recovered material and ensure conformityto local disposal regulations.

Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal site or facility. Wastematerialmaybe incinerated under conditions that meet federal, state, and local environmental control regulations. At present this is not classified as a RCRA hazardous waste. The manufacturer recommends mixing with more flammable solvent and incinerating. Empty Containers: Keep containers closed when not in use. Do not handle or store near heat, sparks, flames, or strong oxidants.

--SPECIAL PROTECTION AND PRECAUTIONS RespiratoryProtection: Where concentrations in air mayexceed the limits given by the manufacturer (OEL), work practice or other means of exposure reduction are notadequate.NIOSH/MSHA-approved respirators maybe necessary to prevent overexposure by inhalation. Type of Ventilation Required: No specific recommendations are givenby manufacturer. Local exhaust systems should use explosion-proof motors. Eye Protection Requirements: contact may occur.

Use splash goggles or face shield when eye

Protective Gloves and Other: Use polyethylene protective gloves. For open systems where contact is likely, wear safety glasses with side shields, long sleeves, and chemical-resistant gloves. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. Thismaterialshouldbe stored underambienttemperature conditions, The recommended storage and transport pressure for this product is atmospheric. Note that loading and unloading temperature recommended is ambient. Note that this materialcanposean electrostatic accumulation hazard. It should be handled using proper grounding procedures.

Amines

589

Other Precautions: Avoid breathing oil mist. Remove oil-soiled clothing and launder before reuse. Discard oil-soaked shoes. Wash skin thoroughly with soap and water after handling.

- REGULATORY INFORMATION --Department of Transportation DOT Hazard Class: Not regulated DOT Identification Number: Not available TSCA: This product is listed on the TSCA inventory as UVCB (Unknown, VariableComposition, or Biological) Chemical at CAS Registry Number 68527-25-3.

CERCLA: If this product is accidentally spilled, it is not subject to any special reporting under the requirementsof the ComprehensiveEnvironmental Response, Compensation, and Liability Act (CERCLA). The manufacturer recommends contacting local authorities to determine if there may be local reporting requirements. SARA TITLE m: Under the provisions of Title 111, Sections 311/312 of the Superfund Amendments and Reauthorization Act, this product is classified into the following hazard category: not hazardous.

--- IDENTIFLERS -4,4’-DI(A,A-DIMETHYLBENZyJ,)

Chemical Name and Synonyms: DIPHENYLAMINE Trade Name and Synonyms: ChemicalFamily:

Naugard 445

AromaticAmine

Manufacturer: UniroyalChemical Co., Middlebury,Connecticut UN ID Number: NA

Chapter 10

--

INGREDIENTS AND COMPOSJTION DATA

Material Product

TLV

%

Cas 10081-67-1

100

--

Not hazardous

--PHYSICAL DATA --BoilingPoint ("F): SpecificGravity (H,O =

1.14

VaporPressure(mm Hg): Percent Volatile by Volume (%): Low VaporDensity(air = 1): FreezingPoint: EvaporationRate: pH:

Solubility in Water: Soluble in most organic compounds. MeltingPoint: 203°F(95°C) Viscosity: Appearance/Color/Odor: White odor.

off white powderwitha

--- FIRE AND EXPLOSION HAZARDS --FlashPoint:

531°F (276.7"C)(COC)

FlammabilityLimits: AutoignitionTemperature: 569°F(298°C) fire point Extinguishing Media: Water spray, dry chemical.

characteristic

591

Amines

Special Fire Fighting Procedures: products.

Protect against inhalation of combustion

Unusual Fire and Explosion Hazards:May form explosive dust-air mixtures. Hazardous Products of Combustion and Decomposition: Oxides of carbon and nitrogen under burning conditions. HazardousPolymerization: Willnot occur.

--HEALTH HAZARD DATA --Effects of Overexposure: No acute or chronic health hazardshavebeen identified. There are no known medical conditions aggravated by exposure to this material. Emergency Response and First Aid: Skin: Flush all affected areas with plenty of water for 15 Remove and clean any contaminated clothing and shoes. Seekmedical attention if skin irritation occurs. Eyes: Flush the eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: Remove victim to fresh air. Ingestion: Consultphysicianimmediately. Cancer Information: None listed under OSHA/NTP/IARC.

