Water-Soluble Resins 2nd Edition An Industrial Guide

WATER-SOLUBLE RESINS An Industrial

Guide

Second Edition

Ernest W. Flick

cl *P

NOY ES PUBLICATIONS Park

Ridge,

New

Jersey,

USA.

Copyright 01991 by Ernest W. Flick No part of this book may be reproduced any form or by any means, electronic or including photocopying, recording or by tion storage and retrieval system, without in writing from the Publisher. Library of Congress Catalog Card Number: ISBN: O-8155-1274-0 Printed in the United States Published in the United States of America Noyes Publications Mill Road, Park Ridge, New Jersey 07858

or utilized in mechanical, any informapermission 91-8388

by

10987854321

Library Flick,

of Congress Cataloging-in-Publication

Data

Ernest W. Water-soluble resins : an industrial guide / by Ernest W. Flick. p. cm. Includes index. ISBN O-8155-1274-0 1. Gums and resins. 2. Gums and resins, Synthetic. 3. Water -soluble polymers. I. Title. TP978.F58 1991 91-8388 888’.37--dc20 CIP

Preface

The second edition of this popular industrial guide contains descriptions of more than 1100 currently avaiiable water-soluble resins, supplied by 47 manufacturers or distributors of these products. Both natural and synthetic resins are included. The book will be of value to technical and managerial personnel involved in the final products made with these resins, as well as the suppliers of basic raw materials. Types of water-soluble resins included in the book are cellulose ethers; collagens; gelatins; natural gums; and synthetic resins, their dispersions, emulsions, and solutions. The data in the book represent selections from manufacturers’ descriptions made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent information has been included. It is believed that all of the products listed are currently available, which will be of utmost interest to readers concerned with product discontinuances. The book lists the following own words, for each product:

information,

as available, in the manufacturer’s

(1)

Company name and product category;

(2)

Trade names and product numbers;

(3)

Product description-important

features, properties and applications.

Products are presented by company, and the companies are listed alphabetically. Also included in the book are a Trade Name Index and a Resin Index, for easy and rapid location of products by the reader. In addition, another section, which will be useful, contains Suppliers’ Addresses. It can be found immediately following the Product Information Section. V

vi

Preface

My fullest appreciation is expressed to the companies and organizations which supplied the data included in the book. April, 1991

Ernest W. FI ick

NOTICE To the best of our knowledge the information in this publication is accurate; however, the Publisher does not assume any responsibility for the accuracy or completeness of, or consequences arising from, such information. This industrial guide does not purport to contain detailed user instructions, and by its range and scope could not possibly do so. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Publisher. In some cases water-soluble resins could be potentially toxic, and therefore due caution should be exercised. Final determination of the suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We strongly recommend that users seek and adhere to a manufacturer’s or supplier’s current instructions for handling each material they use. The Author and Publisher have used their best efforts to include only the most recent data available. The reader is cautioned to consult the supplier in case of questions regarding current availability.

Contents and Subject Index

PRODUCT INFORMATlON Abatron, Inc. Water-Reducible Epoxy Coatings ABOKOTE, PRIMEKOTE Aceto Corp. CELACOLKOURLOSE Water-Soluble Cellulose Ethers EPOMIN Polyethylene lmines Air Products and Chemicals, Inc. AIRFLEX Ethylene-Vinyl Chloride (EVCL) for Building Products Applications AIRFLEX RP Redispersible Powders AIRVOL Polyvinyl Alcohol Super Hydrolyzed Fully Hydrolyzed Intermediate Hydrolyzed Partially Hydrolyzed Tackified Grades (Typical Properties) UNISIZE Emulsions for Adhesive Products AIRFLEX Vinyl Acetate-Ethylene Emulsions, VINAC Polyvinyl Acetate Homopolymer Emulsions, FL EXCR YL Acrylic Emulsions, FLEXBOND Polyvinyl Acetate Copolymer Emulsions Emulsions for Building Products AIRFLEX Vinyl Acetate-Ethylene Emulsions, AIRFLEX Acrylic Emulsions, AIRFLEX Ethylene- Vinyl Chloride Emulsions, VINAC Polyvinyl Acetate Homopolymer Emulsions, AIRFLEX Vinyl Acetate-Ethylene Powders, FLEXBOND Vinyl Acrylic Emulsion Emulsions-for Paper and Paperboard VINAC Polyvinyl Acetate Emulsions, AIRFLEX Vinyl-Ethylene Emulsions, AIR FLEX Ethylene- Vinyl Chloride Emulsions vii

1 2 2

5 11 12 12 14 18 18 18 19 20 21 22

29

35

viii

Contents and Subject Index VANCRYL Acrylic Resins VANCRYL Styrene-Acrylic Emulsions VANCRYL Vinyl Chloride-Ethylene Resins for Waterborne Inks and Overprint Varnishes VINEX Thermoplastic Polyvinyl Alcohol Copolymer Resins: 2000 Series Alto Chemical Corp ALCOCLEAR ACP ALCOCLEAR CCP-I and CCP-II Water Clarification Polymers AQUATREAT Industrial Water Treatment Products Polyacrylic Acids, Sodium Polyacrylates, Sodium Polymethacrylates, Copolymers Aqualon AQUALON Cellulose Gum: Sodium Carboxymethylcellulose AQUALON CMC-T Sodium Carboxymethylcellulose CULMINAL Methylcellulose/Methylhydroxyethylcellulose/Methylhydroxypropylcellulose/Carboxymethylmethylcellulose KLUCEL Hydroxypropylcellulose NATROSOL Hydroxyethylcellulose NATROSOL PLUS, Grade 330, Modified Hydroxyethylcellulose NATROVIS Hydroxypropyl Hydroxyethylcellulose SUPERCOL Guar Gum Bercen, Inc. BERSET 2647 Crosslinker and Cellulose Reactant BERSET 2100 Crosslinker/lnsolubilizer BERSET 2185 Coating lnsolubilizer BERSET 2586 Crosslinker and lnsolubilizer Callaway Chemical Co. Acrylamide Copolymers-Cationic: Cationic PAM/DMDAAC Type JA YFLOC Acrylamide Polymers: Cationic PAM/DMAEMA Type Acrylamide Polymers: Nonionic and Anionic PAMINAAA Type Polyamines: Aminomethylated Polyacrylamide (Mannich or AMPAM) Type Polyamines: Dimethyl Diallyl Ammonium Chloride (DMDAAC) Type Polyamines: Epichlorohydrin Type (EPI) Polyamines: Melamine-Formaldehyde Products (MF) Cargill, Inc. Water Reducible Resins Epoxy Ester, Alkyds-Oxidizing, Alkyds-Oxidizing ChainStopped, Alkyds-Non-Oxidizing, Silicone Modified, Vinyl Modified, Phenolic Modified, Oil Free Polyesters Cook Paint and Varnish Co. COROC Alkyd Resins COROC B-453-V8 Water Reducible Styrenated Epoxy Resin COROC B-1537-M Water Reducible Acrylic Modified Alkyd COROC R-1782-V8 Water Reducible Polyester

40 43 45 47 48 48 49 50

54 54 57 58 60 63 66 67 68 70 70 71 72 73 74 74 77 86 90 92 95 98 100 100

111 111 112 113 114

Contents and Subject Index

COROC S-432-M Water Reducible Alkyd COROC T-1070-M Water Reducible Alkyd Resin COROC XL-l 128-M Water Dispersible Alkyd COROC Z-1722-M Water Dispersible Chain Stopped Alkyd Resin COROC Z-1726-M Water Dispersible Chain Stopped Alkyd COROC Z-1726-Ml Water Dispersible Chain-Stopped Alkyd COROC Z-1727-M Water Dispersible Chain Stopped Alkyd Resin COROC Z-1727-Ml Water Dispersible Chain Stopped Alkyd COROC Z-2055-M Water Reducible Chain Stopped Alkyd Resin CPS Chemical Co., Inc. Polymers: Dimethylamine/Epichlorohydrin Copolymers AGEFLOC Polymers: pDMDACs-Copolymers and Miscellaneous AGEOUAT Polymers: pDMDACs-Paper Industry AGESTAT Polymers: pDMDACs-Water Treatment Polymers: Polymeric Aluminum Salts Polymers: Polymeric Carboxylic Acids AGESPERSE Dock Resins Corp. Acrylic Resins DORESCO, AQUA-HYDE Dow Chemical Co. METHOCEL Cellulose Ethers PRIMACOR Dispersible Polymers DuPont ELVANOL Polyvinyl Alcohol General Purpose, Textile, and Specialty and Adhesive Grades Dynagel, inc. Gelatin Firestone Synthetic Rubber & Latex Co. HARTEX Natural Latex FMC Corp. MARINE COLLOIDS Carrageenan GELCARIN Carrageenan Systems-Water Gelation, SEAGEL Carrageenan Systems-Milk Gelation, VISCARIN Carrageenan Systems-Water Viscosity, SEA KEM Carrageenan Systems-Milk Viscosity, VISCA RIN Carrageenan Systems-Cold Soluble, LACTARIN Carrageenan Systems-Cold Soluble Freeman Chemical Corp. CHEMPOL 10-0091 Water Reducible Alkyd CHEMPOL lo-0095 Water Reducible Alkyd CHEMPOL lo-0097 Water Reducible Alkyd CHEMPOL 19-0503 Water Reducible Polyester CHEMPOL 10-l 105 Water Reducible Alkyd CHEMPOL lo-1210 Water Reducible Alkyd CHEMPOL 10-1300 Water Reducible Copolymer

ix

115 116 117 118 119 120 121 122 123 124 124 126 127 129 131 132 133 133 136 136 139 141 141 144 144 145 145 146 146

152 153 154 155 156 157 158

x

Contents and Subject Index CHEMPOL 1O-l 313 Water Reducible Copolymer CHEMPOL lo-1602 Epoxy Ester Genesee Polymers Corp. GP-165 Silicone Resin Emulsion GP-223 Silicone Resin Emulsion B.F. Goodrich Co. CARBOSET High Performance Polymers for Graphic Arts, Electronics and Coatings Water Dispersion Products, Specialty Products, Dry Products GEON Vinyl Chloride Latexes Resin, Plastic, Internally Plasticized, Vinylidene Chloride GOOD-RITE SB and Vinyl Pyridine Latexes HYCAR Acrylic Latexes Very Soft, Soft, Medium, Firm, Stiff, Hard HYCAR Nitrile Latexes HYSTRETCH Elastomeric Latexes Goodyear Chemicals CHEMIGUM Nitrile Latices GOODYEAR Textile Resin Latex PLIOCORD Vinyl Pyridine Latex PLIOLITE Solution Resins PLIOLITE SBR Rubber Latex PLIOLITE WR-D Water Reducible Thermoplastic Polymer WINGTACK Hydrocarbon Resins WING TACK PLUS, WING TACK EXTRA W.R. Grace 61 Co. DARATAK Adhesive Emulsions Borax Compatible Homopolymers, Non-Borax Compatible Homopolymers, Non-Borox Compatible Copolymers, Special and Blended Systems DAREX Copolymer Latexes 100 Series- Nitriles, 400 Series-Acryla tes EVERFLEX/VERSAFLEX Paint/Coating Emulsions H & C Industries, Inc. ALKOX Polyethylene Oxide Resin Henkel Developmental Water Borne Polyamides GAX G-CRYL Acrylic Resins G-CRY L 250 Acrylic Resin Solution G-CRYL 345 Acrylic Resin Solution G-CRYL 535 Acrylic Resin Solution Hercules, Inc. HERCULES Resin Dispersions FORAL, HERCOL YN, PICCOPALE, PICCOTAC, PICCOVAR, STAYBELITE ESTER PICCONOL Hydrocarbon Resin Emulsions

159 160 161 161 162 163 163 168 172 174 178 181 182 182 183 184 185 188 189 190 192 192

198 199 202 202 203 203 206 210 211 212 213 213

219

Contents and Subject Index

PICCOTEX LC55WK Resin Emulsion DRESINOL Resin Dispersions VINSOL Resin Emulsion Hi-Tek Polymers, Inc. CMD W55-5093 Epoxy Resin Dispersion CMD W60-3515 Epoxy Resin Dispersion CMD W66-5520 Epoxy Resin Dispersion CMD WJ55-3540 Epoxy Resin CMD WJ60-6537 Curing Agent CMD 9790 Acrylic Dispersion EPICURE W50-8535 Curing Agent EPI-REZ WJ-3520 Epoxy Resin EPI-REZ WJ-5522 Epoxy Resin EPI-REZ 35201 Epoxy Resin Dispersion EPI-TEX 611-Q Epoxy Ester Emulsion, Epoxy Water-Reducible Resins Hoechst Celanese Corp. TY LOSE Hydroxyethylcellulose TYLOSE Methylhydroxyethylcellulose TYLOSE Sodium Carboxymethylcellulose Hormel Collagens Dried POL YPRO 5000 Liquid PEPTEIN 2000, PROTECTEIN Gelatins FLA VORSET Gelatin, Gummy Type Gelatin Huls America, Inc. HYDROSI L Silanes Amine, Epoxy, Mercapto, Methacrylate, Vinyl, Vinyl-Amino ICI Resins US HALOFLEX Vinyl/Acrylic Terpolymers NEOCRYL Acrylic Emulsions NEOREZ Water-Borne Polyurethane Dispersions NEOTAC Water-Borne Polymers for Adhesives Mobay Corp. BAYBOND Aqueous Polyurethane Dispersions Monsanto Chemical Co. RESIMENE Amino Crosslinker Resins High Solids Meth ylated Melamines (HSMM), Modified HSMM, High Solids Butylated Melamine, High Solids Methylated/ Butylated Melamines, HS Meth ylated Urea Morton International, Inc. LYTRON General Purpose Polystyrene Latices LYTRON Plastic Pigments: Polystyrene MOR-FL0 Concrete Coatings NL Chemicals, Inc.

xi 221 222 226 227 227 228 229 230 231 232 233 234 235 236 237 238 239 239 240 242 244 244 244 244 246 250 250 251 251 254 267 271 274 274 278 278

287 287 288 290 291

xii

Contents and Subject Index Acrylic Polymers AROLON Norland Products Inc. HIPURE Liquid Gelatin Occidental Chemical Corp. High Molecular Weight PVC Suspension Resins OXY OXY 160 Suspension Resin OXY 185 Suspension Resin OXY 190 Suspension Resin OXY 200 Suspension Resin OXY 225 Suspension Resin OXY 225PG Suspension Resin OXY 230 Suspension Resin OXY 240 Suspension Resin OXY 250 Suspension Resin C.J. Osborn Water Reducibles Polyesters, Epoxy Esters, Alkyds, W. R. Acrylics

291

Oxychem PLYOPHEN Resins for Laminating Applications Industrial Laminates, Filament Winding, High Temperature MIL-Spec Laminates VARCUM Abrasive Resins: Grinding Wheel Resins-Liquid VARCUM Resins: Coated Abrasive Resins Polysat Inc. POLYSAT Emulsions POLYSAT (ERC45%) Emulsion Resin Concentrate POLYSAT Hydrocarbon Resin Emulsions POLYSAT SAE Styrene Acrylate Chemical Resistant VOC Emulsion 45% Solids Ranbar Technology inc. G-4510-BC-75 Water Soluble Alkyd Resin G-4510-S-75 Water Soluble Alkyd Resin G-4674-8S75 Water Soluble Alkyd Resin G-4680-BP-75 Water Soluble Alkyd Resin G-4714-P-75 Water Soluble Alkyd Resin Reichhold Chemicals, Inc. AROLON 465-G4-80 Polyester Resin AROLON 557-B-70 Acrylic Resin AROLON 559-G4-70 Acrylic Resin AR0 LON 580-W-42 Alkyd Resin AROLON 585-W-43 Alkyd Resin AROLON 820-W-49 Styrene Acrylic Emulsion AROLON 840-W-39 Acrylic Emulsion AROLON 845-W-45 Styrene Acrylic Emulsion AROLON 850-W-45 Acrylic Copolymer Emulsion AROLON 860-W-45 Acrylic Copolymer Emulsion

308 308

293 293 294 294 296 296 297 297 298 298 299 299 300 301 301

310 311 314 314 315 316 317 318 318 319 320 321 321 322 322 323 324 325 326 327 328 329 330 331

Contents and Subject Index

AROLON 970-G4-70 Alkyd AROLON 921-G4-70 Alkyd KE LSO L 3900-BG4-75 Alkyd KE LSO L 3904-864-75 Alkyd KELSOL 3905-B2G-75 Alkyd KELSOL 3906-B2G-75 Alkyd KELSOL 3907-G2B-75 Water Reducible Resin KELSOL 3909-864-75 Water Dispersible Resin KELSOL 3910-826-75 Alkyd KE LSO L 391 B-826-70 Alkyd Resin KELSOL 391 g-826-70 Alkyd Resin KELSOL 3922-G-80 Alkyd Resin KELSOL 3950-826-70 Alkyd Resin KELSOL 3960-826-75 Alkyd Resin KELSOL 3961~62G-75 Alkyd Resin KELSOL 3962-826-70 Alkyd Resin KELSOL 3963-B2G-70 Alkyd Resin KELSOL 3970-G4-75 Alkyd Resin KE LSO L 3980-G4-75 Alkyd Resin KELSOL 3990-826-70 Alkyd Resin SPENSOL L Water Reducible Urethane Resins Aliphatic, Aromatic Sartomer Co. SARTOMER Water Dispersible Monomers StanChem Inc. Polymers and Polymeric Specialties Paints and Building Products Polymers, Paper and Paperboard Coatings, Textiles, Caulks and Sealants, Adhesives and Binders, Thickeners and Additives Thibaut 61 Walker Vinyl Acrylic Copolymer Emulsion PARC0 Water Reducible Resins SUPER ALKYD Alkyds, SUPER POLYESTER Oil Free Polyesters, SUPER THANE Oil Modified Urethanes 100% Acrylic Emulsions PARCRYL TIC Gums, Inc. NUTRILOID Soluble Dietary Fibers Arabic, Guar, Locust Bean, Tragacanth, Agar, Carrageenan, Alginate, Xanthan, Cellulose, NUTRILOID TICALOIDS TIC Guar Gum TICALOSE Cellulose Gum Low Viscosity Grades, Medium Viscosity Grades, High Viscosity Grades, “Resistant “ Grades TICAXAN Xanthan Gum Union Carbide Corp. CELLOSIZE Hydroxyethyl Cellulose HEC

xiii

332 333 334 335 336 337 336 339 340 341 342 343 344 345 346 347 348 349 350 351 352 358 358 362

371 371 373

376 380 380

362 383

365 366 386

xiv

Contents and Subject Index POLYOX Water-Soluble Resins Unocal Chemicals Division Acrylic Carboxylated Styrene Butadiene Polyvinylidene Chloride Styrene Acrylic Vinyl Acetate Homopolymer Vinyl Acrylic R.T. Vanderbilt Co., Inc. RHODIGEL Xanthan Gum RHODOPOL Industrial Grade Xanthan Gum

SUPPLIERS’ TRADE

ADDRESSES

NAME INDEX

RESIN INDEX

389 393 393 401 411 413 414 417 423 423 424 425 429 433

PRODUCT

INFORMATION

2

Water-Soluble

Resins

ABATRON, INC.: Water-Reducible ABOKOTE 8106-l: 2-part white epoxy/water able also in other colors.

Epoxy Coatings:

system. High-gloss

enamel. Avail-

Uses: - Floors, Walls. - Damp surfaces. - Fresh-poured concete. - Painted surfaces. - Safety requirements. Characteristics: Part A: White opaque resin. Part B: Clear hardener. solids: 65.5% (54% by vol.). Lbs/Gallon, Part A: 13.6. ,I 11 B: 8.5 Lbs. by volume. Ratios: l/1 Viscosity: 800-1200 cps. Pot Life- 24 hrs, 40%-R.H. PVC: 18.2%. Thinnins: with tap water. Inducti& Period:-30-45 min. 60 Gloss: 95+ across pot life. +B Gardner Yellowing:-3.4. Chemical Properties: (6 mil wet, 3-3.5 mil dry film, 7-10 clays @ 21C, 40% R.H.): 20% NaOH or 10% HCl: No softenins or blisterincr after 24 hrs 500 cotton swag rubs: Xylene: Slight softening, no gloss loss. MEK: Slightly soft, gloss drop.

Abatron,

ABATRON, INC.: Water-Reducible PRIWEKOTE 8106-2: 2-part red epoxy/water

Inc.

3

Epoxy Coatings(Continued):

system. Metal maintenance

primer.

Uses:

- Metal structures. -

Damp surfaces. Industrial equipment. Painted surfaces. Safety requirements.

Characteristics: Part A: Red opaque resin. Part B: Gray opaque hardener. Solids: 65%. (49% by vol.). Lbs/Gallon, Part A:-14.4 II II B: 10.8 II Ratios: l/l by volume. Viscosity: 1100-1200 cps. Pot Life: 4-6 hrs. PVC: 50.4%. Thinning: with tap water. Induction Period: 20-30 min. Gloss: flat. Chemical Properties: (2-3 mil film, 2 coats on polished steel, cured 3 days @ 21C). 30-Day Water Immersion: No blisters, ~2 pencil hardness drop. Salt Fog: 500 hrs: slight rusting in scribe. 1000 hrs: no blisters

4

Water-Soluble

ABATRON,

Resins

INC.: Water-Reducible

PRIMEKOTE 8106-6: l-part gray epoxy/water in other colors.

Epoxy Coatings(Continued):

system. All purpose primer. Also

Uses: - On fresh-poured concrete. - Damp underground surfaces. - Floors, walls. - Fast recoating cycles. - Safety requirements. Characteristics: Part A: Gray opaque resin. Part B: Gray opaque hardener. Solids: 65% (49% by vol.). Lbs/Gallon, Part A: 14.4. II B: 10.8. I, 11 Ratios: l/1 by volume. Viscosity: 1000-1200 cps. Pot Life- 4-6 hrs. PVC: 50.5% Thinning: with tap water. Induction Period: 30-45 min. Gloss: flat. Chemical Properties: (2-3 mil film, 2 coats on polished

steel, cured 3 days @ 21C).

30-Day Water Immersion: hardness drop. no blisters,. <2 oencil _ Salt Fog: 500 hrs: sliqht rusting in scribe. 100 hrs: no blisters

Aceto Corp.

ACRTO CORP.: CRLACOL/COURLOSE

Water-Soluble

Cellulose Ethers:

Trademarks used by Courtaulds Acetate Limited for the watersoluble cellulose products they offer. Properties of CELACOL AND COURLOSE: CELACOL and COURLOSE are supplied as white to cream powdered, or granular materials in a wide range of chemical types and viscosity grades. Standard types of CELACOL and COURLOSE: Purified: CELACOL M: Methyl cellulose Approximate DS: 1.6 MM: Methyl cellulose Approximate DS: 1.9 HPM: Hydroxypropyl methyl celluose Approximate DS: methyl 1.5 hydroxypropyl: 0.3 COURLOSE SCMC: sodium carboxymethyl cellulose Approximate DS: hydroxypropyl 0.3 0.5-0.7 0.75-0.90 Standard types of CELACOL and COURLOSE: Technical: COURLOSE SCMC sodium carboxymethyl cellulose Substitution type: medium Approximate DS: 0.5-0.65 Substitution type: high Approximate DS: 0.75-0.90 CELACOL Gums/COURLOSE Gums--Food grades: Materials specially made for foodstuffs and pharmaceuticals are described as CELACOL and COURLOSE Gums. These are available in most of the purified types. For CELACOLS, 'GP' suffix on the grade denotes food quality. For COURLOSES, 'P' prefix on the grade denotes food quality. Physical Forms of CELACOL and COURLOSE: CELACOL: powder: ranid solubilitv powder DS: easy solubilityfine powder: rapid solubility after premixing COURLOSE: powder standard-and fine: rapid solubility granular: easy solubility

5

6

Water-Soluble Resins

ACRTO CORP.: CRLACOL/COURLOSE Water-Soluble Cellulose Ethers (Continued): Standard Viscosity Grades of CELACOL and COURLOSE: CRLACOL: Grade M20 Ml00 M450

Ml000 M2500 MS000 Ml0000 MM10 MM100 MMPRlP HPM450 HPM2500 HPM5000 HPM15000 HPM30000

Viscosity cps (2% aqueous solution 2OC) 17-23 85-115 350-550 850-1150 2200-2800 4000-6000 8000-12000 9-11 85-115 35011550 2200-2800 4000-6000 13000-17000 25000-30000 approx#

# Viscosity of standard MMPR 1P measured at 1.5% cont. w/v in 80:20 v/v methylene chloride: methanol mix-200-250 cps. Other specifications by arrangement. COURLOSE Technical A&N: Alkaline: Grade: A200: Physical form: Powder Viscosity cps (1% aqueous 25C): 3-6 Active content % (dry basis): 60-64 A590: Physical form: Powder Viscosity cps (1% aqueous 25C): 5-10 Active content % (dry basis): 59-61 A600: Physical form: Powder Viscosity cps (1% aqueous 25C): 7-12 Active content % (dry basis): 60-64 A610: Physical form: Powder Viscosity cps (1% aqueous 25C): 6-10 Active content % (dry basis): 68-72

Aceto Corp.

ACETC CORP.: CELACOL/COURLOSE (Continued):

Water-Soluble

Cellulose Ethers

Standard Viscosity Grades of CELACOL and COURLOSE(Continued): COURLOSE Technical A&N(Continued): Alkaline(Continued): Graded A650: Physical form: Powder Viscosity cps (1% aqueous 25C): 12-20 Active content % (dry basis): 60-65 ASOOHDS :

Physical form: Granular Viscosity cps (1% aqueous 25C): 3-5 Active content % (dry basis): 59-61 A600HDS: Physical form: Granular Viscosity cps (1% aqueous 25C): S-10 Active content % (dry basis): 58-60 A650HDS: Physical form: Granular Viscosity cps (1% aqueous 25C): lo-20 Active content % (dry basis): 59-61 ABOOHDS: Physical form: Granular Viscosity cps (1% aqueous 25C): 50-100 Active content % (dry basis): 59-61 Neutral: N600: Physical form: Powder Viscosity cps (1% aqueous 25C): 12-25 Active content % (dry basis): 62-64 N602: Physical form: Granular Viscosity cps (1% aqueous 25C): 12-25 Active content % (dry basis): 62-64

7

8

Water-Soluble

Resins

ACBTC CORP.: CELACOL/CCURLOSE (Continued):

Water-Soluble

Cellulose Ethers

Standard Viscosity Grades of CELACOL and CCURLOSE(Continued): COURLOSE Purified F: F8P: Viscosity cps (1% aqueous 25C): 5-9 Active content (dry basis): 98 minimum F2OP/G: Viscosity cps (1% aqueous 25C): 15-25 Active content (dry basis : 98 minimum FIOP/G: Viscosity cps (1% aqueous 25C): 30-50 Active content (dry basis : 98 minimum F75P/G: Viscosity cps (1% aqueous 25C): 60-90 Active content (dry basis : 98 minimum F358P/G: Viscosity cps (1% aqueous 25C): 300-450 Active content (dry basis : 98 minimum F808P/G: Viscosity cps (1% _- soo-4000# . _ . _ aqueous . . . 25C): Active content (cry basis): Y8 minimum FlOOOP/G: Viscosity cps (1% aqueous 25C): 4000-lOOOO# Active content (dry basis): 98 minimum # Viscosities of high viscosity grades are measured at 1% concentration using a Brookfield Viscometer.

Aceto Corp.

ACETC CORP.: CRLACOL/C!CDRLOSE Water-Soluble (Continued):

Cellulose Ethers

Other Physical Properties of CELACOL and CCDRLOSE: CELACCL: M/RPM: Appearance: white/cream Odour: none Taste: none Charring Temp.: 300C Moisture (as packed): 10% maximum Ash: 1.0% Salt content maximum: 0.8% Active content (dry basis): 99.0% Physical form: Bulk density kg/m 3tapprox.j: powder: 400 granular: N.A. Particle size: powder: 99% passes 36 mesh. Finer grades by arrangement. granular: minimum 80% between 22-52 mesh. CODRMSE: Technical A & N: Appearance: white/cream @dour: none Taste: salty Charring Temp.: 260C Moisture (as packed): 6% maximum Ash: 30-458 Salt content maximum: 25-40% Active content (dry basis): 50-70% Physical form: Bulk density kg/m 3 (approx.): Powder: 560 Granular: 400 Particle size: Powder: 99% passes 36 mesh. Finer grades by arrangement. Granular: Minimum 80% between 22-52 mesh. Degree of substitution: normal DS: 0.5-0.65 HDS: O-75-0.9

9

10

Water-Soluble Resins

ACETCI CORP.: CELACOL/CCURLOSE (Continued):

Water-Soluble

Cellulose Ethers

Other Physical Properties of CELACOL and COURLOSE(Continued): COURLOSE: Purified F: Appearance: white/cream Odour: none Taste: none Charring Temp.: 250C Moisture (as packed): 10% maximum Ash: 14-19% Salt content maximum: 2.0% Active content ldrv basis): 98% minimum Physical form: Bulk density Kg/m 3 (approx.): __ Powder: 400- _ Granular: 320 Particle size: Powder: 99% passes 36 mesh. Finer grades by arrangement. Granular: minimum 80% between 22-52 mesh. Degree of substitution: normal DS: 0.5-0.70 HDS: O-75-0.9 Specification

for CELACOL and COURLOSE Gums:

CELACOL Gums: M/HPM: Active content min.: 99.0% Salt content: 0.8% Heavy Metals: Arsenic maximum: 1 ppm. Copper maximum: 15 ppm. Lead maximum: 5 ppm. Zinc maximum: 50 ppm. Iron: complies BCP/BP COURLOSE Gums: P: Active content min.: 99.0% Sodium glycollate: nil Salt content: 1.5% Heavy Metals: Arsenic maximum: 1 ppm. Copper maximum: 10 ppm. Lead maximum: 5 ppm. Zinc maximum: 25 ppm. Iron: 150 ppm.

Aceto Corp.

ACETO CORP.: EPOMIN Polyethylene

Imines:

EPOMIN Polyethylene Imine P-1000: Molecular Weight: 70,000 Active Substance: 30% Specific Gravity: l.O/2OC Viscosity: 400-900 cps Freezing Temperature: Minus 3C pH: lo-11 (5% Aqueous Solution) EPOMIN Polyethylene Imime SP-012: Appearance: Yellowish, viscous solution Active Substance: Approximately 99% Brookfield Viscosity: 3,500-7,500 cps pH (of 5% Aq. Soln.): lo-12 Molecular Weight: Approximately 1,200 EPOMIN Polyethylene Imine SP-018: Appearance: Yellowish, viscous solution Active Substance: Approximately 99% Brookfield Viscosity: 8,500-15,000 cps pH (of 5% Aq. Soln.): lo-12 Molecular Weight: Approximately 1,800

11

12

Water-Soluble Resins

AIR PRODUCTS AND CHEMICALS, INC.: AIRFLEX Ethylene-Vinyl Chloride (EVCL) for Building Products Applications: AIRFLEX ethylene-vinyl chloride (EVCl) emulsions are suitable for use in a variety of applications for the building products industry. Their unusual combination of tailored flexibility, alkali and abrasion resistance, vapor barrier properties and fire resistance make them beneficial in formulations ranging from caulks to roof coatings and mastics. AIRFLBX 4500: Typical Emulsion Properties: Polymer Type: Ethylene-Vinyl Chloride Appearance; Milky-White _ Functionality: Amide Solids Content (%): 50 Viscosity (cps): 25-150 pH: 7-9 Average Particle Size, Microns: .12 Moisture Vapor Transmisson Rate (MVTR): 0.13 Particle Charge: Anionic Density (lbs/gal): 9.17 Polymer Specific Gravity: 1.20 Mechanical Stability: Excellent pH Stability: Excelient Typical Film Properties: --Tg

(C):

0

-

Flexibility: Excellent Appearance: Clear Tensile Strength (psi): 600 Ultimate Elongation (%): 1700 Reactivity: Crosslinkable Water Resistance: Good Oil Resistance: Excellent AIRFLEX 4514: Typical Emulsion Properties: Polymer Type: Ethylene-Vinyl Chloride Appearance: Milky White Functionality: Amide Solids Content (%): 50 Viscosity (cps): 25-150 pH: 7-9 Average Particle Size, Microns: -12 Moisture Vapor Transmission Rate (MVTR): 0.17 Particle Charge: Anionic Density (lbs/gal): 9.22 Polymer Specific Gravity: 1.23 Mechanical Stability: Excellent pH Stability: Excelient Typical Film Properties: --Tg

(C):

14

-

Flexibility: Good Appearance: Clear Tensile Strength (psi): 1100 Ultimate Elongation (%): 675 Reactivity: Crosslinkable

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, INC.: AIRFLEX Ethylene-Vinyl Chloride (EVCL) Emulsions for Building Products Applications (Continued): AIRFLEX 4530: Typical Emulsion Properties: Polymer Type: Ethylene-Vinyl Chloride Appearance: Milky White Functionality: Amide Solids Content (%): 50 Viscosity (cps): 25-150 pH: 7-9 Average Particle Size, Microns: .ll Moisture Vaoor Transmission Rate (MVTR): NA Particle Charge: Anionic Density (lbs/gal): 9.37 Polymer Specific Gravity: 1.28 Mechanical Stability: Excellent pH Stability: Excellent Typical Film Properties: Tg (C!): 30 Flexibility: Fair Appearance: Clear Tensile Strength (psi): 2100 Ultimate Elongation (%): 140 Reactivity: Crosslinkable Water Resistance: Excellent Oil Resistance: Excellent AIRFLEX 742BP: Typical Emulsion Properties: Polymer Type: Vinyl Acetate-Vinyl Chloride-Ethylene Appearance: Milky White Functionality: None Solids Content (%): 52 Viscosity (cps): 100-700 pH: 5.0-6.5 Average Particle Size, Microns: .I7 Moisture Vapor Transmission Rate (MVTR): 0.48 Particle Charge: Anionic Density (lbs/sal): 9.10 Polymer Specific Gravity: 1.20 Mechanical Stability: Excellent pH Stability: Excelient Typical Film Properties: Tg (C): 0 Flexibility: Excellent Appearance: Clear Tensile Strensth (asi): 350 Ultimate Elongation (%): 1800 Reactivity: Not Crosslinkable Water Resistance: Good Oil Resistance: Excellent

13

14

Water-Soluble Resins

AIR PRODUCTS AND CHEMICALS, Powders:

INC.: AIRFLEX RP Redispersible

AIRFLEX RP-223: AIRFLEX RP-223, a developmental redispersible powder based on a vinyl acetate-ethylene copolymer, is designed specifically for use in self-leveling floor underlayments based on portland cement. Compared with the other AIRFLEX powder grades, the advantages of using AIRFLEXin a self-leveling floor underlayment include excellent flow and leveling properties, longer open time, improved casein compatibility and lower foaming. Typical Powder Properties: __ Resin Type: Vinyl Acetate-Ethylene Copolymer Appearance: Cream Colored Powder Protective Colloid: Polyvinyl Alcohol Solids Content: 99+-l% Anti-Blocking Agent Content: lo+-2% Typical Properties of Dispersion Made From Powder: Predominant Particle Size: l-8 microns Minimum Film Forming Temperature: +3-5C Film Properties: Opaque, tough-elastic AIRFLEX RP-226 Redispersible Powder: AIRFLEX RP-226 redispersible powder is based on a vinyl acetate-ethylene copolymer, with good resistance to alkali degradation. It is specifically recommended as an admix for use in hydrating cements and plasters, but can also be used as the sole binder as in dry-wall joint treatment systems. AIRFLEX RP-226 powder improves adhesion, flexural strength, abrasion resistance, and workability in a variety of products sold in dry powder form, including thin-set mortars, selfleveling underlayments, patching compounds, and tile grouts. rpical Powder Properties: Resin Type: Vinyl Acetate-Ethylene Copolymer Appearance: White Powder Protective Colloid: Polyvinyl Alcohol Solids Content: 99+-l% Anti-Blocking Agent Content: lo+-2% Particle Size: Max. 2% Over 60 Mesh Typical Properties of Dispersion Made From Powder: Predominant Particle Size: l-5 Microns Minimum Film-Forming Temperature: +4C Film Properties: Semi-Transparent, Tough-Elastic

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, INC.: AIRFLEX RP Redispersible Powders(Continued): AIRFLEX RP-230 Redispersible Powder: AIRFLEX RP-230 redispersible powder is based on a vinyl acetate-ethylene copolymer, with good resistance to alkali degradation. It is recommended as an admix for use in hydraulic cement- and plaster-based products, but is also suitable for use as a binder in other dry-mix formulations. In combination with portland cement or plaster, AIRFLEX RP-230 powder gives a highly thixotropic viscosity. This anti-sag attribute is especially useful for the production of wall troweling compounds, tile mortars, and building adhesives. Typical Powder Properties: Resin Type: Vinyl Acetate-Ethylene Copolymer Appearance: White Powder Protective Colloid: Polyvinyl Alcohol Solids Content: 99+-l% Anti-Blocking Agent Content: lo+-2% Particle Size: Finer Than 60 Mesh Typical Properties of Dispersion Made From Powder: Predominant Particle Size: l-7 Microns Minimum Film-Forming Temperature: +4C Film Properties: Semi-Transparent, Tough-Elastic AIRFLEX RP-244: Typical Powder Properties: Resin Type: Vinyl Acetate-Ethylene Copolymer Appearance: White to Cream Colored Powder Protective Colloid: Polyvinyl Alcohol Solids Content: 99+-l% Anti-Blocking Agent Content: lo+-2% Typical Properties of Dispersion Made From Powder: Predominant Particle Size: l-5 microns Minimum Film Forming Temperature: OC Film Properties: Opaque, tough-elastic

15

16

Water-Soluble Resins

AIR PRODUCTS AND CHEMICALS, Powders(Continued):

INC.: AIRFLEX RP Redispersible

AIRFLEX RP-245: AIRFLEX RP-245 redispersible powder is based on a vinyl acetate-ethylene copolymer, with good resistance to alkali degradation. The relatively high ethylene content of this resin yields a softer, more flexible system with improved adhesion to both inorganic and organic substances. AIRFLEX RP-245 powder is specifically recommended as an admix for use in hydrating cements and plasters, or as the sole binder for producing flexible building adhesives and troweling compounds. Typical Powder Properties: Resin Type: Vinyl Acetate-Ethylene Copolymer Appearance: White Powder Protective Colloid: Polyvinyl Alcohol Solids Content: 99+-l% Anti-Blocking Agent Content: lo+-2% Particle Size: Max. 2% Above 40 Mesh Typical Properties of Dispersion Made From Powder: Predominant Particle Size: l-5 Microns Minimum Film-Forming Temperature: OC Film Properties: Semi-Transparent, Tough-Elastic AIRFLEX RP-246: AIRFLEX RP-246 redispersible powder is based on a vinyl acetate-ethylene copolymer, with good resistance to alkali degradation. It is designed for use as an admix in hydraulic cement- and plaster-based products, but can also be used as a binder in other dry-mix formulations. Typical Powder Properties: Resin Tvve: Vinvl Acetate-Ethvlene Cooolvmer __ Appearance: White Powder Protective Colloid: Polyvinyl Alcohol Solids Content: 99+-l% Anti-Blocking Agent Content: lo+-2% Particle Size: Max. 2% Above 40 Mesh Typical Properties of Dispersion Made From Powder: Predominant Particle Size: l-7 Microns Minimum Film-Forming Temperature: OC Film Properties: Semi-Transparent, Tough-Elastic

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, Powders(Continued1:

17

INC.: AIRFLRX RP Redispersible

AIRFLBX Grades: Cementitious

Applications:

RP-223: Rest grade for application: Self-Leveling Underlayment Well suited for application: Patching and Repair Mortars Past-Set Patching Mortars RP-224: Best grade for application: Fast-Set Patching Mortars Well suited for application: Thin-Set Mortars for Ceramic Tile Tile Grout Self-Leveling Underlayment Patching and Repair Mortars Waterproofing Coatings RP-226: Best grade for application: Patching and Repair Mortars Well suited for application: Thin-Set Mortars for Ceramic Tile Tile Grout Self-Leveling Underlayment Fast-Set Patching Mortars Waterproofing Coatings RP-230: Well suited for application:

Thin-Set Mortars for Ceramic Tile

RP-244: Best grade for application:

Exterior Insulation Systems Adhesives and Coatings Waterproofing Coatings Well suited for application: Thin-Set Mortars for Ceramic Tile Tile Grout Self-Leveling Underlayment Patching and Repair Mortars Stucco and Texture Coatings

RP-245: Best grade for application:

Exterior Insulation Systems Adhesives and Coatings Stucco and Texture Coatings Waterproofing Coatings Well suited for application: Thin-Set Mortars for Ceramic Tile Tile Grout Self-Leveling Underlayment Patching and Repair Mortars

RP-246: Well suited for application:

Thin-Set Mortars for Ceramic Tile

18

Water-Soluble Resins

AIR PRODUCTS AND CHEMICALS,

INC.: AIRVOL Polyvinyl Alcohol:

Physical Properties of Polyvinyl Alcohol: Appearance: White-to-cream granular powder Bulk Density: 40 lbs./cu. ft. Specific Gravity: of solid: 1.27-1.31 of 10 wt % solid at 25C: 1.02 Thermal Stability: Gradual discoloration about 1OOC; darkens rapidly above 150C; rapid decomposition above 200C Refractive Index (film) at 20C: 1.55 Thermal Conductivity, W/(m.K): 0.2 Electrical Resistivity, ohm.cm: (3.1-3.8) X 10 7 Specific Heat, J/(g.K): 1.5 Melting Point (unplasticized), C: 230 for fully hydrolyzed grades; 180-190 for partially hydrolyzed grades Tg, C: 75-85 Storage Stability (solid): Indefinite when protected from moisture Flammability: Burns similarly to paper Stability in Sunlight: Excellent AIRVOL Polyvinyl Alcohol Typical Properties: Super Hydrolyzed: AIRVOL 125: Hydrolysis, %: 99.3+ Viscosity, cps: 26-30 (Medium) pH: 5.5-7.5 Volatiles, % Max.: 5 Ash, % Max.: 1.0 AIRVOL 165: Hydrolysis, %: 99.3+ Viscosity, cps: 55-65 (High) pH: 5.5-7.5 Volatiles, % Max.: 5 Ash, % Max.: 1.0 Fully Hydrolyzed: AIRVOL 103 DEV: Hydrolysis, %: 98-O-98.8 Viscosity, cps: 3.2-4.2 (Ultra Low) pH: 5.0-7.0 Volatiles, % Max.: 5 Ash, % Max.: 1.0

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, (Continued):

INC.: AIRVOL Polyvinyl Alcohol

Standard Grades(Continued): Fully Hydrolyzed(Continued): AIRVOL 107: Hydrolysis, %: 98.0-98.8 Viscosity, cps: 5.4-6.5 (LOW) pH: 5.0-7.0 Volatiles, % Max.: 5 Ash, % Max.: 1.0 AIRVOL 325: Hydrolysis, %: 98.0-98.8 Viscosity, cps: 26-30 (Medium) pH: 5.0-7.0 Volatiles, % Max.: 5 Ash, % Max.: 1.0 AIRVOL 350: Hydrolysis, %: 98.0-98.8 Viscosity, cps: 55-65 (High) pH: 5.0-7.0 Volatiles, % Max.: 5 Ash, % Max.: 1.0 Intermediate Hydrolyzed: AIRVOL WS 42: Hydrolysis, %: 96.5-97.5 Viscosity, cps: 13-16 (Med.-Low) pH: 4.5-6.5 Volatiles, % Max.: 5 Ash, % Max.: 1.0 AIRVOL 425: Hydrolysis, %: 95.5-96.5 Viscosity, cps: 25-29 (Medium) pH: 4.5-6.5 Volatiles, % Max.: 5 Ash. % Max.: 0.7

19

20

Water-Soluble Resins

AIR PRODUCTS AND CHEMICALS, (Continued):

INC.: AIRVOL Polyvinyl Alcohol

Standard Grade(Continued): Partially Hydrolyzed: AIRVOL 203: Hydrolysis, %: 87.0-89.0 Viscosity, cps: 3-4 (Ultra Low) pH: 4.5-6.5 Volatiles, % Max.: 5 Ash, % Max.: 0.7 AIRVOL 205: Hydrolysis, %: 87.0-89.0 Viscosity, cps: 5-6 (Low) pH: 4.5-6.5 Volatiles, % Max.: 5 Ash, % Max.: 0.5 AIRVOL 523: Hydrolysis, %: 87.0-89.0 Viscosity, cps: 22-26 (Medium) pH: 4.0-6-O Vola'ciles, % Max.: 5 Ash, % Max.: 0.3 AIRVOL 540: Hydrolysis, %: 87.0-89.0 Viscosity, cps: 40-50 (High) pH: 4.0-6.0 Volatiles, % Max.: 5 Ash, % Max.: 0.3 AIRVDL 205s: AIRVOL 5238: AIRVOL 5405: Similar to above for AIRVOL grades 205, 523 and 540 except for having a finer particle size. Hydrolysis specification is 87.0-90.08.

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, (Continued): Tackified Grades

INC.: AIRVOL Polyvinyl Alcohol

(Typical Properties):

AIRVOL SE-72: Viscosity, cps: 3800-5500 pH: 4.4-4.9 Derived from Super Hydrolyzed

Grades

AIRVOL S&73: Viscosity, cps: 1200-1600 pli: 4.4-4.9 Derived from Super Hydrolyzed

Grades

UN1SlzE: * Viscosity, cps: 80-155 pH: 3.9-4.6 Derived from Super Hydrolyzed

Grades

AIRVOL MH-82: Viscosity, cps: 4200-5900 pH: 4.4-4.9 Derived from Fully Hydrolyzed

Grades

AIRVOL N&81: viscosity, cps: 1300-1700 pH: 4.4-4.9 Derived from Fully Hydrolyzed

Grades

AIRVOL MM-51: Viscosity, cps: 1100-1500 pH: 4.4-4.9 Derived from Fully Hydrolyzed

Grades

* Use of UNISIZE polyvinyl alcohol No. 3,438,808. Viscosity Type: Ultra Low Low Medium High

is covered by U.S. Patent

Molecular Weight Average 13.000-23.000 31;000-50;ooo 85.000-146.000 124,000-186;OOO

22

Water-Soluble Resins

AIR PRODUCTS AND CHEMICALS, Products:

INC.: Emulsions

AIRFLEX Vinyl Acetate-Ethylene

for Adhesive

Emulsions:

AIRFLEX 400: Adheres to a wide variety of surfaces including PVC film. Increased water resistance over homopolymers, fast setting, good creep resistance and plasticizer migration resistance. Viscosity (cps): 1800-2700 Solids % (Min.): 55 pH: 4.0-5.0 Tg C: 0 Protection: Polyvinyl Alcohol Freeze Thaw Stability: No Borax Compatibility: No Wet Tack: High HZ0 Resistance: Good Substrates: Typically Used: Paper: Coated Cloth: Cotton/Polyester Film: Mylar/Cellulose Acetate PVC (Vinyl) AIRFLEX 400H: A high-viscosity version of AIRFLEX 400 designed to reduce the overall cost of a formulated adhesive by reducing the amount of special additives and fillers required. Viscosity (cps): 3100-4400 Solids % (Min.): 55 pH: 4.0-5.0 Tg C: 0 Protection: Polyvinyl Alcohol Freeze Thaw Stability: No Borax Compatibility: No Wet Tack: High H20 Resistance: Good Substrates: Typically Used: Paper: Kraft/Coated Cloth: Cotton/Polyester Film: Mylar/Cellulose Acetate/ PVC (Vinyl) AIRFLEX 401: Combines easy cleanup with excellent high-speed machinability for packaging and converting applications. Viscosity (cps): 1300-2200 Solids % (Min.): 55 pH: 5.0-6.5 Tg C: -15 Protection: Polyvinyl Alcohol Freeze Thaw Stability: No Borax Compatibility: No Wet Tack: High H20 Resistance: Fair Substrates: Sometimes Used: Paper: Kraft/Coated Film: Mylar/Cellulose Acetate

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, Products(Continued):

INC.: Emulsions

AIRFLEX Vinyl Acetate-Ethylene

23

for Adhesive

Emulsions(Continued):

AIRFLEX 405: Highly water resistant, accepts high loading. Viscosity (cps): 300-1000 Solids % (Min.): 55 pH: 5.0-6.0 Tg C: 7 Protection: Surfactant Freeze Thaw Stability: No Borax Compatibility: Yes Wet Tack: Low H20 Resistance: Excellent Coated Substrates: Sometimes Used: Cotton AIRFLEX 410: Sprayable, good water resistance, compatible with elastomeric latices, heat sealable for hot nip applications. Viscosity (cps): 250-900 Solids % (Min.): 55 pH: 4.5-5.5 Tg C: 5 Protection: Cellulosic Freeze Thaw Stability: No Borax Compatibility: Yes Wet Tack: Low H20 Resistance: Excellent Substrates: Sometimes Used: Paper: Kraft/Coated Cloth: Cotton/Polyester Film: Mylar/Cellulose Acetate Typically Used: Film: PVC (Vinyl) AIRFLEX 416: Carboxylated with excellent adhesion to metal, polyester and other plastic films. Sprayable, good water resistance, heat sealable for hot nip applications. Viscosity (cps): 1900-3800 Solids % (Min.): 52 pH: 3.5-5.0 Tg (C): 0 Protection: Cellulosic Freeze Thaw Stability: Yes Borax Compatibility: Yes Wet Tack: Low H20 Resistance: Excellent Substrates: Typically Used: Film: Cellulose Acetate/ PVC (Vinyl) Metals: Aluminum/Stainless Steel

24

Water-Soluble Resins

AIR PRODUCTS AND CHEMICALS, Products(Conti.nued):

INC.: Emulsions

AIRFLEX Vinyl Acetate-Ethylene

for Adhesive

Emulsions(Continued):

AIRFLRX 465: Combines high solids with a low, workable viscosity, to offer a unique compounding base for a wide range of applications. It exhibits rapid setting speed, film clarity, excellent water resistance and high loading capability. Viscosity (cps): 800-1300 Solids % (Min.): 66 pH: 4.5-5.5 Tg C: -5 Protection: Polyvinyl Alcohol Freeze Thaw Stability: No Borax Compatibility: No Wet Tack: High H20 Resistance: Excellent Substrates: Typically Used: Wood. Paper: Kraft/Coated Film: Mylar/Cellulose Acetate/PVC (Vinyl) AIRFLEX 300: Designed to provide a superior alternative to homopolymer emulsions. Exhibits better thickening response, higher wet tack and grab, greater water resistance and flexibility. Delivers equal performance at less cost or higher performance at equal cost as compared with plasticized homopolymer emulsions. Viscosity (cps): 1800-2700 Solids % (Min.): 55 pH: 4.0-5.0 Tg C: 18 Protection: Polyvinyl Alcohol Freeze Thaw Stability: No Borax Compatibility: No Wet Tack: High H20 Resistance: Fair Substrates: Typically Used: Paper: Kraft/Coated--Cloth: Cotton Film: Cellulose Acetate AIRFLEX 320: Uniquely compatible with both fully and partially hydrolyzed polyvinyl alcohol. Exhibits extended open wet tack time for greater flexibility in machine applications. Excellent plasticizer thickening response, rapid set speed and excellent creep resistance. Viscosity (cps): 1800-2700 Solids % (Min.): 55 pH: 4.0-5.0 Tg C: 14 Protection: Polyvinyl Alcohol Freeze Thaw Stability: No Borax Compatibility: No Wet Tack: High HZ0 Resistance: Good Substrates: Typically Used: Paper: Kraft/Coated--Cloth: Cotton Film: Cellulose Acetate

Air

AIR PRODUCTS AND CHEMICALS, Products(continued1:

INC.: Emulsions

VINAC Polyvinyl Acetate Homopolymer

Products

and

Chemicals

25

for Adhesive

Emulsions:

VINAC XX-21 0: Fast-setting, general-purpose bases for packaging applications and w00a glues. Excellent machinability, solvent tolerance and freeze-thaw stability. Viscosity (cps): 1000-1400 solids % (Min.): 55 pH: 4.5-6.0 Tg c: 30 Protection: Polyvinyl Alcohol Freeze Thaw Stability: Yes Borax Compatibility: No Wet Tack: High H20 Resistance: Fair Substrates: Typically used: w00a Paper: Kraft VINAC Xx-220: Fast-setting, general-purpose bases for packaging applications and w00a glues. Excellent machinablity, solvent tolerance and freeze-thaw stability. Viscosity (cps): 1600-2000 Solids % (Min.): 4.5-6.0 Tg c: 30 Protection: Polyvinyl Alcohol Freeze Thaw Stability: Yes Borax Compatibility: No Wet Tack: High H20 Resistance: Fair Substrates: Typically Used: w00a Paper: Kraft VINAC Xx-230: Fast-setting, general-purpose bases for packaging applications and w00a glues. Excellent machinability, solvent tolerance and freeze-thaw stability. Viscosity (cps): 2000-2600 solids % (Min.): 55 pH: 4.5-6.0 Tg C: 30 Protection: Polyvinyl Alcohol Freeze Thaw Stability: Yes Borax Compatibility: No Wet Tack: High H20 Resistance: Fair Substrates: Typically used: w00a Paper: Kraft

26

Water-Soluble Resins

AIR PRODUCTS AND CHEMICALS, Products(Continued1:

INC.: Emulsions

VINAC Polyvinyl Acetate Homopolymer

for Adhesive

Emulsions(Continued):

VINAC Xx-240: Fast-setting , general-purpose bases for packaging applications and wood glues. Excellent machinability, fast solvent tolerance and freeze-thaw stability. Viscosity (cps): 2900-3700 Solids % (Min.): 55 pH: 4.5-6.0 Tg C: 30 Protection: Polyvinyl Alcohol Freeze Thaw Stability: Yes Borax Compatibility: No Wet Tack: High H20 Resistance: Fair Substrates: Typically Used: Wood Paper: Kraft FLEXCRYL Acrylic Emulsions: FLEXCRYL 1625: High-solids, pressure-sensitive emulsion with very high tack and good shear performance characteristics. Viscosity (cps): 4000-9000 Solids % (Min.): 69 pH: 4.0-5.0 Tci C: -48 Protection: Anionic Freeze Thaw Stability: No Borax Comoatibilitv: Yes Wet Tack:*N/A _ H20 Resistance: Excellent Substrates: Typically Used: Wood Paper: Kraft/Coated Cloth: Cotton/Polyester Film: Mylar/Cellulose Acetate PVC (Vinyl) Metals: Aluminum/Stainless Steel

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, Products(Continued1:

INC.: Emulsions

for Adhesive

FLEXCRYL Acrylic Emulsions(Continued1: FLEXCRYL 1685: Pressure-sensitive emulsion with very high shear and excellent heat resistance. Viscosity (cps): 100-600 Solids % (Min.): 55 pH: 2-O-3.0 Tg

C:

-40

Protection: Anionic Freeze Thaw Stability: No Borax Compatibility: Yes Wet Tack: N/A H20 Resistance: Excellent Substrates: Typically Used: Wood Paper: Kraft/Coated Cloth: Cotton/Polyester Film: Mylar/Cellulose Acetate/ PVC (Vinyl) Metals: Aluminum/Stainless Steel FLEXBOND Polyvinyl Acetate Copolymer Emulsions: FLEXBOND 149: Well balanced, pressure sensitive properties. Exhibit permanently tacky base, excellent aging resistance and very low odor. Viscosity (cps): 200-900 Solids %-(Min.): 55 pH: 4.5-6.0 Tg C: -30 Protection: Surfactant and Cellulosic Freeze Thaw Stability: No Borax Compatibility: Yes Wet Tack: Low HZ0 Resistance: Good Substrates: Typically Used: Paper: Kraft/Coated Film: Mylar/Cellulose Acetate

27

28

Water-Soluble Resins

AIR PRODUCTS AND CHEMICALS, Products(Continued):

INC.: Emulsions

for Adhesive

FLEXBOND Polyvinyl Acetate Copolymer Emulsions(Continued): FLEXBOND 150: Well balanced, pressure sensitive properties. Exhibit permanently tacky base, excellent aging resistance and very low odor. Viscosity (cps): 350-850 Solids % (Min.): 55 pH: 4.5-6.0 Tg C: -28 Protection: Surfactant and Cellulosic Freeze Thaw Stability: No Borax Compatibility: Yes Wet Tack: Low H20 Resistance: Good Substrates: Typically Used: Paper: Kraft/Coated Film: Mylar/Cellulose Acetate FLBXBCND 153: Well balanced, pressure sensitive properties. Exhibit permanantly tacky base, excellent aging resistance and very low odor. Viscosity (cps)": 2500 Solids % (Min.): 55 pH: 4.5 Tg C: -40 Protection: Surfactant Freeze Thaw Stability: No Borax Compatibility: Yes Wet Tack: Moderate H20 Resistance: Fair Substrates: Typically Used: Paper: Kraft/Coated Film: Mylar/Cellulose Acetate/ PVC (Vinyl) Metals: Aluminum/Stainless Steel

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, Products:

INC.: Emulsions

AIRFLEX Vinyl Acetate-Ethylene

for Building

Emulsions:

AIRFLEX 500: Vinyl acetate-ethylene (VAE) copolymer for paints, caulks and mastics. High critical pigment volume concentration. Excellent long term-weathering resistance Weight lbs./gal: 9.0 Viscosity (cp): 150-700 Solids % (min.): 55 pH: 5.0-6.0 Tg+-3C: 5 Applications: Caulk Mastic Masonry Coating Roof Coating Texture AIRFLEX 525-BP: VAE copolymer for use in drywall joint cements, caulks, texture coats and mastics. Also performs well as a portland cement admix. Weight lbs./gal: 8.9 Viscosity (cp): 200-900 Solids % (min.): 55 pH: 4.8-5.5 Tg+-3C: 4 Applications: Caulk Cement Additive Joint Cement Mastic Texture AIRFLEX 526-BP: VAE copolymer for use in drywall joint cements, spackles, grouts, spray-up insulation and as a portland cement admix. Demonstrates superior binder efficiency, low-temperature bond and shrinkage crack resistance for joint cements. Weight lbs./gal: 8.9 Viscosity (cp): 1800-2700 Solids % (min.): 55 pH: 4.0-6.0 Tg+-3C: 0 Applications: Cement Additive Insulation Binder Joint Cement Mastic

29

30

Water-Soluble

Resins

AIR PRODUCTS AND CHEMICALS, Products(Continued):

INC.: Emulsions

for Building

AIRFLEX 529 Dev: Self-crosslinking VAE binder for wet-laid fiberglass mat applications. Imparts flexibility, high-temperature strength and tear resistance to roofing and insulation products. Weight lbs./gal: 9.0 Viscosity (cp): 300-600 Solids % (min.): 50 pH: 6.5-7.5 Tg+-3C: 24 Applications: Fiberglass Binder AIRFLEX 530-BP: VAE copolymer for joint cements, caulks, spackles, grouts and portland cement admix. Demonstrates superior binder efficiency, low-temperature bond and shrinkage crack resistance in joint cements. Weight lbs./gal: 8.9 Viscosity (cp): 1800-2700 Solids % (min.): 55 pH: 4.0-6.0 Tg+-3C: 18 Applications: Caulk Cement Additive Joint Cement AIRFLEX 560 Dev: State-of-the-art VAE emulsion for joint cements, spackles and grouts. Excellent application properties and superior binder efficiency, low-temperature bond, shrinkage crack resistance and viscosity stability. Weight lbs./gal: 9.0 Viscosity (cp): 100-300 Solids % (min.): 60 pH: 3.5-4.5 Tg+-3C: 5 Applications: Joint Cement

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, Products(Continued):

INC.: Emulsions

AIRFLEX Vinyl Acetate-Ethylene

for Building

Emulsions(Continued):

AIRFLEX 565 Dev: State-of-the-art, high-solids VAE emulsion for quality caulk and elastomeric applications. Weight lbs./gal: 9.0 Viscosity (cp): 800-1300 solids % (min.): 66 pH: 4.5-5.5 Tg+-3C: -5 Applications: Caulk Mastic Roof Coating AIRFLEX Acrylic Emulsions: AIRFLEX 600-BP Series: Acrylic polymers and terpolymers elastomeric coatings. Weight lbs./gal: 9.0 Viscosity (cp): 2000-3000 solids % (min.): 55 pH: 4.5 max Tg+-3C: -40 Applications Caulk Mastic AIRFLEX Ethylene-Vinyl

for premium caulks and

Chloride Emulsions:

AIRFLEX 742-BP: Unique ethylene-vinyl chloride polymers which impart flexibility and water resistance to caulks, mastics, tie coats and barrier coats. Fire retardant properties. Weight lbs./gal: 9.1 Viscosity (cp): 150-500 Solids % (min.): 52 pH: 5.0-6.5 Tg+-3C: 0 Applications: Caulk Fire Retardant Insulation Binder Mastic Masonry Coating Roof Coating Texture

31

32

Water-Soluble Resins

AIR PRODUCTS AND CHEMICALS, Products(Continued): AIRFLBX Ethylene-Vinyl

INC.: Emulsions

for Building

Chloride Emulsions(Continued):

AIRFLBX 4500: Unique ethylene-vinyl chloride polymers which impart flexibility and water resistance to caulks, mastics, tie coats and barrier coats. Fire retardant properties. Weight lbs./gal: 9.2 Viscosity (cp): 25-150 Solids % (min.): 50 pri: 7.0-9.0 Tg+-3C: 3 Applications: Concrete Sealer Fire Retardant Masonry Coating AIRFLBX 4514: Unique ethylene-vinyl chloride polymers which impart flexibility and water resistance to caulks, mastics, tie coats and barrier coats. Fire retardant properties. Weight lbs./gal: 9.2 Viscosity (cp): 25-150 Solids % (min.): 50 pH: 7.0-9-O Tg+-3C: 14 Applications: Ceiling Tile Concrete Sealer Fire Retardant Masonry Coating AIRFLEX 4530: Unique ethylene-vinyl chloride polymers which impart flexibility and water resistance to caulks, mastics, tie coats and barrier coats. Fire retardant properties. Weight lbs./gal: 9.4 Viscosity (cp): 25-150 Solids % (min.): 50 pH: 7.0-9.0 Tg+-3C: 30 Applications: Ceiling Tile Concrete Sealer Fire Retardant

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, Products(Continued):

INC.: Emulsions

VINAC Polyvinyl Acetate Homopolymer

33

for Building

Emulsions:

VINAC 521-BP: Vinyl acetate homopolymers in four viscosity grades. Used in caulks, bond coats, grouts, fiberglass mats and a variety of adhesive applications. Weight lbs./gal: 9.0 Viscosity (cp): 1000-1400 Solids % (min.): 55 pH: 4.5-6.0 Tg+-3C: 35 Applications: Caulk Cement Additive Ceiling Tile Fiberglass Binder Mastic VINAC 522-BP: Vinyl acetate homopolymers in four viscosity grades. Used in caulks. bond coats, grouts. fiberglass mats and a variety of adhesive applications. Weight lbs./gal: 9.0 Viscosity (cp): 1600-2000 Solids % (min.): 55 pH: 4.5-6.0 Tg+-3C: 35 Applications: Caulk Cement Additive Ceiling Tile Fiberglass Binder Mastic VINAC 523-BP: Vinyl acetate homopolymers in four viscosity grades. Used in caulks, bond coats, grouts, fiberglass mats and a variety of adhesive applications. Weight lbs./gal: 9.0 Viscosity (cp): 2000-2600 Solids % (min.): 55 pH: 4.5-6.0 Tg+-3C: 35 Applications: Caulk Cement Additive Ceiling Tile Fiberglass Binder Mastic

34

Water-Soluble Resins

AIR PRODUCTS AND CHEMICALS, Products(Continued):

INC.: Emulsions

for Building

VINAC Polyvinyl Acetate Homopolymer Emulsions(Continued): VINAC 524-BP: Vinyl acetate homopolymers in four viscosity grades. Used in caulks, bond coats, grouts, fiberglass mats and a variety of adhesive applications. Weight lbs./gal: 9.0 Viscosity (cp): 2900-3700 Solids % (min.): 55 pH: 4.5-6.0 Tg+-3C: 35 Applications: Caulk Cement Additive Ceiling Tile Fiberglass Binder Mastic

VINAC CEl-P: Fully compounded, remoistenable bond coat product offering excellent rewettable adhesion for plaster and Portland cement applications. Also serves as a cement admix. Weight lbs./gal: 9.2 Viscosity (cp): 500-1000 Solids % (min.): 53 pH: 5.5-7.0 Tg+-3C: NA Applications: Cement Additive AIRFLEX Vinyl Acetate-Ethylene Powders: AIRFLEX RP-223: AIRFLEX RP-224: AIRFLEX RP-226: AIRFLEX RP-230: AIRFLEX RP-244: AIRFLEX RP-245: AIRFLEX RP-246: Spray dried redispersible powders which, when mixed with water, produce a stable latex. Excellent alkali resistance. Tg+-3C: NA Applications: Cement Additive, Joint Cement, Mastic, Masonry Coating FLEXBOND Vinyl Acrylic Emulsion: FLEXBOND 825: Economical vinyl acrylic latex for a variety of general purpose building product applications. Weight lbs./gal: 9.1 Viscosity (cp): 700-1200 Solids %: (min.): 55 pH: 4.0-6.0 Tg+-3C: 13 Ceiling Tile Applications: Caulk Insulation Binder Texture

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, Paperboard:

INC.: Emulsions

for Paper and

VINAC Polyvinyl Acetate Emulsions: VINAC 881: Vinyl Acetate Homopolymer Viscositv Ices): 50-300 Solids (% min.j: 50 Average Particle Size, M: 0.15 Particle Charge: Slightly Anionic Tg C: +33 Use: Pigment binder for coatings, size press applications, and saturation. Advantages: Very good wet and dry pick for web and sheet offset grade coatings. Low foaming. Excellent mechanical stability. VINAC 828: Vinyl Acetate Homopolymer Viscosity (cps): SO-300 Solids (% min.): 50 Average Particle Size, M: 0.15 Particle Charge: Slightly Anionic Tg C: +33 Use: Pigment binder for coatings, size press applications, and saturation. Advantages: Outstanding wet and dry pick for web and sheet offset grade coatings. Exceptionally low grit content. Low foaming. Excellent mechanical stability. VINAC 820: Vinyl Acetate-Acrylate Copolymer Viscosity (cps): 50-300 Solids (0 min.): 50 Average Particle Size, M: 0.18 Particle Charge: Slightly Anionic Tg C: +18 Use: Pigment binder for coatings, size press applications, and saturation. Advantages: Outstanding dry pick. Good wet pick for offset grades. Excellent roto printability. Excellent glueability for board coatings. Higher sheet gloss and gloss ink holdout than homopolymers.

35

36

Water-Soluble Resins

AIR PRODUCTS AND CHRMICALS, Paperboard(Continued):

INC.: Emulsions

for Paper and

VINAC Polyvinyl Acetate Emulsions(Continued): VINAC 810: Vinyl Acetate Self-Crosslinking Copolymer Viscosity (cps): 900-1350 Solids (% min.): 52 Average Particle Size, M: 0.65 Particle Charge: Nonionic Tg C: +41 Use: Filter papers and saturation. Advantages: Surfactant-free polymer. May be diluted with water or methanol to improve binder distribution. High stiffness with flexibility. High wet and dry tensile strength. AIRFLRX Vinyl-Ethylene

Emulsions:

AIRFLRX 100HS: Vinyl Acetate-Ethylene Copolymer Viscosity (cps): 150-700 Solids (% min.): 55 Average Particle Size, M: 0.17 Particle Charge: Essentially Nonionic Tg C: +7 Use: Pigment binder for coatings, spacialty coatings, and wallpaper groundcoat. Advantages: Flexible binder. High dry pick. Excellent scrub resistance. Good for both roto and offset grades. Flexible down coat for barrier resins. AIRFLEX 110: Vinyl Acetate-Ethylene Copolymer Viscosity (cps): 200-600 Solids (% min.): 55 Average Particle Size, M: 0.30 Particle Charge: Nonionic Tg C: +5 Use: Reprographics compatible with conductive polymers. Advantages: Optimum solvent holdout and runnability with little effect on conductivity.

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, Paperboard(Continued): AIRFLEX Vinyl-Ethylene

INC.: Emulsions

37

for Paper and

Emulsions(Continued):

AIRFLEX 122: Vinyl Acetate-Ethylene Self-Crosslinking Copolymer Viscosity (cps): 700-1200 Solids (% min.): 52 Average Particle Sire, M: 0.20 Particle Charge: Anionic Tg C: -16 Use: Size press applications and saturation. Advantages: Very flexible, tough polymer with excellent water and solvent resistance. Soft hand. AIRFLEX 125: Vinyl Acetate-Ethylene Self-Crosslinking Copolymer Viscosity (cps): 400-1000 Solids (% min.): 52 Average Particle Sire, M: 0.15 Particle Charge: Anionic Tg C: 0 Use: Size press applications and saturation. Advantages: Higher water and solvent resistance than A-122, with moderate hand and flexibility. AIRFLEX 130: Vinyl Acetate-Ethylene Copolymer viscosity (cps): 1400-2000 Solids (% min.): 55 Average Particle Size, M: 1.0 Particle Charge: Nonionic Tg C: +18 Use: Tie coats, specialty coatings, and saturants. Advantages: Heat sealable. Bonds to a wide range of surfaces. AIRFLEX 140: Vinyl Acetate-Ethylene Copolymer Viscosity (cps): 1400-2000 Solids (% min.).: 55 Average Particle Size, M: 0.8 Particle Charge: Nonionic Tg C: 0 Use: Tie coats, specialty coatings, and saturants. Advantages: Readily heat sealable. Bonds to a wide range of surfaces.

38

Water-Soluble Resins

AIR PRODUCTS AND CHEMICALS, Paperboard(Continued): AIRFLEX Ethylene-Vinyl

INC.: Emulsions

for Paper and

Chloride Emulsions:

AIRFLHX 456: Vinyl Acetate-Vinyl Chloride-Ethylene Terpolymer Viscosity (cps): ioo-500 Solids (% min.): 52 Average Particle Size, M: 0.17 Particle Charge: Anionic Tg C: 0 Use: Size press applications and saturation. Advantages: Good water resistance, abrasion resistance, flame retardance.

and

AIRFLEX 4500: Ethylene-Vinyl Chloride Terpolymer Viscosity (cps): 25-150 Solids (% min.): 50 Average Particle Size, M: 0.12 Particle Charge: Anionic Tg C: 0 Use: Size press applications, saturation, wallcoverings, and aqueous inks. Pigment compatible. Advantages: Flexible with soft hand. High glossing. Crosslinkable. Excellent water and grease resistance. Inherent flame retardance. AIRFLHX 4514: Ethylene-Vinyl Chloride Terpolymer Viscosity (cps): 25-150 Solids (% min.): 50 Average Particle Size, M: 0.12 Particle Charge: Anionic Tg C: +14 Use: Size press applications, saturation, wallcoverings, and aqueous inks. Pigment compatible. Advantages: Flexible with moderate hand. High glossing. Crosslinkable. Excellent water and grease resistance. Inherent flam retardance.

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, Paperboard(Continued): AIRFLEX Ethylene-Vinyl

INC.: Emulsions

for Paper and

Chloride Emulsions(Continued):

AIRFLJIX 4530: Ethylene-Vinyl Chloride Terpolymer Viscosity (cps): 25-150 Solids (% min.): 50 Average Particle Size, M: 0.11 Particle Charge: Anionic Tg C: +30 Use: Filter papers, size press applications, saturation, aqueous inks, and clear overcoats. Pigment compatible. Advantages: High stiffness with flexibility. High glossing. Crosslinkable. Excellent water and grease resistance. Inherent flame retardance. Does not form a film at room temperature. AIRFLHX 4814: Ethylene-Vinyl Chloride Carboxylated Terpolymer Viscosity (cps): 25-400 Solids (% min.): 49 Average Particle Size, M: 0.12 Particle Charge: Anionic Tg C: +I4 Use: Size press applications, saturation, wallcoverings, and aqueous inks. Pigment compatible. Advantages: Good WV and heat stability. Good adhesion to aluminum foil. Good alcohol tolerance. Longer pot life with UF and MF crosslinkers.

39

40

Water-Soluble

Resins

AIR PRODUCTS AND CHEMICALS,

INC.: VANCRYL Acrylic Resins:

VANCRYL 68 Resin: Solid Acrylic Resin for Inks and Coatings VANCRYL 68 resin provides outstanding pigment wetting along with the viscosity stability needed for aqueous gravure and flexographic inks. The transfer properties and hold-out characteristics of inks prepared with VANCRYL 68 resin are excellent. In coatings, VANCRYL 68 resin provides high gloss, scuff resistance and hardness. VANCRYL 68 resin is compatible with most acrylic vehicles and other vehicles such as-maleic resins. VANCRYL 68 resin is effective as a protective colloid in the production of styrene-acrylic copolyme; emulsions. Key Performance Properties: - Outstanding pigment wetting - Excellent transfer - Good hold-out - Low foam - High gloss - Compatible with most vehicles Typical Properties: Appearance: Solid, water-white pellets Acid Number: 155 Softening Point: 130C Glass Transition Temperature: 57C Molecular Weight: Nn: 4,500 Mw: 20,000 Solution Properties: Gardner Color: ~1 30% solids, Ammonium Salt: 2000 50% Solids; Ethanol: 550 cps

cps

_

VANCRYL 68-S Resin Solution: VANCRYL 68-S resin solution is an aqueous solution of VANCRYL 68 acrylic resin, with ammonia used to effect the solution. Key Performance Properties: - Outstanding pigment wetting - Excellent transfer - Good hold-out - Low foam - High gloss - Compatible with most vehicles Typical Properties: Appearance: Clear solution pH: 7.8-8.6 Density: 8.6 lbs/gal Molecular Weight: Mn: 4,500 Mw: 20,000

Non-volatiles: 29-31% Viscosity: 1,500-3,000 cps Glass Transition Temperature: 57C Freeze-Thaw Stability: Stable

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, (Continued):

41

INC.: VANCRYL Acrylic Resins

VANCRYL 189 Rmulsion: Styrene-Acrylic Emulsion for Inks and Coatings VANCRYL 189 emulsion is a high molecular weight, fine particle size emulsion polymer. As an ink extending vehicle, VANCRYL 189 emulsion provides good gloss and reduces bronzing. As a result of its high solids, VANCRYL 189 emulsion has very rapid drying. Key Performance Properties: - Fast drying - Good gloss - High solids Typical Properties: Appearance: Off-white emulsion pH: 8.2-8.6 Density: 8.7 lbs/gal Surface Tension: 37 dynes/cm Freeze-Thaw Stability: Stable VANCRYL 453 Emulsion: Acrylic Emulsion for Economical

Film clarity Reduced bronzing Compatible with most waterbased vehicles Non-volatiles: 47.5-48.5% Viscosity: 600-1,000 cps Glass Transition Temp.: 81C Particle Size: 0.11 micron Stabilization System: Anionic

Inks

VANCRYL 453 emulsion is a partially neutralized acrylic copolymer emulsion. When converted to a colloidal dispersion with the amine or alkali of your choice, a vehicle with excellent binding properties at low resin solids is obtained. This feature allows the ink maker to incorporate large amounts of water while maintaining stable viscosities and superb transfer properties. Key Performance Properties: - Excellent transfer - Dispersions have Newtonian flow with viscosities up to 10,000 cps - Freeze-thaw stability - Easy water clean-up - Ammonia-stabilized colloidal dispersions available as VANCRYL 454 and VANCRYL 456 dispersions Typical Properties: Appearance: White emulsion Non-volatiles: 25-27% pH_ 6.2-6.8 Viscosity: 100-500 cps Glass Transition Temperature: Density: 8.6 lbs/gal Surface Tension: 45 dynes/cm Molecular Weight: Mn 42,000 Mw 82,000 Flash Point: Non-combustible Freeze-Thaw Stability: Stable

25C

42

Water-Soluble Resins

AIR PRODUCTS AND CHEMICALS, (Continued):

INC.: VANCRYL Acrylic Resins

VANCRYL 454 Colloidal Dispersion: Acrylic Colloidal Dispersion for Economical

Inks

VANCRYL 454 colloidal dispersion provides excellent binding properties at low resin solids. This feature allows the ink maker to incorporate large amounts of water while still maintaining stable viscosities and superb transfer properties. Key Performance Properties: - Excellent transfer - Newtonian flow with viscosities as high as 10,000 cps - Freeze-thaw stability - Easy water clean-up - Can be supplied partially solutioned at higher solids - Can be supplied with bases other than ammonia Prooerties: -*Appearance: Clear solution pH: 8.0-8.5 Density: 8.7 lbs/gal Molecular Weight: Mn 42,000 Mw 82,000

TVDiCd

Non-volatiles: 20-22% Viscosity: 6,000-9,000 cps Glass Transition Temperature: 25C Flash Point: Non-combustible Freeze-Thaw Stability: Stable

VANCRYL 456 Colloidal Dispersion: Acrylic Colloidal Dispersion for Economical

Inks

VANCRYL 456 colloidal dispersion provides excellent binding properties at low resin solids. This feature allows the ink maker to incorporate large amounts of water while still maintaining stable viscosities and superb transfer properties. Key Performance Properties: - Excellent transfer - Freeze-thaw stability - Can be supplied in partial (VANCRYL 453 emulsion) - Can be supplied with bases

- Newtonian flow - Easy water clean-up solution at higher solids other than ammonia

Typical Properties: Appearance: Clear solution Non-volatiles: 16-17% DH: 8.0-8.5 Viscosity: 1,500-2,000 CPS Density: 8.6 lbs/gal Glass Transition Temperature: 25C Molecular Weight: Mn 42,000 Mw 82,000 Flash Point: Non-combustible Freeze-Thaw Stability: Stable

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, Emulsions:

43

INC.: VANCRYL Styrene-Acrylic

VANCRYL 915 Emulsion: Styrene-Acrylic Emulsion for Inks and Coatings VANCRYL 915 emulsion is a fine particle size, high molecular weight polymer. With VANCRYL 915 emulsion, very high gloss is achieved in ink and coating formulations. Gloss levels are similar when coatings based on VANCRYL 915 emulsion are printed over imaged and non-imaged areas. Key Performance Properties: - Very high gloss - Rapid drying - Excellent rheology - Crosslinkable - Compatible with most water-based vehicles Tvvical Proverties: Non-volatiles: 45-47% --Appearance: Off-white emulsion Viscosity: 150-250 cos pH: 8.5-9.0 Density: 8.8 lbs/gal Glass Transition Temperature: 81C Particle Size: 0.13 micron Surface Tension: 38 dynes/cm Freeze-Thaw Stability: Stable Flash Point: Non-combustible Stabilization System: Anionic VANCRYL 930 Emulsion: Styrene-Acrylic Emulsion for Inks and Coatings VANCRYL 930 emulsion is a high solids, fine particle size emulsion polymer. It is a hard polymer which provides excellent gloss in inks and coatings. The filming properties coupled with its rapid water release result in very rapid drying. Inks and coatings formulated with VANCRYL 930 emulsion have outstanding water and abrasion resistance. Key Performance Properties: - Very fast drying - High gloss - Crosslinkable - Excellent rheology for gravure application - Compatible with most water-based vehicles Typical Properties: --Appearance: Off-white emulsion Non-volatiles: 47-48% pH: 8-O-8.5 Viscosity: 100-300 cps Density: 8.7 lbs/gal Surface Tension: 34 dynes/cm Glass Transition Temperature: 24C Particle Size: 0.08 micron Flash Point: Non-combustible Freeze-Thaw Stability: Stable Stabilization System: Anionic

44

Water-Soluble

Resins

AIR PRODUCTS AND CHEMICALS, Rmulsions(Continued1:

INC.: VANCRYL Styrene-Acrylic

VANCRYL 950 Emulsion: Styrene-Acrylic Emulsion for Inks and Coatings VANCRYL 950 emulsion is a soft, fine particle size emulsion polymer. Adhesion to various low energy surfaces such as films and foils is good. Functional side groups in the polymer backbone promote adhesion and afford sites for both ionic and thermoset crosslinking. Key Performance Properties: - Adhesion to low energy surfaces - Good grease resistance - Softness

- Fast drying - Crosslinkable

Typical Properties: Appearance: Off-white emulsion Non-volatiles: 45-47% DH: 8.0-8.6 Viscositv: 400-800 CDS Glass Transition Temperature: -17C Surface Tension: 35 dynes/cm Particle Size: 0.10 micron Flash Point: Non-combustible Freeze-Thaw Stability: Stable Stabilization System: Anionic Density: 8.7 lbs/gal

Air Products and Chemicals

45

AIR PRODUCTS AND CHEMICALS, INC.: VANCRYL Vinyl ChlorideEthylene Resins for Waterborne Inks and Overprint Varnishes: These resins are terpolymers of vinyl chloride and ethylene with a third monomer which imparts either amide or carboxyl functionality. VANCRYL vinyl chloride-ethylene emulsions offer the ink formulator the following properties in water-based flexographic and gravure ink formulations: Excellent mechanical stability Low viscosity at high solids Excellent abrasion resistance Excellent compatibility with most commonly used dispersions and other ink additives Excellent resistance to dry and wet rubs Good adhesion to polyesters and vinyls VANCRYL 600: Emulsion Properties: Solids Content, minimum wt. %: 50 pH: 7-9 Viscosity, cps: 25-150 Functional Group: Amide Odor: Low Mechanical Stability: Excellent over pH range 4-11 Average Particle Size, microns: 0.12 Particle Charge: Anionically stabilized Density (lbs/gal): 9.27 Film Formation at Room Temp.: Yes % Chlorine Content, by weight: 40 Film Properties: Glass Transition Temperature, C: 0 Tensile Strength, psi: 600 Elongation at Break, %: 1700 Relative Heat Sealing Temperature, F: 190 VANCRYL 605: Emulsion Properties: Solids Content, minimum wt. %: 50 pH: 7-9 Viscosity, cps: 25-150 Functional Group: Amide Odor: Low Mechanical Stabilitv: Excellent over DH range 4-11 Average Particle Size, microns: 0.12 Particle Charge: Anionically stabilized Density (lbs/gal): 9.31 Film Formation at Room Temp.: Yes % Chlorine Content, by weight: 42.5 Film Properties: Glass Transition Temperature, C: 14 Tensile Strength, psi: 1100 Elongation at Break, %: 675 Relative Heat Sealing Temperature, F: 210

46

Water-Soluble

Resins

AIR PRODUCTS AND CHEMICALS, INC.: VANCRYL Vinyl ChlorideEthylene Resins for Waterborne Inks and Overprint Varnishes (Continued): VANCRYL Grade 610: Emulsion Properties: Solids Content, minimum wt. %: 50 pH: 7-9 Viscosity, cps: 25-150 Functional Group: Amide Odor: Low Mechanical Stability: Excellent over pH range 4-11 Average Particle Size, microns: 0.11 Particle Charge: Anionically stabilized Density (lbs/gal): 9.42 Film Formation at Room Temp.: No % Chlorine Content, by weight: 48 Film Properties: Glass Transition Temperature, C: 30 Tensile Strength, psi: 2100 Elongation at Break, %: 140 Relative Heat Sealing Temperature, F: 230 VANCRYL Grade 635: Emulsion Properties: Solids Content, minimum wt. %: 47 pH: 8.5-11.0 Viscosity, cps: 100-400 Functional Group: Carboxyl Odor: Ammoniacal Mechanical Stability: Excellent over pH range 4-11 Average Particle Size, microns: 0.12 Particle Charge: Anionically stabilized Density (lbs/gal): 9.20 Film Formation at Room Temp.: Yes % Chlorine Content, by weight: 42 Film Properties: Glass Transition Temperature, C: 14 Tensile Strength, psi: 1100 Elongation at Break, %: 675 Relative Heat Sealing Temperature, F: 210

Air Products and Chemicals

AIR PRODUCTS AND CHEMICALS, INC.: VINEX Thermoplastic Alcohol Copolymer Resins: 2000 Series:

47

Polyvinyl

VINEX 2000 Resin Series: The VINEX 2000 resin series combines water solubility and thermoplasticity in a single resin. These specialty polymers have a low melt temperature, thereby permitting extrusion in conventional equipment. Articles fabricated from the VINEX 2000 resin line offer numerous features including cold water solubility; excellent transparency; good mechanical properties; excellent aroma barrier, anti-fogging and anti-static properties; resistance to most solvents; grease and oil barrier properties. VINEX 2025 Resin: Typical Physical and Thermal Properties: Melt Index, g/10 mins: 24 Melting Range, C: 160-195 Glass Transition, C: 29 Melt Viscosity, n0 poise: 14,900 (195C) 4,560 (21OC) Extrusion Blown Film: Tensile Strength (Break): 3200 psi Elongation (Break): 320% Water Solubility: Breakup: 20 set Total Solubility: 45 set

48

Water-Soluble Resins

ALCO CHEMICAL CORP.: ALCOCLEAR

ACP:

ALCOCLEAR ACP is a reactive# anionic emulsion polymer for oil field water clarification. It is supplied as a freeflowing, stable latex emulsion. ALCOCLEAR ACP is effective for oil in water clarification processes commonly utilized in petroleum operations. ALCOCLEAR ACP helps to remove oil, suspended solids, emulsions, and other contaminants from oil field waters. Typical Properties: Appearance: Milky White Emulsion Emulsion Type: Anionic Solids, Wt.%: 2Oil.O pH: 2.0-4.0 Viscosity, Brookfield, CPA #1/2ORPM @ 20C: 50.0 Specific Gravity @ 20C: 1.055, Typical # Adding an alkaline (e.g., NaOH, KOH, NHIOH, Amines) agent to the ALCOCLEAR ACP emulsion results in the neutralization of acidic groups and the formation of a clear, highly viscous liquid.

Alto Chemical

ALCG CHEMICAL CO.: ALCOCLEAR CCP-I and CCP-II Water Clarification Polymers: ALCOCLEAR CCP-I and CCP-II: ALCOCLEAR CCP-I AND CCP-II are hish molecular weicht cationic polymers for oil field water clarification.-ALCOCLEAR CCP-I and CCP-II are effective in a variety of oilin-water clarification processes commonly employed in oil field operation. Oil field water contains hvdrocarbons and other diswersed materials. These contaminants-must be removed for environmentally safe water disposal. ALCOCLEAR CCP-I AND CCP-II improve the efficiency of these processes. Benefits: - Coalesces Oil Particles - Allows Broad Treatment Level Without Over Treatment - Flocculates Suspended Solids - Resolves Oil-In-Water Emulsions - Helps Meet Environmental Satndards More Easily - Minimizes Oil Carry-Over In Water Injection Systems Applications: ALCOCLEAR CCP-I and CCP-II help to remove oil, suspended solids, emulsions and other contaminants from oil field waters. ALCOCLEAR CCP-I and CCP-II improve phase separation in dispersed gas flotation systems. ALCOCLEAR CCP-I and CCP-II help to break oil and water emulsions in coalescers, precipitators, gun barrels, skimmers and other oil field water handling equipment. Typical Properties: ALCOCLEAR CCP-I: Appearance: Clear Viscous Liquid Solids, Wt. %: 8.0+-0.5 pH: 5.0+-0.03 Viscosity, Brookfield, CPS @ 20C: 3200 Specific Gravity @ 20C: 1.021+-0.02 Density, lbs./gal. @ 20C: 8.5 ALCOCLEAR CCP-II: Appearance: Clear Viscous Liquid Solids, Wt. %: 7.25+-0.5 pH: 4.5+-0.03 Viscosity, Brookfield, cPs @ 25C: 12000 Specific Gravity @ 20C: 0.997+-0.02 Density, lbs./gal. @ 20C: 8.3

49

50

Water-Soluble Resins

CHEMICAL CORP.: AQUATREAT Products:

ALCO

Polyacrylic AR

Industrial Water

Treatment

kids:

4: Total Solids: 24-26 pH: 2.2-3.5 Intrinsic Viscosity: O-16-0.23 Mw: 60000 Water Treatment Dispersant and Sludge Conditioner

AR 6:

Total Solids: 24-26 pH: 2.2-3.5 Intrinsic Viscosity: 0.25-0.33 Mw: 100000 Water Treatment Dispersant and Sludge Conditioner AR

257: Total Solids: 52-56 pH: 4.0-5.5 Intrinsic Viscosity: 0.04-0.06 Mw: 2000 Mn: 1100 Recommended for Severe Calcium Carbonate Fouling Conditions

AR 900A:

Total Solids: 49-51 pH: 2.2-3.5 Intrinsic Viscosity: 0.05-0.08 Mw: 2600 Mn: 1500 General Purpose Antiscalant AR

921A:

Total Solids: 49-51 pH: 3.8-4.3 Intrinsic Viscosity: 0.06-0.08 Mw: 3000 Mn: 2200 General Purpose Antiscalant and Calcium Sulfate Fouling

Alto Chemical

CHEMICAL CO.: AQUATREAT Products(Continued1:

ALCO

Industrial Water Treatment

Sodium Polyacrylates: AR

602: Total Solids: 44-46 pH: 7.0-8.0 Intrinsic Viscosity: 0.10-0.14 Mw: 4500 Mn: 3600 General Purpose Boiler Water Dispersant

and Antiscalant

AR

648: Total Solids: 47-49 pH: 3.5-4.0 Intrinsic Viscosity: 0.05-0.08 Mw: 2600 Mn: 1500 General Purpose Antiscalant

AR

900: Total Solids: 32-34 pH: 5.3-5.7 Intrinsic Viscosity: 0.05-0.08 Mw: 2600 Mn: 1500 General Purpose Antiscalant

AR

855: Total Solids: 54-56 pH: 5.5-6-O Intrinsic Viscosity: 0.06-0.08 Mw: 2600 Mn: 1800 Recommended for Brine and/or High Calcium Water

AR

949: Total Solids: 43-44 pH: 8.1-8.3 Intrinsic Viscosity: 0.06-0.08 Mw: 2400 Mn: 1900 Recommended for Brine and/or High Calcium Water

AR

700: Total Solids: 30-32 pH: 7.0-8.0 Intrinsic Viscosity: 0.06-0.10 Mw: 2600 Mn: 2000 General Purpose Boiler Water Antiscalant

51

52

Water-Soluble

Resins

ALCO CHEMICAL CO.: AQUATREAT ProductsfContinued):

Industrial Water Treatment

Sodium Polymethacrylates: AR

231:

Total solids: 29-31 pH: 8.0-9.0 Intrinsic Viscosity: Mw:

0.11-0.15

6500

Mn: 4000 Boiler Water Dispersant and Sludge Conditioner AR

232:

Total Solids: 29-31 pH: 8.0-9-O Intrinsic Viscosity: 0.17-0.21 Mw: 9500 Mn: 5400 Boiler Water Dispersant and Sludge Conditioner

Alto Chemical

ALCO CHEMICAL CO.: AQUATREAT Products(Continued):

53

Industrial Water Treatment

Copolymers: CPA: Total Solids: 38-42 pH: 4.8-5.2 Intrinsic Viscosity: 0.06-0.10 Mw: 3000 Mn: 2200 Calcium Phosphate Antiscalant and Zinc Stabilizer AR 993: Total solids: 38-40 pH: 8.0-10.0 Intrinsic Viscosity: 0.06-0.10 Mw: 3200 Mn: 2200 General Purpose and Calcium Phosphate Antiscalant AR 626A: Total Solids: 49-51 pH: 2.2-2.6 Intrinsic Viscosity: 0.04-0.06 Mw: 3000 Mn: 1700 Calcium Phosphate, Barium Sulfate, and General Purpose Antiscalant AR 626: Total Solids: 45-47 pH: 6.0-8.0 Intrinsic Viscosity: 0.04-0.06 Mw: 3000 Mn: 1700 Calcium Phosphate, Barium Sulfate, and General Purpose Antiscalant AR 335: Total Solids: 48-50 pH: 6.8-7.5 Intrinsic Viscosity: 0.06-0.10 Mw: 3400 Mn: 2000 General Purpose Antiscalant AR 975: Total Solids: 39-41 pH: 7.0-8.0 Intrinsic Viscosity: 0.25-0.40 Mw: 18500 Mn: 6000 Barium Sulfate Antiscalant, Functions at cpH 4.5 AR 978: Total Solids: 41-43 pH: 4.5-5.5 Intrinsic Viscosity: 0.09-0.14 Mw: SOOO/Mn: 2500 Barium Sulfate Antiscalant, Functions at
54

Water-Soluble Rains

AQUALGN: AQUALON Cellulose Gum: Sodium Carboxymethylcellulose: An Anionic Water-Soluble

Polymer

AQUALON cellulose gum is purified sodium carboxymethylcellulose (CMC) with a minimum purity of 99.5%. An anionic water-soluble polymer derived from cellulose, it has the following functions and properties: - it acts as a thickener, binder, stabilizer, protective colloid, suspending agent, and rheology, or flow control, agent. - it forms films that are resistant to oils, greases, and organic solvents. - it dissolves rapidly in cold or hot water. - it is suitable for use in food systems. - it is physiologically inert. - it is an anionic polyelectrolyte. These properties and functions make it suitable for use in a broad range of applications in the food, pharmaceutical, cosmetic, paper, and other industries. Grades and Types: Grade: Food Designation: F Intended Use: Food, cosmetic, pharmaceutical Grade: Pharmaceutical Designation: P Intended Use: Cosmetic, pharmaceutical Grade: Standard Designation: None Intended Use: Industrial Degree of Substitution: Type: 4: Substitution Range: 0.38-0.55 Sodium Content, %: 4.5-6.1 7: Substitution Range: 0.65-0.90 Sodium Content, %: 7.0-8.9 9: Substitution Range: 0.80-0.95 Sodium Content: 8.1-9.2 12: Substitution Range: 1.15-1.45 Sodium Content: 10.5-12.0

Aqua/on Co.

AQUALON: AQUALON Cellulose Gum: Sodium Carboxymethylcellulose (Continued): Some Types of AQUALON Cellulose Gum: Viscosity Range at 25C, cps: 4: High - at 1% Concentration: SOO-2,000: 4Hl 7: High - at 1% Concentration: 2,500-6,000: 7H4 l,OOO-2,800: 7H3S, 7HOF 1,500-3,000: 7H Medium - at 400-800: 200-800: 100-200: 50-100:

2% Concentration: 7M 7M8S 7M2 7Ml

Low - at 2% Concentration: 25-50: 7L - at 4% Concentration: 50-200: 7L2 9: High - at 1% Concentration: 2,500-6,000: 9H4 Medium - at 2% Concentration: 1,500-3,100: 9M31 400- 800: 9M8 12: Medium - at 2% Concentration: 800-3,100: 12M31 400- 800: 12M8

55

56

Water-Soluble Resins

CO. : AQUAMN (Continued):

AQUALON

Cellulose Gum: Sodium Carboxymethylcellulose

Particle Size: Designation: None : Description: Regular Particle Size: On U.S. 30, %, max: 1 On U.S. 40, %, max: 5 c: Descriotion: Coarse Particie Size: On U.S. 20, %, max: 1 Through U.S. 40, %, max: 55 Through U.S. 80, %, max: 5

x: Description: Fine Particle Size: On U.S. 60, % max: 0.5 Through U.S. 200, %, min: 80 Typical Properties: Polymer - As Shipped: Sodium carboxymethylcellulose--dry basis, % min: 99.5 Moisture content (as packed), %, max: 8.0 Browning temperature, C: 227 Charring temoerature, C: 252 Bulk density; g/ml: 6.75 Biological oxygen demand (BOD), ppm: 7H type: 11,000 7L type: 17,300 Solutions: Specific gravity, 2% solution, 25C: 1.0068 Refractive index, 2% solution, 25C: 1.3355 PHI 2% solution:.7.5 Surface tension, 1% solution, dynes/cm at 25C: 71 Bulking value in solution, gal/lb: 0.0652 TYpiCal

__

Films (Air-Dried): Density, g/ml: 1.59 Refractive index: 1.515

Aqua/on Co.

57

AQUALON CO.: AQUALON CMC-T Sodium Carboxymethylcellulose: AQUALON CMC-T is a technical grade of sodium carboxymethylcellulose (CMC). In making CMC, inorganic salts (primarily sodium chloride and sodium glycolate) are formed as byproducts. CMC-T is used in applications where these salts can be tolerated. The minimum concentration of sodium carboxymethylcellulose in CMC-T is 98%. Several viscosity types, in powder forms of different particle sizes, are available. CMC-T: - Acts as a thickener, agent - Forms films that are organic solvents - Dissolves readily in - Has a low biochemical

binder, stabilizer, resistant

and suspending

to oils, greases, and

hot or cold water oxygen demand (BOD)

With these properties and functions, CMC-T can be used in a wide range of applications in the textile, adhesive, detergent, paper, paint; and other industries. Typical Properties: Polymer--As Shipped: Sodium carboxymethylcellulose--dry basis, %, min: 98.0 Moisture content, %, max: 8.0 Brownins temperature. C: 227 Charring temperature; C: 252 Bulk density, g/ml: 0.75 Biological oxygen demand (BOD), ppm: 7H type: 11,000 7L type: 17,300 Solutions: Specific gravity, 2% solution, 25C: 1.0068 Refractive index, 2% solution, 25C: 1.3355 pH, 1% solution: 6.5-8.5 Surface tension, 1% solution, dynes/cm at 25C: 71 Bulking value in solution, gal/lb: 0.06 Typical Films (Air-Dried): Density, g/ml: 1.59 Refractive index: 1.515

58

Water-Soluble

Resins

AQUALON CO.: CULMINAL Methylcellulose/Methylhydroxyethylcellulose/Methylhydoxypropylcellulose/Carboxymethylmethylcellulose: CULMINAL products are water-soluble, nonionic cellulose ethers that are used in many industrial applications as water retention aids, thickening agents, protective colloids, suspending agents, binders and stabilizers. Chemistry of Cellulose Ethers: Cellulose is a polysaccharide composed of individual anhydroglucose units which are linked through a B-l,4 glycosidic bond. The number "n" of anhydroglucose units in the polymer chain is defined as the degree of polymerisation (DP). Each anhydroglucose ring carries three OH-groups at positions 2, 3 and 6, which are chemically active. The distribution of the substituents introduced onto the polymer chain is largely determined bv the relative reactivitv of these three OH-groups. __ Cellulose Ethers: Industrial cellulose ethers are alkyl, alkylhydroxyalkyl, hydroxyalkyl, and carboxyalkyl ethers derived-from cellulose. Ethers are formed by substituting some of the cellulose hydroxyl groups. The use of one etherification agent in the substitution process results in a simple cellulose ether, whereas other different kinds of agents leads to mixed ethers. TvDeS and substitution ranges of CULMINAL: CZMINAL Type: MC: Reactant: CH3Cl Substitution range: OCH3: DS: 1,41-1,95 %: 24-32 MHEC: Reactant: CH3C1, C2H40 Substitution range: OCH3: DS: 1,30-2,22 %: 22-30 Second subsituent: MS: 0,06-0,50 %: 2-14 MHPC: Reactant: CH3C1, C3H60 Substitution range: OCH3: DS: 1,17-2,33 %: 20-30 Second subsituent: MS: 0,05-0,80 %: 2-25 CMMC: Reactant: CH3C1, ClCH2COONa Substitution range: OCH3: DS: 1,28-1,82 %: 22-30 Second subsituent: MS: 0,04-0,12 %:

2-5

Aqua/on

Co.

59

AQUALON CO.: CULMINAL Uethylcellulose/Methylhydroxyethylcellulose/ Methylhydroxypropylce1lulose/Carboxymethylmethylcelluose (Continued): Product properties of dry CULMINAL: Purity: Active content, dry basis: min. 98,0% Moisture content: max. 8% Salt content: max. 2,0% Ash, as sulfate: max. 2,5% Sieve analysis: Granular: between 0,2-0,Emm: min. 80% on O,Emm/ASTM no. 25: max. 1% Powder: on 0,2mm/ASTM no. 80: max. 8% PF: on O,125mm/ASTM no. 120: max. 8% PFF: on 0,lmm: max. 10% on O,063mm/ASTM no. 230: max. 35% Biological oxygen demand: after 5 days, BOD 5, mg 02/mg product:

O-O,1

Bulk density, g/l: 250-500 Decomposition

temperature,

c:

,220

Properties of CULMINAL solutions: Viscosity-Ranges of 2% aqueous solutions at 20C and 20 rpm, mPas (CDS), Brookfield RV: 10 -15000 CULMINAL MC: 100 -40000 CULMINAL MHEC: 20 -40000 CULMINAL MHPC: 1000 - 2200 CULMINAL CMMC: Flocculation range CULMINAL MC: MHEC: MHPC: CMMC:

of 0.5% aqueous solutions: 50-75c 60-9OC 60-9OC > 9oc

Surface tension at 2oc, O,l% solutions, mN/m (dyne/cm): 45-55 Interfacial tension at 20C O,l% solution versus paraffin oil: mN/m (dvne/cm): ca. 20 pHivalue of 1% solutions at 20C: typically 5,5-9,5 pa-stability at 20C: pH 2 to 11 Freezing point of 2% aqueous solutions: OC Density of 2% aqueous solutions at 20C: 1,0032 g/ml

60

Warer-Soluble Resins

AQUALON CO.: KLUCEL Hydroxypropylcellulose: KLUCEL hydroxypropylcellulose is manufactured by reacting alkali cellulose with propylene oxide at elevated temperatures and pressures. The propylene oxide can be substituted on the cellulose through an ether linkage at the three reactive hydroxyls present on each anhydroglucose monomer unit of the cellulose chain. Published information suggests that etherification takes place in such a way that hydroxypropyl substituent groups contain almost entirely secondary hydroxyls. The secondary hydroxyl present in the side chain is available for further reaction with the oxide, and chaining-out may take place. This results in formation of side chains containing more than one mole of combined propylene oxide. It is probable that most of the primary hydroxyls on the cellulose have been substituted and that the reactive groups remaining are secondary hydroxyls. The number of anhydroglucose units that are joined in the cellulose chain is referred to as the degree of polymerization (DP). Solution viscosity is largely determined by the DP of the cellulose backbone; higher viscosity grades have higher DP values and higher molecular weights. Grades and Viscosity Types: Grades of KLUCEL: Grade: Standard Designation: Intended Use: Industrial Grade: Food Designation: F Intended Use: (Food (Pharmaceutical (Cosmetic

Aqua/on Co.

AQUALON CO.: KLUCEL HydroxypropylcellulosefContinued): Viscosity Types and Their Corresponding

Molecular Weights

Types: Standard: H Food: HF Concentration in Water by Weight: MW: 1,150,000 Standard: M Food: MF Concentration MW: 850,000 Standard: G Food: GF Concentration MW: 370,000 Standard: J Food: JF Concentration MW: 140,000 Standard: L Food: LF Concentration MW: 95,000 Standard: Food: EF Concentration MW: 80,000 Standard: E Food: Concentration MW: 80,000

1%: 1,500-3,000

in Water by Weight: 2%: 4,000-6,500

in Water by Weight: 2%: 150-400

in Water by Weight:

5%: 150-400

in Water by Weight:

5%: 75-150

in Water by Weight:

10%: 200-600

in Water by Weight: 10%: 150-700

61

62

Water-Soluble Resins

AQUALCN CO.: KLUCEL Hydroxypropylcellulose(Continued): Grades and Viscosity Types(Continued): Viscosity Types and Their Corresponding

Molecular Weights

Types: Standard: H Food: HF Concentration in Anhydrous Ethanol by Weight: MW: 1,150,OOO Standard: M Food: MF Concentration MW: 850,000 Standard: G Food: GF Concentration MW: 370,000 Standard: J Food: JF Concentration MW: 140,000 Standard: L Food: LF Concentration MW: 95,000 Standard: E Food: EF Concentration MW: 80,000

1%: l,OOO-3,000

in Anhydrous Ethanol by Weight:

2%: 3,000-6,500

in Anhydrous

Ethanol by Weight:

2%: 75-400

in Anhydrous Ethanol by Weight:

5%: 75-400

in Anhydrous Ethanol by Weight:

5%: 25-150

in Anhydrous Ethanol by Weight:

10%: 150-700

Aqualon Co.

63

AQUALON CO.: NATROSOL Hydroxyethylcellulose: NATROSOL hydroxyethylcellulose is a nonionic water-soluble oolvmer derived from cellulose. Like AQUALON cellulose gum isodium carboxymethylcellulose), it is a cellulose ether, but it differs in that it is nonionic and its solutions are unaffected by cations. NATROSOL dissolves readily in water, either cold or hot. Its solutions have somewhat different flow properties from those obtained with other water-soluble polymers. It is used to produce solutions having a wide range of viscosity. Such solutions are pseudoplastic--that is, they vary in viscosity depending on the amount of stress applied. Chemistry: The NATROSOL polymer is a hydroxyethyl ether of cellulose. Each anhydroglucose unit contains three hydroxyls capable of reaction. By treating cellulose with sodium hydroxide and reacting with ethylene oxide, hydroxyethyl groups are introduced to yield a hydroxyethyl ether. The reaction product is purified and ground to a fine white powder. Substitution: Each anhydroglucose unit in the cellulose molecule has three reactive hydroxyl groups. The number that is substituted in any reaction is known as the "degree of substitution," or DS. Theoretically, all three hydroxyls can be substituted. The product from such a reaction would have a DS of three. Grades and Viscosity Types: Viscosity: NATROSOL 250 HEC is produced listed.

in the 10 viscosity

types

R-Grades: All grades and types of NATROSOL can be treated to provide a powder that displays fast dispersion without lumping when added to water. The grades so treated are designated by the letter R. This treatment does not alter the solution viscosity. Some grades and viscosity types are available without this treatment if desired. B-Grades: Certain medium- and high-viscosity types of NATROSOL are available in a grade that has superior biostability solution. These grades are designated by the letter B.

250 in

Particle Size: NATROSOL can generally be supplied in any one of the three particle sizes listed.

64

Water-Soluble

Resins

AQUALON CO.: NATROSOL Hydroxyethylcellulose(Continued): Typical Viscosity Ranges and Typical Molecular Weights for NATROSOL HEC: Brookfield Viscosity at 25C, cps at Varying Concentrations:

-Viscosity Type: 250HHR: 1%: 3,400-5,000 Molecular Weight:

1.3x10

6

250H4R: 1%: 2,600-3,300 Molecular Weight:

1.1x10

6

250HR: 1%: 1,500-2,500 Molecular Weight:

1.0x10

6

7.2x10

5

3.0x10

5

9.0x10

4

25OMHR: 1%: 800-1,500 250MR: 2%: 4,500-6,500 Molecular Weight: 25OKR: 2%: 1,500-2,500 250GR: 2%: 150-400 Molecular Weight: 250ER: 2%: 25-105 250JR: 5%: 150-400 250LR: 5%: 75-150 Molecular Weight:

Aqualon Co.

AQUALON CO.: NATROSOL Hydroxyethylcellulose(Continued): Typical Properties of NATROSOL HEC: Polymer: Powder, white to light tan Moisture content (as packed), %, max: 5.0 Ash content (calculated as Na2S04), %: 5.5 Effect of heat: Softening range, C: 135-140 Browning range, C: 205-210 Bulk density, g/ml: 0.6 Particle size: Regular grind--on U.S. 40 mesh, %, max.: 10 X srind--on U.S. 60 mesh. %. max: 0.5 W grind--on U.S. 80 mesh; %; max: 0.5 Biological oxygen demand (BOD), ppm: Type H (250): 7,000 Type L (250): 18,000 Solutions: Specific gravity, 2% solution, g/ml: 1.0033 Refractive index, 2% solution: 1.336 pH: 7 Surface tension, dynes/cm (N/m): NATROSOL 250LR at 0.1%: 66.8tO.0668) at 0.001%: 67.3(0.0673) Interfacial tension vs Fractol, dynes/cm(N/m) NATROSOL 250LR at 0.001%: 25.5tO.0255) Bulking value in solution, gal/lb(l/kg): 0.1(8.34) Films: Refractive index: 1.51 Specific gravity at 50% relative humidity, g/ml: 1.34 Moisture content (equilibrium), %: At 73F, 50% relative humidity: 6 At 73F, 84% relative humidity: 29

65

66 Water-Soluble

Resins

AQUALON CO.: NATROSOL PLUS, Grade 330, Modified Hydroxyethylcellulose: NATROSOL PLUS, Grade 330, is an associative cellulosic polymer designed specifically for use in latex paints. Different from traditional cellulosics, this polymer offers the paint formulator enhanced rheology control. NATROSOL PLUS is a unique polymer, combining many of the desirable properties of NATROSOL hydroxyethylcellulose with the rheological performance of synthetic associative thickeners. Although NATROSOL PLUS is useful in all paint types, its performance advantages are most apparent in interior and exterior flat paints. Unique Properties of NATROSOL PLUS: - Outstanding spatter resistance - Enhanced brushing viscosity - Better leveling with good sag resistance - Excellent stability - Excellent color properties - Wide compatibility with latexes Toxic Substances Information: CAS Number: 9004-62-o CAS Name: Cellulose, hydroxyethyl

ether

Typical Properties: Form, as supplied: white to off-white powder Moisture content (as packed), max. %: 5.0 Ash content (calculated as Na2S04), max. %: 10.0 Bulk density, g/ml: 0.55-0.75 Particle size on U.S. 40 mesh, max, %: 10.0 Brookfield viscosity (1% in water, 6 rpm), cps: 150-500 Solution appearance: clear Hydration time at pH 7.2, minutes: 6-20 Bulking value, gal/lb: 0.1 Solution pH: 6.0-8.5 Chemical Composition: NATROSOL PLUS is a nonionic water-soluble polymer. Its composition can be described as hydrophobically modified hydroxyethylcellulose (HMHEC). The hydrophobic modification consists of long-chain alkyl groups chemically bound to the polymer. The physical properties of unmodified hydroxyethylcellulose (HEC) and hydrophobically modified HEC are considerably different. The chemical modification of HEC contributes increased solution viscosity and altered rheological properties. The nonionic nature of NATROSOL PLUS is an advantage in latex paints. Nonionics can be used over a wide pH range, and, unlike polyelectrolytes, are compatible with salts and charged species such as surfactants and latex particles.

Aqua/on Co.

AQUALON

CO.:

67

NATROVIS Iiydroxypropyl Hydroxyethylcellulose:

NATROVIS is the tradename for a novel family of cellulose ethers, that has been developed for use in a variety of building materials. It is a water soluble polymer derived from cellulose. NATROVIS is nonionic in character and its solutions are, therefore, unaffected by anions and cations. NATROVIS is produced bv carefully reactins two substituents on the cellulose backbone; which makes this water soluble Polymer highly compatible with alkaline hydraulic binder and-latex-modified-systems. The addition of NATROVIS imparts to such binder systems the required water retention properties, water retention that is maintained over a wide range of temperature, pH and shear. NATROVIS solutions have flow properties somewhat different from those obtained with other water soluble polymers. Their rheology is pseudoplastic, i.e, they vary in viscosity, depending upon the rate of shear applied. In hydraulic binder systems this pseudoplastic behaviour of NATROVIS results in a unique workability and a high consistency. Properties of NATROVIS: The following typical properties apply to all grades: Appearance: Cream to tan powder Bulk density, ks/l: 0.6 Moisture content, as packed, %: 4.5 Ash content (as Na2S04), %: varies with grade pH: 7 Surface tension, mN/m: 56.5 Viscosity: As specified for the grade The versatility of NATROVIS and its effectiveness at low dosages, make it applicable in a large variety of building materials. Whenever a building material contains water, NATROVIS enables the formulator to control its properties, such as: -

Water balance Workability Water retention Adhesion Consistency Sliding resistance Open time Tackiness

and thus to optimize the performance

of his product.

68

Water-Soluble Resins

AQUALON CO.: SUPERCOL Guar Gum: SUPERCOL guar gum is a high-purity, food-grade, water-soluble polymer that functions in foods by changing the viscosity of the water or controlling its mobility. In this way, usable stabilization, thickening, water-binding, and viscosity control are produced without adding calories. Source and Chemistry: Guar is a leguminous plant that crows to a heiaht of 3 to 6 feet. It bears many beanlike pods, Gash of which contains 6 to 9 small, rounded seeds. Because of its drought resistance, it grows mostly in the semiarid regions of the-world such as-India, Pakistan, amd the Southwestern United States. The growing season is 20 to 25 weeks long, and harvesting takes place in the fall. The guar seed is typically made up of 40 to 46% germ, 38 to 45% endosperm, and 14 to 16% husk. SUPERCOL guar gum is prepared by removing the husk and germ portions before extracting the gum from the endosperm to yield high-purity powder products of varying granulation and viscosity. Chemically, guar gum is a galactomannan, best illustrated with galactose on every other mannose unit. Approximate Analysis: Fiber, l-2% Galactomannan, 80-85% Moisture, lo-128 Ash, 0.5-1-O% Protein, 3-4% Fat, 0.5% On average, the molecular weight is within the range of 1 million to 2 million. SUPERCOL guar gum grades comply with the Food Chemicals Codex and meet standards set by the U.S. Code of Federal Regulations, Title 21, Section 184.1339-"Substances that are generally recognized as safe" (GRAS). Typical Properties of SUPERCOL Guar Gum: Grade of SUPERCOL: 63: Granulation: Form: Coarse Mesh: 100 Viscosity, 11% Moisture Basis(MB): 3,800 Speed of Hydration: Rate: Slow Peak Viscosity Developed in 15 Minutes Dispersibility in Water at 25C: Excellent

(Cold), %: 30

Aqua/on Co.

69

AQUALON CO.: SUPERCOL Guar Gum(Continued): Typical Properties of SUPERCOL Guar Gum: Grade of EPERCOL: -G2: Granulation: _ _. Form: Medium-coarse Mesh: 150 Viscosity, 11% Moisture Basis (MB): 4,500 Speed of Hydration: Rate: Moderate Peak Viscosity Developed in 15 Minutes (Cold), %: 40 Disnersibilitv in Water at 25C: Excellent GF: Granulation: Form: Medium-fine Mesh: 175 Viscosity, 11% Moisture Basis (MB): 4,500 Speed of Hydration: Rate: Fast Peak Viscosity Developed in 15 Minutes (Cold), %: 70 Dispersibility in Water at 25C: Very good (requires some care) F: Granulation: Form: Fine Mesh: 200 Viscosity, 11% Moisture Basis (MB): 4,400 Speed of Hydration: Rate: Very fast Peak Viscosity Developed in 15 Minutes (Cold), %: 90 Dispersibility in Water at 25C: Requires care u: Granulation: Form: Fine Mesh: 200 Viscosity, 11% Moisture Basis (MB): 5,100 Speed of Hydration: Rate: Very fast Peak Viscosity developed in 15 Minutes (Cold), %: 95 Dispersibility in Water at 25C: Fair (requires care) ._ U special: Granulation: Form: Fine Mesh: 200 Viscosity, 11% Moisture Basis (MB): 5,500 Speed of Hydration: Rate: Very fast Peak Viscosity Developed in 15 Minutes (Cold), %: 95 Dispersibility in Water at 25C: Fair (requires care)

70

Water-Soluble

Resins

BERCEN, INC.: BERSET 2047 Crosslinker

and Cellulose Reactant:

BERSET 2047 is a new generation of glyoxal based crosslinking reactivity agents. Unlike conventional glyoxal, BERSET 2047’s is reduced during coating preparation and accelerated in the drying process. BERSET 2047 provides good viscosity in coatings containing starch or protein, while enhancing wet rub and wet pick resistance properties. Typical Properties: Type: Buffered glyoxal reactant Appearance: Clear, straw colored liquid pH: 3.0+-0.5 Solids: 50%+-1.0% Viscosity: Brookfield: 25+-10 cps Specific Gravity: 1.27+-0.02 Solubility: Dilutable with water in all proportions Advantages: - Good wet rub resistance off the machine - No formaldehyde odor - Coating exhibits stable viscosity characteristics - Compatible with most coating additives - Good wet pick resistance - Imparts good dimensional stability to paper Application: BERSET 2047 may be added directly to the coating color. Best results are achieved when BERSET 2047 is added last. The amount of BERSET 2047 depends on the type of binder used. Normally 3-10% as received, based on the weight of the binder, is sufficient for most coating formulations. A good starting point is a direct replacement of the presently used insolubilizer, pound for pound, on an as received basis. Coating colors containing BERSET 2047 exhibit a very modest viscosity increase immediately after addition of insolubilizer and remain stable over a 24 hour period. BERSET 2047 can be used in most types of paper coatings. Its efficiency as a crosslinker and insolubilizer is comparable to glyoxal and complete cure is achieved faster than with MF or UF insolubilizers. Storage Stability: BERSET 2047 should be stored between 45F.-90F., and has a shelf life of six months. Better color stability is maintained when the storage temperature is moderately cool.

Bercen, Inc.

71

BERCEN, INC.: BFRSET 2100 Crosslinker/Insolubilizer: BERSET 2100 is a newly designed and highly effective crosslinking agent. Unlike many other conventional resins, BERSET 2100 has no formaldehvde odor. BERSET 2100's reactivity is slower during coating-preparation and accelerated in the drying process, thus providing a stable viscosity. BERSET 2100 crosslinks all synthetic and natural binders during the drying cycle, resulting in a high degree of wet rub and wet pick resistance off machine. Coating colors containing BERSET 2100 exhibit a very modest viscosity increase immediately after addition of the insolubilizer. Typical Properties: Type: Monomeric reactant Appearance: Light, straw colored liquid pH: 3.0i0.5 Solids: 45%*1.0% Viscosity: Brookfield: 20*10 cps Specific Gravity: 1.25iO.02 Solubility: Dilutable with water in all proportions Advantages: - Develops good wet rub resistance - Coating formulations exhibit stable viscosity - Imparts good wet pick resistance - No formaldehyde odor - Compatible with most coating additives - Good shelf life Application: BERSET 2100 mav be added directlv as received to the coating color. Best results are achieved when BERSET 2100 is added last. The amount of BERSET 2100 depends on the type of binder used. Normally, 3-10% as received,-based on the weight of the binder, is sufficient for most coating formulations. Coating color containing BERSET 2100 exhibit a very modest viscosity increase immediately after the addition of insolubilizer and remain stable over 24 hour periods. Storage Stability: BERSET 2100 should be stored between shelf life of six months.

45-90F., and has a

72

Water-Soluble Resins

BERCEN, INC.: BERSET 2185 Coating Insolubiliser: BERCEN 2185 is part of a new generation of crosslinking agents. Unlike conventional melamines or urea resins, BERSET 2185's reactivity is accelerated only in the drying process. BERSET 2185 provides good viscosity in coatings containing starch or protein binders, and also provides superior wet rub and wet pick resistance properties. Typical Properties: Type: Glyoxal based reactant Appearance: Light straw colored liquid pH: 3.0io.5 Solids: 45%*1.0% Viscosity: Brookfield: 2OilO cps Specific Gravity: 1.2OiO.02 Solubility: Dilutable with water in all proportions Advantages: - Good wet-rub resistance off the machine - No formaldehyde odor - Coating exhibits stable viscosity characteristics - Provides excellent printing properties - Compatible with most coating additives - Imparts good dimensional stability to paper - Provides good wet pick resistance - Liquid for easy handling Applications: BERSET 2185 may be added directly as received to the coating color. Best results are achieved when BERSET 2185 is added last. The amount of BERSET 2185 depends on the type of binder used, but normally 3-10% as received, based on the binder weight, is sufficient for most coating formulations. Coating colors containing BERSBT 2185 exhibit very modest viscosity increases immediately after the addition of insolubilizer, and remain stable for a prolonged time. BERSET 2185 may be used with most type of paper coatings. Its efficiency as a crosslinker and insolubilizer is comparable to glyoxal, and complete cure is acheved faster than M.F. or U.F. insolubilizers. As for dimensional stability, BERSET 2185 can be added at the size press in conjunction with a starch carrier or alone. BERSET 2185 can also be sprayed onto the web at the web end. Beater additions have been made, but in most cases, economics do not permit this application. For good dimensional stability, 15-30% BERSET 2185, based on the weight of the fiber, should prove adequate. Storage Stability: BERSET 2185 should be stored between 45F.-90F. and has a shelf life of six months. Better color stability and longer shelf life is maintained when the storage temperature is moderately cool.

Bercen, Inc.

BERCEN, INC.: BERSET 2586 Crosslinker

73

and Insolubilizer:

BERSET 2586 is a melamine based coating insolubilizer. It is a very effective crosslinker for starch, protein, P.V.A. and latex binders in pigmented or non-pigmented coatings. BERSET 2586 is sufficiently reactive so that 85-90% of insolubilization is acheived directly off the machine and completely developed within a day. Unlike other crosslinkers, BERSET 2586 has little or no effect on coating viscosities. Typical Properties: Type: Modified melamine formaldehyde resin Appearance: Clear liquid pH: 9.0+-1.0 Solids: 70%+-l% Viscosity: Brookfield: 120+-50 cps Specific Gravity: 1.22+-0.02 Solubility: Dilutable in water in all proportions Advantages: - Good wet rub resistance - Economical - Good wet pick resistance - Good printing properties - Excellent storage stability - Low formaldehyde odor - Compatible with most coating additives Application: BERSET 2586 should be added last after the binder and pigment have been combined. Depending on the type of pigment binder used, 5-158 of BERSET 2586 as received based on the binder solids should be sufficient. The performance of BERSET 2586 can be accelerated by the addition of higher levels of resin where low drying temperatures are present as in off machine coatings. The use of BERSET 2586 in conventional or size press coatings greatly improves the wet and dry pick of the coated surface. BERSET 2586 can be used in pigmented or unpigmented treatments to improve the printing properties of the paper. BERSET 2586, used at 20-25% based on the starch solids at the size press, provides increased stiffness. Compatibility: BERSET 2586 is compatible with all commonly used coating additives. Storage Stability: BERSET 2586 should be stored between shelf life of six months.

45F.-90F. and has a

74

Water-Soluble Resins

CALLAWAY CHEMICAL CO.: Acrylamide Cationic PAM/DMDAAC Type:

Copolymers

- Cationic:

Product Properties: High molecular weight liquids (MW = 2 - 6 x 10 6) Several charge density compositions available True H20 solution Primary Application Areas: Wastewater clarification Sludge dewatering JAYFLOC 861 Liquid Cationic Polyelectrolyte: JAYFLOC 861 is a liquid organic cationic polymer with a high molecular weight and a low charge density. This product is designed to improve liquid/solid separation in sludge dewatering, flotation and as a coagulant aid in clarification operations. Typical Physical Properties: Appearance: Colorless, viscous liquid Density @ 77F: 8.5eO.l pounds per gallon Freezing Point: 27F pH (as supplied): 7il Viscosity @ 77F: 30,000-35,000 cps Application: JAYFLOC 861 has demonstrated effectiveness in a wide variety of industrial and municipal applications. The advantages of using JAYFLOC 861 include: 1) Improves centifugation, belt filter press and vacuum filter performance, 2) Improves sedimentation or flotation rates, 3) Reduces sludge volume with improved handling characteristics and 4) Performs effectively over a wide pH range. The most effective JAYFLOC product should be selected based on performance testing using actual system water or sludge.

Cal/away Chemical Co.

CALLAWAY CHEMICAL CO.: Acrylamide PAM/DWDAAC Type(Continued):

Copolymers-Cationic:

Cationic

JAYFLOC 863 Liquid Cationic Polyelectrolyte: JAYFLOC 863 is a liquid organic cationic polymer with a moderate molecular weight and a medium charge density. This product is designed to improve liquid/solid separation in sludge dewatering, flotation and as a coagulant aid in clarification operations. Typical Physical Properties: Appearance: Clear to pale yellow, viscous liquid Density @ JJF: 8.55+-0.1 pounds per gallon Freezing Point: 2JF pH (as supplied): 7+-l Viscosity @ JJF: J,SOO-15,000 cps Application: JAYFLOC 863 has demonstrated effectiveness in a wide variety of industrial and municipal applications. The advantages of using JAYFLOC 863 include: __ 1) Improves centrifugation, belt filter press and vacuum filter performance, 2) Improves centrifugation or flotation rates, 3) Reduces sludge volume with improved handling characteristics and 4) Performs effectively over a wide pH range The most effective JAYFLOC product should be selected based on performance testing using actual system water or sludge.

75

76

Water-Soluble Resins

CALLAWAY CHEMICAL CO.: Acrylamide Copolymers-Cationic: Cationic PAM/DMDAAC Type(Continued): JAYPLOC 865 Liquid Cationic Polyelectrolyte: JAYFLOC 865 is a liquid organic cationic polymer with a moderate molecular weight and a medium charge density. This product is designed to improve liquid/solid separation in sludge dewatering, flotation and as a coagulant aid in clarification operations. Typical Physical Properties: Appearance: Clear to pale yellow, viscous Density @ 77F: 8.5iO.l pounds per gallon Freezing Point: 27F pH (as supplied): 7~1 Viscosity @ 77F: 20,000-25,000 cps

liquid

Application: JAYFLOC 865 has demonstrated effectiveness in a wide variety of industrial and municipal applications. The advantages of using JAYFLOC 865 include: 1) Imvroves centrifusation, belt filter press and vacuum filter performance, 2) Improves sedimentation or flotation rates, 3) Reduces sludge volume with improved handling characteristics and 4) Performs effectively over a wide pH range. The most effective JAYFLOC product should be selected based on performance testing using actual system water or sludge.

Callaway Chemical Co.

CALLAWAY CHEMICAL CO.: Acrylamide Type:

Polymers:

77

Cationic PAM/DMAEMA

Product Properties: Hish molecular weisht emulsions Many charge density compositions readily available Fluid products for ease of handling and dissolution Excellent stability Principle Application Areas: Sludge thickening (DAF) dissolved Biological sludge dewatering Refinery Muncipal Paper Paper industry - Retention aid

air flotation

JAYFLOC 810 Cationic Flocculant: JAYFLOC 810 is a high molecular weight, low charge density cationic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Tvvical Phvsical Proverties: __ Appearance: Opaque water in oil emulsion Density @ 80F: 8.7+-0.1 pounds per gallon Freezing Point: 25F pH (1% solution): 6.0+-1.0 Viscosity @ 80F: 500-800 cps Application: JAYFLOC 810 has demonstrated particular effectiveness in industrial and munipal waste treatment operations (clarification, sludge conditioning, dewatering and thickening). JAYFLOC 811 Cationic Flocculant: JAYFLOC 811 is a high molecular weight, low charge density cationic emulsion poymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Opaque water in oil emulsion Density @ 80F: 8.7+-O-l pounds per gallon Freezing Point: OF Flash Point: >210F Viscosity @ 80F: 300-600 cps Application: JAYFLOC 811 has demonstrated particular effectiveness in industrial and municipal waste treatment operations (clarification, sludge conditioning, dewatering and thickening).

78

Water-Soluble Resins

CALLAWAY CHEMICAL CO.: Acrylamide Type(Continued):

Polymers:

Cationic PAM/DMAEMA

JAYFLOC 812 Cationic Flocculant: JAYFLOC 812 is a high molecular weight, medium charge density cationic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Opaque water in oil emulsion Density @ 80F: 8.7+-O-l pounds per gallon Freezing Point: 25F pH (1% solution): 6.0+-1.0 Viscosity @ 80F: 500-800 cps Application: JAYFLOC 812 has shown particular effectiveness in industrial and municipal wastewater treatment operations (clarification, sludge conditioning, dewatering, and thickening). JAYFLOC 814 Cationic Flocculant: JAYFLOC 814 is a high molecular weight, medium charge density cationic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Tvnical Physical Pronerties: --Appearance: Opaque water in oil emulsion Density @ 80F: 8.7+-0.1 pounds per gallon Freezing Point: 25F pH (1% solution): 6.0+-1.0 Viscosity @ 80~: 500-800 cps Application: JAYFLOC 814 has demonstrated particular effectiveness in industrial and municipal waste treatment operations (clarification, sludge conditioning, dewatering and thickening). JAYFLOC 815 Cationic Flocculant: JAYFLOC 815 is a high molecular density cationic emulsion polymer. to enhance liquid/solid separation industrial applications. Typical Physical Properties: Appearance: White water in oil Density @ 80F: 8.5+-0.1 pounds Viscosity @ 80F: 300-800 cps Freezing Point: -23F Flash Point SETA, CC: >210F

weight, medium charge This product is designed in a wide variety of emulsion per gallon

Application: JAYFLOC 815 has demonstrated particular effectiveness in industrial and municipal waste treatment operations (clarification, sludge conditioning, dewatering and thickening).

Callaway Chemical Co.

CALLAWAY CHEMICAL CO.: Acrylamide Type(Continued):

Polymers:

79

Cationic PAM/DMAEMA

JAYFLOC 816 Cationic Flocculant: JAYFLOC 816 is a high molecular weight, high charge density cationic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Opaque water in oil emulsion Density @ 80F: 8.7+-0.1 pounds per gallon Freezing Point: 25F pH (1% solution): 6.0+-1-O Viscosity @ 80F: 500-800 cps Application: JAYFLOC 816 has demonstrated particular effectiveness in industrial and municipal waste treatment operations (clarification, sludge conditioning, dewatering and thickening). JAYFLOC 817 Cationic Flocculant: JAYFLOC 817 is a high molecular weight, high charge density cationic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Opaque water in oil emulsion Density @ 80F: 8.5+-0.1 pounds per gallon Freezing Point: 25F pH (1% solution): 6.0+-1.0 Viscosity @ 80F: 500-800 cps Application: JAYFLOC 817 has demonstrated particular effectiveness in industrial and municipal wastewater treatment operations (clarification, sludge conditioning, dewatering and thickening). JAYFLOC 818 Cationic Flocculant: JAYFLOC 818 is a high molecular weight, high charge density cationic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Opaque water in oil emulsion Density @ 80F: 8.6+-0.1 pounds per gallon Freezing Point: 25F pH (1% solution): 6.0+-1-O Viscosity @ 80F: 500-800 cps Application: JAYFLOC 818 has demonstrated particular effectiveness in industrial and municipal wastewater treatment operations (clarification, sludge conditioning, dewatering and thickening).

80

Water-Soluble Resins

CALLAWAY CHEMICAL CO.: Acrylamide Type(Continued):

Polymers:

Cationic PAW/DWAEMA

JAYFLOC 819 Cationic Flocculant: JAYFLOC 819 is a hiqh molecular weiqht, low charqe density cationic emulsion polymer. This product is designed-to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Opaque water in oil emulsion Density @ 80F: 8.7+-0.1 pounds per gallon Freezing Point: OF Flash Point: 154F Viscosity @ 80F: 300-600 cps Application: JAYFLOC 819 has demonstrated particular effectiveness in industrial and municipal waste treatment operations (clarifification, sludge conditioning, dewatering and thickening). JAYFLOC 910 Cationic Flocculant: JAYFLOC 910 is a high molecular weight, high charge density cationic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Opaque water in oil emulsion Density @ 80F: 8.6+-0.2 lbs./per gallon Freezing Point: 25F pH (1% solution): 6.0+-1.0 Viscosity @ 80F: 500-2000 cps Application: JAYFLOC 910 has demonstrated particular effectiveness in industrial and municipal wastewater treatment operations (clarification, sludge conditioning, dewatering and thickening). JAYFLOC 911 Cationic Flocculant: JAYFLOC 911 is an extremely high molecular weight, high charge density cationic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Opaque water in oil emulsion Density @ 80F: 8.6+-0.2 lbs/per gallon Freezing Point: 25F pH (1% solution): 6.0+-1-O Viscosity @ 80F: 500-2000 cps Application: JAYFLOC 911 has demonstrated particular effectiveness in industrial and municipal wastewater treatment operations (clarification, sludge conditioning, dewatering and thickening).

Cal/away Chemical Co.

CALLAWAY CHEMICAL CD.: Acrylamide Type(Continued):

81

Polymers: Cationic PAM/DMAEWA

JAYFLOC 912 Cationic Flocculant: JAYFLOC 912 is an extremely high molecular weight, high charge density cationic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Opaque water in oil emulsion Density @ 80F: 8.6+-0.2 lbs./per gallon Freezing Point: 25F pH (1% solution): 6.0+-1.0 Viscosity @ 80F: 500-2000 cps Application: JAYFLOC 912 has demonstrated particular effectiveness in industrial and municipal wastewater treatment operations (clarification, sludge conditioning, dewatering and thickening). JAYFLOC 915 Cationic Flocculant: JAYFLOC 915 is a very high molecular weight, high charge density cationic emulsion polymer. This product is-designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Opaque water in oil emulsion Density @ 8OF: 8.6+-0.2 lbs./per gallon Freezing Point: 25F pH (1% solution): 6.0+-1.0 Viscosity @ 8OF: 500-2000 cps Application: JAYFLOC 915 has demonstrated perticular effectiveness in industrial and municipal wastewater treatment operations (clarification, sludge conditioning, dewatering and thickening). JAYFLOC 920: JAYFLOC 920 is a high molecular weight, low charge density cationic polyacrylamide. It is supplied as a low viscosity, opaque off-white water-in-oil emulsion. JAYFLOC 920 is a quaternernary ammonium cationic polymer which generally performs in the pH range of 2.5 to 12.0. Typical Properties: Appearance: Opaque off-white emulsion Density at 80F: 8.45+-0.2 pounds per gallon Viscosity at 80F: 500-1000 cp Activity: 26% Charge Density: 5% Freeze Point: 20F Application: JAYFLOC 920 is a cationic flocculant which is very effective in many solid-liquid separation processes. The product has been particularly effective for clarification and for sludge conditioning in municipal and industrial waste treatment operations.

82

Water-Soluble

Resins

CALLAWAY CHEMICAL CD.: Acrylamide Type(Continued):

Polymers: Cationic PAM/DMAEMA

JAYFLOC 921: JAYFLOC 921 is a medium molecular weight, low charge density cationic polyacrylamide. It is supplied as a low viscosity, opaque off-white water-in-oil emulsion. JAYFLOC 921 is a quaternary ammonium cationic polymer which generally performs in the pH range of 2.5 to 12.0. Typical Properties: Appearance: Opaque off-white emulsion Density at 80F: 8.65+-0.2 pounds per gallon Viscosity at 80F: 500-1000 cp Activity: 30% Charge Density: 8% Freeze Point: 20F Application: JAYFLOC 921 is a cationic flocculant which is very effective in many solid-liquid separation processes. The product has been particularly effective for clarification and for sludge conditioning in municipal and industrial waste treatment operations. JAYPLDC 922: JAYFLOC 922 is a high molecular weight, medium charge density cationic polacrylamide. It is supplied as a low viscosity, opaque off-white water-in-oil emulsion. JAYFLOC 922 is a quaternary ammonium cationic polymer which generally performs in the pH range of 2.5 to 12.0. Typical Properties: Aooearance: Owaue off-white emulsion Density at aOk:-8.75+-O-2 pounds per gallon Viscosity at 80F: 500-1000 cp Activity; 35% Charge Density: 19% Freeze Point: 20F Application: JAYFLDC! 922 is a cationic flocculant which is very effective in many solid-liquid separation processes. The product has been particularly effective for clarification and for sludge conditioning in municipal and industrial waste treatment operations.

Callaway Chemical Co.

CALLAWAY CHEMICAL CO.: Acrylamide Polymers: Cationic PAM/DMAEMA Type(Continued): JAYFLOC 923: JAYFLOC 923 is a medium molecular weight, medium charge density cationic polyacrylamide. It is supplied as a low viscosity, opaque off-white water-in-oil emulsion. JAYFLOC 923 is a quaternary ammonium cationic polymer which generally performs in the pH range of 2.5 to 12.0. Typical Properties: Appearance: Opaque off-white emulsion Density at 80F: 8.50+-0.2 pounds per gallon Viscosity at 80F: 500-1000 cp Activity: 30% Charge Density: 37% Freeze Point: 20F Application: JAYFLOC 923 is a cationic flocculant which is very effective in many solid-liquid separation processes. The product has been particularly effective for clarification and for sludge conditioning in municipal and industrial waste treatment operations. JAYFLOC 925: JAYFLOC 925 is a high molecular weight, high charge density cationic polyacrylamide. It is supplied as a low viscosity, milky white water-in-oil emulsion. JAYFLOC 925 is a quaternary ammonium cationic polymer which generally performs in the pH range 2.5 to 12.0. Typical Properties: Appearance: Milky white emulsion Density at 80F: 8.60+-0.1 pounds per gallon Viscosity at 80F: 500-1000 cp Activity: 40% Charge Density: 64% Freeze Point: IOF Application: JAYFLOC 925 is a cationic flocculant which is very effective in many solid-liquid separation processes. The product has been particularly effective for clarification and for sludge conditioning in municipal and industrial waste treatment operations.

83

84

Water-Soluble Resins

CALLAWAY CHEMICAL CO.: Acrylamide Type(Continued):

Polymers: Cationic PAW/DWAEMA

JAYFLOC 928: JAYFLOC 928 is a high molecular weight, very high charge density cationic polyacrylamide. It is supplied as a low viscosity, milky white water-in-oil emulsion. JAYFLOC 928 is a quaternary ammonium cationic polymer which generally performs in the pH range 2.5 to 12.0. Typical Properties: Annearance: Translucent white emulsion Density at 80F: 8.6OiO.l pounds per gallon Viscosity at 80F: 500-1000 cp Activity- 40% Charge Density: 80% Freeze Point: IOF Application: JAYFLOC 928 is a cationic flocculant which is very effective in many solid-liquid separation processes. The product has been particularly effective for clarification and for sludge conditioning in municipal and industrial waste treatment operations. JAYFLOC 3461 Cationic Flocculant: JAYFLOC 3461 is a low charge, high molecular weight, dry cationic polymer. This product is designed to enhance liquid/ solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: White free flowing granular powder Bulk Density (lbs/ft3): 50 pH (0.5% solution): 5.0 Viscosity (0.25% solution): 240 cps Application: JAYFLOC 3461 has demonstrated particular effectiveness in industrial, mining and municipal thickening and clarification processes. JAYFLOC 3461 has also exhibited applicability for wastewater treatment and sludge dewatering operations.

Callaway Chemical Co.

CALLAWAY CHEMICAL CO.: Acrylamide Type(Continued):

Polymers: Cationic PAM/DWAEMA

JAYF'LOC 3463 Cationic Flocculant: JAYFLOC 3463 is a medium charge, high molecular weight, dry cationic polymer. This product is designed to enhance liquid/ solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: White free flowing granular powder Bulk Density (lbs/ft3): 53 pH (0.5% solution): 5.0 Viscosity (0.25% solution): 320 cps Application: JAYFLOC 3463 has demonstrated particular effectiveness in industrial, mining and municipal thickening and clarification processes. JAYFLOC 3463 has also exhibited applicability for wastewater treatment and sludge dewatering operations. JAYFLOC 3468 Cationic Flocculant: JAYFLOC 3468 is a very high charge, high molecular weight, dry cationic polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: White free flowing granular powder Bulk Density (lbs/ft3): 53 pH (0.5% solution): 5.0 Viscosity (0.25% solution): 260 cps Application: JAYFLOC 3468 has demonstrated particular effectiveness in industrial, mining and municipal thickening and clarification processes. JAYFLOC 3468 has also exhibited applicability for wastewater treatment and sludge dewatering operations.

85

86

Water-Soluble Resins

CALLAWAY CHEMICAL CO.: Acrylamide Anionic PAM/NAAA Type:

Polymers: Nonionic and

Product Properties: High molecular weight emulsions and powders Many charge density compositions available Fluid products, improve handling and make-down EPA potable approved Principle Application Areas: Coagulant aid surface water clarification Wastewater treatment primary clarification Wastewater treatment coagulant aid - dissolved air flotation Coal preparation plants - refuse thickener Hard rock mineral processing - tailings, thickener Cu. Pb, Zn, U, Au, Ag, Potash Paper Industry - Green and white liquor clarification JAYFLOC 800 Nonionic Flocculant: JAYFLOC 800 is a high molecular weight, nonionic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Milky white water in oil emulsion Density @ 80F: 8.5+-0.1 pounds per gallon Freezing Point: OF pH (1% solution): 6.0+-1.0 Viscosity @ 80F: 300-600 cps Application: JAYFLOC 800 has demonstrated particular effectiveness in industrial, mining and municipal thickening and clarification processes. JAYFLOC 800 has also exhibited applicability for wastewater treatment and sludge dewatering operations. JAYFLOC 802 Anionic Flocculant: JAYFLOC 802 is a high molecular weight, low charge density anionic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Milky white water in oil emulsion Density @ 80F: 8.5+-0.1 pounds per gallon Freezing Point: 25F pH (1% solution): 6.0+-1-O Viscosity @ 80F: 500-800 cps Application: JAYFLOC 802 has demonstrated particular effectiveness in industrial, mining and municipal thickening and clarification processes. JAYFLOC 802 has also exhibited applicability for wastewater treatment and sludge dewatering operations.

Callaway Chemical Co.

CALLAWAY CHEMICAL CO.: Acrylamide PAM/NAAA Type(Continued):

87

Polymers: Nonionic and Anionic

JAYFLOC 803 Anionic Flocculant: JAYFLOC 803 is a high molecular weight, low charge density anionic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Milky white water in oil emulsion Density @ 80F: 8.5+-0.1 pounds per gallon Freezing Point: 25F pH (1% solution): 6.0+-1.0 Viscosity @ 80F: 500-800 cps Application: JAYFLOC 803 has demonstrated particular effectiveness in industrial, mining and municipal thickening and clarification processes. JAYFLOC 803 has also exhibited applicability for wastewater treatment and sludge dewatering operations. JAYFLOC 804 Potable Anionic Flocculant: JAYFLOC 804 is a high molecular weight, anionic emulsion polymer. This product is designed to enhance liquid/solid separations, primarily as a coagulant aid for raw water clarification. This product is approved by the Environmental Protection Agency (EPA). Typical Physical Properties: Appearance: Opaque water in oil emulsion Density @ 80F: 8.5+-0.1 pounds per gallon Freezing Point: OF pH (1% solution): 6.0+-1-O Viscosity @ 80F: 300-600 cps Application: JAYFLOC 804 has demonstrated particular effectiveness in industrial, municipal and mining raw water clarification processes as a coagulant aid where potable water is treated. EPA has approved JAYFLOC 804 for such applications at a maximum recommended concentration of 4 ppm (mg/l). JAYFLOC 804 is also recommended for mechanical sludge dewatering, gravity setting or thickening particlarly those involving inorganic sludges, i.e., aluminum, lime phosphates and hydroxides encountered in heavy metal precipitation.

88

Water-Soluble Resins

CALLAWAY CHEMICAL CO.: Acrylamide Polymers: Nonionic and Anionic PAM/NAAA Type(Continued): JAYFLOC 805 Anionic Flocculant: JAYFLOC 805 is a high molecular weight, medium charge density anionic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Milky white water in oil emulsion Density @ 80F: 8.5+-0.1 pounds per gallon Freezing Point: 25F pH (1% solution): 6.0+-1.0 Viscosity @ 80F: 500-800 cps Application: JAYFLOC 805 has demonstrated particular effectiveness in industrial, mining and municipal thickening and clarification processes. JAYFLOC 805 has also exhibited applicability for wastewater treatment and sludge dewatering operations.

JAYFLOC 806 Anionic Flocculant: JAYFLOC 806 is a high molecular weight, medium charge density anionic emulsion polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: Milky white water in oil emulsion Density @ 80F: 8.5+-0.1 pounds per gallon Freezing Point: OF pH (1% solution): 6.0+-1.0 Viscosity @ 80F: 300-600 cps Application: JAYFLOC 806 has demonstrated particular effectiveness in industrial, mining and municipal thickening and clarification processes. JAYFLOC 806 has also exhibited applicability for wastewater treatment and sludge dewatering applications.

Callaway Chemical Co.

89

CALLAWAY CHEMICAL CO.: Acrylamide Polymers: Nonionic and Anionic PAM/NAAA Type(Continued): JAYFLOC 3452 Anionic Flocculant: JAYFLOC 3452 is a high molecular weight, dry anionic polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. Typical Physical Properties: Appearance: White free flowing granular powder Bulk Density (lbs/ft3): 50 pH (0.5% solution): 7.0 Viscosity (0.25% solution): 800 Application: JAYFLOC 3452 has demonstrated particular industrial, mining and municipal thickening processes.- JAYFLOC 3452 has also exhibited wastewater treatment and sludge dewatering

effectiveness in and clarification applicability for operations.

JAYFLOC 3459 Nonionic Flocculant: JAYFLOC 3459 is a high molecular weight, dry nonionic polymer. This product is designed to enhance liquid/solid separation in a wide variety of industrial applications. JAYFLOC 3459 is approved by the U.S. Environmental Protection Agency for use in potable applications at feed rates up to lppm. Typical Physical Properties: Appearance: White free flowing granular powder Bulk Density (lbs/ft3): 47 pH (0.5% solution): 7.0 Viscosity (0.25% solution): 25 Application: JAYFLOC 3459 has demonstrated particular effectiveness in industrial, mining and municipal thickening and clarification processes. JAYFLOC 3459 has also exhibited applicability for wastewater treatment and sludge dewatering operations.

90

Water-Soluble Resins

CALLAWAY CHEMICAL CO.: PolyamineS: amide (Mannich or AMPAM) Type:

Aminomethylated

Polyacryl-

Product Properties: High molecular weight (2 - 6X10 6) as true solutions pH sensitive Very difficult to handle (viscous) Strong amine odor Primary Application Areas: Wastewater clarification Biological solids clarification Sludge dewatering Paper retention aid Paper drainage aid JAYFLOC 852 Liquid Cationic Polyelectrolyte: JAYFLOC 852 is an organic cationic liquid with a very high molecular weight and a high charge density. This product is highly effective for sludge dewatering, secondary clarification and the treatment of oily wastewater. Typical Physical Properties: Appearance: Colorless, viscous liquid Densitv 8 77F: 8.kO.l oounds ner sallon Freezing-Point: 30F _ pH (as supplied): 1Oil Viscosity @ 77F: 3,000-6,000 cps Application: JAYFLOC 852 has demonstrated particular effectiveness in industrial and municipal sludge dewatering and secondary clarification applications. The advantages of using JAYFLOC 852 include: 1) Improves centrifugation, belt filter press and vacuum filter operations, 2) Forms a low volume, compact sludge for easy disposal, 31 Imnroves settlins and flotation rates and 4j Performs well over the normal pH range of 3-7.5. The most effective JAYFLOC product should be selected based on performance testing using actual system water or sludge.

Calla wa y Chemical Co.

CALLAWAY CHEMICAL CO.: Polyamines: Aminomethylated amide (Mannich or AMPAM) Type(Continued):

Polyacryl-

JAYFLOC 854 Liquid Cationic Polyelectrolyte: JAYFLOC 854 is an organic cationic liquid with a very high molecular weight and a high charge density. This product is highly effective for sludge dewatering, secondary clarification and the treatment of oily wastewater. Typical Physical Properties: Appearance: Colorless, viscous liquid Density @ 77F: 8.45kO.l pounds per gallon Freezing Point: 28F pH (as supplied): 10-11.5 Viscosity @ 77F: lS,OOO-25,000 cps Application: JAYFLOC 854 has demonstrated Darticular effectiveness in industrial and municipal sludge dewatering and secondary clarification applications. The advantages of using JAYFLOC 854 include: _1) Improves centrifugation, belt filter press and vacuum filter operations, 2) Forms a low volume, compact sludge for easy disposal, 3) Improves settling and flotation rates and 4) Performs well over the normal pH range of 3-7.5. The most effective JAYFLOC product should be selected based on performance testing using actual system water or sludge.

91

92

Water-Soluble

Resins

CALLAWAY CHEMICAL CO.: Polyamines: Chloride (DWDAAC) Type:

Dimethyl Diallyl Ammonium

Product Properties: Molecular weight from 1OOK to 500K Products total quaternized, therefore, not pH dependent EPA potable approved

chlorine resistant and

Primary Application Areas: Surface water clarification as primary coagulant or coagulant aid Particularly useful in cold lime softening Coal refuse clarification aid Wastewater clarification Biological solids clarification JAYFLOC 842 Liquid Cationic Polyelectrolyte: JAYFLOC 842 is a liquid organic cationic coagulant with a medium molecular weight and a high charge density. This product is designed to improve liquid/solid separation primarily in clarification operations. However, performance in a wide variety of industrial applications has been observed. JAYFLOC 842 is approved by the U.S. Environmental Protection Agency for use in potable applications at feedrates up to 50 ppm. Typical Physical Properties: Appearance: Clear to pale yellow liquid Density @ 80F: 8.6+-O-l pounds per gallon Freeze Point: 27F pH (as supplied): 3.5+-0.2 Viscosity @ 80F: 50-200 cps Application: JAYFLOC 842 has demonstrated particular effectiveness in industrial, mining and municipal operations. The advantages established with the use of JAYFLOC 842 in various raw water and wastewater clarification operations were as follows: 1) Eliminates iron or aluminum carryover, thereby reducing potential fouling problems, 2) Resists residual chlorine or svstem DH. 3) Improves settling, 4) Reduces sludge volume with improved handling characteristics, and _ 5) Stores and handles conveniently. The most effective JAYFLOC product should be selected based on performance testing using actual water or wastewater to be clarified.

Callawa y Chemical Co.

CALLAWAY CHEMICAL CO.: Polyamines: Dimethyl Diallyl Ammonium Chloride (DMDAAC) Type(Continued): JAYFLOC 844 Liquid Cationic Polyelectrolyte: JAYFLOC 844 is a liquid organic coagulant with a medium molecular weight and a high charge density. This product is designed to improve liquid/solid separation primarily in clarification operations. However, performance in a wide variety of industrial applications has been observed. JAYFLOC 844 is approved by the U.S. Environmental Protection Agency for use in potable applications at feedrates of up to 80 ppm. Typical Physical Properties: Appearance: Clear to pale yellow liquid Density @ 77F: 8.5+-0.1 pounds per gallon Freezing Point: 27F pH (as supplied): 3.5+-O-2 Viscosity @ 77F: Min. 15 cps Application: JAYFLOC 844 has demonstrated particular effectiveness in industrial and municipal operations. The advantages established with the use of JAYFLOC 844 in various raw water and wastewater clar ification operations were as follows: 1 ) Eliminates iron or aluminum carryover, thereby reducing potential fouling problems, 2 Resists residual chlorination or system pH differences, 3 Improves settling, 4 Reduces sludge volume with improved handling characteristics, and 5 ) Stores and handles conveniently.

93

94

Water-soluble

Resins

CALLAWAY CI-IEMICALCO.: Polyamines: Dimethyl Diallyl Ammonium Chloride (DMDAAC) Type(Continued): JAYFLOC 846 Liquid Cationic Polyelectrolyte: JAYFLOC 846 is a liquid organic cationic coagulant with a medium molecular weight and a high charge density. This product is designed to improve liquid/solid separation primarily in clarification operations. However, performance in a wide variety of industrial applications has been observed. JAYFLOC 846 is approved by the U.S. Environmental Protection Agency for use in potable applications at feedrates of up to 25 ppm. Typical Physical Properties: Appearance: Clear to pale yellow liquid Density @ 77F: 8.9+-0.1 pounds per gallon Freezing Point: 24F pH (as supplied): 3.5+-0.2 Viscosity @ 77F: l,OOO-3,000 cps Application: JAYFLOC 846 has demonstrated particular effectiveness in industrial and municipal operations. The advantaqes established with the use of JAYFLCC 846 in various raw water-and wastewater clarification operations were as follows: 1) Eliminates iron or aluminum carryover, thereby reducing potential fouling problems, 2) Resists residual chlorination or system pH differences, 3) Improves settling, 4) Reduces sludge volume with improved handling characteristics, and 5) Stores and handles conveniently. The most effective JAYFLOC product should be selected based on performance testing using the actual system water or sludge.

Callaway Chemical Co.

CALLAWAY CHEMICAL CO.: Polyamines:

Epichlorohydrin

95

Type (EPI):

Product Properties: Molecular weights available from 5K to 500K Products totally quaternized - not pH or chlorine sensitive Very easy to handle or dilute EPA potable approval Primary Application Areas: Replacement/partial replacement for alum in surface water clarification Primary wastewater clarification aid Oily wastewater coagulant (automotive industry) Latex wastewater coagulant Biological solids clarification sludge dewatering Emulsion breaking - reverse oilfields breakers JAYFLOC 832 Liquid Cationic Polyelectrolyte: JAYFLOC 832 is a liquid organic cationic coagulant with a low molecular weight and a very high charge density. This product is designed to improve liquid/solid separation primarily in influent clarification operations; however, performance in a wide variety of industrial applications has been observed. JAYFLOC 832 is approved by the U.S. Environmental Protection Agency for use in potable applications at feedrates up to 20 ppm. Typical Physical Properties: -_ Appearance: Light-amber liquid Density @ 77F: 9.4+-0.1 pounds per gallon Freezing Point: 15F pH (as supplied): 6+-l Viscosity @ 77F: 80 to 125 cps Application: JAYFLOC 832 has demonstrated particular effectiveness in industrial and municipal clarification operations. The advantages of using JAYFLOC 832 in various influent and wastewater clarification operations include: 1) Eliminates iron or aluminum carryover, thereby reducing potential fouling problems, 2) Resists chlorination, 3) Performs well over a wide pH range, 4) Improves settling, 5) Reduces sludge volume with improved handling characteristics, and 6) Stores and handles conveniently. The most effective JAYFLOC product should be selected based on performance testing using the actual water to be clarified.

96

Water-Soluble

Rains

CALLAWAY CWEMICAL (Continued):

co. : Polyamines: Epichlorohydrin Type (EPI)

JAYFLO 835 Liquid Cationic Polyelectrolyte: JAYFLOC 835 is a liquid organic cationic coagulant with a moderate molecular weight and a very high charge density. This product is effective as a sludge dewatering aid and for influent and wastewater clarification and oil demulsification. JAYFLOC 835 is approved by the U.S. Environmental Protection Agency for use in potable applications at feedrates up to 20 ppm. Typical Physical Properties: Appearance: Clear, light yellow to amber liquid Density @ 77F: 9.4+-0.1 pounds per gallon Freezing Point: 15F pH (as supplied): 6+-l Viscosity @ 77F: 600 to 900 cps Application: JAYFLOC 835 has demonstrated particular effectiveness in industrial and municipal clarification and sludge dewatering operations. The advantages of using JAYFLOC 835 include: 1) Eliminates iron or aluminum carryover, thereby reducing potential fouling problems, 2) Resists chlorination, 3) Performs well over a wide PH ranse, 4) Improves settling or flotation rates, 5) Reduces sludge volume with improved handling characteristics, 6) Improves centrifugation, belt filter press and vacuum filter applications, and 7) Stores and handles conveniently. The most effective JAYFLOC product should be selected based on performance testing using actual system water or sludge. JAYFLOC 838 Liquid Cationic Polyelectrolyte: JAYFLOC 838 is a liquid organic cationic coagulant with a high molecular weight and a very high charge density. This product is effective as a sludge dewatering aid and for influent and wastewater clarification and oil demulsification. Typical Physical Properties: Appearance: Clear, light yellow or amber liquid Density @ 80F: 9.1+-0.1 pounds per gallon Freezing Point: 15F pH (as supplied): 4-6 Viscosity @ 80F: 500-1000 cps

Callaway Chemical Co.

CALLAWAY CHEMICAL CO.: PolyamineS: (continued): JAYFLOC 838

Epichlorohydrin

97

Type (EPI)

Liquid Cationic Polyelectrolyte(Continued):

Application: JAYFLOC 838 has demonstrated particular effectiveness in industrial and municipal clarification and sludge dewatering operations. The advantages of using JAYFLOC 838 include: 1) Eliminates iron 0; aluminum carryover, thereby reducing potential fouling problems, 2) Resists chlorination, 3) Performs well over a wide pH range, 4) Improves settling or flotation rates, 5) Reduces sludge volume with improved handling characteristics, 6) Improves centrifugation, belt filter press and vacuum filter applications, and 7) Stores and handles conveniently. The most effective JAYFLOC product should be selected based on performance testing using the actual system water or sludge. JAYFLOC 839 Liquid Cationic Polyelectrolyte: JAYFLOC 839 is a liquid organic cationic coagulant with a high molecular weight and a very high charge density. This product is effective as a sludge dewatering aid and for influent and wastewater clarification and oil demulsification. JAYFLOC 839 is approved by the U.S. Environmental Protection Agency for use in potable applications at feedrates up to 20 ppm. Typical Physical Properties: Appearance: Clear, light yellow or amber liquid Density @ 80F: 9.4kO.l pounds per gallon Freezing Point: 15F pH (as supplied): 4-6 Viscosity @ 80F: 4500-6500 cps Application: JAYFLOC 839 has demonstreted particular effectiveness in industrial and municipal clarification and sludge dewatering operations. The advantages of using JAYFLOC 839 include: 1) Eliminates iron or aluminum carryover, thereby reducing potential fouling problems, 2) Resists chlorination, 3) Performs well over a wide pH range, 4) Improves settling or flotation rates, 5) Reduces sludge volume with improved handling characteristics, 6) Improves centrifugation, belt filter press and vacuum filter applications, and 7) Stores and handles conveniently. The most effective JAYFLOC product should be selected based on performance testing using the actual system water or sludge.

98

Water-Soluble Resins

CALLAWAY CHEMICAL Products (MF):

co.:

Polyamines:

Melamine-Formaldehyde

Product Properties: Very low molecular weight (MW
(Alum, iron salts)

Principle Application Areas: Replacement for alum in surface water or wastewater ication DAF primary oily wastewater clarification Wastewater flotation aid

clarif-

JAYFLOC 820 Liquid Cationic Polyelectrolyte: JAYFLOC 820 is a liquid organic cationic coagulant which has shown to be an effective replacement for conventional metal salts such as aluminum, ferric sulfate or ferric chloride in clarification of water and wastewater. Typical Physical Properties: Appearance: Light blue liquid Density: 8.7+-O-l pounds per gallon Freezing Point: 32F pH (as supplied): 2+-0.3 Viscosity: Not viscous Application: JAYFLOC 820 has demonstrated particular effectiveness in industrial clarification processes. The advantages established with the use of JAYFLOC 820 were as follows: 1) Eliminates iron or aluminum carryover, thereby reducing potential fouling problems, 2) Performs well over a wide range of pH, 3) Contains no metal salts, 4) Reduces sludge volume with improved handling characteristics, and 5) Stores and handles conveniently. The most effective JAYFLOC product should be selected based on performance testing using actual water or wastewater to be clarified.

Callawav Chemical Co.

CALLAWAY CHEMICAL CO.: Polyamines: Products (MF) (Continued):

99

Melamine-Formaldehyde

JAYFLOC 824 Liquid Cationic Polyelectrolyte: JAYFLOC 824 is a liquid organic cationic coagulant which has shown to be an effective replacement for conventional metal salts such as aluminum sulfate, ferrous sulfate, and ferric sulfate in clarification of raw water and wastewater. Typical Physical Properties: Appearance: Light blue liquid Density: 8.7+-0.1 pounds per gallon Freezing Point: 32F pH (as supplied): 2+-0.3 Viscosity: Not viscous Application: JAYFLOC 824 has demonstrated particular effectiveness in industrial raw water and wastewater clarification processes. The advantages established with the use of JAYFLOC 824 were as follows: 1) Contains no metal salts, thus eliminating potential fouling due to iron or aluminum carryover, 2) Applies easily and performs well over a broad range of system pH, 3) Reduces sludge volume with improved handling characteristics, 4) Eliminates post-precipitation of aluminum or iron and extends demineralizer runs, and 5) Stores and handles conveniently. The most effective JAYFLOC product should be selected based on performance testing using actual water or wastewater to be treated.