- TOXICITY DATA -Animal Tests: Oral toxicity: LD50 (rats) 10 g/kg Irritation: eye (rabbits), negative; skin (rabbits), negative Mutagenicity: Ames salmonella, negative No significant adverse effects have been noted with long-term production and use of this material.

--REACTIVITY DATA --Stability and Conditionsto Avoid: This product isstable but should bestored awayfromopen flames. Product is stable at ambienttemperaturesand pressures.

592

Chapter

Materials to Avoid (Incompatibility): Strong oxidizing agents. HazardDecompositionProducts: burning conditions.

Oxidesofcarbonand

nitrogen under

HazardousPolymerization: Willnot occur.

- SPILL AND EMERGENCY RESPONSE -For Spills: Sweep or vacuumup.Shovel into secure containers for proper disposal. Avoid creating dust. Use personal protective equipment as outlined below. Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal site or facility. Wastematerialmaybe incinerated under conditions thatmeet federal, state, and local environmental control regulations. At present this is not classified as a RCRA hazardous waste. The manufacturer recommends mixing with more flammable solvent and incinerating. Empty Containers: Keep containers closed when not in use. Do not handle or store near heat, sparks, flames, or strong oxidants.

--- SPECIAL PROTECTION AND PRECAUTIONS -RespiratoryProtection: In absenceofadequate certified dust cartridge respirator.

ventilation, use NIOSH-

Type of Ventilation Required: No recommendations are given by manufacturer. Eye Protection Requirements: contact may occur. Protective Gloves and Other:

Use splash goggles or face shield when eye

Use polyethylene protective gloves.

Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. Note: This product has a 1 yr shelf life.

593

Amines

Other Precautions: Provide sufficient ventilation to minimize dust exposure. Avoid dust accumulation on building or equipment surfaces.

--REGULATORY INFORMATION --Transportation Incident Information: This product is unregulated by DOT at present.

DOT Identification Number: Not applicable.

--IDENTIFIERS -Name: N-OCTADECYLAMINE Synonyms: Adogenen 142; Alamine 7; Armeen 118D; n-Octadecylamine; Oktadecylamin (Czech); Stearylamine CAS: 124-30-1; RTECS:RG4150000 Formula: C,,H,,,N; MolWt: 269.58 WLN: Z18 ChemicalClass: Aliphatic amine

See other identifiers listed below under Regulations.

--PROPERTIES --BoilingPoint: NA Melting Point: 328.16 to 330.16 K; 55 to 57°C; 131 to 134.6"F FlashPoint: > 383.16 K; > 110°C; >230"F Autoignition: NA

UEL: NA LEL: NA Vapor Density: No data SpecificGravity: No data

Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data PolymerizationPossibilities: No data

Chapter 10

594

Toxic Fire None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: Not given Packaging exceptions: Nonbulk packaging: Bulkpackaging: STCC Number: Notlisted Clean Water Act Sect. 307: No Clean Water Act Sect. 311: No Clean Air Act: Notlisted EPA Waste Number: None CERCLA ReT:Notlisted RQ Designation: Notlisted SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant.

U.S. Postal Service Mailability:

Not given

--TOXICITY DATA --Short-term Toxicity:

Unknown

Long-term Toxicity: Unknown ConcIDLH:

Unknown

NOSH REL Not given ACGIH TLV: Notlisted ACGIH STEL: Not listed

OSHA PEL: Not in Table MAK Information: Not listed

595

Amines

Carcinogen: N; Status: Seebelow Carcinogen Lists: Z A R C Not listed; MAK: Not listed; NZOSH Not listed; NTP Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: orl-rat LD50:2395 mg/kg OtherSpeciesToxicityData: orl-rat LD50:2395 mg/kg orl-mus LD50:3 g/kg ipr-mus LD50:250 mg/kg

(Source:NIOSHRTECS1992)

Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

--

This chemical has

JNITIAL INCIDENT RESPONSE

known

---

No DOT Guide information for this product.