100

Water-Soluble Resins

CARGILL, INC.: Water Reducible Resins: Epoxy Ester: 73 7321: % N.V. by Wt.: 70 % N.V. by Vol.: 66.4 Solvent: EGMBE Viscosity: 26-26 l/2 Max. Color: 7 Acid No. (Solids Basis): 57-63 W.P.G.: 8.5 Type: Oxidizing Fatty Acid Good adhesion to oily and contaminated metal. Good chemical and corrosion resistance. Adhesion to various plastics. Alkyds--Oxidizing: 73 7304: % N.V. by Wt.: 70 % N.V. by Vol.: 65.8 Solvent: Proprietary blend Viscosity: 24-25 Max. Color: 8 Acid No. (Solids Basis): 55-63 W.P.G.: 8.7 Type: TOFA 73 7304 is a water reducible oil modified polyurethane, recommended for general purpose urethane varnishes having excellent dry and wear characteristics. 73 7352: % N.V. by Wt.: 77-83 Solvent: EGMBE Viscosity: 22-25 Max. Color: 14 Acid No. (Solids Basis): 68-78 W.P.G.: 8.3 Type: Linseed 73 7352 is a water reducible exterior vahicle designed for air-dry wood coatings, stains and light duty concrete compounds. 74 7416: % N-V. by Wt.: 80 % N.V. by Vol.: 76.2 Solvent: PTB Solvent Viscosity: 24-26 Max. Color: 8 Acid No. (Solids Basis): 53-58 W.P.G.: 8.5 Type: Oxidizing Fatty Acid 74 7416 is a water reducible long oil alkyd. Enamels formulated with this resin offer excellent gloss and appearance. Designed for deck stains and enamel coatings.

Cargill, Inc.

CARGILL, INC.: Water Reducible Resins(Continued): Alkyds--Oxidising(Continued): 74 7418: % N.V. bv Wt.: SO % N.V. by Vol.: 76.5 Solvent: PGMPE Viscositv: 25-26 Color: 10 Max. Acid No. (Solids Basis): 35-42 W.P.G.: 8.65 Type: Oxidizing Fatty Acid 74 7418 is a medium oil water reducible alkyd, which can be air dried, force cured or baked, recommended for corrosion resistant primers and high gloss top coats. 74 7426: % N.V. by Wt.: 75 % N.V. by Vol.: 69.1 Solvent: PGMPE/S-BuOH 30170 Viscosity: 25 l/2 - Z 6 l/2 Max. Color: 7 Acid No. (Solids Basis): 40 W.P.G.: a.70 Type: Oxidizing Fatty Acid 74 7426 is a short oil water reducible air dry alkyd, designed for formulating quick drying economical enamels which require strontium chromate stability. 74 7427: % N.V. by Wt.: 75 % N.V. by Vol.: 69.5 Solvent: Ektasolve EP/S-BuOH 30170 Viscosity: Z 5 1/2 - Z 6 l/2 Max. Color: 8 Acid No. (Solids Basis): 40-46 w.P.G.: a.85 Type: Oxidizing Fatty Acid 74 7426 type in Ektasolve EP and Secondary Butanol. 74 7429: % N.V. by Wt.: 75 % N.V. bv Vol.: 70.4 Solvent:-EGMBE Viscosity: 26 - 26 l/2 Max. Color: a Acid No. (Solids Basis): 40-46 w.P.G.: a.85 Type: Oxidizing Fatty Acid 74 7429 is designed for use in fast drying economical enamels.

10 1

102

Water-Soluble Resins

CARGILL, INC.: Water Reducible Resins(Continued): Alkyds--Oxidizing(Continued): 74

7434: % N.V.

by Wt.: 75 % N.V. by Vol.: 69.5 Solvent: EGMBE/n-BuOH 35165 Viscosity: 24-25 Max. Color: 10 Acid No. (Solids Basis): 37-44 W.P.G.: 8.60 Type: TOFA 74 7434 is a short to medium oil water reducible alkyd, designed for use in air or force dried industrial coatings which require high gloss. 74 7450: % N.V. by Wt.: 72 % N.V. by Vol.: 64.5 Solvent: n-BuOH Viscosity: 23-25 Max. Color: 7 Acid No. (Solids Basis): 47-53 W.P.G.: 8.45 Type: Soya 74 7450 is a short oil water reducible alkyd, which can be air dried, force cured or cross-linked with methylated melamine. Available in secondary butanol as 74 7469. 74 7451: % N.V. by Wt.: 70 % N.V. by Vol.: 66.8 Solvent: EGMBE Viscosity: 24-26 Max. Color: 8 Acid No. (Solids Basis): 47-54 W.P.G.: 8.80 Type: TOFA 74 7451 is the fatty acid version of 74 7450. The solvent has been changed offering better flow and gloss. 74 7451 offers enhanced stability compared to 74 7450. Excellent film properties can be obtained with methylated melamines at temperatures as low as 275F.

Cargiil, inc.

CARGILL, INC.: Water Reducible Resins(Continued): Alkyds--Oxidixing(Continued): 74 7452: % N.V. by Wt.: 75 % N.V. by Vol.: 70.0 Solvent: EGMBE Viscosity: 23 1/2 - 25 l/2 Max. Color: 10 Acid No. (Solids Basis): 36-44 W.P.G.: 8.95 Type: TOFA 74 7452 is an economical medium oil water reducible resin designed for industrial bake coatings. Designed to be crosslinked with methylated melemines. 74

7469:

% N.V. by Wt.: 70 % N.V. by Vol.: 61.9 Solvent: S-BuOH Viscosity: 24-26 Max. Color: 7 Acid No. (Solids Basis): 47-53 W.P.G.: 8.5 Type: Soya Secondary butanol version of 74 7450. 74

7472: % N.V. by Wt.: 75

% N.V. by Vol.: 69.4 Solvent: EGMBE/S-BuOH 50/50 Viscosity: 26-26 l/2 Max. Color: 7 Acid No. (Solids Basis): 40-44 W.P.G.: 8.64 Type: Oxidizing Fatty Acid 74 7472 is a short oil water reducible alkyd designed for air dry or force dried industrial coatings, offering fast dry rates with good humidity and early water-resistance; 74 7476: % N.V. by Wt.: 75 % N.V. by Vol.: 69.0 Solvent: EGMBE/S-BuOH 50/50 Viscosity: 26-26 l/2 Max. Color: 8 Acid No. (Solids Basis): 39-44 W.P.G.: 8.6 Type: Oxidizing Fatty Acid 74 7476 is a short oil water reducible alkyd designed for air dry or force dried industrial coatings offering very fast dry rates and film hardness as well as humidity resistance.

103

104

Water-Soluble Resins

CARGILL, INC.: Water Reducible Resins(Continued): Alkyds--Oxidizing 74

Chain-Stopped:

7445: % N.V. by Wt.: 75 % N.V. by Vol.: 69.5

Solvent: EGMBE/i-BuOH 75/25 Viscositv: 25-26 Max. Color: 10 Acid No. (Solids Basis): 39-41 W.P.G.: 8.85 Type: Oxidizing Fatty Acid 74 7445 offers excellent gloss and gloss retention, as well as humidity and early moisture resistance. 74 7448:

% N.V. by Wt.: 75 % N.V. by Vol.: 69.5

Solvent: EGMBE/s-BuOH so/50

Viscosity: 24-26 Max. Color: 10 Acid No. (Solids Basis): 40-45 W.P.G.: 8.65 Type: Oxidizing Fatty Acid 74 7448 is a short oil chain-stopped water reducible alkyd for air dry or force cure applications. Coatings based on 74 7448 exhibit fast dry rates and outstanding gloss. 74

7456: % N.V. by Wt.: 75 % N.V. bv Vol.: 69.6

Solvent:- n-BuOH/EGMBE so/so Viscositv: 24-26 Max. Color: 10 Acid No. (Solids Basis): 37-43 W.P.G.: 8.54 Type: Oxidizing Fatty Acid 74 7456 is a water alternative to solvent air dry systems. Coatings based on 74 7456 offer excellent humidity resistance and gloss retention as well as good dry rates and adhesion properties.

Cargill, inc.

CARGILL, INC.: Water Reducible Resins(Continued): Alkyds --Oxidizing Chain-Stopped(Continued): 74 7458: % N.V. by Wt.: 75 % N.V. by Vol.: 69.5 Solvent: EGMBE/s-BuOH 50/50 Viscosity: 25-26+ Max. Color: 10 Acid No. (Solids Basis): 40-45 W.P.G.: 8.65 Type: Oxidizing Fatty Acid 74 7458 is an economical chain-stopped alkyd, designed for air dry, force dry and baking industrial coatings. 74 7459: % N.V. by Wt.: 75 % N.V. by Vol.: 69.6 Solvent:-EGMBE/n-BuOH 50/50 Viscosity: 24-26 Max. Color: 10 Acid No. (Solids Basis): 40-45 W.P.G.: 8.65 Type: Oxidizing Fatty Acid 74 7459 is an economical chain-stopped alkyd that can be formulated to exhibit excellent salt fog and early water resistance. Designed for air dry, force dry and baking industrial coatings. 74 7464: % N.V. by Wt.: 75 % N.V. By Vol.: 69.5 Solvent: EGMBEls-BuOH so/50 Viscosity: 25-26 Max. Color: 10 Acid No. (Solids Basis): 40-45 W.P.G.: 8.65 Type: Oxidizing Fatty Acid 74 7464 exhibits fast dry rates and early water resistance also detergent resistance. -

105

106 Water-Soluble Resins

CARGILL, INC.: Water Reducible Resins(Continued): Alkyds--Oxidizing 74

Chain-Stopped(Continued):

7466: % N.V.

by Wt.: 75 % N.V. by Vol.: 70.9 Solvent: EGMBE Viscosity: 24-26 Max. Color: 10 Acid No. (Solids Basis): 37-43 W.P.G.: 0.75 Type: Oxidizing Fatty Acid 74 7466 is designed to be used in formulations which require compatability with chromate pigments. 74 7470: % N.V. by Wt.: 75 % N.V. by Vol.: 69.0 Solvent: EGMBE/s-BuOH 50150 Viscosity: Z5-Z6+ Max. Color: 8 Acid No. (Solids Basis): 36-41 W.P.G.: 8.72 Type: Oxidizing Fatty Acid 74 7470 is designed for air or force-dry systems. Coatings formulated with 74 7470 offer exceptional early water resistance. 74 7474: % N.V. by Wt.: 75.0 % N.V. by Vol.: 69.0 Solvent: EGMBE/s-BuOH 50150 Viscosity: 26-26 l/2 Max. Color: 0 Acid No. (Solids Basis): 37-43 W.P.G.: 8.80 Type: Oxidizing Fatty Acid 74 7474 is designed for air dry or force dry industrial coatings. Coatings formulated with 74 7474 exhibit excellent gloss and corrosion resistance along with fast dry rates.

Cargiil, inc.

CARGILL, INC.: Water Reducible Resins(Continued): Alkyds--Non-Oxidizing: 74 7455: % N.V. by Wt.: 70.0 % N.V. by Vol.: 64.0 Solvent: EGMBE Viscosity: 24 l/2 - 26 Max. Color: 4 Acid No. (Solids Basis): 40-45 W.P.G.: 9.0 Type: non-drying Offers excellent resistance to yellowing on over bake. 74 7412: % N.V. by Wt.: 98 min % N.V. by Vol.: 99 min Viscosity: X-21 Max. Color: 3 Acid No. (Solids Basis): 2 W.P.G.: 9;45 Thermosetting resin for force dry and low temp. bake catalyzed coatings. For use on forest products. Silicone Modified: 74 7435: % N.V. by Wt.: 75 % N.V. by Vol.: 70 Solvent: EGMBE Viscosity: 24-26 Max. Color: 6 Acid No. (Solids Basis): 43-48 W.P.G.: 9.02 Type: Oxidizing Fatty Acid High quality enamels based on 74 7435 offer excellent gloss, early water resistance, fast dry and high application solids.

107

108

Water-Soluble Resins

CARGILL, INC.: Water Reducible Resins(Continued): Vinyl Modified: 74 7432: % N.V. by Wt.: 70 % N.V. by Vol.: 64.5 Solvent: PGMPE/s-BuOH 67/33 Viscosity: Z 5 112 - Z 6 l/2 Max. Color: 4 Acid No. (Solids Basis ): 45-49 W.P.G.: 8.0 Type: Acrylic Alkyd Air dry acrylic alkyd, enamels exhibit quick film hardness, very fast dry rates offer ing excellent adhesion to various plastic substrates. 74 7460: % N.V. by Wt.: 70 % N.V. by Vol.: 66 Solvent:- s-BuOH/PTB 52148 Viscosity: 22-25 Max. Color: 7 Acid No. (Solids Basis): 40-46 W.P.G.: 8.0 Type: Acrylic Alkyd 74 7462: % N.V. by Wt.: 70 % N.V. by Vol.: 66 Solvent: s-BuOH/EGMBE 52/48 Viscosity: 22-25 Max. Color: 7 Acid No. (Solids Basis): 40-46 W.P.G.: 8.0 Type: Acrylic Alkyd 74 7460 and 74 7462 are designed for very fast dry coatings with very early water resistance and early film hardness. Salt spray, humidity resistance and resistance to yellowing are similar to high quality solvent based vinyl-toluenated oil copolymers.

Cargill, Inc.

CARGILL,

INC.:

Water Reducible Resins(Continued):

Phenolic Modified: 74 7478: % N.V. by Wt.: 75 % N.V. by Vol.: 70.2 Solvent:- EGMBE/s-BuOH so/50 Viscositv: 26 - 26 l/2 Max. Color: 8 Acid No. (Solids Basis): 39-44 W.P.G.: 8.65 Type: Oxidizing Fatty Acid Phenolic modified alkyd for corrosion resistant, lifting resistant primers. Recommended for black air dry and red iron oxide primers. 74 7488: % N.V. by Wt.: 75 % N.V. by Vol.: 70.2 Solvent:- EEP/s-BuOH so/50 Viscosity: 26 - 26 l/2 Max. Color: 8 Acid No. (Solids Basis): 39-44 W.P.G.: 8.65 Type: Oxidizing Fatty Acid EEP version of 74 7478. Oil Free Polyesters: 72 7202: % N.V. by Wt.: 75 % N.V. by Vol.: 68 Solvent: EGMBE Viscosity: 24-26 Max. Color: 5 Acid No. (Solids Basis): SO-60 W.P.G.: 9:lO Water reducible polyester 72 7202 offers benefits of outstanding weatherability, excellent color and color retention, excellent hardness and impact resistance and freedom from llsolvent popping." Suggested uses include appliances, automotive parts, bicycles, general industrial bake coatings and applications requiring excellent exterior durability.

109

110

Water-Soluble Resins

CARGILL, INC.: Water Reducible Resins(Continued1: Oil Free Polyesters(Continued): 72 7203: % N.V. by Wt.: 75 % N.V. by Vol.: 68 Solvent: s-BuOH/EGMBE 75125 Viscosity: 23-25 Max. Color: 5 Acid No. (Solids Basis): 50-60 W.P.G.: 8.9 Good general industrial performance, good color retention and corrosion resistance. 72 7209: % N.V. by Wt.: 80 % N.V. bv Vol.: 75 Solvent:-EGMBE Viscosity: 21-23 Max. Color: 3 Acid No. (Solids Basis): 29-34 W.P.G.: 9.00 72 7209 is a low temperature curing resin designed for forest products and conversion varnish systems. 72 7222: % N.V. by Wt.: 75 % N.V. by Vol.: 69.6 Solvent: EGMBE Viscosity: 25-26 Max. Color: 2 Acid No. (Solids Basis): 48-56 W.P.G.: 9.1 72 7222 is designed for appliance, automotive and general industrial bake applications. 72 7289: % N.V. by Wt.: 75 % N.V. by Vol.: 68.6 Solvent: PGMPE Viscosity: Z5 l/2 - 26 l/2 Max. Color: 5 Acid No. (Solids Basis): 54-60 W.P.G.: 9.20 72 7289 can be formulated to yield industrial baking enamels offering excellent color retention on overbake, flexibility, corrosion and humidity resistance. For interior and exterior applications. Key

for Solvent Abbreviations: n-BuOH Normal butyl alcohol i-BuOH Isobutyl alcohol s-BuOH Secondary butyl aclcohol Ethylene glycol mono-butyl ether EGMBE EEP Ethyl 3-ethoxy propionate Tertiary butoxy propanol PTB PGMPE Propylene glycol mono-propyl ether

Cook Paint and Varnish Co.

111

COOK PAINT AND VARNISH CO.: COROC Alkyd Resins: Z-27-M Water Dispersible Alkyd Resin: COROC Z-27-M is a low cost, chain stopped, water dispersible alkyd supplied at 70% NV in a 50/50 blend of butanol and ethylene glycol monobutyl ether. It is a lower solids version of 2-1727-M. Z-27-M is recommended for industrial metal finishes with an air dry or force dry cure schedule. COROC resins Z-1726-M and Z-1727-Ml are recommended for those applications which require a faster dry than obtained with Z-27-M. Typical Physical Characteristics: Nonvolatile: 70+-l Solvent: n-butanol: 50% Ethylene Glycol Monobutyl Ether: 50% Viscosity: W-Y Acid Number: 35-40 Color: 0 Max. Weight/Gallon: 8.50+-0.1 Suggested Uses: Automotive under the hood (chassis, shocks, water pumps, etc.) Implements and hardware General industrial finishes Advantages: LOW voc Good corrosion and humidity resistance Excellent application properties Good exterior durability XZ-128-MXA Water Dispersible Alkyd: COROC XZ-128-MXA is an experimental water dispersible chain-stopped alkyd. It is supplied in a 50/50 blend of butoxyethanol and set-butanol at 70% nonvolatile. The material displays excellent humidity resistance and application properties. Typical Physical Characteristics: Nonvolatile: 70+-l Solvent: Butoxyethanol: 50 Set-Butanol: 50 Viscosity: 23-25 Reduced Viscosity (50% NV in Butoxyethanol): L-O Acid Number: 35+-2 Color: 8 Max. Weight/Gallon: 8.65 Properties: Excellent Package Stability--Good Corrosion and Humidoty Resistance--Excellent Application Properties-Good Tack-Free Times Suggested Uses: Automotive under the Hood Parts--Small Appliances Recreational Equipment--Implement and Hardware

112

Water-Soluble Resins

COOK PAINT AND VARNISH CO.: COROC B-453-V8 Water Reducible Styrenated Epoxy Resin: COROC Resin B-453-V8 is a stvrenated epoxy ester which may be used for both air dry and bake applications. When neutralized this resin can readily be reduced with water. B-453-V8 can be cured with water dispersible melamine or urea resins at elevated temperatures. B-453-V8 can also be air dried with metallic driers at room temperature. Superior humidity and corrosion resistance can be attained with B-453-V8 when used in either air dry or bake primers. This resin exhibits good cure response at 220 to 350F and air dry to tack free in pigmented films in about one hour. This resin also has good gloss, good adhesion, and good compatability with other water reducible resins. Physical Characteristics: Nonvolatile: 70+-l Solvent: Ethylene Glycol Monobutyl Ether: 100% Viscosity: Z5 - Z6+ Acid Number: 55-65 Color: 6 Max. Weight per Gallon: 8.48 Reduced Viscosity: at 50% Nonvolatile in Ethylene Glycol Monobutyl Ether: R-U PI:operties: Excellent Adhesion Excellent Humidity Resistance Excellent Corrosion and Salt Spray Resistance Good Hydrolytic Stability Very Good Gloss Excellent Early Water Resistance Good Compatability with other Resins Good Cure Response Suggested Uses: B-453-V8 is recommended to be used where fast dry and superior corrosion resistance are required. It should be considered as a primer vehicle for farm implements, automotive parts, outdoor furniture, and appliances. B-453-V8 gives excellent hardness, adhesion to the substrate, and intercoat adhesion. B-453-V8 is not recommended for exterior use where chalk resistance and gloss retention are critical. Drier Recommendations: Air Dry: 0.05% Cobalt 0.05% Manganese Bake: 0.005-0.05% Cobalt

Cook Paint and Varnish Co.

113

COOK PAINT AND VARNISH CO.: COROC B-1537-M Water Reducible Acrylic Modified Alkyd: COROC resin B-1537-M water reducible acrylic modified alkyd was designed for high quality, rapid dry coatings. When neutralized with a suitable amine, B-1537-M will give excellent film properties and may be used in air or force dry systems. This resin may also be blended with water reducible melamines to obtain full gloss enamels which are hard and chemical resistant. B-1537-M is supplied at 75% nonvolatile in ethylene glycol monobutyl ether and butanol. Physical Characteristics: Nonvolatile: 75+-l Solvent: ethylene glycol monobutyl ether: 50% butanol: 50% Viscosity: 26 Heavy Acid Number: 40-44 Color: 9 Max. - Slight Haze Weight/Gallon: 8.70 Properties: Excellent Spray Characteristics Good Humidity and Salt Spray Resistnace Excellent Mar Resistance Excellent Color and Gloss Retention Very Good Exterior Durability Rapid Dry Good Chemical Resistance Suggested Uses: B-1537-M is a very versatile resin which may be cured at elevated temperatures or air dry rapidly at room temperature. The acrylic portion of the resin is not "post added", but an integral part of the formulation which will yield a very hard and chemical resistant coating. B-1537-M should be considered for use in general industrial applications in such areas as: Small Appliances Garden Tools and Small Implement Enamels Engine Enamels Primers for Structural Steel Toy Enamels Computer Hardware Drier Recommendations: 0.2-0.4% Cobalt 0.2-0.4% Manganese O-l-0.5% Antiskin (if desired) Air dry charactersistics Dust Free (hours) Tack Free (hours)

of a pigmented system: l/4 314

114 Water-Soluble Resins

COOK PAINT AND VARNISH CO.: COROC R-1782-V8 Water Reducible Polyester: COROC resin R-1782-V8 is a high solids water soluble oil free polyester that is supplied at 81 nonvolatile in Ethylene Glycol Monobutyl Ether. Upon neutralization with a suitable amine and reduced with water, R-1782-V8 has good hydrolytic stability over a long period of time. Enamels based on R-1782-V8 should be considered for coil coatings and general industrial bake systems. R-1782-V8 will cross-link with water soluble melamines or ureas to form a hard thermoset film that exhibits excellent flexibility, gloss and color retention. Physical Characteristics: Nonvolatile: 81+-l Solvent: Ethylene Glycol Monobutyl Ether: 100% Viscosity: 25 - 26 Acid Number: 55-65 Color: 5 Max. Weisht/Gallon: 8.95 Viscosity at 70 Nonvolatile in Ethylene Glycol Monoethyl Ether Acetate#: P-Q # Cellosolve Acetate (Union Carbide) Properties: Excellent Color Retention Excellent Gloss Retention Excellent Exterior Durability Good Mar Resistance Good Humidity Resistance Suggested Uses: R-1782-V8 should be considered for the following applications in which color retention during the cure cycle and-exterior durability are important considerations. Coil Coatings Small Appliances Office Equipment Lawn Furniture Lighting Fixtures (exterior and interior) Metal Shelving Film Properties: R-1782-V8 is a hvdroxv functional resin that must be blended with water soluble amine-or urea resins to form a thermoset coating. Typical properties of films prepared with R-1782-V8, 25% Cymel 303 and-O-i% PTSA catalyst are-shown below: Bake: Time (Mins.): 2O/Temp (F): 325/Sward Hardness: 45 MEK Double Rubs: lOO+ Time (Mins.): ZO/Temp (F): 350/Sward Hardness: 58 MEK Double Rubs: lOO+

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115

COOK PAINT AND VARNISH CO.: COROC S-432-M Water Reducible Alkyd: COROC Resin ~-432-M is rapid dry, water reducible, soya alkyd. The resin is supplied at 71% nonvolatile in a 45:55 mixture of isobutyl alcohol and butyl cellosolve, respectively. In order to reduce S-432 in water, the resin must be first neutralized with an appropriate amine. S-432-M may be used in baking enamels by blending the resin with water soluble melamine or urea resins. S-432-M may also be force air dried at elevated temperatures using metallic driers. Enamels prepared with S-432-M have high gloss retention and very good durability. Some yellowing may occur at high bake temperatures. However, increasing the melamine level may improve this discoloration. Physical Characteristics: Nonvolatile: 71+-l% Solvent: ethylene glycol monobutyl ether: 55% isobutyl alcohol: 45% Viscosity: 25-26 hy Acid Number: 40-50 Color: 8 Max. - Clear to slightly hazy Weight/Gallon: 8.68 Properties: Excellent gloss Very good hardness and mar resistance Good flexibility Good humidity resistance Excellent durability Suggested Uses: Automotive under the hood parts Implement and hardware Small appliances Toy enamels Recreational equipment Film Characteristics: Air Dry: Typical film properties of a non-pigmented system. Dust Free (hours): 314 Tack Free ihoursj: 6 l/2 Sward Hardness 24 Hours: 10 Bake: .005% Cobalt: Time (Mins.): ZO/Temp (Fj: 180/ Sward Hardness: 8 20% Cymel 303: Time (Mins.): 30/Temp (F): 275/.Sward Hardness: 50

116

Water-Soluble

Resins

COOK PAINT AND VARNISH CO.: COROC T-1070-M Water Reducible Alkyd Resin: COROC Resin T-1070-M is a water reducible medium tall oil alkyd resin designed especially for use in industrial baking finishes. T-1070-M may be blended with water soluble melamine or urea-formaldehyde resins to obtain full gloss enamels. Enamels prepared from T-1070-M produce hard, tough, mar resistant finishes having good resistance to salt spray and humidity. Physical Properties: Nonvolatile: 75+-l Solvent: propylene glycol monomethyl ether: 50% butanol: 50% Viscosity: 22-24 Acid Number: 55-59 Color: 6 Max. Weight/Gallon: 8.55 Properties: Excellent spray characteristics Good humidity and salt spray resistance Excellent mar resistance Excellent color and gloss Very good exterior durability Suggested Uses: T-1070-M is recommended as a general purpose baking enamel for the following areas: Water heater covers Metal cabinets Heat registers Metal signs Film Characteristics: The film properties of T-1070-M with 20% Cymel 303 at various bake schedules are given below: Time Time Time Time Time

(Mins): (Mins): (Mins): (Mins): (Mins):

30/Temp. 30/Temp. 2O/Temp. ZO/Temp. lti/Temp.

(F.): (F.): (F.): (F.): (F.):

275/Sward 300/Sward 300/Sward 325/Sward 325/Sward

Hardness: 29 Hardness: 41 Hardness: 30 Hardness: 41 Hardness: 40

Cook Paint and Varnish Co.

COOK PAINT AND VARNISH CO.: COROC XL-1128-M Water Dispersible Alkyd(Formerly X2-128-MlX2): COROC XL-1128-M is a low cost version of XZ-128-MXA Experimental Water Dispersible Chain-Stopped Alkyd. It is supplied in a 50/50 blend of butoxyethanol and set-butanol at 70% nonvolatile. Like XZ-128-MXA, the material displays excellent humidity resistance and application properties. Typical Physical Characteristics: Nonvolatile: 70+-l Solvent: Butoxyethanol: 50 See-Butanol: 50 Viscosity: 23-25 Reduced Viscosity (50% NV in Butoxyethanol): Acid Number: 35+-2 Color: 8 Max. Weight/Gallon: 8.65

L-O

Properties: Excellent Package Stability Good Corrosion and Humidity Resistance Excellent Application Properties Good Tack-Free Times Low Cost Relative to Similar Systems Suggested Uses: Automotive under the Hood Parts Small Appliances Recreational Equipment Implement and Hardware Gloss White Water Reducible Air Dry Enamel: Film Properties: Application: Conventional Spray Film Thickness: 0.9 Mils Cure: 7 Days Air Dry Tack-Free: Approximately 2 Hours 60 Gloss: 89 20 Gloss: 79 Pencil Hardness: HB Crosshatch Adhesion: Excellent Impact Resistance: (Reverse): Less than 10 Inch - Lbs. Red Iron Oxide Water Reducible Primer: W3-144-87: Film Properties: Tested on Bonderite 1000 Cold Rolled Steel Substrate Application: Conventional Spray Film Thickness: 0.7 Mils Cure: 7 Days Air Dry Tack-Free: Approximately 45 Minutes 60 Gloss: 4 20 Gloss: 1

117

118

Water-Soluble Resins

COCK PAINT AND VARNISH CO.: COROC Z-1722-M Water Dispersible Chain Stopped Alkyd Resin: COROC Resin Z-1722-M is a water dispersible alkyd designed to give exceptional salt spray and humidity resistance coupled with outstanding exterior durability. Coatings formulated with Z-1722-M have excellent application properties at low VOC values with moderately fast drv. These finishes exhibit outstandinq adhesion and impact-resistance. Z-1722-M may be used in primers and topcoats for spray, dip or flowcoat application and may be air dried or baked. Physical Characteristics: Nonvolatile: 75+-l Volatile: 2-Butoxvethanol: 50% n-butanol: 50% Viscosity: 21-23 Acid Number: 38-42 Color: 8 Max Weight/Gallon: 0.57 Properties: Excellent humidity resistance Excellent salt spray resistance Very good exteror durability Excellent application properties LOW voc Good package stability Excellent impact resistance Excellent adhesion Suggested Uses: Automotive Implement and heavy equipment Plastics Appliances Metal furniture Drier Recommendations: 0.05% - 0.15% Cobalt 0.00% - 0.10% Manganese

(metal on solids) (metal on solids)

Water Reducible Red Oxide Primer: B8-49-86: Film Properties: Tested on Bonderite 1000 Cold Rolled Steel Substrate Application: Conventional Spray Film Thickness: 0.7 mils Cure: 7 days air dry Tack Free: Approximately 40 minutes 60 Gloss: 3/85 Gloss: 6 Pencil Hardness: HB Crosshatch Adhesion: Excellent-100% retention Impact Resistance (reverse): Excellent-160 inch-lbs.

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119

COCK PAINT AND VARNISH CO.: COROC Z-1726-M Water Dispersible Chain Stopped Alkyd: COROC Z-1726-M is a chain stopped water dispersible alkyd resin supplied at 75 nonvolatile in a 1:l mixture in 2-butoxyethanol and set-butanol. COROC Z-1726-M was designed for air-dry and low bake coatings. It may be used in high or low gloss enamels and primers for spray, dip or flow coat application. COROC 2-1726-M has outstanding corrosion and humidity resistance coupled with excellent exterior durability. Physical Characteristics: Nonvolatile: 75+-l Solvent: 2-Butoxyethanol: 50 Set-Butanol: 50 Viscosity: 21-23 Acid Number: 40+-2 Color: 8 Max Weight/Gallon: 8.56 Properties: Very good gloss Excellent flexiblity Very good humidity resistance Very good salt spray resistance Very good durability Good stability Suggested Uses: Automotive under the hood parts Small appliances Recreational equipment Implement and hardware Drier Recommendations: (% metal on resin solids) .05% Cobalt (% metal on resin solids) -10% Manganese Water Reducible Red Oxide Primer B8-49-86 Film Properties: Tested on Bonderite 1000 Cold Rolled Steel Substrate: Application: Conventional Spray Film Thickness: O-8-0.9 mils Cure: 7 days air dry 60 Gloss: 3 20 Gloss: 1 Pencil Hardness: HB-F Crosshatch Adhesion: Excellent-100% retention Impact Resistance(reverse): Excellent-Greater than 160 in-lbs.

120

Water-Soluble Resins

COCK PAINT AND VARNISH CO.: COROC Z-1726-Ml Water Dispersible Chain-Stopped Alkyd: COROC Z-1726-Ml is a chain-stopped water dispersible alkyd resin supplied at 75 nonvolatile in a 1:l mixture of Propasol P and set-butanol. COROC Z-1726-Ml was designed for air-dry and low-bake coatings. It may be used in high or low gloss enamels and primers for spray, dip or flow coat application. COROC Z-1726-Ml has outstanding corrosion and humidity resistance coupled with excellent exterior durability. Physical Characteristics: Nonvolatile: 75+-l Solvent: Propasol P: 50 Set-Butanol: 50 Viscositv: 22-24 Reduced Viscosity (50% N.V. in Propasol P): F-H Acid Number: 40+-2 Color: 8 Max Weight/Gallon: 8.58 Properties: Very good gloss Excellent flexibility Very good humidity resistance Very good salt spray resistance Very good durability Good stability Suggested Uses: Automotive under the hood parts Small appliances Recreational equipment Implement and hardware Drier Recommendations: .05% Cobalt .lO% Manganese

(% metal on resin solids) (% metal on resin solids)

Water Reducible Red Oxide Primer B8-49-86: Film Properties: Tested on Bonderite 1000 Cold Rolled Steel Substrate: Application: Conventional Spray Film Thickness: 0.8-0.9 mils Cure: 7 days air dry Tack Free: Less than 20 minutes 60 Gloss: 3 20 Gloss: 1 Pencil Hardness: HB-F Crosshatch Adhesion: Excellent-100% retention Impact Resistance (reverse): Excellent-Greater than 160 inch-lbs.

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121

COOK PAINT AND VARNISH co. : COROC 2-1727-M Water Dispersible Chain Stopped Alkyd Resin: COROC Z-1727-M is a low cost, chain stopped, water dispersible alkyd supplied at 75% NV in a SO/50 blend of butanol and butyl cellosolve. Z-1727-M is recommended for industrial metal finishes with an air dry or force dry cure schedule. For those applications requiring faster dry, COROC Z-1726-M and Z-1727-Ml are recommended. Typical Physical Characteristics: Nonvolatile: 75+-l Solvent: n-butanol: 50% Butyl Cellosolve: 50% Viscosity: 21 - 23 Acid Number: 35-40 Color: 8 Max. Weight/Gallon: 8.56+-0.1 Suggested Uses: Automotive under the hood parts Appliances Lawn furniture Hardware Advantages: Low voc Good salt spray and humidity resistance Excellent application properties-spray, dip or flow coat Good impact resistance Good exterior durability Drier Recommendations: 0.05-0.15% Cobalt 0.10% Manganese 2.0% CK-10

(% metal on resin solids) (% metal on resin solids) (% on resin solids)

Black Water Reducible Chassis Enamel: Film Properties: Tested on Bonderite 1000 Cold Rolled Steel Substrate: Application: Conventional Spray Film Thickness: 1.0-1.1 Mils Cure: 7 Days Air Dry 60 Gloss: 46 20 Gloss: 8 Pencil Hardness: HB Crosshatch Adhesion: Excellent-100% Retention Impact Resistance (Reverse): 40 inch-lbs.

122 Water-Soluble Resins

COOK PAINT AND VARNISH CO.: COROC Z-1727-Ml Water Dispersible Chain Stopped Alkyd: COROC Z-1727-Ml is a chain stopped, water dispersible alkyd resin supplied at 75% NV in a 50/50 blend of set-butanol and Propasol P. Z-1727-Ml is recommended for general industrial or automotive under the hood parts requiring good corrosion and humidity resistance as well as fast dry. For those applications requiring a higher degree of corrosion resistance, COROC Z-1726-M is recommended. Typical Physical Characteristics: Nonvolatile: 75+-l Solvent: Set-butanol: 50% Propasol P: 50% Viscosity: Zl - 23 Acid Number: 30 - 42 Color: 8 Max. Weight/Gallon: 8.56+-0.1 Suggested Uses: Automotive under the hood Implements and hardware General maintenance coatings Scaffolding Meter housings Advantages: LOW voc Good salt spray and humidity resistance Good application properties Drier Recommendations: 0.05 - 0.15% Cobalt 0.10% Manganese 2.0% CK-10

(% metal on resin solids) (% metal on resin solids) (% on resin solids)

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123

COOK PAINT AND VARNISH CO.: COROC Z-2055-M Water Reducible Chain Stopped Alkyd Resin: Z-2055-M is a medium oil alkyd which when neutralized with a suitable amine, is reducible in water. The resin is supplied at 70% nonvolatile in a 1:l solvent blend of propylene glycol monomethyl ether and butanol. 2-2055-M may be used in an air dry application where very good drying characteristics are required. This resin may also be blended with water soluble melamines and ureas for use in off-white and light colored baking enamels. 2-2055-M offers good flexibility, excellent gloss, and durability. Physical Characteristics: Nonvolatile: 70+-l Solvent: propylene glycol monomethyl butanol: 50 Viscosity: 2-22 Color: 6 Max Acid Number: 50-59 Weight/Gallon: 0.55

ether: 50%

Properties: Excellent exterior durability Very good gloss Excellent color and color retention Good impact resistance Good humidity resistance Suggested Uses: Implement and hardware Primers Automotive accessories Metal signs and building products Household appliances Drier Recommendations: Air Dry: .02 - .04% .03 - -05% .5%

Cobalt Manganese Antiskin (on vehicle solids)

Film Characteristics: Air Dry: Dust Free: 15 minutes Tack Free: 1 hour Bake: .02% Cobalt Time (Mins.): 20 Temp. (F.): 155 Sward Hardness: 8

124

Water-Soluble

Resins

CPS CHEMICAL CO., INC.: Polymers: Dimethylamine/Epichlorohydrin Copolymers: AGEFLOC B-SOLV: Molecular Weight: v. low Intrinsic Viscosity dl/g: 0.04 Solids %: 50 Viscosity cps: 25 pH: 8.0 Specific Gravity: 1.14 AGEFLOC B-4508: Molecular Weight: v. low Intrinsic Viscosity dl/g: 0.06 Solids %: 50 Viscosity cps: 60 pH: 7.5 Specific Gravity: 1.14 AGEFLOC B-50: Molecular Weight: v. low Intrinsic Viscosity dl/g: 0.10 Solids %: 50 Viscosity cps: 120 pH: 7.5 Specific Gravity: 1.14 Registration: 1,5,6 AGEFLOC A-50LV: Molecular Weight: low Intrinsic Viscosity dljg: 0.15 Solids %: 50 Viscosity cps: 300 pH: 5.0 Specific Gravity: 1.14 Registration: 1,5,6 AGEFLOC A-50: Molecular Weight: med Intrinsic Viscosity dl/g: 0.25 Solids 8: 50 Viscosity cps: 700 pH: 5.0 Specific Gravity: 1.14 Registration: 1,5,6

CPS Chemical Co., Inc.

125

CPS CHEMICAL CO., INC.: Polymers: Dimethylamine/Epichlorohydrin Copolymers(Continued): AGEFLOC A-50HV: Molecular Weight: high Intrinsic Viscosity dl/g: 0.50 Solids %: 50 Viscosity cps: 5000 pH: 4.5 Specific Gravity: 1.14 Registration: 1 AGEFLOC 4506: Molecular Weight: med Intrinsic Viscosity dl/g: 0.25 Solids %: 50 Viscosity cps: 700 pH: 5.0 Specific Gravity: 1.14 Registration: 2,5,6 Registration: 1) USEPA-Potable Water 2) 21 CFR 173.60 sugar liquor decolorization and clarification 5) 21 CFR 176.170 paper in contact with fatty and aqueous foods 6) 21 CFR 176.180 paper in contact with dry foods EPA and FDA approved. Wide range of molecular weights. Unaffected by temperature or pH. Uses: color removal, low turbidity water clarification, sugar and sugar beet processing, latex coagulation, latex waste clarification, liquid solid separation, filter belt sludge dewatering.

126

Water-Soluble

Resins

CPS CHEMICAL CO., INC.: Polymers: pDMDACs-Copolymers Miscellaneous:

and

AGEQUAT C-505: Molecular Weight: high Charge: ++ Solids %: 11 Viscosity cps: 15000 Color APHA: 100 Specific Gravity: 1.03 Registration: 5,6 FDA approved. Uses: drainage and retention aids, sludge dewatering AGEQUAT 500: Molecular Weight: high Charge: ++ Solids %: 11 Viscosity cps: 15000 Color APHA: 50 Specific Gravity: 1.03 Registration: 7 AGEQUAT 5008: Molecular Weight: high Charge: ++ Solids %: 8.5 Viscosity cps: 10000 Color APHA: 50 Specific Gravity: 1.02 Registration: 7 AGEQUAT 400: Molecular Weight: medium Charge: ++++ Solids %: 40 Viscosity cps: 10000 Color APHA: 100 Specific Gravity: 1.08 Registration: 7 CTFA registered Polyquaternium 6 & 7. Low Draize ratings for personal care formulations including hiar sprays, shampoos, conditioners, mousses, and rinses. AGEQUAT 1000: Molecular Weight: low Charge: +++ Solids %: 40 Viscosity cps: 2000 Color APHA: 200 Specific Gravity: 1.08 Retention aid, fines retention and drainage Registration: 5) 21 CFR 176.170 paper in contact with fatty and aqueous food 6) 21 CFR 176.180 paper in contact with dry foods 7) CTFA (Cosmetics, Toiletry and Fragrance Assoc.)

CPS Chemical Co., Inc.

CPS CHEMICAL CO., INC.: Polymers: pDMDACs-Paper AGEFLOC PC-20HV: Molecular Weight: med Intrinsic Viscosity al/g: 0.8 solids %: 20 Viscosity cps: 350 Color APHA: 200 Specific Gravity: 1.04 Registration: 5,6 AGEFLOC PC-20VHV: Molecular Weight: high Intrinsic Viscosity al/g: 1.0 Solids %: 20 Viscosity cps: 700 Color APHA: 250 Specific Gravity: 1.04 Registration: 5,6 AGEFLOC PC-40: Molecular Weight: low Intrinsic Viscosity dug: solids %: 40 Viscositv cus: 2000 Color APHA:‘200 Specific Gravity: 1.08 Registration: 5,6

0.5

AGEFLOC PC-IOHV: Molecular Weight: med Intrinsic Viscosity al/g: 0.8 solids %: 40 Viscosity cps: 10000 Color APHA: 200 Specific Gravity: 1.08 Registration: 5,6 AGESTAT 41: Molecular Weight: low Intrinsic Viscosity al/g: solids %: 40 Viscosity cps: 2000 Color APHA: 100 Specific Gravity: 1.08

0.5

Industry:

1.27

128

Water-Soluble Resins

CPS CHEMICAL CD., INC.: Polymers: pDMDACs-Paper (Continued):

Industry

AGESTAT 41T: Molecular Weight: low Intrinsic Viscosity dl/g: 0.4 Solids %: 40 Viscosity cps: 700 Color APHA: 100 Specific Gravity: 1.08 AGESTAT 42: Molecular Weight: med Intrinsic Viscosity dl/g: 0.8 Solids %: 40 Viscosity cps: 10000 Color APHA: 200 Specific Gravity: 1.08 Registration: 5) 21 CFR 176.170 paper in contact with fatty and aqueous foods 6) 21 CFR 176.180 paper in contact with dry foods FDA approved. Uses: retention aid, pigment dispersion, pitch dispersant, fines retention, drainage aid, electroconductive polymer, raw and waste water clarification.

CPS Chemical Co.. Inc.

CPS CHEMICAL CO., INC.: Polymers: pDMDACs-Water AGEFLOC WT-20: Molecular Weight: low Intrinsic Viscosity dl/g: 0.5 Solids %: 20 Viscosity cps: 130 pH: 6 Specific Gravity: 1.04 Registration: USEPA-Potable Water AGEFLOC WT-ZOHV: Molecular Weight: med Intrinsic Viscosity dl/g: 0.8 Solids %: 20 Viscosity cps: 350 pH: 6 Specific Gravity: 1.04 Registration: USEPA-Potable Water AGEFLOC WT-20VHV: Molecular Weight: high Intrinsic Viscosity dl/g: 1.0 Solids %: 20 Viscosity cps: 700 pH: 6 Specific Gravity: 1.04 Registration: USEPA-Potable Water AGEFLOC WT-2206: Molecular Weight: high Intrinsic Viscosity dl/g: 1.3 Solids %: 20 Viscosity cps: 1400 pH: 6 Specific Gravity: 1.04 Registration: USEPA-Potable Water AGEFLOC WT-40: Molecular Weight: low Intrinsic Viscosity dl/q: 0.5 Solids %: 40 Viscosity cps: 2000 pH: 6 Specific Gravity: 1.08 Registration: USEPA-Potable Water

Treatment:

129

130 Water-Soluble Resins

CPS CHEMICAL CO., INC.: Polymers: pDMDACs-Water (Continued):

Treatment

AGEFLOC WT-40HV: Molecular Weight: med Intrinsic Viscosity dl/g: 0.8 Solids %: 40 Viscosity cps: 10000 pH: 6 Specific Gravity: 1.08 Registration: USEPA-Potable Water AGEFLOC WT-35VLV: Molecular Weight: low Intrinsic Viscosity dl/g: 0.3 Solids %: 35 Viscosity cps: 150 pH: 6 Specific Gravity: 1.08 Registration: USEPA-Potable Water AGEFLOC WT-SOSLV: Molecular Weight: v. low Intrinsic Viscosity dl/g: 0.1 Solids %: 50 Viscosity cps: 150 pH: 6 Specific Gravity: 1.09 EPA approved. Wide range of molecular weights. Unaffected by temperature or pH. Uses: low turbidity water clarification, municipal water treatment, sludge dewatering, recycled mining water, laundry effluents, oil field waters, yarn processing.

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131

CPS CHEMICAL CO., INC.: Polymers: Polymeric Aluminum Salts: AGEFLOC CF-50: Chemistry: Inorganic-Aluminum Al as A1203: 23.5 Al/Cl: 2/l pH 15% solution: 4.2 Specific Gravity: 1.34 Registration: 1

Complex

AGEFLOC CF-SOD: Chemistry: Blend w/polye lectro lyte Al as A1203: 23.5 Al/Cl: 2/l pH_15% Soln: 4.2 Specific Gravity: 1.34 Registration: 1 AGEFLOC CF-50G: Chemistry: Blend w/organic polymer Al as A1203: 23.5 Al/Cl: 2/l pH 15% Soln: 4.2 Specific Gravity: 1.34 Registration: 1 AGEFLOC CF-5020: Chemistry: Blend w/polyelectrolyte Al as A1203: 23.5 Al/Cl: 2/l pH 15% Soln: 4.2 Specific Gravity: 1.34 EPA approved. Doesn't affect pH; non corrosive. Reduces phosporus and heavy metal levels. Unaffected by temperature and pH. Uses: meat and poultry plant effluents, emulsion breaking, fat and grease separation, oil/water separation, raw water clarification, mining recycle water, replacement for alum or ferric chloride.

132

Water-Soluble Resins

CPS CHEMICAL CO., INC.: Polymers: Polymeric Carboxylic Acids: AGESPERSE 71: Form: Liquid Na+ Salt Activity %: 25 Color APHA: 250 Viscosity cps: 150 Specific Gravity: 1.10 Registration: 3,4,6 AGESPERSE 80: Form: Liquid Na+ Salt Activity %: 30 Color APHA: 100 Viscosity cps: 150 Specific Gravity: 1.10 Registration: 3,4,5,6 AGESPERSE 81: Form: Liquid Na+ Salt Activity %: 25 Color APHA: 60 Viscosity cps: 75 Specific Gravity: 1.10 Registration: 3,4,5,6 AGESPERSE 82: Form: Liquid NH4+ Salt Activity %: 25 Color APHA: >250 Viscosity cps: 35 Specific Gravity: 1.10 Registration: 3,4,6 Dispersants: paper, rubber, mining, textiles, ceramic slip, detergents, boiler water compounds, cooling water compounds. Registration: 3) 21 CFR 175.105 4) 21 CFR 175.300 5) 21 CFR 176.170 foods 6) 21 CFR 176.180

adhesives resinous coatings paper in contact with fatty and aqueous paper in contact with dry foods

Dock Resins Corp.

133

DOCK RESINS CORP.: Acrylic Resins: DORESCO ACW8-6: DORESCO ACW8-6 is a thermoplastic acrylic resin dispersion in water. It is used in formulating water flexo inks, gravure inks, and paper coatings. As a grinding vehicle, DORESCO ACW8-6 produces low viscosities at high pigment loading. It can be diluted with water and or alcohols to any desired solids. To suppress foaming, small amounts of antifoams may be used, although isopropanol as part of a diluent will also cut foam. This resin is compatible with rosin ester resins in water systems, styrenated shellac, and other water soluble acrylics. Adhesion to aluminum is excellent so that foil inks can be formulated from these items. Harder films with improved water spotting resistance can be formulated by adding up to 10% prilled urea on a solids basis. The ability to continuously run water gravure inks is enhanced by including moderate amounts of DORESCO ACW8-6 due to its tendency to increase open time. This resin minimizes the clogging of the engravings in the gravure roller, an important feature of DORESCO ACW8-6. DORESCO ACW8-6 has been accepted by the Food and Drug Administration and the Department of Agriculture as chemically acceptable as components of printing inks in minimal contact with meat or poultry food product prepared under Federal inspection. Physical Constants: Solids: 30+-l% Solvent: Water Viscosity: 300 cps max. Lbs./Gal.: 8-S+-0.2 pH: 8.0-8.3 Neutralizer: DMEA DORESCO ACW25-1: DORESCO ACW25-1 is a styrene-acrylic multipolymer dispersed in water and ammonia. It is designed to be compatible with acid terminated air or forced-drying alkyds dispersed in water and amines. The Tg is high enough so that the speed of dry of the alkyd is improved without imparting brittleness. The effect on durability is expected to be positive, but must be tested with the alkyd and the substrate for each use. Physical Constants: Solids: 33-34-S% Solvent: Water Viscosity: 600-1200 cps Lbs./Gal.: 8.7+-0.1 Appearance: Hazy, milky solution pH: 7.0-8.0 Dispersant: Ammonia

134

Water-Soluble Resins

DOCK RESINS CORP.: Acrylic Resins(Continued): DORESCO ACW35-1: DORESCO ACW35-1 is a thermoplastic acrylic resin dispersion in water. It is formulated to produce bright gold prints with acid coated bronze powders. DORESCO ACW35-1 has a high acid content and properly buffered pH which makes it compatible with, yet non-destructive to, bronze powders. Further, the acid will enhance the adhesion properties facilitating its usage on a wide variety of substrates. Side by side prints have demonstrated that inks and bronzing liquids, formulated with DORESCO ACW35-1, appear much brighter than those formulated with competitive vehicles. Physical Constants: Solids: 19.5+-l% Solvent: Water Viscosity: approx. 80 cps. Lbs./Gal.: 8.68+-0.20 pH: 4.0-5.0 Neutralizer: NaOH Appearance: Milky Liquid DORESCO AETl-1: DORESCO AHTl-1 is water based, hydroxyl functional acrylic latex. It is designed to yield a high quality, compliant, baking enamel in conjunction with water dispersible urea-formaldehyde or melamine-formaldehyde resins. Due to the low film forming temperature of DORESCO AETl-1, it requires little to no coalescing solvent. However, sometimes coalescing type solvents are added to impart better wetting of or adhesion to the substrate. The baking time and temperature required to cure the film varies greatly with the crosslinking resins used, catalyst level, and film thickness. However, the resin has similar speed of cure to its solvent based counterparts. Physical Constants: Solids: 43.0+-1.0% Solvent: Water Viscosity: 100-120 cps Color: White Hydroxyl number (on N.V.): 48 Lbs./Gal.: 9.04+-0.1

Dock Resins COUJ.

DOCK RESINS CORP.: Acrylic Resins(Continued): AQUA-HYDE

100:

Water-soluble

acrylic polymer

Important Characteristics: High Finish in Pigmented Inks and Coatings Wet-Rub Resistance Dry-Rub Resistance Pigment Wetting: Low Viscosity at High Pigment Loading Heat Resistance - improved with melamine Low Viscosity at High Resin Content Main Uses: Water Flexographic Paper Coatings Gravure Inks

Inks

Typical Characteristics: Non-Volatile: 30% Lbs./Gal.: 8.16 pH: 7.25 Viscosity: 14 poises Solubility and Compatibility: AQUA-HYDE 100 can be diluted with water and/or alcohols to any desired solids. No ammonia or volatile base need be added to AQUA-HYDE 100. Inks made from AQUA-HYDE 100 are generally free of foaming. Fresh ink is easily cleaned up with water. In most applications, AQUA-HYDE 100 is used without modifying resins. However, for special purposes limited amounts of Casein, Shellac, Rosin Maleic esters or Styrene-Acrylic are suggested. Heat Resistance: AQUA-HYDE 100 has heat resistance suitable for many applications when cured with melamine. Testing was conducted at 500 Deg. F with 60 second dwell.

135

136

Water-Soluble Resins

DOW CHEMICAL CO.: METHOCEL Cellulose Ethers: METHOCEL cellulose ethers are water-soluble polymers derived from cellulose, the most abundant polymer in nature. METHOCEL products are used as thickeners, binders, film formers, and water retention agents. They also function as suspension aids, surfactants, lubricants, protective colloids, and emulsifiers. In addition, solutions of METHOCEL thermally gel, a unique property that plays a key role in a surprising variety of applications. General Properties of MeTHOCEL cellulose ethers: Water solubility: METHOCEL cellulose ethers dissolve in water with no sharp solubility limit. Organic solubility: Certain types and grades of METHOCEL are also soluble in binary organic and organic solvent/water systems, providing a unique combination of organic solubility and water solubility. No ionic charge: METHOCEL cellulose ethers are non-ionic and will not complex with metallic salts or other ionic species to form insoluble precipitates. Thermal gelation: Aqueous solutions of METHOCEL products gel when heated above a particular temperature, providing controllable quick-set properties. Surface activity: METHOCEL products exhibit surfactancy in aqueous solutions to provide emulsification, protective colloid action, and phase stabilization. Metabolic inertness: Used as food and drug additives, METHOCEL products do not add calories to the diet. Enzyme resistance: Enzyme resistant METHOCEL products provide excellent viscosity stability during long-term storage. Low taste and odor: Important in food and pharmaceutical applications. pH stability: Stable over a pH range of 3.0-11.0. Water retention: METHOCEL cellulose ethers are highly efficient water retention agents. Thickening: METHOCEL cellulose ethers thicken both aqueous and nonaqueous systems. Film Formation: METHOCEL products form clear, tough, flexible films. Binding: Used as high performance binders for pigments... Lubrication: Used to reduce friction in rubber, portland cement... Suspending: Used to control settling of solid particles. Colloidal action: Used to prevent droplets from coalescing. Emulsification: METHOCEL cellulose ethers stabilize emulsions.

Dow Chemical U.S.A.

DOW CHEMICAL U.S.A.: WETHOCEL Cellulose Ethers(Continued): Properties of METHOCEL powders: WETHOCEL cellulose ether products are white to slightly off-white powders which are essentially odorless and tasteless. The apparent density of the powders ranges from 0.25 to 0.70 g/CC. Moisture sorption: METHOCEL products sealed in their original shipping containers absorb little to no atmospheric moisture._ Once a container is opened, however, there is pick-up of moisture from the air. Properties of Solutions of MRTHOCEL: General solution properties: Specific gravity, 1% solutions: 5% solutions: 10% solutions:

4C, all types: 1.0012 1.0117 1.0245

Refractive index, 2% solutions, all types: 1.336 n20 D Partial suecific volume: 4,000 &Pa-s METHOCEL A: 4,000 mPa-s METHOCEL E: 41000 mPa-s METHOCEL F: 5,000 mPa-s METHOCEL J: 4,000 mPa-s METHOCEL K: 15,000 mPa-s METHOCEL K:

0.725 0.767 0.734 0.725 0.717 0.724

cc/g(O.O87 cc/s(O.O92 cc/g(O.O87 cc/g(O.O87 cc/g(O.O86 cc/g(O.O87

gal/lb) gal/lb) gal/lb) gal/lb) gal/lb) gal/lb)

Freezing point, 2% solutions, all types: O.OC at 2% concentration Surface tension, 25C, 0.05% concentrations: Water: 72-74 x 10 -3 Newton/meter (72-74 dynes/cm) Methylcellulose: 53-59 x 10 -3 Newton/meter (53-59 dynes/cm) Hydroxypropyl methylcellulose: 43-55 x 10 -3 Newton/meter (43-55 dynes/cm)

137

138

Water-Soluble

Resins

DOW CHEMICAL U.S.A.: METHOCEL Cellulose Ethers(Continued): Properties of

films

of METHOCEL:

High strength, water-soluble films, supported or unsupported, may be rolled, cast, or extruded from formulations of METHOCEL cellulose ether products. These clear, smooth, films or coatings are impervious to oils, greases, and most solvents. They are also effective binders, even when loaded with inert materials. Properties of unplasticized

films of METHOCEL:

METHOCEL A15-LV: Specific gravity: 1.39 Area factor: 24,000 in'/lb/mil Moisture vapor transmission rate, lO.OF, 50% RH: 67.5g/100ina/24hr/mi1 Oxygen transmission rate, 75F: 25cc/lOOin"/24hr/mil Tensile strenath. 75F. 50% RH: 9.000 lbs/in'ilO% Elongation, 75F;50% RH: 5-15% . Stability to ultraviolet light, 500 hrs, Fadeometer exposure: Excellent Resistance to oils and most solvents: Excellent Ultraviolet transmission, 400 nm: 55% (2 mil film) 290 nm: 49% 210 nm: 26% METHOCEL E15-LV: Specific gravity: 1.29 Area factor: 25,860 in'/lb/mil Moisture vapor transmission rate, lOOF, 50%: 65g/100ina/24hr/mil Oxygen transmission rate, 75F: 70cc/lOOin"/24hr/mil Tensile strength, 75F, 50% RH: 10,000 lbs/in'+lO% Elongation, 75F, 50% RH: 5-15% Stability to ultraviolet light, 500 hrs, Fadeometer exposure: Excellent Resistance to oils and most solvents: Excellent Ultraviolet transmission, 400 nm: 82% (2 mil film) 290 nm: 34% 210 nm: 6%

Dow Chemical U.S.A.

DOW CHEMICAL CO.: PRIMACOR Dispersible

139

Polymers:

PRIMACOR Adhesive Polymer 5980: Melt Index, g/10 min: 300 Melt Flow, g/10 min: 15(B) % Acrylic Acid: 20 Density, g/cc: 0.958 Ultimate Tensile, psi: 1400 Elongation, %: 390 2% Secant Modulus, osi: 4800 Hardness, Shore D: ‘50 Vicat Softening Point, F: 108 Crystalline Melting Point, F: 175 PRIMACOR Adhesive Polymer 5990: Melt Index, g/l0 min: 1300 Melt Flow, gjl0 min: 65(B) % Acrylic Acid: 20 Density, g/cc: 0.955 Ultimate Tensile, psi: 900 Elongation, %: 350 2% Secant Modulus, psi: 3200 Hardness, Shore D: 42 Vicat Softening Point, F: 104 Crystalline Melting Point, F: 167 FDA Listing: 21 CFR 175.105 21 CFR 176.170

Adhesives Components of paper and paperboard with aqueous A fatty foods 21 CFR 176.180 Components of paper and paperboard with dry food 21 CFR 177.1310 Ethylene acrylic acid

Applications: - Adhesives - Paper and paperboard saturation and sizing - Laminations - Foil priming - Heat sealing - Nonwoven binding - Metal coating - Paper coating

in contact in contact

140

Water-Soluble Resins

DOW CHEMICAL CO.: PRIMACOR Dispersible Polymers(Continued): Outstanding Properties: Dispersible in aqueous amines and alkali "Clean" . ..dispersion requires no salts, surfactants, or solvents Excellent adhesion to metallic, cellulosic, glass, other substrates Dispersions use existing water-borne application equipment Low heat seal temperature High hot tack Excellent water, grease and oil resistance Low odor High gloss, excellent clarity Crosslinkable Versatile binder for nonwoven fibers including polypropylene, polyester, glass, nylon, others High wet strength retention Fabrics can be thermoformed Low resin density/high binder efficiency

DuPont

DUPONT:

ELVANOL

141

Polyvinyl Alcohol:

General Purpose -__Grades: -ELVANOL 90-50: Viscosity: 12-15 Percent Hydrolysis: 99.0-99.8 Solution pH: 5.0-7.0 Volatiles, % max: 5 Ash, % max: 0.7 Medium-low viscosity, fully hydrolyzed grade designed to provide high film strength and binding power in relatively low viscosity systems. Used in paper and paperboard coating and sizing, for textile warp sizing, in adhesives and as a pigment binder for highly filled systems. ELVANOL 71-30: Viscosity: 27-33 Percent Hydrolysis: 99.0-99.8 Solution pH: 5-O-7.0 Volatiles, % max: 5 Ash, % max: 0.7 Medium viscosity, fully hydrolyzed grade. Hot-water soluble, with excellent resistance to cold water. Used in textile, paper and adhesive applications and for gastight, solvent-resistant film. ELVANOL HV: Viscosity: 55-65 Percent Hydrolysis: 99.0-99.8 Solution pH: 5-O-7.0 Volatiles, % max: 4 Ash, % max: 0.7 High viscosity, fully hydrolyzed grade. Provides exceptionally high tensile and adhesive strength with strong resistance to grease and hydrocarbons. Used in adhesive, textile and paper applications. Textile Grades: --ELVANOL T-66: Viscositv: 12-15 Solution-pH: 5.0-7.0 Volatiles, % max: 5 Ash, % max: 0.7 ELVANOL T-66LR: Viscosity: 9-14 Solution pH: 5.0-7-O Volatiles, % max: 7 Ash, % max: 0.7 Unique copolymer for textile warp sizing. Designed for smooth slasher operation and easy desize, while still providing excellent weaving performance.

142

Water-Soluble Resins

DUPONT: KLVANOL Polyvinyl Alcohol(Continued): Textile Grades(Continued): RLVANOL T-25: Viscosity: 24-32 Solution pH: 5.0-7.0 Volatiles, % max: 5 Ash, % max: 0.7 HLVANOL T-25LR: Viscosity: 17-24 Solution pH: 5.0-7.0 Volatiles, % max: 5 Ash, % max: 0.7 Unique copolymer for textile warp sizing. Provides excellent weaving performance and desizes readily even after heat-setting sized fabric in the greige. Specialty and Adhesive Grades: HLVANOL 75-15: Viscosity: 12-15 Percent Hydrolysis: 98.0-99.8 Solution pH: 5.0-7.0 Volatiles, % max: 5 Ash, % max: 0.7 Medium-low viscosity grade which imparts improved viscosity stability and gel resistance to aqueous solutions. For use in adhesives, films, paper applications and as an emulsifier for improved water resistance. HLVANOL 85-82: Viscosity: 24-32 Percent Hydrolysis: 99.0-99.8 Solution pH: 5.0-7-O Volatiles, % max: 5 Ash, % max: 0.7 Medium viscosity grade which combines high tensile and adhesive strength with good gel resistance. Used for adhesives, films and specialty applications. ELVANOL 85-30: Viscosity: 1100-1500 Solution pH: 3.1-4.1 Medium viscosity, tackified grade providing water-resistant solutions. For adhesives use in paper tube, core and can winding and solid fiber laminating. Useful in adhesives where a high degree of wet tack and/or water resistance is required.

DuPont

DUPONT: HLVANOL Polyvinyl Alcohol(Continued): ELVANOL 51-05: Viscosity: 5-6 Percent Hydrolysis: 87-89 Solution pH: 5.0-7-O Volatiles, % max: 5 Ash, % max: 0.7 Low viscosity, gel-resistant grade, soluble in cold water. Used for sizing synthetic filament yarns, as a ceramic binder, as a protective colloid and emulsifier, and for cold-watersoluble film. ELVANOL 52-22: Viscosity: 21-26 Percent Hydrolysis: 87-89 Solution pH: 5.0-7-O Volatiles, 8 max: 5 Ash, % max: 0.7 Medium viscosity, gel-resistant grade, soluble in cold water. Used as a protective colloid and emulsifier, in remoistenable adhesives, as a ceramic binder, and for coldwater-soluble film. ELVANOL 50-42: Viscosity: 44-50 Percent Hydrolysis: 87-89 Solution pH: 5.0-7.0 Volatiles, % max: 5 Ash, % max: 0.7 High viscosity, gel resistant grade, soluble in cold water. Used as a protective colloid and emulsifier, as a thickener, and as an adhesive component.

143

144

Water-Soluble Resins

DYNAGEL, INC.: Gelatin: The only natural protein of commercial importance capable of producing clear thermoreversible gels with water systems is gelatin. It is a fascinating material with unique gelling and thickening properties in combination with other commercially useful characteristics. Gelatin is extracted from collagen, the major structural protein in connective tissue and bone. It is the skin and bone material of animals processed for food by the meat industry that provides raw material for the gelatin manufacturer. Physical Properties: Gel Strength: DynaGel offers grades of gelatin over a wide range of gel strengths. pH: DynaGel gelatins are being produced at a naturally low pH (4.0-4.5) giving advantages in a number of applications where additional acid is required in the final product. Viscosity: Besides gel strength, viscosity in water is an important property of gelatin for some product applications. Gelatins readily available vary in viscosity between 20-50 millipoise. Solubility: Gelatin is readily insoluble in cold water but readily soluble in warm water. Microbiological Aspects: DynaGel gelatins are produced to the highest microbiological purity. Moisture Content: As with many complex hygroscopic substances, the moisture content of dry commercial gelatin will vary with the moisture content of the surrounding atmosphere, usually in the range from lo-13%. Process Control: Precise control of the gelatin process plant is needed to ensure the most efficient product handling and to minimize hydrolysis. Analysis: Primary analysis of dried gelatin powder is carried out to assess gel strength and other physical properties upon which is based the blending of gelatin for the different grades. Effect of Additives: Organic and inorganic chemicals can affect the physical properties of gelatin in many ways. Color: The color of gelatin is measured by optical evaluation of a solution of standard concentration of the gelatin under test. Clarity: The phenomenon of light scattering by insoluble particles present as ultra fine suspensions or emulsions in the gelatin solution is related to clarity. Ash Content: The ash yielded by any gelatin depends upon the type of raw material and the method of processing. Trace Metal Analysis: Extremely small amounts: Aluminum, Manganese, Zinc, Copper...

Firestone Synthetic Rubber & Latex Co.

145

FIRESTONE SYNTHETIC RUBBER & LATEX CO.: HARTEX Natural Latex: 101:

Total Solids, %: 62.1 Ammonia % on Wet Weight: 0.21 KOH Number: 0.54 Mechanical Stability, sec.: 1400 pH: 9.8 102:

Total Solids, %: 62.1 Ammonia % on Wet Weight: 0.15 KOH Number: 0.55 Mechanical Stability, sec.: 1750 pH: 9.4 103: Total Solids, %: 62.1 Ammonia % on Wet Weight: 0.21 KOH Number: 0.55 Mechanical Stability, sec.: 1400 pH: 9.8 104: Total Solids, %: 62.1 Ammonia % on Wet Weight: 0.71 KOH Number: 0.55 Mechanical Stability, sec.: 1250 pH: 10.4 Surgical and household gloves, adhesives for tapes, shoes, labels and envelopes, elastic thread, automotive weather-stripping, scatter rugs and carpet backing, balloons, toys, rubber footwear and tubing.

146 Water-Soluble Resins

FMC CORP.: MARINE COLLOIDS Carrageenan: Carrageenan is a generic term applied to hydrocolloids extracted from a number of closely related species of red seaweed. From this natural source, Marine Colloids has developed hundreds of variations for stabilizing and gelling foods, cosmetics and industrial products. Chondrus Crispus: - Also known as Irish Moss. - Small bushy plant about 10 cm in height. - Harvested along coast of the North Atlantic. - Most familiar of the red seaweeds. - Yields kappa and lambda carrageenans Eucheuma Species: - Cultivation pioneered by Marine Colloids. - Spiny, bushy plant about 50 cm in height. - Harvested from coral reefs in the Far East. - Yields kappa and iota carrageenans. Gigartina Species: - Grows worldwide in cold coastal waters. - Bushy or leafy plant ranging up to 5 m in height. - Yields more carrageenan than any other species. - Yields kappa and lambda carrageenans. Properties of Carrageenan: Carraseenan is a hish molecular weisht linear wlvsaccharide made up of repeating galactose units, and 3,6 anhydrogalactose (3, 6-AG), both sulfated and nonsulfated, joined by alternating 011-3, pl-4 glycosidic linkages. The many red seaweed plants approved as sources for extracts used in foods contains various amounts of three types of carrageenan known as kappa, iota and lambda. The primary differences which influence the properties of the types of carrageenan are the number and position of the ester sulfate groups on the repeating galactose units.

FMC Corp.

FMC CORP.: MARINE COLLOIDS Carrageenan(Continued): Properties of Carrageenan: Kappa: Solubility: 80C water: yes 20C water: Na+ salt soluble K+, Ca++ and NH4+ salts swell 80C milk: yes 20C milk: no 50% sugar solution: hot 10% salt solution: no Gelation: strongest gels: with K+ ion gel texture: brittle regelation after shear: no syneresis: yes freeze/thaw stability: no synergism with locust bean gum: yes Acid Stability: gels-pa >3.5: stable Salt Tolerance: poor Iota: Solubility: 80C water: yes 20C water: Na+ salt soluble CA++ salt swells to form thixotropic dispersion 80C milk: yes 20C milk: no 50% sugar solution: no 10% salt solution: hot Gelation: strongest gels: with Ca++ ion gel texture: elastic regelation after shear: yes syneresis: no freeze/thaw stability: yes synergism with locust bean gum: no Acid Stability: gels-pa >3.5: stable Salt Tolerance: good

147

148

Water-Soluble Resins

FMC CORP.: MARINE COLLOIDS Carrageenan(Continued1: Properties of Carrageenan(Continued1: Lambda: Solubility: 80C water: yes 20C water: yes 80C milk: yes 20C milk: thickens 50% sugar solution: yes 10% salt solution: hot Gelation: strongest gels: no gel gel texture: no gel regelation after shear: no syneresis: no freeze/thaw stability: yes synergism with locust bean gum:'no Acid Stability: gels-pa >3.5: stable Salt Tolerance: good Kappa: - Strong, rigid gel, some syneresis, forms helix with K+ ions. Ca++ causes helices to aggregate and the gel to contract and become brittle. - Slightly opaque gel. Becomes clear with sugar. - Approximately 25% ester sulfate and 34% 3,6-AG. Iota: - Elastic gels, forms helix with Ca++. Limited aggregation contributes to elasticity, no syneresis. - Clear gel. - Freeze/thaw stable. - Approximately 32% ester sulfate and 30% 3,6-AG. Lambda: - No gel, random distribution of polymer chains. - High viscosity. - Approximately 35% ester sulfate and little or no 3,6-AG.

FMC Corp.

FMC CORP.: MARINE COLLOIDS Carrageenan(Continued): GELCARIN Carrageenan

Systems - Water Gelation:

Application: Air Freshener Gels (Boat Type Cannisters): First Product Choice: GELCARIN AF 650B Second Product Choice: GELCARIN AF 917B Air Freshener Gels (Self-Support Cannisters): First Product Choice: GELCARIN AF 387B Second Product Choice: GELCARIN AF 920B Aloe Vera: First Product Choice: GELCARIN GP 812 second Product Choice: VISCARIN GP 209 Aquaculture Diets: First Product Choice: GELCARIN PS 398 Cake Glaze: First Product Choice: GELCARIN DG 812 Second Product Choice: GELCARIN DG 555L Cheese, Imitation Block: First Product Choice: GELCARIN GP 911 Second Product Choice: GELCARIN SA 910 Cheese, Imitation Spread: First Product Choice: GELCARIN GP 911+ SEA KEM GP 418 Second Product Choice: GELCARIN GP 911 Desserts, Water Gels (Dry Mix): First Product Choice: GELCARIN DG 425B Second Product Choice: GELCARIN DG 567 Desserts, Water Gels (RTE): First Product Choice: GELCARIN DG 654 Second Product Choice: GELCARIN DG 764B Desserts. Water Gels (Susar Free): FirstvProduct Choice:-GELCARIN DG 425B Second Product Choice: GELCARIN DG 567 Entrapment/Encapsulation: First Product Choice: GELCARIN GP 911 Second Product Choice: GELCARIN GP 379 Fabricated/Formed Foods: First Product Choice: GELCARIN FF 961L Second Product Choice: GELCARIN GP 812

149

150

Water-Soluble Resins

FMC CORP.: MARINE CCLLOIDS Carrageenan(Continued): GELCARIN Carrageenan

Systems-Water

Gelation(Continued):

Application: Fish Gels: First Product Choice: GELCARIN GP 379+ GELCARIN GP 812 Fruit-in-Gel: First Product Choice: GELCARIN DG 654 Second Product Choice: GELCARIN XP 7019 Ham, Further Processed: First Product Choice: GELCARIN SA 911 Second Product Choice: GELCARIN SA 811 Jelly, Imitation (Low Calorie Dry Mix): First Product Choice: GELCARIN SA 426L Jelly, Imitation (Low Calorie RTE): First Product Choice: GELCARIN SA 536 Second Product Choice: GELCARIN SA 329B Mayonnaise, Imitation: First Product Choice: GELCARIN GP 379 Second Product Choice: VISCARIN SD 389 Pasta: First Product Choice: GELCARIN GP 379 Second Product Choice: VISCARIN SD 389 Peanut Butter, Extended: First Product Choice: GELCARIN GP 911 Pet Food: First Product Choice: GELCARIN PF 911 Second Product Choice: GELCARIN PF 545 Pet Food, Gravy: First Product Choice: GELCARIN PF 545 Second Product Choice: GELCARIN PF 911 Pie Filling: First Product Choice: GELCARIN GP 812 Poultry Nuggets: First Product Choice: GELCARIN XP 8007 Second Product Choice: GELCARIN GP 812+ VISCARIN SD 389

FMC Corp.

FMC CORP.: MARINE COLLOIDS Carrageenan(Continued): GELCARIN Carrageenan Systems-Water

Gelation(Continued):

Application: Poultry, Further Processed: First Product Choice: GELCARIN SA 911 Second Product Choice: GELCARIN SA 812 Red Meats. Further Processed: First Product Choice: GELCARIN XP 8004 Second Product Choice: GELCARIN GP 379 Seafood, Further Processed: First Product Choice: GELCARIN GP 812 Sorbet: First Product Choice: GELCARIN GP 379 Second Product Choice: VISCARIN SD 389 Sour Cream: First Product Choice: GELCARIN GP 359 Second Product Choice: VISCARIN GP 109 SurimifKamaboko: First Product Choice: GELCARIN XP 8009 Tomato Sauces: First Product Choice: GELCARIN GP 379 Second Product Choice: SEAKEM CM 611+ GELCARIN GP 379 Whipped Cream: First Product Choice: GELCARIN GP 359 Second Product Choice: VISCARIN GP 109 SEAGEL Carrageenan

Systems--Milk

VISCARIN Carrageenan SEAKEM Carrageenan

Gelation:

Systems-Water

Viscosity:

Systems-Milk Viscosity:

VISCARIN Carrageenan Systems-Cold

Soluble:

LACTARIN Carrageenan Systems-Cold

Soluble:

151

152

Water-Soluble Resins

FREEMAN CHEMICAL CORP.: CHRWPOL lo-0091 Water Reducible Alkyd: Water reducible short oxidizing oil alkyd Features: - Can be used in air dry, force dry or baking finishes - Hard water resistant films - Good gloss retention and corrosion resistance Typical Characteristics: Total solids, wt. %: 75+-l Solvent: Mixture# Acid number (on solution): 25-29 Color, Gardner-Holdt: 5-10 Viscosity, as supplied: 25-27 Reduced viscosity, 50% solids in ethylene glycol monobutylether: M-Q Hydroxyl number (theoretical on solids): 126 Isophthalic acid: Present Oil: Oxidizina Weight/gallon; (solution) lbs.: 8.7-8.9 Weight/gallon, (solids) lbs.: 9.4-9.7 Volume solids (calculated), %: 69 Flash point (T.C.C.) F/C: 74/23 # Ethylene glycol monobutylether/sec-butanol Suggested Uses: - Water reducible primers - One-coat industrial enamels - Implement finishes Curing Information: - Air Dry - 3.0 mil wet film on glass (50-60% relative humiditv. 72F) Set.to touch: lo-20 minutes Dry hard: 0.5-1.5 hours Dry through: 2-4 hours - Force Dry - 3.0 mil wet film on glass Time(min) 20 15

Temperature(F/C) 160/71 180182

Solubility Information: - Percent solids to which CHEMPOL lo-0091 may be reduced in water at pH 8.0-9-O Solids, Wt.% 40 30 25

Viscosity 21-22 X-Y
Freeman Chemical Corp.

153

FREEMAN CHEMICAL CORP.: CHEMPOL lo-0095 Water Reducible Alkyd: Water reducible short oil alkyd Features: - Economical - Can be used in air dry, force dry or baking finishes - Good film hardness - Good early water resistance Typical Characteristics: Total solids, wt. %: 75+-l Solvent: Mixture# Acid number (on solution): 27-32 Color, Gardner-Holdt: 10 max Viscosity, as supplied: 26-27 Reduced viscosity, 50% solids in ethylene glycol monobutylether: K-N Hydroxyl number (theoretical on solids): 126 Isophthalic acid: Present Oil: TOFA Weight/gallon (solution) lbs.: 8.6-8.8 Flash point (T.C.C.) F/C: 74/23 # Ethylene glycol monobutyletherisec-butanol

1:l by weight

Suggested Uses: - Water reducible primers - One-coat industrial enamels Curing Information: - Air Dry (Method A) Set to touch Dry hard Dry through

3.0 mil wet film on glass (50-608 relative humidity, 72F) 15-25 minutes 1.0-2.0 hours 3-5 hours

- Force Drv (Method B) Time(min) 20 15

3.0

mil wet film on glass Temperature (F/C) 160/71 180/82

Solubility Information: - Percent solids to which CHEMPOL lo-0095 may be reduced in water at pH 8.0-9.0# Solids, Wt. % 40 30 25

Viscosity 21-23 w-z
# Maintaining CHEMPOL lo-0095 at temperatures above 140F for prolonged periods can result in poor water solubility and/or loss of drying speed

154

Water-Soluble

Resins

FREEMAN CHEMICAL CORP.: CHEMPOL lo-0097 Water Reducible Alkyd: Water reducible short oil alkyd Features: - Can be used in air dry, rorce dry or baking finishes - Water resistant films - Good gloss retention and very good corrosion resistance Typical Characteristics: Total solids, wt. %: 70+-l Solvent: Mixture# Acid number (on solution): 25-30 Color, Gardner-Holdt: 7 max Viscosity, as supplied: 24-26 Reduced viscosity, 50% solids in ethylene glycol monobutylether: K-P Hydroxyl number (theoretical on solids): 90 Isophthalic acid: Present Oil: TOFA Weight/gallon, (solution) lbs.: 8.6-0.8 Flash point (T.C.C.) F/C: 74123 # Ethylene glycol monobutylether/sec-butanol

1:l by weight

Suggested Uses: - Water reducible primers - One-coat industrial enamels - Implement finishes Curing Information: - Air Dry (Method A) -

3.0 mil wet film on glass (50-60% relative humidity, 72F)

Set to touch: lo-20 minutes Dry hard: 0.5-1.5 hours Dry through: 2-4 hours - Force Dry (Method B) - 3.0 mil wet film on glass Time(min) Temperature(F/C) 20 160/71 15 180182 Solubility Information: Percent solids to which CHEMPOL lo-0097 may be reduced in water at pH 8.0-9.0#: Solids, Wt. % Viscosity 40 22-23 30 X-Z 25
Freeman Chemical Corp.

FREEMAN CHEMICAL CORP.: CHEMPOL lo-0503 Water Reducible Polyester: Water reducible saturated polyester Features: - Rapid cure response - Hardness and flexibility - Good solubility in water and cosolvent - Good hydrolytic stability - Excellent color and gloss retention Typical Characteristics: Total solids, wt. %: 75+-l Solvent: Proovlene slvcol t-butvlether Acid number ion solution): 42-48 Color, Gardner-Holdt: O-3 Viscosity, as supplied: 23-25 Reduced viscosity, 50% solids in propylene glycol t-butylether: H-K Hydroxyl number (theoretical on solids): 207 Weight/gallon (solution): 8.9-9.1 Weight/gallon (solids): 9.7-9.9 Volume solids (calculated): 69.1 Flash point (T.C.C.) F/C: 113/45 Suggested Uses: - High performance coil coatings - High performance general industrial applications Curing Information: - Bake - 1.5 mil wet film on Bonderite 1000 Time(min) Temperature(F/C) 15 2751135 Suggested Reduction Formula: CHEMPOL IO-0503 Triethyl amine Cymel 303 Tap water NVM

-

40.0;

melamine/resin

Parts by Weight 37.3 3.2 12.0 47.5 - 30/70; Viscosity

- D

Solubility Information: - Tertiary amines should be used to neutralize CHEMPOL lo-0503 prior to dispersion in water. The following amines may be used per 100 parts by weight. CHEMPOL 10-0503: Amine pbw i.1 Dimethylethanol amine Methyldiethanol amine 9.6 Triethylamine 8.1 11.9 DMAMP-80

155

156

Water-Soluble Resins

FREEMAN CHEMICAL CORP. : C?IEMPOL lo-1105

Water Reducible Alkyd:

Water reducible coconut baking alkyd Features: - Good flexibility and hardness - Outstanding color retention on overbake Typical Characteristics: Total solids, wt. %: 70+-l Solvent: See-below# Acid number (on solution): 25-35 Color, Gardner-Holdt: 2-6 Viscosity, as supplied: 25-27 Reduced viscositv. 50% solids in ethylene slvcol _ _ monobutyletheri K-P Hydroxyl number (theoretical on solids): 110 Isophthalic acid: Present Oil: Coconut Weight/gallon, lbs.: 9.0-9.2 Flash point (T.C.C.) F/C: 143162 #Ethylene glycol monobutylether Suggested Uses: - Appliance finishes - General industrial metal coatings - Lighting fixture coatings Curing Information: - Bake - 3.0 mil wet film on cold rolled steel Temperature(F/C) Time(min) 3001149 10 2751135 20 Solubility Information: CHEMPOL lo-1105 may be reduced to (25% solids by wt. in water at a pH of 8.5-9-O (with dimethylethanolamine).

Freeman Chemical Corp.

FREEMAN CHEMICAL CORP.: CHEWPOL lo-1210 Water Reducible Alkyd: Water reducible short oil alkyd Features: - Rapid tack free, fast through dry, early water spot resistant film - Can be used in air dry, force dry or baking finishes Typical Characteristics: Total solids, wt. %: 70+-l Solvent: Ektapro EP# Acid number (on solution): 28-32 Color, Gardner-Holdt: 10 max Viscosity, as supplied: 25-27 Reduced viscosity, 50% solids in ethylene glycol monobutylether: O-R Hydroxyl number (theoretical on solids): 84 Isophthalic acid: Present Oil: Soya Weight/gallon, (solution) lbs.: 8.7-8.9 Flash point (T.C.C.) F/C: 74/23 # Ethylene glycol monopropylether Suggested Uses: - Water reducible primers Curing Information: - Air Dry (Method A) - 3.0 mil wet film on glass (50-608 relative humidity, 72F) Set to touch: 5-15 minutes Dry hard: 0.5-l-5 hours Dry through: 1.5-3.0 hours - Force Dry (Method B) - 3.0 mil wet film on glass Time(min) Temperature(F/C) 20 160/71 15 180/82 Solubility Information: - Percent solids to which CHEMPOL lo-1210 may be reduced in water at pH 8.0-9.0#: Solids, Wt % Viscosity 40 2-22 30 v-x 25
157

158

Water-Soluble Resins

FREEMAN CHEMICAL CORP.: CHEMPOL Copolymer:

lo-1300

Water Reducible

Water reducible acrylic alkyd copolymer Features: - Very rapid air dry - Early water resistance - Good corrosion resistance - May be force dried or crosslinked with aminoplasts Typical Characteristics: Total solids, wt. %: 70+-l Solvent: Mixture# Acid number (on solution): 32-42 Color, Gardner-Holdt: 3-8 Viscosity, as supplied: 24-26 Reduced viscosity, 50% solids in ethylene glycol monobutylether: L-O Hydroxyl number (theoretical on solids): 33 Isophthalic acid: Present Oil: Fatty acids Weight/gallon, lbs.: 8.15-8.35 Flash point (T.C.C.): 74123 # Ethylene glycol monobutylether/isobutanol Suggested Uses: - General industrial finishes - Fast dry machinery and implement enamels - Engine enamels and chassis paints Curing Information: - Air Dry - 3.0 mil wet film# on glass (50-60% relative humidity, 72F) Set to touch: 15-25 minutes Dry hard: 50-75 minutes Dry through: 3-5 hours # Using 0.15% cobalt on resin solids - Bake - 3.0 mil wet film on cold rolled steel Time(min) 15 20

Temperature(F/C) 200/93 160/71

Solubility Information: - CHEMPOL 10-1300 may be reduced to 25% solids by wt. in water at a pH of 8.0-9.0 (with triethylamine)

Freeman Chemical Corp.

FREEMAN CHEMICAL CORP.: CHEMPOL lo-1313 Water Reducible Copolymer: Water reducible acrylic alkyd copolymer Features: - Good exterior durability - Exceptional stability, useful for dip or flow coat applications - Excellent adhesion to metals and electrocoat primers Typical Characteristics: Total solids, wt. %: 70+-l Solvent: Mixture# Acid number (on solution): 26-31 Color, Gardner-Holdt: 5-9 Viscosity, as supplied: 22-24 Reduced viscosity, 50% solids in ethylene glycol monobutylether: I-L Hyaroxyl number (theoretical on solids): 41 Isophthalic acid: Present Oil: Soya/DC0 Weight/gallon, lbs.: 8.6 Flash point (T.C.C.) F/C: 74/23 # Ethylene glycol mononbutylether/sec-butanol Suggested Uses: - Drum enamels - General exterior uses on metal substrates - Dip or spray applications Curing Information: - Air Dry: 3.0 mil wet film# on glass (50-60% relative humidity, 72F) Set to touch: 30-40 minutes Dry hard: 2-3 minutes Dry through: 4-6 hours # Drier recommendation, % metal on resin solids: Cobalt: 0.05 Calcium: 0.10 Manganese: 0.10 A&iv-8: 0.50 - Bake - 3.0 mil wet film on cold rolled steel Time(min) z

Temperature(F/C) 180/82 200/93

Solubility Information: - CHEMPOL lo-1313 may be reduced to 25% solids by wt. in water at a pH of 8.0-9.0 (with triethylamine).

159

160

Water-Soluble Resins

FREEMAN CHEMICAL CORP.: CHEMPOL lo-1602 Epoxy Ester: Water reducible epoxy ester Features: - Exceptional stability, _ useful for dip or flow coat applications - Usable in air dry, force dry or bake formulations - Extremely good chemical resistance Typical Characteristics: Total solids, wt. 8: 65+-l Solvent: See below# Acid number (on solution): 26-31 Color, Gardner-Holdt: 6-12 Viscosity, as supplied: 23-24 Reduced viscositv. 50% solids in ethylene slvcol _ _ monobutyletheri T-V Hvdroxvl number (theoretical on solids): 29 Oil: Tall oil Weight/gallon, lbs.: 8.5-8.7 Flash point (T.C.C.) F/C: 157/47 # Ethylene glycol monobutyl ether Suggested Uses: - Automotive primers - General industrial coatings - Flow coat and dipping primers Curing Information: - Air Dry - 1.5 mil wet film# on glass (50-60% relative humidity, 72F) Set to touch: 30-60 minutes Dry hard: 2-3 hours Dry through: 4-6 hours # Drier recommendation, Cobalt: 0.05 Calcium: 0.10 Manganese: 0.10 Activ-8: 0.50

% metal on resin solids:

- Bake - 3.0 mil wet film on cold rolled steel Time(min) 30 20

Temperature(F/C) 180/82 200/93

Solubility Information: CHEMPOL lo-1602 may be reduced to 20% solids by wt. in water at a pH of 8.0-9.0 (with triethylamine).

Genesee Polymers Corp.

161

GENESEE POLYMERS CORP.: GP-165 Silicone Resin Emulsion: GP-165 Silicone Resin Emulsion is a concentrated emulsion of a reactive, further curable silicone resin in water carrier. GP-165 forms a continuous solid resin film, when applied to substrates and allowed to air dry. Curing to a solvent resistant coating takes place over a prolonged time period at room temperature, but may be accelerated by heating at 1OOC for 2 hours. GP-165 is suggested for use as a binder in aqueous paints intended for application to substrates exposed to high temperatures and as a component of water based masonry water repellent formulations. Typical Properties: Appearance: White, opaque liquid Specific Gravity: 1.0 Solids Content: 44% Carrier: Water Solvent Content: 13% (By Weight) pH: 6 Silicone Resin Content: 40% Applications: Latex Paint Additive (Improve Weathering) Water Repellent Formulations Binder in High Temperature Paints Protective Coatings Aqueous Adhesive Formulations Special Features: Stable Emulsion Concentrate Forms Continuous Films (Room Temperature) Good Water Repellency Dilutable with Water

162 Water-Soluble Resins

GENESEE POLYMERS CORP.: GP-223 Silicone Resin Emulsion: GP-223 Silicone Resin Emulsion is a 50% active emulsion of Methyl Silicone Resin. The resin component cures to a soft, pliable film upon application of GP-223 Silicone Resin Emulsion to a variety of substrates. Suggested applications of GP-223 Silicone Resin Emulsion include: use a water proofing agent in leather, textile, paper and masonry treatments. GP-223 Silicone Resin Emulsion contains water as a carrier and may be readily diluted further with water when required. Typical Properties: Appearance: White, opaque liquid Silicone Resin Content: 50% Wt./Gallon: 8.7 lbs. pH: 7.0 Type Emulsifiers: Non Ionic Carrier: Water Diluent: Water Applications: Water Repellents Car Polish Ingredient Mold Release Agents Special Features: Water Carrier and Water Dilutable No Solvent Present Good Emulsion Stability Film Forming Properties Imparts Water Repellent Film

6. F. Goodrich Co.

B. F. GOODRICH CO.: CARBOSET High Performance Graphic Arts, Electronics and Coatings:

163

Polymers for

Water Dispersion Products: XL-11: Percent (%) Non-Volatile By Weight: 30 Translucent Dispersion Viscosity cps, 25C: 50 pH: 6.7 Acid Number: 75 Glass Transition Temp., C: 55 Sward Hardness/Pencil Hardness: 35/2H Weight Per Gallon: 8.7 Hard glossy coatings with excellent water and corrosion resistance. For use in paper coatings, overprint varnishes, general metal and plastic finishes. XL-19: Percent (%) Non-Volatile by Weight: 40 Translucent Dispersion Viscosity cps, 25C: 35 pH: 7.8 Acid Number: 32 Glass Transition Temp., C: 26 Sward Hardness/Pencil Hardness: 21/2B Weight per Gallon: 8.8 Lower carboxyl content polymer with broad FDA acceptability. Superior water resistance, adhesion and flexibility on paper, foil and films. XL-30: Percent (%) Non-Volatile By Weight: 35 Translucent Dispersion Viscosity cps, 25C: 100 pH: 7.8 Acid Number: 32 Glass Transition Temp., C: 55 Sward Hardness/Pencil Hardness: 30/H Weight per Gallon: 8.8 Harder version of XL-19 with improved block resistance. For use in paper and paperboard coatings where broad FDA acceptability is required.

164

Water-Soluble Resins

B. F. GOODRICH CO.: CARBOSET High Performance Polymers for Graphic Arts, Electronics and Coatings(Continued): Water Dispersion Products(Continued): XL-33: Percent (%) Non-Volatile By Weight: 37.5 Translucent Dispersion Viscosity cps, 25C: 250 pH: 7.8 Acid Number: 32 Glass Transition Temp., C: 55 Sward Hardness/Pencil Hardness: 32/H Weight per Gallon: 8.8 Excellent adhesion to flexible vinyls. Recommended for vinyl substrate inks and overprints where block resistance is required. XL-37: Percent Non-Volatile By Weight: 35 Translucent Dispersion Viscosity cps, 25C: 100 pH: 7.0 Acid Number: 75 Glass Transition Temp., C: 42 Sward Hardness/Pencil Hardness: 26/HB Weight Per Gallon: 8.8 Excellent adhesion to treated polyethylene. Recommended pigment grinding vehicle for inks and coatings.

as

XL-52: Percent (%) Non-Volatile By Weight: 37 Clear Dispersion Viscosity cps, 25C: 500 pH: 7.0 Acid Number: 63 Glass Transition Temo.. C: 3 Sward Hardness/Pencil Hardness: 1/5B Weight Per Gallon: 8.8 Soft flexible coatings with adhesion to metals, plastics, paper. Recommended as pigment dispersant and tackifier.

B.F. Goodrich Co.

B. F. GOODRICH CO.: CARBOSET High Performance Polymers for Graphic Arts, Electronics and Coatings(Continued): Water Dispersion Products(Continued): 514Fi: Percent (%) Non-Volatile By Weight: 40 Translucent Dispersion Viscosity cps, 25C: 350 pH: 7.0 Acid Number: 65 Glass Transition Temp., C: 28 Sward Hardness/Pencil Hardness: 24/2B Weight Per Gallon: 8.7 Versatile general coatings polymer. Excellent balance of properties. Recommended for all applications. 531:

Percent (%) Non-Volatile By Weight: 25 Clear Dispersion Viscosity cps, 25C: 16,000 pH: 7.0 Sward Hardness/Pencil Hardness: 32128 Weight Per Gallon: 8.8 Thermosetting acrylic polymer. Recommended inks and coatings.

for heat curable

5338: Percent (%) Non-Volatile By Weight: 36 Milky Dispersion Viscosity cps, 25C: 100 pH: 8.5 Weight Per Gallon: 9.0 Hard thermosetting acrylic polymer. For use as modifier for RFL tire cord adhesives and thermoformable binders.

165

166

Water-Soluble Resins

B. F. GOODRICH CO.: CARBOSET High Performance Polymers for Graphic Arts, Electronics and Coatings(Continued): Specialty Products: 514A: Percent Non-Volatile By Weight: 70 Clear Solution Viscosity cps, 25C: 25,000 Percent (%) Volatiles: 30 Isopropanol Acid Number: 65 Glass Transition Temp., C: 28 Sward Hardness/Pencil Hardness: 24/2B Weight Per Gallon: 8.6 Same polymer as 514H except supplied in isopropanol. For use in solvent and water/solvent formulations. 515: Percent (%) Non-Volatile By Weight: 99 Clear Viscous Liquid Viscosity cps, 25C: 2,000,OOO Acid Number: 63 Glass Transition Temp., C: -14 Weight Per Gallon: 9.2 Soft low molecular weight polymer. For use as modifier where improved tack, flexibility and water resistance are required. Dry Products: XL-27: Percent ($1 Non-Volatile By Weight: 99 Solid Flake MEK Solution Viscosity (cps) 40% weight solids, 25C: 166 Acid Number: 80 Glass Transition Temp., C: 54 Sward Hardness/Pencil Hardness: 32/2B Specific Gravity: 1.18 Forms hard, glossy coatings. Broad solvent solubility and co-resin compatibility. For coatings on metals, plastic, paper.

E.F. Goodrich Co.

167

B. F. GOODRICH CO.: CARBCSET High Performance Polymers for Graphic Arts, Electronics and Coatings(Continued): Dry Products(Continued): XII-44: Percent Non-Volatile By Weight: 99 Solid Flake MEK Solution Viscosity (cps) 40% weight solids, 25C: 88 Acid Number: 75 Glass Transition Temp., C: 42 Sward Hardness/Pencil Hardness: 26/HB Specific Gravity: 1.13 Excellent piqment qrindinq vehicle. Broad solubilitv and compatibility-suggest-use in-general coatings and printing ink formulations. 525:

Percent I%) Non-Volatile Bv Weiuht: 99 Solid Flake MEK Solution Viscosity (CPS) 40% weisht solids, 25C: 1640 Acid Number: 80 Glass Transition Temp., C: 37 Sward Hardness/Pencil Hardness: 24/HB Specific Gravity: 1.17 High molecular weight polymer with balance of flexibility, hardness and adhesion properties. For general purpose coatings. 526:

Percent (%) Non-Volatile By Weight: 99 Solid Flake MEK Solution Viscosity (cps) 40% weight solids, 25C: 6360 Acid Number: 100 Glass Transition Temp., C: 70 Sward Hardness/Pencil Hardness: 40/3H Specific Gravity: 1.18 Very hard high molecular weight polymer. For use as modifier to improve block resistance, abrasion resistance and hardness.

168

Water-Soluble

Resins

B.F. GOODRICH CO.: GEON Vinyl Chloride Latexes: General Description: GEON Latex: -151: Vinyl chloride homopolymer 351: Vinyl chloride copolymer 352: Vinyl chloride copolymer 460X6: Heat-reactive vinyl chloride copolymer 552: Plasticized with nitrile rubber latex 575X43: Plasticized with 25 phr of phosphate plasticizer flame-retardancy

for

576: Plasticized with 35 phr of dioctyl phthalate 577: Plasticized with 35 phr of phosphate plasticizer retardancy

for flame-

580X119: Plasticized with 65 phr of dioctyl phthalate 580X158: Plasticized with 30 phr of dioctyl phthalate 590X4: Heat-reactive, plasticized with 25 phr of phosphate plasticizer for flame-retardancy 450X60: Carboxy-modified

vinyl chloride copolymer

460X45: Heat-reactive

vinyl chloride copolymer

460X46: Heat-reactive

vinyl chloride copolymer

650X17: Vinylidene chloride--vinyl 660X13: Heat-reactive

chloride copolymer

vinylidene chloride--acrylic

copolymer

8. F. Goodrich Co.

B.F. GOODRICH CO.: GECN Vinyl Chloride Latexes(Continued): GEON Latex: -.--Resin: 151: Total Solids %: 56 Latex Specific Gravity: 1.18 pH: 10.0 Surface Tension dynes/cm: 42 Glass Transition Temp. (Tg) C: +85 Brookfield Viscosity mPa.s (cP): 25 351: Total Solids %: 56 Latex Specific Gravity: 1.16 pH: 10.5 Surface Tension dynes/cm: 39 Glass Transition Temp. (Tg) C: +62 Brookfield Viscosity mPa.s (cP): 20 352: Total Solids %: 56 Latex Specific Gravity: 1.16 pH: 10.5 Surface Tension dynes/cm: 41 Glass Transition Temp. [Tg) C: +69 Brookfield Viscosity mPa.s (cP): 20 460X6: Total Solids %: 49 Latex Specific Gravity: 1.15 pH: 3.7 Surface Tension dynes/cm: 33 Glass Transition Temp. (Tg) C: +73 Brookfield Viscosity mPa.s (cP): 16 Plastic: 552: Total Solids %: 57 Latex Specific Gravity: 1.09 pH: 10.0 Surface Tension dvneslcm: 35 Glass Transition &, (Tg) C: +4 Brookfield Viscosity mPa.s (cP): 17 MVTR:

18

169

170 Water-Soluble Resins

B.P. GOODRICH: GEON Vinyl Chloride Latexes(Continued): GEON Latex: --Plastic(Continued): 575x43: Total Solids %: 56 Latex Specific Gravity: 1.14 pH: 10.0 Surface Tension dynes/cm: 35 Glass Transition Temp. (Tg) C: +31 Brookfield Viscosity mPa.s (cP): 20 576: Total Solids %: 57 Latex Specific Gravity: 1.12 pH: 9.8 Surface Tension dvnes/cm: 37 Glass Transition Temp. (Tg) C: +I4 Brookfield Viscosity mPa.s (cP): 40 MVTR: 12 577: Total Solids %: 56 Latex Specific Gravity: 1.14 pH: 9.7 Surface Tension dynes/cm: 34 Glass Transition Temp. (Tg) C: +I9 Brookfield Viscosity mPa.s (cP): 35 580X119: Total Solids %: 57 Latex Specific Gravity: 1.10 pH: 9.8 Surface Tension dynes/cm: 33 Glass Transition Temp. (Tg) C: -15 Brookfield Viscosity MPa.s (cP): 30 580X158: Total Solids %: 55 Latex Specific Gravity: 1.13 pH: 9.6 Surface Tension dynes/cm: 36 Glass Transition Temp. (Tg) C: +23 Brookfield Viscosity mPa.s (cP): 30 590x4: Total Solids %: 51 Latex Specific Gravity: 1.13 pH: 5.4 Surface Tension dynes/cm: 33 Glass Transition Temp. (Tg) C: +20 Brookfield Viscosity mPa.s (cP): 20

B.F. Goodrich Co.

B.F. GOODRICH CO.: GEON Vinyl Chloride Latexes(Continued): GEON Latex: --Internally Plasticized: 450X60: Total Solids %: 54 Latex Specific Gravity: 1.12 pH: 5.5 Surface Tension dynes/cm: 41 Glass Transition Temp. (Tg) C: +37 Brookfield Viscosity nPa.s (cP): 40 460X45: Total Solids %: 49 Latex Specific Gravity: 1.12 pH: 5.0 Surface Tension dvnes/cn: 36 Glass Transition Temp. (Tg) C: +26 Brookfield Viscosity nPa.s (cP): 40 MVTR: 23 460X46: Total Solids %: 49 Latex Specific Gravity: 1.09 pH: 5.0 Surface Tension dynes/cm: 36 Glass Transition Temp. (Tg) C: +7 Brookfield Viscosity nPa.s (cP): 40 MVTR: 21 Vinylidene Chloride: 650X17: Total Solids %: 53 Latex Specific Gravity: 1.21 pH: 8.3 Surface Tension dvneslcm: 40 Glass Transition Temp. (Tg) C: +I5 Brookfield Viscosity nPa.s (cP): 10 MVTR: 1.3 660X13: Total Solids %: 53 Latex Specific Gravity: 1.21 pH: 5.0. Surface Tension dynes/cm: 44 Glass Transition Temp. (Tg) C: +7 Brookfield Viscosity mPa.s (cP): 50 MVTR: 1.3 Emulsifier Type: synthetic anionic

171

172

Water-Soluble Resins

B.F. GOODRICH CO.: GOOD-RITE SB and Vinyl Pyridine Latexes: GOOD-RITE Styrene-Butadiene: 2570x59: Glass Transition Temp. (Tg), C: -20 Emulsifier: SA Total Solids, %: 52 Specific Gravity of Latex: 1.00 pH: 7.5 Surface Tension, dynes/cm: 36 Brookfield Viscosity, cP: 50 Relative Particle Size: medium Special Properties: Carboxy-modified. Low viscosity, high total solids. Typical Applications: General purpose coatings, carpet backings, adhesives. Paper saturation. Tie coat for tape. 1800X73: Glass Transition Temp. (Tg), C: +lO Emulsifier: SP Total Solids, %: 40 Specific Gravity of Latex: 1.01 DH:

9.0

Surface Tension, dynes/cm: 70 Brookfield Viscosity, cP: 50 Relative Particle Size: Medium Special Properties: Reactive. Colloidal system essentially free of emulsifiers and other water-sensitive ingredients. Typical Applications: General purpose coatings, metal coatings, textile sizing. Salt and corrosion-resistant coatings Emulsifier type: SA--synthetic anionic SP--special FA--fatty acid

B. F. Goodrich Co.

173

B. F. GOODRICH CO.: GOOD-RITE SB and Vinyl Pyridine Latexes (Continued): GOOD-RITE SB Vinyl Pyridine: 2508:

Glass Transition Temp. (Tg), C: -48 Emulsifier: FA Total Solids, %: 38 Specific Gravity of Latex: 0.98 pH: 10.4 Surface Tension, dynes/cm: 49 Brookfield Viscosity, cp: 20 Relative Particle Size: small Special Properties: High adhesion to rubber. Stable RFL dips. Typical Applications: Adhesives, tire cord and chafer fabric dips, industrial rubber goods. 2528X10: Glass Transition Temp. (Tg), C: -48 Emulsifier: SA Total Solids, %: 41 Specific Gravity of Latex: 0.98 pi-l:10.2 Surface Tension, dynes/cm: 50 Brookfield Viscosity, cp: 20 Relative Particle Size: small Special Properties: Excellent adhesion and adhesion retention in RFL dips. Good chemical, mechanical, and shelf stability. Wickproof fabric in one pass. Emulsifier type: SA--synthetic anionic SP--special FA--fatty acid

174

Water-Soluble Resins

B.F. GOODRICH CO.: HYCAR Acrylic Latexes: HYCAR acrylic latexes are uniform colloidal dispersions of acrylate polymers and copolymers in water. They are true colloids, having spherical particles, usually of 0.2 micron average diameter. These latexes contain no solvents to cause flammabilility or toxicity hazards during processing. Certain properties are common to HYCAR acrylic latexes as a class of polymers. All have excellent heat and light aging stability. They are stable in processing and are compounded easily. All have excellent adhesive properties. In their manufacture, these basic properties are varied in chemical design for the following uses: Nonwoven binders Pigment binders Flock adhesives Textile coatings Textile finishes Wear coatings, flooring Pressure-sensitive adhesives Packaging systems Heat sealable adhesives

Paper saturants Wet end additives Clear coatings ._Leather finishes Paper coatings - Adhesive for glass fibers Permanent press finishes Laminating adhesives Fiberglass sizing release coatings Release coatings, tape

HYCAR latexes: ----_ Very Soft: 26146: Glass Transition Temperature Tg, C: -55 Total Solids, %: 50 Specific Gravity of Latex: 0.99 pH: 7.3 Surface Tension, dynes/cm: 44 Brookfield Viscosity, mPa.s (cP): 125 26171: Glass Transition Temperature Tg, C: -43 Approximate Total Solids, %: 50 Specific Gravity of Latex: 1.03 pH: 2.4 Surface Tension, dynes/cm: 45 Brookfield Viscosity, mPa.s (cP): 135

8. F. Goodrich Co.

B.F. GOODRICH CO.: HYCAR Acrylic LatexestContinued): HYCAR ----: latexes. Soft: 26322: Glass Transition Temperature Tg, C: -15 Total Solids, %: 51 Specific Gravity of Latex: 1.06 pH: 6.0 Surface Tension, dynes/cm: 38 Brookfield Viscosity, mPa.s (cP): 40 26083:

Glass Transition Temperature Tg, C: -15 Total Solids, %: 52 Specific Gravity of Latex: 1.07 pH: 6.1 Surface Tension, dynes/cm: 36 Brookfield Viscosity, mPa.s (cP): 60 Medium: 26092:

Glass Transition Temperature Tg, C: -12 Total Solids, %: 50 Specific Gravity of Latex: 1.06 pH: 4.0 Surface Tension, dynes/cm: 42 Brookfield Viscosity, mPa.s (cP): 125 2671:

Glass Transition Temperature Tg, C: -11 Total Solids, %: 53 Specific Gravity of Latex: 1.07 pH: 5.1 Surface Tension, dynes/cm: 38 Brookfield Viscosity, mPa.s (cP): 170 26120:

Glass Transition Temperature Tg, C: -11 Total Solids, %: 50 Specific Gravity of Latex: 1.07 pH: 3.8 Surface Tension, dynes/cm: 48 Brookfield Viscosity, mPa.s (cP): 115

175

176

Water-Soluble Resins

B.F. GOODRICH: HYCAR Acrylic Latexes(Continued): HYCAR latexes: ----Medium(Continued): 2679: Glass Transition Temperature Tg, C: -3 Total Solids, %: 49 Specific Gravity of Latex: 1.06 pH: 3.7 Surface Tension, dynes/cm: 43 Brookfield Viscosity, mPa.s (cP): 100 Firm: 26796: Glass Transition Temperature Tg, C: -3 Total Solids, %: 40 Specific Gravity of Latex: 1.07 pH: 4.8 Surface Tension, dynes/cm: 44 Brookfield Viscosity, mPA.s (cP): 120 26084:

Glass Transition Temperature Tg, C: +8 Total Solids, %: 48 Specific Gravity of Latex: 1.07 pH: 6.1 Surface Tension, dynes/cm: 37 Brookfield Viscosity, mPa.s (cP): 110 Stiff: 26138: Glass Transition Temperature Tg, C: +25 Total Solids, %: 50 Specific Gravity of Latex: 1.07 pH: 5.5 Surface Tension, dynes/cm: 43 Brookfield Viscosity, mPa.s (cP): 165

8.F. Goodrich Co.

B.F. GOODRICH CO.: HYCAR Acrylic Latexes(Continued): HYCAR latexes: --Hard: 26106: Glass Transition Temperature Tg, C: +29 Total Solids, %: 50 Specific Gravity of Latex: 1.05 pH: 5.0 Surface Tension, dynes/cm: 37 Brookfield Viscosity, mPa.s (cP): 80 26172:

Glass Transition Temperature Tq, C: +33 Total Solids, %: 50 Specific Gravity of Latex: 1.05 ps: 2.5 Surface Tension, dynes/cm: 50 Brookfield Viscosity, mPa.s (cP): 125

177

178 Water-Soluble Resins

B.F. GOODRICH CO.: HYCAR Nitrile Latexes: HYCAR nitrile latexes are uniform colloidal dispersions of acrylonitrile/butadiene copolymers in water. They are true colloids, having spherical particles, ranging in size from 0.06 microns to 0.25 microns in diameter. These latexes contain no solvents to cause flammability or toxicity hazards during processing. HYCAR Latex: ---___ 1552: Glass Transition Temperature (Tg) (C): -26 Total Solids %: 53 pH: 10.5 Soap Type: FA Surface Tension: 40 Brookfield Viscosity (cP): 35 Mooney (4 min.): 90 (ml) Particle Size: Large 1561: Glass Transition Temperature (Tg) (C): -19 Total Solids %: 41 pH: 10.5 Soap Type: FA Surface Tension: 50 Brookfield Viscositv (cP1: 25 Mooney (4 min.): 110 (mlj Particle Size: Small 1561X87: Glass Transition Temperature (Tg) (C): -19 Total Solids %: 41 pH: 10.5 Soap Type: FA Surface Tension: 47 Brookfield Viscosity (cP): 12 Mooney (4 min.): 100 (ms) Particle Size: Small 1562:

Glass Transition Temperature (Tg) (C): -26 Total Solids %: 41 pH: 10.5 Soap Type: FA Surface Tension: 45 Brookfield Viscosity (cP): 30 Mooney (4 min.): 95 (ml) Particle Size: Small Key: FA--Fatty Acid

RA--Rosin Acid

SA--Synthetic

Anionic

B. F. Goodrich Co.

BF GOODRICH: HYCAR Nitrile Latexes(Continued): HYCAR Latex: __-~ 1562X103: Glass Transition Temperature (Tg) (C): -26 Total Solids %: 41 pH: 10.5 Soap Type: RA Surface Tension: 45 Brookfield Viscosity (cP): 15 Mooney (4 min.): 65 (ml) Particle Size: Small 1562X117: Glass Transition Temperature (Tg) (C): -26 Total Solids %: 41 pH: 10.5 Soau Tvne: RA Surface*Tension: 55 Brookfield Viscosity (cP): 15 Mooney (4 min.): 125 (ms) Particle Size: Small 1562X159: Glass Transition Temperature (Tg) (C): -26 Total Solids %: 41 pH: 10.5 Soap Type: SA Surface Tension: 45 Brookfield Viscosity (cP): 50 Mooney (4 min.): 60 (ml) Particle Size: Small 1562X160: Glass Transition Temperature (Tg) (C): -14 Total Solids %: 35 pH: 10.5 Soap Type: SA Surface Tension: 60 Brookfield Viscosity (cP): 15 Mooney (4 min.): 100 (ms) Particle Size: Small 1570x55: Glass Transition Temperature (Tg) (C): -48 Total Solids %: 45 pH: 9.0 Soap Type: SA Surface Tension: 45 Brookfield Viscosity (cP): 20 Mooney (4 min.): 70 (ms) Particle Size: Medium Key: FA--Fatty Acid

RA--Rosin Acid

SA--Synthetic

Anionic

179

180

Water-Soluble Resins

B.F. GOODRICH CO.: HYCAR NITRILE Latexes(Continued): HYCAR Latex: ----1571:

Glass Transition Temperature (Tg) (C): -16 Total Solids %: 43 pH: 8.5 Soap Type: SA Surface Tension: 30 Brookfield Viscosity (cP): 30 Mooney (4 min.): 110 (ms) Particle Size: Medium 15 ‘2:

Glass Transition Temperature (Tg) (C): -27 Total Solids %: 50 pH: 7.0 Soap Type: SA Surface Tension: 45 Brookfield Viscosity (cP): 30 Mooney (4 min.): 125 (ms) Particle Size: Medium 1572X64: Glass Transition Temperature (Tg) (C): -30 Total Solids %: 47 pH: 6.5 Soap Type: SA Surface Tension: 45 Brookfield Viscosity (cP): 85 Mooney (4 min.): 115 (ms) Particle Size: Medium 1578X1: Glass Transjtion Temperature (Tg) (C): +18 Total Solids %: 50 pH: 8.0 Soap Type: SA Surface Tension: 42 Brookfield Viscosity (cP): 20 Particle Size: Large Key: FA--Fatty Acid

RA--Rosin Acid

SA--Synthetic

Anionic

B. F. Goodrich Co.

B. F. GOODRICH CO.: HYSTRETCH Elastomeric

Latexes:

V-60: Glass Transition Temp. (Tg), C: -60 Emulsifier: SP Total Solids, %: 50 Specific Gravity of Latex: 1.01 pH: 7.0 Surface Tension, dynes/cm: 44 Brookfield Viscosity, cP: 40 v-43: Glass Transition Temp. (Tg), C: -43 Emulsifier: SP Total Solids, %: 50 Specific Gravity of Latex: 1.03 pH: 8.5 Surface Tension, dynes/cm: 40 Brookfield Viscosity, cP: 200 v-29

:

Glass Transition Temp. (Tg), C: -29 Emulsifier: SP Total Solids, %: 49 Specific Gravity of Latex: 1.04 pH: 5.0 Surface Tension, dynes/cm: 42 Brookfield Viscosity, cP: 70 Special Properties: Soft hand with high strength and low tack. Highly elastic films will contribute memory and durability to substrate. Typical Applications: Saturants or coatings for textiles, paper and non-wovens requiring memory and resiliency. Emulsifier Type: SP--special

181

182

Water-Soluble Resins

GOODYEAR

CHEMICALS:

CHEMIGUM

Nitrile Latices:

CHEMIGUM latices are copolymers of acrylonitrile and butadiene. Properly cured, these latices are noted for resistance to oils, greases, alcohols, glycols, aromatic and aliphatic solvents. They are used extensively in applications requiring both resistance to these agents and inherent elastomeric properties, particularly where the latex form (water dispersion) is an advantage. CHEMIGUM latices, which can be used in either a vulcanized or an unvulcanized state, are extremely tough and resilient. They exhibit a unique balance of tensile strength (when vulcanized), low compression set, high elongation and good tear resistance. This class of nitrile latices also demonstrates good washability, high abrasion resistance, excellent long term aging, adhesion to hydrophilic materials and compatibility with polar resins such as copolymers of vinyl chloride and vinylidine chloride. Specific properties may generally be varied with the type and degree of vulcanization. All CHEMIGUM latices are protected with non-staining, nondiscoloring antioxidant. CHEMIGUM LCGClG: Bound Acrylonitrile High Total Solids %: 40.0 Emulsifier: RA A.O.: Non-Staining pH: 10.5 Viscosity Cps (Typical): 25 Surface Tension Dynes/Cm: 36 Mooney Viscosity (M/S-212F-1.5'): loo-135 CHEMIGUM 260: Medium with Styrene Total Solids %: 34.0 Emulsifier: Syn Anionic A.O.: Non-Staining pH: 10.5 Viscosity Cps (Typical): 20 Surface Tension Dynes/Cm: 60 Mooney Viscosity (M/S-212F-1.5'): 75-95 CHEMIGUM 520: Medium Carboxylated Total Solids %: 50.0 Emulsifier: Syn Anionic A.O.: Non-Staining pH: 8.0 Viscosity Cps (Typical): 75 Surface Tension Dynes/Cm: 33 CHEMIGUM LCG 3845: Low Carboxylated with Styrene Total Solids %: 41.5 Emulsifier: Syn Anionic A.O.: Non-Staining pH: 9.5 Viscosity Cps (typical): 35 Surface Tension Dynes/Cm: 42

Goodyear Chemicals

183

GOODYEAR CHEMICALS: GOODYEAR Textile Resin Latex: The GOODYEAR resin latex products group is designed for textile . applications with the major markets of carpet lamination, carpet precoat and fabric backcoating. In addition these products are used as sprayable binders, tape base saturants, and binders for miscellaneous adhesive and coating applications. These products are carboxylic acid modified copolymers of styrene and butadiene with variations in bound styrene content to provide the hand required for the major market applications. In the major market, the carpet market, these products are applied by conventional and froth lamination techniques. LPR-6632: 'Approximate Monomer Composition: 63/37 (STY/BD) Total Solids: 52.0% pn: a.7 Brookfield Viscosity (cps): 150 Styrene Tension (dynes/co): 55.0 Emulsifier: Syn Anionic A.O.: Non-Staining Properties: Carboxylated, firm hand Applications: Carpet backing, adhesives LPR-6640: Approximate Monomer Composition: 57/43 (STY/BD) Total Solids: 52.0% pH: 8.7 Brookfield Viscosity (cps): 180 Surface Tension (dynes/co): 57.0 Emulsifier: Syn Anionic A.O.: Non-Staining Properties: Carboxylated, soft hand Applications: Carpet backing, adhesives LPR-6735: Approximate Monomer Composition: 60/40 (STY/BD) Total Solids: 52.0% pH: 8.7 Brookfield Viscosity (cps): 165 Surface Tension (dynes/co): 56.0 Emulsifier: Syn Anionic A-0.: Non-Staining Properties: Carboxylated, medium hand Applications: Carpet backing, adhesives

184

Water-Soluble

Resins

GOODYEAR CHEMICALS: PLIOCORD Vinyl Pyridine Latex: The PLIOCORD vinyl pyridine latex product line is a specialty product group used specifically to provide adhesion between rubber stocks and fabric reinforcement materials in the fabrication of tires, conveyor belts, hoses and other industrial rubber products. The major applications for PLIOCORD products are in the tire industry where PLIOCORD latex is used in formulations with resorcinol-formaldehyde resins to produce dip systems for nylon, polyester, fiberglass and aramid fabrics for tire cord or for chafer fabric applications to provide the required adhesion. PLIOCORD 4666 is a standard product in the tire industry. PLIOCORD 5622 was developed for fiberglass cord impregnation. LVP-4668: Approximate Monomer Composition: 15/70/15 (STY/BD/VP) Total Solids: 42.0% pH: 11.5 Brookfield Viscosity (cps): 60 Surface Tension (dynes/co): 51.0 Mooney Viscosity (M/L-212F-4'): 32-48 Emulsifier: Mixed Acid A.O.: None Properties: Medium Mooney, good compound & mechanical stability Applications: Fabric to rubber adhesion in hoses, belts and all non-fiberglas tire cord dips LVP-5263: Approximate Monomer Composition: 19/7O/ll (STY/BD/VP) Total Solids: 41.5% pH: 11.5 Brookfield Viscosity (cps): 50 Surface Tension (dynes/co): 52.0 Mooney Viscosity (M/L-212F-4'): NA Emulsifier: Mixed Acid A.O.: None Properties: Lower VP content, good compound & mechanical stability Applications: Fabric to rubber adhesion in hoses, belts and ann non-fiberglas tire cord dips LVP-5622: Approximate Monomer Composition: 15/70/15 (STY/BD/VP) Total Solids: 41.0% pH: 10.5 Brookfield Viscosity (cps): 80 Surface Tension (dynes/co): 52.0 Mooney Viscosity (M/L-212F-4'): 65-90 Emulsifier: Mixed Acid Properties: High Mooney, good compound & mechanical stability Applications: Fabric to rubber adhesion in fiberglass tire cord dips

Goodyear Chemicals

185

GOODYEAR CHEMICALS: PLIOLITE Solution Resins: PLIOLITE solution resins are emulsion copolymers used by the coatings industry as binders for a wide variety of products. They are excellent binders for all types of masonry and concrete paints, sealers, curing membranes, industrial maintenance finishes, metal primers, and paints for swimming pools and traffic marking. They serve as a base for high-speed printing inks and silk screen inks. PLIOLITE resins are modified for moistureproof paper coatings of glassine, bleached krafts, paperboard, films and foils. They also are used in the manufacture of dry toners for electrostatic copying. These resins dry rapidly to form tough, hard films that adhere to many different substrates. They have resistance to chemicals, water, and ultra-violet light. They also have particularly good resistance to fats and oils. PLIOLITE S-5 is a high styrene/butadiene copolymer, used in concrete interior enamels, exterior masonry paints, concrete curing membranes, fill coats, corrosion resistant maintenance paints, paper coatings, and durable road marking paints. It is available in a variety of viscosity ranges and color bases for formulation of coatings applied by brush, roller, dip or spray. PLIOLITE S-5 has excellent alkali resistance. The resin dissolves readily in aromatic solvents as well as in mixtures of aromatic and aliphatic solvents with a minimum KB value of 60. The PLIOLITE AC resins are high styrene/acrylate copolymers and are available in two viscosity ranges. Like the PLIOLITE S-5 resins, the PLIOLITE AC resins are soluble in 60 KB solvent systems. The PLIOLITE AC resins are differentiated from the S-5 resins by their superior W resistance. PLIOLITE AC-80 is a styrene/acrylate resin which offers the greatest UV resistance of the PLIOLITE family of resins. PLIOLITE AC-4 is a polymeric rheology modifying resin, which is a homolog of PLIOLITE AC-80. PLIOLITE VT resins are vinyl-toluene/butadiene copolymers whose outstanding feature is solubility in aliphatic solvents with a minimum KB of 38. Films produced with these resins have unusual clarity, strength, hardness and chemical resistance. Areas of application for the PLIOLITE VT resins include traffic paints, block fillers, paper coatings, adhesives, laminates, printing inks, hot melts, multicolor finishes and abrasion-resistant coatings. The PLIOLITE VTAC resins are vinyl-toluene/acrylate copolymers. Like the PLIOLITE VT resins, they are soluble in aliphatic solvents with a minimum KB of 38. The VTAC resins are superior to the VT resins for resistance to UV light. Areas of application for the PLIOLITE VTAC resins include texture coatings, interior and exterior masonry paints and intumescent fire-retardant paints. PLIOLITE AC-3 is a polymeric thickener which is similar in composition to PLIOLITE VTAC. Because polymeric thickeners become a part of the total binder, these resins (AC-3 or AC-41 can be used to reduce the amount of binder resin by replacing them on a volume basis.

186 Water-Soluble Resins

GOODYEAR CHEMICALS: PLIOLITE Solution Resins(Continued): PLIOLITE S-5A: White Friable Granules Specific Gravity: 1.05 Softening Point C (R&B): 155-165 Minimum Solvent Requirement (KB): 60 #4 Ford Cup Viscosity (set): 195-240 PLIOLITE S-5B: White Friable Granules Specific Gravity: 1.05 Softening Point C (R&B): 150-160 Minimum Solvent Requirement (KB): 60 #4 Ford Cup Viscosity (set): 160-195 PLIOLITE S-5D: White Friable Granules Specific Gravity: 1.05 Softening Point C (R&B): 150-160 Minimum Solvent Requirement (KB): 60 #4 Ford Cup Viscosity (set): loo-130 PLIOLITE S-5E: White Friable Granules Specific Gravity: 1.05 Softening Point C (R&B): 130-140 Minimum Solvent Requirement (KB): 60 #4 Ford Cup Viscosity (set): 30-60 PLIOLITE AC: White Friable Granules Specific Gravity: 1.04 Softening Point C (R&B): 155-165 Minimum Solvent Requirement (KB): 60 #4 Ford Cup Viscosity (set): 160-195 PLIOLITE AC-L: White Friable Granules Specific Gravity: 1.04 Softening Point C (R&B): 130-140 Minimum Solvent Requirement (KB): 60 #4 Ford Cup Viscosity (set): 35-55 PLIOLITE AC-4: White Friable Granules Specific Gravity: 1.06 Softening Point-C (R&B): ,190 Minimum Solvent Requirement (KB): 45 Viscosity: Thixotropic Gel

Goodyear Chemicals

GOODYEAR CHEMICALS: PLIOLITE Solution Resins(Continued): PLIOLITE AC-80: White Friable Granules Specific Gravity: 1.06 Softening point C (R&B): 135-145 Minimum Solvent Requirement (XB): 40 #4 Ford Cup Viscosity (set): 135-145 PLIOLITE AC-3: White Friable Granules Specific Gravity: 1.028 Minimum Solvent Requirement Viscosity: Thixotropic Gel

(KB): 38

PLIOLITE VT: White Friable Granules Specific Gravity: 1.026 Softening Point C (R&B): 155-165 Minimum Solvent Requirement (KB): 38 #4 Ford Cup Viscosity (set): 160-195 PLIOLITE VT-L: White Friable Granules Specific Gravity: 1.026 Softening Point C (R&B): 130-140 Minimum Solvent Requirement (KB): 38 #4 Ford Cup Viscosity (set): 30-70 PLIOLITE VTAC: White Friable Granules Snecific Gravitv: 1.03 Softening Point-C (R&B): 155-165 Mimimum Solvent Requirement (KB): 38 #4 Ford Cup Viscosity (set): 160-195 PLIOLITE VTAC-L: White Friable Granules Specific Gravity: 1.03 Softening Point C (R&B): 130-140 Minimum Solvent Requirement (KB): 38 #4 Ford Cup Viscosity (set): 25-50 PLIOLITE S-5 Bases: Pigmented Chips Minimum Solvent Requirement

(KB): 60

187

188

Water-Soluble Resins

GOODYEAR CHEMICALS: PLIOLITE SBR Rubber Latex: The PLIOLITE rubber latex product group consists of a family of high-solids styrene/butadiene copolymer latices. The major market applications for these products are spread foam on carpet or fabric, molded foam for automotive and home furnishing applications, washable backings for scatter rugs, binders for miscellneous mastic and adhesive formulations and asphalt modifiers for the construction industry. LPF-5356: Approximate Monomer Composition: 23.5/76.5(STY/BD) Total Solids: 69.5% pH: 10.0 Brookfield Viscosity (cps): 1,500 Surface Tension (dynes/co): 32.0 Properties: Low modulus, good mechanical & chemical stability Applications: Spread foam, molded foam, scatter rug, adhesives, asphalt modification LPF-6687: Approximate Monomer Composition: 31/69 (STY/BD) Total Solids: 69.5% pH: 12.3 Brookfield Viscosity (cps): 1,500 Surface Tension (dynes/co): 35.0 Properties: Extra high modulus Applications: Non-gel spread foam LPF-6733: Approximate Monomer Composition: 34/66 (STY/BD) Total Solids: 69.5% pH: 12.3 Brookfield Viscosity (cps): 1,800 Surface Tension (dynes/co): 35.0 Emulisifier: Mixed Acid Properties: Extra high modulus Applications: Non-gel spread foam, adhesives LPF-6758: Approximate Monomer Composition: 29/71 (STY/BD) Total Solids: 70.5% pH: 10.3 Brookfield Viscosity (cps): 1,500 Surface Tension (dynes/co): 35.0 Properties: High modulus Applications: Spread foam, adhesives LPF-2108: Approximate Monomer Composition: 29171 (STY/BD) Total Solids: 40.0% pH: 11.2 Brookfield Viscosity (cps): 30 Surface Tension (dynes/co): 60.0 Properties: Extra high Mooney Applications: Tire cord dip additive

Goodyear Chemicals

189

GOODYEAR CHEMICALS: PLIOLITE RR-D Water Reducible Thermoplastic Polymer: PLIOLITE WR-D is a water reducible thermoplastic polymer designed to replace solvent borne resins in demanding specialty and OEM coating applications. The unique chemistry of PLIOLITE WR-D provides for formulation of extremely tough, rapid-dry coatings. These coatings can be formulated to exceptionally high gloss, and demonstrate extremely early block resistance, low moisture vapor transmission rate (MVTR), an excellent alka li resistance. PLIOLITE WR-D is an aqueous dispersion of carboxylated styrene-acrylate polymer supplied at 45 solids by weight. PLIOLITE WR-D: 45% Aqueous Dispersion Specific Gravity: 1.025 Softening Point C (R&B): 130-145 Minimum Solvent Requirement (KB): Glycol Ether #4 Ford Cup Viscosity (set): 160-210## ## 40% solution in 88112 xylene/n-butanol

at 25C

190

Water-Soluble Resins

GOODYEAR CHEMICALS: WINGTACK Hydrocarbon

Resins:

WINGTACK resins were the first commercially available tackifying and modifying resins based on C5, hydrocarbon monomers. WINGTACK resins, because of their unique patented chemistry, can be used in many of the applications where most other hydrocarbon resins do not adequately perform. The WINGTACK resin's light color, high tack properties, low specific gravity, oxidative stability, and day to day consistency of properties make these resins excellent tackifiers for pressure sensitive adhesives. In addition to the above mentioned properties, low melt viscosity and good heat stability have resulted in quick acceptance in hot melt adhesives and coatings. WINGTACK resins are also currentlv being used as tackifiers and/or processing aids (to help in mixing,-molding, extruding) with EPDM, SBR, NATSYN, butyl, SIS, and a variety of other elastomers. WINGTACK 95 Resin: WINGTACK 95, a unique synthetic polyterpene resin, was developed for use in hot melt coatings, adhesives, rubber compounding, and various other applications. WINGTACK 10 Resin: WINGTACK 10 is a unique liquid resin developed as a plasticizer/tackifier. It also is chemically similar to WINGTACK 95 resin, yet is a polymeric liquid at room temperature. WINGTACK PLUS Resin: In some adhesive systems, especially SIS-based pressure sensitives, tack fall-off can be a problem unless the proper resin is used at carefully controlled levels. WINGTACK PLUS resin acts as a "buffer" to provide high, aggressive tack without the danger of tack loss after a period of time. The compounder can now add higher levels of WINGTACK PLUS (with less SIS) and maintain high tack, peel and shear sterngth. WINGTACK EXTRA Resin: WINGTACK EXTRA is an aromatically modified C5 resin designed to exhibit improved performance in a variety of applications while retaining the many excellent qualities of the other WINGTACK resin grades. WINGTACK 86 Resin: WINGTACK 86, a modified C5, petroleum hydrocarbon resin, has been specially developed for use as a tackifier in hot melt and pressure sensitive adhesives based on SBS, SBR, SIS and EVA copolymers. WINGTACK 115 Resin: WINGTACK 115 is quite similar to WINGTACK been polymerized to a high softening point.

95, except it has

Goodyear Chemicals

GOODYEAR CHEMICALS: WINGTACK: C5 Grade Hydrocarbon (Continued): WINGTACK 95: Light Yellow Flake Specific Gravity @ 25C: 0.93 Softening Point C (R&B): 95-101 Typical Gardner Color (50% Solution): WINGTACK 10: Light Yellow Liquid Specific Gravity @ 25C: 0.88 Softening Point C (R&B): lo-15 Typical Gardner Color (50% Solution): Viscosity, cps 8 25C: 20,000-40,000

3

3

WINGTACK PLUS: Light Yellow Flake Specific Gravity @25C: 0.93 Softening Point C (R&B): 93-100 Typical Gardner Color (50% Solution):

3

WINGTACK EXTRA: Light Yellow Flake Specific Gravity @ 25C: 0.96 Softening Point C (R&B): 94-100 Typical Gardner Color (50% Solution):

3

WINGTACK 86: Light Yellow Flake Specific Gravity @ 25C: 0.97 Softening Point C (R&B): 84-90 Typical Gardner Color (50% Solution):

2t

WINGTACK 115: Light Yellow Flake Specific Gravity @ 25C: 0.94 Softening Point C (R&B): 110-115 Typical Gardner Color (50% Solution):

5

Resins

191

192

Water-Soluble

Resins

W.R. GRACE I CO.: DARATAK Adhesive Emulsions: Borax Compatible Hompopolymers: 61L:

Medium viscosity, good water resistance, mastics % Total Solids: 55 Viscosity (cps): 2,000-4,000 pH: 4.0-5.5 Particle Size (microns): 1.0 Clarity: Clear Water Resistance: Excellent Tg C: 40

heat sealing, F/R

92L:

Hiuh viscositv. excellent water resistance, % Total Solids; 55 Viscosity (cps): 3,000-5,000 pH: 4.0-5.5 Particle Size (microns): 1.0 Clarity: Clear Water Resistance: Excellent Tg C: 40

clear film

Non-Borax Compatible Homopolymers: 55L: Medium molecular wt., high viscosity, solvents, acids & plasticizer % Total Solids: 55 Viscosity (cps): 3,000-4,000 pH: 4.5-6.0 Particle Size (microns): 1.5 Clarity: Slight haze Water Resistance: Good Tg C: 31

high speed, tolerates

56L Very high molecular wt., low viscosity, break % Total Solids: 55 Viscosity (cps): 300-600 pH: 5.5-7.0 Particle Size (microns): 1.0 Clarity: Slight haze Water Resistance: Good Tg C: 37

fast drying, quick

W. R. Grace & Co.

193

W.R. GRACE & CO.: DARATAK Adhesive Emulsions(Continued): Non-Borax Compatible Homopolymers(Continued): 62L: High molecular wt., high viscosity, tration to coated surfaces % Total Solids: 55 Viscosity (cps): 2,300-2,700 pH: 5-o-7.0 Particle Size (microns): 1.0 Clarity: Slight haze Water Resistance: Good Tg C: 35 65L: Medium molecular wt. and viscosity, ible with fully hydrolyzed PVOH % Total Solids: 55 Viscosity (cps): 1,400-2,000 pH: 4.5-5.5 Particle Size (microns): 1.5 Clarity: Slight haze Water Resistance: Good Tg C: 31

fast setting, good pene-

strong

tack, compat-

71L: Medium molecular wt., imparts fast grab to adhesives, ates larae amounts of solvents & ulasticizers. % Total Solids: 55 Viscosity 1co.s.):1.500-2.200 pH: 5.0-6.0 Particle Size (Microns): 1.5 Clarity: Slight haze Water Resistance: Good Tg (C): 35

toler-

95L: Medium molecular wt. and viscosity, strong wet tack, excellent compatibility with fully hydrolyzed PVOH % Total Solids: 55 Viscosity (cps): 2,000-4,000 pH: 4.5-5.5 Particle Size (microns): 1.5 Clarity: Slight haze Water Resistance: Good Tg C: 31

194

Water-Soluble

Resins

W.R. GRACE & CO.: DARATAK Adhesive Emulsions(Continued): Non-Borax Compatible Homopolymers(Continued): 17-200: Medium molecular wt., low-medium viscosity, superior compounding & machining % Total Solids: 55 Viscosity (cps): 1,500-2,000 pH: 4.5-6.0 Particle Size (microns): 1.5 Clarity: Slight haze Water Resistance: Fair Tg C: 31 17-230:

Medium-high viscosity version of 17-200 % Total Solids: 55 Viscosity (cps): 2,400-2,800 DH: 4.5-6-O Particle Size (microns): 1.5 Clarity: Slight haze Water Resistance: Fair Tg C: 31 17-300:

Hish viscositv version of 17-200 % Total Solids: 55 Viscosity (cps): 3,000-4,000 pH: 4.5-6.0 Particle Size (microns): 1.5 Clarity: Slight haze Water Resistance: Fair Tg C: 31

general purpose,

W. R. Grace & Co.

W.R. GRACE & CD.: DARATAK Adhesive Emulsions(Continued): Non-Borax Compatible Copolymers: A: Similar to "B" with greater hardness and less flexibility % Total Solids: 55 Viscosity (cps): l,OOO-1,400 pH: 4.0-5.0 Particle Size (microns): 1.5 Clarity: Clear Water Resistance: Excellent Tg C: 12 B: Excellent compounding properties, strates, good machining % Total Solids: 55 Viscosity (cps): l,OOO-1,400 pH: 4.0-5.0 Particle Size (microns): 1.5 Clarity: Clear Water Resistance: Excellent Tg C: 8

bonds to non-porous

Special & Blended Systems: 74L: Acrylic terpolymer; dries to permanently % Total Solids: 55 Viscosity (cps): 2,000-4,000 pH: 4.5-5.5 Particle Size (microns): 1.0 Clarity: Clear Water Resistance: Excellent Tg C: -18 83L: Fully compounded envelope back gum % Total Solids: 58 Viscositv (CDS): 2.900-3.500 pH: 3.0-4.0 . . Particle Size (microns): 1.0 Clarity: Cloudy Water Resistance: Poor

tacky film

sub-

195

196

W.R.

Water-Soluble Resins

GRACE & CO.: DARATAK Adhesive Emulsions(Continued):

89L: Dextrin compatible emulsion, reduced stringing, high speed, good lay flat, high gloss % Total Solids: 62 Viscosity (cps): 250 pH: 3.5-4.5 Particle Size (microns): 1.0 Clarity: Slight haze Water Resistance: Poor Tg C: 27 sp1012: Homopolymer emulsion; fast setting, non-borax compatible % Total Solids: 55 Viscosity (cps): 800-1,400 PH: 5-O-7.0 Particle Size (microns): 1.2 Clarity: Slight haze Water Resistance: Good Tg C: 36 SP1025: Uniquely plast icized copolymer emulsion; adhesion to vinyl, plastics, foil % Total Solids : 55 Viscosity (cps): 900-1,500 pH: 4.0-5.0 Particle Size (microns): 1.5 Clarity: Clear Water Resistance: Very Good Tg C: -2 sP1028: Plasticized homopolymer; fast setting, non-borax compatible % Total Solids: 55 Viscosiity (cps): 2,000-3,000 pH: 5.0-7.0 Particle Size (microns): 1.0 Clarity: Slight haze Water Resistance: Good Tg C: 23

W. R. Grace & Co.

197

W.R. GRACE & CO.: DARATAK Adhesive Emulsions(Continued): Special & Blended Systems(Continued1: sP1066: Plasticized homopolymer, useful in mastics & F/R paints, borax comoatible % Totai Solids: 55 Viscosity (ens): 900-1.500 pH: 4.5-5.5 Particle Size (microns): 1.0 Clarity: Slight haze Water Resistance: Very Good Tg C: 28 sp1071: Plasticized homopolymer, fast setting, clean machining, borax compatible % Total Solids: 55 Viscosity (cps): 1,700-2,200 pH: 4.5-6.5 Particle Size (microns): 1.5 Clarity: Slight haze Water Resistance: Very Good Tg C: 25 SPlOt39: Type III wood glue % Total Solids: 54 Viscosity (cps): 2,000-3,000 pH: 4.0-5.0 Particle Size (microns): 1.0 Clarity: Slight haze Water Resistance: Fair Tg C: 33 SP1500: Film-to-paper & foil-to-paper % Total Solids: 52 Viscosity (cps): l,OOO-3,000 pH: 6.0-7.5 Particle Size (microns): 1.0 Clarity: Cloudy Water Resistance: Excellent Tg C: 8

laminating adhesive

non-

198

Water-Soluble Resins

W.R. GRACE & CO.: DAREX Copolymer Latexes: 100 Series--Nitriles: 1lOL: Bu/An/Sy: % TS: 47% pH: 7.0 Tg: -38C MFT: 4C Designed specifically for paper and felt saturation, this latex imparts an unusual combination of high delamination resistance and edge tear. Suitable for sandpaper and tape bases, it provides superior oil, solvent and plasticizer resistance. Sy/An: % TS: 50 pH: 9.0 Tg: 102 Designed as a fiberglass bond coat, this tough, stiff latex improves the adhesion between fiberglass and the resin to be "reinforced." Good solvent resistance.

165L:

400

Series--Acrylates:

409L: AcryljAn: % TS: 42 pH: 7.5 Tg: 11 MFT: 24 This unique latex results in high gloss, block resistant coatings. It can be compounded to give excellent release against pressure sensitive adhesives used in many tape and label applications Sy/Acryl: % TS: 50 pH: 7.0 Tg: 44 MFT: 100 A styrene/acrylic latex that forms tough stiff films at elevated temperatures. When dried at temperatures below 9OC, webs saturated with this latex can be heat molded, at which time additional heat may be applied to crosslink the latex. 442L:

NOTE: As a general rule, DAREX latexes have the following physical properties: Viscosity: 30-200 CPS (Brookfield, 60 rpm. 25C) Surface Tension: 35-65 dynes/cm 2. Avg. Particle Size: O-1-0.2 microns Emulsifier: Synthetic Anionic (600 Series latexes contain rosin acid or fatty acid emulsifiers)

W. R. Grace & Co.

W. R. GRACE & CO.: EVERFLEXIVERSAFLEX

Paint/Coating

199

Emulsions:

BG: A very flexible, high molecular weight vinyl copolymer emulsion. BG combines excellent flow properties, low temperature coalescence and high flexibility to provide outstanding performance in exterior coatings for wood and masonry. % Total Solids: 51 Viscosity (cps): 200-500 pH: 4-O-6.5 Particle Size (microns): 1.5 Clarity: Excellent Water Resistance: Excellent MFT C: 0 Tg C: -15 G:

A high molecular weight permanently flexible vinyl acetate COD0 -. lymer emulsion. It offers excellent flow, holdout, flexibility and machining properties. Widely use in primers, sealers, and specialty coatings applications. % Total Solids: 52 Viscosity (cps): 300-700 pH: 4.0-6.5 Particle Size (microns): 1.5 Clarity: Excellent Water Resistance: Very Good MFT C: 3 Tg C: -7 GT:

A unique vinyl copolymer emulsion designed for high solids mastic compounds, caulks, sealants and joint cements. Its outstanding chemical and mechanical stability enebles the formulator to develop highly loaded compounds with excellent rheological characteristics % Total Solids: 55 Viscosity (cps): 1,500-3,000 pH: 4.0-6.5 Particle Size (microns): 1.0 Clarity: Excellent Water Resistance: Excellent MFT C: 4 Tg C: 6

200

Water-Soluble Resins

W.R. GRACE & CO.: EVERFLEX/VERSAFLEX (Continued):

Paint/Coating

Emulsions

MA: A unique, colloid-free microparticle size vinyl acrylic copolymer emulsion with excellent chemical and mechanical stability. Used as a vehicle for trade sales paints, factory finishes for wood and composition board, and in the coating and impregnations of paper and textiles. % Total Solids: 51 Viscosity (cps): 200-800 pH: 4.0-6.5 Particle Size (microns): 0.1 Clarity: Excellent Water Resistance: Excellent MFT C: 10 Tg C: 12 SP1084: A high molecular weight vinyl acetate copolymer emulsion. Widely used as concrete additive to improve adhesion and compressive strength. % Total Solids: 53 Viscosity (cps): 300-700 pH: 4.5-5.5 Particle Size (microns): 1.5 Clarity: Good Water Resistance: Good MFT C: 12 Tg C: 14 RC: An acrylic latex polymer designed for use in roof coating and mastic applications. Compounded, dry films exhibit excellent adhesion and ponded water resistance. % Total Solids: 55 Viscosity (cps): 500-1,800 pH: 4-O-6.0 Particle Size (microns): 0.15 Clarity: Excellent Water Resistance: Excellent MFT C: 3 Tg C: 0

W R.

W.

R. GRACE & CO.: RVERFLEX/VERSAFLEX (Continued):

VERSAFLEX Acrylic Paint/Coatings

Paint/Coating

Grace & Co.

201

Emulsions

Emulsions:

1: A versatile acrylic terpolymer designed specifically to prevent paint blistering and peeling soon after application and before the paint film is leached of its water extractables. It is then that paint films are most susceptible to loss of adhesion due to extreme condensation--heavy dew or prolonged rain. % Total Solids: 55 Viscosity (cps): 200-800 pH: 5.0-6.0 Particle Size (microns): 0.2 Clarity: Excellent Water Resistance: Excellent MFT C: 3 Tg C: 7

202 Water-Soluble Resins

H & C INDUSTRIES,

INC.: ALKOX Polyethylene

Oxide Resin:

ALKOX is a high molecular weight compound manufactured by chemically polymerizing ethylene oxide to the extent of lO,OOO-100,000 molecules. ALKOX is in white powder form with melting point around 66C, and is easily soluble in water and in a number of organic solvents. ALKOX has the characteristics of a strong thermosettinq resin and yet is soluble in water. These unique properties stem from the fact that ALKOX is exceedingly high in molecule and its ethylene oxide chains are extremely slippery and movable, and also that its crystallization is extremely high. On the other hand, ALKOX can also be processed as a low melting point thermoplastic resin & is compatible with most commonly used thermoplastic resins as follows: Polyethylene (Low Density) Polyethylene (High Density) Polyvinyl Acetate (PVAC) Polyvinyl Chloride (PVC) Polypropylene (PP) Polystyrene (PS) Poly-Methyl-Methacrylate Ethylene-Acrylonitrile

very good poor very good very good fair fair fair fair

General Properties: Chemical name: Polyethylene oxide Chemical structure: HO-(CH2CH20)n-CH2-CH2H Appearance: White to slightly yellowish granules Particle size: Less than 10 mesh Odor: Slightly aromatic Softening point: 65C-67C Brittle temperature: -50C Ash content, max.: Less than 1.5% Moisture content: Less than 2.0% pH (in aqueous solution): Slightly weak alkaline 7.2-7.5-(5% aq. sol'n) Viscosity (E-100): More than 500 cps (1% sol'n) Ionic activity: Nonionic Nature: Always even Price: Decreasing Solubility: Completely soluble and stable Compatibility: Wide Putrefaction: No change of quality Stability to metal: Does not sedimentate Resistance to bacterium: Strons Compatibility: Wide Elastic elongation of film: Good Solubility to organic solvent: Soluble in some solvents Film forming: Easy heat-sealing, good elongation and easy film forming To heat: Not become gel Solidifying point: Above 1OOC

Henkel

HENKEL: Developmental

Water Borne Polyamides:

GAX 11-966 and GAX 12-250: GAX 11-966 is a higher acid value version of GAX 12-250; acid values 95 and 50 respectively. GAX 11-966 gives lower solution viscosities, faster drying speed, better pigment wetting and improved gloss. GAX 12-250 exhibits excellent alkali resistance which suggests its use in cold seal overprint varnish and milk carton applications. These resins both exhibit excellent water resistance and excellent resolubility. GAX 12-201 and GAX 12-513: GAX 12-201 exhibits excellent adhesion to polyethylene, polypropylene and polyester packaging films. It also gives excellent water resistance, resolubility and organic pigment wetting. Inorganic pigments from ammonia water systems even with 20% alcohol only give fair results. GAX 12-513, a 150 acid value version, corrects this problem of inorganic pigment wettinq but qives reduced adhesion properties to the above films: It is recommended that GAX 72-513 be used as a pigment wetting resin and let down with GAX 12-201 for maxim&n properties. Since GAX 12-513 is also compatible with acrylic emulsions this dispersion can be let down with them for increased properties, i.e. toughness and resistance properties. GAX 11-966: GAX 11-966 is a polyamide resin that can be dissolved in ammonia or amine water systems with or without small levels of alcohol. It is a 95 Acid Value version of GAX 12-250 which gives GAX 11-966 lower solution viscosities promoting faster drying, better pigment wetting and improved gloss. lpical Properties: Acid Value: 95 SP c: 130 Water Resistance: Excellent Resolubility: Excellent Gloss: Excellent Drying Speed: Good

203

204

Water-Soluble Resins

HENKEL: Developmental

Water Borne Polyamides(Continued):

GAX 12-201: GAX 12-201 is a polyamide resin that can be dissolved in ammonia or amine water system with or without small levels of alcohol. It has the same 95 Acid Value as GAX 11-966, but has been formulated to give excellent water resistance and adhesion to polyethylene, polypropylene and polyester packaging films. Typical Properties: Acid Value: 95 SP c: 100 Water Resistance: Excellent Resolubility: Excellent Gloss: Excellent* Drying Speed: Very Good * organic pigments - okay inorganic pigments - low GAX 12-513: GAX 12-513 is a polyamide resin that can be dissolved in ammonia or amine water systems with or without small levels of alcohol. It is 150 Acid Value version of GAX 12-201. This gives it lower viscosity at higher solids and excellent inorganic and organic pigment wetting. Therefore, it could be used as a pigment grinding resin and let down with a polyamide like GAX 12-201 or acrylic emulsions. These formulations will give pigmented systems superior gloss as well as water resistance and adhesion to polyethylene, polypropylene and polyester packaging films. Typical Properties: Acid Value: 150 SP c: 100 Water Resistance: Excellent Drying Speed: Excellent Resolubility: Excellent Acrylic Resin Capability: Excellent Gloss: Excellent

Henkel

HENKEL: Developmental

Water Borne Polyamides(Continued):

GAX 12-250: GAX 12-250 is a polyamide resin that can be dissolved in ammonia or amine water systems with or without small levels of alcohol. Its low Acid Value of 50, gives it good properties for use in cold seal release overprint varnishes, metallic inks and milk carton applications: Typical Properties: Acid Value: 50 SP c: 160 Water Resistance: Excellent Alkali Resistance: Excellent Resolubility: Excellent Heat Resistance: Good Gloss: Good

205

206

Water-Soluble

Resins

HENKEL: G-CRYL Acrylic Resins: G-CRYL 130: Acrylic Resin Solution G-CRYL 130 is a 30% solids solution of G-CRYL 5001 solid acrylic resin in aqueous ammonia. It can be used to prepare alkali or detergent resistant ink, coating and overprint varnish vehicles with good resolubility and transfer properties. It can be used as the sole vehicle or be modified with other water soluble resins or acrylic emulsion polymers such as G-CRYL 1124, 1138 and 2000. Useful plasticizers include diethylene glycol, Butyl Carbitol and Polypropylene Glycol P-1200. Key Benefits: - High alkali and detergent resistance - Excellent water resistance - Good resolubility properties - Excellent pigment wetting and transfer properties - Broad compatibility range Typical Properties: Appearance: Clear, amber solution Non-volatile: 30+-l% Density: 8.8 lbs./gallon pH: 8.0-8.5 Viscositv. CDS: 1000-2000 Acid number ion solid): 135 Alcohol reducibility: Excellent Freeze/thaw stability: Excellent The formulation of G-CRYL 130 is:

Wt. % G-CRYL 5001 28% Ammonia n-Propanol Water

30.0 4.0 10.0 56.0

Henkel

207

HENKEL: G-CRYL Acrylic Resins(Continued): G-CRYL 1124: Acrylic Emulsion Polymer G-CRYL 1124 is a unique acrylic emulsion polymer designed for flexo/gravure ink and coatings applications. It is a soft, internally plasticized, film-forming emulsion which offers water, oil and grease resistance. It has excellent adhesion to foil, vaoer. wawerboard and wolv coated board and is recommended where.high gloss, water resistance and good transfer are key factors. In combination with G-CRYL 535 resin solution, G-CRYL 1124 offers outstanding high gloss overprint varnishes with good block resistance. Key Benefits: - Outstanding gloss - Excellent water, oil and grease resistance - Excellent adhesion to poly coated board and foil - Good pigment wetting and transfer characteristics - Broad compatibility range Typical Properties: Appearance: Translucent emulsion Non-volatile: 48+-j% pH: 8.0-8.5 Viscosity, cps: 300-1300 Density: 8.8 lbs./gallon Alcohol reducibility: Excellent Freeze/thaw stability: Excellent G-CRYL 1138: Acrylic Emulsion Polymer G-CRYL 1138 is a high gloss stvrenated acrylic emulsion polymer designed for flexo/gravure ink and coating applications. It is harder than G-CRYL 1124 and 2000 so that it has potentially better block resistance, making it ideal for paper/paperboard applications. This internally plasticized emulsion has very qood water and qrease resistance, good pigment wetting characteristics, and offers fast drying to accomodate various coating applications. G-CRYL 1138 is also an ideal candidate for high gloss overprint varnishes and functional coatings. Key Benefits: - High gloss - Good adhesion to various substrates - Good block resistance, drying speed and resolubility - Very good water and grease resistance - Good pigment wetting and transfer characteristics

208

Water-Soluble Resins

HENKEL: G-CRYL Acrylic Resins(Continued): G-CRYL 1138(Continued): Typical Properties: Appearance: Translucent emulsion Non-volatile: 46+-l% pH: 8.0-8.5 Viscosity, cps: 200-1000 Density: 8.8 lbs./gallon Alcohol reducibility: Excellent Freeze/thaw stability: Excellent G-CRYL 1139: Acrylic Emulsion Polymer G-CRYL 1139 is a styrenated acrylic emulsion polymer designed for flexo/gravure ink and coating applications. It is particularly designed to be used as a fast drying "let-down" vehicle to impart hardness, gloss and water resistance. G-CRYL 1139 can also offer outstanding low cost, high gloss overprint varnish formulations in combination with G-CRYL 1124 and G-CRYL 250. Key Benefits: - Fast drying speed - High gloss and clarity - Hardness, water and grease resistance - Broad compatibility range Typical Properties: Appearance: Milky emulsion Non-volatile: 49+-l% pH: 8.0-8.5 Viscosity, cps: 300-1300 Density: 8.7 lbs./gallon Alcohol reducibility: Excellent Freeze/thaw stability: Excellent

Henkel

209

HENKBL: G-CRYL Acrylic Resins(Continued): G-CRYL 2000: Acrylic Emulsion Polymer G-CRYL 2000 is an all-purpose acrylic emulsion polymer designed for flexo/gravure ink and coating applications. It is particularly recommended for ink applications requiring exceptional adhesion to treated polyolefin films and foil or as a component in high quality, high gloss overprint varnishes. It has excellent grease, oil and water resistance. Key Benefits: - Excellent adhesion to treated polvolefin films and foil _ _ - Outstanding gloss - Excellent grease, oil and water resistance - Good pigment wetting and transfer characteristics - Broad compatibility range Typical Properties: Appearance: Translucent emulsion Non-volatile: 47+-l% pH: 8-O-8.5 Viscosity, cps: 300-1300 Density: 8.7 lbs./gallon Alcohol reducibility: Excellent Freeze/thaw stability: Excellent

210

Water-Soluble Resins

HENKEL: G-CRYL 250 Acrylic Resin Solution: G-CRYL 250 is a 50% solids solution of G-CRYL 5002 solid acrylic resin in aqueous ammonia. It is designed for flexo/ gravure ink and coating applications where high solids, excellent pigment wetting, transfer and printability are of importance. Ink and coating formulations based on G-CRYL 250 give fast dry, excellent holdout and gloss approaching nitrocellulose or U.V. systems. It can be used as the sole vehicle or be modified with other water soluble resins or acrylic emulsions such as G-CRYL 1124, 1138 or 2000. Overprint varnishes formulated using G-CRYL 250 and G-CRYL 2000 offer excellent gloss, water and rub resistance. Due to the softness and flexibility of G-CRYL 5002, dry pigment grinds of G-CRYL 250 and G-CRYL 2000 are highly recommended for flexible film applications. Useful plasticizers include diethylene glycol, Butyl Carbitol and Polypropylene Glycol P-1200. Key Benefits: - Very high gloss - High solids - Low viscosity - Excellent holdout - Excellent pigment wetting, - Broad compatibility range

transfer and printability

Typical Properties: Appearance: Clear, amber solution Non-volatile: 50+-l% Density: 8.9 lbs./gallon pH: 8.0-8.5 Viscosity, cps: 1000-2000 Acid number (on solid): 225 Alcohol reducibility: Excellent Freeze/thaw stability: Excellent The formulation of G-CRYL 250 is: G-CRYL 5002 28% Ammonia Isopropanol Water

Wt. % 50.0 12.0 10.0 28.0

Henkel

211

HENKEL: G-CRYL 345 Acrylic Resin Solution: G-CRYL 345 is a 45% solids solution of G-CRYL 5003 solid acrylic resin in aqueous ammonia. It is particularly useful for gravure applied inks and coatings. It can be used as the grinding vehicle for pigmented inks and coatings and also for high gloss overprint varnishes. When combined with emulsion polymers such as G-CRYL 1124, 1138 and 2000, very high gloss overprint varnishes are achievable with fast drying speed and resolubility. Useful plasticizers include diethylene glycol, Butyl Carbitol and Propylene Glycol P-1200. Key Benefits: - High solids and low viscosity - High gloss and holdout - Excellent pigment wetting, transfer and printability - Broad compatibility range - Good rub and water resistance Typical Properties: Appearance: Clear, amber solution Non-volatile: 45+-l% Density: 8.9 lbs./gallon pH: 8.0-8.5 Viscosity, cps: 1300-2300 Acid number (on solid): 215 Alcohol reducibility: Excellent Freeze/thaw stability: Excellent The formulation of G-CRYL 345 is: G-CRYL 5003 28% Ammonia Isopropanol Water

wt. % 45.0 10.5 10.0 34.5

2 12

Water-Soluble Resins

HENKEL: G-CRYL 535 Acrylic Resin Solution: G-CRYL 535 is a 35% solids solution of G-CRYL 5000 solid acrylic resin in aqueous ammonia for use in waterborne flexo/ gravure inks and overprint varnishes. G-CRYL 535 can be used as a sole grinding vehicle to make up to 40% organic or up to 70% inorganic pigment grinds. It can also be used for presscakes or color chip applications. Fast drying, high gloss, optimum color strength waterborne inks can be made using master grinds from G-CRYL 535 and using G-CRYL 1139 acrylic emulsion polymer as the "let down". Overprint varnishes based on G-CRYL 535 and G-CRYL 1124 offer outstanding gloss, block and heat resistance and wet rub resistance. G-CRYL 535 can be used as a sole vehicle or as a modifying vehicle with rosin maleics, shellac, caseins and other acrylic polymers such as G-CRYL 1124, 1138 and 2000. It can be plasticized to form a film by using 15 to 25% of G-CRYL 1124 or G-CRYL 2000 acrylic emulsion polymers or lo-20% of diethylene glycol, Butyl Carbitol and Polypropylene Glycol P-1200. Key Benefits: - Excellent pigment dispersion properties chips and presscakes - Good gloss and holdout - Good water and wet rub resistance - Excellent transfer and printability - Broad compatibility range Typical Properties: Annearance: Clear, amber solution Non-volatile: 35+11% Density: 8.8 lbs/gallon pH: 8.0-8.5 Viscosity, cps: 2300-3300 Acid number (on solid resin): 200 Alcohol reducibility: Excellent Freeze/thaw stability: Excellent The formulation of G-CRYL 535 is: G-CRYL 5000 Ammonia (28%) Isopropanol Propylene glycol Water

Wt. % 35.0 7.5 5.0 1.5 51.0

for inks, color

Hercules,inc. 213

HERCULES, INC.: HERCULES Resin Dispersions: FORAL 85-55WXX: Base Resin Type: Glycerol ester of highly hydrogenated Emulsifier: Anionic (Ion-Tolerant) Properties: Softening point of base resin, C: 82 Base resin color, Gardner: 5 pH: 10.4 Solids, %: 55 Viscosity at 25C, cps: 2,100 Particle size, microns: Over 90% of particles micron in diameter Surface tension. dvnes/cm: 50 Specific gravity ai 25c: 1.04 Lbs/sal at 25C: 8.65 Mechanical stability: Good Storage stability (6 months): Good Ion-tolerant: Yes

rosin

less than 1

Film Characteristics: After 48 hrs at 70F (21C): Film continuity and tackiness: Crazed, dry Water resistance: Fair After 5 min at 225F (107C): Film continuity and tackiness: Continuous, dry Water resistance: Good Compatibility of Blends (Dried Films): With latexes of: Natural rubber: Excellent; films clear SBR (carboxvlated): Excellent: films clear Polyacrylics: Fair; films show considerable haze Polyvinyl acetate: Fair; films show considerable haze Vinylacetate-ethylene: Poor; films show component separation

214

Water-Soluble Resins

HERCULES, INC.: HERCULES Resin Dispersions(C!ontinued): HERCOLYN D-55WXX: Base Resin Type: Methyl ester of hydrogenated Emulsifier: Anionic (Ion-Tolerant) Properties: Softening point of base resin, C: Liquid Base resin color, Gardner: 2 pH: 10.9 Solids, %: 55 Viscosity at 25C, cps: 2,000 Particle size, microns: Over 90% of particles 1 micron in diameter Surface Tension, dynes/cm: 47 Specific gravity at 25C: 1.02 L&/gal at 25C:-8.49 Mechanical stability: Excellent Storage stability (6 months): Good Ion-Tolerant: Yes Film Characteristics: After 48 hrs at 70F (21C): Film continuity and tackiness: Continuous, Water resistance: Poor After 5 min at 225F (107C): Film continuity and tackiness: Continuous, Water resistance: Poor

rosin

less than

oily oily

Compatibility of Blends (Dried Films): With latexes of: Natural rubber: Excellent; films clear SBR (carboxylated): Excellent; films clear Polyacrylics: Excellent; films clear Polyvinyl acetate: Fair; films show considerable haze Vinylacetate-ethylene: Good; films show slight haze

Hercules,

Inc.