--- IDENTIFIERS --Chemical Name and Synonyms: DIPJ3ENYLAMINE-ACETONE CONDENSATE Trade Name and Synonyms: BLE 25 ChemicalFamily:

Amine

Manufacturer: UniroyalChemicalCo.,Naugatuck,Connecticut

UN IDNumber: NA

--INGREDIENTS AND COMPOSITION DATA Material 9003-79-6Product

No.

Cas

% 100

m Not established

Chapter 10

--

PHYSICAL DATA

Boiling Point ("F):> 170°C at

--

mm Hg

= 1): 1.08to 1.10

SpecificGravity

VaporPressure(mmHg):NA Percent Volatile by Volume (%): Low at 70°C VaporDensity(air = 1): NA FreezingPoint:NA EvaporationRate:

NA

p H NA Solubility in Water: Insoluble in water; soluble in acetone and benzene. MeltingPoint: NA Viscosity: 25 to 50 poises at 30°C AppearancelColorlOdor: Dark brown liquid. No odor description given by manufacturer.

-FlashPoint:

FIRE AND EXPLOSION HAZARDS ---

>230°F (TCC)

FlammabilityLimits: NA AutoignitionTemperature:NA Extinguishing Media: Water spray, foam, carbon dioxide. Special Fire Fighting Procedures: products.

Protect against inhalation of combustion

Unusual Fire and Explosion Hazards:

None reported by manufacturer.

597

Amines

Hazardous Products of Combustion and Decomposition: Oxides of carbon and nitrogen under burning conditions. HazardousPolymerization: Willnot occur.

- HEALTH HAZARD DATA -Effects of Overexposure: No acute or chronic health hazardshavebeen identified. There are no known medical conditions aggravated by exposure to this material. Emergency Response and First Aid: Skin: Flush all affected areas with plenty of water for 15 min. Remove and clean any contaminated clothing and shoes. Seek medical attention if skin irritation occurs. Eyes: Flush the eyes with plenty of running water for at least 15 min. Hold the eyelids apart during the flushing to ensure rinsing of the surface of the eye and lids with water. Seek medical attention if eye irritation occurs. Inhalation: Remove victim to fresh air. Ingestion: Consult physician immediately. Cancer Information: None listed under OSHA/NTP/IARC.

--TOXICITY DATA Animal Effects: Oral toxicity: LD50 (rats), mg/kg Dermal irritation (rabbit): slight Eye irritation (rabbit): slight No significant adverse effects have been noted with long-term production and use of this material.

--REACTIVITY DATA -Stability and Conditionsto Avoid: This product is stable but should be stored awayfromopen flames. Productis stable atambienttemperaturesand pressures. Materials to Avoid(Incompatibility): agents.

Strongmineral

acids and oxidizing

598

Chapter 10

HazardDecompositionProducts: burning conditions.

Oxidesofcarbonand

nitrogen under

Hazardous Polymerization: Will not occur.

--

SPILL AND EMERGENCY RESPONSE

--

For Spills: Absorb on industrial absorbent. Sweep up. Put into containers for proper disposal. Use proper personal protective equipment. Waste Disposal Method: Assure conformity with applicable disposal regulations. Dispose of absorbed material at an approved waste disposal site or facility. Wastematerialmaybe incinerated under conditions that meet federal, state, and local environmental control regulations. At present this is not classified as a RCRA hazardous waste. The manufacturer recommends mixing with more flammable solvent and incinerating. Empty Containers: Keep containers closed when not in use. Do not handle or store near heat, sparks, flame, or strong oxidants.

--- SPECIAL PROTECTION AND PRECAUTIONS -Respiratory Protection: In the absence of adequate ventilation, use NIOSHcertified dust cartridge respirator. Type of Ventilation Required: No recommendations are given by manufacturer. Eye Protection Requirements: contact may occur.