HERCULES, INC.: HERCULES Resin Dispersions(Continued): PICCOPALE 85-55WXX: Base Resin Type: Petroleum aliphatic Emulsifier: Anionic (Ion-Tolerant) Properties: Softening point of base resin, C: 82 Base resin color, Gardner: 6 pH: 10.8 Solids, %: 55 Viscosity at 25C, cps: 1,450 Particle size, microns: Over 90% of particles 1 micron in diameter Surface tension, dynes/cm: 53 Specific gravity at 25C: 0.96 Lbs/gal at 25C: 7.99 Mechanical stability: Excellent Storage stability (6 months): Good Ion-tolerant: Yes

less than

Film Characteristics: After 48 hrs at 70F (21C): Film continuity and tackiness: Crazed, dry Water resistance: Poor After 5 min at 225F (107C): Film continuity and tackiness: Continuous, dry Water resistance: Fair Compatibility of Blends (Dried Films): With latexes of: Natural rubber: Excellent; films clear SBR (carboxylated): Good; films show slight haze Polyacrylics: Fair; films show considerable haze Polyvinyl acetate: Poor; films show component separation Vinylacetate-ethylene: Poor; films show component separation

215

216

Water-Soluble Resins

HERCULES, INC.: HERCULES Resin Dispersions(Continued): PICCOTAC 95-55WR: RES D-180: Base Resin Type: Petroleum aliphatic Emulsifier: Anionic Properties: Softening point of base resin, C: 95 Base resin color, Gardner: 5 pH: 10.9 Solids, %: 55 Viscosity at 25C, cps: 750 Particle size, microns: Over 90% of oarticles 1 micron in diameter Surface tension, dynes/cm: 52 Specific gravity at 25C: 0.94 Lbs/gal at 25C: 7.82 Mechanical stability: Excellent Storage stability (6 months): Good Ion-tolerant: No

less than

Film Characteristics: After 48 hours at 70F (21C): Film continuity and tackiness: Crazed, dry Water resistance: Fair After 5 min. at 225F (107C): Film continuity and tackiness: Crazed, dry Water resistance: Fair Compatibility of Blends (Dried Films): With latexes of: Natural rubber: Excellent; films clear SBR (carboxylated): Good; films show considerable haze Polyacrylics: Fair; films show considerable haze Polyvinyl acetate: Fair; films show considerable haze Vinylacetate-ethylene: Poor; films show component separation

Hercules, Inc.

217

HERCULES, INC.: HERCULES Resin Dispersions(Continued): PICCOVAR AP25-55WEX: Base Resin Type: Alkylaryl aromatic hydrocarbon Emulsifier: Anionic (Ion-Tolerant) Properties: Softening point of base resin, C: 32 Base resin color, Gardner: 13 pH: 12.2 Solids, %: 55 Viscosity at 25C, cps: 2,700 Particle size, microns: Over 90% of particles 1 micron in diameter Surface tension, dynes/cm: 55 Specific gravity at 25C: 1.02 Lbs/gal at 25C: 8.49 Mechanical stability: Excellent Storage stability (6 months): Good Ion-tolerant: Yes Film Characteristics: After 48 hrs at 70F (21C): Film continuity and tackiness: Continuous, Water resistance: Good After 5 min at 225F (107C): Film continuity and tackiness: Continuous, Water resistance: Good

resin

less than

tacky tacky

Compatibility of Blends (Dried Films): With latexes of: Natural rubber: Good; films show slight haze SBR (carboxylated): Excellent; films clear Polyacrylics: Fair; films show considerable haze Polyvinyl acetate: Fair; films show considerable haze Vinylacetate-ethylene: Fair; films show considerable haze

218

Water-Soluble

Resins

HERCULES, INC.: HERCULES Resin Dispersions(Continued): STAYBELITE ESTER lo-55WEX: Base Resin Type: Glycerol ester of hydrogenated Emulsifier: Anionic (Ion-Tolerant) Properties: Softening point of base resin, C: 83 Base resin color, Gardner: 5 RH: 10.5 Solids, %: 55 Viscosity at 25C, CPS: 2,200 bver 90% of particles Particle-size, microns: 1 micron in diameter Surface tension, dynes/cm: 50 Specific gravity at 25C: 1.10 Lbs/gal at 25C: 9.15 Mechanical stability: Good Storage stability (6 months): Good Ion-tolerant: Yes

rosin

less than

Film Characteristics: After 48 hrs at 70F (21C): Film continuity and tackiness: Crazed, dry Water resistance: Poor After 5 min at 225F (107C): Film continuity and tackiness: Continuous, dry Water resistance: Good Compatibility of Blends (Dried Films): With latexes of: Natural rubber: Excellent; films clear SBR (carboxylated): Excellent; films clear Polyacrylics: Fair; films show considerable haze Polyvinyl acetate: Poor; films show component separation Vinylacetate-ethylene: Poor; films show component separation

Hercules,

HERCULES, INC.: PICCONOL Hydrocarbon

Inc.

Resin Emulsions:

PICCONOL AAlOl: Base Resin Type: Petroleum-Aliphatic Emulsifier: Anionic (Ion-Tolerant) Properties: Softening point of base resin, C: 71 Base resin color, Gardner: 11 pH: 4.2 Solids, %: 50 Viscosity at 25C, cps: 130 Particle size, microns: Over 90% of particle 1 micron in diameter Surface tension, dynes/cm: 42 Specific gravity at 25C: 0.98 Lbs/gal at 25C: 8.15 Mechanical stability: Excellent Storage stability: Excellent Ion-tolerant: Yes Fi .m Characteristics: After 48 hrs at 70F (21C): Film continuity and tackiness: Water resistance: Poor After 5 min at 225F (107C): Film continuity and tackiness: Water resistance: Fair

less than

Continuous,

tacky

Continuous,

tacky

Film Clarity (Dried Films): With latexes of: Natural rubber: Excellent; films clear SBR: Good; films show slight haze Polyacrylics: Fair; films show considerable haze Polyvinyl acetate: Poor; films show component separation

219

220

Water-Soluble Resins

HERCULES, INC.: PICCONOL Hydrocarbon

Resin Emulsions(Continued):

PICCONOL A153: Base Resin Type: Petroleum-Aliphatic Emulsifier: Anionic Rosin Soap Properties: Softening point of base resin, C: 75 Base resin color, Gardner: 11 pH: 11 Solids, %: 50 Viscosity at 25C, cps: 620 Particle size, microns: Over 90% of particles 1 micron in diameter Surface tension, dynes/cm: 49 Specific gravity at 25C: 1.00 Lbs/gal at 25C: 0.32 Mechanical stability: Excellent Storage stability: Excellent Ion-tolerant: No Film Characteristics: After 48 hrs at 70F (21C): Film continuity and tackiness: Water resistance: Poor After 5 min at 2251 (107C): Film continuity and tackiness: Water resistance: Fair

less than

Continuous,

tacky

Continuous,

tacky

Film Clarity (Dried Films): With latexes of: Natural rubber: Excellent; films clear SBR: Good; films show slight haze Polyacrylics: Fair; films show considerable haze Polyvinyl acetate: Poor; films show component separation

Hercules, Inc.

HERCULES, INC.: PICCOTEX LC-55WR Resin Emulsion: Base Resin Type: Copolymer-Aromatic Emulsifier: Anionic Rosin Soap Properties: Softening point of base resin, C: 85 Base resin-color, Gardner: 1 pH: 12.2 Solids. %: 55 Viscosity at 25C, cps: 550 Particle size, microns: Over 90% of particles 1 micron in diameter Surface tension, dynes/cm: 51 Specific gravity at 25C: 1.02 Lbs/gal at 25C: 8.49 Mechanical stability: Excellent Storage stability: Excellent Ion-tolerant: No

less than

Film Characteristics: After 48 hrs at 70F (21C): Film continuity and tackiness: Powdery, _. dry Water resistance: Good After 5 min at 225F (107C): Film continuity and tackiness: Continuous, dry Water resistance: Good Film Clarity (Dried Films): With latexes of: Natural Rubber: Good: films show slight haze SBR: Good; films show slight haze Polyacrylics: Good: film show slight haze Polyvinyl acetate: Excellent; films clear

221

222

Water-Soluble Resins

HERCULES, INC.: DRESINOL Resin Dispersions: DRESINOL 40: Base Resin Type: Pale grade of rosin Emulsifier: Aqueous ammonia Properties: Softening point of base resin, C: 77 Base resin color, Gardner: Pale amber pH: 9.1 Solids, %: 40 Brookfield viscosity at 25C, cps: 550 Particle size, microns: Over 90% of particles less than 1 micron in diameter Surface tension, dynes/cm: 40 Specific gravity at 25C: 1.03 Lbslgal at 25C: 0.57 Mechanical stability (after 125 min of centrifugal pumping): Excellent Storage stability (6 months): Excellent Ion-tolerant: No Film Characteristics: After 48 hrs at 70F (2lC): Film continuity and tackiness: Continuous, Water resistance: Excellent After 5 min at 225F (107C): Film continuity and tackiness: Continuous, Water resistance: Excellent

dry tacky

Film Clarity (Dried Films): With latexes of: Natural rubber: Excellent; films clear SBR: Excellent; films clear Polyacrylics: Good; films show slight haze Polyvinyl acetate: Good; films show slight haze

Hercules,

Inc.

223

HERCULES, INC.: DRESINOL Resin Dispersions(Continued): DRESINOL 155: Base Resin Type: Glycerol ester of polymerized Emulsifier: Aqueous ammonia

rosin

Properties: Softening point of base resin, C: 107 Base resin color, Gardner: Pale amber pH: 10.5 Solids, %: 40 Brookfield viscosity at 25C, cps: 125 Particle size, microns: Over 90% of particles less than 1 micron in diameter Surface tension, dynes/cm: 35 Soecific aravitv at 25C: 1.04 L&/gal at 25C:-8.68 Mechanical stability (after 125 min of centrifugal pumping): Excellent Storage stability (6 months): Excellent Ion-tolerant: No Film Characteristics: After 48 hrs at 70F (21C): Film continuity and tackiness: Powdery, dry Water resistance: Fair After 5 min at 225F (107C): Film continuity and tackiness: Continuous, slightly tacky Water resistance: Fair Film Clarity (Dried Films): With latexes of: Natural rubber: Good; films show slight haze SBR: Good; films show slight haze Polyacrylics: Fair; films show considerable haze Polyvinyl acetate: Good; films show slight haze

224

Water-Soluble Resins

HERCULES, INC.: Dresinol Resin Dispersions(Continued): DRESINOL 205: Base Resin Type: Hydrogenated Emulsifier: Aqueous ammonia

wood rosin

Properties: Softening point of base resin, C: 75 Base resin color, Gardner: Pale amber pH: 9.5 Solids, %: 45 Brookfield viscosity at 25C, cps: 1,200 Particle size, microns: Over 90% of particles less than 1 micron in diameter Surface tension, dynes/cm: 41 Snecific uravitv at 25C: 1.05 L&/gal at 25C:-8.76 Mechanical stability (after 125 min of centrifugal pumping): Excellent Storage stability (6 months): Excellent Ion-tolerant: No Film Characteristics: After 48 hrs at 70F (21C): Film continuity and tackiness: Continuous, Water resistance: Good After 5 min at 225F (107C): Film continuity and tackiness: Continuous, Water resistance: Good

dry tacky

Film Clarity (Dried Films): With latexes of: Natural rubber: Excellent; films clear SBR: Good; films show slight haze Polyacrylics: Excellent; films clear Polyvinyl acetate: Good; films show slight haze

Hercules, Inc.

HERCULES, INC.: DRESINOL Resin Dispersions(Continued): DRESINOL 210B: Base Resin Type: Plasticized Emulsifier: Aqueous ammonia

hydrogenated

rosin

Properties: Softening point of base resin, C: 67 Base resin color, Gardner: Pale amber pH: 9.0 Solids, %: 40 Brookfield viscosity at 25C, cps: 1,000 Particle size, microns: Over 90% of particles less than 1 micron in diameter Surface tension, dynes/cm: 37 Specific gravity at 25C: 1.03 Lbs/gal at 25C: 8.60 Mechanical stability (after 125 min of centrifugal pumping): Excellent Storage stability (6 months): Excellent Ion-tolerant: No Film Characteristics: After 48 hrs at 70F (21C): Film continuity and tackiness: Water resistance: Fair After 5 min at 225F (107C): Film continuity and tackiness: Water resistance: Fair

Continuous,

dry

Continuous,

tacky

Film Clarity (Dried Films): With latexes of: Natural rubber: Excellent: films clear SBR: Good; films show slight haze Polyacrylics: Excellent; films clear Polyvinyl acetate: Good; films show slight haze

2.X

226

Water-Soluble

Resins

HERCULES, INC.: VINSOL Resin Emulsion: Base Resin Type: Dark Wood Rosin Emulsifier: Aqueous ammonia Properties: Softening point of base resin, C: 106 Base resin color, Gardner: Dark brown pH: 8.5 Solids, %: 40 Brookfield viscosity at 25C, cps: 700 Particle size, microns: Over 90% of particles less than 1 micron in diameter Surface tension, dynes/cm: 39 Specific gravity at 25C: 1.06 Lbslgal at 25C: 8.85 Mechanical stability (after 125 min of centrifugal pumping): Excellent Storage stability (6 months): Excellent Ion-Tolerant: No Film Characteristics: After 48 hrs at 70F (21C): Film continuity and tackiness: Powdery, dry Water resistance: Fair After 5 min at 225F (107C): Film continuity and tackiness: Continuous, dry Water resistance: Fair Film Clarity (Dried Films): With latexes of: SBR: Good; films show slight haze Polyvinyl acetate: Good; films show slight haze

Hi- Tek Polymers

227

HI-TEK POLYMERS, INC.: CMD W55-5003 Epoxy Resin Dispersion: CMD W55-5003 Epoxy Resin Dispersion is a non-ionic aqueous dispersion of a polyfunctional aromatic epoxy resin with an average functionality of three. It is intended for high performance applications such as industrial fabric finishes and adhesives which require maximum chemical and solvent resistance and/or elevated temperature service. CMD W55-5003 Epoxy Resin Dispersion contains reactive epoxide functionality. Water dispersible or water soluble curing agents which react with epoxide groups or promote self polymerization are recommended as crosslinking agents for CMD W55-5003. Such curing agent types include dicyandiamide, polyamides, and aliphatic and aromatic amines. Upon evaporation of water, CMD W55-5003 Epoxy Resin Dispersion coalesces to form a clear, continuous, tacky film at ambient temperature. In baking applications, CMD W55-5003 in combination with a suitable crosslinking agent, will form a clear, highly crosslinked, tough, chemical resistant film. CMD W55-5003 Epoxy Resin Dispersion promotes wetting and adhesion to fiberglass, polyester, nylon, and inorganic mineral fillers. It is recommended as a surface treatment, binder or adhesion promoter in applications involving these and many other substrates. Advantages associated with CMD W55-5003 Epoxy Resin Dispersion when compared to standard bisphenol A base epoxy resin include improved elevated temperature performance, increased water and solvent resistance, and improved chemical resistance. CMD W55-5003 Epoxy Resin Dispersion contains no organic solvent and is completely water reducible. This dispersion is thixotropic. Typical Properties: Viscosity at 25C, cps.: 10,000 Nonvolatiles, percent: 57 Pounds/gallon: 9.2 Particle Size, average, microns: pH: 7.0 Solvent: water Weight per Epoxide: 205

cl.5

228

Water-Soluble Resins

HI-TEK POLYMERS, INC.: CMD W60-3515 Epoxy Resin Dispersion: CMD W60-3515 is a nonionic, aqueous dispersion of a bisphenol A epoxy resin with an equivalent weight of 220-260. Supplied at approximately 63% non-volatile, CMD W60-3515 has a moderate viscosity and is mechanically stable. No organic solvents are present. CMD W60-3515 is completely water reducible, providing wide latitude for viscosity reduction. Performance Highlights/Features: - High epoxy functionality - High solids - Completely water reducible - Compatible with most latex resins and some waterborne phenolic resins - Good water resistance - Good chemical resistance Suggested Uses: - Industrial textile binders or finishes - Adhesives - Fiberglass reinforced plastics - Coatings - Performance modifiers for other waterborne

resins

CMD W60-3515 Epoxy Resin Dispersion offers a solvent free approach to the formulation of film adhesives, fiberglass reinforced plastics, coatings and electrical dip coatings and varnishes. It can also be incorporated into formulations which are traditionally water-based and which require strength and outstanding chemical or water resistance. Examples of such applications are industrial fiber finishes, binders or stiffeners. Latex resins which benefit most from CMD W60-3515 modification are those which contain sufficient amine or carboxyl functionality to react with the available epoxy groups. Typical Properties: Viscosity at 25C, cps: 11,000 Nonvolatiles, %: 63 Volatile portion: Water Pounds/Gallon: 9.2 Particle size, average, microns: (3 pH: 3.1 Weight per Epoxide, on solids: 250

Hi-Tek Polymers

HI-TEK POLYMERS, INC.: CMD W60-5520 Epoxy Resin Dispersion: CMD W60-5520 Epoxy Resin Dispersion is a nonionic, aqueous dispersion of urethane modified epoxy resin with an epoxide equivalent weight of 540. Supplied at 60 percent nonvolatiles, CMD W60-5520 has a moderate viscosity and is mechanically stable. No organic solvents are present. CMD W60-5520 is completely water reducible, providing wide latitude for viscosity reduction. Since this dispersion is thixotropic, vicosity readings will vary with spindle speed. CMD W60-5520 Epoxy Resin Dispersion offers a solvent free approach to the formulation of film adhesives, fiberglass reinforced plastics, and electrical dip coats and varnishes. It may also be incorporated in formulations which are traditionally water based and which require good strength and outstanding chemical or water resistance. Examples of such anolications are fiber finishes and industrial textile applications. When compared to standard bisphenol A epoxy resins, CMD W60-5520 Epoxy Resin Dispersion will provide improved chemical resistance and thermal properties. CMD W60-5520 can be cured through both epoxy functionality and hydroxyl functionality. Curing agents most conveniently employed are those which are water soluble or dispersible and which are stable in an aqueous medium. Examples of such converters include dicyandiamide, substituted imidazoles, aliphatic and aromatic amines, melamine resins and urea formaldehyde resins. When applied at room temperature, CMD W60-5520 Epoxy Resin Dispersion does not form a continuous film after evaporation of the water. However, upon application of heat (greater than 180F.), the resin system will readily coalesce to a smooth film. Typical Properties: Viscosity at 25C, cps: 12,000 Nonvolatiles, percent: 60 Pounds/Gallon: 9.2 Particle size, average, microns: pH: 4.0 Solvent: water Weight per Epoxide, solids: 540

2

229

230

Water-Soluble Resins

HI-TEK POLYMERS, INC.: CMD WJ55-3540

Epoxy Resin:

CMD WJ55-3540 Epoxy Resin is a 55 percent solids dispersion of an EPI-REZ 540-C Epoxy Resin in water and 2-propoxyethanol. This resin is designed for use in formulating industrial baking finishes. When crosslinked with an appropriate melamine or urea-formaldehyde resin and baked, epoxy coatings can be obtained that offer performance comparing favorably to solvent-borne epoxy coatings. Performance Highlights: - May be formulated to low VOC coatings - Possesses excellent adhesion to steel or aluminum - Compatibility with a variety of aminoplast resins - Stability with a wide range of solvents Product Formulary - Clear Bake Coating - White Baking Enamel - Red Iron Oxide Primer Typical Properties: Viscosity cps at 25C: 12,000 Nonvolatiles, percent: 55 Pounds/Gallon: Solution: 9.0 Solids, calculated: 10.1 Appearance: milky Solvent: 76% water 24% 2-propoxyethanol Weight per Epoxide: 1800 CMD WJ55-3540 Epoxy Resin may be formulated into gloss enamels, primers, and clear coatings. The viscosity and stability of these coatings are dependent on the solvents, surfactants, pigments, and other additives used in formulating. It is therefore advisable to include one of the given formulations as a control when formulation changes are made in order to determine the effect of the change on formulation constants. A wide variety of aminoplast resins have been screened with CMD WJ55-3540 Epoxy Resin. Evaluation of cured films using these crosslinking resins indicates that Beetle 80 at an 80:20 ratio (epoxy resin solids/crosslinker solids) offers the best combination of hardness, flexibility, resistance properties and stability. There are a number of crosslinking agents and combinations of crosslinking agents that may be used with CMD WJ55-3540 which offer the formulator latitude in developing coatings for specific end use requirements. Generally, 10 to 30 percent crosslinker resin solids will give optimum results.

Hi-Tek Polymers

HI-TEK POLYMERS, INC.: CMD WJ60-8537 Curing Agent: CMD WJ~O-8537 Curing Agent is a water soluble amine adduct supplied at 60 percent solids in water, 2-propoxyethanol and glacial acetic acid. When combined with suitable epoxy resins, waterborne coatings may be formulated to meet a variety of end use requirements. Performance Highlights: - Low VOC coatings - Water cleanup - Overnight recoat - Resistance to flash rusting - Solvent resistance comparable to solvent based epoxy systems - Good color - Excellent sealing over fresh concrete and damp masonry - Acceptance of universal machine colorants - Adhesion to various substrates: - Untreated and treated cold rolled steel - Electrolytic and hot dip galvanized metal - Aluminum - Aged alkyd and epoxy enamel films - Seals wood surfaces without raising nap - Bridging of voids and freedom from mud cracking in block fill coatings - No bleed through over asphaltic surfaces - Excellent film properties at low temperature bakes - Early resistance to wash-off and water spotting Suggested Uses: - Trade Sales - sealers, primers, block fills, masonry coatings, asphalt coatings, enamels. - Industrial Maintenance - sealers, primers, block fills, masonry coatings, enamels. - Industrial Finishes - Low temperature bake primers and enamels. Product Formulary: - Gloss white enamel - Corrosion inhibitive metal primer - Block fill coating - Semigloss black enamel - Intermediate coating for film build - Lead silica chromate primer - Iron oxide primer Typical Properties: Viscosity, Gardner-Holdt: 22 Nonvolatiles, percent: 60 Pounds/Gallon: Solution: 9.0 Solids, calculated: 9.75 Color, Gardner, maximum: 9 Solvent: 49% water 38% 2-propoxyethanol 13% glacial acetic acid Equivalent Weight, solids: 174 Flashpoint, Setaflash, F: ,200

231

232

Water-Soluble

Resins

HI-TEK POLYMERS, INC.: CMD 9790 Acrylic Dispersion: CMD 9790 Acrylic Dispersion is a preneutralized and water dispersed version of CMD 979 Acrylic Resin, supplied at 42 percent solids in water, solvent, and amine. This resin was designed for use with liquid epoxy resins in the manufacture of two-package, high performance, ambient cure and thermoset water reducible coatings. Performance Highlights: Compliance with CARB regulations Better exterior durability than medium TOFA alkyd Pot life of 20 to 30 hours Resistance to flash rusting, early water spotting, humidity, water, acid, and salt spray Versatile formulating vehicle: - Air dry and heat curable with epoxy resin - Heat curable with amino resins - Sole vehicle in package systems Suggested Uses: - Primers and sealers. - White enamels with good durability. - Heat cured coatings with epoxy and/or amino resins. Product Formulary: - Two-package white enamel. - Clear coating. foical Properties: Viscosity, cps: 15,000 Nonvolatiles, percent: 42 Pounds/Gallon: Solution: 8.53 Solids, calculated: 9.2 Appearance: milky Solvent: 75% water 14% 2-propoxyethanol 6% xylene 5% triethylamine Equivalent Weight, solids(calculated):

660

When combined with liquid epoxy resins such as EPI-REZ 510 Epoxy Resin, CMD 9790 Acrylic Dispersion produces coatings that are dry enough to handle in 20 to 30 minutes and dry to hard, high gloss films possessing unique characteristics, when compared to conventional two component epoxy systems. Due to good atomization these coatings may be spray applied in the 85 to 95 Krebs Unit range. Films with excellent hardness and gloss can be achieved immediately upon mixing the two components and for 20 to 30 hours thereafter. A definite gel will signal the end of usable pot life. After 20 hours induction time, additional thinning with water may be necessary for further application.

Hi- Tek Polymers

HI-TEK POLYMERS, INC.: EPI-CURE

W50-8535

233

Curing Agent:

EPI-CURE W50-8535 Curing Agent is a modified polyamido-amine adduct supplied at 50 percent solids in water which, when combined with liquid epoxy resins, provides completely solvent free, two-package epoxy systems. Performance Highlights: - Offers combination of hardness, flexibility and solvent resistance - 100 percent water base systems - Water cleanup - No flash rusting - Overnight recoating with epoxy enamel - Acceptance of the universal machine tinting system - Excellent adhesion to various substrates: - Concrete masonry - Untreated and treated cold rolled steel - Aluminum - Aged alkyd and epoxy enamel films - Absence of nap raising on wood surfaces - Excellent sealer for concrete and masonry - Bridges voids and is free from mud cracking and block fills - No bleeding when applied to asphalt substrates Suggested Uses: - Sealers, primers and block fills for various masonry substrates - Sealer coats for subgrade and other moisture problem masonry substrates - Sealer coat on plywood forms for concrete - Lane marking paint for concrete or asphalt substrates in plant and parking lots Product Formulary: - White Enamel - Flat Concrete Floor Sealer - Clear Coating - Block Fill Coating - Red Oxide Primer - Lead Silica Chromate Primer TYDiCal

Properties: --Viscosity, Gardner-Holdt: 25 Nonvolatiles, percent: 50 Pounds/Gallon: Solution: 8.77 Solids, calculated: 9.19 Color, Gardner, maximum: 12 Solvent: 96% water 4% acetic acid Equivalent Weight, solids: 102

234

Water-Soluble Resins

HI-TEK POLYMERS, INC.: EPI-REZ WJ-3520 Epoxy Resin: EPI-REZ WJ-3520 Epoxy Resin is a 55 percent solids dispersion of an EPI-REZ 520-C EDOXV Resin in water and 2-DroRoxvethanol. This resin is designed for use in waterborne, two-package coatinqs. When combined with suitable curing agents, EPI-REZ WJ-3520 Epoxy Resin offers the potential for high performance aqueous systems. Performance Highlights: - Same molecular weight epoxy resins as standard solventborne epoxy systems - High gloss - Excellent stability - Insensitive to pH - Accepts variety of pigments - Nonsettlins or creamins on storase - Mechanically stable - Compatible with various solvents and curing agents - Negligible solvent odor roical Properties: -Viscosity at 25C, cps: 12,000 Nonvolatiles, percent: 55 Pounds/Gallon: Solution: 9.1 Solids, calculated: 10.05 Appearance: milky Solvent: 78.0% water 22.0% 2-propoxyethanol Weight per Epoxide, solids: 535 Flashpoint, Setaflash, F: >200 EPI-REZ WJ-3520 Epoxy Resin is compatible with a variety of water reducible curing agents. Extensive evaluations have been made using CMD JT60-8536 and CMD WJ60-8537 Curing Agents. The choice of curing agent will depend on the ultimate film properties desired for a particular application. Where optimum chemical resistance is desired, CMD JT60-8536 Curing Agent is suggested. If fast cure and film hardness are needed, then CMD WJ60-8537 is the choice. Variations in performance are posssible with a particular curing agent by adjusting the ratio of curing agent to EPI-REZ WJ-3520 Epoxy Resin.

Hi- Tek Polymers

235

HI-TEK POLYMERS, INC.: EPI-REZ WJ-5522 Epoxy Resin: EPI-REZ WJ-5522 Epoxy Resin is a 55 percent nonvolatile dispersion of a modified epoxy resin in water and 2-propoxyethanol. This polyfunctional epoxy resin dispersion is intended for use in ambient cure, two-component, water-reducible epoxy coatinqs formulated for applications requiring a high degree of chemical and corrosion-protection. Although EPI-REZ WJ-5522 exhibits qood compatibility with several amine functional water-reducible converters, it is suggested for use with CMD J60-8290 water-reducible curing agent. Performance Highlights: - Rapid room temperature cure - Low volatile organic content (VOC) - Excellent stability - No settling or creaming during storage - Mechanically stable - Performance versatility - Long-term water and humidity resistance - Corrosion resistance over a variety of substrates - Adhesion to damp concrete Formulary: - Clear Enamels - Corrosion Resistant - White Enamels

Primers

Typical Properties: Viscosity at 25C, cps: 14,000 Nonvolatiles, percent: 53.5 Pounds/Gallon: Solution: 9.0 Solids, calculated: 9.88 Appearance: milky Solvent: 82.9% water 17.1% 2-propoxyethanol Weight per Epoxide, solids: 625 Flashpoint, Setaflash, F: ,200 Coatings formulated with EPI-RES WJ-5522 Epoxy Resin and CMD 560-8290 Curing Agent can be applied to a variety of substrates. These coatings exhibit excellent adhesion and long-term protection. Adhesion is particularly good over damp concrete, an exclusive feature of waterborne epoxy systems. This resin combination may be formulated into sealers, primers and low to high sheen topcoats for various industrial maintenance and specialty architectural applications. CMD J60-8290, the water-reducible amine adduct recommended for conversion of EPI-REZ WJ-5522, is a highly reactive hardener. Therefore, certain formulating parameters must be considered in order to achieve maximum performance from these coatings.

236

Water-Soluble Resins

HI-TEK POLYMERS, INC.: EPI-REZ 35201 Epoxy Resin Dispersion: EPI-REZ 35201 Epoxy Resin Dispersion is a nonionic, aqueous dispersion of a solid bisphenol A epoxy resin similar to EPI-REZ 522-C Epoxy Resin, with an epoxide equivalent weight of 550 to 650 and a Durran's melting point of 75 to 85C. EPI-REZ 35201 is supplied at a moderate viscosity and is mechanically stable. No organic solvents are present. EPI-REZ 35201 Epoxy Resin Dispersion is completely water reducible , providing for a wide latitude in viscosity reduction. This dispersion is thixotropic; therefore, viscosity readings vary with the spindle speed of the viscometer. EPI-REZ 35201 Epoxy Resin Dispersion a solvent-free approach to the formulation of film adhesives, fiberglass reinforced plastics, chemical resistant pipe, and electrical dip coatings and varnishes. In addition, EPI-REZ 35201 can be used in the formulation of coatings where conventional solvent based epoxy resins are normally used. EPI-REZ 35201 can also be used in formulations which are traditionally water based and require improved chemical and water resistance. Examples of such applications are fiber finishes and industrial textile applications. EPI-REZ 35201 Epoxy Resin Dispersion can be cured through both functionality and hydroxyl functionality. Curing agents most conveniently employed are those which are water soluble or dispersible and are stable in an aqueous medium. Examples of such converters include dicyandiamide, various substituted imidazoles, aliphatic and aromatic amines, melamine resins, and urea-formaldehyde resins. When applied at room temperature, EPI-REZ 35201 Epoxy Resin Dispersion does not form a continuous film after evaporation of the water. However, upon the application of heat (170F) the resin system will readily coalesce to a smooth coating. Typical Properties: Viscosity at 25C, cps: 12,000 Nonvolatiles, percent: 60 Pounds/Gallon: 9.2 Particle size, average, microns: pH: 8.0 Solvent: water Weight per Epoxide: 700

2

Hi-Tek

HI-TEK POLYMERS,

Polymers

237

INC.: EPI-TEX 611-Q Epoxy Ester Emulsion:

EPI-TEX _ 611-Q Epoxy Ester Emulsion _ _. is used to modify polyvinyl acetate emulsions and thermoplastic latex resins. Providing films with increased water and wear resistance, it makes an excellent modifier of emulsion type coatings used on floors, structural masonry, roofs, patios, driveways, etc. Outstanding performance has been obtained over concrete, wood and asphalt. Suggested Uses: Modifier for emulsion-based - Floors - Structural masonry - Roofs - Patios - Driveways

type coatings used on:

EPI-TEX 611-Q Epoxy Ester Emulsion, when used in a base coat on exterior masonry surfaces which contain excessive water soluble salts, greatly inhibits efflorescence effects observed with the application of emulsion paints. It also reduces stain development due to tramp iron or iron salts in the substrate on the film surface. Incorporating EPI-TEX 611-Q in the base coat over old chalky paint films on masonry substrates assists in tying down the loose chalk and improves intercoat adhesion of conventional emulsion topcoats. Various latex resins, when modified with EPI-TEX 611-Q, exhibit less thermoplasticity due to the oxidative cure of the epoxy ester emulsion. Typical Properties: Viscosity, Krebs units: 100 Nonvolatiles, percent: 60 Pounds/Gallon: Solution: 8.47 Solids, calculated: 8.80 Appearance: milky-white pH: '3.3 Solvents: 77.5% water 16.9% aromatic naphtha 5.6% xylene Flash Point, Setaflash, F: ,200 Formulation: EPI-TEX 611-Q Epoxy Ester Emulsion is suggested for use at levels from 10 to 30 percent based on total vehicle solids. Since the EPI-TEX emulsion dries by oxidation, the addition of metallic driers is necessary. Manganese and cobalt, at levels of 0.1 percent based on epoxy ester solids, are suggested. Use of water-dispersible driers is recommended, but not mandatory. Thoroughly pre-mix the driers with EPI-TEX 611-Q, whether water dispersible or not, prior to addition to the batch.

238

Water-Soluble

Resins

HI-TEK POLYMERS,

INC.: Epoxy Water-Reducible

Resins:

EPI-REZ WD-510 Epoxy Resin: EPI-REZ WD-510 Epoxy Resin is a liquid, bisphenol A type epoxy resin specifically designed for convenient water dilution in combination with amine curing agents, forming fine particle size emulsions useful as modifiers for Portland Cement, concrete, mortars, stuccos, grouts, as binders for trowel applied floor toppings, as bond coats, base coats, membrane coatings, and sealers. EPI-REZ WD-510 can also be combined with CMD 9790 Acrylic Dispersion to produce two-package water reducible coatings. Aliphatic amine curing agents, including adducts, amidoamines, polyamides, and accelerated amines, in combination with EPI-REZ WD-510 form uniform dispersions in water when the resin/converter blends are diluted with water to a solids level of 40 to 80 percent by weight. Typical Properties: Viscosity at 25C. CPS: 10,000 Pounds/Gallon: 9;64‘ Color, Gardner, maximum: 2 Weight per Epoxide: 200 CMD W65-3510 Epoxy Resin Dispersion: CMD W65-3510 is a nonionic, aqueous dispersion of a bisDhenOl A eooxv resin similar to EPI-REZ 510, a liquid epoxy resin with-an-equivalent weight of 187. Supplied at 65% nonvolatile, CMD W65-3510 has a moderate viscosity and is mechanically- stable. No organic solvents are present. CMD W653510 is completely water reducible, providing wide latitude for viscosity reduction. Performance Highlights/Features: - High epoxy functionality - Hish solids - Completely water reducible - Compatible with most latex resins and some waterborne phenolic resins - Good water resistance - Good chemical resistance Suggested Uses: - Industrial textile binders or finishes - Adhesives - Fiberglass reinforced plastics - Coatings - Performance modifiers for other waterborne resins Typical Properties: Viscosity at 25C, cps: 10,000 Nonvolatiles, percent: 65 Volatile portion: Water Pounds/Gallon: 9.0 Particle size, average, microns: (2 pH: 3.5 Weight per Epoxide, on solids: 195

Hoechst

239

HOECHST CELANESE CORP.: TYLOSE Hydroxyethylcellulose: TYLOSE H grades: HEC, normally etherified granules TYLOSE H-p grades: HEC, normally etherified powders, readily soluble TYLOSE H-yp grades: HEC, normally etherified powders, with retarded swelling properties Moisture content: approx. 5% on filling Degree of purity: a.i. content approx. 96%, dry weight basis Viscosity stages in mPa s, 2oc: TYLOSE TYLOSE TYLOSE TYLOSE TYLOSE

H H H H H

10 20 300 4000 10000

TYLOSE TYLOSE TYLOSE TYLOSE TYLOSE

H H H H H

2OP 2oop 3oop 4ooop 10000P

TYLOSE TYLOSE TYLOSE TYLOSE TYLOSE

H H H H H

6000~~ 15000yp 3ooooyp 60000yp loooooyp

2%

solutions, Hoppler viscometer,

The TYLOSE H grades are of the nonionic cellulose ether group. They are readily soluble in water at any temperature, forming clear solutions. The solutions have particularly good compatibility with salts.

240

Water-Soluble Resins

HOECHST-CELANESE

CORP.: TYLOSE Methylhydroxyethylcellulose:

TYLOSE MH grades: MHEC, normally etherified granules TYLOSE MH-p grades: MHEC, normally etherified powders TYLOSE MHB grades: MHEC, highly etherified granules TYLOSE MHB-p grades: MHEC, highly etherified powders TYLOSE MB grades: MC, highly etherified granules Moisture content: approx. 5% on filling Degree of purity: a.i. content at least 98.5%, dry weight basis Viscosity stages in mPa s, 2% solutions, Hoppler viscometer, 2oc: TYLOSE TYLOSE TYLOSE TYLOSE TYLOSE TYLOSE

MH MH MH MH MH MH

20 50 300 1000 2000 4000

TYLOSE TYLOSE TYLOSE TYLOSE

MH MH MH MH

3oop IOOOp 2ooop 4ooop

TYLOSE TYLOSE TYLOSE TYLOSE

MHB MHB MHB MHB

TYLOSE MHB TYLOSE MHB TYLOSE MHB TYLOSE MB

1000 3000 10000 30000 3ooop 1 oooop

3oooop 1500

The TYLOSE MH and MHB grades are of the nonionic cellulose ether group. TYLOSE MHB grades are soluble in water and also in mixtures of chlorinated hydrocarbons and alcohols, e.g. methylene chloride/methanol. TYLOSE MB 1500 is a special grade for use in the tobacco and pharmaceutical industries.

Hoechst

HOECHST-CELANESE (Continued):

241

CORP.: TYLOSE Methylhydroxyethylcellulose

TYLOSE MH-K grades: MHEC, normally etherified granules, readily soluble TYLOSE MH-xp grades: MHEC, normally etherified powders, with-retarded swelling properties TYLOSE MHB-y grades: NHEC, highly etherified fine granules with retarded swelling properties TYLOSE MHB-yp grades: MHEC, highly etherified powders, with retarded swelling properties Moisture content: approx. 5% on fillinq Degree of purity: a,i. content at least 98.5%, dry weight basis Viscosity stages in mPa s, 2% solutions, Hoppler viscometer, 2oc: TYLOSE TYLOSE TYLOSE TYLOSE TYLOSE TYLOSE TYLOSE

MH MH MH MH MH MH MH

TYLOSE MH TYLOSE MH TYLOSE MH

200K 15OOK 2000K 4000K 6000K 1OOOOK 30000K

TYLOSE TYLOSE TYLOSE TYLOSE

MHB MHB MHB MHB

TYLOSE MHB TYLOSE MHB

3oooy 6000~ 15000y 3ooooy looooyp 3ooooyp

2ooxp 2oooxp 6000~~

The TYLOSE MH-K grades contain additives which improve their dissolving and processsing properties and increase the stability of their solutions. Hence the moisture content of these grades may be slightly higher on filling (approx. 7%). TYLOSE MH-xp grades are powders with short-time retarded swelling. TYLOSE MHB-y grades are particularly free-flowing, low dusting fine granules with a special particle size distribution spectrum and longer retarded swelling. TYLOSE MHB-yp grades are powders with longer retarded swelling. Swelling-retarded TYLOSE MHB grades are not intended for use in organic solvent mixtures.

242

Water-Soluble Resins

HOECHST-CELANESE

CORP.: TYLOSE Sodium Carboxymethylcellulose:

TYLOSE C grades: NaCMC, normally etherified granules TYLOSE C-p grades: NaCMC, normally etherified powders TYLOSE CB grades: NaCMC, highly etherified granules TYLOSE CB-p grades: NaCMC, highly etherified powders Moisture content: approx. 7% on filling Degree of purity: a-i. content approx. 99%, dry weight basis Viscosity stages in mPa s, 2% solutions, Hoppler viscometer, 2oc: TYLOSE TYLOSE TYLOSE TYLOSE TYLOSE TYLOSE TYLOSE

C C C C C C C

TYLOSE C TYLOSE C TYLOSE C

30 100 300 600 1000 6000 10000

TYLOSE CB TYLOSE CB

200 30000

TYLOSE CB

3oooop

3oop IOOOp 10000P

The TYLOSE C and CB grades are anionic cellulose ethers.

Hoechst

HOECHST-CELANESE CORP.: TYLOSE Sodium Carboxymethylcellulose, Technical Grades: TYLOSE CR grades: 65% NaCMC, normally etherified granules TYLOSE CR-p grades: 65% NaCMC, normally etherified powders TYLOSE CR-w grades: >65% NaCMC, normally etherified fine granules TYLOSE CR-n grades: 55% NaCMC, highly etherified granules TYLOSE CBR grades: 60% NaCMC, highly etherified granules TYLOSE CBR-np grades: 60% NaCMC, highly etherified powders Moisture Reaction CR-P, Viscosity 2oc:

content: approx. 7% on fillins of aqueous-solution: weakly alkaline with TYLOSE CR, CR-w, CBR neutral with TYLOSE CR-n, CBR-np stages in mPa s, 5% solutions, Hoppler viscometer,

TYLOSE CR

1500

TYLOSE CR

15oop

TYLOSE CR

15oow

TYLOSE CR

700n

TYLOSE TYLOSE TYLOSE TYLOSE

CBR CBR CBR CBR

TYLOSE CBR

30 4000 6000 10000 5000np

243

244

Water-Soluble

Resins

HORMRL: Collagens: PEPTEIN CAA: Collagen Amino Acids PEPTEIN CAA are enzymatically prepared natural collagen amino acids produced under closely controlled conditions from high collagen content raw materials. Collagen is the principle structural protein comprising about 30% of the oroteins in animals. An imoortant feature of collagen is that it can be water extracted, purified, and then carefully modified in further chemical processes. PEPTEIN CAA is ideally suited for applications in hair care. PEPTEIN CAA demonstrates its efficacy when used in skin care treatment products by enhancing the moisture binding quality of the product and slowing transepidermal water loss. Dried: POLYPRO 5000: Edible Hydrolyzed Collagen An enzymatic hydrolysate of collagen processed under controlled conditions to produce edible, relatively bland and completely water soluble protein. POLYPRO 5000 contains no carriers or preservatives. A light tan color, free flowing powder, stable for 12 months, is ideal for applications for meal supplement products where protein fortification is needed. It is also an excellent flavor carrier or encapsulator. It can be used to replace 25% of the egg whites in foam systems. POLYPRO 15000: Edible Hydrolyzed Collagen This is an enzymatic hydrolysate of gelatin processed under exacting conditions to produce a bland, tepid, water soluble protein that is nearly clear when in solution. POLYPRO 15000 is an excellent encapsulator and film former. It will gel at refrigerated temperatures at high concentrations (12% or higher typically). POLYPRO 15000 can be used for many food applications. It is especially useful in areas where a slight increase in viscosity is beneficial at room temperature. Liquid: Hydrolyzed Collagen-Unflavored: This liquid collagen, a shelf stable product, is an enzymatic hydrolysis of collagen without added flavor. This product is used as an excellent starting material for liquid dietary protein drinks. Hydrolyzed Collagen-Wild Cherry Flavored: This liquid collagen, a shelf stable product, is an enzymatic hydrolysis of collagen protein with an added cherry flavor. This product used for liquid dietary drinks is excellent.

Geo. A. Hormel & Co.

245

HORMEL: Collagens(Continued): PEPTEIN 2000: PEPTEIN 2000 is an enzymatically hydrolyzed animal protein that is produced under closely controlled conditions from high collagen content raw materials. Collagen is the principle structural protein in animals. It comprises about 30% of the protein in animals. PEPTEIN 2000, hydrolyzed animal protein, is especially beneficial to hair. PEPTEIN 2000 will penetrate through the cuticle layer of the hair into the cortex, actually becoming part of the hair shaft. PEPTEIN 2000 will repair damaged hair, increase tensile strength and elasticity, mend split ends, add body, shine and manageability, improving the total health of the hair. PROTECTEIN: Modified Collagen for Surfactant

Irritation Reduction

Physical Attributes: Odor: Characteristic Color (Gardner): 11 Maximum Chemical: pH (diluted 2:l): 6-7 Solids: 54-56% Microbiological: APC:
for S. aureus

246

Water-soluble

Resins

HORMEL: Gelatins: FLAVORSET Gelatin 150 Bloom type A FLAVORSET gelatin is specially blended for general use. This 30 mesh gelatin is suited to most food applications as it is easily wetted, and placed into solution when heated using equipment commonly found in food plants. It dissolves quicker than coarse mesh gelatin with only slightly more air entrapped in the solution. Modified mesh profiles can be produced as required. Physical Attributes: Bloom (grams): 150+-5 Viscosity (mps): 24+-2 Mesh Profile: % on US Sieve: on on on on in Chemical Attributes: pH: 4.5-5.5 Moisture %: 12.0 max Ash %: 1.5 max Isoionic Point: 8.5-9.5 Odor: Weak bouillon like Color: Ivory

20: Trace 30: 20-35 50: 50-60 100: lo-30 Pan: 1-5

Microbiological Profile: TPC/gm: 3000 max coliform/gm: 10 max Salmonella/25 gm: Negative FLAVORSET Gelatin: 200 Bloom type A Physical Attributes: Bloom (grams): 200+-5 Viscosity (mps): 32+-2 Mesh Profile: % on US Sieve: On On On On In Chemical Attributes: pff: 4.5-5.5 Moisture %: 12.0 max Ash %: 1.5 max Isoionic Point: 8.5-9.0 Odor: Weak bouillon like Color: Ivory

20: Trace 30: 20-35 50: 50-60 100: lo-20 Pan: 1-5

Geo. A. Hormel & Co.

HORMEL: Gelatins(Continued): FLAVORSET Gelatin: 250 Bloom type A Physical Attributes: Bloom (grams): 250+-5 Viscosity (mos): 42+-3 Mesh Profile: % on US Sieve: On On On On In

20: Trace 30: 20-35 50: 50-60 100: lo-20 Pan: l-5

Chemical Attributes: pH: 4.5-5.5 Moisture %: 12.0 max Ash %: 1.5 max Isoionic Point: 8.5-9.5 Odor: Weak bouillon like Color: Ivory Microbiological Profile: TPC/gm: 3000 max coliformlgm: 10 max Salmonella/25 gm: Negative FLAVORSET Gelatin: 300 Bloom Type A Physical Attrubutes: Bloom (grams): 300+-5 Viscosity (mpg): 54+-4 Mesh Profile: % on US Sieve: On On On On In Chemical Attributes: pH: 4.5-5.5 Moisture %: 12.0 max Ash %: 1.5 max Isoionic Point: 8.5-9.5 Odor: Weak bouillon like Color: Ivory Microbiolosical Profile: TPC/gm:-3000 max coliform/gm: 10 max Salmonella/25 gm: Negative

20: Trace 30: 20-35 50: 50-60 100: lo-20 Pan: l-5

247

248

Water-Soluble &sins

HORMRL: Gelatins(Continued): Gummy Type Gelatin: 225 Bloom Gummy-bear gelatin is specially blended for use in starch deposited confections where clarity, viscosity and final elasticity are critical. Coarse mesh gelatin is preferred as it wets easier with less agitation and dissolves with fewer entrapped air bubbles. Physical Attributes: Bloom: 230+-7 Viscosity (mps): 32-36 Mesh Profile: % on US Sieve: On 6: Trace On 8: 5-10 On 20: 70-80 On 40: lo-25 Pan: 1-5 Chemical Attributes: DH: 4.8-5.4 Moisture %: 11.5 max Ash %: 1.5 max POLYPRO 2000 CF 45%: Cherry Flavored Hydrolyzed Gelatin (food grade) This liquid food grade gelatin is enzymatically hydrolyzed under exacting conditions to produce a deep red colored, wild cherry flavored protein. POLYPRO 2000 CF has a sharp but desirable flavor. The preservative system depends upon a low pH for preservation. Physical Attributes: Color: Deep red Odor: Cherry/protein Chemical Attributes: pH: 3.8-4-O Solids %: 45-48 Ash %: 2.0 max Total Nitrogen %: 7.0 min Microbiological Profile: Aerobic Plate Count/Gm: Less than 1000 Coliform/gm: Less than 10 Salmonella/25 gm: Negative

Geo. A. Hormel & Co.

HORMHL: Gelatins(Continued): POLYPRO 5000 XL: Hydrolyzed Gelatin (food grade) This food grade gelatin is enzymatically hydrolyzed under exacting conditions to produce a bland, cold water soluble protein that is remarkably clear when placed in solution. POLYPRO 5000 XL is used when color and flavor must be the lightest possible. It is ideally used for delicate flavored high protein drinks or soups. Physical Attributes: Color: Nearly white Odor: Bland, hardly detectable Chemical Attributes: pH: 4.5-5.5 Moisture %: 6.0 max Ash %: 2.0 max Total Nitrogen %: 16.5 Fat %: Trace Microbiological Profile: Aerobic Plate Count/Gm: Less than 1000 Coliform/Gm: Less than 10 Salmonella/25 Gm: Negative

249

250

Water-Soluble

Resins

HULS AMERICA, INC.: HYDROSIL Silanes: The same applications as traditional hazard. - All new, waterborne - Immediately water-dispersible - Non-flammable - VOC compliant

silanes, but with less

Type/Application: Amine: for fiberglass/nylon polyester; primers, binder resins, phenolics HYDROSIL 2627: Dilution: 3:1-25:1 HYDROSIL 2628: Dilution: 5:1-25:l HYDROSIL 2776: Dilution: 5:1-25:l HYDROSIL 2775: Dilution: 5:1-25:l Epoxy: for binders/urethanes, paint/latex epoxy sealants: HYDROSIL 2759: Dilution: 5:1-25:1

acrylic, potting resins/

Mercapto: sealants/polysulfides, filler pretreatments/EPDM HYDROSIL 2788: dilution: 5:1-25:l Methacrylate: fiberglass/polyester metal primers/acrylic HYDROSIL 2789: dilution: 5:1-25:1

rubber:

finishes:

Vinyl: filler treatment polyolefins: HYDROSIL 2783: dilution: 5:l-25:1 Vinyl-Amino: filler treatment/polyesters, primers/acrylics: HYDROSIL 2781: dilution: 5:1-25:1

ICI Resins US

ICI RESINS US: HALOFLEX Vinyl/Acrylic

251

Terpolymers:

202: Solids: 60 V.0.C2(g/1k 0 pH: Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 60 cps MFFT: IO-13 Weight/Gallon (25C): 10.8 lbs. Chlorine Content %: 64 Prestabilized: No Films exhibit very low moisture/vapor transmission rates (MVTR), excellent corrosion resistance and the potential for very low V.O.C. formulations. End-use applications include: under-body/under-hood coatings, maintenance coatings, rustconverting products and over-print varnishes. 202s:

Solids: 59 ;$.C2'g/1':

0

Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 60 cps MFFT: IO-13 Weight/Gallon (25C): 10.7 lbs. Chlorine Content %: 62 Prestabilized: Yes Prestabilized version of 202. Exhibits better storage stability. Not recommended for tannic acid-based rust-convertor products. 208:

Solids: 57 ;Hp.C2(g/1):

0

Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 60 cps MFFT: 14-17 Weight/Gallon (25C): 9.9 lbs. Chlorine Content %: 49 Prestabilized: No Recommended for topcoats over 202 primers, and for galvanized steel primers. 208 offers improved light and thermal stability.

252

Water-Soluble Resins

ICI RESINS US: HALOFLEX Vinyl/Acrylic

Terpolymers(Continued):

251: Solids: 55 v.o.c12(g/l): 0 pH: Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 60 cps MFFT: IO-13 Weight/Gallon (25C): 9.9 lbs. Chlorine Content %: 30 Prestabilized: Yes Improved blocking resistance and lower dirt pick-up properties. Recommended for topcoats over 202 primers. 307:

Solids: 54 V.O.C. (g/l): 0 pH: l-2 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 60 cps MFFT: 25C Weight/Gallon (25C): 9.8 lbs. Chlorine Content %: 43 Prestabilized: Yes Hardest HALOFLEX resin. Recommended as a modifier coating formulations to improve hardness.

in HALOF ,EX

312:

Solids: 50 ;Hp.C2(g/1):

0

Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 60 cps MFFT:
ICI Resins US

ICI RESINS US: HALOFLEX Vinyl/Acrylic

Terpolymers(Continued):

402: Solids: 60 v.0.c (g/l): 0 pH: l-2_ Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 60 cps MFFT: lo:13 Weight/Gallon (25C): 10.5 lbs. Chlorine Content %: 63 Prestabilized: No Barrier coatings for corrugated and solid fiber board. Coatings may be overprinted and glued. FDA 21 CFR compliance: 176.170. 404: Solids: 60 V.O.C. (g/l): 0 pH: l-2 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 60 cps MFFT: 6-9 Weight/Gallon (25C): 10.5 lbs. Chlorine Content %: 55 Prestabilized: No Alternative to 402 where coalescence at lower temperature is required. FDA 21 CFR compliance: 176.170.

253

254

Water-Soluble Resins

ICI RESINS US: NRCCRYL Acrylic Emulsions: A-601: Type: Acrylic Solids: 32% XYdC# (g/l): 300 : 33 pH: 7.7 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 100 cps MFFT: 3C Sward Hardness: 34 Weight/Gallon: 0.5 lbs. Outstanding exterior durability, wide adhesion latitude, and good pigment wetting characteristics. For use in general metal and plastic finishing, paper and wall board coatings. A-603A: Type: Acrylic Solids: 36.5% xc&C; ($1: 230 pH: 710 Freeze/Thaw Stability: Passes 5 cycles Viscosity (25C): 180-cps MFFT: 2C Sward Hardness: 34 Weight/Gallon: 8.7 lbs. Excellent brushing properties and sandability. a non-yellowing brushing varnish.

For use as

A-612: Type: Acrylic Solids: 32% I,&"; (g/l): 325 .r: 39 pH: 7.7 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 150 cps MFFT: -lOC Sward Hardness: 32 Weight/Gallon: 8.5 lbs Replacement product for A-602 with different cosolvent blend. Recommended for use in clear and pigmented board coatings.

ICI Resins US

ICI RESINS US: NEOCRYL Acrylic Emulsions(Continued): A-61 4:

Type: Acrylic Solids: 32% ;,M&; (g/l): 207 :

39

pH: 8.0 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 200 cps MFFT: -lOC Sward Hardness: 26 Weight/Gallon: 8.5 lbs. Replacement product for A-604 with different cosolvent blend. Recommended for use in clear and pigmented lacquers for wood and plastics. A-621:

Type: Acrylic Copolymer Solids: 40% ;c~dC;:(;;l): 187 pH: 8.3 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 300 cps MFFT: 11C Sward Hardness: 56 Weight/Gallon: 8.5 lbs. High application solids and high pigmented gloss. Rapid tack-free time. Recommended for use on metals and plastics as a sole vehicle or blended with water reducible alkyds. A-622: Type: Acrylic Copolymer Solids: 32% ;,&C; (g/l): 263 : 51 pH: 8.0 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 100 cps MFFT: 9C Sward Hardness: 34 Weight/Gallon: 8.5 lbs. Exceptional humidity, water and corrosion resistance. Wide adhesion latitude and broad compatibility with other film formers including water reducible alkyds and urethane dispersions. Recommended for use in high performance industrial primers and topcoats for automotive and farm implements.

255

Water-Soluble Resins

256

ICI RESINS US: NEOCRYL Acrylic Emulsions(Continued): A-623:

Type: Acrylic Copolymer Solids: 35% LLL~C~ (g/l): 232 :

36

pH: 7.3 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 180 cps MFFT: 1OC Sward Hardness: 48 Weight/Gallon: 8.5 lbs. Fast hardness development, excellent gasoline resistance and solvent resistance. For use in high performance air dry industrial primers and topcoats where block resistance is critical. A-625:

Type: Acrylic Copolymer Solids: 45% V.O.C. (g/l): 0 Acid #: 33 pH: 7.8 Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 130 cps MFFT: 35C Sward Hardness: 40 Weight/Gallon: 8.6 lbs. Good balance of properties for general use on metal and plastic substrates where economy is of primary concern. Can _ be modified with water reducible alkyds, A-630: Type: Acrylic Copolymer Solids: 44.5% 28 pH: 7.7 Freeze/Thaw Stability: Passes 3 Cycles Viscosity (25C): 150 cps MFFT: 36C Sward Hardness: 56 Weight/Gallon: 8.6 lbs. Uncoalesced version of A-621. Can be formulated into roll, flow or dip coatings that exhibit excellent gloss and hardness.

ICI Resins US

257

ICI RESINS US: NEOCRYL Acrylic Emulsions(Continued): A-633: Type: Acrylic Copolymer Solids: 42% ;;$C# (g/l): 0 : 34 pH: 1.5 Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 40 cps MFFT: 49C Sward Hardness: 44 Weight/Gallon: 8.6 lbs. Wide adhesion latitude with excellent corrosion and chemical resistance. For use in pigmented primers or topcoats on plastics requiring good chemical resistance. A-634: Type: Acrylic Copolymer Solids: 35% X&C; (g/l): 270 : 20 pH: 6.5 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 200 cps MFFT: OC Sward Hardness: 44 Weight/Gallon: 8.5 lbs. Excellent print resistance and clarity. Suitable for many types of wood furniture applications including fine furniture and kitchen cabinets. A-636: Type: Acrylic Copolymer Solids: 35% X&C; (g/l): 274 : 23 pH: 6.4 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 300 cps MFFT: -3C Sward Hardness: 26 Weight/Gallon: 8.6 lbs. Rapid hardness development and short tack-free time. For use on high speed board coating lines where block resistance under low temperature curing conditions is required.

258

Water-Soluble

Resins

ICI RESINS US: NEOCRYL Acrylic Emulsions(Continued): A-639: Type: Acrylic Copolymer Solids: 45% ;;J;C# (g/l): 0 : 42 pH: 6.5 Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 160 cps MFFT: 53C Sward Hardness: 54 Weight/Gallon: 8.6 lbs. Suggested for board coatings, metal coatings, and paper coatings where block resistance and economy are important. An uncoalesced copolymer used to modify water-borne alkyds to improve dry time. Also used as an economical let-down vehicle for flexographic inks. FDA 2lCFR compliance: 176.180, 175.105. A-640: Type: Acrylic Copolymer Solids: 40% ;,p;c; (g/l): 0 : 50 pH: 8.0 Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 50 cps MFFT: 40C Sward Hardness: 34 Weight/Gallon: 8.6 lbs. Uncoalesced version of A-622. Broad compatibility with water reducible alkyds and urethane dispersions. For use in primers and topcoats with excellent water, humidity and corrosion resistance. A-640 can also be used as a let-down vehicle with excellent adhesion to treated polypropylene. Exhibits high gloss and fast dry characteristics, and excellent adhesion to a variety of plastics. A-644: Type: Acrylic Copolymer Solids: 40% V.O.C. (g/l): 102 Acid #: 31 pH: 7.1 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 30 cps MFFT: 41C Sward Hardness: 40 Weight/Gallon: 8.6 lbs. Outstanding mar resistance, sandability, and block resistance. For use in clear and pigmented coatings including high build dip applications for many types of wood articles.

ICI Resins US

259

ICI RESINS US: NRCCRYL Acrylic Emulsions(Continued): A-645: Type: Acrylic Copolymer Solids: 40% ;;J;C# (g/l): 0 : 44 pH: 7.5 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 50 cps MFFT: 49C Sward Hardness: 48 Weight/Gallon: 8.6 lbs. Uncoalesced version of A-623. For use in clear and pigmented air dry coatings which require exceptional solvent resistance. A-650: Type: Acrylic Copolymer Solids: 40% V.O.C. (g/l): 0 Acid #: 23 pH: 6.3 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 50 cps MFFT: 31C Sward Hardness: 44 Weight/Gallon: 8.6 lbs. Uncoalesced version of A-634. Can be formulated for use in wood furniture coatings which require exceptional clarity and alcohol resistance. A-655: Type: Acrylic Copolymer Solids: 45% ;,p,c.# (g/l): 0 : 34 pH: 7.8 Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 250 cps MFFT: 34C Sward Hardness: 40 Weight/Gallon: 8.7 lbs. Wide adhesion latitude including excellent adhesion to "oily" substrates and many plastics. For use as primer or topcoat for engine components, business machines, and metal castings.

260

Water-Soluble Resins

ICI RESINS US: NEOCRYL Acrylic Emulsions(Continued): A-1044:

Type: Acrylic Copolymer Solids: 47% ;,pdc.# (g/l): 0 :9 pH: 9.5 Freeze/Thaw Stability: Passes 3 Cycles Viscosity (25C): 30 cps MFFT: 12C Weight/Gallon: 8.8 lbs. An easy to use Portland cement additive which increases its flexural, compressive and tensile strength. Mortars have a wide adhesion latitude for concrete, masonry, brick and metals. They resist many industrial chemicals and are UV resistant. A-l

049:

Type: Acrylic Copolymer Solids: 34% ;,J&$ ($1,: 223 pH: 7.5 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 40 cps MFFT: 9C Sward Hardness: 38 Weight/Gallon: 8.6 lbs. A polymer with excellent adhesion and plasticizer migration resistance. It demonstrates excellent hardness, flexibility and water resistance. A-1052: Type: Acrylic Copolymer Solids: 49% pH: 8.5 Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 200 cps MFFT: 7CSward Hardness: 14 Weight/Gallon: 8.8 lbs. An acrylic copolymer which can be used to formulate inks for printing on treated polyethylene. It exhibits excellent gloss, rapid dry time and superior press runnability. Complies with FDA 2lCFR 176.170.

ICI Resins US

261

ICI RESINS US: NEOCRYL Acrylic Emulsions(Continued): A-1054: Type: Acrylic Copolymer Solids: 45% X&C# (g/l): 0 : 57 pH: 8.5 Freeze/Thaw Stability: Passes 3 Cvcles Viscosity (25C): 200-cps MFFT: 18C Sward Hardness: 30 Weight/Gallon: 8.7 lbs. An acrvlic copolymer which can be formulated into flexographic and gravure-inks, for printing on unprimed aluminum foil. Can also be formulated into high gloss overprint varnishes. Has good pigment wetability, excellent water resistance and complies with FDA 2lCFR 176.170. A-5030: Type: Acrylic Copolymer Solids: 38% V.O.C. (g/l): 0 pH: 9.0 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 150 cps MFFT: COC Weight/Gallon: 8.7 lbs. An acrylic copolymer used as an adhesion promoter printing on treated polyethylene.

for

A-5030: Type: Acrylic Copolymer Solids: 52% V.O.C. (g/l): 0 Acid #: 50 pH: 9.0 Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 700 cps MFFT: 7C Sward Hardness: 14 Weight/Gallon: 8.8 lbs. A high solids acrylic copolymer designed for rapid drying. Has excellent adhesion to treated polyethylene. Exhibits excellent gloss, superior press runnability and has broad FDA compliance.

262

Water-Soluble Resins

ICI RESINS US: NEOCRYL Acrylic Emulsions(Continued): A-5050: Type: Acrylic Copolymer Solids: 48% l;&C.# (g/l): 0 : 72 pH: 8.6 Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 600 cps MFFT: OC Weisht/Gallon: 8.6 lbs. A high gloss acrylic copolymer emulsion which provides room temperature film formation and 400F block resistant over print varnishes. FDA 21 CFR compliance: 175.105, 176.170, 176.180. A-6037: Type: Acrylic Copolymer Solids: 49% ;,pdci:($l): 0 pH: 8.6 Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 257 cps MFFT: 50C Sward Hardness: 97 Weight/Gallon: 8.8 lbs. High solids, uncoalesced, suggested for wood, metal, plastic coatings which require hardness, block resistance, water resistance and high gloss. Can be used as a grind vehicle to upgrade gloss of other acrylics. ET-8: Type: Acrylic Copolymer Solids: 40% XJdC# (g/l): 0 : 72 pH: 5.0 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 1500 cps MFFT: 20C Weight/Gallon: 8.8 lbs. A soft alkali soluble acrylic emulsion with excellent adhesion to plastics, films and foils. Films exhibit excellent clarity, toughness and flexibility as well as high alcohol tolerance. BT-8 heat seals at 225F. FDA 2lCFR compliance: 175.105, 175.300, 175.320, 176.180.

ICI Resins US

263

ICI RESINS US: NEOCRYL Acrylic Emulsions(Continued): BT-24: Type: Acrylic Copolymer Solids: 40% V.O.C. (g/l): 0 Acid #: 17 pH: 5.0 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 300 cps MFFT: 8C Weight/Gallon: 8.8 lbs. High gloss and good pigment wetting with excellent adhesion to fiberglass-reinforced polyester (SMC). For use with water reducible monomeric melamines in thermoset svstems. When amine solubilized, suggested as a pigment grinding-vehicle for waterborne coatings. BT-24 has good adhesion to various flexible films. BT-44: Type: Acrylic Copolymer Solids: 40% ;,ydc;:(;;l): 0 pH: 9.0 Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 250 cps MFFT: 97C Weight/Gallon: 8.9 lbs. A very hard acrylic with excellent heat resistance. Excellent pigment dispersion resin. Has wide adhesion latitude and can be used in flexographic and gravure inks, as well as overprint varnishes. FDA 21 CFR compliance: 175.105, 175.300, 176.170, 176.180. BT-175: Type: Acrylic Copolymer Solids: 45% ;;C&# (g/l): 0 : 100 pH: 3.0 Freeze/Thaw Stability: Keep from Freezing Viscosity (25C): 500 cps MFFT: 26C Weight/Gallon: 8.8 lbs. When solubilized, has low viscosity at high solids with stable viscosity over a wide alkaline pH range. Excellent pigment dispersant. Recommended for use as a pigment grinding vehicle for water-borne coatings. BT-175 can be formulated into high performance flexographic and gravure inks.

264

Water-Soluble

Resins

ICI RESINS US: NEOCRYL Acrylic Emulsions(Continued): BT-520: Type: Acrylic Copolymer Solids: 45% pH: 7:0 Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): lOO_cps MFFT: 26C Weight/Gallon: 8.9 lbs. Hard films with excellent water and corrosion resistance. For use as a water-borne coating for bright metals such as brass and chrome. BT-520 is also an excellent pigment grinding vehicle. cc-lo: Type: Acrylic Polymer Solids: 40% ;;o.;.o(g/l): 100 : . Freeze/Thaw Stability: Passes 3 Cycles Viscosity (25C): 10 cps MFFT: 14C Weight/Gallon: 8.8 lbs. A polymer designed for sealer formulas for use on resilient tile, terrazzo and cement. It effectively seals the floor providing an excellent base for future topcoats of floor finish. CL-300: Type: Acrylic Polymer Metal Complexed Solids: 40% V.;.$.o(g/l): 0 . Freeze/Thaw Stability: Passes 3 Cycles Viscosity (25C): 15 cps MFFT: 50C Weight/Gallon: 8.9 lbs. A durable emulsion with detergent resistance. Polishes based on CL-300 exhibit clarity, good gloss and leveling, outstanding slip and powdering resistance, plus exceptional black heel mark and scuff resistance, and resistance to dirt pickup.

ICI Resins US

265

ICI RESINS US: NEOCRYL Acrylic Emulsions(Continued): CL-340: Type: Acrylic Solids: 40% ;;;.;.5(4/1): 0 . Freeze/Thaw Stability: Passes 3 Cycles Viscosity (25C): 200 cps Weight/Gallon: 8.8 lbs. A water-borne acrylic alkali soluble resin specially designed to improve the gloss and leveling of floor polishes. Easy to use and will not add color to the finish. SR-203: Type: Acrylic Copolymer Metal Complexed Solids: 38% ;;;.;.o(g/l): 0

.

Freeze/Thaw Stability: Passes 3 Cycles Viscosity (25C): 15 cps MFFT: 65C Weight/Gallon: 8.0 lbs. A general purpose, low cost emulsion. Floor finishes based on SR-203 demonstrate outstanding gloss and scuff resistance in combination with excellent black heel mark end powdering . resistance. SR-204: Type: Acrylic Copolymer Metal Complexed Solids: 40% V.O.C. (g/l): 0 pH: 8.7-9.2 Freeze/Thaw Stability: Passes 3 Cycles Viscosity (25C): 150 cps MFFT: 65C Weight/Gallon: 8.8 lbs A high gloss emulsion with maximum high solids stability. Designed for use in high performance industrial floor polishes. Formulations based on it exhibit high gloss, excellent wear properties and exceptional detergent resistance with very easy removability.

266

Water-Soluble Resins

ICI RESINS US: NEOCRYL Acrylic Emulsions(Continued): SR-270: Type: Acrylic Copolymer Metal Complexed Solids: 40% V.$.;.o(g/l): 0 . Freeze/Thaw Stability: Passes 3 Cycles Viscosity (25C): 25 cps MFFT: 51C Weight/Gallon: 8.9 lbs. An emulsion with exceptional durability. Floor finishes based on SR-270 demonstrate outstanding black heel mark resistance and black mark rub out. Excellent gloss, powdering and water resistance are combined with detergent resistance and ammonia removability. SR-276: Type: Acrylic Copolymer Metal Complexed Solids: 40% ;h;.;.5(g/1): 0 . Freeze/Thaw Stability: Passes 3 Cycles Viscosity (25C): 30 cps MFFT: 53C Weight/Gallon: 8.9 lbs. A general purpose emulsion. Floor finishes based on SR-276 demonstrate high gloss, optimum flow and leveling combined with detergent resistance and ammonia removability. SR-2001: Type: Acrylic Copolymer Metal Complexed Solids: 40% ;Hp.;.g(g/l): 0 . Freeze/Thaw Stability: Passes 3 Cycles Viscosity (25C): 50 cps MFFT: 70C Weisht/Gallon: 8.8 lbs. A high.gloss polymer designed for maximum scuff and abrasion resistance. Floor finishes based on SR-2001 provide the highest protection of all of ICI's acrylic floor polish polymers.

ICI Resins US

ICI RESINS US: NEOREZ Water-Borne

Polyurethane

267

Dispersions:

R-940: Type: Aromatic Solids: 31% ;$.;.3(g/1): 365 . Weight/Gallon: 8.8 lbs. Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 70 CDS Sward Hardness; 40 Tensile Strength: 7,500 psi Elonaation: 200% GeneGal purpose urethane dispersion designed for chemical resistance and durability. At ambient temperatures, hard and glossy, yet tough and flexible films are formed which exhibit exceptional resistance to abrasion, water and solvents. R-940 can be crosslinked to further enhance properties. R-940 forms films with tensile and modulus values similar to R-960. For use in clear and pigmented coatings on metal, wood and plastics. R-940 has a wide range of water-borne acrylic compatibility. Can be used in flexographic and gravure inks and overprint varnishes to improve water, abrasion, rub and scuff resistances. R-941: Type: Aromatic Solids: 31% ;L$.;.8(g/1): 317 Weish;/Gallon: 8.8 lbs. Freeze/Thaw Stability: Passes 3 Cycles Viscosity (25C): 70 cps Sward Hardness: 42 _ Tensile Strength: 5,300 psi Elongation: 210% A durable urethane dispersion designed for chemical and water resistance. At ambient temperatures, hard and glossy, vet touch and flexible films are formed which exhibit exceptional resistance to abrasion, water and solvents. Used to modify floor polishes. Can be cross-linked to further enhance properties.

268

Water-Soluble Resins

ICI RESINS US: NEOREZ Water-Borne (Continued):

Polyurethane

Dispersions

R-960: Type: Aliphatic Solids: 33% ;H;.;.o(g/l): 400 . Weight/Gallon: 8.8 lbs. Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 300-cps Sward Hardness: 44 Tensile Strength: 8,000 psi Elongation: 200% Forms hard films with high tensile and modulus values. For use in tough, UV resistance clear and pigmented coatings on metal, wood and plastics. Also recommended for use in tough, UV resistant clear overprint varnishes and pigmented ink systems. Has wide compatibility with water-borne acrylics. Used to improve film properties of inks and overprints. R-962: Type: Aliphatic Solids: 33% ;H;.;.o(g/l): 412 Weigh;/Gallon: 8.8 lbs. Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 250 cps Sward Hardness: 6 Tensile Strength: 3,500 psi Elongation: 500% Forms flexible films with high elongation values. Suggested for light stable, abrasion resistant coatings applied to flexible plastics, elastomers, and foams. Modified for acrylic based adhesives to improve adhesion to vinyl, polyester, polyethylene and polypropylene films. Especially useful to modify acrylics such as NEOCRYL A-5044. R-966: Type: Aliphatic Solids: 33% V.O.C. (g/l): 37 pH: 7.5 Weight/Gallon: 8.6 lbs. Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 30 cps Sward Hardness: 32 Tensile Strenath: 6.000 osi Elongation: 225% ’ * Cosolvent free, uv resistant with ultimate hardness rapidly developed after water evaporation. For use in clear and pig- _ mented coatings on textiles, rubber and plastics.

ICI Resins US

ICI RESINS US: NEOREZ Water-Borne (Continued):

Polyurethane

269

Dispersions

R-967: Type: Aliphatic Solids: 40% ;H;.;.o(g/l): 25 . Weisht/Gallon: 8.6 lbs. FreezejThaw Stability: Keep from Freezing Viscosity (25C): 250 cps Sward Hardness: 6 Tensile Strength: 4,000 psi Elongation: 500% Similar to R-966, but softer and more extensible. R-972: Type: Aliphatic Solids: 34% L;.;.o(g/l): 245 Weigh;/Gallon: 8.6 lbs. Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 150 cps Sward Hardness: 6 Tensile Strength: 7,500 psi Elongation: 550% A soft, fully reacted aliphatic urethane dispersion with a wide range of water-borne acrylic compatibility. Adds plasticizer resistance for flexographic and rotogravure inks for vinyl wallpaper. Has best (urethane) press runnability. R-9409: Type: Aromatic Solids: 31% V.O.C. (g/l): 378 pH: 8.0 Weight/Gallon: 8.9 lbs. Freeze/Thaw Stability: Passes 3 Cycles Viscosity (25C): 75 cps Sward Hardness: 44 Elongation: 300% A general purpose aromatic MD1 urethane which has exceptional water and chemical resistance. R-9409 also has outstanding film strength which provides superior abrasion resistance.

270

Water-Soluble Resins

ICI RESINS US: NEOREZ Water-Borne (Continued):

Polyurethane

Dispersions

R-9637: Type: Aliphatic Solids: 36% V.O.C. (g/l): 252 pH: 8.0 Weight/Gallon: 8.8 lbs. Freeze/Thaw Stability: Passes 5 Cycles Viscosity (25C): 250-cos Sward Hardness; 58 _ Tensile Strength: 8,000 psi Elongation: 200% Higher solids, lower solvent containing product, similar to R-960. For use in tough, UV resistant coatings on wood, plastic and metal substrates. R-9920: Type: Aromatic Solids: 31% ;;I;.;.o(g/l): 300 . Weight/Gallon: 8.8 lbs. Freeze/Thaw Stability: Passes 3 Cycles Viscositv (25C): 75 CDS Sward Hardness; 50 _ Tensile Strength: 500 psi Elonaation: 200% A durable ready-to-use water-borne aromatic urethane designed for wood floor finishing. It provides a light colored coating which is water and chemical resistant. Easy to clean up with water.

ICI Resins US

ICI RESINS US: NECTAC Water-Borne

Polymers

271

for Adhesives:

A-5044: Type: Acrylic Solids: 47% pH: 9.0 Viscosity (25C): 30 cps Weight/Gallon: 8.0 lbs. FDA 21 CFR Conformance: 175.105/175.300/176.170/176.180/ 177.1010 Heat Seal Temp.: 250F Modifier for urethane polymers. Improves compatibility of DA-5012 with other emulsion systems. A-5117: Type: Acrylic Solids: 43% pH: 7.5 Viscositv (25C): 50 CDS Weight/Gallon:-8.7 lb:. FDA 21 CFR Conformance: 175.105 High gloss, non-blocking polymer ideally suited for blister packaging applications. DA-5102: Type: Acrylic Solids: 47% DH: 10.5 Viscosity (25C): 50 cps Weight/Gallon: 8.7 lbs. FDA 21 CFR Conformance: 175.105 Heat Seal Temp: 150F Amine-functional acrylic which reacts with epoxy resins at room temperature. Forms boil-resistant bonds for food packaging applications. DA-5119: Type: Acrylic Solids: 45% pH: 7.0 Viscositv (25C): 50 CDS Weight/Gallon:'8.6 lb:. FDA 21 CFR Conformance: 175.105/175.300/176.170/176.180 Heat Seal Temp: 275F Base polymer for staple adhesives and pharmaceutical blister packaging. Excellent MEX resistance without crosslinking. Adhesion to polypropylene.

272

Water-Soluble Resins

ICI RESINS US: NEOTAC Water-Borne (Continued):

Polymers for Adhesives

DA-5120: Type: Acrylic Solids: 48% pH: 7.0 Viscosity (25C): 25 cps Weight/Gallon: 8.6 lbs. FDA 21 CFR Conformance: 175.105/175.300 Heat Seal Temp: 275F Base polymer for high performance 1idding adhes ives used in food packaging. R-9314: Type: Aliphatic Urethane Solids: 40% pH: 8.0 Viscosity (25C): 200 cps Weight/Gallon: 8.8 lbs. Heat Seal Temp: 275F Non-yellowing urethane with excellent adhesion to vinyl, polyethylene, nylon and polycarbonate films. High heat and solvent resistance. Adhesion to glass. DR-9611: Type: Aliphatic Urethane Solids: 35% pH: 9.0 Viscosity (25C): 400 cps Weight/Gallon: 8.8 lbs. FDA 21 CFR Conformance: 175.105 Heat Seal Temp: 150F Base for low temperature laminating adhesives for flexible packaging. Modify with HALOFLEX 312 and DA-5119 for meat and cheese packaging. DR-9617: Type: Aliphatic Urethane Solids: 35% pH: 8.0 Viscosity (25C): 100 cps Weight/Gallon: 8.7 lbs. Heat Seal Temp.: 175F Crystallizing polymer for high strength industrial applications. Excellent adhesion to polyester and polypropylene. Excellent viscosity stability on aging.

ICI Resins US

ICI RESINS US: NEOTAC Water-Borne (Continued):

Polymers

for Adhesives

DR-9619: Type: Aliphatic Urethane Solids: 35% pH: 8.0 Viscosity (25C): 100 cps Weight/Gallon: 8.7 lbs. Heat Seal Temp: 275F Non-blocking urethane polymer with improved adhesion to untreated polyester films and copper. Produces optically clear films with excellent heat and solvent resistance. Excellent viscosity stability on aging.

273

274

Water-Soluble Resins

MOBAY CORP.: BAYBOND Aqueous Polyurethane

Dispersions:

Outstandina Features Include: Dispersion Stability Abrasion Resistance Substrate Adhesion Solvent/Water Resistance Elasticity Hydrolytic Stability Light Stability Typical Applications: - High performance surface coatings - Concrete - Metal - Glass - Plastic - wood - Inks and overprints - Glass fiber sizings - Textile coatings - Leather and vinyl coatings - Composite primers Aqueous Polyurethane

Dispersion

Product Line:

BAYBOND Dispersion Grades: --__---_xw-110-2: Polyester-polyurethane backbone containing carboxylate groups. 2H pencil hardness with 160% elongation at break. Very good abrasion, chemical and solvent resistance. Good hydrolytic stability. Topcoat applications or blending partner. XW-114: Polyester-polyurethane backbone containing sulfonate groups. Ultimate tensile of 4,000 psi with 550% elongation at break. Good chemical and solvent resistance. Very good hydrolytic stability. Primer application or soft blending partner. PU-402A: Film properties similar to XW-114 with only 1% cosolvent. XW-121/123: Polycarbonate-polyurethane backbone containing carboxylate groups. XW-121 is similar to XW-110-2 having an ultimate tensile of 6,000 psi with 160% elongation at break. 123 is softer with an ultimate tensile of 5,000-6,000 psi and 350% elongation at break. Both have outstanding hydrolytic stability. XW-116 Crosslinker: A blocked, water dispersible, polyisocyanate which can be used to crosslink active hydrogen containing aqueous resins-E.G. BAYBOND dispersions and epoxies. IMPRANIL DLN Dispersion: Forms a soft film with good hand. 700% elongation at break with an ultimate tensile of 3,000 psi. Particularly well suited for textile applications. 0% cosolvent. Imported from Bayer AG. Note: All of MOBAY's aqueous polyurethane stable.

dispersions

are light

Mobay

MOBAY CORP.: BAYBOND Aqueous Polyurethane BAYBOND: --XW-110-Z: % Solids: 35 % Co-Solvent: 15 Viscosity (cps): lOO-1,000 pH: 7.5-9.0 (75F, 20% relative humidity): Tack free: 2 Mar free: 35 xw-114: % Solids: 40 % Co-Solvent: 10 Viscosity (cps): 50-500 pH: 6.0-7.5 (75F, 20% relative humidity): Tack free: 2 Mar free: 12 PU-402A: % Solids: 40 % Co-Solvent: 1 Viscosity (cps): IOO-1,000 pH: 6.0-7.5 (75F, 20% relative humidity): Tack free: 2 Mar free: 7 XW-121: % Solids: 35 % Co-Solvent: 15 Viscosity (cps): 700-900 pH: 7.5-9.0 (75F, 20% relative humidity): Tack free: 2 Mar free: 25 XW-123: % Solids: 35 % Co-Solvent: 12 Viscosity (cps): 600-800 pH: 7.5-9.0 (75F, 20% relative humidity): Tack free: 2 Mar free: 60

275

Dispersions(Continued):

276

Water-Soluble

Resins

MOBAY CORP.: BAYBOND Aqueous Polyurethane

Dispersions(Continued):

BAYBOND: -~ XW-116: % Solids: 70 % Co-Solvent: Crosslinker

30

IMPRANIL DLN: % Solids: 40 Viscosity (cps): SO-500 pH: 6.0-7.5 (75F, 20% relative humidity): Tack free: 2 Mar free: 7 Physical Film Properties: BAYBOND: xw-110-2: Yield Modulus: 4500 100% Modulus: 4200 Ultimate Tensile: 5400 % Elongation at Break: 160 m-114:

100% Modulus: 500 200% Modulus: 700 300% Modulus: 1000 Ultimate Tensile: 4000 % Elongation at Break: 550 PU-402A: 100% Modulus: 700 200% Modulus: 900 300% Modulus: 1300 Ultimate Tensile: 5000 % Elongation at Break: 540 xw-121: Yield Modulus: 4800 100% Modulus: 4500 Ultimate Tensile: 6000 % Elongation at Break: 160

Mobay

MOBAY CORP.: BAYBOND Aqueous Polyurethane

Dispersions(Continued):

Physical Film Properties(Continued): EN-123: 100% Modulus: 800 200% Modulus: 1500 300% Modulus: 3600 Ultimate Tensile: 5000 % Elongation at Break: 350 IMPRANIL DLN: 100% Modulus: 200 200% Modulus: 300 300% Modulus: 400 Ultimate Tensile: 3000 % Elongation at Break: 700 Film Properties: BAYBOND: ~~_ xw-110-2: Pencil Hardness: 2H Pendulum Hardness (Set): 120 xw-114: Pencil Hardness: F Pendulum Hardness (Set): 30 PU-402A: Pencil Hardness: H Pendulum Hardness (Set): 30 EN-121: Pencil Hardness: 2H Pendulum Hardness (Set): 130

XW-123:

Pencil Hardness: H Pendulum Hardness (Set): 35 IMPRANIL DLN: Pencil Hardness: 3B Pendulum Hardness (Set): 30

277

278

Water-Soluble Resins

MONSANTO CHEMICAL CO.: RESIMENE Amino Crosslinker High Solids Methylated Melamines

Resins:

(HSMM):

RESIMENE 714: Partially methylated melamine resin with rapid uncatalyzed cure response. Supplied at 80% solids in water. Intended for aqueous coatings. RESIMENE 717: Designed to give rapid low temperature crosslinking, without the need for strong acid catalysis. Alkylation alcohol is methanol with product supplied at 84% solids in n-butanol. Used in high solids coatings and in water-borne coatings (with co-solvent). RESIMENE 730, 731: Versatile solvent and water-soluble melamine resins with fast uncatalvzed cure resnonse and sood uncatalvzed enamel stability. RESIMENR 730 resin is supplied-at 90% solids in isopropyl al- cohol. RESIMENE 731 is an 80% solids version of RESIMENE 730; the lower viscosity of RESIMENE 731 makes it ideal for bulk shipments. RESIMENE 735: Versatile solvent and water-soluble melamine with good compatibility, fast cure response, and excellent uncatalyzed enamel stability. These properties lead to high gloss, flexible and impact-resistant films. RESIMHNE 740: Versatile solvent and water-soluble melamine. Excellent cure response is achieved with minimal catalyst (less than 0.2% pTSA solids on melamine solids) or high acid number vehicles. The cure response is coupled with excellent enamel stability and compatibility. RESIMHNE 741: A faster cure version of 740. Unique balance of properties contributed makes this a very versatile product. Used in both aqueous and solvent-borne coatings due to excellent balance between compatibility and cure response.

Monsanto Chemical Co.

MONSANTO CHEMICAL CO.: RESIMENE Amino Crosslinker (Continued): High Solids Methylated Melamines

279

Resins

(HSMM) (Continued):

RESIMENE 745: Solvent soluble (active solvent) and water extendable melamine. Its monomeric composition offers excellent catalyzed cure response, stability and compatibility. Very versatile catalyzed cure response between 180F to well over 600F. Outstanding film flexibility and toughness are generally achieved. Commercial liquid hexamethoxymethyl melamine. RESIMENE 747: Slightly higher molecular weight than RESIMENE 745 resin. In many coating systems provides for excellent catalyzed cure response with very good film flexibility and toughness. Used in both solvent and aqueous coatings. Liquid hexamethoxymethyl melamine. Modified HSMM: RESIMENE 797: Offers excellent catalyzed cure response combined with toughness, hardness, adhesion and flexibility. Modified solvent soluble (active solvent) melamine containing 20% styrene ally1 alcohol (solids basis). RESIMENE 2040: Modified HS melamine containing 40% styrene ally1 alcohol (solids basis) offering significant lower temperature catalyzed cure with excellent coating hardness and toughness. Recommended primarily for wood coatings. RESIMHNE 2060: Another modified HS melamine containing 60% styrene ally1 alcohol (solids basis). Provides for very fast cure at low temperatures with excellent gloss and scratch resistance. Used primarily for overprint varnishes on paper, film and foil coatings.

280

Water-Soluble Resins

MONSANTO CHEMICAL CO.: RESIMENE Amino Crosslinker (Continued):

Resins

High Solids Butylated Melamine: RESINBNE 750: 80% solids butylated melamine resin. Has same level of compatibility as lower solids conventional butylated types, but lower molecular weight allows higher solids. Low threshold cure response temperature. Very high compatibility and enamel stability. Excellent flow properties and resistance to cratering. Solvent soluble (active solvent) and water extendable with cosolvent. High Solids Methylated/Butylated

Melamines:

RESIMHNE 753: Hexaalkoxymethyl melamine of mixed methoxy/butoxy functionality. Primarily methoxy--but 10% butoxy groups improve resistance to cratering and enhance flow properties and compatibility. Solvent soluble (active solvent) and water extendable with cosolvent. RESIMENE 755: Another mixed methyl-butyl type, with approximately equivalent levels of methoxy and butoxy functionality. Hexaalkoxymethyl melamine. Exhibits better flow properties, significantly better resistance to hydrolysis, less tendency to crater than hexamethoxy resins. Solvent soluble (active solvent) and water extendable with co-solvent. RESIMBNE 757: Mixed methyl-butyl type with approximately 75125 ratio of methoxy to butoxy functionality. The balance of monomeric/ oligomeric species in 757 contributes to the cure response of high solids coatings, especially at reduced temperatures. RESIMENE 764: Essentially a fully butylated, 98% N.V. coetherified melamine, offering optimum catalyzed cure response with superior rheological contributions typical of a non-polar crosslinker. Superior as a grinding medium for high solids mill bases which can be reduced for solvent or water reducible coating systems.

Monsanto Chemical Co.

MONSANTO CHEMICAL CO.: RESIMENE Amino Crosslinker (Continued): High Solids Methylated Melamine: 747:

% Solids-Weight: 98 min. Viscosity, G-H: Y-Z3 Water Solubility: Co-solvent Lbs/Gallon: 9.9-10.1 Flash Point F(C): 230+(110+) Alkylation: Methylated Monomer Content, %: 62 Degree of Polymerization: 1.3 Degree of Alkylation: Very High Methyl01 Content: Very Low Equivalent Weight: 75-185

745: % Solids-Weight: 98 min. Viscositv. G-H: Y-Z2 Water Soiubility: Co-solvent Lbs/Gallon: 9.9-10.1 Flash Point F(C): 230+(110+) Monomer Content, %: 67 Degree of Polymerization: 1.2 Degree of Alkylation: Very High Methyl01 Content: Low Equivalent Weight: 75-185 741: % Solids-Weight: 89 Viscosity, G-H: W-Z3 Solvent: -Isopropanol Water Solubility: Co-solvent Lbs/Gallon: 9.7-9.9 Flash Point F(C): 67(19) Monomer Content, %: 42 Degree of Polymerization: 1.7 Degree of Alkylation: High Methyl01 Content: Mod. Equivalent Weight: 90-200

Resins

281

282

Water-Soluble

Resins

MONSANTO CHEMICAL (Continued):

co. : RESIMENE Amino Crosslinker Resins

High Solids Methylated Melamine(Continued): 740: % Solids-Weight: 89 Viscosity, G-H: W-22 Solvent: Isopropanol Water Solubiiity: Yes Lbs/Gallon: 9.7-9.9 Flash Point F(C): 71(22) Monomer Content, %: 45 Degree of Polymerization: 1.6 Degree of Alkylation: High Methyl01 Content: Mod. Equivalent Weight: 90-200 735: % Solids-Weight: 80 Viscosity, G-H: T-W Solvent: Isopropanol Water Solubility: Yes Lbs/Gallon: 9.4-9.6 Flash Point F(C): 50(10) Monomer Content, %: 45 Degree of Polymerization: 1.7 Degree of Alkylation: Mod. Methyl01 Content: Mod.-High Equivalent Weight: 100-200 731: % Solids-Weight: 81 Viscosity, G-H: T-Z Solvent: Isopropanol Water Solubilitv: Yes Lbs/Gallon: 9.4-9.6 Flash Point F(C): 64(18) Monomer Content, %: 45 Degree of Polymerization: 1.6 Degree of Alkylation: Mod. Methyl01 Content: Mod--High Equivalent Weight: 100-200 730: % Solids-Weight: 90 Viscosity, G-H: 22-26 Solvent: Isopropanol Water Solubilitv: Yes Lbs/Gallon: 9.9110.1 Flash Point F(C): 72(22) Monomer Content, %: 45 Degree of Polymerization: 1.6 Degree of Alkylation: Mod. Methyl01 Content: Mod.-High Equivalent Weight: 100-200

Monsanto Chemical Co.

MONSANTO CHEMICAL (Continued):

co.

:

RESIMENE Amino Crosslinker

High Solids Methylated Melamine(Continued): 717: % Solids-Weight: 84 Viscosity, G-H: Y-23 Solvent: n-Butanol Water Solubilitv: Co-solvent Lbs/Gallon: 9.519.7 Flash Point F(C): 92(93) Monomer Content< %: 45 Degree of Polymerization: 1.6 Degree of Alkylation: Very High Methyl01 Content: Low Equivalent Weight: 100-200 714: % Solids-Weight: 80 Viscosity, G-H: H-W Solvent: Water Water Solubility: Yes Lbs/Gallon: 10.1-10.4 Flash Point F(C): 82(28) Monomer Content, %: 55 Degree of Polymerization: N/A Degree of Alkylation: Low Methyl01 Content: High Equivalent Weight: N/A Modified HS Melamine: 797: % Solids-Weight: 92 Viscosity, G-H: W-Z Solvent: Ethanol Water Solubility: Co-solvent Lbs/Gallon: 9.5-9.7 Flash Point F(C): 86(30) Monomer Content (%): N/A Degree of Polymerization: N/A Degree of Alkylation: N/A Methyl01 Content: Very Low Equivalent Weight: N/A

Resins

283

284

Water-Soluble

Resins

MONSANTO CHEMICAL CO.: RESIMENE Amino Crosslinker (Continued): Modified HS Melamine(Continued): 2040: % Solids-Weight: 85 Viscosity, G-H: W-21 Solvent: Ethanol Water Solubility: No Lbs/Gallon: 9.0-9.2 Flash Point F(C): 60(16) Monomer Content, %: N/A Degree of Polymerization: N/A Degree of Alkylation: N/A Methyl01 Content: Very Low Equivalent Weight: N/A 2060: % Solids-Weight: 79.5 Viscosity, G-H: V-Z Solvent: Ethanol Water Solubility: No Lbs/Gallon: 8.6-8.8 Flash Point F(C): 67(19) Monomer Content, %: N/A Degree of Polymerization: N/A Degree of Alkylation: N/A Methyl01 Content: Very Low Equivalent Weight: N/A

HS Methylated/Butylated

Melamine:

764: % Solids-Weight: 98 min. Viscosity, G-H: 21-24 Water Solubility: Co-solvent Lbs/Gallon: 8.8-9.0 Flash Point F(C): 230+(110+) Monomer Content; %: 47 Deqree of Polymerization: 1.9 Degree of Alkylation: High Methyl01 Content: Very Low Equivalent Weight: 125-270

Resins

Monsanto Chemical Co.

MONSANTO CHEMICAL CO.: RESIMENE Amino Crosslinker (Continued): HS Methylated/Butylated

Melamine(Continued):

757: % Solids-Weight: 97 min. Viscosity, G-H: 2-24 Water Solubility: Co-solvent Lbs/Gallon: 9.4-9.6 Flash Point F(C): 150+(66+) Monomer Content, %: 38 Degree of Polymerization: 1.9 Degree of Alkylation: Very High Methyl01 Content: Very Low Equivalent Weight: 90-200 755: % Solids-Weisht: 98 min. Viscosity, GIH: T-W Water Solubilitv: Co-solvent Lbs/Gallon: 9.0-9.2 Flash Point F(C): 230+(110+) Monomer Content, %: 60 Degree of Polymerization: 1.4 Degree of Alkylation: Very High Methyl01 Content: Very Low Equivalent Weight: 90-200 753: % Solids-Weight: 98 min. Viscositv, G-H: Y-Z3 Water Soiubility: Co-solvent Lbs/Gallon: 9.4-9.6 Flash Point F(C): 200+(93+) Monomer Content, %: 45 Degree of Polymerization: 1.5 Degree of Alkylation: Very High Methyl01 Content: Very Low Equivalent Weight: 75-200 HS Butylated Melamine: 750: % Solids-Weight: 80 Viscosity, G-H: X-Z4 Solvent: n-Butanol Water Solubilitv: Co-solvent Lbs/Gallon: 8.8L9.0 Flash Point F(C): 90(32) Monomer Content; %: N/A. Degree of Polymerization: N/A Degree of Alkylation: Mod. Methyl01 Content: Mod.-High Equivalent Weight: N/A

Resins

285

286

Water-Soluble Resins

MONSANTO CHEMICAL CO.: RESIMENE Amino Crosslinker (Continued): AS Methylated Urea: 980: % Solids-Weight: 97 min. Viscositv. G-H: U-Y Water Soiubility: Yes Lbs/Gallon: 9.8-10.0 Flash Point F(C): 175(79) Monomer Content, %: Very High Degree of Alkylation: High Methyl01 Content: Low Equivalent Weight: N/A 975:

% Solids-Weight: 98 min. Viscosity, GIH: 22-25 Water Solubility: Yes Lbs/Gallon: 9.9-10.1 Flash Point F(C): 230+(110+) Monomer Content, %: Hiqh Degree of Alkylation: High Methyl01 Content: Low Equivalant Weight: N/A 970:

% Solids-Weight: 05 Viscositv, G-H: X-Z1 Solvent: -Isobutanol Water Solubility: Yes Lbs/Gallon: 9.6-9.8 Flash Point F(C): 89(32) Monomer Content, %: Mod--High Degree of Alkylation: High Methyl01 Content: Mod. Equivalent Weight: N/A

Resins

Morton

MORTON INTERNATIONAL, Latices:

International,

Inc.

287

INC.: LYTRON General Purpose Polystyrene

This series of LYTRON's comprise a family of stable latices of high molecular weight carboxylated polystyrene at high solids in an easily handled form. LYTRON 5100: Approximate Particle Size (Microns): Appearance: Milky White Liquid Total Solids (%,): 48+-l pH: 9 Specific Gravity 0 25C: 1.03 Weiaht. lbs/sal: 8.6 Dispersion System: Anionic Viscosity, cps @ 25C: Less Than 50 Dilutabilitv in water: Infinite LYTRON 5200: Anproximate Particle Size (Microns): Total Solids (%): 48+-l pH: 9 Specific Gravity @ 25C: 1.03 Weight, lbs/gal: 8.6 Dispersion System: Anionic Viscosity, cps @ 25C: Less Than 50 Dilutability in water: Infinite LYTRON 5202: Approximate Particle Size (Microns): Total Solids (%): 48+-l pH: 8.8 Specific Gravity @ 25C: 1.03 Weight, lbs/gal: 8.6 Dispersion System: Anionic Viscosity, cps @ 25C: Less Than 50 Dilutability in water: Infinite LYTRON 5251: Approximate Particle Size (Microns): Total Solids (%): 48+-l pH: 8.6 Specific Gravity 0 25C: 1.03 Weight, lbs/gal: 8.6 Dispersion System: Anionic Viscosity, cps @ 25C: Less Than 50 Dilutability in water: Infinite LYTRON 5450: Approximate Particle Size (Microns): Total Solids (%): 48+-l pH: 6 Specific Gravity @ 25C: 1.03 Weight, lbs/gal: 8.6 Dispersion System: Anionic Viscosity, cps @ 25C: Less Than 50 Dilutability in water: Infinite

0.1

0.2

0.16

0.25

0.45

288

Water-Soluble Resins

MORTON INTERNATIONAL, Polystyrene:

INC.: LYTRON Plastic Pigments:

LYTRON plastic pigments are uniform, hard, lightweight, spherical, polystyrene polymer particles. LYTRON 2503: Appearance: White. milky liquid Total Solids Content, %_ 48,O pH: 9.0 Viscosity (cps): 50 Surface Tension (dynes/cm): 50 Particle Charge: Anionic Specific Gravity (8.6 lbs/gal): 1.03 Polymer: Particle Size, microns: ca 0.42 Specific Gravity: 1.05 Fusion Temperature, F: 215 Refractive Index: 1.59 Copolymer Type: Styrene/Acrylate LYTRON 2203: Appearance: White, milky liquid Total Solids Content, %I 48;O pH: 9.0 Viscosity (cps): 50 Surface Tension (dynes/cm): 60 Particle Charge: Anionic Specific Gravity (8.6 lbs/gal): 1.03 Polymer: Particle Size, microns: ca. 0.21 Specific Gravity: 1.05 Fusion Temperature, F: 215 Refractive Index: 1.59 Copolymer Type: Styrene/Acrylate LYTRON 2202: Appearance: White, milky liquid Total Solids Content, %: 48.0 pH: 9.0 Viscosity (cps): 50 Surface Tension (dynes/cm): 50 Particle Charge: Anionic Specific Gravity (8.6 lbs/gal): 1.03 Polymer: Particle Size, microns: ca. 0.16 Specific Gravity: 1.05 Fusion Temperature, F: 215 Refractive Index: 1.59 Copolymer Type: Styrene/Acrylate

Morton International,

MORTON INTERNATIONAL (Continued):

INC.: LYTRON Plastic Pigments:

inc.

289

Polystyrene:

LYTRON 2101: Appearance: White, milky liquid Total Solids Content, %: 48.0 RH: 9.0 Viscosity (cps): 50 Surface Tension (dynes/cm): 60 Particle Charge: Anionic Specific Gravity (8.6 lbs/gal): 1.03 Polymer: Particle Size, microns: ca 0.10 Specific Gravity: 1.05 Fusion Temperature, F: 215 Refractive Index: 1.59 Copolymer Type: Styrene/Acrylate LYTRON 604: Appearance: White, milky liquid Total Solids Content, %: 40.0 DH: 10.0 iriscosity (cps): 50 Surface Tension (dynes/cm): 50 Particle Charge: Anionic Specific Gravity (8.6 lbs/gal): 1.03 Polymer: Particle Size, microns: ca 0.03 Specific Gravity: 1.05 Fusion Temperature, F: 215 Refractive Index: 1.59 Copolymer Type: Styrene/Acrylate Advantages of Plastic Pigments in Paper: Lightweight-substantial reduction in weight of base sheet and/or coating. Bulk-provides high bulk coated paper and paperboard. Gloss-uniform high gloss coatings at moderate calendering conditions. Improved printability-smooth level surface, good holdout and excellent ink affinity. High brightness and opacity-no interference with optical brightener efficiency.

290

Walter-Soluble Resins

MORTON INTERNATIONAL,

INC.: MOR-PLO Concrete Coatings:

MOR-FL0 CS-38: MOR-FL0 CS-38 is a waterborne polyurethane modified acryllate copolymer designed for 1s.e as a concrete sealer. Film-formimg at room temperature, MOR-FL0 CS-38 eliminates the need for costly plasticizers and coalescing agents; just dilute wi=h water and add a preservative. Typical Properties: Percent solids: 38 Porunds per gallon: 8-6 DH:

8.3

Viscosity, cps: 100 Minimum film-forming temperature: 1OC Freeze-thaw stability: Protect from freezing MOR-FI,O 155 Concrete Seal Latex: MOIR-FLO 155 water based polymer emulsieon is designed use in formulaking aqueous concrete sealeus.

for

Typical Properties: Solids, %: 38 pH: 8 Viscosity, cps: 40 Glass transition temp. (Tg), Z: 66 Minimum film forming temp., C (MFT): 45 Weight, lbs./gal.: 8,.6 AA-421 Latex: AA-421 Latex is reconmended for use as a sealer on surfaces ranging from a.11 varieties of floor tile to terrazzo and concrete. It provides excellent hold-out and can be used as an underecoat for a wide variety of floor polishes at concentrations up to 20% solids. Typical Properties: Pe.rcent solids: 38+-1 Pcunds per gallon: 8.60 Specific gravity (25C): 1.03 pH: 8.0-9.0 Viscosity clps. max. (25C): 250 Particle size: 0.04 microns Minimum film forming temperature: 45F Tukon hardness (KHN): 7 Freeze-thaw stability: Protect from freezing

NL Chemicals, Inc.

NL CHEMICALS,

INC.: Acrylic Polymers:

AROLON 840: Type: Emulsion Percent Solids Weight: 39 Percent Solids Volume: 36.1 Solvent: W Solvent Percentages: 100 Viscositv: 50-200 cos Gardner Color, Max.: Milky Lbs./Gal., Solution: 8.70 Lbs./Gal., Solids: 9.40 Flash Point: None Description: Hard, Solvent Resistant Typical Uses: Air Dry and Force Dry Industrial Metal Finishes; Blends with SPENSOLS AROLON 845: Type: Emulsion Percent Solids Weight: 45 Percent Solids Volume: 43.0 Solvent: W Solvent Percentages: 100 Viscosity: 100-300 cps Gardner Color, max.: Milky Lbs./Gal., Solution: 8.70 Lbs./Gal., Solids: 9.40 Description: Chemical and Solvent Resistance, Very Good Corrosion Resistance Typical Uses: Air Dry and Force Dry Industrial Finishes AROLON 850: Type: Emulsion Percent Solids Weight: 45 Percent Solids Volume: 43.0 Solvent: W Solvent Percentages: 100 Viscosity: 200-500 cos Gardner Color, max.:-Milky Lbs./Gal., Solution: 8.64 Lbs./Gal., Solids: 9.04 Flash Point: None Description: Hard, Excellent Adhesion to Oily Metal and Plastic, High Gloss. Typical Uses: Air Dry for General Industrial Finishes Solvent Legend: W: Water

291

292

Water-Soluble Resins

NL CHEMICALS,

INC.: Acrylic PolymersfContinued):

AROLON 860: Type: Emulsion Percent Solids Weight: 45 Percent Solids Volume: 43.0 Solvent: W Solvent Percentages: 100 Viscosity: 1000 cps max Gardner Color, Max.: Milky Lbs./Gal., Solution: 8.80 Lbs./Gal., Solids: 9.33 Flash Point: None Description: Chemical and Solvent Resistance, Adhesion to Plastic, Block Resist, Crosslinkable Typical Uses: Air Dry, Force Dry, and Bake Industrial Finishes Solvent Legend: W: Water

Norland Products Inc.

293

NORLAND PRODUCTS INC.: HIPURE Liquid Gelatin: NORLAND HIPURE Liquid Gelatin is a specially purified gelatin with an average molecular weight of 60,000. It is unique because, although it has the same basic chemical constituents as animal gelatin, they are in different proportions. HIPURE Liquid Gelatin has lower amounts of proline and hydroxyproline, the amino acids responsible for hydrogen bonding in gelatin. This allows water solutions of NORLAND gelatin to remain liquid at room temperature, even in high concentrations. HIPURE Liquid Gelatin has properties and reactivities similar to animal gelatin, but offers much easier handling characteristics. It can be mixed into water with simple stirring and the solution does not have to be heated to remain fluid. This opens a new field to manufacturers who never considered the chemical characteristics of gelatin before because of the gel properties. Features of HIPURE Liquid Gelatin: Supplied as a pourable liquid. Completely water soluble. Acts as a protective colloid to suspend small particles or monomers in solution. Excellent adhesion to metal, rubber, glass, leather, cork, wood and paper. Insoluble in organic solvents. Coatings can be made water resistant and insoluble in water. Dries to a hard, smooth finish. Coatings will accept water soluble dyes. Compatible with a wide variety of water soluble monomers. Physical Properties: Color: Clear, light amber Solids: 45% in water Viscosity @ 70F: 6000 cps. Average Molecular Wt.: 60,000 Gel Point: 5-1OC Ash: 0.1% Preservatives: Methyl/Propyl para-Hydroxybenzoates pH: 5.4 Chemical Properties: NORLAND HIPLJRE Liquid Gelatin is a protein molecule consisting of a complex chain of 20 amino acids.

294

Water-Soluble Resins

OCCIDENTAL CHEMICAL CORP.: High Molecular Weight PVC Suspension Resins: The OXYCHEM line of High Molecular Weight (HMW) PVC Suspension Resins is designed to give formulators the resins needed for tough, elastic, thermoplastic compounds. These resins can be processed with conventional PVC resin equipment, and the range of molecular weights permits the optimizing of physical properties with ease of processing. The OXY HMW-PVC resins can be formulated with high clarity and luster or they can be filled and brightly colored. For the most part, the formulations use high levels of plasticizers and/or incorporate other non-vinyl polymers to give compounds with unique properties. The rubber-like qualities of these highly plasticized compounds suggest applications currently using various rubber compounds. The primary advantage being raw material and processing economics through scrap recycling and elimination of the vulcanization process. OXY 280: Relative Viscosity: 1% Sol. in Cyclohexanone: Inherent Viscosity: 1.23 K Value: 77 Sp. Gr.: 1.4 Bulk Density, gm/cc: 0.47 Particle Size Distribution: % Retained, 40 Mesh: 0 % Through, 200 Mesh: 10 Plasticizer Sorption: 110 Volatiles, %: 0.3 Classification: GP7-25440 CAS Number: 9002-86-2 OXY

2.77

300:

Relative Viscosity: 1% Sol. in Cyclohexanone: Inherent Viscosity: 1.32 K Value: 82 Sp. Gr.: 1.4 Bulk Density, cm/cc: 0.48 Particle Size Distribution: % Retained, 40 Mesh: 0 % Through, 200 Mesh: 10 Plasticizer Sorption: 125 Volatiles, %: 0.3 Classification: GP8-25440 CAS Number: 9002-86-2

2.97

Occidental Chemical Corp.

295

OCCIDENTAL CHEMICAL CORP.: High Molecular Weight PVC Suspension Resins(Continued): OXY 320: Relative Viscosity: 1% Sol. in Cyclohexanone: Inherent Viscosity: 1.42 K Value: 87 Sp. Gr.: 1.4 Bulk Density, gm/cc: 0.45 Particle Size Distribution: % Retained, 40 Mesh: 0 % Through, 200 Mesh: 10 Plasticizer Sorption: 130 Volatiles, %: 0.3 Classification: GP9-25586 CAS Number: 9002-86-2 oxy 410: Relative Viscosity: 1% Sol. in Cyclohexanone: Inherent Viscosity: 1.71 K Value: 93 So. Gr.: 1.4 Bulk Density, gm/cc: 0.40 Particle Size Distribution: % Retained, 40 Mesh: 0 % Through, 200 Mesh: 5 Plasticizer Sorption: 135 Volatiles, %: 0.3 Classification: GP9-15540 CAS Number: 9002-86-2

3.20

4.00

296

Water-Soluble Resins

OCCIDENTAL CHEMICAL CORP.: OXY 160 Suspension Resin: OXY 160 is an extremely low molecular weight suspension polymerized polyvinyl chloride homopolymer resin. It is readily adapted to operations having a minimum of energy available to qenerate fusion or where the product cannot be subjected to conditions required to fuse higher molecular weight resins. When used alone in formulations, the compound will have qood clarity and flow properties. It is also recommended as a modifying _ resin with both homopolymer and copolymer resins. Typical Applications: - Flooring - Powder Coatings - Records - Blending Resin - Injection Molding - Injection Blow Typical-Properties: Relative Viscosity (1% in Cyclohexanone @ 25C): 1.57 Inherent Viscosity: 0.48 _ K Value: 48 Specific Gravity: 1.4 Bulk Density: gms./cc.: 0.62 lbs./cu.ft.: 38 Particle Size Distribution: Retained on: 40 Mesh, %: 0 Thru 200 Mesh, %: 15 Volatiles, %: 1.6 Classification: GPI-26260 CAS Number: 9002-86-2 OXY 185 Suspension Resin: OXY 185 is a low molecular weight PVC homopolymer resin designed for calendering, extrusion and injection molding processes where a balance of easy processing and good physical properties are desired. Its excellent color and clarity, heat stability and low gels make it especially desirable for clear rigid packaging applications. Typical Applications: - Rigid Injection Molding - Blow Moldina - Solid and Foam Profiles - Clear Calendered or Extruded Rigid Film and Sheetinq - Pipe Fittings Typical Properties: Relative Viscosity: 1.82 Inherent Viscosity: 0.67 K Value: 56 Specific Gravity: 1.40 Bulk Density: gms./cc.: 0.59 Particle Size Distribution: Retained on 140 Mesh, %: 50 Plasticizer Sorption: 75 Volatiles, %: 0.3 Classification: GPl-16340 CAS Number: 9002-86-2

Occidental

Chemical Corp.

297

OCCIDENTAL CHEMICAL CORP.: OXY 190 Suspension Resin: OXY 190 is a suspension polymerized polyvinyl chloride homopolymer resin of low molecular weight for use in calendering, extrusion and injection molding processes where a combination of low molecular weight and good physical properties are desired. Its excellent color and clarity, heat stability and low gels make it especially desirable for clear rigid packaging applications. Typical Applications: - Rigid Injection Molding - Pipe Fittings - Solid and Foam Profiles - Clear Rigid Film and Sheeting Typical Properties: Relative Viscosity: 1.90 Inherent Viscosity: 0.73 K Value: 50 Specific Gravity: 1.40 Bulk Densitv: sms./cc.: 0.59 ibs./cu.ft.: 37 Particle Size Distribution: Retained on: 140 Mesh, %: 50 Plasticizer Sorption: 75 Volatiles, %: 0.3 Classification: GP2-16340 CAS Number: 9002-86-2 200 Suspension Resin: OXY 200 is a suspension polymerized polyvinyl chloride resin of medium molecular weight. Its low gels, excellent color and clarity, and heat stability allow its use in both flexible and semi-rigid applications such as extrusion, injection molding and calendering. Typical Applications: - Film and Sheeting - Wall Coverings - Extruded Profiles - Injection Molded Parts Typical Properties: Relative Viscosity: 2.03 Inherent Viscosity: 0.82 K Value: 62 Specific Gravity: 1.40 Bulk Density: gms./cc.: 0.54 ibs./cu.ft.: 34 Particle Size Distribution: Retained on: 40 Mesh, %: 0 60 Mesh, %: 2 140 Mesh, %: 25 Plasticizer Sorption: 100 Volatiles, %: 0.3 Classification: GP3-15330 CAS Number: 9002-86-2

OXY

298

Water-Soluble Resins

OCCIDENTAL

CHEMICAL CORP.:

OXY

225

Suspension

Resin:

OXY 225 is a suspension polymerized polyvinyl chloride homopolymer resin. It is a medium molecular weight resin having superior plasticizer absorption, excellent color and clarify and low gels. The use of OXY 225 will result in a product having outstanding electrical and physical properties along with the advantage of ease of processing. Typical Applications: - Wire Insulation and Cable Jackets - Clear Tubing - Injected Molded Parts - Clear and Opaque Film and Sheeting - Extruded Gasketing and Profiles Typical Properties: Relative Viscosity: 2.26 Inherent Viscosity: 0.96 K Value: 67 Specific Gravity: 1.40 Bulk Density: gms./cc.: 0.51 Particle Size Distribution: Retained on: 200 Mesh, %: 15 Plasticizer Sorvtion: 100 Volatiles, %: 013 Classification: GP4-15443 CAS Number: 9002-86-2 OXY 225PG Suspension Resin: OXY 225PG is a medium molecular weight PVC homopolymer resin primarily designed for rigid PVC applications. Its narrow particle size distribution, low fines and high bulk density make it especially desirable for single and multiscrew dry blend extrusion where consistent high feed rates are important. Typical Applications: - Pipe and Conduit - Rigid Profiles Typical Properties: Relative Viscosity: 2.19 Inherent Viscosiity: 0.92 K Value: 66 Specific Gravity: 1.40 Bulk Density: gms./cc.: 0.54 Particle Size Distribution: Retained on: 40 Mesh, %: 0 140 Mesh, %: 50 Plasticizer Sorption: 70 Volatiles, %: 0.3 Classification: GP4-16340 CA.5 Number: 9002-86-2

Occidental Chemical Corp.

OCCIDENTAL CHEMICAL CORP.:

OXY

230

Suspension Resin:

OXY 230 is a suspension polymerized polyvinyl chloride homopolymer resin. It is a medium molecular weight resin having excellent plasticizer absorption and offers ease of processing. The use of OXY 230 will result in products having excellent color and clarity and very low gels. Typical Applications: - Clear Tubing - Injected Molded Parts - Clear and Opaque Film and Sheeting - Extruded Gasketing and Profiles Typical Properties: Relative Viscosity: 2.30 Inherent Viscosity: 0.98 K Value: 68 Specific Gravity: 1.40 Bulk Density: gms./cc.: 0.51 Particle Size Distribution: Retained on: 200 Mesh, %: 15 Plasticizer Sorption: 100 Volatiles, %: 0.3 Classification: GP4-15443 CAS Number: 9002-86-2 240 Suspension Resin: OXY 240 is a suspension polymerized polyvinyl chloride homopolymer resin. Its medium-high molecular weight allows ease of processing coupled with high output rates, while maintaining excellent physical properties. It is well suited for operations such as wire and cable, which require rapid plasticizer dry up rates and superior-electrical properties. OXY 240 has excellent color and clarity and low gels. Typical Applications: - Color Concentrates - Wire and Cable and Jacket - Clear and Opaque Tubing - Gasketing and Profiles - Film and Sheetins Typical Properties: Relative Viscosity: 2.38 Inherent Viscosity: 1.03 K Value: 69.5 Specific Gravity: 1.40 Bulk Density: gms./cc.: 0.51 Particle Size Distribution: Retained on: 200 Mesh, %: 15 Plasticizer.Sorption: 100 Volatiles, %: 0.3 Classification: GP5-15443 CA.9 Number: 9002-86-2

OXY

299

300

Water-Soluble Resins

OCCIDENTAL CHEMICAL CORP.: OXY 250 Suspension

Resin:

OXY 250 is a suspension polymerized polyvinyl chloride homopolymer resin. It is a high molecular weight resin having superior plasticizer absorpton, excellent color and clarity and low gels. The use of OXY 250 will result in a product having outstanding electrical and physical properties along with the advantage of ease of processing. Typical Applications: - Wire Insulation and Cable Jackets - Clear Tubing - Injection Molded Parts - Clear and Opaque Film and Sheeting - Extruded Gasketing and Profiles Typical Properties: Relative Viscosity: 2.40 Inherent Viscosity: 1.08 K Value: 72 Specific Gravity: 1.40 Bulk Density: gms./cc.: 0.51 Particle Size Distribution: Retained on: 200 Mesh, %: 15 Plasticizer Sorption: 100 Volatiles, %: 0.3 Classification: GP5-15443 CAS Number: 9002-86-2

C.J. Osborn

301

C.J. OSRCRN: Water Reducibles: Water Reducibles have a primary use in the industrial baking market. These products are known for their outstanding adhesion and flexibility to metal surfaces. Their use may be interior or exterior. These products are generally oil-free and are available in high-solids versions. Water Reducibles may also be used to plasticize nitrocellulose lacquers, both air-dry and forced. Polyesters: 10-A-1559: Type: Saturated polyester solution % Non-Volatile: 74-76 Solvent: Butyl cellosolve Viscosity: 22-25 Color (Gardner): 3 max. Acid Number (Solids): 70-85 Modifying Oil: None WPG Average: 8.80 Water reducible for industrial baking finishes. 10-A-2197:

Type: High solids water reducible, oil-free polyester % Non-Volatile: 74-76 Solvent: Butyl carbitol Viscosity: 25-27 Color (Gardner): 4 max. Acid Number (Solids): 40-45 Modifvina Oil: None WPG AGerage: 9.30 Hish gloss, sood flow, flexibility and hardness and excellent exterior-durability make-this a useful resin for aluminum siding, can coatings, automotive and appliance finishes. 10-A-4067: Type: Polyester, reducible in water without the aid of amine % Non-Volatile: 79-81 Solvent: Butyl cellosolve Viscosity: 25-27 Color (Gardner): 3 max. Acid Number (Solids): 50-60 Modifying Oil: None WPG Average: 9.53 This resin is designed in such a way that it may be introduced in a water system without the help of amines. It may be used with substantial amounts of ureas or melamine resins with which it is capable of crosslinking.

302

Water-Soluble Resins

C.J. OSBORN: Water Reducibles(Continued): Polyesters(Continued): 10-A-5423: Type: Water soluble polyester 8 Non-Volatile: 77-79 Solvent: Set-butanol, butyl cellosolve Viscosity: 25-27 Color (Gardner): 9 max. Acid Number (Solids): 50-60 Modifying Oil: None WPG Average: 8.82 This polyester is designed to be water-borne with a minimum amount of co-solvent--this resin needs only moderate quantities of melamine or urea crosslinker to produce a tough glossy film. Low temps and short cycles are recommended for better color with this product. 10-A-5426: Type: Water soluble polyester % Non-Volatile: 79-81 Solvent: Sec. butanol, butyl cellosolve Viscosity: 25-27 Color (Gardner): 4 max. Acid Number (Solids): 50-65 Modifying Oil: None : 9.01 YE!isAverage water soluble polyester is designed to be water-borne with a minimum amount of co-solvents. The resin needs only moderate quantities of melamine or urea crosslinker to produce a tough, glossy film. 10-A-5816: Type: Oil-free polyester % Non-Volatile: 79-81 Solvent: Butyl cellosolve, xylol Viscosity: 22-24 Color (Gardner): 3 max. Acid Number (Solids): 41-49 Modifying Oil: None WPG Averacre: 9.23 Designed f-or being water-dispersible. Crosslinked with melamine and urea resin 10-A-5816 produces very flexible enamels.

C.J. Osborn

303

C.J. OSBORN: Water Reducibles(Continued): Polyesters(Continued): 10-9105: Type: Oil modified water reducible polyester % Non-Volatile: 74-76 Solvent: Butanol, butyl cellosolve Viscosity: 24-26 Color (Gardner): 6 max. Acid Number (Solids): 50-60 Modifying Oil: Specialty fatty acids WPG Average: 8.70 Used for interiors as well as exterior applications where good gloss, flexibility, hardness and color retention are required over metal substrates. The baked films exhibit excellent durability. 1 O-A-9889

:

Type: Oil-free water reducible polyester (not pre-neutralized) % Non-Volatile: 78-82 Solvent: N-butyl alcohol Viscosity: 24-26 Color (Gardner): 2 max. Acid Number (Solids): 50-60 Modifying Oil: None WPG Averaqe: 9.00 For exterior as well as interior applications where gloss, flexibility, hardness and color retention is required over metal substrates. Raked films exhibit superior salt spray resistance and durability. 10-10070: Type: Oil-free water reducible polyester % Non-Volatile: 79-81 Solvent: Butyl cellosolve Viscositv: 24-26 Color (Gardner): 3 max. Acid Number (Solids): 55-65 Modifying Oil: None WPG Average: 9.35 This water reducible can be used for industrial baking coatings as well as metal decorating finishes.

304

Water-Soluble Resins

C.J. OSBORN: Water Reducibles(Continued): Epoxy Esters: 10-A-5763: Type: Water reducible epoxy ester % Non-Volatile: 69-71 Solvent: Butyl cellosolve/Butanol Viscosity: 22-25 Color (Gardner): 12 max. Acid Number (Solids): 50-60 Modifying Oil: None WPG Average: 8.50 Water soluble vehicle capable of delivering desired properties of an epoxy ester.

many of the

10-A-5795: Type: Water reducible epoxy ester % Non-Volatile: 69-71 Solvent: Diethylene glycol ethyl ether, glycol butyl ether, butanol Viscosity: 22-25 Color (Gardner): 9 max. Acid Number (Solids): 50-60 Modifying Oil: None WPG Average: 8.61 Epoxy ester baking vehicle. 10-A-5995: Type: Water dispersible epoxy ester % Non-Volatile: 79-81 Solvent: Butyl cellosolve, carbitol, butanol Viscosity: 26-28 Color (Gardner): 10 max. Acid Number (Solids): 40-50 Modifying Oil: DC0 FA WPG Average: 8.80 Low temperature metal baking finish.

C.J. Osborn

C.J. OSBORN: Water Reducibles(Continued): Alkyds: 10-A-1084: Type: Pre-neutralized short oil water reducible alkyd % Non-Volatile: 50-52 Solvent: Water + co-solvents Viscosity: S-W Color (Gardner): 7 max. Modifying Oil: Soya WPG Average: 8.65 This product is unique in that it performs similarly to a conventionally based solvent product, yielding high gloss, industrial bake finishes with good hardness, mar resistance and color retention. 10-A-1086: Type: Short oil, water reducible alkyd % Non-Volatile: 74-76 Solvent: Propanol Viscosity: 21-23 Color (Gardner): 4 max. Acid Number (Solids): 45-55 Modifying Oil: Soya WPG Average: 8.60 This resin is unique in that it performs similar to conventional solvent based products yielding high gloss industrial baking finishes with good hardness, mar resistance and color retention. 10-A-6383: Type: Water reducible alkyd % Non-Volatile: 74-76 Solvent: Ethylene glycol butyl ether, butanol Viscositv: 25-27 Color (Gardner): 8 max. Acid Number (Solids): 55-70 Modifying Oil: Soya WPG Average: 8.85 Architectural or industrial air-dry enamels. 10-A-6441: Type: Water soluble oleoresinous vehicle % Non-Volatile: 100 Solvent: None Viscosity: 25-27 Color (Gardner): 10 max. Acid Number (Solids): loo-120 Modifying Oil: Tung WPG Average: 8.30 This vehicle produces baked films which are very hard, marproof and fairly glossy. They do not need a crosslinker. Airdry films from this resin are flat because of micro-wrinkling. The drying time is about 6 hours.

305

306

Water-Soluble Resins

C.J. OSBORN: Water Reducibles(Continued): Alkyds(Continued): 10-A-7006: Type: Water dispersible alkyd % Non-Volatile: 74-76 Solvent: Sec. butanol, butyl cello. Viscosity: 24-26 Color (Gardner): 9 max. Acid Number (solids): 35-42 Modifying Oil: None WPG Average: 8.80 10-A-7006 has been designed for good drying, early hardness and good stability. 10-9900: Type: Short oil, water reducible alkyd % Non-Volatile: 74-76 Solvent: N-butyl alcohol Viscosity: 23-25 Color (Gardner): 6 max. Acid Number (.&lids): 45-55 Modifying Oil: Soya WPG Averase: 8.60 lo-9900 water reducible resin is unique in that it performs to conventional solvent based products yielding high gloss industrial bake finishes with good hardness, mar resistance and color retention. W.R. Acrylics: 10-A-1268: Type: High solid, water reducible acrylic % Non-volatile: 69-71 Solvent: Butyl cellosolve Viscositv: 24-26 Color (Gardner): 4 max. Acid Number (Solids): 120-130 Modifying Oil: None WPG Average: 8.50 Water reducible industrial baking finishes, metal decorating applications.

C.J. Osborn

307

C.J. OSBORN: Water Reducibles(Continued): W.R. Acrylics(Continued): 10-A-1522: Type: Water reducible acrylic terpolymer % Non-Volatile: 69-71 Solvent: Butyl cellosolve/Butyl carbitol Viscosity: 25-27 Color (Gardner): 3 max. Acid Number (Solids): 120-130 Modifying Oil: None WPG Average: 8.60 Water reducible industrial baking finishes, metal decorating applications with good flow and leveling. 10-10026: Type: Water reducible acrylic % Non-Volatile: 64-66 Solvent: Bu'cyl cellosolve Viscositv: 22-25 Color (Gardner): 3 max. Acid Number (Solids): 55-65 Modifying Oil: None WPG Average: 8.40 Acrylic for metal deco water reducible coating.

industrial baking

10-10096:

Type: High solids, water reducible acrylic % Non-Volatile: 69-71 Solvent: Rutyl cellosolve Viscosity: 24-26 Color (Gardner): 4 max. Acid Number (Solids): 125-135 Modifying Oil: None WPG Average: 8.60 Water reducible acrylic may be used for industrial baking coatings as well as metal decorating application.

308

Water-Soluble Resins

OXYCHEM: PLYOPHEN Resins for Laminating

Applications:

Industrial Laminates: 22520: Solids %: 63-69 Solvent: Water Viscosity cps @ 25C: loo-150 Specific Gravity @ 25C: 1.190-1.210 Storage Stability: 45 days @ 40F. pH 7.2-7.8. Water tolerance 1000% minimum. Good penetration into cellulose. NEMA XXXP, XXXPC. 22032:

Solids %: 56-61 Solvent: Water Viscosity cps @ 25C: 25-750 Specific Gravity @ 25C: 1.174-l .189 Storage Stability: 45 days @ 40F. Good penetration into cellulose. 43775:

Solids %: 75-79 Solvent: Water Viscosity cps @ 25C: 6000-10000 Specific Gravity @ 25C: 1.2450-1.275 Storage Stability: 30 days @ 40F. Designed for impact resistance of molding materials.

Filament Winding: 43791:

Solids %: 68-72 Solvent: Water & Methanol Viscosity cps @ 25C: 750-850 Specific Gravity @ 25C.: 1.190-1.210 Storage Stability: 2 months @ 40F. Filament wound ducting. 95019: Solids %: 71-75 Solvent: Water & Methanol Viscosity cps @ 25C: 1000-1300 Specific Gravity @ 25C.: 1.190-1.220 Storage Stability: 2 months @ 40F. Low free formaldehyde binder.

Oxychem

OXYCHEM:

PLYOPHEN Resins for Laminating

High Temperature

309

Applications(Continued):

MIL-Spec Laminates:

23029: Solids %: 57-60 Solvent: Ethanol & Water Viscosity cps @ 25C: 50-200 Specific Gravity 8 25C.: 1.062-1.082 Storage Stability: 3 months @ 40F. High carbon resin. Laminates meet MIL-R-9299-C, classification.

Grade A

23900:

Solids %: 62-66 Solvent: Ethanol 8 Water Viscosity CPS @ 25C: 50-150 Specific-Gravity @ 25C: 1.120-1.140 Storage Stability: 12 months @ 40F. Works-well in pre-pregs. Heat resistant varnish for use in production of components for rockets and missiles. Laminates meets MIL-R-9299-C. Grade B classification. 23973:

Solids %: 62-66 Solvent: Isopropanol & Water Viscosity cps @ 25C: 300-450 Specific Gravity @ 25C: 1.060-1.080 Storase Stability: 1 month @ 40F. Silicone modified phenolic for heat resistant applications. Laminates meet MIL-R-9299-C, Grade A classification. 23983:

Solids %: 55-62 Solvent: Isopropanol 8 Water Viscosity cps @ 25C: 250-425 Specific Gravity @ 25C: 1.050-1.070 Storage Stability: 6 months @ 40F. Epoxy modified phenolic for heat resistant applications. Laminates meet MIL-R-9299-C, Grade A classification.

310

Water-Soluble

Resins

OXYCHEM: VARCUM Abrasive Resins: Grinding Wheel Resins-Liquid: 29353: Resin Solids %: 72-76 Viscosity @ 25C. Cps.: 325-405 Gel Time @ 121C. Min.: 32-38 Water Tolerance %: 250-350 pH: 7.85-8.05 Solvent System: Water-Phenol General purpose liquid resin for use in low and medium density wheel formulations. 29358:

Resin Solids %: 75-79 Viscosity @ 25C. Cps: 1200-1500 Gel Time @ 121C. Min.: 20-26 Water Tolerance %: 100-150 pH: 7.8-8.0 Solvent System: Water-Phenol High viscosity wetting agent. 32199: Resin Solids %: 75-81 Viscosity @ 25C. Cps: 1100-1388 Gel Time @ 121C. Min.: 80-11 Solvent System: Phenol-Water For use in manufacturing pulp stone. 32534:

Resin Solids %: 67 min Viscosity @ 25C. Cps.: 355-420 Gel Time @ 121C. Min.: 14-20 Solvent System: Water-Phenol Liquid resin-wetting agent.

Oxychem

OXYCHEM: VARCUM Resins: Coated Abrasive Resins: 29363: Resin Solids Content %: 77-80 Volatile Component: Water Specific Gravity: l-220-1.225 Viscosity @ 25C. Cps: 2600-3500 Gel Time @ 121C. Min.: 19-24 Water Tolerance %: 200-400 pH: 7.6-8-O General purpose resin. 29368:

Resin Solids Content %: 63-67 Volatile Component: Water Specific Gravity: 1.190-1.230 Viscosity @ 25C. Cps: 125-200 Gel Time @ 121C. Min.: 8-12 Water Tolerance %: 45-110 pH: 7.7-8.1 General purpose resin, may be used in both make and size coats. 29371:

Resin Solids Content %: 68-72 Volatile Component: Water Specific Gravity: 1.220-1.250 Viscosity @ 25C. Cps: 600-800 Gel Time @ 12lC. Min.: 9-13 Water Tolerance %: 350-550 pH: 8.6-8.9 General purpose resin, suggested for spray application. 29373:

Resin Solids Content %: 72-76 Volatile Component: Water Specific Gravity: 1.220-1.260 Viscosity @ 25C. Cps: 3000-6000 Gel Time @ 121C. Min.: 8.5-11.5 Water Tolerance %: 175-225 pH: 8.6-8.9 General purpose resin, fast curing.

311

3 12

Water-Soluble Resins

OXYCHEM: VARCUM Resins: Coated Abrasive Resins(Continued): 29379: Resin Solids Content %: 74.5-70.5 Volatile Component: Water & Phenol Specific Gravity: 1.190-1.210 Viscosity @ 25C; Cps: 800-1200 Gel Time @ 12lC. Min.: 26-30 Water Tolerance %: 160-210 pH: 7.9-8.1 Slow curing--used for sizing of cloth backing for coated abrasives. 29382 :

Resin Solids Content %: 70-75 Volatile Component: Water Viscosity @ 25C Cps: 15000-25000 Gel Time @ 121C. Min.: 9-12 Light color scrub pads. 29386:

Resin Solids Content %: 77-81 Volatile Component: Water Specific Gravity: 1.200-1.230 Viscosity @ 25C Cps: 7000-11000 Gel Time-@ 121C. Min.: 6-9 Water Tolerance %: 20-40 pH: 7.6-8.2 For use in manufacture of water-resistant

coated abrasives.

29394:

Resin Solids Content %: 74-70 Volatile Component: Water Specific Gravity: 1.240-1.250 Viscosity @ 25C. Cps: 1000-2000 Gel Time @ 121C. Min.: lo-12 Water Tolerance %: 80-140 pH: 7.5-8.0 For use in manufacture of fiber discs. Excellent and water resistance.

flexibility

Oxychem

OXYCHEM: VARCUM Resins: Coated Abrasive Resins(Continued): 29770: Resin Solids Content %: 78-83 Volatile Component: Water Specific Gravity: 1.270-1.300 Viscosity @ 25C. Cps: 18000-30000 Gel Time @ 121C. Min.: 8-11 Water Tolerance %: 80-175 pH: 7.5-8.5 General purpose resin. 29771: Resin Solids Content %: 69-73 Volatile Component: Water Specific Gravity: 1.220-1.250 Viscosity @ 25C. Cps: 700-1000 Gel Time @ 121C. Min.: 9-12 Water Tolerance %: 90-150 pH: 8.0-8.4 For use where light colored cure is desired.

29786:

Resin Solids Content %: 78-82 Volatile Component: Water Specific Gravity: 1.31-1.35 Viscosity @ 25C. cps: 35000-65000 Gel Time @ 12lC. Min.: 6-8 Water Tolerance %: 70 max pH: 6.5-7.5 Used in the manufacture of waterproof coated abrasives. Very high viscosity and high resin solids content. 29787:

Resin Solids Content %: 75-79 Volatile Component: Water Specific Gravity: 1.220-1.250 Viscosity @ 25C. cps: 650-850 Gel Time @ 121C. Min.: 13-17 Water Tolerance %: 400-900 pH: 8.6-9.6 For use in both make and size coats. Low molecular weight provides for good penetration of substrate. 31223: Resin Solids Content %: 67-72 Volatile Component: Water Specific Gravity: 1.220-1.250 Viscosity @ 25C Cps: 1300 max Gel Time @ 121C. Min.: 11 max Water Tolerance %: 50-90 For scouring and scrub pads.

313

314

Water-Soluble Resins

POLYSAT INC.: POLYSAT Emulsions: POLYSAT ERC 45%: Hydrocarbon Polymer Emulsion Material or Comuonent: Hydrocarbon Resin 45% Stoddard Solvent 23% Emulsifiers 3% H20 29% Physical/Chemical Characteristics: Boiling Point, 760 mm Hg: Azeotrope Solvent+Water 200F Specific Gravity: 0.788 (60/60F) % Volatiles by Vol: 59% Appearance and Odor: Cream Colored Liquid Emulsion pH (as is): 9-10 POLYSAT HCRE: Hydrocarbon

Polymer Emulsion

Material or Comoonents: Hydrocarbon Resin: 49% Stoddard Solvent: 21% Water: 27% Emulsifiers: 3% Physical/Chemical Characteristics: Boiling Point, 760 mm Hg: Azeotrope Solvent+Water: 200F Specific Gravity: 0.788 (60/60F) % Volatiles BY Vol: 51% Appearance and Odor: Cream Colored Liquid Emulsion w/ Typical Aromatic Odor. pH (as is): 9-10 POLYSAT SAE 45%: Styrene Acrylate Emulsion Material or Components: Styrene Acrylate Polymer: AR-100 Solvent: Acetic Acid Ester: Water: Emulsifiers & Other Additives:

45.00 18 9 25.4 2.6

Physical/Chemical Characteristics: -Boiling Point, 760 mm Hg: 240F Specific Gravity: 0.9784 %-Volatiles by Vol: 55% Appearance and Odor: Milky White Emulsion with Aromatic Odor California VOC Requirement: 350 grams/liter pH (As Is): 7-8

Polvsat Inc.

POLYSAT INC.: POLYSAT

315

(ERC45%) Emulsion Resin Concentrate:

POLYSAT ERC-45% is a solvent water emulsion of POLYSAT CMR-70 Hydrocarbon Resin. This unique emulsion will yield a clear continuous water resistant film on drying. Key Benefits & Application Areas: 1. Clear water deposited film 2. Passes ASTM C-309-89 3. Water & chemical resistant film 4. Can be used as a concrete curing membrane 5. Excellent compatibility with other film formers 6. Adds water & chemical resistance to other emulsions and coating system Typical Physical Properties: Solids: 45.0+-l% Viscosity: 4-8000 cps Weight/Gallon: 8.26-8.32#/gal. California VOC: 293 Grams/Liter. pH: 8.5-9.0 Resin Properties ERC45%: Solids: Solvent: Softening Point: Color Gardner @ 70%: Color Gardner @ 50% in Toluene: Weight/Gallon: Iodine Value: Acid Value: Saponification Value: Viscosity:

70+-l% Mineral Spirits 90-100 10-13 9-12 8.29/# 85-115 Nil Nil 21-23

paint

316

Water-Soluble Resins

POLYSAT INC.: POLYSAT Hydrocarbon

Resin Emulsions:

POLYSAT HCRE Series Emulsions are solvent-water emulsions of hydrocarbon resins with excellent compatabilities with most adhesive binder systems, such as styrene butadiene, acrylic, and PVA, emulsions. These emulsions provide increased emulsion stability, water resistance and adhesion when compared to in situ emulsions. Key Benefits to Adhesive Formulations: - Excellent Water Resistance - Increased Tack - Increased Wet Strength - Increased Adhesion to Metal - Emulsion Stability H.C. Resin Emulsion: General Composition: Percent POLYSAT CMR-70 Percent Mineral Spirits Percent Water Percent Additives

49.0 21.5 27.0 2.5

Typical Physical Properties: Solids: pH: Viscosity, Brookfield: Weight/Gallon:

49-51% 9-10 1400-2000 cps 8.35-8.45#/gal.

H.C. Resin Emulsion Oil Modified: General Composition: Percent POLYSAT CMR-70 Percent Mineral Spirits Percent Process Oil Percent Water Percent Additives

34.7 14.9 20.9 27.2 2.3

Typical Physical Properties: Solids: pH: Viscosity, Brookfield: Weight/Gallon:

54-55% 9-10 250-500 cps 8.25-8.35#/gal.

POLYSAT HC-70 Specifications: (Base Polymer for HCRE): 70+-l% Solids: Solvent: Mineral Spirits Softeninu Point Rins and Ball C: 90-100 10-13 Color Gardner @ 70%: 9-12 Color Gardner @ 50% in Toluene: Weight/Gallon: 8.29/# 85-115 Iodine Value: Acid Value: Nil Nil Saponification Value: Viscosity: 21-23

Polysat Inc.

317

POLYSAT INC.: POLYSAT SAE Styrene Acrylate Chemical Resistant VOC Emulsion 45% Solids: POLYSAT SAE is an emulsion of a solvent base styrene acrylic polymer designed to provide solvent base performance from a water emulsion system. Films of SAE 45% when reduced with water as per the reduction formula listed below - are crystal clear water white polymer films which are resistant to water, chemicals, and exterior weathering. These products can be used as coatinss for concrete, floor sealers, and waterproofing, texture and masonry paints. Coatings and paints formulatedfrom SAE 45% emulsions will meet the requirements of California VOC regulations. California VOC Rating 350 Grams/Liter Typical Physical Properties: Solids: Viscosity Brookfield: Weight/Gallon: pH: VOC Rating:

45.0+-1.0% 4-8000 cps 8.19+-.l Lbs/Gal. 8.5-9.0 350 grams/liter

Film Properties: Film Integrity: Forms a continuous clear film. Water and Chemical Resistance: Good to Excellent POLYSAT SAE Water Reduced Clear Coating: Gallons Pounds POLYSAT SAE 45% 49.33 404.2 50.67 422.6 Water Yield 100 Gallons @ 22% solids - Wt/Gal: 8.27 Lbs/Gal. Production Method: 1. Put POLYSAT SAE 45% in tank 2. Add water slowly to SAE 45%. The water should be added at a rate that prevents free water on top of the emulsion. 3. Check pH - Adjust to 8.5-9.0 with base agent.

318

Water-Soluble Resins

RANBAR TECHNOLOGY

INC.: G-4510-BC-75

Water Soluble Alkyd Resin:

G-4510-BC-75 is a water soluble alkyd which may be used in air dry, force dry, or baking coatings. As supplied, the resin will require neutralization with an amine and some additional co-solvent before the addition of water. Sufficient co-solvent should be used to maintain an 80:20 ratio of water to co-solvent. For baking coating, lo-20% of a melamine resin can be used for crosslinking. Co-solvent, driers and/or melamines, and neutralizer should be added to the resin and mixed completely before the addition of water. Solution Properties: Non-volatiles by weight: 75+-l% Non-volatiles by volume: 69.9+-l% Viscosity, 25C: 24-26 Weight/gallon, 25C: 8.7+-.l pounds Flash Point (Seta): 140F Color: 8 maximum Solvent: 2-Butoxyethanol# Solid Resin Properties: IPA: Present Oil type: TOFA Oil length: Short Acid value: 42-49 Drier Recommendation (Per cent metal based on resin solids): a. 0.07-0.158 Cobalt b. 0.15-0.3% Zirconium # Butyl Cellosolve

Ranbar Technology,

RANBAR TECHNOLOGY INC.:

G-4510-S-75

Inc.

319

Water Soluble Alkyd Resin:

G-4510-S-75 is a water soluble alkyd which may be used in air dry, force dry, or baking coatings. As supplied, the resin will require neutralization with an amine and some additional co-solvent before the addition of water. Sufficient co-solvent should be used to maintain an 80:20 ratio of water to co-solvent. For baking coating, lo-20% of a melamine resin can be used for crosslinking. Co-solvent, driers, and/or melamines, and neutralizer should be added to the resin and mixed completely before the addition of water. Solution Properties: Non-volatile by weight: 75+-l% Non-volatile by volume: 69+-l% Viscosity, 25C: 24-26 Weight/gallon, 25C: 8.45+--l pounds Flash Point (Seta): 90F Color: 8 maximum Solvent: 2-Butanol# Solid Resin Properties: IPA: Present Oil type: TOFA Oil length: Short Acid value: 42-49 Drier Recommendation (Per cent metal based on resin solids): a. 0.07% - 0.15% Cobalt b. 0.15% - 0.3% Zirconium # Secondary Butyl Alcohol

320

Water-Soluble Resins

RANBAR TECHNOLOGY

INC.: G-4674-BS-75

Water Soluble Alkyd Resin:

G-4674-BS-75 is a water soluble alkyd which may be used in air dry, force dry, or baking coatings. As supplied, the resin will require neutralization with an amine and some additional cosolvent before the addition of water. Sufficient co-solvent should be used to maintain an 880:20 ratio of water to cosolvent. For baking coating, lo-20% of a melamine resin can be used for crosslinking. Co-solvent, driers, and/or melamines, and neutralizer should be added to the resin and mixed completely before the addition of water. Solution Properties: Non-volatile by weight: 75+-l% Non-volatile by volume: 69+-l% Viscosity, 25C: 24-26 Weight/gallon, 25C: 8.5+-.l pounds Color: 8 maximum Flash Point (Seta): 110F Solvent: 2-butoxyethanol/2-butanol# Solid Resin Properties: IPA: Present Oil type: TOFA Oil length: Short Acid value: 42-49 Drier Recommendation (Per cent metal based on resin solids): a. 0.07-0.15% Cobalt b. 0.15-O-3% Zirconium # Butyl Cellosolve/Secondary

Butyl Alcohol

(50:50 blend)

Ranbar Technology, Inc.

RANBAR TECHNOLOGY

INC.: G-4680-BP-75

321

Water Soluble Alkyd Resin:

G-4680-BP-75 is a water soluble alkyd which may be used in air dry, force dry, or baking coatings. As supplied, the resin will require neutralization with an amine and some additional co-solvent before the addition of water. Sufficient co-solvent should be used to maintain an 80:20 ratio of water to co-solvent. For baking coating, IO-20% of a melamine resin can be used for crosslinking. Co-solvent, driers, and/or melamines, and neutralizer should be added to the resin and mixed completely before the addition of water. Solution Properties: Non-volatile by weight: 75+-l% Non-volatile by volume: 69.9+-l% Weight/gallon, 25C: 8.60+-.I pounds Viscosity: 24-26 Flash Point (Seta): 125F Color: 8 maximum alcohol# Solvent: n-propoxypropanolln-butyl Solid Resin Properties: _ IPA: Present Oil type: TOFA Oil length: Short Acid value: 42-49 Drier Recommendation (Per cent metal based on resin solids): a. 0.07-0.15% Cobalt b. 0.15-0.3% Zirconium # 50/50 Blend RANBAR TECHNOLOGY

INC.: G-4714-P-75

Water Soluble Alkyd Resin:

G-4714-P-75 is a water soluble alkyd intended primarily for fast air dry and force dry coatings. As supplied, the resin will require neutralization with an amine and additional co-solvent before the addition of water. The recommended co-solvent ratio in finished product should be 80:20 ratio of water to cosolvent by volume. Solution Pronerties: Non-Volatile by Weight: 75+-l% Non-Volatile by Volume: 69.1+-l% Viscosity, 25C; 24-26 Weight/Gallon, 25C: 8.85+-0.1 Color: 8 Maximum Solvent: n-propoxypropanol# Flash Point (Seta): 119F Solid Resin Properties: IPA: Present Oil Type: TOFA Oil Length: Short Acid Value: 55-65 Drier Recommendation (Per cent metal based on resin solids): 0.06-0.11% Cobalt O.lO-0.20% Zirconium # Propasol P

322

Water-Soluble Resins

REICHHOLD

CHEMICALS,

Water Reducible, Coatings

INC.:

AROLON 465-64-80 Polyester Resin:

Thermosetting

Polyester Resin for Industrial

AROLON 465-G4-80 is a nonoxidizing, water-reducible, oilfree polyester which thermosets when crosslinked with watersoluble amino resins. AROLON 465 may be formulated to meet most air pollution regulations. It is the unneutralized version of AROLON 465-WAB-70 and requires neutralization before use. Suggested Uses: Coil Coatings Durable interior and exterior finishes for spray, dip, or flow application Performance:

Imparts excellent hardness and flexibility Furnishes outstanding gloss and gloss retention, plus good overbake color Adapts to coil coating, spray, dip, or flowcoating operations Cures in a range from 1 minute at 500F to 20 minutes at 300-350F Performs comparably to solvent-thinned, oil-free alkyds and coconut alkyds after 1 year Florida exposure

Alternative Products: AROLON 557 water-reducible acrylic resin is suggested for applications requiring superior hardness and alkali resistance where post forming is not required. KELSOL 2080 is a polyester resin designed for electrodeposition and spray application. Tentative Specifications: Percent Solids, Weight: 79-81 Viscosity @ 25C: Stokes: 60-120 Gardner-Holdt: 24-25+ approx. Color-Gardner: 3 max. Specific Gravity, 25C/25C: 1.11 approx. Pounds/Gallon, solution: 9.1-9.3 Acid Value, on Solids: 60-70 Solvent: Ethylene Glycol Monobutyl Ether

Reichhold Chemicals, inc.

REICHHOLD CHEMICALS,

323

INC.: AROLON 557-B-70 Acrylic Resin:

Water Dispersible Acrylic Resin for Industrial Coatings AROLON 557-B-70 is a nonoxidizing water dispersible acrylic resin for formulating thermosetting coatings crosslinked with aminoplast resins. The uncrosslinked polymer is a hard film former. Suggested Uses: - Exterior-durable baked enamels - Non-yellowing clear coatings and general industrial topcoats Performance: - Disperses readily in amine and water - Develops excellent hardness and high gloss - Provides excellent color and color retention - Offers good chemical and stain resistance - Has very good pigment wetting properties - Excellent dispersing media for emulsion type lacquers such as AROLON 840 Alternative Products: AROLON 559 for lower viscosity/higher solids; AROLON 465 water reducible oil-free polyester for applications requiring superior flexibility. Specifications: Percent Solids, Weight: 69-71 Percent Solids; Volume: 61 approx. Viscosity at 25C, Stokes: 240-310 Gardner-Holdt: 26+ Color, Gardner: 2 max. Specific Gravity, 25C/25C: 1.00 approx. Pounds/Gallon. solution: 8.25-8.35 PoundsjGallon; solids: 9.6 approx. Acid Value, on solids: 66-75 Solvent: See-Butyl Alcohol TvDiCal Performance Data: Solvent Tolerance (Percent Solvent to Produce Haze) Unneutralized Solvent Alcohols Infinite Glvcol Ethers Infinite Aliphatic Limited Infinite Aromatic Suggested Neutralization: (Based on Resin as Supplied) Pounds Amine Per 100 Pounds Resin: Dimethyl Ethanolamine: 7.00 Triethylamine: 7.98 28% Ammonia: 4.48

324

Water-Soluble

Resins

REICHHOLD CHEMICALS,

INC.: AROLON 559-G4-70 Acrylic Resin:

Water Dispersible Acrylic Resin for Industrial Coatings AROLON 559-G4-70 is a non-oxidizing water dispersible acrylic resin for formulating thermosetting coatings crosslinked with aminoplast resins. The uncrosslinked polymer is a hard film former. AROLON 559 is cut in 2-butoxy ethanol and gives improved viscosity reduction. The resin should be neutralized with a volatile amine before dilution with water. Suggested Uses: - Exterior - durable baking enamels - Non-yellowing clear coatings and general industrial topcoats Performance: Reduces faster with water Gives increased solids and lower VOC enamels Develops excellent hardness and gloss Provides excellent color retention Offers qood chemical and stain resistance Has very good pigment wetting properties Excellent dispersing vehicle for emulsion type lacquers such as AROLON 840 Alternative Products: AROLON 557 for higher viscosity acrylic coatings, KELSOL 5293 is a water reducible oil-free polyester is suggested for applications requiring superior flexibility and KELSOL 3980, a coconut oil alkyd for ease of application. KELSOL 4069 and 4097 acrylic polyesters give lower VOC levels. Specifications: Percent Solids, Weight: 69-71 Percent Solids; Volume: 66 approx. Viscosity @ 25C: Stokes: 130-200 Gardner-Holdt: 26 approx. Color, Gardner: 5 max. Pounds/Gallon, Solution: 8.7-8.8 Pounds/Galion, Solids: 9.26 approx. Specific Gravity, 25C/25C: 1.05 approx. ._ Acid-Value, on solids: 60-70 Solvent: 2-Butoxy Ethanol Typical Performance Properties: AROLON 559120% Cymel 303: Bake: 30' @ 300F: Gloss Readings (60/20): 92186 100 Double MEK Rubs: Pass Pencil Hardness: 2H Reverse/Direct Impact (In-Lbs): lo/20 Salt Spray-100 hrs.-Q-Panel: 2/16" Creepage 300 hrs.-BlOOO: 2/16" Creepage

Reichhold Chemicals, Inc.

REICHHOLD CHEMICALS,

INC.: AROLON 580-W-42 Alkyd Resin:

Water Dispersible Alkyd Resin for Fast Drying Multipurpose Trade Sales and Industrial Coatings AROLON 580-W-42 is a water dispersible alkyd resin which cures rapidly whether air dried or baked, with or without melamine or urea crosslinkers. Suggested Uses: Trade Sales interior decorative and general purpose enamels Floor enamels Flat wall paints Maintenance paints Exterior house paints Industrial general utility dip, spray, flow coat and brushing enamels Printing inks Performance: Air dries set-to-touch in approximately 10 minutes; passes 500-gram Zapon in 5-6 hours Bakes in 20-30 minutes at 250-350F with minimal discoloration Imparts excellent dip and spray properties to properly formulated industrial enamels Improves color acceptance, brush drag, leveling, gloss & adhesion to chalky substrates when used as a modifier for latex paints Alternative Products: AROLON 585 for very fast air dry. KELSOL 3907 for fast drying maintenance and industrial applications where greater salt spray resistance is needed. AROLON 465 for more flexible bake enamels. Specifications: Percent Solids, Weight: 41-43 Viscosity @ 25C (Brookfield) #3 Spindle at 30 rpm, cps.: 700-2500 Color/Appearance: Opalescent Snecific Gravitv. 25C/25C: 1.06-1.08 Pounds/Gallon; solution: 8.89 approx. Pounds/Gallon, solids: 9.80 approx. Acid Value, on solids: 12-17 -pH @ 25C: 6.5-7.5 Solvent: Water Typical Performance Data: Zinc Oxide Compatibilty: Very Good Solvent Tolerance: Water: Infinite Toluene: Limited Mineral Spirits: Limited

325

326

Water-Soluble Resins

REICHHOLD CHEMICALS,

INC.: AROLON 505-W-43 Alkyd Resin:

Water Dispersible Alkyd Resin for Air Dry and Low Bake AROLON 585-W-43 is a water dispersible alkyd resin, supplied without cosolvent, which exhibits extremely fast water-release characteristics. Air dry properties compare with those of vinyltoluenated or styrenated alkyds. Suggested Uses: - Fast air dry or force dry industrial primers, enamels, and clear finishes - High solids (fast water reduction) coatings - Modifier for other water reducible resins or emulsions - Inks requiring quick set and early wet-rub resistance Performance: - Very fast air dry - Very good adhesion and toughness - Good lift resistance - High hydroxyl value for crosslinking Alternative Products: KELSOL 3907 and 3961 for better corrosion coupled with fast dry.

resistance

Specifications: Percent Solids, Weight: 42-44 Percent Solids, Volume: 38.6 approx. Viscosity @ 25C, cps: Brookfield, #3 spindle, 30 rpm: 300-1500 Color, Gardner: Milky Pounds/Gallon, Solution: 8.85-8.95 Pounds/Gallon, Solids: 9.9 approx. Specific Gravity, 25/25C: 1.07 approx. pH: 6.8-8.0 Solvent: Water Film Compatibility: KELSOL 3900 Series AROLON 580 Resin Styrene-Butadiene Emulsions Exterior Acrylic Emulsions Interior Acrylic Emulsions Polyvinyl Acetate Emulsions Water-Soluble Melamine Resins Water-Soluble Urea Resins C=compatible M=Medium haze

Percent Modifier 50 90 10 C C C C C C SL SL SL M C SL I I I I I I C C SL=Slight haze I=Incompatible

Solvent Tolerance: Water - Infinite Oxygenated Solvent - Check for compatibility

Reichhold Chemicals, Inc.

REICHHOLD CHEMICALS, Emulsion:

327

INC.: AROLON 820-W-49 Styrene Acrylic

Vehicle for Water Thinned Industrial Maintenance AROLON 820 is a thermoplastic air dry applications.