Use splash goggles or face shield when eye

Protective Gloves andOther: Use polyethylene protective gloves. Storage and Handling Precautions: Containers should be stored in a cool, dry, well-ventilated area. Store away from flammable materials, sources of heat, flame, sparks, and foodstuffs. Exercise due caution to prevent damage to or leakage from the container. Avoid any conditions that might tend to create a dust explosion. Maintain good housekeeping practices to minimize dust buildup. Note: This product has a 1 yr shelf life. Other Precautions: Provide sufficient ventilation to minimize dust exposure. Avoid dust accumulation building or equipment surfaces.

Amines

599

--REGULATORY INFORMATION -Transportation Incident Information: This product is unregulated by DOT at present.

DOT Identification Number: Not applicable.

--IDENTIFIERS --Name: N-ISOPROPYLN'-PHENn-P-PHENnENE"IAMINE Synonyms: Cyzone; Elastozone 34; N-Fenyl-W-Isopropyl-p-Fenylendiamin (Czech); Flexzone 3C; 4-Isopropylaminodiphenylamine;N-Isopropyl-W-Fenylp-Fenylendiamin (Czech); N-Isopropyl-W-Phenyl-p-Phenylenediamine; NCIC56304; Nonox ZA; N-Phenyl-W-Isopropyl-p-Phenylenediamine;N-ZPropyl-W-Phenyl-p-Phenylenediamine;Santoflex 36 CAS: 101-72-4; RTECS: ST2650000 Formula: C,5H,8NZ;MolWt: 226.35 WLN: lYMR DMR ChemicalClass: Aromaticamine See other identifiers listed below under Regulations.

--- PROPERTIES -BoilingPoint: NA MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density: No data SpecificGravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data PolymerizationPossibilities: No data

Chapter Toxic Fire None reported other than possible unburned vapors Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--

REGULATIONS

--

DOT hazard class: Not given Packaging exceptions: Nonbulk packaging: Bulkpackaging: STCC Number: Notlisted Clean Water Act Sect. 307: No Clean Water ActSect. 311: No Clean Air Act:Notlisted EPA WasteNumber: None CERCLA Ref: Not listed RQ Designation: Notlisted SARA TPQ Value: Not listed SARA Sect. 312 Categories: Acute toxicity: irritant.

U.S. Postal Service Mailability:

Not given

- TOXICITY DATA -Short-term Toxicity:

Unknown

Long-term Toxicity: Unknown Conc IDLH Unknown NOSH REL: Notgiven ACGIH TLV: Not listed ACGIH STEL: Notlisted

OSHA PEL: Not in Table MAK Information: Not listed

Amines

601

Carcinogen: N; Status: Seebelow CarcinogenLists: I A R C Not listed; MAK: Not listed; NIOSH Not listed; N T P Notlisted: ACGIH Not listed; OSHA: Not listed. LD50 Value: orl-rat LD50:720 mgkg OtherSpeciesToxicityData: (Source:NIOSH orl-rat LD50:720 mg/kg orl-mus LD50: 1122 mg/kg Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

RTECS 1992)

This chemical has no known

--- PROTECTION AND FIRST AID -Recommended Respiration Protection Source: NIOSH Pocket Guide (85-1 14) NIOSH (N-Isopropyl-llr-Phenyl-p-Phenylene-Diamine)100 ppm: Any supplied-air respirator. Substance reported to causeeye irritation or damage may require eye protection. Any self-contained breathing apparatus. 250 ppm: Any supplied-air respirator operated in a continuous-flow mode. Substance reported to causeeye irritation or damagemay require eye protection. 3OOppm: Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. Emergency or Planned Entryin Unknown Concentrationsor IDLH Conditions: Any self-contained breathing apparatus with a full facepiece and operated in pressure-demand a or other positive-pressure mode. Any supplied-air respirator with a full facepiece and operated in a pressure-demand or other positive-pressure mode in combinationwithan auxiliary self-contained breathing apparatus operated in a pressuredemand or other positive-pressure mode. Escape: Any air-purifying full facepiece respirator (gas mask) with a chinstyle or front- or back-mounting canister. Any appropriate escape-type selfcontained breathing apparatus.