Finishes

Styrene acrylic emulsion for

Suggested Uses: - Maintenance coatings for application over ferrous, nonferrous and masonry surfaces - Rust inhibitive primers where three mil dry film thickness may be used - Exterior gloss and semigloss enamels - Semigloss rust inhibitive enamels Performance: - Offers exceptional corrosion resistance when formulated with rust inhibitive pigments - Provides good stability with reactive pigments - Develops tough but flexible films at room temperature - Excellent non-yellowing properties - May be formulated to resist flash rusting - Displays good gloss in a variety of pigmentations Alternative Products: AROLON 850 for coatings on plastic; AROLON 840 and 850 acrylic emulsions for fast air dry industrial primers and enamels: the KELSOL series of water dispersible air dry alkyds for trade sales, maintenance and industrial coatings. Specifications: Percent Solids, Weight: 48-50 Percent Solids, Volume: 46 approx. Viscosity @ 25C (Brookfield LVT, #2 at 60 rpm): loo-350 Appearance: Milky White Pounds/Gallon, Solution: 8.75-8.85 Pounds/Gallon, Solids: 9.3 approx. Specific Gravity, 25/25C: 1.06 approx. pH: 8.0-9.0 Solvent: Water, Ammonia plus a small amount of ethylene glycol Typical Performance Data: Minimum Film Forming Temperature: +8C Tg (calculated): +3C Tg (measured): +13.2C Freeze Thaw Resistance: Emulsion (Neat): 1 Cycle (Thickens) Mechanical Stability: 30 minutes on High Speed Mixer: No Coagulum Chemical Stability: Very Good Compatible Coalescing Solvents: Texan01 Butyl Carbitol Acetate Butyl Carbitol Compatible Thickeners: QP-4400/RHEOLATE 255, 278

328

Water-Soluble

Resins

REICHHOLD CHEMICALS,

INC.: AROLON 840-W-39 Acrylic Emulsion:

Acrylic Emulsion for Industrial Finishes AROLON 840 is a thermoplastic styrene acrylonitrile acrylic emulsion designed for air dry or force dry applications. Suggested Uses: - Implement finishes - Fast air dry primers and shopcoats - Metal cabinets - Fast dry enamels - Floor finishes when blended with SPENSOL water dispersible urethanes Performance: - Provides very fast dry - Develops early water resistance - May be formulated with low cosolvent levels - Imparts hard, tough films - Withstands Cleveland Humidity Cabinet exposure Alternative Products: AROLON 820 for maintenance coatings. AROLON 850 for best adhesion to plastics and oily metals. Specifications: Percent Solids, Weight: 38-40 Percent Solids; Volume: 36 approx. Viscosity @ 25C, cps (Brookfield LVT, #2 Spindle 8 60 RPM): 20-100 PoundsjGallon, solution: 8.6-8.8 Specific Gravity, 25/25C: 1.05 approx. Pounds/Gallon, solids: 9.4 approx; Free Acrylonitrile: 100 ppm max. pH: 7.0-8.0 Volatiles: Water, Ammonia Typical Performance Data: Film Properties: Set-to-Touch(minutes): 9 200 g. Zapon(minutes): 20 500 g. Zapon(minutes): 20 4 Hour Sward Hardness: 14 24 Hour Sward Hardness: 24 Dry Properties: (White enamel. P/B = 0.7, 3 mil drawdown, DFT = 1.1-1.3 mils) Substrate: Bonderite 37 Air Dry 16 Hours: 4 Hour HZ0 Snot: Sl. soft-recovers Air Dry 5 days: (100 Hours Salt Spray) X-Rust: Trace - Blister: #6F

Reichhold Chemicals. lnc

REICHEOLD CHEMICALS, Emulsion:

INC.: AROLON 845-W-45 Styrene Acrylic

ARCLON 845-W,-45 is a thermoplastic styrsne acrylic emulsion design'ed for use in air dry or force dry applications over metal substrates. The copolymer contains no acrylonitrile or _ organic solvent. Suggested Uses: - Air dry primer and/or topcoat for plastics and metals Performance: - F'ast air dry - B:xcellent >water/hum:idity resistance - Good gasoline resistance - Excellent chemical resistance - Very good solvent resistance - Very good corrosion resistance Alternative Products: AROLON 850 flor adhesion to more plastic substrates; AROLON 860 folr a crosslinked sylstem. Specifications: Percent Solids. Weight: 44-46 Percent Solids; Volume: 43 approx. Viscosity @ 25C. ens (Brookfield LVT, #2 spindle at 60 rpm):- loo-306 Pocnds/Gallcn: 8.6-8.:8 Specific {Gravity, .25C/25C: '1.05 approx. Pounds/Gallon, Solids: 9.4 approx. pH: 8-O-8.5 Applearance: IOpaque White Liquid Volatiles: l,ater, Ammonia Typical Perform,ance Data: White Enamel (2402-24A): Gardner Dry 'Time (3 mil drawdmn): Set: 25 rin. Through cry: 40 min. Dry Hard: 50 min. ZapIon Tack Free (500 Igms): 25 min. Swa rd Hardness: 1 Day: 32 3 Days: 38 7 Days: 40 Minimum Filr-Forming 'Temperature: +63C (measured) Gle.ss Transition Temperature (Tg): +67C (measured) Pencil Hardness (7 da:ys): H Gloss (60/20): 70/35 Implact Resistance (in-lbs) Direct/Reverse: lO/FlO Conical Mandrel: Pass Salt Fog (1CO hrs) B-1000: l/3:2" Q-<Steel: l/,16"

329

330

Water-Soluble Resins

REICHHOLD CHEMICALS, Emulsion:

INC.: AROLON 850-W-45 Acrylic Copolymer

AROLON 850-W-45 is an acrylic copolymer emulsion designed for primer and topcoat use on a variety of engineering grade plastics and metals. It is supplied at a slightly basic pH and contains no organic solvent. Suggested Uses: - Air dry primer and/or topcoat for plastics and metals Performance: - Fast air dry - High gloss - Good water resistance - Excellent adhesion to Noryl, polycarbonate, acrylic, polystyrene and ABS plastics - Excellent adhesion to metal surfaces, including those with oily contamination - Excellent mechanical stability Alternative Products: AROLON 840 for improved gasoline resistance; AROLON 820 for maintenance primers requiring improved corrosion resistance. Specifications: Percent Solids, Weight: 44-46 Percent Solids, Volume: 43 approx. Viscosity @ 25C (Brookfield LVT, Cps, #3 Spindle @ 60RPM): 700-1500 Avoearance: Milkv. White Specific Gravity;'25C/25C: 1.04 approx. Pounds/Gallon, solution: 8.6-8.7 Pounds/Gallon; solids: 9.04 approx. pH: 7.3-8.5 Volatile: Water Typical Performance

Data: Cross-Hatch Adhesion and Metals:

Gardner Dry Time (3 mil drawdown): Set: l/2 hr. Through: l-l/2 hr. Hard: 2-314 hr. Sward Hardness: 1 Day: 24 3 Days: 30 7 Days: 38 Pencil Hardness (at 7 days): B Gloss (60/20): Over Steel: 89161 Over Norvl N-190: 90/58 Adhesion to_Noryl: After 1 day dry: Excellent After 7 days dry: Excellent

to Plastics

Reichhold Chemicals. Inc.

REICHHOLD CHEMICALS, Emulsion:

331

INC.: AROLON 860-W-45 Acrylic Copolymer

AROLON 860-W-45 is an acrylic copolymer emulsion designed for nrimer and topcoat use on a variety of metals and enqineerinq grade plastics. Crosslinking with melamines, polyaziridines or carbodiimides provides improved solvent and chemical resistance. It is compatible with reactive pigments for improved corrosion resistance and contains no organic solvent. Suggested Uses: - Air dry/force dry/baking - Air dry/force dry/baking

primers for plastics and metals. topcoats for plastics and metals.

Performance: Crosslinkable with polyaziridines, carbodiimides, and melamines. Fast air dry. High gloss. Good gasoline resistance. Outstanding chemical, solvent and stain resistance when crosslinked. Excellent adhesion to Noryl, polycarbonate, acrylic, polystyrene, and ABS plastics. Excellent mechanical stability. Alternative Products: AROLON 850 for higher gloss and improved corrosion resistance; AROLON 820 for maintenance primers requiring corrosion resistance. Specifications: Percent Solids, Weight: 44-46 Percent Solids, Volume: 43 approx. Viscosity @ 25C, cps (Brookfield LVT, #3 spindle @ 60 rpm): 1000 max. Appearance: Opaque White Liquid Pounds/Gallon. Solution: 8.7-8.9 Pounds/Gallon, Solids: 9.33 approx. Swecific Gravity. _ 25C/25C: 1.05 approx. pH: ‘8.0-8.5 Volatile: Water, Ammonia Typical Performance Data: White Gloss Ename1(2402-17A), Air-Dried: Gardner Dry Time (3 mil drawdown): Set: 15 min. Through Dry: 30 min. Dry Hard: 45 min. Zapon Tack Free (500 gms): 15 min. Sward Hardness: 1 Day: 36 3 Days: 38 7 Days: 48 Minimum Film-Forming Temperature: 98C

332

Water-Soluble Resins

REICHHOLD CHEMICALS,

INC.: AROLON 970-G4-70 Alkyd:

Water Dispersible and Bake

Styrenated Alkyd for Air Dry, Force Dry,

AROLON 970 is an economical, water dispersible copolymer resin for fast air dry and force dry industrial primer and shop coat applications. Suggested Uses: Fast dry, low cost industrial primers Colored enamels Spray finishes Low bake or force dry finishes Quick-dry clear varnish Melamine crosslinkable enamels (e.g. drum and strapping enamels) Performance: - Disperses readily in economical ammonia-water and several amine-water combinations - Formulates to meet many air pollution regulations - Resists repeated freeze-thaw cycles in water dispersed form - Mechanically stable for dispersing pigments - Air dries to excellent gloss in enamel-type formulas - Develops excellent early hardness/hot hardness Specifications: Percent Solids, Weight: 69-71 Percent Solids, Volume: 67.7 (approx.) Viscosity at 25C: Stokes: 144-268 Gardner-Holdt: Z6(approx.) Color, Gardner: 0 max. Acid Value, on solids: 65-75 Pounds/Gallon, Solution: 8.7-8.8 Pounds/Gallon, Solids: 9.09 (approx.) Specific Gravity, 25/25C: 1.05 (approx. Solvent: Butoxy Ethanol Film Compatibility (Reduced to 50%, neutralized AROLON AROLON AROLON KELSOL KELSOL

557 580 585 3902 3907

with ammonia) Percent Modifier(solids) 50 10 90 C I I C I C# C C C# C I C# C I I

C = Compatible I = Definite haze or incompatible C#= Slight haze

Reichhold Chemicals, Inc.

REICHHOLD CHEMICALS,

INC.: AROLON 921-64-70 Alkyd:

Water Dispersible and Bake

Styrenated Alkyd for Air Dry, Force Dry,

333

AROLON 921 is an economical, water dispersible copolymer alkyd resin for fast air dry, force dry and baking industrial primer and shop coat applications. Suggested Uses: - Fast dry, low cost industrial coatings - White or colored enamels - Low bake or force dry finishes - Drum and strapping enamels - Quick dry clear varnish Performance: - Formulates to meet air pollution regulations - Air dries to excellent gloss in enamel formulations - Develops excellent early hardness in air dry applications - Develops good early water resistance - Crosslinkable with melamine resins - Good hot hardness Alternative Products: AROLON 585 for faster dry-to-handle. KELSOL 3910 for greater flexibility. KELSOL 3919 for improved corrosion resistance, and AROLON 970 for a higher drink resin. Specifications: Percent Solids, Weight: 69-71 Percent Solids, Volume: 65.4 (approx.) Viscosity at 25C: Stokes: 50-100 Gardner-Holdt: 23-25 Color, Gardner: 9 max. Acid Value, on solids: 58-68 Pounds/Gallon, Solution: 8.55-8.65 Pounds/Gallon, Solids: 9.20 (approx.) Specific Gravity, 25/25C: 1.03 (approx.) Solvent: Butoxy Ethanol

334

Water-Soluble

Resins

REICHHOLD CHEMICALS,

INC.: KHLSOL 3900-BG4-75 Alkyd:

Water Dispersible Alkyd Resin for Air Dry and Low Bake KELSOL 3900-BG4-75 is a water dispersible chain-stopped alkyd for economical industrial finishes. Additional cosolvent beyond what is supplied in KELSOL 3900-BG4-75 is usually required for optimum solubility and stability in water-based paints. Suggested Uses: - Air dry or force dry topcoats and primers - Low cost primers Performance: - Past dry - Rapid development

of hardness

Alternative Products: KELSOL 3919 for better corrosion resistance. KELSOL 3960 series for best overall performance and stability. Specifications: Percent Solids, Weight: 74-76 Percent Solids, Volume: 68.7 approx. Viscosity @ 25C: Stokes: 130-180 Gardner-Holdt: 26+ Color, Gardner: 8 max. Acid Value, on Solids: 51-57 Pounds/Gallon, Solution: 8.72-8.82 Specific Gravity, 25/25C: 1.05 approx. Pounds/Gallon, Solids: 9.60 approx. Solvent: Butoxy Ethanol/n-Butanol (50/50) rpical Performance Data: White Gloss Ename1(1619-16): Performance Properties(1 mil dry film) Gardner Dry Time, Hours: Set: 1 Through Dry: 3 Dry Hard: 6.5 Zavon Tackfree (500 mss) Sward Hardness:‘ _ l/3/7 days: 14/18/30 Physical Properties: Gloss (60/20): 90/85 Pencil Hardness: HB Reverse/Direct Impact (in-lbs): 10120 Conical Mandrel, l/8": Pass

Reichhold Chemicals, Inc.

REICHHOLD CHEMICALS,

335

INC.: KELSOL 3904-BG4-75 Alkyd:

Water Dispersible Alkyd Resin for Air Dry and Low Bake KELSOL 3904-BG4-75 is a water dispersible alkyd for economical industrial finishes. Additional cosolvent beyond what is supplied in KELSOL 3904-BG4-75 is usually required for optimum solubility and stability in water-based paints. Suggested Uses: - Air dry or force dry topcoats and primers - Low cost primers Performance: - Good dry rate - Fair corrosion resistance Alternative Products: KELSOL 3918 and 3919 for better corrosion. KELSOL 3960 series for best overall performance and stability. Specifications: Percent Solids, Weight: 74-76 Percent Solids, Volume: 69.4 approx. Viscosity @ 25C: Stokes: 120-170 Gardner-Holdt: 25-26 Color, Gardner: 0 max. Pounds/Gallon, Solution: 8.6-8.7 Specific Gravity, 25/25C: 1.04 approx. Pounds/Gallon, Solids: 9.4 approx. Solvent: Butoxy Ethanol/n-Butanol (50/50) Performance Properties (1 mil dry film): Gardner Dry Time, Hours: Set: 1.0 Through Dry: 2.5 Dry Hard: 7.0 Sward Hardness: l/3/7 Days: 14/24/26 Physical Properties: Gloss (60/20): 90/85 Reverse/Direct Impact (in-lbs): 20/40 Conical Mandrel, l/8": Pass Pencil Hardness: HB Compatibility: KELSOL 3904-BG4-75 is compatible the other KELSOL alkyd resins.

in all ratios with

336

Water-Soluble Resins

REICHHOLD CHEMICALS,

INC.: KELSOL 3905-B2G-75 Alkyd:

Water Dispersible Alkyd Resin For Air Dry and Low Bake RELSOL 3905-B2G-75 is a water dispersible alkyd designed to aive excellent corrosion resistance as well as excellent stability. It must be neutralized prior to the addition of water and usually requires additional cosolvent for best solubility in water-thinned paints. Suggested Uses: - Air dry and low bake industrial enamels and primers - Flowcoat, spray and diptank coatings Performance: - Excellent package stability in paints - High degree of corrosion resistance - Early water resistance Alternative Product: KELSOL 3907 for faster dry. KELSOL 3960 series for best overall performance and stability. Specifications: Percent Solids, Weight: 74-76 Percent Solids, Volume: 69.7 approx. Viscosity @ 25C: Stokes: 80-120 Gardner-Holdt: 25+Color, Gardner: 8 max. Pounds/Gallon, Solution: 8.50-8.60 Pounds/Gallon, Solids: 9.2 approx. Specific Gravity, 25/25C: 1.03 approx. Acid Value, on Solids: 38-42 Solvent, Weight Percent: Butoxy Ethanol/see-Butanol

(50/50)

Typical Performance Data: White Gloss Enamel (1697-25): Gardner Dry Time, Hours: Set: l/2 Through Dry: 4 Dry Hard: 6 Sward Hardness: l/3/7 Days: 14128138 Physical Properties: Gloss (60/20): 90/86 Reverse/Direct Impact (in-lbs): 5/20 Conical Mandrel, l/8": Pass Pencil Hardness: HB-F Salt Spray, CRS, 100 hrs: l/16" creepage

Reichhold Chemicals, Inc.

REICHHOLD CHEMICALS, Water Dispersible

337

INC.: KELSOL 3906-B2G-75 Alkyd: Alkyd Resin for Air Dry and Low Bake

KELSOL 3906-B2G-75 is a water dispersible alkyd designed to give excellent corrosion resistance as well as early water spot resistance. It must be neutralized prior to the addition of water and usually requires additional cosolvent for best solubility and stability in water-thinned paints. Suggested Uses: - Air Dry or force dry primers and topcoats - Spray, dip, and flowcoat applications Performance: - Excellent corrosion resistance - Good air dry rate - Very good humidity and water resistance Alternative Products: KELSOL 3961 for faster dry, KELSOL 3918 and 3919 for lower cost. Specifications: Percent Solids, Weight: 74-76 Percent Solids, Volume: 69.4 approx. Viscosity @ 25C: Stokes: 130-180 Gardner-Holdt: 26+ Color, Gardner: 8 max. Pounds/Gallon, Solution: 8.60-8.70 Pounds/Gallon, Solids: 9.3 approx. Specific Gravity, 25/25C: 1.03 approx. Acid Value, on Solids: 39-43 Solvent, Weight Percent: Butoxy Ethanol/set-Butanol

(SO/SO)

Typical Performance Data: White Gloss Ename1(1697-26): Performance Properties (1 mil dry film): Gardner Dry Time, Hours: Set: l/2 Through Dry: 2 Dry Hard: 4 Zapon Tackfree Time (hrs): 500 gms (drawdown): 3 500 gms (sprayout): 3/4 Sward Hardness: _ 1 Day: 20 3 Days: 24 7 Days: 30 Physical Properties: Gloss (60/20): 92/85 Reverse Impact, in-lbs: 10 Compatibility: KELSOL 3906-B2G-75 is compatible in all ratios with the other KELSOL alkyd resins.

338

Water-Soluble Resins

REICHHOLD CHEMICALS, Resin:

INC.: KELSOL 3907-G2B-75 Water Reducible

Water Reducible Resin For Air Dry and Low Bake KELSOL 3907-G2B-75 is a fast drying water dispersible alkyd designed to give early hardness and good humidity resistance. Additional cosolvent is required for the best solubility and stability in paint formulations. Normal butanol or a blend of n-butanol and butoxy ethanol is required for optimum stability and film performance. Suggested Uses: - Fast drying primers and enamels. - Spray, dip or flowcoat applications. Performance: - Very fast dry. - Excellent stability. - Excellent humidity resistance. - Very g00a corrosion resistance. - Passes hypoid gear lubricant test (100 hrs. @

225F).

Alternative Products: KELSOL 3961 for fast dry at a low cost. Soecifications: Percent solids, Weight: 74-76 Percent solids, Volume: 69.5 (approx.) Viscosity @ 25C: Stokes: 160-210 Gardner-Holdt: Z5+-Z6+ Acid Value. on solids: 39-43 Color, Gardner: 8 max. Soecific Gravity, 25C/25C: 1.02-1.04 Pounds/Gallon; Solution: 8.56 (approx.) Pounds/Gallon, Solids: 9.30 (approx.) Solvent: Propoxy Propanol/Sec-Butanol (50/50) Compatibility: KELSOL 3907-G2B-75 is compatible with all the other air dry alkyds. AROLONS 840 and 850 can be blended in at the 25% level (based on resin solids). Melamines should be used at the lo-20% level.

Reichhold Chemicals, Inc.

REICHHOLD CHEMICALS, Resin:

339

INC.: KELSOL 3909-BG4-75 Water Dispersible

Water Dispersible Resin for Air Dry and Low Bake KELSOL 3909-BG4-75 is a water dispersible alkyd resin similar to KELSOL 3902 but specifically designed for improved corrosion resistance, particularly in thin films. It is lower in viscosity than KELSOL 3902 but, in general, can be substituted at equal weights in the KELSOL 3902 formulations. KELSOL 3909 requires some additional cosolvent beyond what is in the vehicle for the best stability and solubility in paints. Suggested Uses: - Air dry or force dry primers and top coats for spray, dip or flowcoat applications - Metal finishing applications where film thickness is only expected to be in the 0.2 to 0.7 mil range Performance: - Outstanding corrosion resistance, particularly in thin films - Excellent humidity resistance - Very good exterior durability and early water spot resistance Alternative Products: KELSOL 3961 for faster dry, KELSOL 3910 for lower cost, KELSOL 3906 for equivalent corrosion resistance with faster dry, KELSOL 3907 for very good corrosion resistance with the fastest dry. Specifications: Percent Solids, Weight: 74-76 Percent Solids, Volume: 69.4 (approx.) Viscosity @ 25C: Stokes: 90-120 Gardner-Holdt: 25 approx. Color, Gardner: 8 max. Specific Gravity, 25C/25C: 1.02-l -04 Pounds/Gallon, Solution: 8.56 approx. Pounds/Gallon, Solids: 9.30 approx. Acid Value, on solids: 34-38 Solvent: Butoxy Ethanol/n-Butanol (50/50) Typical Performance Data: White Gloss Ename1(1788-36): Dry Times, 1 Mil Dry Film (Drawdown): Set: 45 minutes Thru Dry: 5 l/2 hours Sward-Hardness: One Day: 16 Three Days: 30 Physical Properties: Direct Impact: 120 inch lbs. Reverse Impact: 120 inch lbs.

340

Water-Soluble Resins

REICHHOLD CHEMICALS,

INC.: KELSOL 3910-B2G-75 Alkyd:

Water Dispersible Resin For Air Dry and Low Bake KELSOL 3910-B2G-75 is a water dispersible short oil alkyd designed for economical industrial finishes. Additional cosolvent beyond what is supplied in KELSOL 3910-B2G-75 is usually required for optimum solubility and stability in water-based paints. Manganese driers are incompatible with this resin. Suggested Uses: - Air dry or force dry topcoats and primers - Used for spray, dip, and flowcoat applications - LOW cost shopcoat primers - High hydroxyl value for melamine cross linking Performance: - Good corrosion resistance - Excellent stability - Good humidity resistance - Very flexible in air dried and crosslinked

coatings

Alternative Products: KELSOL 3918 and KELSOL 3919 for broader pigment and drier compatibility. Specifications: Percent Solids, Weight: 74-76 Percent Solids, Volume: 70 approx. Viscosity @ 25C: Stokes: 120-200 Gardner-Holdt: 25+-26+ Color, Gardner: 7 max. Pounds/Gallon, Solution: 8.55-8.65 Pounds/Gallon, Solids: 9.23 approx. Specific Gravity, 25/25C: 1.04 approx. Acid Value, on Solids: 39-43 Solvent: 2-Butoxy Ethanol/set-Butanol(64/36) Typical Performance Data: (Based on White Gloss Enamel 2134-3) Drying Time (3 mil wet film--drawdown): Set: 30 minutes Through Dry: 2 hours Hard Dry: 5 hours Zapon Tack-free Time (500 gram): 3 hours Sward Hardness (1 mil dry film): One Day: 22 Three Davs: 28 Physical Properties (1 mil dry film): Gloss (60/20): 90/84 Reverse Impact, in-lbs.: 120 Direct Impact, in-lbs.: 160 Conical Mandrel, l/8": Passed

Reichhold

REICHHOLD CHEMICALS, Water Dispersible

Chemicals,

Inc.

INC.: KELSOL 3918-B2G-70 Alkyd Resin: Alkyd Resin For Air Dry and Low Bake

KELSOL 3918-B2G-70 is a water-dispersible short oil alkyd designed to give fast dry with good early water resistance. Corrosion resistance is moderate. This resin must be neutralized prior to the addition of water and usually requires additional cosolvent for best solubility and stability in water-thinned paints. Suggested Uses: - Fast air dry or force dry primers and topcoats - Spray, dip and flowcoat applications Performance: - Fast air dry rate - Excellent humidity and early water resistance - Moderate corrosion reSiStaIm? Higher solids paints Soecifications: mL Percent Solids, Weight: 69-71 Percent Solids, Volume: 64.6 (approx.) Viscosity @ 25C: Stokes: 90-130 Gardner-Holdt: Z5+ (approx.) Color, Gardner: 8 max. Pounds/Gallon, Solution: 8.48-8.58 Pounds/Gallon, Solids: 9.1 (approx.) Specific Gravity, 25C/25C: 1.023 (approx.) Acid Value, on solids: 37-41 Solvent, Weight Percent: Butoxy Ethanolfsec-Butanol

SO/50

Typical Performance Data: White Gloss Enamel (2383-13): Gardner Dry Time (hrs.): Set: 0.5 Through Dry: 1.0 Dry Hard: 2.5 Zapon Tackfree (hrs.)--Drawdown: 200 gm: 2.5 500 gm: 3.5 Sward Hardness: (l/3/7 Days): 22/30/34 Reverse/Direct Impact (in-lb): FlO/lO Conical Mandrel, i/8": Pass 4-Hour Water Spot (24 hr. air dry): OK Gloss (60/20): 90178 Corrosion Resistance (100 hrs., CRS, creepage): 2/16" QUV (60/20): Initial: 87/77 Humidity Resistance (60/20): Initial: 88/77 Cleveland Humidity Resistance (60/20): Initial: 89/78

34 1

342

Water-Soluble Resins

REICHHOLD CHEMICALS, Water Dispersible

INC.: KELSOL 3919-B2G-70

Alkyd Resin:

Alkyd Resin For Air Dry and Low Bake

KELSOL 3919-B2G-70 is a water-dispersible, chain-stopped alkyd designed to give fast dry coupled with excellent corrosion resistance. It must be neutralized prior to the addition of water and usually requires additional cosolvent for best solubility and stability in water-thinned paints. Suggested Uses: - Fast air dry or force dry primers and topcoats - Spray, dip and flowcoat applications Performance: - Excellent corrosion resistance - Fast air dry rate - Excellent humidity and water soak resistance Specifications: Percent Solids, Weight: 69-71 Percent Solids, Volume: 64 (approx.) Viscosity @ 25C: Stokes: 90-130 Gardner-Holdt: 25+ (aoorox.) __ Color, Gardner: t3max. Pounds/Gallon, Solution: 8.6-8.7 Pounds/Gallon; Solids: 9.3 (approx.) Specific Gravity, 25C/25C: 1.04 (approx.) Acid Value, on solids: 33-37 Solvent, Weight Percent: Butoxy Ethanol/set-Butanol

(SO/SO)

Typical Performance Data: High Gloss White Enamel (2383-66): Gardner Dry Time (hrs.): Set: 1.0 Through Dry: 2.0 Dry Hard: 3.5 Zapon Tackfree (hrs.)-Drawdown: 200 gm: 2.0 500 gm: 3.5 Sward Hardness (l/3/7 Days): 28/30/32 Reverse/Direct Impact (in-lb): FlO/lO Conical Mandrel, l/8": Pass 4-Hour Water Spot (24 hr. air dry): V. Sl. Haze Gloss (60/20): 89/80 Corrosion Resistance (100 hrs., CRS, creepage): l/32" QUV (60/20): Initial: 92/82 Humidity Resistance (60/20): Initial: 91/80 Cleveland Humiditv Resistance (60/20): Initial: 89/75Water Soak (60/20): Initial: 90/80

Reichhold Chemicals, Inc.

REICHHOLD

CHEMICALS,

343

INC.: KELSOL 3922-G-80 Alkyd Resin:

Water Dispersible Resin For Architectural Coatings

and Maintenance

KELSOL 3922-G-80 is a water dispersible alkyd designed for the stringent stability requirements of consumer shelf goods. It is a higher solids improved version of KELSOL 3920 developed for minimum viscosity drift while maintaining dry and homogeneity after 60-90 days at 120F. Suggested Uses: - Architectural gloss and semi-gloss brushing enamels - Exterior trim and trellis enamels - Industrial maintenance primer--topcoat systems - Modifier for SPENSOL F74 varnishes and enamels - Water dispersed wood stains Performance: Develops excellent 60 and 20 gloss Brushes or rolls easily with outstanding flow Develops early water spot resistance Dries to tough non-thermoplastic films Maintains gloss in accelerated and prototype exterior exposure on a par with the more durable alkyds May be formulated to meet VOC regulations Exhibits better performance over poorly prepared surfaces than latex systems Provides good salt fog resistance when properly formulated into rust inhibitive multicoat systems Specifications: Percent Solids, Weight: 79-81 Percent Solids, Volume: 78.2 approx. Viscosity @ 25C: Stokes: 90-130 Gardner-Holdt: 25 approx. Color, Gardner: 8 max. Specific Gravity, 25/25C: 1.03-1.05 Pounds/Gallon, Solution: 8.64 approx. Pounds/Gallon, Solids: 8.90 approx. Acid Value, on solids: 52-58 Solvent: Propoxy Propanol/Diethylene Glycol n-Butyl Ether

344

Water-Soluble Resins

REICHHOLD CHEMICALS,

INC.: KELSOL 3950-B2G-70

Alkyd Resin:

Water Dispersible Phenolic Modified Resin for LiftResistant Air Dry and Baking Primers KELSOL 3950-B2G-70 is a water-dispersible phenolicmodified alkyd designed to be used in lift-resistant primers, under topcoats such as nitrocellulose lacquer, alkyds, twocomponent urethanes, etc., which contain strong solvents. Suggested Uses: - Lift-resistant primer vehicle for lacquers and enamels. - Air-dry or baking primers. - Colored topcoats. Performance: - Exhibits excellent adhesion. - Fast air dry. - Imparts good bake properties. - Resists lifting by strong solvents. Tentative Specifications: Percent Solids, Weight: 69-71 Percent Solids, Volume: 65 approx. Viscosity at 25C: Stokes: 45-70 Gardner-Holdt: 23 (approx.) Color, Gardner: 9 max. Pounds/Gallon, solution: 8.43-8.53 Pounds/Gallon, solids: 9.1 (approx.) Specific Gravity, 25C/25C: 1.02 (approx.) Acid Value, on solids: 39-43 Solvent: Butoxy Ethanol/see-Butanol(70/30) Typical Performance Data: Performance Properties (Primer Formula-2419-391) (1 mil dry film) Drying Time, Hours--Drawdown: Set: l/2 Through Dry: l-1/2 Dry Hard: 2 Zapon Tackfree Time (Mins.)--Drawdown: 200 gm: 20 Sward Hardness: One Day: 16 Physical Properties: Gloss: Flat Reverse Impact, in-lbs.: 10 Direct Impact, in-lbs.: 20 Resistance Properties: Salt Spray, 250 hrs, CRS: l/16" creep Lift Resistance @ 1,2,16,24,72 and 96 hours: Excellent Humidity (BlOOO), 500 hrs: No blisters Hydrocarbon Resistance (4 hrs.): Excellent Water Immersion (72 hrs.): Excellent

Reichhold Chemicals, Inc.

REICHHOLD

CHEMICALS,

INC.:

KELSOL

3960-B2G-75

Alkyd Resin:

Water Reducible Resin for Air Dry and Low Bake KELSOL 3960-B2G-75 is a water dispersible chain-stopped alkvd desianed to aive a combination of excellent corrosion, humidity and water-resistance. Additional cosolvent beyond what is supplied in KELSOL 3960 is usually required for the best solubiiity and stability. Suggested Uses: - Topcoats and primers for air dry, force dry or bake. - Spray, dip or flowcoat applications. - Blending resin for use with acrylic emulsions. Performance: - Excellent corrosion and humidity resistance. - Excellent early water and water soak resistance. - Excellent exterior durability. Alternative Products: KELSOL 3963 for faster dry. Specifications: Percent Solids, Weight: 74-76 Percent Solids, Volume: 69.4 (approx.) Viscositv B 25C: Stokes:.120-180 Gardner-Holdt: 25+ - Z6+ Color, Gardner: 8 max. Specific Gravity, 25C/25C: 1.03-1.05 Pounds/Gallon, Solution: 8.70 (approx.) Pounds/Gallon, Solids: 9.41 (approx.) Solvent: Butoxy Ethanol/set-Butanol (50/50) Typical Performance Data: Performance Properties (1 mil dry film): White Gloss Enamel (2343-23): Drying Time, hours: Set: 1 Through Dry: 3 Dry Hard: 6 Sward Hardness: One Day: 16 Physical Properties: Gloss (60/20): 92/84 Reverse impact, in.-lbs.: FlO Direct Impact, in.-lbs.: 10 Conical Mandrel, l/8 inch: Pass Pencil Hardness - 7 days: HB Resistance Properties: _ 4 hrs. AD - 4 hrs. H20 spot: Pass 1000 hours water soak: Pass Corrosion Resistance: Ext. Humidity Resistance (500 hrs.): Ext.

345

346

Water-Soluble

Resins

REICHHOLD CHEMICALS,

INC.: KELSOL 3961-B2G-75

Alkyd Resin:

Water Dispersible Resin for Air Dry and Low Bake KELSOL 3961-B2G-75 is a water-dispersible chain-stopped designed to give excellent corrosion resistance in addition to very fast dry rate. It must be neutralized prior to the addition of water and usually requires additional cosolvent for best solubility and stability in water thinned paints. alkyd

Suggested Uses: - Fast air dry or force dry topcoats and primers - Spray, dip and flowcoat applications - Bake systems using melamine resins Performance: - Excellent corrosion resistance - Very fast dry rate - High hydroxyl value for better crosslinking Alternative Products: KELSOL 3960 for best durability in a chain-stopped alkyd with slower dry rate, KELSOL 3907 or KELSOL 3963 for superior humidity reeistance with fast dry. Specifications: Percent Solids, Weight: 74-76 Percent Solids, Volume: 69 approx. Viscosity @ 25C: Stokes: 130-180 Gardner-Holdt: 25+ - 26+ approx. Color. Gardner: 8 max. Pounds/Gallon, Solution: 8.75-8.85 Svecific Gravity, 25Cf25C: 1.06 approx. Pounds/Gallon, Solids: 9.53 approx; Acid Value, on solids: 35-39 Solvent: Butoxy Ethanol/set-Butanol (50/50) Typical Performance Data: Performance Properties (1 mil dry film): White Gloss Enamel: (2103-2): Drying Time, Hours: Set: 0.5 Through Dry: 1.5 Dry Hard: 3.0 Sward Hardness: One Day: 20 Three Days: 24 Seven Days: 34 Physical Properties: -Gloss (60720): 90/84 Reverse Impact, in.-lbs.: FlO Direct Impact, in.-lbs.: 10 Conical Mandrel, l/8": Fail Pencil Hardness @ 7 days: HB-F

Reichhold Chemicals, Inc.

REICHHOLD CHEMICALS,

INC.: KELSOL 3962-B2G-70

347

Alkyd Resin:

Water Dispersible Alkyd Resin KELSOL 3962-B26-70 is a water dispersible chain-stopped alkyd at 70% nonvolatile in an equal blend of butoxy ethanol/sec-butanol. It must be neutralized prior to the addition of water and requires addition of cosolvent for best solubility and paint stability. Suggested Uses: - Air-dry and low bake industrial enamels and primers - Flow coat, spray and dip-tank coatings - Crosslinkable with melamine resins Performance: - Excellent package stability in paints - Hish decree of corrosion resistance - Excellent early adhesion in the first hour - High hydroxyl value for better crosslinking - Excellent hot hardness Alternative Products: KELSOL 3960 for better water and humidity KELSOLS 3907 and 3961 for faster dry rate.

resistance,

Specifications: Percent Solids, Weight: 69-71 Percent Solids, Volume: 65 approx. Viscosity @ 25C: Stokes: 90-130 Gardner-Holdt: 25+ Color, Gardner: 8 max. Pounds/Gallon, solution: 8.59-8.69 Pounds/Gallon, solids: 9.29 approx. Specific Gravity, 25/25C: 1.04 approx. Acid Value, on solids: 33-37 Solvent: Butoxy Ethanol/see-Butanol (SO/SO) Typical Performance Data: Performance Properties (1 mil dry film): White Gloss Enamel (2440-3): Drying Time, Hours: Set: 0.5 Through Dry: 1.5 Dry Hard: 3.0 Sward Hardness: 1 Day: 18 Physical Properties: Gloss (60/20): 93/80 Reverse Impact, in.-lbs.: FlO Direct Impact, in.-lbs.: 10 Conical Mandrel, l/8": Fail Pencil Hardness @ 7 days: HB Salt Spray, 100 days, CRS: l/32"

348

Water-Soluble Resins

REICHHOLD CHEMICALS, Water Dispersible

INC.: KELSOL 3963-B2G-70 Alkyd Resin: Alkyd Resin for Air Dry and Low Bake

KELSOL 3963-B2G-70 is a water-dispersible chain-stopped alkyd designed to give excellent corrosion resistance as well as early water spot resistance. It must be neutralized prior to the addition of water and usually requires additional cosolvent for best solubility and stability in water-thinned paints. Suggested Uses: - Fast air dry or force dry primers and topcoats - Spray, dip and flowcoat applications Performance: - Excellent corrosion resistance - Very fast air dry rate - Excellent humidity and water resistance Alternative Products: KELSOL 3960 for better water soak resistance, for faster dry. Specifications: Percent Solids, Weight: 69-71 Percent Solids, Volume: 64 approx. Viscosity @ 25C: Stokes: 90-130 Gardner-Holdt: 25 - 26 approx. Color-Gardner: 0 max. Pounds/Gallon, Solution: 8.50-8.60 Specific Gravity, 25/25C: 1.03 approx. Pounds/Gallon, Solids: 9.3 approx. Acid Value, on solids: 33-37 (SO/SO) Solvent: Butoxy Ethanol/set-Butanol Typical Performance Data: Performance Properties (1 mil dry film): Gardner Dry Time, Hrs: Set: 1 Through Dry: l-1/2 Dry Hard: 2-l/2 Zapon Tack-free Time: Drawdown (1 dry mil): 2:20 Sward Hardness: One Day: 22 Physical Properties: Gloss (60/20): 92/81 Reverse Impact, in-lbs.: FlO Direct Impact, in-lbs: 10 Conical Mandrel. l/8": Pass Pencil Hardness.@ 7 days: HB Salt Spray, 100 hrs, CRS: l/16" 4-Hour Water Spot (24 hr air dry): OK

KELSOL 3961

Reichhold Chemicals, Inc.

REICHHOLD CHEMICALS, Water Dispersible

349

INC.: KELSOL 3970-G4-75 Alkyd Resin: Silicone Modified Alkyd

KELSOL 3970-G4-75 is a water dispersible, silicone-modified alkyd resin intended for use in air dry and baking maintenance and industrial finishes where outstanding gloss and color retention are required. Laboratory tests indicate that paints made with KELSOL 3970 have the same outstandins exterior durability as those made with conventional, solvent thinned siliconemodifed alkyds. KELSOL 3970 is supplied at 75% solids in butoxy ethanol. Additional cosolvent may-be added to modify reductioncharacteristics. Addition of a volatile amine or ammonia is required before dilution with water. Suggested Uses: - Air dry enamels for outstanding gloss and color retention - Transportation and implement finishes - Exterior siding and signs - Exterior maintanence coatings - Moderately high temperature resistant coatings Alternative Products: KELSOL 3960 is a lower cost, non-silicone dispersible alkyd.

containing water

Specifications: Percent Solids, Weight: 74-76 Percent Solids, Volume: 70.5 approx. Typical Performance Data: KELSOL 3970 White Enamel (2025-24-l): Dry Time, hours: Set: 1.0 Through Dry: 2.75 Dry Hard: 7.5 Sward Hardness: 1 Day: 16 3 Days: 20 7 Days: 30 Direct/Reverse Impact (in-lbs): 40/20 l/8" Conical Mandrel: Pass Pencil Hardness: HB-B Gloss Readings (60/20): 93/92 4 Hours Water Spot (blistering): Sliqht Weatherometer (60/20): Initial: 92/92 1000 Hrs: 83/52 OUV /60/20): Initial; 96/99 Clear Stabilitv (30% in water): 9 davs at 160F Florida Exposuge, 45 South: Initial: 91/83 3 months, UW: 73153 6 months, W: 85/63

350

Water-Soluble Resins

REICHHOLD CHEMICALS,

INC.: KELSOL 3980-G4-75 Alkyd Resin:

Water Dispersible Finishes

Coconut Baking Alkyd for Industrial

KELSOL 3980-G4-75 is a water dispersible coconut oil alkyd resin designed for use in melamine crosslinked finishes. It is supplied at 75% solids in 2-butoxy ethanol. Suggested Uses: - White finishes for light fixtures and other light colored appliances - Durable light colored baking clears - Baking enamels for metal hardware and equipment Performance: - Exhibits excellent color and gloss retention - Provides very good chemical, stain and water resistance - Produces enamels with outstanding application properties - Cure to hard mar resistant films Alternative Products: AROLON 559-G4-70 W.D. acrylic resin and KELSOL 5293-B-75 W.D. oil free polyester. Tentative Specifications: Percent Solids, Weight: 74-76 Percent Solids, Volume: 70 approx. Viscosity @ 25C: Stokes: 120-180 Gardner-Holdt: Z6+ approx. Color, Gardner: 5 max Pounds/Gallon, Solution: 8.93-9.03 Specific Gravity, 25/25C: 1.08 approx. Pounds/Gallon, Solids: 9.60 approx. Acid Value, on solids: 52-58 Solvent: 2-Butoxy Ethanol Typical Performance Data: (Data Obtained on 2166-12~ Revised Formulation) (Resistance Properties: 2 hours exposure) 10% NaOH 10% H2S04 10% Acetic Acid Gasoline Iodine Ketchup Coffee Film Performance: Gloss

(60/20):

Pass Pass Pass Pass Pass Pass Pass

Shoe Polish Merthiolate Oil Lipstick Pepsi Mustard

Baking Schedule 93/80-

Pencil Hardness: F Impact, D/R: 100/60 MEK Rubs: lOO+

Fail Pass Pass Pass Pass Slight Stain

(min./F): 10/275:

Reichhold Chemicals, Inc.

REICHHOLD CHEMICALS,

351

INC.: KELSOL 3990-B2G-70 Alkyd Resin:

Water Dispersible Acrylic Modified Alkyd KELSOL 3990-B2G-70 is a fast drying water dispersible acrvlic-modified alkyd designed to gave early hardness, excellent durability; and good adhesion to plastics. Additional cosolvent is required for the best solubility and stability in paint formulations. Suggested Uses: - Fast-drying primers and topcoats for metals and plastics - Spray, dip, or flowcoat applications Performance: - Very fast dry - Excellent durability - Excellent adhesion to plastics - Good corrosion resistance Alternative Products: KELSOL 3907 and 3961 for fast dry and good durability. AROLON 850 for excellent adhesion to engineering plastics. Tentative Specifications: Percent Solids, Weight: 69-71 Percent Solids, Volume: 66 approx. Viscosity at 25C: Stokes: 60-120 Gardner-Holdt: 24-25 Acid Value, on Solids: 38-42 Gardner Color: 5 max. Specific Gravity, 25/25C: Pounds/Gallon, Solution: 8.40-8.50 Pounds/Gallon, Solids: 9.0 approx. Solvent: Butoxy Ethanol/set-Butanol (SO/SO) Typical Performance Data: Performance Propertes (White Enamel 2470-59, 1 mil dry film): Drying Time, Hours (Drawdown): Set: 0.5 Thru Dry: 1.5 Dry Hard: 2.5 Sward-Hardness: l/3/7 Days: 30/30/32 Phvsical Prowerties: -Gloss (6Oj20): 91/82 Reverse Impact (in-lbs): F10 Direct Impact (in-lbs): 10 Conical Mandrel, l/8": Pass Pencil Hardness @ 7 Days: F Salt Spray, 100 Hrs, CRS: l/16" Rust Creep Adhesion to Plastics: Noryl Excellent Plexiglass Excellent Polycarbonate Excellent a) V052 Excellent

352

Water-Soluble Resins

REICHHOLD CHEMICALS, Resins:

INC.: SPENSOL L Water Reducible Urethane

The SPENSOL L resins are a series of anionic colloidal dispersions of thermoplastic urethane polymers that air dry to form tough, elastomeric, high tensile strength films exhibiting a wide range of flexibility and hardness characteristics. Features: Fast dry-to-handle properties Extraordinary flexibility and impact resistance Outstanding toughness and abrasion resistance Excellent adhesion to heat and solvent sensitive substrates Suitable color for white and light pastel shades Stable to repeated freeze/thaw cycles Fully reacted polyurethane elastomer with no free isocyanate Low solvent content Hydrolytically stable Non-flammable solution Water clean-up Compatible with acrylic emulsions Suggested Uses: - Air dry primers or color coats for interior plastic, rubber, wood, or metal substrates - Coatings for flexible substrates (textiles & leather) - Low bake crosslinked exterior coatings - Spray, dip, brush & flow applied systems - Trade sales sealers, stains & clear finishes for interior wood substrates - Concrete sealers - Flexographic and gravure ink and overprint varnish modifier Applications are found in transportation, textile, building products, sporting goods, graphics and trade sales areas.

Reichhold Chemicals, inc.

REICHHOLD CHEMICALS, INC.: SPENSOL L Water Reducible Resins(Continued): Typical Resin Analysis: Aliphatic: SPENSOL: L51: Percent Solids, Weight: 30 Viscosity @ 25C Stokes: 1.0 Color, Gardner: 2 Specific Gravity 25C/25C: 1.05 Lbs./Gal., Solution: 8.73 Lbs./Gal., Solids: 9.87 pH: 8.5 Solvents: Water/N-Methyl-2-pyrrolidone: L52: Percent Solids, Weight: 30 Viscositv P 25C Stokes: 0.5 Color, Gardner: 3 Specific Gravity 25C/25C: 1.05 L&./Gal., Solution: 8.75 Lbs./Gal., Solids: 10.03 pH: 8.0 Solvents: Water/N-methyl-2-pyrrolidone: L53: Percent Solids, Weight: 30 Viscosity @ 25C Stokes: 0.5 Color, Gardner: 3 Specific Gravity 25C/25C: 1.05 Lbs./Gal., Solution: 8.70 Lbs./Gal., Solids: 9.77 pH: 8.0 Solvents: Water/N-methyl-2-pyrrolidone: L53-40: Percent Solids, Weight: 40 Viscosity @ 25C Stokes: 4 Color, Gardner: 3 Specific Gravity 25C/25C: 1.06 Lbs./Gal., Solution: 8.80 Lbs./Gal., Solids: 9.74 pH: 8.0 Solvents: Water/N-methyl-2-pyrrolidone: L54: Percent Solids, Weight: 32 Viscosity @ 25C Stokes: 20 Color, Gardner: 4 Specific Gravitv 25C/25C: 1.05 Lbs./Gal., Solution:.8.75 Lbs./Gal., Solids: 10.03 pH: 8.5 Solvents: Water/N-methyl-2-pyrrolidone:

76124

80/20

80/20

83117

75125

Urethane

353

354

Water-Soluble Resins

REICHHOLD CHEMICALS, INC.: SPENSOL L Water Reducible Urethane Resins(Continued): Typical Resin Analysis

(Continued):

Aliphatic(Continued) SPENSOL: -L55: Percent Solids, Weight: 35 Viscosity @ 25C Stokes: 2.0 Color, Gardner: 2 Specific Gravity 25C/25C: 1.02 Lbs./Gal., Solution: 8.50 Lbs./Gal., Solids: 9.01 pH: 7.5 Solvents: Water/N-methyl-2-pyrrolidone:

80/20

L56: Percent Solids, Weight: 38 Viscosity @ 25C: 20 Color, Gardner: 3 Specific Gravity 25C/25C: 1.01 Lbs./Gal., Solution: 8.80 Lbs./Gal.. Solids: 9.60 pH: 8.0 . Solvents: Water/N-methyl-2-pyrrolidone:

76/24

Aromatic: L41: Percent Solids, Weight: 32 Viscositv a 25C Stokes: 5 Color, Gardner: 3 Specific Gravity 25C/25C: 1.06 L&./Gal., Solution: 8.85 Lbs./Gal., Solids: 10.17 pH: 9.0 Solvents: Water/N-methyl-2-pyrrolidone:

73/27

L-44: Percent Solids, Weight: 32 Viscositv @ 25C: 3 Color, Gardner: Hazy Specific Gravity 25C/25C: 1.05 Lbs./Gal., Solution: 8.75 Lbs./Gal., Solids: 9.83 pH: 8.0 Solvents: Water/N-methyl-2-pyrrolidone:

85/15

Reichhold Chemicals, inc.

355

REICHHOLD CHEMICALS, INC.: SPENSOL L Water Reducible Urethane Resins(Continued): Typical Clear Film Properties: Aliphatic: L51: Dry Time: Set, minutes (3 mils wet film): 45 Dry Hard: minutes: 210 Sward Hardness @ 24 Hours/72 hours: 52/56 Film Properties: Tensile Strength-psi: 5000 Elongation-Percent: 150 100% Modulus-psi: 4000 Tear Strength, Split-pli: 75 Hardness-Shore D: 60 Taber Abrasion Resistance (mg. loss): 31 Key Characteristics: Hardness, Flexibility, Abrasion Res. L52: Dry Time: Set, minutes (3 mils wet film): 75 Dry Hard: minutes: 270 Sward Hardness @ 24 hours.172 hours: 18/20 Film Properties: Tensile Strength-psi: 7000 Elonuation-Percent: 360 lOO%-Modulus-psi: 1500 Tear Strength, Split-pli: 300 Hardness-Shore D: 35 Taber Abrasion Resistance (mg. loss): 14 Key Characteristics: Flexibility, Low Temp., Impact, Weather L53: Dry Time: Set, minutes (3 mils wet film): 100 Dry Hard: minutes: 330 Sward Hardness @ 24 hours/72 hours: 12/14 Film Properties: Tensile Strength-psi: 5600 Elongation-Percent: 410 100% Modulus-psi: 1100 Tear Strength, Split-pli: 390 Hardness-Shore D: 40 Taber Abrasion Resistance (mg. loss): 11 Key Characteristics: Flexibility, Adhesion, Abrasion Res.

356

Water-Soluble Resins

REICHHOLD CHEMICALS, INC.: SPENSOL L Water Reducible Resins(Continued):

Urethane

Typical Clear Film Properties(Continued): Aliphatic: SPENSOL: _IL53-40: Dry Time: Set, minutes (3 mils wet film): 25 Dry Hard: minutes: 110 Sward Hardness @ 24 hours.172 hours: 12/16 Film Properties: Tensile Strength-psi: 5800 Eloncation-Percent: 400 lOO%-Modulus-psi: 1000 Tear Strength, Split-pli: 320 Hardness-Shore Di 38 _ Key Characteristics: Flexibility, Abrasion Res., Higher Solids L54: Dry Time: Set, minutes (3 mils wet film): 100 Dry Hard: minutes: 330 Sward Hardness @ 24 hours/72 hours: 12/16 Film Properties: Tensile Strensth-nsi: 7000 Elongation-Percent: 300 100% Modulus-psi: 3000 Tear Strength, Split-pli: 130 Hardness-Shore D: 55 Taber Abrasion Resistance (mg. loss): 30 Key Characteristics: Flexibility, Viscosity Control ifier), Compatibility L55: Dry Time: Set, minutes (3 mils wet film): 30 Dry Hard: minutes: 75 Sward Hardness @ 24 hours/72 hours: 8/8 Film Properties: Tensile Strength-psi: 6200 Elonsation-Percent: 660 lOO%-Modulus-psi: 500 Tear Strenqth, Split-pli: 180 Hardness-Shore Di 36 _ Key Characteristics: Flexibility, Wet Rub, Cold Flex

(mod-

Reichhold Chemicals, Inc.

REICHHOLD CHEMICALS, INC.: SPENSOL L Water Reducible Resins(Continued):

Urethane

Typical Clear Film Properties(Continued): Aliphatic: L56: Dry Time: Set, minutes (3 mils wet film): 90 Dry Hard: minutes: 330 Sward Hardness @ 24 hours/J2 hours: 8/10 Film Properties: Tensile Strength-psi: 5200 Elongation-Percent: JO0 100% Modulus-psi: 350 Tear Strength, Split-pli: 125 Hardness-Shore D: 60 Key Characteristics: Flexibility, Higher Solids Aromatic: L41: Dry Time: Set, minutes (3 mils wet film): 135 Dry Hard: minutes: 420 Sward Hardness @ 24 hours/J2 hours: 26/38 Film Properties: Tensile Strength-psi: 7500 Elongation-Percent: 280 100% Modulus-psi: 3100 Tear Strength, Split-pli: 200 Hardness-Shore D: 58 Taber Abrasion Resistance (mg. loss): J Key Characteristics: Hardness, Flexibility, Abrasion Res. L44: Dry Time: Set, minutes (3 mils wet film): 45 Dry Hard: minutes: 115 Sward Hardness @ 24 hours/72 hours: 24/26 Film Properties: Tensile Strength-psi: 6300 Elongation-Percent: 360 100% Modulus-psi: 2400 Tear Strength, Split-pli: 210 Hardness-Shore D: 50 Taber Abrasion Resistance (mg. loss): 35 Key Characteristics: Flexibility, Low Cost

357

358 Water-Soluble

Resins

SARTCIWRR CO.: SARTOMRR Water Dispersible

Monomers:

344:

Polyethylene Glycol (400) Diacrylate Clear Liquid Reactive Esters %: 99+ Odor: Mild Color APHA: 100 Molecular Weight: 508 Specific Gravity @ 25C: 1.1134 Viscosity @ 25C cps: 56-65 Inhibitor HQ ppm: 500+-100 MEHQ Water @ 25C Solubility (g/l00 g H20): (5 >75 Water @ 25C Dispersability (g/100 g H20): 5-75 361

:

Diethylamino-ethyl Acrylate Clear Yellow Liquid Reactive Esters %: 99+ Odor: Fishv Color APHA- 100 Molecular Weight: 171 Specific Gravity @ 25C: 0.9250 Viscosity @ 25C cps: l-10 Inhibitor HQ ppm: 25+-10 MEHQ Water @ 25C Solubility (g/l00 g H20): 0.1 Water @ 25C Dispersability (g/l00 g H20): 0.5 604: Polypropylene Glycol Monomethacrylate Appearance: Clear Liquid Reactive Esters %: 99 Odor: Mild Color APHA: 50 Molecular Weight: 350-387 Snecific Gravitv @ 25C: 1.0100 Viscosity @ 25C!-cps: lo-20 Inhibitor HQ ppm: 900+-100 MEHQ Water @ 25C Solubility (g/lOOg H20): 0.1 Water @ 25C Dispersability (g/lOOg H20): 0.5 607:

Polypropylene Glycol Monacrylate Clear Liquid Reactive Esters %: 99 Odor: Mild Color APHA: 50 Molecular Weisht: 335-372 Specific Gravity @ 25C: 1.0284 Viscosity @ 25C cps: 50-60 Inhibitor HQ ppm: 900+-100 MEHQ Water @ 25C Solubility (g/lOOg H20): 0.1 Water @ 25C Dispersability (g/lOOg H20): 0.5

Sartomer Co.

SARTOMBR CO.: SARTOMBR Water Dispersible

Monomers(Continued):

676: Butanediol Monoacrylate Clear Liquid Reactive Esters %: 98 Odor: Virtually Odorless Color APHA: 150 Molecular Weight: 144 Specific Gravity @ 25C: 1.0390 Viscosity @ 25C cps: IO-15 Inhibitor HQ ppm: 300+-50 MEHQ Water 8 25C Solubility (g/lOOg H20): Soluble Water 8 25C Dispersability (g/lOOg H20): 681: Vinyl Caprolactam Yellow Solid Reactive Esters %: 98 Odor: Mild Color APHA: 250 Molecular Weight: 139 Specific Gravity @ 25C: 1.0100 Viscosity @ 25C cps: N/A Inhibitor HQ ppm: 10 Kerobit BPD Water @ 25C Solubility (g/lOOg H20): 4 9035:

Highly Alkoxylated Triacrylate Clear Liquid Reactive Esters %: 99+ Odor: Mild Color APHA: 100 Molecular Weisht: 1000 Specific Gravity 8 25C: 1.1490 Viscosity 8 25C cps: 150-250 Inhibitor HQ ppm: 500+-200 MEHQ Water @ 25C Solubility (g/lOOg H20): (5 >75 Water 8 25C Dispersability (g/lOOg H20): 5-75

359

360

Water-Soluble

Resins

SARTOMRR CO.: SARTOMER Water Dispersible

Monomers(Continued):

344: Monomer Features: * Difunctional * Produces Soft, Flexible Films Applications: * Flexible Coatings * Overprint Varnishes * Offset Inks * "No Wax" Vinyl Tile Coatings * Dental Compounds 361:

Monomer Features: * Monofunctional * Wet Adhesion Promoter * Contains an Amino Group, a Source for Cationic Charge Density Applications: * Dye Additives * Coatings * Resists * Photopolymers 604:

Monomer Features: * Monofunctional Applications: * Coatings * Emulsion Polymers * Photoresists * Photopolymer Printing Plates 607

:

Monomer Features: * Monofunctional Awlications: *-Coatings * Emulsion Polymers * Photoresists * Photopolymer Printing Plates

Sartomer

SARTOMER CO.: SARTOMER Water Dispersible

Co.

Monomers(Continued):

676: Monomer Features: * Monofunctional * Contains a Reactive Hydroxyl Moiety Applications: * Urethane Prepolymers * Acrylamide Cationic Polymers * Wet Strength Paper Additives * Homopolymers used in Electrophotographic Resins * Copolymers and Homopolymers for Water Treatment and Mineral Processing * Aqueous Automotive OEM Finishes * Wood Topcoats * Vinyl Tile Coatings * Textile Backcoatings * Aqueous Dispersions for Coil Coatings and Wood Products * Flat Board Topcoatings 681: Monomer Features: * Excellent Reactive Diluent * Fast Cure Response * Can Undergo Cationic Cure Mechanisms * Contains Polar Captam Group Applications: * Lubricating Oil Additives * Homopolymer for Potential use in Water Soluble Coatings * Vinyl CaprolactamfVinyl Acetate Copolymers 9035:

Monomer Features: * Highly Water Soluble * Trifunctional Annlications: *‘Photoresists * Photopolymer Printing Plates * Emulsion-Polymers * Aqueous Thickeners

361

362

Water-Soluble

Resins

STANCHEM INC.: Polymers and Polymeric

Specialties:

Paints and Building Products Polymers: 5011:

Vehicle base for interior in high PVC range. Excellent svstems. Polyvinyl acetate-acrylic Viscosity (cps): 800-1400 Solids % (min.): 54.5 Average Particle Size, M: Ta. C: 9 pi'@ 25C: 2-4 Weight lb/gal: 9.0 Ionic Charge: Nonionic

and exterior paints, especially compatibility with tinting

-z

copolymer 0.2-0.4

6035: Excellent scrubbability, freeze-thaw resistance, leveling properties. Outstanding exterior durability and long term tint retention. Acrylic copolymer Viscosity (cps): 500-1000 Solids % (min.): 46 Average Particle Size, M: 0.05-0.1 Tg, C: 8 pH @ 25C: 9-10 Weight lb/gal: 8.6 Ionic Charge: Nonionic 6064: Emulsion for exterior paints with good adhesion to chalky surfaces. Acrvlic covolvmer Viscosity icpS): 300-1000 Solids % (min.): 60 Average Particle Size, M: 0.2-1.0 Tg, C: 2 pH @ 25C: 9.0-9.5 Weight lb/gal: 8.9 Ionic Charge: Anionic 6088:

Excellent leveling and high film build properties, for use in formulating one coat systems. Resists dirt pick up. Acrylic copolymer Viscosity (cvs): 1500-2500 Solids %-(min.): 49.5 Average Particle Size, M: 0.2-1.0 Ta. C: 8 pi'@ 25C: 9-10 Weight lb/gal: 8.7 Ionic Charge: Anionic

StanChem,

Inc.

STANCHEM INC.: Polymers and Polymeric Specialties(Continued): Paints and Building Products Polymers(Continued): 7013: Superior hardener with chemical resistance discoloration at high temperatures. Acrylic polymer solution Viscosity (cps): 1200-2500 Solids % (min.): 39 Tg, C: 105 Weight lb/gal: 8.0 Ionic Charge: MEK system

properties.

No

Paper and Paperboard Coatings: 5071: Superior pigment binder. Excellent chemical and mechanical stability. Polyvinyl acetate homopolymer Viscositv Icus 1: 100 Solids %-(min.i: 49.5 Averaqe Particle Size, M: 0.15-0.25 TU.

CI

34

pii.@ 25C: 6.3-7.3 Weight lb/gal: 8.6 Ionic Charge: Anionic 5086:

Fine particle size pigment binder with superior binding ability. Excellent pit resistance. Polyvinyl acetate homopolymer Viscosity (cps): (200 Solids % (min.): 49.5 Average Particle Size, M: 0.1-0.25 Tg, c: 33 pH 8 25C: 6.5-7.5 Weight lb/gal: 8.7 Ionic Charge: Essentially nonionic 6026:

Excellent binder for paper products. Acrylic solution Viscosity (cps): 750-900 Solids % (min.): 29.5 Tg, C: 105 Weight lb/gal: 8.5 Ionic Charge: Solvent system

Superior wet strength.

363

364

Water-Soluble

Resins

STANCHEM INC.: Polymers and Polymeric

Specialties(Continued):

Paper and Paperboard Coatings(Continued1: 7071: Finish coat for high gloss with good printability. drying clear solution. Water-soluble acrylic solution Viscosity (cps): (500 Solids % (min.): 19 Tg, C: 10 pH @ 25C: 7.5-8.0 Weight lb/gal: 8.4 Ionic Charge: Nonionic

Quick

Textiles: 6008: Superior dry cleaning and laundering wear for nonwovens and fabrics. Outstanding non-yellowing resistance. Crosslinking soft acrylic Viscosity (cps): 300-700 solids % (min.): 45 Average Particle Size, M: 0.05-0.1 Tg, C: 7 pH @ 25C: 2.8-3.2 Weight lb/gal: 8.9 Ionic Charge: Essentially nonionic 6016:

Excellent stiffener for high loft nonwovens loft characteristics without imparting tack. Crosslinking hard acrylic Viscosity (cps): 50-300 Solids % (min.): 46 Average Particle Size, M: 0.05-0.1 Tg, c: 40 pH @ 25C: 5.0-6.0 Weight lb/gal: 8.9 Ionic Charge: Nonionic

to maintain

6026:

Imparts soft hand to fabrics and nonwovens. ance to dry cleaning and laundering. Crosslinking soft acrylic Viscosity (cps): (200 Solids % (min.): 45 Average Particle Size, M: 0.05-0.1 Tg, C: -20 pH @ 25C: 6.0-6.5 Weight lb/gal: 8.7 Ionic Charge: Anionic

Excellent

resist-

StanChem, Inc.

STANCHEM INC.: Polymers and Polymeric

365

Specialties(Continued):

Textiles(Continued): 6074: Excellent finishing properties, color stabil ity, res istance to laundering and dry cleaning. Good binder for natural fibers. Selfcrosslinking acrylic Viscosity (cps): 50 Solids % (min.): 45 Average Particle Size, M: 0.1-1.0 Tc. C: 19 PI-I.@25C: 3-5 Weight lb/gal: 8.8 Ionic Charge: Anionic Caulks and Sealants: 5009: Wide compatibility with modifiers and high solvent tolerance for general purpose adhesive compounding. A higher viscosity version is available. Polyvinyl acetate homopolymer Viscosity (cps): 850-1000 Solids % (min.): 54.5 Average Particle Size, M: l-3 Tg, C: 38 pH @ 25C: 4.0-5-O Weight lb/gal: 9.1 Ionic Charge: Nonionic 5019: Good water resistance and high electrolyte tolerance for use in adhesives, joint cements and textile sizing. Polyvinyl acetate homopolymer Viscosity (cps): 1000-1600 Solids % (min.): 54.5 Average Particle Size, M: 0.5-1.0 Tg, C: 36 pH @ 25C: 4.0-5.0 Weight lb/gal: 9.0 Ionic Charge: Nonionic 6050: High pigment tolerance and excellent and ultraviolet light. Acrylic copolymer Viscosity (cps): (300 Solids % (min.): 54.5 Average Particle Size, M: 0.2-1.5 Tg, C: -4 pH @ 25C: 4.2-4.8 Weight lb/gal: 8.8 Ionic Charge: Anionic

resistance

to water

366

Water-Soluble Resins

STANCHEM INC.: Polymers and Polymeric

Specialties(Continued):

Adhesives and Binders: 5016: Excellent quick tack, highly branched adhesive. Available a lower viscositv arade. Polyvinyl acetate homopolymer Viscosity (cp.5): 1500-1700 Solids %-(min.): 54.5 Average Particle Size, M: 1-3 To, C: 38 pi.@ 25C: 4.0-5.0 Weight lb/gal: 9.1 Ionic Charge: Nonionic

in

6053: Pressure sensitive with good adhesion, water resistance and mechanical stability. Excellent for instant grab applications. Acrylic copolymer Viscositv (cus): 500-1500 Solids %-(I&. j: 51 Average Particle Size, M: 0.2-1.0 Tg, Cl -50 pH 8 25C: 4.0-5.0 Weight lb/gal: 9.1 Ionic Charge: Nonionic 6116: Copolymer designed for pressure sensitive adhesives. Combines good peel strength, creep resistance and hot tensile strength. Acrylic copolymer Viscosity (cps): 50-175 Solids % (min.): 53 Average Particle Size, M: 0.1-0.5 Tg, CI -40 pH @ 25C: 7.2-8.2 Weight lb/gal: 8.6 Ionic Charge: Anionic 8000: General purpose adhesive. Dries clear with strong bonding for porous substrates such as wood. Compounded polyvinyl acetate Viscosity (cps): 2500-4000 Solids % (min.): 50 Average Particle Size, M: l-3 Tc. C: 15 pi?-@ 25C: 4.0-5.0 Weight lb/gal: 8.9 Ionic Charge: Nonionic

StanChem.

STANCHEM

Inc.

INC.: Polymers and Polymeric Specialties(Continued):

Thickeners and Additives: 6006: Effective "in situ" thickener for a variety of emulsion systems. Can be used as pigment dispersant. Acrylic copolymer Viscosity (cps): (50 solids % (min.): 27.5 Average Particle Size, M: 0.05-0.1 Tg, c: 14 pH @ 25C: 3.0-4.0 Weight lb/gal: 0.7 Ionic Charge: Anionic 6070:

Superior additive for water-base thickening applications. Acrylic emulsion with good mechanical shear resistance. Acrylic copolymer Viscosity (cps): cl00 solids % (min.): 29.5 Average Particle Size, M: 0.05-0.1 Tg, C: 14 pH @ 25C: 2.0-3.5 Weight lb/gal: 8.7 Ionic Charge: Anionic

367

368

Water-Soluble

Resins

STANCHEM INC.: Polymers and Polymeric

Specialties(Continued):

STANCHEM 5179: STANCHEM 5179 is a poly-vinyl acetate homopolymer designed as a specialty binder for use in the non-wovens industry. STANCHEM 5179 also exhibits good water resistance and high wet strength. Typical Physical Properties: Type: Poly-vinyl acetate Solids by weight: 54.5-55.5% Viscosity @ 25C: ~2,000 cps pH @ 25C: 4.5-5.5 Free monomer: <0.3% maximum Particle size: (2.0 microns Weight/gallon: 9.1+-0.01 lbs./gal. Tg: 3oc STANCHEM 6015: STANCHEM 6015 is an acrylic copolymer latex which dries to a flexible clear film with excellent properties as a general purpose binder. Recommended as a high quality acrvlic binder for wismented paper coatings, the superior pe;formance characteristi& and versatility of SC 6015 include: high ink receptivity, blister resistance; and improved wet rub resistance, along with good hiding and varnish holdout. SC 6015 also exhibits excellent bonding strength and mechanical stability as well as resistance to heat and light aging. STANCHEM 6015 is also recommended for use as a binder in nonwoven applications due to its excellent adhesion to natural and synthetic fibers or blends. Tvwical Phvsical Prowerties: __ Type: Soft Acrylic Solids by weiqht: 45.5-46.5% Viscosity @ 25C: less than 200 pH @ 25C: 6.2-6.8 Free monomer: less than 0.3% Weight/gallon: 8.8 lbs./gal. Tg: -3c Ionic Charge: Nonionic

cps

StanChem, Inc.

STANCHEM INC.: Polymers and Polymeric

369

Specialties(Continued1:

STANCHEM 6085: STANCHEM 6085 is a very hard acrylic polymer that is used as a modifier for softer acrylic polymers to impart increased hardness and improved blocking resistance. Blends of SC 6085 and softer acrylics are used in many genera industrial applications including coatings for wall coverings and flooring products. Films cast from straight SC 6085 are discontinuous if cured at room temperature. Curing at elevated temperatures will yield a hard, brittle film. Plasticizer can be incorporated in the latex to improve film formation, however, blends of SC 6085 with softer acrylic latices are a more common application of this polymer. Typical Physical Properties: Type: Extremely hard acrylic - non-film forming Solids by weight: 37.5-38.5% Viscosity 8 25C: less than 200 cps pH @ 25C: 9.6-10.0 Free monomer: >0.2% Weight/gallon: 8.7 lbs./gal. Tg: 85C Ionic Charge: Anionic STANCHEM 6201: STANCHEM 6201 is a crosslinking acrylic polymer which is useful in a variety of textile and nonwoven applications. SC 6201 imparts laundering and dry cleaning durability, excellent tear strength and crease recovery, as well as improved pilling resistance. STANCHEM 6201 forms a hard, clear film which is highly resistant to UV discoloration. SC 6201 can be used to impart moderate stiffness of hand to all types of textiles and nonwovens. It is recommended for use in fabric finishing, as an adhesive in laminating, and for bonding nonwovens. Typical Physical Properties: Type: Crosslinking acrylic Solids by weight: 45-46% Viscosity @ 25C: less than 250 cps pH @ 25C: 3-4 Free monomer: less than 0.2% Weight/gallon: 8.8 lbs./gal. Tg: 40C Ionic Charge: Non-ionic

370

Water-Soluble Resins

STANCHEM INC.: Polymers and Polymeric

Specialties(Continued):

STANCHEM 6291: STANCHEM 6291 is a 100% acrylic copolymer emulsion designed for use in cementitous compositions. The addition of STANCHEM 6291 to cementitious compositions imparts increased flexibility, excellent weatherability and superior corrosion and water resistance. Advantages: - Excellent weatherability - Superior corrosion and water resistance - Increased flexibility - Odorless - Non-flammable - Solvent-free Typical Physical Properties: Type: 100% Acrylic copolymer emulsion Appearance: white liquid Solids by weight: 47-48% Viscosity @ 25C: 250 cps+-100 pH: 9.5-10.0 Ta: 12 c. Particle Size: 0.05-0.1 micron Weight/gallon: 8.8+-0.01 lbs./gal. Emulsifier Type: Nonionic

Thibaut

and

Walker

371

THIBAUT & WALKER: Vinyl Acrylic Copolymer Emulsion: pARc0: 58-C-55: NV:

55

Viscosity, cps: 1000-3000 pH: 4-5 Lbs./Gal. Wet: 8.80 Gals./Lb. Dry: .I08 Mechanical Stability: Exe % Free Monomer: ~0.5% Clarity: Exe Tg: 9C Gloss: High Interior wall paints, gloss and semi-gloss exterior house paints, and masonry paints. 69-C-55:

NV: 55 Viscosity, cps: 500-1500 pH: 4-5 Lbs./Gal. Wet: 8.80 Gals-/Lb. Dry: .I08 Mechanical Stability: Exe % Free Monomer: <0.5% Clarity: Exe Tg: 9C Gloss: High Excellent scrub and stain resistance and enamel hold-out interior paints. For interior-exterior gloss and semi-gloss house paints and masonry paints. 71 -C-60:

NV: 60 Viscosity, cps: 1500-4000 pH: 4-5 Lbs./Gal. Wet: 9.07 Gals./Lb. Dry: .104 Mechanical Stability: Exe % Free Monomer: t0.5% Clarity: Exe Tg: OC High tack adhesion binder for construction

adhesives.

in

372

Water-Soluble Resins

THIBAUT & WALKER: Vinyl Acrylic Copolymer Emulsion(Continued): PAHCO(Continued): 72-C-60: % NV: 60 Viscosity, cps: 1500-4000 pH: 4-5 Lbs./Gal. Wet: 9.15 Gals./Lb. Dry: -102 Mechanical Stability: Exe % Free Monomer: ~0.5% Clarity: Exe Tg: 9C Gloss: High Interior-exterior high gloss house paints with wide formulating latitude. 75-c-55: % NV: 55 Viscosity, cps: 1000-3000 pH: 4-5 Lbs./Gal. Wet: 8.80 Gals;/Lb. Dry: .108 Mechanical Stability: Exe % Free Monomer: (0.5% Clarity: Exe Gloss: High An economy product for use in flat and semi-gloss house and masonry paints. SWA-555: % NV: 55 Viscosity, cps: ZOO-2000 pH: 4-5 Lbs./Gal. Wet: 8.90 Gals-/Lb. Dry: -107 Mechanical Stability: Exe % Free Monomer: (0.5% Clarity: Exe Tg: 8C Gloss: High Interior-exterior high gloss paints with performance equal to acrylics at much reduced cost. The wet adhesion exceed those obtained with acrylics.

Thibau t and Walker

373

THIBAUT & WALKER: Water Reducible Resins: SUPER ALKYD Alkyds: 900-75: NV: 75 Solvent: PGMBE Viscosity (G-H): 22-24 Reduced Vise.: Y-Z Vise. % NV Reducer: 60 Water Acid Value (Solids) (Max.): 45-55 Color (Max.): 8 Type Oil: Mixed Average Wt./Gal.: 8.90 Water reducible medium-short oil alkyd for air, forced air, and baking applications. 901-75: NV: 75 Solvent: PGMBE/sec-Butanol Viscosity (G-H): 23-25 Reduced Vise.: Z-Z1 Vise. % NV Reducer: 60 Water Acid Value (Solids) (Max.): 45-55 Color (Max.): 8 Type Oil: Mixed Average Wt./Gal.: 8.90 Water reducible medium alkyd for air, forced air and bake applications with good gloss and moisture resistance. 902-75:

NV: 75 Solvent: PGMBE Viscosity (G-H): 23-25 Acid Value (Solids) (Max.): 50-60 Color (Max.): 8 Type Oil: Soya Average Wt./Gal.: 8.80 Water reducible air dry alkyd for early moisture

resistance.

374

Water-Soluble Resins

THIBAUT & WALKER: Water Reducible Resins(Continued): SUPER POLYESTER Oil Free Polyesters: 950-75: NV: 75 Solvent: PGMBE Viscosity (G-H): 24-26 Acid Value (Solids) (Max.): 45-55 Color (Max.): 5 Average Wt./Gal.: 9.10 General purpose, water reducible oil-free polyester industrial baking coatings.

for

960-75:

NV: 75 Solvent: PGMBE Viscosity (G-H): 24-26 Acid Value (Solids) (Max.): 50-60 Color (Max.): 5 Average Wt./Gal.: 9.20 A high performance water reducible polyester that offers excellent color and gloss retention, outstanding weatherability and exceptional hardness and impact resistance. T&W 950-75 is recommended for coatings requiring excellent exterior durability.

Thibaut

and

Walker

THIBAUT & WALKER: Water Reducible Resins(Continued): SUPER THANE Oil Modified Urethanes: 975-70: NV: 70 Solvent: PGMBE/sec-Butanol Viscosity (G-H): 24-26 Acid Value (Solids) (Max.): SO-60 Color (Max.): 7 Type Oil: TOFA Average Wt./Gal.: 8.70 Water reducible oil modified urethane varnish applications. 980-70: NV:

70

Solvent: PGMBE/sec-Butanol Viscosity (G-H): 24-26 Acid Value (Solids) (Max.): 50-60 Color (Max.): 7 Type Oil: SOYA Average Wt./Gal.: 8.70 Soya version of T & W 975-70.

for general purpose

375

376

Water-Soluble

Resins

THIBAUT & WALKER: 100% Acrylic Emulsions: PARCRYL: 200: NV: 46.5 Viscosity, cps: SO-500 pH: 9-10 Lbs./Gal. Wet: 8.80 Gals./Lb. Dry: -107 Mechanical Stability: Exe Stability @ 100 Hrs; 140F: OK Wet Adhesion: Exe Water Resist.: Exe Tg: 1C Gloss: High Interior house paints and masonry paints. 250:

NV: 46.5 Viscosity, cps.: 50-500 pH: 9-10 Lbs./Gal. Wet: 8.80 Gals./Lb. Dry: .107 Mechanical Stability: Exe Stability @ 100 Hrs. 140F: OK Wet Adhesion: Exe Water Resist.: Exe Tg: 1C Gloss: High Caulking compounds and masonry paints. 300:

NV: 46.5 Viscosity, cps.: SO-500 pH: 9-10 Lbs./Gal. Wet: 8.80 Gals./Lb. Dry: .107 Mechanical Stability: Exe Stability @ 100 Hrs: 140F: OK Wet Adhesion: Exe Water Resist.: Exe Tg: 1C Gloss: High Interior and exterior house paints and masonry paints. Suitable for roof and tennis court coatings.

Thibaut and Walker

377

THIBAUT & WALKER: 100% Acrylic Emulsions(Continued): PARCRyL(Continued): 311: NV: 46.5 Viscosity, cps: 50-500 pH: 9-10 Lbs./Gal. Wet: 8.80 Gals./Lb. Dry: -107 Mechanical Stability: Exe Stability @ 100 Hrs. 140F: OK Wet Adhesion: Exe Water Resist.: Exe Tg: -22c Gloss: High Extremely flexible polymer for high pigment loading. Suitable for roof and tennis court coatings. 357:

NV: 60 Viscosity, cps: 100-1000 pH: 8.5-9 Lbs./Gal. Wet: 8.80 Gals-/Lb. Drv: .107 Mechanical Stability: OK Stability @ 100 Hrs. 140F: OK Wet Adhesion: Exe Water Resist.: Exe Tg: 7C A fast drying vehicle for water-borne excellent weather resistance.

traffic paints with

4001: NV: 50 Viscosity, cps: 750-1800 pH: 8.5-9.5 Lbs./Gal. Wet: 8.80 Gals./Lb. Dry: -107 Mechanical Stability: Exe Stability @ 100 Hrs. 140F: OK Wet Adhesion: Exe Water Resist. Exe Tg: 2C Gloss: High Interior and exterior house paints. Interior and exterior.

378

Water-Soluble Resins

THIBAUT

& WALKER:

100%

Acrylic Emulsions(Continued):

RARCRyL(Continued): 4501: NV: 46.5 Viscosity, cps: 300-1800 DH: 8.5-9.5 Lbs./Gal. Wet: 8.80 Gals./Lb. Dry: .107 Mechanical Stability: Exe Stability @ 100 Hrs. 140F: OK Wet Adhesion: Exe Water Resist.: Exe Tg: 9C Gloss: High A versatile polymer for use in quality interior and exterior gloss house paints. 5001: NV: 46.5 Viscosity, cps: 300-1800 pH: 8.5-9.5 Lbs./Gal. Wet: 8.80 Gals./Lb. Dry: .107 Mechanical Stability: Exe Stability @ 100 Hrs. 140F: OK Wet Adhesion: Exe Water Resist.: Exe Tg: 9C Gloss: High Exterior gloss paints where color retention 870: NV: 55 Viscosity, cps: 1000-2500 pH: 5.5-6.5 Lbs./Gal. Wet: 8.80 Gals./Lb. Dry: .107 Mechanical Stability: OK Stability @ 100 Hrs. 140F: OK Water Resist.: Exe Tg: -8C Water-based caulking compounds.

is important.

Thibaut and Walker

379

THIBAUT 1 WALKER: 100% Acrylic Emulsions(Continued): PARCRYL(Continued): 900: NV: 43 Viscosity, cps: 100-600 pH: 9-10 Lbs./Gal. Wet: 8.80 Gals-/Lb. Dry: .I07 Mechanical Stability: Exe Stability @ 100 Hrs. 140F: OK Wet Adhesion: Exe Water Resist.: Exe Tu: 3C Gioss: NA Flash rust and rust-resistant metal primers and stain-resistant wood primers.

380

Water-Soluble Resins

TIC GUMS, INC.: NUTRILOID Soluble Dietary Fibers: Vegetable gums typically have soluble dietary fiber contents averaging 75% to 80%. NUTRILOI& Arabic: Crude Fiber: 0.1% Soluble Fiber: 94.2% Guar: Crude Fiber: 1.0% Soluble Fiber: 91.8% Locust bean: Crude Fiber: 0.5% Soluble Fiber: 90.3% Tragacanth: Crude Fiber: 1.0% Soluble Fiber: 91.2% Agar: Crude Fiber: 0.1% Soluble Fiber: 85.0% Carrageenan: Crude Fiber: 0.1% Soluble Fiber: 78.0% Alginate: Crude Fiber: 0.1% Soluble Fiber: 80.0% Xanthan: Crude Fiber: 0.1% Soluble Fiber: 85.0% Cellulose: Crude Fiber: 0.3% Soluble Fiber: 88.0% Functional Properties of NUTRILOID Products: The primary function of all NUTRILOID products is to thicken water. Additional benefits include forming gels with water or with protein solutions. The water thickening properties of NUTRILOIDS varies widely. In addition, there are subtle differences in rheology (flow) of solutions with similar viscosities. Gel-forming NUTRILOID products also exhibit differences in gel strength and texture.

TIC Gums, Inc.

TIC GUMS, INC.: NUTRILOID

381

Soluble Dietary Fibers(Continued):

NUTRILOID Arabic: Cold water soluble, yielding virtually no water viscositv, and taste-neutral, NUTRILOID Arabic is ideal for increasing-. fiber level in an existing product. NUTRILOID Guar: Several grades of NUTRILOID Guar, from low to high viscosity, are available in various granulations. All NUTRILOID Guars are cold water soluble and used as thickeners. A special low viscosity NUTRILOID Guar allows higher usage levels. NUTRILOID Locust: Similar to NUTRILOID Guar, except NUTRILOID Locust requires heating to 180F to hydrate and is ideal for products where initial viscosity must be low and heat is applied later. Unlike NUTRILOID Guar; NUTRILOID Locust is synergistic with NUTRILOID Xanthan and most NUTRILOID Carrageenans, forming gels of increased strength. NUTRILOID Xanthan: NUTRILOID Xanthan is extremely thixotropic and stable over wide pH and temperature ranges. Its viscosity contribution is lower than for NUTRILOID Guar or NUTRILOID Locust. NUTRILOID Agar & Carrageenans: NUTRILOID Agar and Carrageenan gelling ability.

offer wide variations

in

NUTRILOID Cellulose Gums: NUTRILOID Cellulose Gums offer a wide range of water viscosities from 10 cps to 4,000 cps, making them ideal for addition of fiber to specific formulations. NUTRILOID TICALOIDS: NUTRILOID TICALOIDS are blends of the various gums combined to achieve specific functional characteristics and process requirements.

382

Water-Soluble Resins

TIC GUMS, INC.: TIC Guar Gum: Solubility: Guar Gum is cold water soluble, with the rate of solution Guak Gum has a tendency to form dependent upon particle size. clumps unless properly dispersed. Viscosity: The cost efficient water-binding excels other hydrocolloids.

ability of Guar Gum far

Rheology: Rheology of Guar Gum solutions is dependent

upon concentration.

Temperature: Viscosity of Guar Gum solutions vary inversely with temperature, and are reversible. Type --of Guar Gum: SCM: Viscosity (1% solution): 3000 cps. min. Mesh (on a USS #lOO): 60% min. a/2oc: Viscosity (1% solution): 3000 cps. min. Mesh (on a USS #lOO): 4% max. a/22: Viscosity (1% Solution): 3800 cps. min. Mesh (on a USS #lOO): 4% max. 8/22A: Viscosity (1% Solution): 3000 cps. min. Mesh (on a USS #lOO): 15% max. 8/24: Viscosity (1% Solution): 4000 cps. min. Mesh (on a USS #lOO): 5% max. TICOLV: Viscosity (1% Solution): 350 cps. min. Mesh (on a USS #lOO): 80% min. NUTRILOID: Viscosity (1% Solution): 3000 cps. min. Mesh (on a USS #lOO): 15% max. Applications: Food Paper Textile

Soluble Fiber Explosives Mining

TICGums.Inc. 383

TIC GUMS, INC.: TICALOSE Cellulose Gum: TICALOSE is a line of sodium carboxymethyl cellulose polymers commonlv referred to as CMC. especiallv for Pharmaceutical and Food quality applications. In addition to the many standard grades available, TIC has formulated a wide range of specialty grades for specific applications. Classification

of Grades:

Particle Size: (G) Granular: 16 mesh (C) Coarse: 40 mesh (S) Standard: 80 mesh (F) Fine: 120 mesh Low Viscosity Grades: TICALOSE 15: Particle Size: C,S,F Viscosity: 1%: lo-15 2%: 25-50 TICALOSE 30: Particle Size: C,S,F Viscosity: 1%: 20-30 2%: 100-150 These low viscosity grades are extremely useful in applications where high solids levels are required, or where other properties, such as encapsulation, or film forming, are desirable, but viscosity development is not. Typical uses: Carbonated Beverages/Fruit Drinks/Vitamins/ Icings Medium Viscosity Grades: TICALOSE 75: Particle Size: C,S,F Viscosity: 1%: 40-75 2%: 400-600 TICALOSE 100: Particle Size: C,S,F Viscosity: 1%: 70-110 2%: 800-1200 These medium viscosity grades are used in applications where some viscosity development is desired along with the other functional qualities provided with CMC. Typical uses: Table Syrups/Icings/Acidified Milk/Frozen Juices

384

Water-Soluble Resins

TIC Gums, Inc.: TICALOSE Cellulose Gum(Continued): High Viscosity Grades: TICALOSE 750: Particle Size: C,S,F Viscosity 1%: 550-750 TICALOSE 1200: Particle Size: C,S,F Viscosity 1%: 800-1200 TICALOSE 2500: Particle Size: C,S,F Viscosity 1%: 1500-2500 TICALOSE 4000: Particle Size: G Viscosity 1%: 2500-4000 TICALOSE 4500: Particle Size: C,S,F Viscosity 1%: 3000-4500 These high viscosity grades are used where viscosity development is as important as the other benefits derived from the CMC. The proper grade selection depends upon the total gum solids required to develop the desired secondary benefits while maintaining the desired final viscosity. Typical uses: Ice Cream/Ice Milk, Sorbets, Tofu Frozen Desserts, and Soft Serve Ice Cream/Fried Foods/Cake Mixes/ Meringues/Pizza Dough/Frozen Dough/Bar Mixes/Breakfast Drinks/ Instant Gravies, Sauces and Prepared Sauces Substitution Range: TICALOSE CMC is also available toward a high D.S., still within the permitted range for Pharmaceutical and Food use. "Resistant" Grades; TICALOSE 150 "R": Particle Size: C.S.F Viscosity 1%: 501150 Viscosity 2%: 600-1000 TICALOSE 700 "R".. Particle Size: C,S,F Viscositv 1%: 200-400 TICALOSE 2060 "R"-. Particle Size: C,S,F Viscosity 1%: 1060L1500 TICALOSE 5000 "R".. Particle Size: C,S,F Viscosity 1%: 2500-3500

TIC Gums, inc.

385

TIC GUMS, INC.: TICAXAN Xanthan Gum: TICAXAN Xanthan Gum is produced by fermentation by an improved strain of the microorganism Xanthomonas Campestris. The process is carefully controlled for uniformity of molecular structure, most important being the careful balance of pyruvic and acetyl groups which conform specific functionality characteristics to food products. TICAXAN Xanthan Gum exhibits high viscosity at low concentrations, with suspending properties at concentrations as low as 0.05%. TICAXAN also exhibits pseudoplasticity which imparts excellent stability under storage conditions while providing smooth mouthfeel characteristics under normal mastication conditions. Solutions made with TICAXAN are able to tolerate large temperature, electrolytic, and pH ranges. The double helix structure of TICAXAN conveys rigidity of the molecule in solution. This makes TICAXAN an excellent choice for stressful processes such as homogenization, retortion and UHT. TICAXAN hydrates rapidly, reaching full dissolution within 2 minutes of addition. This property of TICAXAN makes it extremely useful in dry mix preparations where instant suspension is required, but just as importantly, in modern processing plants where shorter mixing times allow for greater efficiencies. TICAXAN is compatible with other hydrocolloids and starches, and with some exhibits synergy. The best known synergistic reaction occurs with Locust Bean Gum. Not only does this blend form excellent gels, it also can be used in conjunction with starches to protect the starch from retrogradation. Lesser known combinations, such as TICAXAN and TICALOSE (CMC) are extremely useful in fruit juice beverages. Also, TICAXAN in combination with kappa carrageenan (such as COLLOID 710H) can replace eggs in baked products, while gelatin and whey powder with a touch of TICAXAN can replace egg whites in meringues, and confectionery products.

TICAXAN Applications: Dairy Dairy Desserts Dry Mixes Frozen Foods Bakery Sauces, Soups, Prepared Foods Fruit Beverages Meats Cosmetics & Toiletries Pharmaceutical

386

Water-Soluble Resins

UNION CARBIDE CORP.: CELLOSIZE Hydroxyethyl * * * * *

Cellulose HEC:

Thickener Binder Stabilizer Film Former Protective Colloid

CELLOSIZE Hydroxyethyl Cellulose (HEC!) is a nonionic, watersoluble polymer that can thicken, suspend, bind, emulsify, form films, stabilize, disperse, retain water, and provide protective colloid action. It is readily soluble in hot or cold water and can be used to prepare solutions with a wide range of viscosities. It has outstanding tolerance for dissolved electrolytes. Performance Characteristics: Thickening: CELLOSIZE Hydroxyethyl Cellulose (HEC) helps contribute a desired body in paints and cosmetics. In many applications, thickening is combined with suspension, stabilization, dispersion, and water retention to produce desired results. Pseudoplasticity: Solutions of high-viscosity grades are pseudoplastic and thin out under shear. Latex paints must stay on the brush or roller, yet flow out easily on brushing or rolling and then level out to reduce brush or lap marks. Hair shampoos must pour rich and heavy from the container and yet thin out, feel wet, and disperse easily when rubbed between the hands and applied to the hair. Salt Tolerance: Because CELLOSIZE HEC is nonionic, it is stable in solution with high concentrations of salts. In electroplating, this property contributes to brighter and more uniform plating. In cosmetics, it can be used to thicken underarm deodorants despite the high salt levels of such products. In latex paints, tolerance of borates, silicates, and carbonates is important in maintaining desired viscosity. Film Forming: Films of CELLOSIZE HEC can be applied from water solutions. In paper manufacturing, coatings that are impervious to oils, greases, and most solvents can be prepared. This property also contributes to excellent ink holdout in paper-sizing formulations. Water Retention: CELLOSIZE HEC helps maintain the water content of formulations at desired levels. This property enebles formulators to reduce the amount of water needed in a formulation because of the more efficient use made of water in the presence of small quantities of CELLOSIZE HEC.

Union Carbide Corp.

UNION CARBIDE CORP.: CELLOSIZE Hydroxyethyl (Continued):

387

Cellulose HEC

Applications: Agriculture: CELLOSIZE Hydoxyethyl Cellulose (HEC) effectively suspends solid toxicants in water-based sprays. Building Materials: CELLOSIZE HEC is used in gypsum, cement, lime and organic plasters, tile adhesives, and mortars. Cosmetics and Detergents: CELLOSIZE HEC is an effective film-former, binder, thickener, stabilizer, and dispersant in shampoos, hair sprays, neutralizers, creams and lotions. Latex Polymerization: The molar substitution of the protective colloid grades of CELLOSIZE HEC was chosen to optimize its role in the initiation of catalyst-protective colloid polymerization sites, in the stabilization of the growing polymer particles, and in the stabilization of the finished latex to freeze-thaw and mechanical shear. Oil Production: CELLOSIZE HEC is a viscosifier in workover and completion fluids. It helps provide clear, low-solid fluids that impart minimum formation-damage. Paint Thickening: In latex paint formulations, CELLOSIZE HEC offers ease of solution, low-foaming, thickening efficiency and improved color development and stabilization. Paper and Inks: CELLOSIZE HEC is a useful gloss and ink hold-out size for paper and paperboard. Textile Sizes: Solutions of CELLOSIZE HEC make useful warp sizes that can be removed from the fiber by waterwashinq. Textile Latex Coatings, Binders, and Adhesives: Latex adhesives thickened with CELLOSIZE HEC are pseudoplastic. Textile Carpet Dyeing and Printing: In carpet dyeing, such as Kusters continuous dyeing system, very few thickeners can match the thickening efficiency of CELLOSIZE HEC QP-100MH. Special Applications: Foundries Fire Fighting Photography Microscopy Ceramics Fluorescent Tube Coatings Electoplating and Electra-Refining

388

Fater-Soluble

Resins

UNIOK CARBIDE CORP.: CmLOSIZE (Continued):

Hydroxyethyl

Cellulose HEC

Visccsity Rangles of Aqueous CELL!DSIZE Hydroxyethyl Sa~lutions:

Cellulose

Solution Conce!ntration. %: 5: CELLOlSIZE ---2 HEC (Grade: ~6' -._ WP/QP09L: 75-112 WP'/GP 09H: 113-150 QE' 3L: 215-282 WP' 3H: 283-350 Solution Concentration. %: 2: CELLOSIZE HEC 'Grade: c+* Y-----_-z QP' 40: 80-125 iP'/QP 300: 300-400 QP' 4400: 4800-6000 Solution Concentration, %: 1: CELLOSIZE -~HEC ___ Grade: 2 cP* QP 15 000: 1100-1500 QP 30 000: 1500-1900 Qp' 52 000: 2400-3000 QP' 1OOMH: 4400-6000

Typical Properties of CELLOSIZE IHydroxyethyl Cellu:lose: Appearance: Cream-cclored, frleely flowing powdeir Bulk Density, lb/ft 3: 25-38 Decomposition Temper,ature, F (C): About 400 (20!5) Softening Point, F ((C): >285 (140) Particle Size: 98% through, U.IS. 20 me& Specific Gravity at 20/2OC: 1.38 to 1.,40 Volatile Matter, % ?zy wt: 5 Environmental Impact: Aqueous solutions of CELLOSIZE Hydroxyqethyl Cellulose do not appear to pose any ecological prloblems. FDA and EPA Status: CELLOSIZE Eydroxyethyl Cellulose (HEC) is presemtly approved, under regulations of the United States Folod and Drug Administration (FDA), folr use in indirect food applications, such as :foodpackaging adheisives and can and paper coatings. CE:LLOSIZE HlEC has ruot been c!leared fcr direct use as a component of food products. Under regulations of the Environmental Protection Agency (EPA;', it is e!xempt fro'm the requirement Iof a residue tolerance in pesticide formulaticns.

Union Carbide Corp.

UNION CARBIDE CORP.: POLYOX Water-Soluble

389

Resins:

POLYOX Water-Soluble Resins, CAS Registry No. 25322-68-3, are nonionic water-soluble poly(ethylene oxide) polymers supplied in a variety of viscosity grades. The degree of polymerization, n, varies from about 2,000 to about 180,000, depending on the viscosity grade of resin. Special Features: High Molecular Weight: The molecular weights of POLYOX Water-Soluble Resins range from about one hundred thousand to eight million and above. Completely Water Soluble: POLYOX Water-Soluble Resins, being polyethers, hydrogen bond with water and are completely soluble to just below the boiling point of water. Thickening Ability: POLYOX Water-Soluble Resins are extremely effective thickening agents in water. Friction Reduction: Very small (0.003 percent) concentrations of the higher molecular weight POLYOX Water-Soluble Resins can reduce the turbulent frictional drag of the water in which they are dissolved by as much as 80 percent. Lubricity: POLYOX Water-Soluble Resins impart a high degree of lubricity to water. Aesthetics: When solutions are applied to the skin, they produce a soft and "silky" feel. Nonionic: Being nonionic, POLYOX Water-Soluble Resins are more tolerant of salts than are polyelectrolytes. Form Novel Complexes: The strong hydrogen bonding affinity of POLYOX Water-Soluble Resins accounts for the association of these polyethers with various polar compounds. High Binding Efficiency: POLYOX Water-Soluble Resins have high binding efficiency for pigments, fillers, metal powders, and ceramics. Thermoplastic: As thermoplastics, POLYOX Water-Soluble Resins are readily calendered, extruded, molded, or cast. Soluble in Many Organic Solvents: POLYOX Water-Soluble Resins are readily soluble in and will thicken certain chlorinated solvents. Viscoelastic Behavior: The flexibility of ether linkages combined with the extremely high molecular weight of POLYOX Water-Soluble Resins produces elastic behavior in solution. Wet Tack: Solutions exhibit a high degree of wet tack. Flocculant Activity: Low Toxicity:

390

Water-Soluble Resins

UNION CARBIDE CORP.: POLYOX Water-Soluble Function/Effect: Adhesive Binder Coating/Sizing Dispersant Drift Control Flocculation Hydrodynamic-Drag Reduction Lubricant/Emollient Rheology Modifier Thermoplastic Water Retention Industry: Agriculture Ceramics and Glass Chemical Construction Products Electrical Industrial Supply Metals and Mining Municipal Services Paint Paper Personal Care Products Petroleum Pharmaceutical Printing Soap and Detergents Textile

Resins(Continued):

Union Grbide

UNION CARBIDE CORP.: POLY'OX Water-Soluble

Corp.

391

RNesins(Continued):

POLYOX Grade: -WSR N-*0: Approximate Molecular Weight: 100,000 Viscosity Range, cP: Aqueous Salution at 25C: 5%: 12-50 WSR N-80: Approximate Molecular Weight: 200,000 Viscosity Range, cP: Aqueous Solution at 25C: 5%: 65-115 WSR N-750: Approximate Molecular Weight: 300,000 Viscosity Range, cP: Aqueous Sollution at 25C: 5%: 600-1100 WSR N-3000: Approximate Molecular Weight: 400,000 Viscosity RaNge, cP: A,queous Sollution at 25C: 5%: 2250-450~0 WSR-3333: Approximate Molecular Weight: 400,000 Viscosity RaNge, cP: Aqueous Solution at 25C: 5%: 2250-3350 WSR-205: Approximate Molecular Weight: 600,000 Viscosity RaNge, cP: Aqueous Sollution at 25C: 5%: 4500-8800 WSR-1105: Approximate Eolecular Weight: 9~00,000 Viscosity Range, cPi Aqueous Solution at 25C: 5%: 8800-17,600 WSR-N-121(: Approximate Molecular Weight: l,OOO,OOO Viscosity RaNge, cP: Aqueous Solution at 25C: 2%: 400-800 WSR-N-COK: Approximate Molecular Weight: 21,000,OOO Viscosity RaNge, cP: Aqueous Solution at 25C: 2%: 2000-4000 WSR-301: Approximate Molecular Weight: &,,OOO,OOO Viscosity Range, cP: Aqueous Solution at 25C: 1%: 1650-5560 WSR Coagulant: Approximate Nlolecular Weight: 51,000,OOO Viscosity Range, cP: Aqueous Solution at 25C: 1%: 5500-75C0 WSR-30%: Approximate Mlolecular Weight: 7,000,OOO Viscosity Range, cP: Aqueous Solution at 25C: 1%: 7500-10,000 UCARFLOC Polymer 309: Approximate Molecular Weight: 8,000,OOO Viscosity Range, cP: Aqueous Solution at. 25C: 1%: lO,OOO-15,000

392

Water-Soluble

Resins

UNION CARBIDE CORP.: POLYOX Water-Soluble

Resi.ns(Continued):

Properties(Continued): POLYOX NF Grades: Contact your Union Carbide Sales Representative resins that meet the NF standard.

regarding

POLYOX Compounds: WRPA-3154 Extrusion Grade: WRPA-3154 Molding Grade: WRPA-5779 Extrusion Grade: WRPA-5779 Molding Grade: Specially formulated compounds for injection molding and extrusion applications, possessing improved thermal stability and stress cracking resistance. Available in a range of melt flows for a variety of thermoplastics processing applications. Typical Physical Properties of POLYOX Water-Soluble

Resins:

Appearance: Off-white powder Crystalline Melting Point (X-ray and NMR), C: 62-67 Odor: Slightly ammoniacal Melt Flow Temperature, C: >98 Volatiles Content. as oackaued. % bv wt (at 105C): ~1.0 Alkaline Earth Metals,*% by-wt.as CaO, max: 1.0 Powder Bulk Density, lb/ft 3 (kg/m 3): 19-37 (304-593) Polymer Density, glee: 1.15-1.26 Moisture Content, as packaged, %: (1 Heat of Fusion, cal/gm: 33 Solution pH: 8-10 Particle Size, % by wt: Average through IO-mesh (U.S. Standard): 100 20-mesh 96 EPA Status: POLYOX Water-Soluble Resins are identified by the Federal Environmental Protection Agency in 40 CFR 180.1001(d) for unrestricted use as inert ingredients in pesticide formulations applied to crops up to the time of harvest. FDA Status: Considerable interest has been shown in POLYOX Water-Soluble Resins for diverse applications in food, drug and cosmetic products. Such uses fall within the scope of the Federal Food, Drug and Cosmetic Act. FDA has recognized and approved the use of poly(ethylene oxide) polymers (POLYOX Water-Soluble Resins) for specific food packaging uses, and as direct additive to beer.

Unocal Chemicals Division

UNOCAL CHEMICALS DIVISION: Acrylic: 76 RES 6272: Solids (%): 66.0 Viscosity (cps): 2,800 pH: 4.0 Wt. (lbs)/Gal.: 8.30 Particle Charge: Nonionic Particle Size (Microns): 0.3 Tg (C): -68 Crosslink: N/A Comments: Compounding base for repositionable high peel and tack systems. Markets: Pressure Sensitive Adhesives 76 RES 9201: Solids (%): 66.0 Viscosity (cps): 2,250 pH: 4.8 Wt. (lbs)/Gal.: 8.30 Particle Charge: Nonionic Particle Size (Microns): 0.3 Tg (C!): -68 Crosslink: N/A Comments: PSA application, general purpose, semi-permanent removable. Markets: Pressure Sensitive Adhesives 76 RES 6204: Solids (%): 64.0 Viscosity (cps): 1,650 pH: 5.0 Wt. (lbs)/Gal.: 8.40 Particle Charge: Nonionic Particle Size (Microns): 0.3 Tg (C): -66 Crosslink: N/A Comments: Acrylic compounding base for general purpose permanent applications. Imparts good adhesion to polyolefins. Markets: Pressure Sensitive Adhesives 76 RES 6247: Solids (%): 65.0 Viscosity (cps): 2,500 pH: 4.6 Wt. (lbs)/Gal.: 8.60 Particle Charge: Nonionic Particle Size (Microns): 0.3 Tg (C): -66 Crosslink: N/A Comments: Specifically designed to be compounded into a high peel, high tack PSA. Markets: Pressure Sensitive Adhesives

393

394

Water-Soluble Resins

UNOCAL CHEMICALS DIVISION: Acrylic(Continued): RES 9202: Solids (%): 64.0 Viscosity (cps): 3,300 DH: 4.8 Wt. (lbs)/Gal.: 8.50 Particle Charge: Nonionic Particle Size-(Microns): 0.3 Tg (C): -66 Crosslink: N/A Comments: High peel general purpose permanent pressure sensitive adhesive. Markets: Pressure Sensitive Adhesive 76 RES 9204: Solids (%): 64.0 Viscosity (cps): 3,350 pH: 5.3 Wt. (lbs)/Gal.: 8.40 Particle Charge: Nonionic Particle Size (Microns): 0.3 Tg (C): -66 Crosslink: N/A Comments: PSA application, water resistant. With good adhesion to polvolefins. Markets: Pressure Sensitive Adhesives 76 RES 9211: Solids (%): 62.0 Viscosity (cps): 1,500 pH: 5.5 Wt. (lbs)/Gal.: 8.50 Particle Charge: Nonionic Particle Size (Microns): 0.3 Tg (C): -66 Crosslink: N/A Comments: PSA application, excellent adhesion to polyolefins. Markets: Pressure Sensitive Adhesives 76 RES 6230: Solids (%): 51.0 Viscosity (cps): 50 pH: 3.5 Wt. (lbs)/Gal.: 8.50 Particle Charge: Anionic Particle Si&(Microns): 0.4 Tg (C): -50 Crosslink: N/A Comments: High clarity, high tack compounding base for permanent and overlaminating applications. Markets: Pressure Sensitive Adhesives 76

Unocal Chemicals Division

UNOCAL CHEMICALS DIVISION: Acrylic(Continued): RES 6501: Solids (0): 51.0 Viscosity (cps): 55 pH: 4.5 Wt. (lbs)/Gal.: 8.60 Particle Charge: Anionic Particle Size (Microns): 0.4 Tg (C): -50 Crosslink: N/A Comments: High clarity, low viscosity laminating adhesive for film and paper. High temperature-humidity resistant primer for PVDC film coatings. Markets: Flexible Packaging 76 RES 9611: Solids (%): 60.0 Viscosity (cps): 1,100 pH: 4.9 Wt. (lbs)/Gal.: 8.50 Particle Charge: Nonionic Particle Size (Microns): 0.3 Tg (C): -40 Crosslink: Yes Comments: Compounding base with excellent balance of properties including plasticizer and humidity resistance. Markets: Pressure Sensitive Adhesives 76 RES 9612: Solids (%): 56.0 Viscosity (cps): 3,300 pH: 6.5 Wt. (lbs)/Gal.: 8.50 Particle Charge: Nonionic Particle Size (Microns): 0.28 Tg (C): -40 Crosslink: Yes Comments: Has excellent plasticizer resistance and adhesion build. Should be used in vinyl applications where intermediate shear is desired. Markets: Pressure Sensitive Applications 76 RES 3114: Solids (%): 46.0 Viscosity (cps): 300 DH: 2.7 Wt. (lbs)/Gal.: 8.70 Particle Charge: Nonionic Particle Size-(Microns): 0.2 Tg (C): -33 Crosslink: Self Comments: Textile finishing. Nonwoven binder. Flocking and laminating adhesive. Markets: Nonwovens/Textiles 76

395

396

Water-Soluble Resins

UNOCAL CHEMICALS DIVISION: Acrylic(Continued): 76 RES 3514: Solids (%): 46.0 Viscosity (cps): 60 pH: 2.4 Wt. (lbs)/Gal.: 8.70 Particle Charge: Nonionic Particle Size (Microns): 0.2 Tg (C): -33 Crosslink: Self Comments: Self-crosslinkins acrylic exhibiting high humidity adhesion to nylon, polypropylene and polyester films. Should not be self wound. Markets: Flexible Packaging 76 RES 9634: Solids (2): 46.0 Viscositv (CDs): 300 pH: 2.7 Wt. (lbs)/Gal.: 8.70 Particle Charge: Nonionic Particle Size (Microns): 0.2 Tg (C): -33 Crosslink: Self Comments: Low tack, low peel adhesive for protective films and removable graphic arts applications. Markets: Pressure Sensitive Adhesives 76 RES 6308: Solids (%): 46.0 Viscosity (cps): 200 pH: 3.5 Wt. (lbs)/Gal.: 8.90 Particle Charge: Anionic Particle Size (Microns): 0.25 Tg (C): -27 Crosslink: Self Comments: Soft hand with excellent water and solvent tensile properties. Pigment binder and flocking adhesive. Markets: Nonwovens/Textiles 76 RES 9628: Solids (%): 56.0 Viscosity (cps): 3,000 pH: 5.5 Wt. (lbs)/Gal.: 8.60 Particle Charge: Nonionic Particle Size (Microns): 0.3 Tg (C): -25 Crosslink: Yes Comments: High temperature and high shear PSA for tape and label applications with exceptional plasticizer resistance. Markets: Pressure Sensitive Adhesives

Unocal Chemicals Division

397

UNOCAL CHEMICALS DIVISION: Acrylic(Continued): 76

RES 9636: Solids (%): 56.0 Viscosity (cps): 1,000 pH: 5.2 Wt. (lbs)/Gal.: 8.50 Particle.Charge: Nonionic Particle Size (Microns): N/A Tg

(C):

-25

Crosslink: Yes Comments: Compounding base with outstanding shear and high temperature performance plus plasticizer resistance. Markets: Pressure Sensitive Adhesives 76 RES 6922: Solids (%): 46.0 Viscositv (~13s): 500 pH: 3.5 Wt. (lbs)/Gal.: 8.80 Particle Charge: Anionic Particle Size (Microns): 0.2 Tg (C): -23 Crosslink: Self Comments: Textile finishing, pigment binder. Nonwoven binder. Markets: Nonwovens/Textiles 76 RES 6326: Solids (%): 46.0 Viscosity (cps): 100 DH: 6.5 Wt. (lbs)/Gal.: 8.60 Particle Charge: Anionic Particle Size-(Microns): 0.2 Tg (C): -21 Crosslink: Self Comments: Nonwoven binder. Markets: Nonwovens/Textiles 76 RES 3218: Solids (%): 46.0 Viscositv (CDS): 250 pH: 2.7 Wt. (lbs)/Gal.: 8.70 Particle Charge: Nonionic Particle Size (Microns): 0.1 Tg (C): -20 Crosslink: Self Comments: Textile finishing, backcoating, flocking and laminating. Markets: Textiles

398

Water-Soluble Resins

UNOCAL CHEMICALS DIVISION: Acrylic(Continued): 76 RES 6304: Solids (%): 46.0 Viscosity (cps): 300 pH: 5.5 Wt. (lbs)/Gal.: 8.70 Particle Charge: Nonionic Particle Size (Microns): 0.2 Tg (C): -11 Crosslink: Self Comments: Textile finishing, backcoating, pigment binder. Nonwoven binder. Markets: Nonwovens/Textiles 76 RES 6309: Solids (%): 49.0 Viscosity (cps): 350 pH: 5.0 Wt. (lbs)/Gal.: 8.80 Particle Charge: Anionic Particle Size (Microns): N/A Tg (C): -9 Crosslink: Self Comments: Textile finishing, pigment binder. Nonwoven binder and backcoating. Excellent solvent resistance. Markets: Nonwovens/Textiles 76 RES 3215: Solids (%): 40.0 Viscosity (cps): 200 pH: 7.3 Wt. (lbs)/Gal.: 8.80 Particle Charge: Anionic Particle Size (Microns): 0.1 Tg (C): -5 Crosslink: yes Comments: Leather finishing. Markets: Textiles 76 RES ST6004: Solids (%): 55.0 Viscosity (cps): 350 pH: 8.0 Wt. (lbs)/Gal.: 8.90 Particle Charge: Anionic Particle Size (Microns): 0.25 Tg (C): +2 Crosslink: N/A Comments: Excellent flexibility and wet adhesion in exterior and interior coatings. Markets: Paint

Unocal Chemicals Division

399

UNOCAL CHEMICALS DIVISION: Acrylic(Continued): RES 6510: Solids (%): 65.0 Viscosity (cps): 800 pH: 9.0 Wt. (lbs)/Gal.: 9.00 Particle Charge: Anionic Particle Size (Microns): 0.2 Tg (C!): +3 Crosslink: N/A Comments: Fine particle size and high molecular weight provide excellent grain crack resistance and tint retention. Higher solids allow greater formulating latitude. Markets: Paint 76 RES UC60012: Solids (%): 55.0 Viscosity (cps): 450 pH: 7.5 Wt. (lbs)/Gal.: 8.90 Particle Charge: Anionic Particle Size (Microns): 0.3 Tg (C): +3 Crosslink: N/A Comments: Vinyl chloride free terpolymer for interior semi-gloss systems. Excellent gloss, enamel holdout, wet adhesion, and chalk adhesion. Markets: Paint 76 RES 3112: Solids (pi): 46.0 Viscosity (cps): 35 pH: 2.7 Wt. (lbs)/Gal.: 8.90 Particle Charge: Nonionic Particle Size (Microns): 0.1 Tg (C): +26 Crosslink: Self Comments: Textile finishinq and backcoatinq. Nonwoven binder. Markets: Nonwovens/Textiles 76 RES 3512: Solids (%): 46.0 Viscosity (cps): 35 pH: 2.3 Wt. (lbs)/Gal.: 8.90 Particle Charge: Nonionic Particle Size (Microns): 0.1 Tg (C): +26 Crosslink: Self Comments: Self-crosslinking acrylic exhibiting good adhesion to nylon, polypropylene and polyester films. Nonblocking primer for films. Markets: Flexible Packaging 76

400

Water-soluble

Resins

UNOCAL CHEMICALS DIVISION: Acrylic(Continued): 76

76

RES 6038: Solids (%): 13.5 Viscosity (cps): 21,000 pH: 9.0 Wt. (lbs)/Gal.: 8.90 Particle Charge: N/A Particle Size (Microns): N/A Tg (C): N/A Crosslink: No Comments: Sodium Polyacrylate thickener for adhesive applications. Markets: General Adhesives/Pressure Sensitive Adhesives RES 8306: Solids (%): 13.5 Viscosity (cps): 21,000 pH: 9.0 Wt. (lbs)/Gal.: 8.90 Particle Charge: N/A Particle Size (Microns): N/A Crosslink: No Comments: Sodium Polyacrylate thickener for textile applications. Markets: Textiles

Unocal Chemicals Division

UNOCAL CHEMICALS DIVISION: Carboxylated

401

Styrene Butadiene:

76 RES 9410: Solids (%): 50.0 Viscosity (cps): 500 pH: 8.7 Wt. (lbs)/Gal.: 8.10 Particle Charge: Anionic Particle Size (Microns): 0.15 Tg (C): -61 Crosslink: N/A S/B Ratio: 25175 Comments: A very soft carboxylated SBR with high molecular weight. Excellent for compounding low temperature tapes and label systems. Markets: Pressure Sensitive Adhesives 76 RES 9413: Solids (%I: 50.0 Viscositv (CDS): 200 pH: 8.8 Wt. (lbs)/Gal.: 8.20 Particle Charge: Anionic Particle Size (Microns): 0.15 Ts (C): -46 Crossiink: N/A S/B Ratio: 35/65 Comments: A very soft carboxylated SBR for compounding general purpose permanent labels, especially where high adhesion to corrugated surfaces is required. Markets: Pressure Sensitive Adhesives 76 RES 9412: Solids (%): 50.0 Viscosity (cps): 600 pH: 9.7 Wt. (lbs)/Gal.: 8.30 Particle Charge: Anionic Particle Size (Microns): 0.15 Tg (C): -45 Crosslink: No S/B Ratio: 20/80 Comments: Very soft carboxylated SBR with outstanding shear properties. Excellent for compounding high performance tapes and labels. Markets: Pressure Sensitive Adhesives

402

Water-Soluble Resins

UNOCAL CHEMICALS DIVISION: Carboxvlated (Continued):

Stvrene Butadiene _

76 RES 4125:

Solids (%): 50.0 Viscosity (cps): 300 pH: 9.0 Wt. (lbs)/Gal.: 8.30 Particle Charge: Anionic Particle Size (Microns): 0.15 Tg (C): -32 Crosslink: Yes S/B Ratio: 45155 Comments: Upholstery backcoating. Markets: General Adhesives/Textiles 76 RES 6105: Solids (%): 50.0 Viscosity (cps): 150 PH: 8.7 wt. (lbs)/Gal.: 8.30 Particle Charge: Anionic Particle Size-(Microns): 0.25 Tg (C): -32 Crosslink: N/A S/B Ratio: 45/55 Comments: Pressure sensitive latex for compounding Hi-Tack adhesives. Markets: Pressure Sensitive Adhesives 76 RES 6130: Solids (%a): 50.0 Viscosity (cps): 300 pH: 8.1 Wt. (lbs)/Gal.: 8.30 Particle Charge: Anionic Particle Size (Microns): 0.2 Tg (C): -32 Crosslink: N/A S/B Ratio: 45/55 Comments: Compounding base for High-Tack label and tape adhesives. Markets: Pressure Sensitive Adhesives 76 RES 9415: Solids (%): 50.0 Viscosity (cps): 200 pH: 9.5 Wt. (lbs)/Gal.: 8.20 Particle Charge: Anionic Particle Size (Microns): 0.25 Tg (C): -32 Crosslink: N/A S/B ratio: 45/55 Comments: PSA, for compounding Hi-Tack, available West Coast only. Markets: Pressure Sensitive Adhesives

Unocal Chemicals Division

UNOCAL CHEMICALS DIVISION: Carboxylated (Continued):

Styrene Butadiene

76 RES 4151: Solids (%a): 50.0 Viscositv Icns): 300 pH: 9.0 Wt. (lbs)/Gal.: 8.35 Particle Charge: Anionic Particle Size (Microns): 0.15 Tu (C): -30 Crosslink: Yes S/B Ratio: 45/55 Comments: Textile backcoating, nonwoven binder, pigment binder. Markets: Nonwovens/Texiles 76 RES 4305: Solids (%): 53.0 Viscosity (cps): 500 pH: 8.7 Wt. (lbs)/Gal.: 8.40 Particle Charge: Anionic Particle Size (Microns): 0.2 Tg (C): -30 Crosslink: Yes S/B Ratio: 45/55 Comments: A soft zero formaldehyde binder for textiles and nonwovens. Markets: Nonwovens/Textiles 76 RES 4425: Solids (%): 53.0 Viscosity (cps): 600 pH: 8.7 Wt. (lbs)/Gal.: 8.30 Particle Charge: Anionic Particle Size (Microns): 0.15 Tg (C): -30 Crosslink: Yes S/B Ratio: 45/55 Comments: Textile backcoating finishing. Markets: Textiles

403

404

Water-Soluble Resins

UNOCAL

CHEMICALS

DIVISION:

Carboxylated

Styrene Butadiene

(Continued): 76 RES 5550: Solids (%): 50.0 Viscosity (cps): 300 pH: a.7 Wt. (lbs)/Gal.: 8.40 Particle Charge: Anionic Particle Size (Microns): 0.15 Tg (C): -30 Crosslink: Self S/B Ratio: 45/55 Comments: Self-crosslinkinq, nonwoven binder. Markets: NonwovensfTextiles 76 RES 4176: Solids (%): 50.0 Viscosity (cps): 200 pH: 9.0 Wt. (lbs)/Gal.: 8.40 Particle Charge: Anionic Particle Size (Microns): 0.15 Tg (C): -22 Crosslink: Yes S/B Ratio: 50/50 Comments: Textile backcoating, nonwoven binder. Markets: General Adhesives/Nonwovens/Textiles 76 RES 4402: Solids (%): 53.0 Viscosity (cps): 300 i:I y&)/Gal.: 8.40 Particle Charge: Anionic Particle Size (Microns): 0.2 Tg (C): -22 Crosslink: Yes S/B Ratio: 50150 Comments: A medium soft polymer for nonwovens and paper saturation. Markets: Nonwovens/Textiles

Unocal Chemicals Division

UNOCAL CHEMICALS DIVISION: Carboxylated (Continued): 76 RES 4416: Solids (%): 51.0 Viscosity (cps): 300 pH: 8.7 Wt. (lbs)/Gal.: 8.35 Particle Charge: Anionic Particle Size (Microns): 0.2 Tg (C): -22 Crosslink: Yes S/B Ratio: SO/SO Comments: A medium soft binder with outstanding nonwovens or paper saturation. Markets: Nonwovens/Textiles 76

RES 4150: Solids (%): 50.0 Viscositv (ens): 300 pH: 9.0 Wt. (lbs)/Gal.: 8.40 Particle Charge: Anionic Particle Size (Microns): 0.15 Ts (C): -16 Crosslink: Yes S/B Ratio: 55/45 Comments: Carpet and upholstery backing. Markets: General Adhesives/Textiles

76

RES 4816: Solids (%): 53.0 Viscosity (cps): 300 pH: 8.7 Wt. (lbs)/Gal.: 8.35 Particle Charge: Anionic Particle Size (Microns): 0.2 Tg (C): -14 Crosslink: Yes S/B Ratio: 58/42 Comments: Carpet backing. Markets: Textiles

Styrene Butadiene

runnability for

405

406

Water-Soluble Resins

UNOCAL CHEMICALS DIVISION: Carboxylated (Continued):

Styrene Butadiene

76 RES 4817: Solids (%): 53.0 Viscosity (cps): 300 pH: 8.7 Wt. (lbs)/Gal.: 8.40 Particle Charge: Anionic Particle Size (Microns): 0.2 Tg (C): -14 Crosslink: Yes S/B Ratio: 58142 Comments: Carpet backing. Markets: Textiles 76 RES 4105: Solids (%): 50.0 Viscosity (cps): 300 pH: 6.0 Wt. (lbs)/Gal.: 8.40 Particle Charge: Anionic Particle Size (Microns): 0.14 Tg (C): -11 Crosslink: N/A S/B Ratio: 57143 Comments: Particle size designed for high solids blade coating runnability. Markets: Paper 76 RES 4100: Solids (%): 50.0 Viscosity (cps): 300 DH: 6.5 Ht. (lbs)/Gal.: 8.35 Particle Charge: Anionic Particle Size-(Microns): 0.2 Tg (C): -10 Crosslink: N/A S/B Ratio: 57/43 Comments: Paper coating, designed for offset & rotogravure grades. Protein compatible. Markets: Paper

Unocal Chemicals Division

UNOCAL CHEMICALS DIVISION: Carboxylated (Continued):

Styrene Butadiene

76 RES 4040: Solids (%): 50.0 Viscosity (cps): 150 pH: 6.0 Wt. (lbs)/Gal.: 8.30 Particle Charge: Nonionic Particle Size (Microns): 0.2 Tg (C): -8 Crosslink: N/A S/B Ratio: 65/35 Comments: Adhesives, caulks & mastics; cement additive. Markets: General Adhesives 76 RES 4400: Solids (%): 53.0 Viscosity (cps): 200 DH: 8.5 Wt. (lbs)/Gal.: 8.35 Particle Charge: Anionic Particle Size-(Microns): 0.2 Tg (C): -8 Crosslink: Yes S/B Ratio: 63/37 Comments: Carpet backing. Markets: Textiles 76 RES 4002: Solids (%): 50.0 Viscosity (cps): 200 pH: 8.25 Wt. (lbs)/Gal.: 8.40 Particle Charge: Anionic Particle Size (Microns): 0.15 Tg (C): -7 Crosslink: N/A S/B Ratio: 65/35 Comments: Low odor SBR for use in interior vapor barrier primer sealers and flat wall paint. Markets: Paint

407

408

Water-Soluble Resins

DNOCAL CHEMICALS DIVISION: Carboxylated (Continued): 76

Styrene Butadiene

RES 4076: Solids (%): 50.0 Viscosity (cps): 200

;Y: T&)/Gal.: 8.30 Particle Charge: Anionic Particle Size (Microns): 0.15 Tg (C): -7 Crosslink: N/A S/B Ratio: 65/35 Comments: Superior cold temperature touch-up. Outstanding low permeability coatings. Markets: Paint

vehicle for

76 RES 4104: Solids (%): 50.0 Viscosity (cps): 300 pH: 9.0 Wt. (lbs)/Gal.: 8.30 Particle Charge: Anionic Particle Size (Microns): 0.15 Tc (Cl: -7 Crosslink: N/A S/B Ratio: 65/35 Comments: Tape joint cement. Markets: General Adhesives 76 RES 4170: Solids (%): 50.0 Viscosity (cps): 200 t3FI ?&)/Gal.: 8.40 Particle Charge: Anionic Particle Size (Microns): 0.15 Tg (C): -7 Crosslink: Self S/B Ratio: 65/35 Comments: Carpet precoat. Coatings polymer. Nonwoven binder. Markets: General Adhesives/Nonwovens/Textiles

Unocal Chemicals Division

UNOCAL CHEMICALS DIVISION: Carboxylated (Continued):

409

Styrene Butadiene

76 RES 4800: Solids (2): 50.0 Viscosity (cps): 200 pH: 10.5 Wt. (lbs)/Gal.: 8.35 Particle Charge: Anionic Particle Size (Microns): N/A Tg (C): -7 Crosslink: N/A S/B Ratio: 65/35 Comments: Extremely stable SBR emulsion designed for use as a modifier for concrete applications. Markets: General Adhesives 76 RES 4470: Solids (%): 53.0 Viscosity (cps): 350 DH: 9.0 Wt. (lbs.)/Gal.: 8.30 Particle Charge: Anionic Particle Size-(Microns): 0.15 Tg (C): -6 Crosslink: Yes S/B Ratio: 67/33 Comments: Firm polymer for carpets and textiles. Nonwoven binder. Markets: Nonwovens/Textiles 76 RES 4103: Solids (%): 50.0 Viscosity (cps): 300 pH: 6.0 wt. (lbs)/Gal.: 8.40 Particle.Charge: Anionic Particle Size (Microns): 0.2 Tg (C): -5 Crosslink: N/A S/B Ratio: 57/43 Comments: Excellent runnability and printability coatings. Markets: Paper

for high speed blade

4 10

Water-Soluble Resins

UNOCAL CHEMICALS DIVISION: Carboxylated (Continued):

Styrene Butadiene

76 RES 8100: solids (%I: 50.0 Viscosity (cps): 500 pH: 6.8 Wt. (lbs)/Gal.: 8.70 Particle Charge: Anionic Particle Size (Microns): 0.2 Tg (C): 0 Crosslink: N/A Comments: Paper coating, high strength for paper & paperboard. Markets: Paper 76 RES 4106: solids (a): 50.0 Viscosity (cps): 200 pH: 6.5 Wt. (lbs)/Gal.: 8.40 Particle Charge: Anionic Particle Size (Microns): 0.2 Tg (C): +76 Crosslink: No S/B Ratio: gO/lO Comments: An extremely hard latex used to modify hand. Develops sheet gloss for paper coatings. Markets: General Adhesives/Nonwovens/Paper/Textiles

Unocal Chemicals Division

UNOCAL CHEMICALS DIVISION: Polyvinylidene

Chloride:

76 RES 701: Solids (%): 45.0 Viscosity (cps): 150 pH: 2.0 Wt. (lbs)/Gal.: 10.00 Particle Charge: Anionic Particle Size (Microns): 0.25 Tg (C): -10 Alcohol Stable: Yes Comments: Laminating adhesive, excellent adhesion, solvent urethane replacement. -Flame retardant textile backcoating. Markets: Flexible Packaging/Textiles 76 RES 546: Solids (%): 46.0 Viscosity (cps): 160 ;:I f&)/Gal.: 10.30 Particle Charge: Anionic Particle Size (Microns): 0.25 Tg (C): +9 Alcohol Stable: Yes Comments: Waterbased laminating adhesive giving a good balance of bond strength and oxygen barrier in dry bond laminations. Also used as a primer for extrusion coating and laminating. Markets: Flexible Packaging 76

RES

917:

Solids (%): 50.0 Viscosity (cps): 50 pH: 3.5 Wt. (lbs)/Gal.: 9.90 Particle Charge: Anionic Particle Size (Microns): 0.25 Tg (C): +9 Alcohol Stable: Yes Comments: Softer version of 76 RES 777. Flame retardant textile backcoating. Leather finish. Markets: Paint/Textiles 76 RES M3-153: Solids (%): 50.0 Viscosity (cps): 100 pH: 2.0 Wt. (lbs)/Gal.: 10.40 Particle Charge: Anionic Particle Size (Microns): 0.25 Tg (C): +ll Alcohol Stable: Yes Comments: Moderate barrier laminating adhesive for film to film applications. Markets: Flexible Packaging

4 11

4 12 Water-Soluble Resins

UNOCAL CHEMICALS DIVISION: Polyvinylidene

Chloride(Continued):

76 RES 5517: Solids (%): 55.0 Viscositv (CDS): 10 pH: 2.0 Wt. (lbs)/Gal.: 10.50 Particle Charge: Anionic Particle Size (Microns): 0.25 Tg (C): +20 Alcohol Stable: Yes Comments: High barrier PVDC base coat for use on glassine, paper and paperboard. Markets: Flexible Packaging 76 RES 5527: Solids (8): 55.0 Viscosity (cps): 10 pH: 2.0 Wt. (lbs)/Gal.: 10.50 Particle Charge: Anionic Particle Size (Microns): 0.25 Tg (C): +20 Alcohol Stable: Yes Comments: High barrier basecoat for use on glassine, paper, and paperboard. High barrier laminating adhesive for treated film. Markets: Flexible Packaging 76 RES 777: Solids (%): 55.0 Viscosity (cps): 75 pH: 4.5 Wt. (lbs.)/Gal.: 9.70 Particle Charge: Anionic Particle Size (Microns): 0.35 Tg (C): +22 Alcohol Stable: Yes Comments: Latex vehicle for interior flat and semigloss flame retardant coatings. Markets: Paint 76 RES 5518: Solids (%): 60.0 Viscosity (cps): 50 pH: 2.5 Wt. (lbs)/Gal.: 11.00 Particle Charge: Anionic Particle Size (Microns): 0.25 Tg (C): Crystallizes Alcohol Stable: Yes Comments: High barrier coating for polyolefins and PET. Markets: Flexible Packaging

Unocal Chemicals Division

413

UNOCAL CHEMICALS DIVISION: Styrene Acrylic: 76 RES 1019: Solids (%): 50.0 Viscosity (cps): 9,000 pH: 8.50 Wt. (lbs)/Gal.: 8.50 Particle Charge: Anionic Particle Size (Microns): 0.15 Tg (C!): -15 Comments: Provides flexibility, alkali resistance and water resistance in high performance roof coatings and mastics. Exhibits high pigment binding capacity and adhesion to a variety of substrates. Textile printing. Markets: Nonwovens Paint Textiles 76 RES 1018: Solids (%): 50.0 Viscosity (cps): 5,000 pH: 7.5 Wt. (lbs)/Gal.: 8.50 Particle Charge: Anionic Particle Size (Microns): 0.15 Tg (C): +22 Comments: Highly effective in water-resistant coatings such as clears for masonry surfaces, vertical wall textured finishes. Provides good gloss-and clarity. Exhibits high pigment binding capacity. Textile finishing. Markets: Nonwovens Paint Textiles

4 14

Water-Soluble Resins

UNOCAL CHEMICALS DIVISION: Vinyl Acetate Homopolymer: 76

RES 6206: Solids (%): 55.0 Viscosity (cps): 5,000 PH: 4.5 Wt. (lbs)/Gal.: 9.10 Particle Charge: Nonionic Particle Size-(Microns): 3.0 Tg (C): +20 Crosslink: N/A Borax Stability: Unstable Comments: Adhesives. Wood glue. Markets: General Adhesives

76

RES 3151: Solids (%): 55.0 Viscosity (cps): 1,200 PH:

5.0

Wt. (lbs)/Gal.: 9.10 Particle Charge: Nonionic Particle Size-(Microns): 0.4 Tg (C): +26 Crosslink: N/A Borax Stability: Unstable Comments: Concrete & stucco additive. Markets: General Adhesives 76

RES 6213: Solids (%): 55.0 Viscosity (cps): 2,500 pH: 4.5 Wt. (lbs)/Gal.: 9.10 Particle Charge: Nonionic Particle Size (Microns): 1.8 Tg (C): +26 Crosslink: N/A Borax Stability: Unstable Comments: Adhesives, high molecular weight. Markets: General Adhesives

76

RES 19RB64: Solids (%): 58.0 Viscosity (cps): 1,700 pH: 4.5 Wt. (lbs)/Gal.: 9.20 Particle Charge: Nonionic Particle Size (Microns): 0.6 Tg (C): +28 Crosslink: No Borax Stability: Stable Comments: Adhesives. Textile finishing. Markets: General Adhesives Textiles

Unocal Chemicals Division

4 15

UNOCAL CHEMICALS DIVISION: Vinyl Acetate Homopolymer(Continued): 76

76

76

76

RES 202A: Solids (%): 55.0 Viscosity (cps): 2,150 PH: 5.0 wt. (lbs)/Gal.: 9.10 Particle Charge: Nonionic Particle Size-(Microns): 0.9 Tg (C): +30 Crosslink: N/A Borax Stability: Unstable Comments: Adhesives. Textile finishing. Markets: General Adhesives Textiles RES 202AH: Solids (%): 55.0 Viscosity (cps): 3,000 PH: 5.0 it. (lbs)/Gal.: 9.10 Particle Charge: Nonionic Particle Size-(Microns): 0.9 Tg (C): +30 Crosslink: N/A Borax Stability: Unstable Comments: Adhesives. Textile finishing. Markets: General Adhesives Textiles RES 202AM: Solids (%): 55.0 Viscosity (cps): 1,250 pH: 5.0 Wt. (lbs)/Gal.: 9.10 Particle Charge: Nonionic Particle Size (Microns): 0.9 Tg (C): +30 Crosslink: N/A Borax Stability: Unstable Comments: Adhesives. Textile finishing. Markets: General Adhesives Textiles RES S-55: Solids (%): 55.0 Viscosity (cps): 1,000 pH: 5.0 Wt. (lbs)/Gal.: 9.10 Particle Charge: Nonionic Particle Size (Microns): 1.7 Tg (C): +35 Crosslink: Yes Borax Stability: Unstable Comments: Textile finishing & adhesives. Markets: General Adhesives Textiles

4 16

Water-Soluble Resins

UNOCAL CHEMICALS DIVISION: Vinyl Acetate Homopolymer(Continued): 76

RES S-55E: Solids (%): 55.0 Viscosity (cps): 1,000 pH: 5.0 Wt. (lbs)/Gal.: 9.10 Particle Charge: Nonionic Particle Size (Microns): 1.7 Tg

(C):

+35

Crosslink: Yes Borax Stability: Unstable Comments: Textile finishing with excellent non-stick properties. Markets: Textiles 76

RES 6215: Solids (%): 65.0 Viscosity (cps): 2,300 EFi f&)/Gal.: 9.60 Particle Charge: Nonionic Particle Size (Microns): 0.35 Tg (C): N/A Crosslink: N/A Borax Stability: Stable Comments: Dextrine stabilized remoistenable Markets: General Adhesives

adhesive.

Unocal Chemicals Division

4 17

UNOCAL CHEMICALS DIVISION: Vinyl Acrylic: 76 RES 6255: Solids (%): 55.0 Viscosity (cps): 600 pH: 4.3 Wt. (lbs)/Gal.: 8.80 Particle Charge: Nonionic Particle Size (Microns): 0.4 Tg (C): -47 Crosslink: N/A Comments: Excellent for compounding high peel, high tack PSA's. Markets: Pressure Sensitive Adhesives 76 RES 9214: Solids (%): 55.0 Viscosity (cps): 2,100 pH: 4.5 Wt. (lbs)/Gal.: 8.70 Particle Charge: Nonionic Particle Size (Microns): 0.4 Tg (C!):-47 Crosslink: N/A Comments: Permanent high tack pressure sensitive adhesive for vinyl applications. Markets: Pressure Sensitive Adhesives 76 RES 9620: Solids (%): 53.0 Viscosity (cps): 4,000 pH: 5.6 Wt. (lbs)/Gal.: 8.60 Particle Charge: Nonionic Particle Size (Microns): 0.5 Tg (C): -35 Crosslink: N/A Comments: Repositionable pressure sensitive adhesive with excellent plasticizer migration resistance. Formulated for reverse roll coaters. Markets: Pressure Sensitive Adhesives 76 RES NWS-26: Solids (%): 46.0 Viscosity (cps): 300 pH: 5.0 Wt. (lbs)/Gal.: 8.80 Particle-Charge: Anionic Particle Size (Microns): 0.2 Tg (C): -15 Crosslink: Self Comments: A soft binder with good tensile properties and compatibility with a variety of chemical additives. Markets: Nonwovens/Textiles

4 18 Water-Soluble Resins

UNOCAL CHEMICALS DIVISION: Vinyl Acrylic(Continued): 76 RES 6930: Solids (%): 45.0 Viscosity (cps): 400 pH: 4.5 Wt. (lbs.)/Gal.: 8.80 Particle Charge: Anionic Particle Size (Microns): 0.2 Tg (C): -8 Crosslink: Self Comments: Textile finishing, backcoating, printing. Size press coating. Nonwoven binder. Markets: Nonwovens/Textiles 76 RES 3077: Solids (%): 55.0 Viscosity (cps): 2,150 pH: 5.0 Wt. (lbs)/Gal.: 9.00 Particle Charge: Nonionic Particle Size (Microns): 0.3 Tg (C): +l Crosslink: N/A Comments: Coatings polymer, excellent scrub resistance & film forming properties. Markets: Paint 76 RES 661: Solids (%): 55.0 Viscosity (cps): 1,000 pH: 4.5 Wt. (lbs)/Gal.: 9.00 Particle Charge: Nonionic Particle Size: 0.35 Tg (C): +3 Crosslink: N/A Comments: Coatings polymer, excellent scrub resistance. Good exterior ._.. durability. Markets: Paint 76 RES PEP: Solids (%): 40.0 Viscosity (cps): 2,000 pH: 5.0 wt. (lbs)/Gal.: 8.80 Particle-Charge: Anionic Particle Size (Microns): 1.25 Tg (C): +4 Crosslink: N/A Comments: Textile finishing, heat sealing & nonwoven binder. Markets: Nonwovens/Textiles

Unocal Chemicals Division

4 19

UNOCAL CHEMICALS DIVISION: Vinyl Acrylic(Continued): 76 RES 3083: Solids (%): 55.0 Viscosity (cps): 350 pH: 5.0 Wt. (lbs)/Gal.: 9.00 Particle Charge: Nonionic Particle Size (Microns): 0.3 Tg (C): +5 Crosslink: N/A Comments: Fine particle size for interior and exterior. Exhibits excellent scrub resistance and enamel holdout. Provides grain crack resistance and exterior durability. Markets: Paint 76 RES 3011: Solids (%): 55.0 Viscosity (cps): 2,000 pH: 3.0 wt. (lbs.)/Gal.: 9.00 Particle Charge: Nonionic Particle Size (Microns): 0.45 Tg

(C!):

+6

Crosslink: N/A Comments: Coatings polymer, excellent scrub resistance. Textile finishing. Markets: Paint 76 RES 3103: Solids (%): 50.0 Viscosity (cps): 120 pH: 6.0 Wt. (lbs)/Gal.: 9.10 Particle Charge: Anionic Particle Size (Microns): 0.25 Tg

(C):

+13

Crosslink: N/A Comments: Provides improved pick resistance, runnability. Markets: Paner 76 RES 3016: Solids (%): 55.0 Viscosity (cps): 2,100 pH: 3.0 Wt. (lbs)/Gal.: 9.00 Particle Charge: Nonionic Particle Size (Microns): 0.45 Tg

(C):

opacity and blade coating

+14

Crosslink: N/A Comments: Textile finishing. Trade sales paint. Markets: Paint

Water-Soluble

420

Resins

UNOCAL CHEMICALS DIVISION: Vinyl Acrylic(Continued): 76 RES 6110:

Solids (%): 50.0 Viscosity (cps): 600 pH: 6.0 Wt. (lbs)/Gal.: 9.10 Particle Charge: Anionic Particle Size (Microns): 0.15 Tg (C): +19 Crosslink: N/A Comments: Papercoating, superior rheology and strength properties. Markets: Paper 76 RES 6108: Solids (%): 50.0 Viscosity (cps): 500 pH: 6.0 Wt. (lbs)/Gal.: 9.10 Particle Charge: Anionic Particle Size (Microns): 0.15 Tg (C): +20 Crosslink: N/A Comments: Papercoating, good printing characteristics, high pick resistance. Markets: Paper 76 RES 6107: Solids (%): 50.0 Viscosity (cps): 275 pH: 6.0 wt. (lbs)/Gal.: 9.10 Particle.Charge: Nonionic Particle Size (Microns): 0.15 Tg

76

(C):

+24

Crosslink: N/A Comments: Papercoating. Heat sealable nonwoven binder. Markets: Paper RES 7800: Solids (%): 50.0 Viscosity (cps): 250

;Fi Y&)/Gal.: 9.00 Particle Charge: Anionic Particle Size (Microns): 0.2 Tg (C): +30 Crosslink: N/A Comments: Papercoating, low latex viscosity, ance. Markets: Paper

superior coating perform-

Unocal Chemicals Division

UNOCAL CHEMICALS DIVISION: Vinyl Acrylic(Continued): 76 RES 1170:

Solids (%): 45.0 Viscosity (cps): 200 pH: 4.0 Wt. (lbs)/Gal.: 9.00 Particle Charge: Anionic Particle Size (Microns): 0.35 Tg

(C):

+33

Crosslink: Self Comments: Nonwoven high loft binder for spray applications. Markets: Nonwovens 76 RES 2302: Solids (%): 46.0 Viscosity (cps): 100 pH: 4.0 Wt. (lbs)/Gal.: 9.00 Particle Charge: Anionic Particle Size (Microns): 0.35 Tg (C): +33 Crosslink: Self Comments: Fiberfill & high loft nonwoven binder for spray applications. Textile finishing. Markets: Nonwovens/Textiles 76 RES 2304: Solids (%): 46.0 Viscosity (cps): 200 pH: 4.0 Wt. (lbs)/Gal.: 9.00 Particle Charge: Anionic Particle Size (Microns): 0.35 Tg (C): +33 Crosslink: Self Comments: Fiberfill & high loft nonwoven binder, frothable. Textile finishing. Markets: Nonwovens/Textiles 76

RES

2306:

Solids (%): 45.0 Viscosity (cps): 200 pH: 4.0 Wt. (lbs)/Gal.: 9.10 Particle Charge: Anionic Particle Size (Microns): 0.35 Tg (C): +33 Crosslink: Self Comments: Fiberfill & hiqh loft nonwoven binder, frothable. Textile finishing. Markets: Nonwovens/Textiles

421

422

Water-Soluble Resins

UNOCAL CHEMICALS DIVISION: Vinyl Acrylic(Continued): 76 RES 2307: Solids (%): 45.0 Viscosity (cps): 50 pH: 4.0 Wt. (lbs)/Gal.: 8.50 Particle Charge: Anionic Particle Size (Microns): 0.35 Tg (C): +33 Crosslink: Self Comments: Fiberfill & high loft nonwoven binder for spray applications. Textile finishing. Markets: Nonwovens/Textiles

R. T. Vanderbilt Co., Inc.

R.T. VANDERBILT

423

CO., INC.: RHODIGEL Xanthan Gum:

RHODIGEL is produced by a fermentation process using the natural plant organism Xanthomonas campestris. The resulting product is a water-soluble, anionic polysaccharide. Each repeating unit consists of a backbone of four B-D glucose units linked at the 1 and 4 positions. At the 3 position of alternating glucose units, are trisaccharide side chains consisting of an acetylated mannose unit, a glucuronic acid unit and either a mannose or pyruvic acid unit. The resulting stiff polymer chain may exist, in a solution, as a single, double or triple helix which interacts with other xanthan gum molecules to form complex, loosely bound networks held together by secondary valence forces. It is this network formation which produces many of the desirable benefits of using RHODIGEL Xanthan Gum. Grades and Typical Physical Properties: RHODIGEL Xanthan Gum is produced in two grades. RHODIGEL is the standard grade product and RHODIGEL 200 is a fine mesh, ground version of RHODIGEL. RHODIGEL: Appearance: Cream-White Powder Moisture Content, %: 12 max. pH (1.0 wt% Aqueous Solution): 6 to 8 Viscosity, ens: 1200-1600 Mesh Size; % thru 60 mesh: 100 % thru 80 mesh: 95 min. % thru 200 mesh: ---RHODIGEL 200: Appearance: Cream-White Powder Moisture Content, %: 12 max. pH (1.0 wt% Aqueous Solution): 6 to 8 Viscosity, cps: 1200-1600 Mesh Size: % thru 60 mesh: ---% thru 80 mesh: 100 % thru 200 mesh: 92 min. Performance Benefits: - High Efficiency Thickener - Dissolves Easily in Cold or Warm Water - Produces Highly-Pseudoplastic Solutions - Aqueous Solutions Have High Yield Values - Excellent Stabilizing Agent for Emulsions, Suspensions and Foams - Stable Viscosity Over a Broad PH Range - Little Viscosity Change With Temperature - Synergistic Rheological Performance with other Organic Gums and Inorganic-Suspending Agents - Compatible with Acids, Bases, Salts, and most Pharmaceutical and Cosmetic Ingredients Note: RHODIGEL is a Tradename of Rhone-Poulenc,

France

424

Water-Soluble Resins

R.T. VANDERBILT Gum:

CO., INC.: RAODOPOL Industrial Grade Xanthan

Xanthan gum is the versatile polysaccharide thickener and stabilizer produced by fermentation and extraction of the naturally occuring plant bacteria Xanthomonas campestris. The resulting stiff chain may exist as a single, double or triple helix, which interacts with other polymer molecules to build a complex loosely bound network held together by secondary valence forces. The xanthan gum is about 2 X 10 6 molecular weight with a narrow molecular weight distribution compared to most polysaccharides. Intermolecular association among polymer chains results in the formation of a complex network of entangled rod like molecules. These weakly bound aggregates are progressively disrupted under the influence of applied shear: this explains the pronounced pseudoplasticity of xanthan gum solutions. In addition, this highly ordered network of entangled stiff molecules accounts for the high yield value of xanthan gum, which translates - in practical terms - to the effective suspending properties exhibited by the gum. RHODOPOL is an anionic polymer which is soluble in water but insoluble in most organic solvents. It performs a number of unique functions in water solutions because of its original molecular structure. Typical Specifications: __ Physical state: Powder Moisture content: 12% max. Bulk density (g/ml): 0.8 Mesh size (through 50 mesh): 98% pH: 6-8 RHODOPOL meets the needs for a highly effective viscosifier stabilizer, and suspending agent Unique properties even at low concentration: - Effective suspending agent - Viscosifier with pseudoplastic behaviour (shear-thinning) - Exceptional stability of rheolosical properties over a broad pH and temperature range - - Soluble and stable in wide range of salt concentration - Ability to be gelled and cross-linked Note: RHODOPOL

is a tradename of RHONE POULENC, France.

SUPPLIERS’

ADDRESSES

425

426

Water-Soluble Resins

Abatron. Inc. 33 Center Drive Gilberts, IL 60136 (312)-426-2200/(800)-445-1754

CPS Chemical Co., Inc. P.O. Box 162 Old Bridge, NJ 08857 (201)-727-3100

Aceto Corp. One Hollow Lane Lake Success, NY 11042-1215 (516)-627-6000

Dock Resins Corp. 1512 West Elizabeth Ave. Linden, NJ 07036 (201)-862-2351

Air Products and Chemicals Box 538 Allentown, PA 18105 (215)-481-6799/(800)-345-3148

Dow Chemical U.S.A. Midland, MI 48674 (800)-258-2436

Alto Chemical 909 Mueller Drive P.O. Box 5401 Chattanooga, TN 37406 (615)-629-1405/(800)-251-1080 Aqualon Co. Little Falls Centre One 2711 Centerville Road P.O. Box 15417 Wilmington, DE 19850-5417 (302)-996-2000/(800)-345-8104 Bercen, Inc. 1381 Cranston St. Cranston, RI 02920-6789 (401)-943-7400/(800)-525-0595 Callaway Chemical Co. P.O. Box 2335 Columbus, GA 31993-3559 (404)-576-2000 Cargill, Inc. Box 5630 Minneapolis, MN 55440 (612)-475-6478 Cook Paint and Varnish Co. P.O. Box 419389 Kansas City, MO 64141-6389 (816)-391-8000

DuPont Polymer Products Dept. Wilmington, DE 19880 (302)-992-3475/(800)-441-7111 DynaGel, Inc. Wentworth Ave. and Plummer St. Calumet City, IL 60409 (708)-891-8400 Firestone Synthetic Rubber & Latex Co. P.O. Box 26611 Akron, OH 44319-0006 (216)-379-6538/(800)-282-0222 FMC Corp. Marine Colloids Div. 2000 Market St. Philadelphia, PA 19103 (215)-299-6000/(800)-526-3649 Freeman Chemical Corp. P.O. Box 996 217 Freeman Dr. Port Washington, WI 53074 (414)-284-5541/(800)-558-8658 Genesee Polymers Corp. 5251 Fenton Rd. P-0. Box 7047 Flint, MI 48057 (313)-238-4966

Suppliers’

B.F. Goodrich Co. 6100 Oak Tree Blvd. Cleveland, OH 44131 (216)-447-6000/(800)-528-0200 Goodvear Chemicals 1485-E. Archwood Ave. Akron, OH 44316 (216)-796-8812/(800)-321-2416 W.R. Grace & Co.-Conn. Organic Chemicals Div. Lexington, MA 02173 (617):861-6600 H & C Industries. Inc. 1311 Crenshaw Blvd. Torrance, CA 90501 (213)-328-3683

Henkel Polymers Div. 5325 South 9th Ave. LaGrange, IL 60525-3602 (312)-579-6150/(800)-237-4037 Hercules, Inc. Hercules Plaza Wilmington, DE 19894 (800)-247-4372 Hi-Tek Polymers Rhone-Poulenc Inc. 9808 Bluegrass Parkway Jeffersontown, KY 40299 (502)-499-4300/(800)-626-2613 Hoechst Celanese Corp. Route 202-206 P.O. Box 2500 Somerville, NJ 08876-1258 (201)-231-2268 Geo. A. Hormel & Co. P.O. Box 800 Austin, MN 55912 (507)-437-5608

Addresses

Huls America Inc. P.O. Box 456 80 Centennial Ave. Piscataway, NJ 08855-0456 (908)-980-6800/(800))-526-0339 ICI Resins US 730 Main St. Wilmington, MA 01887 (508)-658-6600/(800)-225-0947 Mobay Corp. Mobav Road Pittsburgh, PA 15205-9741 (412)-777-2000 Monsanto Chemical Co. 800 N. Lindbergh Blvd. St. Louis, MO 63167 (314)-694-1000/(800)-325-4330 Morton International, Inc. Specialty Chemicals Group P.O. Box 3089 Greenville, SC 29602 (803)-292-5700/(800)-962-3839 NL Chemicals, Inc. P.O. Box 700 Hightstown, NJ 08520 (609)-443-2500 Norland Products Inc. 695 Joyce Kilmer Ave. New Brunswick, NJ 08902 (201)-545-7828 Occidental Chemical Corp. PVC Resins and Compounds Armand Hammer Boulevard Box 699 Pottstown, PA 19464 C.J. Osborn P.O. Box 1310 Merchantville, NJ 08109 (609)-662-0128

427

428

Water-Soluble Resins

OxyChem Durez Division 673 Walck Road North Tonawanda, NY 14120

Thibaut and Walk& P-0. Box 296 Newark, NJ 07101 (201)-589-3331

(716)-696-6000/(800)-828-2020

Polysat Inc. 7240 State Rd. Philadelphia, PA 19135 (215)-332-7700 Ranbar Technology, Inc. 1114 Wm. Flinn Hwv. Glenshaw, PA 15116-2638 (412)-486-1111 Reichhold Chemicals, Inc. P-0. Box 13582 Research Triangle Park, NC 27709

TIC Gums, Inc. 4609 Richlynn Drive Belcamp, MD 21017 (301)-273-7300/(800)-221-3953 Union Carbide Corn. 39 Old Ridgebury ba. Danbury, CT 06817-0001 (203)-js4-5300/(800)-342-3698 Unocal Chemicals Division 1345 N. Meacham Rd. Schaumburg, IL 60196 (800)-CHEMS~~

(919)-361-7500/(800)-431-1920

Sartomer Co. Marshall Bldg. West Chester Pike West Chester, PA 19382 (215)-430-2200/(800)-345-8247 StanChem, Inc. 401 Berlin St. East Berlin, CT 06023 (203)-828-0571

R.T. Vanderbilt Co., Inc. 30 Winfield St. Norwalk, CT 06855 (203)-853-1400

TRADE

NAME INDEX

430

Water-Soluble Resins

Trade Name

Supplier

ABOKOTE AGEFLOC AGEQUAT AGESPERSE AG ESTAT AIRFLEX AIRVOL ALCOCLEAR ALKOX AQUA-HYDE AQUALON AQUATREAT AROLON AROLON

Abatron CPS Chemical CPS Chemical CPS Chemical CPS Chemical Air Products and Chemicals Air Products and Chemicals Alto Chemical H & C Industries Dock Resins Aqualon Alto Chemical NL Chemicals Reichhold Chemicals

BAYBOND BERSET

Mobay Bercen

CARBOSET CARGILL CELACOL CELLOSIZE CHEMIGUM CHEMPOL COROC COURLOSE CULMINAL

B.F. Goodrich Cargill Aceto (Courtaulds Acetate) Union Carbide Goodyear Chemicals Freeman Chemical Cook Paint and Varnish Aceto (Courtaulds Acetate) Aqualon

DARATAK DAREX DORESCO DRESINOL

W.R. Grace & Co. W.R. Grace & Co. Dock Resins Hercules

E LVANOL EPI-CURE EPI-REZ EPI-TEX EPOMIN EVERFLEX

DuPont Hi-Tek Polymers Hi-Tek Polymers Hi-Tek Polymers Aceto W.R. Grace & Co.

FLAVORSET FLEXBOND FLEXCRYL FURAL

Hormel Air Products and Chemicals Air Products and Chemicals Hercules

GAX G-CRYL GELCARIN GEON GOOD-RITE GOODYEAR

Henkel Henkel FMC B.F. Goodrich B.F. Goodrich Goodyear Chemicals

HALOFLEX HARTEX HERCOLYN HERCULES HIPURE HYCAR HYDROSIL HYSTRETCH

ICI Resins US Firestone Synthetic Rubber & Latex Hercules Hercules Norland Products B.F. Goodrich Huls America B.F. Goodrich

Trade Name Index

Trade Name

Supplier

IMPRANI L

Mobay

JAY F LOC

Callaway Chemical

KELSOL KLUCEL

Reichhold Chemicals Aqualon

LACTA R I N LYTRON

FMC Morton International

MARINE COLLOIDS METHOCEL MOBAY MOR-FL0

FMC Dow Chemical Mobay Morton International

NATROSOL NATROSOL NATROVIS NEOCRY L NEOREZ NEOTAC NUTRILOID

Aqualon Aqualon Aqualon ICI Resins US ICI Resins US ICI Resins US TIC Gums

PLUS

OXY

Occidental Chemical

PARC0 PARCRYL PEPTEIN PICCONOL PICCOPALE PICCOTAC PICCOTEX PICCOVAR PLIOCORD PLIOLITE PLIOWAY PLYOPHEN POLYOX POLYPRO POLYSAT PRIMACOR PRIMEKOTE PROTECTEIN

Thibaut and Walker Thibaut and Walker Hormel Hercules Hercules Hercules Hercules Hercules Goodyear Chemicals Goodyear Chemicals Goodyear Chemicals Oxychem Union Carbide Hormel Polysat Dow Chemical Co. Abatron Hormel

RES RESIMENE RHEOLATE RHODIGEL RHODOPOL

Unocal Chemicals Monsanto Chemical Reichhold Chemicals Rhone-Poulenc (R.T. Vanderbilt) Rhone-Poulenc (R.T. Vanderbilt)

SARTOMER SEAGE L SEAKEM SPENSOL STANCHEM STAYBELITE ESTER SUPER ALKYD SUPERCOL SUPER POLYESTER SUPER THANE

Sartomer FMC FMC Reichhold Chemicals StanChem Hercules Thibaut and Walker Aqualon Thibaut and Walker Thibaut and Walker

431

432

Water-Soluble Resins

Trade Name

Supplier

TIC TICALOSE TICAXAN TY LOSE

TIC Gums TIC Gums TIC Gums Hoechst-Celanese

UNISIZE

Air Products and Chemicals

VANCRY L VARCUM VERSAFLEX VINAC VINEX VINSOL VISCARIN

Air Products and Chemicals Oxychem W.R. Grace & Co. Air Products and Chemicals Air Products and Chemicals Hercules FMC

WINGTACK WINGTACK WINGTACK

EXTRA PLUS

Goodyear Chemicals Goodyear Chemicals Goodyear Chemicals

RESIN INDEX

434

Water-Soluble Resins

Resin

.*

Acrylamide Copolymers Acrylamide Polymers Acrylic Alkyd Copolymers Acrylic Dispersions Acrylic Emulsions Acrylic Emulsions Acrylic Emulsions Acrylic Latexes Acrylic Polymers Acrylic Resins Acrylic Resins Acrylic Resin Solution and Emulsions Acrylics Acrylics Adhesive Emulsions Alkyd Resins Alkyd Resins Alkyds Alkyds Alkyds Alkyds Alkyds-Non-oxidizing Alkyds-Oxidizing Amino Crosslinker Resins Anionic Polymers

Callaway Chemical Callaway Chemical Freeman Chemical Hi-Tek Polymers Air Products and Chemicals ICI Resins Thibaut and Walker B.F. Goodrich NL Chemicals Air Products and Chemicals Dock Resins Henkel Reichhold Chemicals Unocal Chemicals W.R. Grace & Co. Cook Paint and Varnish Ranbar Technology Freeman Chemical C.J. Osborn Thibaut and Walker Reichhold Chemicals Cargill Cargill Monsanto Chemical Alto Chemicals

Carboxylated Styrene Butadiene Carrageenan Cationic Polymers Cellulose Ethers Cellulose Ethers Cellulose Ethers Cellulose Gums Collagens Copolymer Latexes Copolymers Crosslinking Agents

Unocal Chemicals FMC Alto Chemical Aceto Aqualon Dow Chemical TIC Gums Hormel W.R. Grace Alto Chemical Bercen

DimethylaminefEpichlorohydrin Copolymers Dispersible Polymers

CPS Chemical Dow Chemical

Elastomeric Latexes Emulsion Copolymers Epoxy Coatings Epoxy Curing Agents Epoxy Resin Dispersions Epoxy Resins Epoxy Ester Emulsions Epoxy Esters Epoxy Esters Epoxy Esters Ethylene-Vinyl Chloride Emulsions

B.F. Goodrich Goodyear Chemicals Abatron Hi-Tek Polymers Hi-Tek Polymers Cook Paint and Varnish Hi-Tek Polymers Cargi II Freeman Chemical C.J. Osborn Air Products and Chemicals

Gelatin Gelatin Gelatin Guar Gum Guar Gum

Dynagel Hormel Norland Products Aqualon TIC Gums

Resin index

Resin

Supplier

Hydrocarbon Resin Emulsions Hydrocarbon Resin Emulsions Hydrocarbon Resins Hydroxyethylcellulose Hydroxyethylcellulose Hydroxyethylcellulose Hydroxypropyl Hydroxyethylcellulose

Hercules Polysat Goodyear Chemicals Aqualon Hoechst-Celanese Union Carbide Aqualon

Latex Concrete Coatings

Morton International

Methylhydroxyethyicellulose Monomers

Hoechst-Celanese Sartomer

Natural Latex Nitrile Latexes Nitrile Latexes

Firestone Synthetic Rubber & Latex B.F. Goodrich Goodyear Chemicals

Polyacrylic Acids Polyamide Resins Polyamines: Dimethyl Diallyl Ammonium Chloride Polyamine:Epichlorohydrin Polyamines:Melamine-Formaldehyde Polyesters Polyesters Polyesters Polyesters Polyesters Polyesters Polyethylene lmines Poly(ethylene oxide) Polymers Polyethylene Oxide Resin Polymer Emulsions Polymeric Aluminum Salts Polymeric Carboxylic Acids Polystyrene Latexes Polyurethane Dispersions Polyurethane Dispersions Polyvinyl Acetate Copolymer Emulsions Polyvinyl Acetate Homopolymer Emulsions Polyvinyl Alcohol Polyvinyl Alcohols Polyvinylidene Chlorides

Alto Chemical Henkel

Resin Dispersions Resins-Abrasive Rosin Emulsions

Hercules OxyChem Hercules

Silanes Silicone Resin Emulsions Sodium Carboxymethylcellulose Sodium Carboxymethylcellulose Sodium Polyacrylates Sodium Polymethacrylates Styrene-Acrylic Emulsions Styrene Acrylic Emulsions Styrene Acrylics Styrene/Butadiene Copolymer Latices Stvrene-Butadiene Latexes

Huls America Genesee Polymers Aqualon Hoechst-Celanese Alto Chemical Alto Chemical Air Products and Chemicals Reichhold Chemicals Unocal Chemicals Goodyear Chemicals B.F. Goodrich

Callaway Chemical Callaway Chemical Callaway Chemical Cargill Cook Paint and Varnish Freeman Chemical C.J. Osborn Reichhold Chemicals Thibaut and Walker Aceto Union Carbide H & C Industries Polysat CPS Chemical CPS Chemical Morton International ICI Resins Mobay Air Products and Chemicals Air Products and Chemicals Air Products and Chemicals DuPont Unocal Chemicals

435

436

Water-Soluble Resins

Resin

..

Suspension Resins

Occidental Chemical

Textile Resin Latexes

Goodyear Chemicals

Urethanes Urethanes

Reichhold Chemicals Thibaut and Walker

Vinyl Acetate-Ethylene Copolymer Vinyl Acetate-Ethylene Emulsions Vinyl Acetate-Ethylene Powders Vinyl Acetate Homopolymers Vinyl Acrylic Copolymer Emulsions Vinyl Acrylic Emulsion Vinyl Acrylics Vinyl/Acrylic Terpolymers Vinyl Chloride-Ethylene Resins Vinyl Chloride Latexes Vinyl Pyridine Latexes Vinyl Pyridine Latexes

Air Products and Chemicals Air Products and Chemicals Air Products and Chemicals Unocal Chemicals Thibaut and Walker Air Products and Chemicals Unocal Chemicals ICI Resins Air Products and Chemicals B.F. Goodrich B.F. Goodrich Goodyear Chemicals

Water Reducible Acrylics

C.J. Osborn

Xanthan Gums Xanthan Gums

TIC Gums R.T. Vanderbilt