602

Chapter 10 IDENTIFIERS

--

Name: SELENIUM, TETRAKIS@OCARBAMATO)Synonyms: Ethyl Selenac; EthylSeleram;Selenium Diethyldithiocarbamate; Tetrakis(Diethy1carbamodithioato-S,S’)Selenium; Tetrakis(Diethy1dithiocarbamato)Selenium CAS: 5456-28-0; RTECS: VT07oooOO Formula: C2,,H,N,S, Mol Wt: 672.08 WLN: 2N2 See other identifiers listed below under Regulations.

--- PROPERTIES --Boiling Point: NA MeltingPoint: NA FlashPoint: NA Autoignition: NA UEL: NA LEL: NA Vapor Density: No data Specific Gravity: No data Reactivity with Water: No data on water reactivity Reactivity with Common Materials: No data Stability during Transport: No data Neutralizing Agents: No data Polymerization Possibilities: No data Toxic Fire Gases: Oxides of nitrogen Odor Detected at (ppm): Unknown Odor Description: No data 100% Odor Detection: No data

--REGULATIONS -DOT hazard class: Not given Packaging exceptions: 173. Nonbulk packaging: 173. Bulk packaging: 173. STCC Number: Not listed

Amines Clean Water Act Sect. 307: Yes 311: No Clean Water Act Clean Air Act: CAA '90 by category EPA Waste Number: DO10 CERCLA Ref: Notlisted RQ Designation: Notlisted SARA TPQ Value: Not listed SARA Sect. 312 Categories: Nocategory Listed in SARA Sect. 313: Yes De Minimus Concentration: 1

U.S. Postal Service Mailability:

Not given

--TOXICITY DATA -Short-term Toxicity:

Unknown

Long-term Toxicity: Unknown ConcIDLH:

Unknown

NIOSH REL: Notgiven ACGIH TLV: TLV = 0.2 mg/m3 as selenium ACGIH STEL: As selenium

OSHA PEL: TransitionalLimits: TWA = 0.2 mg/m3

PEL = 0.2 mg/m3;FinalRuleLimits:

MAK Information: Not listed Carcinogen: N; Status: Seebelow References: Animal indefinite IARC** 9,245,75; Animal indefinite IARC** 12, 107, 76 CarcinogenLists: ZARC Notclassified as to humancarcinogenicity or probably not carcinogenic to humans; MAK: Not listed; NZOSH Not listed; NTP: Not listed; ACGZH Not listed; OSHA: Not listed. LD50 Value: No LD50 in RTECS 1992

Chapter 10

604

Reproductive Toxicity (1992 RTECS): mammalian reproductive toxicity.

This chemical has no known

--IDENTIFIERS -Name: HVA-2 MSDSNumber: HVAOOl Manufacturer/Distributor: DuPontPolymers,Wilmington,Delaware Chemical Family: N, N’-m-Phenylene Dimaleimide CAS Number: 3006-93-7

--COMPONENTS -Material

No.

Cas

%

100 NI-m-Phenylenebis3006-93-7 N, maleimide No skin or eye irritation tests have been run specifically on HVA-2. Tests on a closely similar product show it to be a primary skin irritant and capable of causing eye damage.

- PHYSICAL DATA -MeltingPoint:

195°C

Specific Gravity:

1.44

PercentVolatiles:

NA

Solubilityin Water: Negligible Color: Yellow to light brown Odor: Essentially none

Form: Powder

Amines

605

- HAZARDOUS REACTIVITY -Stability at RoomTemperature: Stable. Materials to Avoid: None are known. Conditions to Avoid: None are known. Hazardous Decomposition Products: Carbon monoxide and nitrogen oxides. Polymerization: Willnot occur.

- FIRE AND EXPLOSION HAZARDS Flash Ignition Temperature: Above208°C. Method: Open cup. Unusual Fire, Explosion Hazards:

No unusual hazards known.

HazardousCombustionProducts:

Carbon monoxide, nitrogen oxides.

Extinguishing Media: Water, carbon dioxide, foam, dry chemical. Special Fire Fighting Instructions: Use self-contained breathing apparatus if exposed to fumes.

--HEALTH HAZARD DATA --Before using HVA-2, read the bulletin on the safe handling of this material.

Acute or Immediate Effects: Routes of Entry and Symptoms: Ingestion: The LD50 ofHVA in rats is 2025 mgkg bodyweight.This classifies the material as being slightly toxic. Ingestion is not a probableroute of exposure. Skin: No data are available on HVA-2. Tests on a similar product showed that it is a strong primary irritant to guinea pig skin. Results are predicted to be similar for HVA-2. HVA-2 is probably not a skin sensitizer.

Chapter 10

606

Eye: No data are available on HVA-2. Tests on a closely similar product showed it is an eyeirritant capable of causingsevere and irreversible damage. TreatHVA-2 as if it had the same reaction. Avoid all eye contact with HVA-2. Inhalation: There are no data on the inhalation toxicity of HVA-2. In view of the fact that it may be a strong skin irritant and strong eye irritant, dust from HVA-2 should not be inhaled.

Medical Conditions Aggravated byExposure: Skin dermatitis problems will be aggravated by exposure to HVA-2. Carcinogenicity: None of the components in this material is listed by IARC, NTP, OSHA, or ACGIH as a carcinogen. ExposureLimits: established.

TLV(ACGIH),none

established; PEL (OSHA),none

Safety Precautions: See First Aid and Protection Information sections.

--

FIRST AID

If exposed to fumesfromoverheating Consult a physician.

--

or combustion,move

to fresh air.

Wash skin with soap and plenty of water. Flush eyes with water. Consult a physician

--- PROTECTION INFORMATION -Generally Applicable Control Measures and Precautions: Ventilation: During handling and use of HVA-2, local ventilation must be used to prevent breathing of dust or fumes. Personal Protective Equipment: Eye: Eye protection is required to prevent dust from getting in the eyes. Skin: Impermeable gloves are required to prevent skin contact. Respirator: Required if local ventilation is not adequate.

Amines

- DISPOSAL INFORMATION -Spill, Leak, or Release: Note: Review Fire and Explosion Hazards and Safety Precautions sections before proceeding with cleanup. Use appropriate personal protective equipment during cleanup. Material should be vacuumed up or swept up. Exercise caution to not create a dusthazard.Wear equipment.

appropriate protective

Aquatic toxicity: No data are available. Material is probably toxic to fish.

Waste Disposal: Landfill or incinerate in accordance with federal, provincial, and local regulations.

--- STORAGE CONDITIONS -Store in a cool dry place. Keep containers closed to prevent contamination.

--TITLE III HAZARD CLASSIFICATIONS -Section 313 SupplierNotification: This productcontains no known toxic chemicalssubject the reportingrequirements of Section ofthe Emergency Planning and Community Right-to-Know Act of and of 40 CFR

--ADDITIONAL INFORMATION AND REmRENCES --NA = Not applicable NE = Not established # = New or revised information in this section when # is in right margin.

State Right-to-Know Laws: No substances on the state hazardous substances list, for the states indicated below, are used in the manufacture products this Material Safety Data Sheet, with the exceptions indicated. While we do not specifically analyze these products or the raw materials used in their manufacture for substances various state hazardous substanceslists, to the best of our knowledge the products this Material Safety Data Sheet contain no such substances except for those specifically listed below:

608

Chapter 10

Substances on the Pennsylvania Hazardous Substances List Present Concentration of or More: None known.

at a

Substances on the Pennsylvania Special Hazardous Substances List Present at a Concentration of 0.01%or More: None NonhazardousIngredientsPresent at aConcentration of 3%or More Requiredto be Listed by Pennsylvania: Since this product contains hazardous substances as defined by the Pennyslvania R-T-K Regulations, a MSDS is not required law. Warning:Substances Known to the State of California to Cause Birth Defects or Other Reproductive Harm: None known. substances on the New Jersey Workplace Hazardous Substance List Present at aConcentration of 1% or More (0.1% for SubstancesIdentified as Carcinogens, Mutagens, or Teratogens): None known.